JP2944300B2 - Fiberglass insulation - Google Patents

Fiberglass insulation

Info

Publication number
JP2944300B2
JP2944300B2 JP11976192A JP11976192A JP2944300B2 JP 2944300 B2 JP2944300 B2 JP 2944300B2 JP 11976192 A JP11976192 A JP 11976192A JP 11976192 A JP11976192 A JP 11976192A JP 2944300 B2 JP2944300 B2 JP 2944300B2
Authority
JP
Japan
Prior art keywords
oil
parts
weight
halogen compound
insulating material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP11976192A
Other languages
Japanese (ja)
Other versions
JPH05296387A (en
Inventor
忠 半沢
寿 新保
正道 池上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KYOEISHA KAGAKU KK
PARAMAUNTO GARASU KOGYO KK
Original Assignee
KYOEISHA KAGAKU KK
PARAMAUNTO GARASU KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KYOEISHA KAGAKU KK, PARAMAUNTO GARASU KOGYO KK filed Critical KYOEISHA KAGAKU KK
Priority to JP11976192A priority Critical patent/JP2944300B2/en
Publication of JPH05296387A publication Critical patent/JPH05296387A/en
Application granted granted Critical
Publication of JP2944300B2 publication Critical patent/JP2944300B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Thermal Insulation (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、ガラス繊維製断熱
材であって、不燃性、撥水性を有すると共に、防塵性を
有するガラス繊維製断熱材並びに該ガラス繊維製断熱材
に含浸されている水性エマルジョンに関するものであ
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a glass fiber heat insulating material, which is nonflammable, water repellent and dustproof, and impregnated in the glass fiber heat insulating material. It relates to an aqueous emulsion.

【0002】[0002]

【従来の技術】無機質繊維製断熱材、特にガラス繊維製
断熱材を製造するに当たって、通常ある厚さに成形する
ため、未硬化のフェノール樹脂、尿素その他の副成分か
らなる添加剤を、フェルト生地ウェブを形成する前に、
水溶液の形で均一に吹き付けるか又は含浸し、所定の温
度、時間で焼き付けて硬化成形して製品化されている。
2. Description of the Related Art In the manufacture of a heat insulating material made of inorganic fiber, particularly, a heat insulating material made of glass fiber, an additive composed of uncured phenolic resin, urea and other auxiliary components is usually added to a felt cloth to form a certain thickness. Before forming the web,
It is sprayed or impregnated uniformly in the form of an aqueous solution, baked at a predetermined temperature and time, and cured to form a product.

【0003】しかし、上記添加剤のみで処理した無機質
断熱材は、所定の寸法に切断するときに粉塵が発生し、
作業者或は施工業者等はマスクをかける等、それ相当の
対策を講じなければならない。従来この粉塵の対策とし
て上記添加剤に粉塵防止剤(鉱物油等)を併用して問題
解決に当たっている。
[0003] However, the inorganic heat insulating material treated only with the above-mentioned additives generates dust when cut into predetermined dimensions,
The worker or the contractor must take appropriate measures such as putting on a mask. Conventionally, as a countermeasure against this dust, a problem has been solved by using a dust inhibitor (such as mineral oil) in combination with the above additive.

【0004】[0004]

【発明が解決しようとする課題】前述のように、粉塵防
止剤は、ある程度粉塵防止効果が見られるが、 1)建設省告示第1828号による不燃材料試験の基材
試験において、温度の判定基準値が50℃以下の処、4
9℃と判定基準値に接近している(但し、2%付着、例
えば鉱物油をガラスウール1Kg当り0.5〜2.0%
付着したものでは50℃を超えてしまう)。 2)単独使用においては、撥水性のあるものがない。 3)従って、どうしてもシリコーン樹脂との併用が必要
である。
As mentioned above, the dust inhibitor has a certain dust-preventing effect. 1) In the base material test of the non-combustible material test according to the Ministry of Construction Notification No. 1828, the criteria for judging the temperature are as follows. Where the value is 50 ° C or less, 4
9 ° C., which is close to the criterion value (however, 2% adhesion, for example, 0.5 to 2.0% of mineral oil per 1 kg of glass wool)
If it adheres, it will exceed 50 ° C). 2) When used alone, none of them have water repellency. 3) Therefore, it is absolutely necessary to use the silicone resin together with the silicone resin.

【0005】かかる実状に鑑み、本発明は従来撥水剤と
防塵剤とを別個に使用している点を改良し、1種の薬剤
で撥水性と防塵性を付与でき、かつ不燃性をも有するガ
ラス繊維製断熱材を提供することにある。
In view of such circumstances, the present invention has improved the conventional use of a water repellent and a dustproof agent separately, and can impart water repellency and dustproofness with one kind of chemical, and have a nonflammable property. It is an object of the present invention to provide a glass fiber heat insulating material.

【0006】[0006]

【課題を解決するための手段】本発明は、ガラス繊維
に、鉱物油、合成油、天然油脂の少なくとも1種からな
る油分100重量部に対し、250℃以上で安定な耐熱
性を有するハロゲン化合物100〜10重量部が配合さ
れ、また界面活性剤が前記油分と、前記ハロゲン化合物
合計100重量部に対し、30〜5重量部配合され、更
に前記油分、ハロゲン化合物、界面活性剤の3成分合計
10〜80重量と、水90〜20重量の組成からな
る水性エマルジョンが含浸されているものである。
According to the present invention, glass fibers are made of at least one of mineral oils, synthetic oils and natural fats and oils.
That relative oil 100 parts by weight, is blended is 100 to parts by weight of the halogen-compound having a stable heat resistance at 250 ° C. or higher, and a surfactant is the oil, relative to the halogen compound per 100 parts by weight, 30 to 5 parts by weight, and further impregnated with an aqueous emulsion composed of a total of 10 to 80 % by weight of the three components of the oil, the halogen compound and the surfactant and 90 to 20 % by weight of water.

【0007】[0007]

【発明の実施の形態】本発明におけるガラス繊維製断熱
材は、特別のものではなく一般に使用されているものが
用いられる。
BEST MODE FOR CARRYING OUT THE INVENTION The glass fiber heat insulating material according to the present invention is not particularly limited, but a generally used material is used.

【0008】また、本発明における油分中、鉱物油とし
ては、例えばエッソ石油(社)、商品名320、合成油
としては、例えば日本油脂(社)製のポリブテン、商品
名ポリビス、天然油脂としては、例えば公知の硬化ひま
し油、ナタネ白絞油、ヤシ油又は牛脂硬化油等が使用で
きる。
In the oil component of the present invention , mineral oil is, for example, Esso Petroleum Co., Ltd., trade name 320, and synthetic oil is, for example, polybutene manufactured by Nippon Oil & Fats Co., Ltd., polybis, trade name is natural oil and fat. For example, known hardened castor oil, rapeseed white squeezed oil, coconut oil, or tallow hardened oil can be used.

【0009】更に、天然油脂としては、精製ラノリン油
が好ましく、またハロゲン化合物としては、例えば外観
が粘稠な液体で、250℃以上で安定な耐熱性を有する
ハロゲン化合物、特に有機臭素化合物が好ましく、また
界面活性剤としては公知のノニオン、アニオン、カチオ
ン、両性界面活性剤等各種のものが使用できる。
Furthermore, as the natural fats and oils, refined lanolin oil is preferred, and as the halogen compound, for example appearance in a viscous liquid, the halogen compound having a stable heat resistance at 250 ° C. or higher, and particularly organic bromine compound As the surfactant, various known surfactants such as nonionic, anionic, cationic and amphoteric surfactants can be used.

【0010】本発明における水性エマルジョンは、これ
に未硬化フェノール樹脂、尿素樹脂、アンモニア水、更
に通常使用している副成分としてのバインダーが併用で
きる。前記水性エマルジョンは、油分、ハロゲン化合
物、界面活性剤等の効果が夫々相乗されて撥水性、難燃
性に優れていると共に、更に粉塵の発生をほぼ完全に防
止することができる。
In the aqueous emulsion of the present invention , an uncured phenol resin, a urea resin, aqueous ammonia and a binder as a commonly used auxiliary component can be used in combination. The aqueous emulsion is excellent in water repellency and flame retardancy due to synergistic effects of an oil component, a halogen compound, a surfactant and the like, and can almost completely prevent generation of dust.

【0011】更に、本発明の水性エマルジョンは、従来
油分と未硬化フェノール樹脂、尿素樹脂等とのエマルジ
ョンが形成し難い点が改善され、未硬化フェノール樹
脂、尿素樹脂等を併用しても安定した水性エマルジョン
とすることができるという効果がある。
Further, the aqueous emulsion of the present invention is improved in that it is difficult to form an emulsion of an oil component and an uncured phenol resin, a urea resin or the like, and is stable even when an uncured phenol resin or a urea resin is used in combination. There is an effect that an aqueous emulsion can be obtained.

【0012】[0012]

【実施例】以下、実施例によって本発明を具体的に説明
する。 実施例1 精製ラノリン油(新日本理科社製、商品名 リカランD
G)12重量部(以下重量部を部で示す)、ネオペンチ
ルアルコールエステル油(日本油脂社製、商品名ニッサ
ンユニスターH334R)4部、ハロゲン化合物(Great Lak
es Chemical Corp.製、商品名 RHT4-DIOL)6部、乳化
剤としてポリオキシエチレンノニルフェノールエーテル
(H.L.B.16)0.5部を均一に混合し、乳化機ホモディ
スパーで激しく攪拌している水70部に上記混合液を加
えて粗乳化液を得た。これを高圧ホモジナイザー圧力3
00Kgf/cmに通して安定なエマルジョンを得た。
The present invention will be specifically described below with reference to examples. Example 1 Refined lanolin oil (manufactured by Shin Nippon Rika Co., Ltd., trade name Rikaran D)
G) 12 parts by weight (hereinafter referred to as parts by weight) , 4 parts of neopentyl alcohol ester oil (manufactured by NOF CORPORATION, trade name Nissan Unistar H334R), halogen compound (Great Lak)
es Chemical Corp., RHT4-DIOL (trade name), 6 parts, polyoxyethylene nonylphenol ether (HLB16) 0.5 part as an emulsifier were uniformly mixed and mixed in 70 parts of water vigorously stirred with an emulsifier homodisper. The mixture was added to obtain a crude emulsion. This is set to high pressure homogenizer pressure 3
Passing through 00 Kgf / cm 2 , a stable emulsion was obtained.

【0013】実施例2 実施例1と同一な精製ラノリン油及びハロゲン化合物を
夫々16部、10部及び乳化剤としてポリオキシエチレ
ンノニルフェノールエーテル(H.L.B.14)2
部、ポリオキシエチレンラウリルエーテル(H.L.
B.16)1部を混合し、実施例1と同様にして水70
部中に加えて安定なエマルジョンを得た。
Example 2 16 parts and 10 parts of the same purified lanolin oil and halogen compound as in Example 1, respectively, and polyoxyethylene nonylphenol ether (HLB 14) 2 as an emulsifier were used.
Part, polyoxyethylene lauryl ether (HL.
B. 16) One part was mixed, and water 70 was mixed in the same manner as in Example 1.
In addition, a stable emulsion was obtained.

【0014】比較例1 実施例1と同一な精製ラノリン油18部、塩素化パラフ
ィン(東ソウ社製、商品名 トヨパラックスA40)1
2部及びポリオキシエチレンノニルフェノールエーテル
(H.L.B.10.9)2部、ドデシルベンゼンスル
ホン酸カルシウム0.5部、ポリオキシエチレンラウリ
ルエーテル1部を混合し、実施例1と同様にして水70
部中に加えてエマルジョンを得た。
Comparative Example 1 18 parts of the same purified lanolin oil as in Example 1, chlorinated paraffin (Toyoparax A40, manufactured by Tosoh Corporation) 1
2 parts, 2 parts of polyoxyethylene nonylphenol ether (HLB 10.9), 0.5 part of calcium dodecylbenzenesulfonate and 1 part of polyoxyethylene lauryl ether were mixed, and the mixture was mixed in the same manner as in Example 1. Water 70
In addition, an emulsion was obtained.

【0015】比較例2 比較例1と同一の精製ラノリンを30部とした以外は、
比較例1と同様にしてエマルジョンを得た。実施例1〜
2及び比較例1、2で得られたエマルジョンの性状を表
1に示す。
Comparative Example 2 Except that 30 parts of the same purified lanolin as Comparative Example 1 was used,
An emulsion was obtained in the same manner as in Comparative Example 1. Example 1
Table 1 shows the properties of the emulsions obtained in Comparative Example 2 and Comparative Examples 1 and 2.

【0016】[0016]

【表1】 [Table 1]

【0017】次に、前記実施例2、比較例1及び比較例
2のエマルジョンをガラスを繊維化した直後に噴霧し、
集綿してマットを形成し、このマットを200〜250
℃の加熱炉内を通過させてバインダーを硬化させ、所定
の密度と厚さに調整してフェルト又はボードを作成して
ガラス繊維製断熱材を得た。得られたガラス繊維製断熱
材の粉塵発生率、撥水性及び不燃性を表2に示す。
Next, the emulsions of Example 2, Comparative Example 1 and Comparative Example 2 were sprayed immediately after fiberizing the glass,
Cotton is collected to form a mat, and this mat is
The mixture was passed through a heating furnace at a temperature of ℃ ° C. to cure the binder. The binder was adjusted to a predetermined density and thickness to prepare a felt or board to obtain a glass fiber heat insulating material. Table 2 shows the dust generation rate, water repellency, and nonflammability of the obtained glass fiber heat insulating material.

【0018】[0018]

【表2】 [Table 2]

【0019】尚、粉塵発生率は、JIS A 9523
の振動篩通過率により、また不燃性は、建設省告示第1
828号により、撥水性は、試験片を50×50mmに
切断し、水を入れた容器(容量5リットル)の水中に5
分間沈め、試験片が浮上するか否かを調べて性能を評価
する。
The dust generation rate is based on JIS A 9523.
According to the vibrating sieve passage rate of
According to No. 828, water repellency was measured by cutting a test piece into 50 × 50 mm and placing it in water in a container (5 liter capacity) containing water.
Submerge for a minute and check whether the test piece floats to evaluate its performance.

【0020】[0020]

【発明の効果】以上の如く本発明はガラス繊維製断熱材
に、油分、ハロゲン化合物及び界面活性剤の3成分を配
合している水性エマルジョンが含浸されており、これら
の成分の効果が夫々相乗され、建設省告示第1828号
による基材試験において、温度の判定基準値を20〜3
5℃と著しく抑えることができ、しかも難燃性、撥水性
に加えて優れた防塵効果を発揮することができる。ま
た、従来の技術のように、特にシリコーン樹脂を使用す
る必要がないという効果を奏することができる。
As described above, according to the present invention, the glass fiber insulation material is impregnated with an aqueous emulsion containing an oil component , a halogen compound and a surfactant, and the effects of these components are synergistic. In the base material test according to the Ministry of Construction Notification No. 1828, the reference value of the temperature was set to 20 to 3
The temperature can be remarkably suppressed to 5 ° C., and in addition to flame retardancy and water repellency, an excellent dustproof effect can be exhibited. Further, there is an effect that it is not necessary to use a silicone resin as in the related art.

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭62−40055(JP,A) (58)調査した分野(Int.Cl.6,DB名) F16L 59/02 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-62-40055 (JP, A) (58) Fields investigated (Int. Cl. 6 , DB name) F16L 59/02

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 ガラス繊維に、鉱物油、合成油、天然油
脂の少なくとも1種からなる油分100重量部に対し、
250℃以上で安定な耐熱性を有するハロゲン化合物1
00〜10重量部が配合され、また界面活性剤が前記油
分と、前記ハロゲン化合物合計100重量部に対し、3
0〜5重量部配合され、更に前記油分、ハロゲン化合
物、界面活性剤の3成分合計10〜80重量と、水9
0〜20重量の組成からなる水性エマルジョンが含浸
されていることを特徴とするガラス繊維製断熱材。
Claims: 1. Mineral oil, synthetic oil , natural oil
With respect to 100 parts by weight of oil consisting of at least one kind of fat ,
Halogen compound 1 having stable heat resistance at 250 ° C. or higher
00 to 10 parts by weight, and the surfactant is added to the oil and the halogen compound in a total amount of 3 parts by weight based on 100 parts by weight.
0 to 5 parts by weight, and the oil and the halogen compound
And a surfactant in a total of 10 to 80 % by weight and water 9
A glass fiber heat insulating material impregnated with an aqueous emulsion having a composition of 0 to 20 % by weight.
JP11976192A 1992-04-13 1992-04-13 Fiberglass insulation Expired - Fee Related JP2944300B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11976192A JP2944300B2 (en) 1992-04-13 1992-04-13 Fiberglass insulation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11976192A JP2944300B2 (en) 1992-04-13 1992-04-13 Fiberglass insulation

Publications (2)

Publication Number Publication Date
JPH05296387A JPH05296387A (en) 1993-11-09
JP2944300B2 true JP2944300B2 (en) 1999-08-30

Family

ID=14769525

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11976192A Expired - Fee Related JP2944300B2 (en) 1992-04-13 1992-04-13 Fiberglass insulation

Country Status (1)

Country Link
JP (1) JP2944300B2 (en)

Also Published As

Publication number Publication date
JPH05296387A (en) 1993-11-09

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