JP2908633B2 - Coagulant for tofu - Google Patents
Coagulant for tofuInfo
- Publication number
- JP2908633B2 JP2908633B2 JP4111316A JP11131692A JP2908633B2 JP 2908633 B2 JP2908633 B2 JP 2908633B2 JP 4111316 A JP4111316 A JP 4111316A JP 11131692 A JP11131692 A JP 11131692A JP 2908633 B2 JP2908633 B2 JP 2908633B2
- Authority
- JP
- Japan
- Prior art keywords
- tofu
- coagulant
- present
- magnesium chloride
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Beans For Foods Or Fodder (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は豆腐用凝固剤に関するも
のであり、特に塩化マグネシウムのように豆腐の凝固速
度の極めて速い速効性凝固剤の凝固速度を制御でき、内
相が均一で、また風味的にも非常に良好な豆腐を得るた
めの凝固剤に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coagulant for tofu, and more particularly to a coagulant for a fast-acting coagulant, such as magnesium chloride, which has a very high coagulation rate and has a uniform internal phase. The present invention relates to a coagulant for obtaining very good tofu also in flavor.
【0002】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
豆腐製造用凝固剤としては、塩化マグネシウム、塩化カ
ルシウム、硫酸カルシウム、グルコノデルタラクトン等
が使用されてきた。しかし、それぞれの凝固剤には一長
一短があり、出来上がった豆腐の内相が細かく均一で保
水性に富み、且つ食感及び風味に優れたものを製造する
ことは困難であった。その内でも塩化マグネシウムは最
も古くから使用されており、最も美味しい豆腐が製造で
きるといわれているが、その凝固速度は極めて速く、得
られた豆腐は内相の荒れた保水性の乏しいものになるの
が欠点である。また、一般的にはグルコノデルタラクト
ンのような遅効性凝固剤を使用すると、豆腐の内相が細
かく均一で保水性の良いものが得られるが、風味の点で
不十分であった。2. Description of the Related Art
Magnesium chloride, calcium chloride, calcium sulfate, glucono delta lactone and the like have been used as coagulants for tofu production. However, each coagulant has advantages and disadvantages, and it has been difficult to produce a product having a fine and uniform internal phase of the tofu, rich in water retention, and excellent in texture and flavor. Among them, magnesium chloride has been used for the longest time, and it is said that the most delicious tofu can be produced, but the coagulation rate is extremely fast, and the resulting tofu has poor internal phase and poor water retention This is a disadvantage. Generally, when a slow-acting coagulant such as glucono-delta-lactone is used, a tofu having a fine and uniform internal phase and good water retention can be obtained, but it is insufficient in flavor.
【0003】そこで、塩化マグネシウムの凝固速度をコ
ントロールするため、特開昭60−248148号公報に記載の
如く金属イオン封鎖剤や、特開昭61−88849 号公報に記
載の如く有機酸塩を併用する方法が提案された。しかし
ながら、これらは豆腐の風味に影響を及ぼすため好まし
くない。さらに、特開平2−203758号公報に記載の如く
凝固剤を可食性フィルムでコーティングする方法が提案
されたが、製造方法が煩雑であるため好ましくなかっ
た。このため、良好な風味を付与できる塩化マグネシウ
ムの凝固速度をコントロールし、風味が良好で、かつ均
一で高品質の豆腐を製造することのできる凝固剤が求め
られていた。Therefore, in order to control the solidification rate of magnesium chloride, a sequestering agent as described in JP-A-60-248148 and an organic acid salt as described in JP-A-61-88849 are used in combination. A way to do that was suggested. However, these are not preferred because they affect the flavor of the tofu. Furthermore, as described in JP-A-2-203758, a method of coating a coagulant with an edible film has been proposed, but it is not preferable because the production method is complicated. For this reason, a coagulant capable of controlling the solidification rate of magnesium chloride capable of imparting a good flavor and producing a uniform, high-quality tofu having a good flavor has been demanded.
【0004】[0004]
【課題を解決するための手段】本発明者らは、上記の課
題を解決するために鋭意検討した結果、塩化マグネシウ
ムをポリグリセリン脂肪酸エステル中に分散させ、それ
をジグリセライドで乳化することにより、塩化マグネシ
ウムの凝固速度をコントロールできることを見出し、本
発明を完成するに至った。即ち、本発明は、塩化マグネ
シウムとポリグリセリン脂肪酸エステルとジグリセライ
ドとを含有することを特徴とする豆腐用凝固剤を提供す
るものである。Means for Solving the Problems The present inventors have made intensive studies to solve the above problems, and as a result, disperse magnesium chloride in polyglycerin fatty acid ester and emulsify it with diglyceride to obtain chloride. The present inventors have found that the solidification rate of magnesium can be controlled, and have completed the present invention. That is, the present invention provides a coagulant for tofu characterized by containing magnesium chloride, polyglycerin fatty acid ester and diglyceride.
【0005】以下、本発明を詳細に説明する。本発明に
使用する塩化マグネシウムは、無水物、結晶水含有物の
どちらでも良い。また、ポリグリセリン脂肪酸エステル
としては、グリセリン単位が2〜15、好ましくは5〜10
のポリグリセリンと、炭素数が10〜24、好ましくは14〜
20の飽和又は不飽和脂肪酸からなるエステル、グリセリ
ン単位2〜15のポリグリセリンと炭素数10〜24のヒドロ
キシカルボン酸又はその縮合物からなるエステルが挙げ
られる。特にグリセリン単位が5〜10のポリグリセリン
と、直鎖又は分岐鎖、及び飽和もしくは不飽和の炭素数
10〜24、好ましくは14〜20のヒドロキシカルボン酸の2
〜10量体、好ましくは3〜6量体のポリヒドロキシカル
ボン酸からなるエステルが好ましい。このようなエステ
ルとしては、例えば、ポリグリセリンとリシノール酸の
縮合度が2〜10、好ましくは3〜6の縮合リシノレート
からなる群から選ばれる脂肪酸のエステル等が挙げら
れ、市販品には坂本薬品(株)製のSYグリスターCR
−310、CR−500、更に太陽化学(株)製のサン
ソフト818SK等がある。Hereinafter, the present invention will be described in detail. The magnesium chloride used in the present invention may be either anhydrous or containing water of crystallization. The polyglycerin fatty acid ester has a glycerin unit of 2 to 15, preferably 5 to 10
With polyglycerin, having 10 to 24 carbon atoms, preferably 14 to
Esters composed of 20 saturated or unsaturated fatty acids, and esters composed of polyglycerol having 2 to 15 glycerin units and hydroxycarboxylic acid having 10 to 24 carbon atoms or a condensate thereof. In particular, a polyglycerin having 5 to 10 glycerin units, a linear or branched chain, and a saturated or unsaturated carbon number
2 to 10 to 24, preferably 14 to 20, hydroxycarboxylic acids
Esters consisting of polyhydroxycarboxylic acids of from 10 to 10 mers, preferably from 3 to 6 mers, are preferred. Examples of such esters include fatty acid esters selected from the group consisting of condensed ricinoleates having a degree of condensation of polyglycerin and ricinoleic acid of 2 to 10, preferably 3 to 6, and commercially available products include Sakamoto Yakuhin SY Glister CR manufactured by Co., Ltd.
-310, CR-500, and Sunsoft 818SK manufactured by Taiyo Kagaku Co., Ltd.
【0006】また、ジグリセライドとしては、構成脂肪
酸の炭素数が6〜24のものが好ましく、これらの脂肪酸
とグリセリンをエステル化反応して得られるジグリセラ
イドの内、ジグリセライド純度が40%以上、好ましくは
60%以上のものが用いられる。このようなジグリセライ
ドとしては、例えばステアリン酸或いはオレイン酸のジ
グリセライド等が挙げられる。これらは1種もしくは2
種以上任意に用いられ、2種以上を併用する場合、その
まま混合してもよいし、飽和脂肪酸系ジグリセライドの
如く融点の高いものを用いる場合は、加熱等の手段によ
り均一混合して用いてもよい。[0006] The diglycerides are preferably those having 6 to 24 carbon atoms in the constituent fatty acids. Among the diglycerides obtained by esterifying these fatty acids with glycerin, the purity of the diglycerides is preferably at least 40%, more preferably
More than 60% is used. Examples of such diglycerides include diglycerides of stearic acid and oleic acid. These are one or two
When two or more kinds are used in combination, they may be mixed as they are, or when using a substance having a high melting point such as a saturated fatty acid-based diglyceride, they may be mixed uniformly by heating or the like. Good.
【0007】本発明の凝固剤中のジグリセライドとポリ
グリセリン脂肪酸エステルの重量比は99.9999:0.0001
〜0.0001:99.9999の範囲であり、好ましくは99.999:
0.001 〜0.001 :99.999の範囲である。ポリグリセリン
脂肪酸エステルの比率が上記範囲よりも高くなると豆乳
の凝固速度が著しく遅くなり、作業時間が長くかかりす
ぎる。また、できた豆腐の風味も悪くなる。また、ポリ
グリセリン脂肪酸エステルの比率が上記範囲よりも低く
なると、凝固速度のコントロール効果が劣り、均一な豆
腐が得難くなる。また、本発明の凝固剤において、ポリ
グリセリン脂肪酸エステル及びジグリセライドは、塩化
マグネシウムに対して、それぞれ1:0.05〜1:0.1 、
1:1〜1:3(重量比)の範囲で配合するのが好まし
い。The weight ratio of diglyceride to polyglycerin fatty acid ester in the coagulant of the present invention is 99.9999: 0.0001.
~ 0.0001: range of 99.9999, preferably 99.999:
0.001 to 0.001: The range is 99.999. When the ratio of the polyglycerin fatty acid ester is higher than the above range, the coagulation rate of soymilk becomes extremely slow, and the working time is too long. In addition, the flavor of the resulting tofu becomes worse. On the other hand, when the ratio of the polyglycerin fatty acid ester is lower than the above range, the effect of controlling the coagulation rate is inferior, and it is difficult to obtain uniform tofu. In the coagulant of the present invention, the polyglycerin fatty acid ester and the diglyceride are respectively 1: 0.05 to 1: 0.1 with respect to magnesium chloride,
It is preferable to mix them in the range of 1: 1 to 1: 3 (weight ratio).
【0008】更に、本発明の凝固剤の乳化状態は、任意
の量の水もしくは油脂等を加えて油中水型、水中油型も
しくは二重乳化型(O/W/O,W/O/W)等の多相
乳化型のいずれの状態にしても何ら効果には影響ない
が、菌による汚染等を考えると油中水型が好ましい。Further, the emulsified state of the coagulant of the present invention may be prepared by adding an arbitrary amount of water or oil or the like to a water-in-oil type, an oil-in-water type or a double emulsification type (O / W / O, W / O / In any state of the multi-phase emulsification type such as W), the effect is not affected at all, but the water-in-oil type is preferred in consideration of bacterial contamination and the like.
【0009】本発明の凝固剤の豆乳に対する添加量は、
本発明の凝固剤中の塩化マグネシウム量を通常豆乳に使
用する量、即ち、0.05〜0.5 重量%の範囲で用いれば良
い。また、本発明の凝固剤は、硫酸カルシウム、グルコ
ノデルタラクトンなどの他の豆腐用凝固剤と併用して使
用することもできる。本発明の凝固剤は、目的とする豆
腐の物性によって種々の配合で用いられるが、上記範囲
以内であれば、良好な物性の豆腐を得ることができ、絹
ごし豆腐、ソフト豆腐、木綿豆腐、凍豆腐、油揚などの
豆腐類製造に自由に使用できる。The amount of the coagulant of the present invention added to soymilk is as follows:
The amount of magnesium chloride in the coagulant of the present invention may be the amount usually used for soymilk, that is, 0.05 to 0.5% by weight. Further, the coagulant of the present invention can be used in combination with other tofu coagulants such as calcium sulfate and glucono delta lactone. The coagulant of the present invention is used in various combinations depending on the physical properties of the desired tofu, but within the above range, good physical properties of tofu can be obtained, and silky tofu, soft tofu, cotton tofu, and frozen tofu can be obtained. , Can be used freely for the production of tofu such as fried oil.
【0010】[0010]
【作用】本発明では、単に塩化マグネシウムをポリグリ
セリン脂肪酸エステル中に分散させただけでは蛋白質と
の反応速度がコントロールできず、ジグリセライドを系
内に添加することにより蛋白質溶液と接触した際に徐々
に乳化が破壊され、系内の塩化マグネシウムが順次蛋白
質と反応するようになる。従って、蛋白質との反応速度
がコントロールされ、豆乳の凝固速度を遅効性にする効
果が発現する。In the present invention, the reaction rate of the protein with the protein cannot be controlled only by dispersing magnesium chloride in the polyglycerol fatty acid ester. The emulsification is broken, and the magnesium chloride in the system reacts with the protein sequentially. Therefore, the reaction rate with the protein is controlled, and the effect of slowing down the coagulation rate of soymilk is exhibited.
【0011】[0011]
【実施例】以下、本発明を実施例により更に詳細に説明
するが、本発明はこれらの実施例に限定されるものでは
ない。EXAMPLES Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.
【0012】実施例1 定法により得られた絹ごし用豆乳の各々1000ml(品温90
℃)に、下記組成を有する本発明凝固剤を10g(塩化マ
グネシウムとして3.0 g)添加し、直方体の容器に入れ
静置し、凝固速度、凝固状態、及びできた豆腐の内相、
保水性、風味について専門パネラー10名にて5点法によ
り評価した。結果を表1に示す。Example 1 1000 ml of soymilk for silk sieving obtained by a conventional method (each having a temperature of 90
C), 10 g of the coagulant of the present invention having the following composition (3.0 g as magnesium chloride) is added, and the mixture is allowed to stand in a rectangular parallelepiped container. The solidification speed, the solidification state, and the inner phase of the resulting tofu,
Water retention and flavor were evaluated by a 10-point panelist using a 5-point method. Table 1 shows the results.
【0013】 <本発明凝固剤組成> 塩化マグネシウム(60% act.) 50 重量% オレイン酸ジグリセライド 49.9 〃 ポリグリセリン脂肪酸エステル 0.1 〃 (SYグリスターCR−310,坂本薬品(株)製) 比較例1 定法により得られた絹ごし用豆乳の各々1000ml(品温90
℃)に、塩化マグネシウム3.0 gを添加し、直方体の容
器に入れ静置し、凝固速度、凝固状態、及びできた豆腐
の内相、保水性、風味について専門パネラー10名にて5
点法により評価した。結果を表1に示す。<Coagulant composition of the present invention> Magnesium chloride (60% act.) 50% by weight Diglyceride oleate 49.9 {polyglycerin fatty acid ester 0.1} (SY Glister CR-310, manufactured by Sakamoto Yakuhin Co., Ltd.) Comparative Example 1 1000 ml of silky soy milk obtained by
℃), 3.0 g of magnesium chloride was added, and the mixture was allowed to stand in a rectangular parallelepiped container. The solidification rate, the solidification state, and the inner phase, water retention and flavor of the tofu were determined by 10 expert panelists.
It was evaluated by the point method. Table 1 shows the results.
【0014】比較例2 定法により得られた絹ごし用豆乳の各々1000ml(品温90
℃)に、グルコノデルタラクトン3.0 gを添加し、直方
体の容器に入れ静置し、凝固速度、凝固状態、及びでき
た豆腐の内相、保水性、風味について専門パネラー10名
にて5点法により評価した。結果を表1に示す。Comparative Example 2 1000 ml of soymilk for silk screening obtained by a conventional method (each having a temperature of 90
C)), add 3.0 g of glucono delta lactone, place in a rectangular parallelepiped container and let it stand. Five points by 10 expert panelists on coagulation speed, coagulation state, internal phase of tofu, water retention and flavor It was evaluated by the method. Table 1 shows the results.
【0015】[0015]
【表1】 [Table 1]
【0016】[0016]
【発明の効果】如上の如く本発明の凝固剤を使用するこ
とにより、豆乳の凝固性をコントロールすることがで
き、均一な内相、保水性、風味の点で優れた豆腐の製造
が可能になった。As described above, the use of the coagulant of the present invention makes it possible to control the coagulability of soy milk and to produce a tofu excellent in uniform internal phase, water retention and flavor. became.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭53−133653(JP,A) 特開 平5−304923(JP,A) 特公 昭62−5581(JP,B1) (58)調査した分野(Int.Cl.6,DB名) A23L 1/20 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-53-133653 (JP, A) JP-A-5-304923 (JP, A) JP-B-62-5581 (JP, B1) (58) Field (Int.Cl. 6 , DB name) A23L 1/20
Claims (1)
酸エステルとジグリセライドとを含有することを特徴と
する豆腐用凝固剤。1. A tofu coagulant comprising magnesium chloride, polyglycerin fatty acid ester and diglyceride.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4111316A JP2908633B2 (en) | 1992-04-30 | 1992-04-30 | Coagulant for tofu |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4111316A JP2908633B2 (en) | 1992-04-30 | 1992-04-30 | Coagulant for tofu |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH05304923A JPH05304923A (en) | 1993-11-19 |
JP2908633B2 true JP2908633B2 (en) | 1999-06-21 |
Family
ID=14558135
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4111316A Expired - Fee Related JP2908633B2 (en) | 1992-04-30 | 1992-04-30 | Coagulant for tofu |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2908633B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8739685B2 (en) | 2009-12-28 | 2014-06-03 | Takai Tofu & Soymilk Equipment Co. | Tofu coagulant producing apparatus and soymilk coagulation machine comprising the same |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000050827A (en) * | 1998-08-07 | 2000-02-22 | Yoshikawa Kagaku Kogyosho:Kk | Production of bean curd and emulsion-type coagulating agent therefor |
CN103444901A (en) * | 2009-10-28 | 2013-12-18 | 太子食品工业株式会社 | Method for producing tofu |
JP5385809B2 (en) * | 2010-02-02 | 2014-01-08 | 太子食品工業株式会社 | Tofu production method |
KR101212072B1 (en) * | 2009-12-11 | 2013-01-10 | (주)신선촌 | Coagulant For Bean Curd And Process for Preparing thereof |
JP7253732B2 (en) * | 2018-03-09 | 2023-04-07 | 味の素株式会社 | Method for producing tofu using enzyme, composition for coagulating soymilk, coagulant for tofu |
-
1992
- 1992-04-30 JP JP4111316A patent/JP2908633B2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8739685B2 (en) | 2009-12-28 | 2014-06-03 | Takai Tofu & Soymilk Equipment Co. | Tofu coagulant producing apparatus and soymilk coagulation machine comprising the same |
Also Published As
Publication number | Publication date |
---|---|
JPH05304923A (en) | 1993-11-19 |
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