JP2921201B2 - Decorative material - Google Patents
Decorative materialInfo
- Publication number
- JP2921201B2 JP2921201B2 JP23183491A JP23183491A JP2921201B2 JP 2921201 B2 JP2921201 B2 JP 2921201B2 JP 23183491 A JP23183491 A JP 23183491A JP 23183491 A JP23183491 A JP 23183491A JP 2921201 B2 JP2921201 B2 JP 2921201B2
- Authority
- JP
- Japan
- Prior art keywords
- plating
- decorative member
- present
- gold
- plating layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Description
【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION
【０００１】[0001]
【産業上の利用分野】本発明は、装飾部材のメッキ構成
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a plating structure for a decorative member.
【０００２】[0002]
【従来の技術】従来の携帯時計、メガネフレームなどの
装飾部材の表面処理による金色または 金色と白色の
二色メッキ構成は、該部材表面に 下地メッキとして 耐食性等の基本品質を有する
Ｎｉ、ＮｉーＰ等のメッキ層を被覆した後、該表面に
仕上げメッキとして 所望の色調を有するＡｕーＮｉ、
Ａｕ−Ｎｉ−Ｉｎ等のメッキ層を被覆積層した金色の装
飾部材。2. Description of the Related Art Conventional gold plating or two-color plating of gold and white by surface treatment of decorative members such as portable watches and eyeglass frames has basic qualities such as corrosion resistance as a base plating on the surface of the member.
After coating a plating layer of Ni, Ni-P, etc.,
Au-Ni with desired color tone as finish plating,
A gold decorative member in which a plating layer of Au-Ni-In or the like is coated and laminated.
【０００３】 前記 の金色の装飾部材の表面に
ＰｄーＮｉ等の白色仕上げメッキ層を 部分選択的に被
覆積層して 金色と白色の二色に構成をした装飾部材が
主流であった。[0003] On the surface of the golden decorative member
A decorative member mainly composed of two colors of gold and white by partially covering and laminating a white finish plating layer such as Pd-Ni was mainly used.
【０００４】[0004]
【発明が解決しようとする課題】しかし、前述の金色
または 金色と白色の二色の構成を有する装飾部材で
は、Ｎｉ含有メッキを使用しているため、一部のＮｉア
レルギー体質の人が携帯した際に、かぶれ、肌荒れなど
の炎症を起こしてしまうという欠点を有していた。However, the aforementioned gold color
Or, decorative members having a two-color configuration of gold and white use Ni-containing plating, so that some Ni-allergic persons carry inflammation, such as rash and rough skin, when they carry them. Had disadvantages.
【０００５】本発明は、これらの課題を解決するもの
で、その目的とするところは、装飾部材としての耐食性
等の基本品質を有し、かつ 所望の金色 または 金色
と白色の二色を有するＮｉを含有しないメッキ層で構成
し、Ｎｉによる肌荒れ等の炎症を起こさない装飾部材を
提供することにある。The present invention solves these problems. It is an object of the present invention to provide Ni having a basic quality such as corrosion resistance as a decorative member and a desired gold or two colors of gold and white. An object of the present invention is to provide a decorative member which is constituted by a plating layer containing no Ni and does not cause inflammation such as rough skin due to Ni.
【０００６】[0006]
【課題を解決するための手段】本発明の装飾部材は、
合金素材の表面上にＣｕ、Ｃｏ、Ｐｄ、Ａｇ、Ｉｎ、
Ｐｄ−Ｃｏ、Ｐｄ−Ａｇ、Ｓｎ−Ｃｕ、Ｓｎ−Ｚｎ、Ａ
ｇ−Ｓｎ、Ｐｂ−Ｓｎ、Ｃｕ−Ｓｎ−Ｚｎメッキの内の
二種以上の下地メッキ層を被覆構成し、該表面上にＡｕ
−Ｃｏ、Ａｕ−Ｐｄ、Ａｕ−Ｓｎ、Ａｕ−Ｐｄ−Ｃｕ、
Ａｕ−Ｐｄ−Ｉｎ、Ａｕ−Ｃｏ−Ｉｎ、Ａｕ−Ａｇ−Ｃ
ｕ、Ａｕ−Ａｇ、Ａｕ−Ｃｕ、Ａｕメッキの内の一種ま
たは二種以上の仕上げメッキ層を被覆構成したことを特
徴とする。The decorative member of the present invention comprises:
Cu, Co, Pd, Ag, In, on the surface of the alloy material
Pd-Co, Pd-Ag, Sn-Cu, Sn-Zn, A
g-Sn, Pb-Sn, and Cu-Sn-Zn plating are coated with at least two types of underlying plating layers, and Au is formed on the surface.
-Co, Au-Pd, Au-Sn, Au-Pd-Cu,
Au-Pd-In, Au-Co-In, Au-Ag-C
It is characterized in that one or more of the u, Au-Ag, Au-Cu, and Au platings are coated with a finish plating layer.
【０００７】 の金色の装飾部材表面上に、Ｐｄ−
Ｃｏ、Ｐｄ、Ｐｔ、Ｒｈ、Ｒｕ、Ｃｒメッキの内の一種
の白色メッキ層を部分選択的に被覆積層し、金色と白色
の 二色に構成したことを特徴とする。[0007] Pd-
One type of white plating layer of Co, Pd, Pt, Rh, Ru, and Cr plating is partially selectively coated and laminated to form two colors of gold and white.
【０００８】[0008]
【作用】本発明の上記構成によれば、Ｎｉを使用しない
メッキ構成であるから、一部のＮｉアレルギー体質の人
が携帯した際に、汗に含まれる塩化ナトリウム等の電解
質が、Ｎｉの溶出を助長せしめ、イオン化して、皮膚が
それを吸収し Ｎｉアレルギーを起こし、かぶれてく
る現象を防止し、しかも 耐食性等の基本品質および
装飾性を満足させる。According to the above-mentioned structure of the present invention, since the plating structure does not use Ni, when some Ni-allergic persons carry it, the electrolyte such as sodium chloride contained in sweat causes the elution of Ni. The skin absorbs it and causes Ni allergy, prevents rash phenomenon, and has basic quality such as corrosion resistance.
Satisfies the decorativeness.
【０００９】[0009]
【実施例】以下本発明について、［実施例群Ａ］および
［実施例群Ｂ］に基づいて 説明する。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below based on [Example group A] and [Example group B].
【００１０】［実施例群Ａ］図１から図６は 本発明請
求項１の［実施例群Ａ］の装飾部材のメッキ構成を示す
断面図である。黄銅あるいは亜鉛合金により形成された
時計用外装部品を素材とし、該素材表面上に 一種また
は二種以上の下地メッキ層を 表１〜表２に示したメッ
キ条件にて被覆形成した。さらに、該下地メッキ層上に
一種または二種以上の仕上げメッキ層を 表３〜表４
に示したメッキ条件にて被覆積層した。図１〜図６に示
した各々のメッキ構成毎に 本発明実施例Ｎｏ．１〜Ｎ
ｏ．１２０、比較例Ｎｏ．１〜Ｎｏ．１５との合計１３
５例を サンプルとし時計用外装部品に用い、携帯時計
を完成させた後、Ｎｉ非溶出性、密着性、耐摩耗性 お
よび 耐食性について評価した結果と メッキ構成等を
まとめて表５〜 表１２に整理した。Embodiment Group A FIGS. 1 to 6 are sectional views showing a plating structure of a decorative member according to a first embodiment of the present invention. A watch exterior part made of brass or a zinc alloy was used as a material, and one or more base plating layers were formed on the surface of the material under the plating conditions shown in Tables 1 and 2. Further, one or two or more finish plating layers are provided on the base plating layer.
Under the plating conditions shown in FIG. Each of the plating configurations shown in FIGS. 1 to N
o. 120, Comparative Example No. 1 to No. 15 and 13 in total
Tables 5 to 12 summarize the results of the evaluation of Ni non-elution, adhesion, abrasion resistance and corrosion resistance and the plating composition, etc., after completing the mobile watch using the five cases as samples and used as watch exterior parts. Tidy.
【００１１】[0011]
【表１】 [Table 1]
【００１２】[0012]
【表２】 [Table 2]
【００１３】[0013]
【表３】 [Table 3]
【００１４】[0014]
【表４】 [Table 4]
【００１５】[0015]
【表５】 [Table 5]
【００１６】[0016]
【表６】 [Table 6]
【００１７】[0017]
【表７】 [Table 7]
【００１８】[0018]
【表８】 [Table 8]
【００１９】[0019]
【表９】 [Table 9]
【００２０】[0020]
【表１０】 [Table 10]
【００２１】[0021]
【表１１】 [Table 11]
【００２２】[0022]
【表１２】 [Table 12]
【００２３】前述の 表５〜表１２に示す 評価特性に
対する 評価基準を表１３に示す。Table 13 shows evaluation criteria for the evaluation characteristics shown in Tables 5 to 12.
【００２４】[0024]
【表１３】 [Table 13]
【００２５】次に、各評価特性の 評価方法について以
下述べる。Next, a method for evaluating each evaluation characteristic will be described below.
【００２６】評価に当たっては、基本的には ＪＩＳ
Ｈー８６２２の装飾用金および金合金メッキに準じて行
った。Basically, JIS was used for the evaluation.
The plating was performed in accordance with the decorative gold and gold alloy plating of H-8622.
【００２７】被膜厚は、ＪＩＳ Ｈー８５２１の 顕微
鏡断面試験方法により 層の厚さを求めた。The thickness of the layer was determined by a microscope cross section test method according to JIS H-8521.
【００２８】耐摩耗性は、牛皮上に携帯時計の側面を密
着させ ５００ｇ荷重を携帯時計に加えながら、５ｃｍ
ストロークにて３万回擦って摩耗させた携帯時計側面の
被膜の摩耗程度を確認した。The wear resistance was measured by placing the side of the portable watch on cowhide in close contact with the watch and applying a load of 500 g to the watch for 5 cm.
The degree of wear of the film on the side of the mobile watch that was worn by rubbing 30,000 times with the stroke was confirmed.
【００２９】密着性は、携帯時計をバイスにて両端より
圧縮荷重を加え、折曲部が９０゜以上になるようにして
折曲部の被膜の剥離程度を調べた。The adhesion was measured by applying a compressive load from both ends to a portable watch with a vise so that the bent portion became 90 ° or more, and the degree of peeling of the coating on the bent portion was examined.
【００３０】耐食性については、人工汗、人工海水（３
％ＮａＣｌ）中に携帯時計完成品を４０℃×９０％の温
湿雰囲気中で２０時間 携帯時計の半分を浸漬し、腐食
および変色の発生を調べた。Regarding corrosion resistance, artificial sweat, artificial seawater (3
% Watch) was immersed in a hot and humid atmosphere of 40 ° C. × 90% for 20 hours, and the occurrence of corrosion and discoloration was examined.
【００３１】Ｎｉ検出方法については、デンマークの
「ニッケル含有製品販売禁止行政命令」４７２条（１９
８９年６月２７日付け）に定められた許容基準「遊離の
ニッケルが０．５μｇ／ｃｍ2／週以下」を 満足して
いるかどうか、該法令に定められた検出方法（１％ジメ
チルグリオキシムエチルアルコール溶液と １０％アン
モニア水を用い 綿布上に それぞれの溶液を２滴ずつ
滴下し、その布で３０秒間一定の動作で試料の表面を擦
りつけ、薄い赤から明るい赤の範囲での 赤色変化の程
度を見る。そして、赤い色を検出しない場合は、０．５
μｇ／ｃｍ2／週以下とみなす。）で評価した。（薄い
赤から明るい赤の範囲での赤色変化は、Ｎｉ最少溶出検
出量が ０．５μｇ／ｃｍ2／週を 越えていることを
示す）。Regarding the method for detecting Ni, see Denmark's “Administrative Order Prohibiting the Sale of Nickel-Containing Products”, Article 472 (19).
To determine whether the free nickel satisfies the acceptable standard “0.5 μg / cm 2 / week or less” specified on June 27, 1989, the detection method (1% dimethylglyoxime Ethyl alcohol solution and 10% ammonia water are used to drop two drops of each solution on a cotton cloth, and the surface of the sample is rubbed with the cloth for 30 seconds with a constant movement to change the red color from light red to bright red. And if no red color is detected, 0.5
Considered to be less than μg / cm 2 / week. ). (A red change in the range from light red to light red indicates that the minimum detectable Ni elution is greater than 0.5 μg / cm 2 / week).
【００３２】本発明における前記本発明［実施例群Ａ］
の実施例Ｎｏ．１〜Ｎｏ．１２０のサンプルにおいて、
黄銅あるいは亜鉛合金を素材とした 新規のメッキ構成
による携帯時計完成品は、装飾的価値の高い金色色調を
呈し、Ｎｉ検出試験においては、すべて 全く検出され
ず Ｎｉによるアレルギーに対し 高い防止効果が確認
できた。さらに人工汗および人工海水の耐食試験にて腐
食の発生が見られず、また 折り曲げによる密着性試験
および 牛皮による耐摩耗性試験においては、本発明
実施例Ｎｏ．１〜Ｎｏ．１２０のいずれにおいても、密
着性品質、耐摩耗性品質は、時計用外装部品として十分
であった。次に 比較例Ｎｏ．１〜Ｎｏ．１５のうち
Ｎｏ．２、Ｎｏ．４、Ｎｏ．５、Ｎｏ．７、Ｎｏ．１
０、Ｎｏ．１１、Ｎｏ．１２、Ｎｏ．１３、Ｎｏ．１５
に示すように 仕上げメッキ層にＮｉを含有したメッキ
を被覆した従来構成は、Ｎｉ検出試験において 強いＮ
ｉの溶出が見られた。また比較例Ｎｏ．１、Ｎｏ．３、
Ｎｏ．６、Ｎｏ．８、Ｎｏ．９、Ｎｏ．１４に示すよう
に、仕上げメッキ層にＮｉ含有メッキを使わなくても、
下地メッキ層にＮｉ含有メッキを被覆した構成では、Ｎ
ｉ検出試験において下地メッキ層のＮｉ成分より 若干
のＮｉ溶出が確認された。つまり、下地メッキ層および
仕上げメッキ層の少なくとも一層に Ｎｉ含有メッキを
被覆した比較例Ｎｏ．１〜Ｎｏ．１５においては、Ｎｉ
検出試験において Ｎｉの溶出がありＮｉアレルギーに
対する防止効果は無いといえる。また、比較例において
密着性、耐摩耗性および耐食性については、携帯時計
として十分であった。The present invention in the present invention [Example group A]
Example No. 1 to No. In 120 samples,
The finished mobile watch with a new plating composition made of brass or zinc alloy has a golden color tone with high decorative value, and is not detected at all in the Ni detection test, confirming a high protective effect against allergy due to Ni. did it. Furthermore, no corrosion was observed in the corrosion test of artificial sweat and artificial seawater, and in the adhesion test by bending and the abrasion resistance test by cowhide, Example No. of the present invention was used. 1 to No. In any of Nos. 120, the quality of adhesion and the quality of abrasion resistance were sufficient as exterior parts for watches. Next, in Comparative Example Nos. 1 to No. Out of 15
No. 2, No. 4, no. 5, no. 7, no. 1
0, No. 11, No. 12, No. 13, No. Fifteen
The conventional configuration in which the plating layer containing Ni is coated on the finish plating layer as shown in FIG.
Elution of i was observed. In Comparative Example No. 1, No. 3,
No. 6, no. 8, No. 9, No. As shown in FIG. 14, even without using Ni-containing plating for the finish plating layer,
In the configuration in which the underlying plating layer is coated with Ni-containing plating, N
In the i detection test, a slight elution of Ni from the Ni component of the base plating layer was confirmed. That is, in Comparative Example No. 1 in which at least one of the base plating layer and the finish plating layer was coated with the Ni-containing plating. 1 to No. In No. 15, Ni
In the detection test, Ni was eluted, and it can be said that there was no preventive effect against Ni allergy. Further, in the comparative example, the adhesion, abrasion resistance and corrosion resistance were sufficient for a portable watch.
【００３３】以上金色仕上げを行う場合の 図１〜図６
に示した被覆構成を応用した本発明の［実施例群Ａ］に
ついて述べた。FIGS. 1 to 6 in the case of performing the above-mentioned gold finishing
[Example Group A] of the present invention to which the coating structure shown in FIG.
【００３４】［実施例群Ｂ］図７〜図１２は、本発明請
求項２の［実施例群Ｂ］の装飾部材のメッキ構成を示す
断面図である。黄銅あるいは亜鉛合金により形成された
時計用外装部品を素材とし、該素材上に 一種または二
種以上の下地メッキ層を被覆し、次に該下地メッキ層上
に 一種または二種以上の金色仕上げメッキ層を被覆
し、さらに金色の仕上げメッキ層を残す部分の表面上に
有機レジストを塗り、次にＰｄーＣｏ、Ｐｄ、Ｐｔ、Ｒ
ｈ，Ｒｕ、Ｃｒメッキの内の一種の白色部分メッキを行
ったのち、有機レジストを有機溶剤により除去し、最終
的に金色と白色の二色に構成した。[Embodiment Group B] FIGS. 7 to 12 are sectional views showing a plating structure of a decorative member according to a second embodiment of the present invention. A watch exterior part made of brass or zinc alloy is used as a material, and one or more undercoating layers are coated on the material, and then one or more gold finish plating on the undercoating layer Organic resist is applied on the surface where the layer is to be coated and the gold finish plating layer is left, and then Pd-Co, Pd, Pt, R
After white plating, a kind of h, Ru, and Cr plating, was performed, the organic resist was removed with an organic solvent to finally form two colors of gold and white.
【００３５】下地メッキ層および金色の仕上げメッキ層
は 請求項１の［実施例群Ａ］と同様の それぞれ表１
〜表２、表３〜表４に示したメッキ条件にて被覆形成
し、また白色の部分メッキ層は 表１４に示したメッキ
条件にて被覆した。図７〜図１２に示した各々のメッキ
構成毎に本発明［実施例群Ｂ］の実施例Ｎｏ．１〜Ｎ
ｏ．６、比較例Ｎｏ．１〜Ｎｏ．６の合計１２例をサン
プルとし 時計用外装部品を用い携帯時計を完成させた
後、Ｎｉ非溶出性・耐摩耗性・密着性および耐食性につ
いて評価した結果と メッキ構成等をまとめて 表１５
に整理した。なお表１５に示す評価特性に対する評価基
準については、［実施例群Ａ］に示した表１３と全く同
様に行った。The undercoating layer and the gold finish plating layer are the same as those of [Example group A] of claim 1 respectively.
The coating was formed under the plating conditions shown in Tables 2 and 3 and Table 4, and the white partial plating layer was coated under the plating conditions shown in Table 14. For each of the plating configurations shown in FIGS. 1 to N
o. 6, Comparative Example No. 1 to No. Table 12 summarizes the results of evaluation of Ni non-elution, abrasion resistance, adhesion and corrosion resistance, and the plating composition, etc., after completing a mobile watch using the watch exterior parts using a total of 12 cases as samples.
Organized. The evaluation criteria for the evaluation characteristics shown in Table 15 were exactly the same as those in Table 13 shown in [Example Group A].
【００３６】[0036]
【表１４】 [Table 14]
【００３７】[0037]
【表１５】 [Table 15]
【００３８】さて、前記本発明［実施例群Ｂ］の実施例
Ｎｏ．１〜Ｎｏ．６のサンプルにおいては、［実施例群
Ａ］と同様に、Ｎｉ検出試験においては Ｎｉの溶出が
全く見られず Ｎｉアレルギーに対し高い防止効果が確
認できた。また、密着性・耐摩耗性・耐食性についても
携帯時計として十分であった。次に比較例Ｎｏ．１〜
Ｎｏ．６については、下地メッキ層、仕上げメッキ層の
少なくとも一層以上にＮｉ含有メッキを使用しているた
め Ｎｉ検出試験にてＮｉの溶出が見られ、いずれもＮ
ｉアレルギーに対する防止効果が見られなかった。しか
し 耐摩耗性・密着性・耐食性については 携帯時計と
して十分であった。Now, the embodiment No. of the present invention [embodiment group B] will be described. 1 to No. In sample No. 6, as in [Example Group A], no Ni elution was observed in the Ni detection test, and a high preventive effect against Ni allergy was confirmed. In addition, adhesion, abrasion resistance, and corrosion resistance were sufficient for mobile watches. Next, in Comparative Example Nos. 1 to
No. As for No. 6, since Ni-containing plating was used for at least one of the base plating layer and the finish plating layer, the elution of Ni was observed in the Ni detection test.
i. No protective effect against allergy was observed. However, the wear resistance, adhesion, and corrosion resistance were sufficient for mobile watches.
【００３９】[0039]
【発明の効果】以上述べたように 本発明によれば、合
金素材の表面上に Ｃｕ、Ｃｏ，Ｐｄ、Ａｇ、Ｉｎ、Ｐ
ｄ−Ｃｏ、Ｐｄ−Ａｇ、Ｓｎ−Ｃｕ、Ｓｎ−Ｚｎ、Ａｇ
−Ｓｎ、Ｐｂ−Ｓｎ、Ｃｕ−Ｓｎ−Ｚｎメッキの内の一
種または二種以上の下地メッキ層を構成し、該表面上に
ＡｕーＣｏ、ＡｕーＰｄ、ＡｕーＳｎ、ＡｕーＰｄー
Ｃｕ、ＡｕーＰｄーＩｎ、ＡｕーＣｏ−Ｉｎ、Ａｕ−Ａ
ｇーＣｕ、Ａｕ−Ａｇ、ＡｕーＣｕ、Ａｕメッキの一種
または二種以上の金色仕上げメッキ層を被覆積層するこ
とを特徴とし、さらに該金色装飾部材表面に Ｐｄ−Ｃ
ｏ、Ｐｄ、Ｐｔ、Ｒｈ、Ｒｕ、Ｃｒメッキの内の一種の
白色メッキを部分選択的に被覆し、金色と白色の二色構
成したことを特徴とすることから、次のような効果を有
する。As described above, according to the present invention, Cu, Co, Pd, Ag, In, P
d-Co, Pd-Ag, Sn-Cu, Sn-Zn, Ag
One or two or more of the Sn, Pb-Sn, and Cu-Sn-Zn plating layers are formed, and Au-Co, Au-Pd, Au-Sn, and Au-Pd-Cu are formed on the surface. , Au-Pd-In, Au-Co-In, Au-A
g-Cu, Au-Ag, Au-Cu, Au plating or one or more of gold-colored finish plating layers, and furthermore, Pd-C
One of white platings of o, Pd, Pt, Rh, Ru, and Cr platings is partially selectively coated to form two colors of gold and white, and thus has the following effects. .
【００４０】Ｎｉを使用しないメッキ構成であるから、
一部のＮｉアレルギー体質の人が携帯した際に、汗に含
まれる塩化ナトリウム等の電解質が Ｎｉの溶出を助長
せしめ、イオン化して、皮膚がそれを吸収しニッケルア
レルギーを起こし、かぶれてくるような現象を防止し、
しかも 密着性・耐食性・耐摩耗性およびデザインバラ
ェティーに富んだ時計用外装・メガネフレーム、指輪、
ネックレス、イヤリング等の装飾部材を提供できる。こ
のように 本発明の効果は極めて大きい。Since the plating structure does not use Ni,
When carried by some Ni-allergic individuals, electrolytes such as sodium chloride contained in sweat can promote the elution of Ni and ionize it, causing the skin to absorb it and cause nickel allergies and rash. To prevent unwanted phenomena,
In addition, watch exteriors, eyeglass frames, rings, etc., which are rich in adhesion, corrosion resistance, abrasion resistance and design variety
Decorative members such as necklaces and earrings can be provided. Thus, the effect of the present invention is extremely large.
【図１】 本発明の［実施例群Ａ］の装飾部材のメッキ
構成を示す断面図。FIG. 1 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group A] of the present invention.
【図２】 本発明の［実施例群Ａ］の装飾部材のメッキ
構成を示す断面図。FIG. 2 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group A] of the present invention.
【図３】 本発明の［実施例群Ａ］の装飾部材のメッキ
構成を示す断面図。FIG. 3 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group A] of the present invention.
【図４】 本発明の［実施例群Ａ］の装飾部材のメッキ
構成を示す断面図。FIG. 4 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group A] of the present invention.
【図５】 本発明の［実施例群Ａ］の装飾部材のメッキ
構成を示す断面図。FIG. 5 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group A] of the present invention.
【図６】 本発明の［実施例群Ａ］の装飾部材のメッキ
構成を示す断面図。FIG. 6 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group A] of the present invention.
【図７】 本発明の［実施例群Ｂ］の装飾部材のメッキ
構成を示す断面図。FIG. 7 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group B] of the present invention.
【図８】 本発明の［実施例群Ｂ］の装飾部材のメッキ
構成を示す断面図。FIG. 8 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group B] of the present invention.
【図９】 本発明の［実施例群Ｂ］の装飾部材のメッキ
構成を示す断面図。FIG. 9 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group B] of the present invention.
【図１０】 本発明の［実施例群Ｂ］の装飾部材のメッ
キ構成を示す断面図。FIG. 10 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group B] of the present invention.
【図１１】 本発明の［実施例群Ｂ］の装飾部材のメッ
キ構成を示す断面図。FIG. 11 is a cross-sectional view showing a plating configuration of a decorative member of [Example Group B] of the present invention.
【図１２】 本発明の［実施例群Ｂ］の装飾部材のメッ
キ構成を示す断面図。FIG. 12 is a cross-sectional view illustrating a plating configuration of a decorative member of [Example Group B] of the present invention.
１・・・・・・素材 ２・・・・・・下地メッキ層１ ３・・・・・・仕上げメッキ層１ ４・・・・・・仕上げメッキ層２ ５・・・・・・下地メッキ層２ ６・・・・・・下地メッキ層３ ７・・・・・・部分メッキ層 DESCRIPTION OF SYMBOLS 1 ... Material 2 ... Base plating layer 1 3 ... Finish plating layer 1 4 ... Finish plating layer 2 5 ... Base plating Layer 26: Base plating layer 37: Partial plating layer
───────────────────────────────────────────────────── フロントページの続き (72)発明者 真保 晃 長野県諏訪市大和３丁目３番５号セイコ ーエプソン株式会社内 (56)参考文献 特開 平２−310037（ＪＰ，Ａ) 特開 昭49−105572（ＪＰ，Ａ) 特開 昭59−208093（ＪＰ，Ａ) (58)調査した分野(Int.Cl.6，ＤＢ名) C25D 5/00 - 7/12 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Akira Maho 3-5-5 Yamato, Suwa-shi, Nagano Seiko Epson Corporation (56) References JP-A-2-310037 (JP, A) JP-A-49 -105572 (JP, A) JP-A-59-208093 (JP, A) (58) Fields investigated (Int. Cl. 6 , DB name) C25D 5/00-7/12
Claims (2)
ｇ、Ｉｎ、Ｐｄ−Ｃｏ、Ｐｄ−Ａｇ、Ｓｎ−Ｃｕ、Ｓｎ
−Ｚｎ、Ａｇ−Ｓｎ、Ｐｂ−Ｓｎ、Ｃｕ−Ｓｎ−Ｚｎメ
ッキの内の二種以上の下地メッキ層を被覆構成し、該表
面上にＡｕ−Ｃｏ、Ａｕ−Ｐｄ、Ａｕ−Ｓｎ、Ａｕ−Ｐ
ｄ−Ｃｕ、Ａｕ−Ｐｄ−Ｉｎ、Ａｕ−Ｃｏ−Ｉｎ、Ａｕ
−Ａｇ−Ｃｕ、Ａｕ−Ａｇ、Ａｕ−Ｃｕ、Ａｕメッキの
内の一種または二種以上の仕上げメッキ層を被覆構成し
たことを特徴とする装飾部材。1. Cu, Co, Pd, A on a surface of an alloy material
g, In, Pd-Co, Pd-Ag, Sn-Cu, Sn
-Zn, Ag-Sn, Pb-Sn, and Cu-Sn-Zn plating are coated with at least two types of base plating layers, and Au-Co, Au-Pd, Au-Sn, Au- P
d-Cu, Au-Pd-In, Au-Co-In, Au
-A decorative member characterized by being coated with one or more finish plating layers of Ag-Cu, Au-Ag, Au-Cu, and Au plating.
Ｐｄ−Ｃｏ、Ｐｄ、Ｐｔ、Ｒｈ、Ｒｕ、Ｃｒメッキの内
の一種の白色メッキ層を部分選択的に被覆積層し、金色
と白色の二色に構成したことを特徴とする装飾部材。2. On the surface of the golden decorative member according to claim 1,
A decorative member comprising two types of gold and white by selectively covering and laminating a kind of white plating layer of Pd-Co, Pd, Pt, Rh, Ru, and Cr plating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23183491A JP2921201B2 (en) | 1991-09-11 | 1991-09-11 | Decorative material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23183491A JP2921201B2 (en) | 1991-09-11 | 1991-09-11 | Decorative material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0570989A JPH0570989A (en) | 1993-03-23 |
| JP2921201B2 true JP2921201B2 (en) | 1999-07-19 |
Family
ID=16929746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23183491A Expired - Fee Related JP2921201B2 (en) | 1991-09-11 | 1991-09-11 | Decorative material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2921201B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0808921B1 (en) * | 1995-12-07 | 2001-11-14 | Citizen Watch Co., Ltd. | Ornamental member |
| GB2349391A (en) * | 1999-04-27 | 2000-11-01 | Mayfair Brassware Limited | Outer gold coated article |
| JP2002161393A (en) * | 2000-11-22 | 2002-06-04 | Bikutoria:Kk | Method for plating noble metal having corrosion resistance and noble metal plate accessories |
-
1991
- 1991-09-11 JP JP23183491A patent/JP2921201B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0570989A (en) | 1993-03-23 |
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