JP2879372B2 - Electrophotographic photoreceptor, electrophotographic apparatus provided with the electrophotographic photoreceptor, and facsimile - Google Patents

Description

The present invention relates to an electrophotographic photosensitive member, an electrophotographic apparatus, and a facsimile, and more particularly, to an electrophotographic photosensitive member having a photosensitive layer containing a compound having a specific structure, The present invention relates to an electrophotographic apparatus and a facsimile provided with the electrophotographic photosensitive member.

[Prior Art] Conventionally, as an electrophotographic photosensitive member, an inorganic photosensitive member having a photosensitive layer containing selenium, zinc oxide, cadmium sulfide or the like as a main component has been widely used. Although they have some basic properties, they have problems such as difficulty in film formation, poor plasticity, and high production cost. Furthermore, inorganic photoconductive materials are generally highly toxic, and have great restrictions on production and handling.

On the other hand, an organic photoreceptor containing an organic photoconductive compound as a main component has many advantages such as compensating for the above-mentioned disadvantages of an inorganic photoreceptor, and has recently attracted attention. It has been put to practical use.

As such an organic photoreceptor, a photoconductive polymer represented by poly-N-vinylcarbazole and the like, 2,4,
An electrophotographic photoreceptor having a charge transfer complex formed from a Lewis acid such as 7-trinitro-9-fluorenone as a main component has been proposed. These organic photoconductive polymers are superior to inorganic photoconductive materials in terms of lightness, film formability, etc., but are inferior in terms of sensitivity, durability, stability due to environmental changes, etc., and are not always satisfactory. Not something.

On the other hand, a function-separated type electrophotographic photoreceptor in which a charge generation function and a charge transport function are respectively assigned to different substances has brought improvements in sensitivity and durability, which have been disadvantages of conventional organic photoreceptors. Such a function-separated type electrophotographic photosensitive member has an advantage that a material selection range of each of a charge generation material and a charge transport material is wide, and an electrophotographic photosensitive member having arbitrary characteristics can be relatively easily manufactured. .

As charge generation materials, various azo pigments, polycyclic quinone pigments, cyanine dyes, squaric acid dyes, pyrylium salt dyes, and the like are known.

Among them, many materials have been proposed as azo pigments because of their high light resistance, high charge generation ability, and easy material synthesis.

On the other hand, examples of charge transport materials include pyrazoline compounds described in JP-B-52-4188, hydrazone compounds described in JP-B-55-42380 and JP-A-55-52063, JP-B-58-32372 and JP-A-58-32372. Triphenylamine compounds described in JP-A-61-132955, JP-A-54-1519
Stilbene compounds and the like described in JP-A-55-55 and JP-A-58-198043 are known.

However, most of the charge transport materials mentioned here and charge transport materials used in organic electrophotographic photoreceptors which have been put to practical use have hole transporting properties. Conventionally, a photoreceptor using a charge transporting material having a hole transporting ability has a negative polarity for charging the photoreceptor because a substrate, a charge generating layer, and a charge transporting layer are sequentially laminated. Therefore, there arises a problem that the photoreceptor is chemically deteriorated by the ozone generated by the negative charge, and has a disadvantage that the printing resistance is remarkably low as compared with an inorganic photoreceptor such as a-Se or a-Si. Was.

As a countermeasure against photoconductor deterioration due to ozone generated by negative charging, an electrophotographic photoconductor using a substrate, a charge transport layer, and a charge generation layer sequentially laminated, or an electrophotographic photoconductor further provided with a protective layer thereon Have been proposed, for example, in JP-A-61-753555 and JP-A-54-58445.

However, in the electrophotographic photoreceptor having such a layer configuration, since a relatively thin charge generating layer is an upper layer, characteristic deterioration due to abrasion during repeated use is remarkable.

Further, in an electrophotographic photoreceptor provided with a protective layer for the purpose of improving this, since the protective layer material is an organic insulating material, the potential is not stabilized during repeated use, and the repeatedly stable characteristics cannot be maintained. Was.

From the above points, development of an organic electrophotographic photoreceptor that can be used in positive electrode charging by sequentially laminating a substrate, a charge generation layer, and a charge transport layer is expected.

However, this requires a charge transporting material having an electron transporting ability. Examples of charge transporting materials having electron transporting ability include, for example, 2,4,7-trinitro-9-fluorenone (TNF) and dicyanomethylenefluorene carboxylate compounds disclosed in JP-A-61-148159.
JP-A-63-70257, JP-A-63-72664 and JP-A-63-72664
Anthraquinodimethane compound disclosed in 63-1004061 Publication,
1,4-naphthoquinone compounds disclosed in JP-A-63-85749, diphenyldicyanoethylene compounds disclosed in JP-A-63-175860 and JP-A-63-174993, Proceedings of the 58th Annual Meeting of the Chemical Society of Japan (3IH38), 431, (1989) and the like.

However, in the photoconductor for charging a positive electrode using a charge transporting material having these electron transporting capabilities, the sensitivity is not sufficient, the residual potential upon repeated use is high, the production cost is high, and an organic solvent and a binder are used. However, there is a problem that the compatibility of the compound is low, and it is not satisfactory enough to be put to practical use, and further improvement is required.

[Problem to be Solved by the Invention] An object of the present invention is to use a specific compound which satisfies the characteristics required for the above-described charge transport compound,
Various disadvantages of the conventional electrophotographic photoreceptor have been solved.
That is, to provide an electrophotographic photoreceptor having high sensitivity and capable of stably maintaining electrophotographic characteristics when used repeatedly.
Another object of the present invention is to provide an electrophotographic apparatus provided with the electrophotographic photoreceptor, and to provide a facsimile incorporating the electrophotographic apparatus.

[Means for Solving the Problems and Action] The present invention relates to an electrophotographic photosensitive member having a photosensitive layer on a conductive support, wherein the photosensitive layer has an electron transporting ability represented by the following general formula (1). And an electrophotographic photoreceptor characterized by containing

General formula In the formula, R ₁ , R ₂ , R ₃ and R _{4 each} represent an alkyl group, an aralkyl group, an aromatic ring group, a heterocyclic group, — (CH ＝ CH) _n —NO ₂ or a cyano group; Or an integer of 2.

However, at least two or more of R _{1 to} R ₄ represent a nitrothiophene group or a dinitrothiophene group.

Specifically, as an alkyl group, a group such as methyl, ethyl, propyl, and butyl, as an aralkyl group, a group such as benzyl, phenethyl, and naphthylmethyl; as an aromatic ring group, a group such as phenyl and naphthyl; and as a heterocyclic group, Is a group such as thienyl, pyridyl, furyl, etc., and further as a substituent, an alkyl group such as methyl, ethyl, propyl, butyl, a halogen atom such as a fluorine atom, a chlorine atom, a bromine atom, a cyano group or a nitro group. No.

Further, the present invention comprises an electrophotographic apparatus provided with the electrophotographic photoreceptor of the present invention.

Further, the present invention comprises an electrophotographic apparatus provided with the electrophotographic photoreceptor of the present invention and a facsimile having a receiving means for receiving image information from a remote terminal.

Hereinafter, typical examples of the compound represented by the general formula (1) will be given. However, it is not limited to these compounds.

As an example method, only the part that changes in the basic type is described.

The electrophotographic photoreceptor of the present invention is constituted by combining the charge transporting material represented by the general formula (1) and an appropriate charge generating material.

Examples of the configuration of the photosensitive layer include the following forms.

(1) a conductive support / a layer containing a charge generating substance / a layer containing a charge transporting substance; and (2) a conductive support / a layer containing a charge transporting substance / a layer containing a charge generating substance. Sequentially laminated (3) Conductive support / layer containing charge generating material and charge transport material (4) Conductive support / layer containing charge transport material / layer containing charge generating material and charge transport material sequentially Lamination (5) Conductive support / Layer containing charge generation material / Lamination of layer containing charge generation material and charge transport material The compound represented by the general formula (1) of the present invention has a high electron transport ability. Therefore, it can be used as a charge transport material in the photosensitive layer of the above embodiment.

Positive charge is preferable when the form of the photosensitive layer is (1), negative charge is preferable in the case of (2), and both positive and negative charge can be used in the case of (3), (4) and (5). .

Further, in the above-mentioned electrophotographic photoreceptor, a protective layer or an undercoat layer may be provided on the photosensitive layer for improving adhesion and controlling charge injection. The configuration of the electrophotographic photosensitive member is not limited to the above-described basic configuration.

Note that, among the above configurations, the mode (1) is particularly preferable, and will be described in more detail below.

Examples of the conductive support include the following forms.

(1) Aluminum, aluminum alloy, stainless steel,
Plates or drums made of metal such as copper.

(2) Aluminum, palladium, etc. on a non-conductive support such as glass, resin, paper or the conductive support of the above (1).
A film formed by depositing or laminating a metal such as rhodium, gold, or platinum.

(3) A layer of a conductive compound such as a conductive polymer, tin oxide, or indium oxide is formed on a non-conductive support such as glass, resin, paper, or the conductive support described in (1) by vapor deposition or coating. What you did.

Examples of effective charge generating substances include the following substances. These charge generating substances may be used alone or in combination of two or more.

(1) Azo pigments such as monoazo, bisazo, trisazo, etc. (2) Phthalocyanine pigments such as metal phthalocyanine and nonmetal phthalocyanine (3) Indigo pigments such as indigo and thioindigo (4) Perylene anhydride, perylene imide and the like (5) Polycyclic quinine pigments such as anthraquinone and pyrenequinone (6) Squarylium dyes (7) Pyrylium salts and thiopyrylium salts (8) Triphenylmethane dyes (9) Selenium and amorphous silicon The layer containing the inorganic substance charge generating substance, that is, the charge generating layer can be formed by dispersing the above-described charge generating substance in an appropriate binder, and coating this on a conductive support. it can. Further, it can also be formed by forming a thin film on a conductive support by a dry method such as evaporation, sputtering, or CVD.

The binder can be selected from a wide range of binder resins, for example, polycarbonate, polyester, polyarylate, butyral resin, polystyrene, polyvinyl acetal, diallyl phthalate resin, acrylic resin,
Examples include, but are not limited to, methacrylic resins, vinyl acetate resins, phenolic resins, silicone resins, polysulfones, styrene-butadiene copolymers, alkyd resins, epoxy resins, urea resins, vinyl chloride-vinyl acetate copolymers, and the like. Not something. These resins may be used alone or in combination of one or more as a copolymer polymer.

The resin contained in the charge generation layer is desirably 80% by weight or less, preferably 40% by weight or less. Further, the thickness of the charge generation layer is preferably 5 μm or less, particularly preferably 0.01 to 2 μm. Various sensitizers may be added to the charge generation layer.

The layer containing the charge transporting material, that is, the charge transporting layer, can be formed by combining the compound represented by the general formula (1) and a suitable binder resin.

Here, as the binding resin used for the charge transport layer,
Examples thereof include those used in the charge generation layer, and further include photoconductive polymers such as polyvinyl carbazole and polyvinyl anthracene.

The compounding ratio of the binder resin to the compound represented by the general formula (1) is preferably 10 to 500 parts by weight per 100 parts by weight of the binder.

Since the charge transport layer has a limit for transporting charge carriers, it cannot be made thicker than necessary.
A range of 40 μm, particularly 10 to 30 μm is preferred.

Further, an antioxidant, an ultraviolet absorber, a plasticizer, or a known charge transport substance can be added to the charge transport layer as needed.

When forming such a charge transport layer, using a suitable organic solvent, using a dip coating method, a spray coating method, a spinner coating method, a roller coating method, a Meyer bar coating method, a coating method such as a blade coating method. It can be carried out.

The electrophotographic photoreceptor containing the compound represented by the general formula (1) in the charge transport layer is used not only for electrophotographic copying machines but also for electrophotographic applications such as laser printers, CRT printers, and electrophotographic plate making systems. Can also be widely used.

Next, an electrophotographic apparatus and a facsimile provided with the electrophotographic photosensitive member of the present invention will be described.

FIG. 1 shows a schematic configuration of a general transfer type electrophotographic apparatus using the drum type photoreceptor of the present invention.

In FIG. 1, reference numeral 1 denotes a drum-type photosensitive member as an image carrier, which is driven to rotate at a predetermined peripheral speed in the direction of an arrow around a shaft 1a. The photoreceptor 1 is uniformly charged at a predetermined positive or negative potential on its peripheral surface by a charging means 2 during the rotation process, and then exposed at a light exposure section 3 by an image exposure means (not shown) at an exposure section 3.
(Slit exposure, laser beam scanning exposure, etc.).

As a result, an electrostatic latent image corresponding to the exposure image is sequentially formed on the peripheral surface of the photoconductor.

The electrostatic latent image is then developed with toner by a developing unit 4, and the developed toner image is transferred by a transfer unit 5 between a photosensitive unit 1 and a transfer unit 5 from a paper supply unit (not shown) in synchronization with the rotation of the photosensitive unit 1. It is sequentially transferred onto the surface of the transfer material P taken and fed.

The transfer material P having undergone the image transfer is separated from the photoreceptor surface, introduced into the image fixing means 8 and subjected to image fixing, and is printed out as a copy (copy) outside the machine.

The surface of the photoreceptor 1 after the image transfer is cleaned and cleaned by removing the untransferred toner by the cleaning means 6, subjected to a charge removal treatment by the pre-exposure means 7, and used repeatedly for image formation.

As the uniform charging means 2 for the photoreceptor 1, a corona charging device is generally widely used.

Also, the corona transfer means is generally widely used for the transfer device 5.

As an electrophotographic apparatus, a plurality of components such as the above-described photoreceptor, developing means, and cleaning means are integrally connected as an apparatus unit, and this unit is configured to be detachable from the apparatus body. May be. For example,
The photoreceptor 1 and the cleaning means 6 may be integrated into one apparatus unit, and may be configured to be detachable using guide means such as rails of the apparatus body. At this time, the above-described device unit may be provided with a charging unit and / or a developing unit.

In the case where the electrophotographic apparatus is used as a copier or a printer, the light image exposure L is performed by reflecting or transmitting light from the original, or by reading the original and converting it into a signal. This is performed by driving an array or driving a liquid crystal shutter array.

When used as a facsimile printer, the light image exposure L is an exposure for printing received data.

FIG. 2 is a block diagram showing one example of this case.

The controller 10 controls the image reading unit 9 and the printer 18.

The whole of the controller 10 is controlled by the CPU 16.

The read data from the image reading unit is transmitted to the partner station through the transmission circuit 12. Data received from the partner station is sent to the printer 18 through the receiving circuit 11. Predetermined image data is stored in the image memory. The printer controller 17 controls the printer 18. 13 is a telephone.

An image received from the line 14 (image information from a remote terminal connected via the line) is demodulated by the receiving circuit 11, and then the CPU 16 performs signal processing of the image information and is sequentially stored in the image memory 15. . When at least one page of the image is stored in the memory 16, the image of the page is stored. The CPU 16 reads out one page of image information from the memory 15 and sends out one page of image information signaled to the printer controller 17.

When receiving the image information of one page from the CPU 16, the printer controller 17 controls the printer 18 to record the image information of the page.

Note that the CPU 16 is receiving the next page during recording by the printer 18.

 As described above, image reception and recording are performed.

EXAMPLES Example 1 4 g of oxytitanyl phthalocyanine obtained according to the production example disclosed in Japanese Patent Application Laid-Open No. 61-239248 was converted to 2 g of polyvinyl butyral (butyralization degree: 70 mol%, weight average molecular weight: 40,000) by cyclohexanone. The mixture was dispersed with a liquid dissolved in 95 ml with a sand mill for 24 hours to prepare a coating liquid.

After diluting this coating liquid, it was applied on an aluminum sheet with a Meyer bar so that the film thickness after drying was 0.2 μm, to form a charge generation layer.

Next, 5 g of Compound Example (4) and 7 g of polycarbonate (weight average molecular weight: 35,000) as a charge transport material are dissolved in 100 g of chlorobenzene, and this solution is applied on the previous charge generation layer by a Meyer bar, and dried. A charge transport layer having a thickness of 17 μm was formed, and an electrophotographic photoreceptor was prepared.

The electrophotographic photoreceptor was statically charged at +6 KV using Kawaguchi Electric Co., Ltd. electrostatic copying paper tester EPA-8100.
After charging for 1 second in a dark place, exposure was performed at an illuminance of 20 lux, and charging characteristics were examined.

As the charging characteristics, the surface potential (V ₀ ) and the exposure amount (E1 / 2) required to attenuate the potential (V ₁ ) after dark decay for 1 second to 1/2, and 5 seconds after the start of light irradiation after it was measured potential (V _R) of.

Further, in order to measure the fluctuation of the light portion potential and the dark portion potential when repeatedly used, the above-prepared electrophotographic photoreceptor was attached to a cylinder for a photoreceptor drum of a copying machine NP-6650 manufactured by Canon Inc. 2,000 sheets were copied using a modified machine of the same machine, and the variations in the dark part potential (V _D ) and the light part potential (V _L ) at the initial stage and after the 2,000 sheets were copied were measured.

Incidentally, the initial V _D and V _L are each + 650V, it was set to be + 150 V. The results are shown.

_{V 0: + 690V V 1:} + 680V E1 / 2: 3.6lux · sec V R: + 55V initial potential _{V D: + 650V V L:} + 150V 2 thousand endurance potential after _{V D: + 655V V L:} + 140V Examples 2-9 and Comparative Examples 1 to 4 In this example, compound examples (1), (2) and (1) were used instead of compound example (4) as the charge transport compound used in Example 1.
1), (15), (19), (22), (26) and (27) were used to prepare an electrophotographic photosensitive member in the same manner as in Example 1 except for the above. Then, the electrophotographic characteristics of each electrophotographic photosensitive member were measured by the same method as in Example (1).

For comparison, an electrophotographic photoreceptor was prepared in the same manner except that the following comparative compound was used as a charge transport compound,
The electrophotographic properties were measured.

 The results are shown.

Comparative Example V _R (+ V) 1 250 2 660 3 580 4 550 As is clear from the above results, the general formula (1) of the present invention
It can be seen that, when the compound represented by is used as a charge transporting compound, the electrophotographic photoreceptor is extremely excellent in sensitivity and potential stability upon repeated use as compared with the comparative compound.

Example 10 On an aluminum substrate, 5 g of N-methoxymethylated 6 nylon resin (weight average molecular weight: 200,000) and 5 g of alcohol-soluble copolymerized nylon resin (weight average molecular weight: 80,000) were added to methanol 10
A solution dissolved in 0 g was applied with a Meyer bar to form an undercoat layer having a thickness of 1 μm after drying.

Next, 1 g of a charge generating substance having the following structural formula 0.4 g of polyvinyl butyral (butyral degree 70%, weight average molecular weight 100,000) and 50 g of dioxane in a ball mill 20
Time dispersion was performed. After diluting this dispersion, apply it by a blade coating method on the undercoat layer formed earlier,
A charge generation layer having a thickness of 0.2 μm after drying was formed.

Next, 10 g of the compound of the compound example (17) and 10 g of polymethyl methacrylate (weight average molecular weight of 80,000) are dissolved in 100 g of chlorobenzene, applied on the previously formed charge generating layer by a blade coating method, and dried. 17μm thick
Was formed.

A +6 KV corona discharge was applied to the electrophotographic photosensitive member thus produced. At this time, the surface potential (V ₀ ) was measured. Further, the surface potential (V ₁ ) of the photoconductor after leaving it in a dark place for 1 second was measured. The potential V ₁ of the following sensitivity was dark decay 1/2
Exposure (E _1/2 : μJ / cm ² ) required for attenuation to
Evaluation was made by measuring the residual potential (V _R ) after light exposure at 20 μJ / cm ² . At this time, a gallium / aluminum / arsenic ternary semiconductor laser (output: 5 mW;
An oscillation wavelength of 780 nm) was used. The results are shown.

V ₀ : +700 V, V ₁ : +690 V E _1/2 : 2.1 μJ / cm ² V _R : +60 V Next, a reversal-developing digital copying machine equipped with the same semiconductor laser, NP-9330, manufactured by Canon Inc. The above photoreceptor was attached to the remodeled machine, and an actual image forming test was performed.

The surface potential after primary charging was +600 V, and the surface potential after image exposure was +100 V (exposure amount: 4.9 μJ / cm ² ). Good prints were obtained for both characters and images.

Further, when 5,000 images were continuously output, stable prints from the initial stage to 5,000 sheets were obtained.

Example 11 7 g of oxytitanyl phthalocyanine obtained according to the production example disclosed in JP-A-62-67094 was dissolved in 10 g of cyclohexanone in 4 g of polyvinyl benzal (benzalization degree: 78 mol%, weight average molecular weight: 100,000). The mixture was dispersed in a ball mill for 48 hours.

After this dispersion was diluted, it was applied on an aluminum sheet with a Meyer bar, and dried at 90 ° C. for 0.5 hour to form a 0.2 μm charge generation layer.

Next, a solution prepared by dissolving 5 g of the compound of Compound Example (24) and 5 g of a bisphenol Z-type polycarbonate resin (weight average molecular weight: 100,000) in 80 g of chlorobenzene was applied on the previously formed charge generation layer with a Meyer bar, and then applied at 140 ° C. Dry for 1 hour with 1
An 8 μm charge transport layer was formed.

The electrophotographic photosensitive member thus prepared was measured in the same manner as in Example 11.

V ₀ : +700 V, V ₁ : +695 V E _1/2 : 1.8 μJ / cm ² V _R : +55 V Example 12 A 5% methanol solution of alcohol-soluble copolymerized nylon (weight average molecular weight: 50,000) is applied on an aluminum substrate. Then, an undercoat layer having a thickness of 0.5 μm after drying was formed.

Next, 5 g of a pigment represented by the following structural formula was added to tetrahydrofuran.
Dispersed with a sand mill in 50 ml.

Next, 5 g of the compound of Compound Example (12) and 7 g of polycarbonate (weight average molecular weight: 50,000) were dissolved in 50 g of a chlorobenzene (70 parts by weight) -dichloromethane (30 parts by weight) solution,
In addition to the previously prepared dispersion, the mixture was further dispersed by a sand mill for 25 hours.

The thickness of the undercoat layer after drying of this dispersion is
It was applied with a Meyer bar to a thickness of 18 μm and dried.

The charging characteristics of the thus prepared electrophotographic photosensitive member were measured in the same manner as in Example 1. The results are shown.

V ₀ : +700 V V ₁ : +690 V E _1/2 : 4.0 lux · sec V _R : +65 V Example 13 5 g of the compound of compound example (23) and 5 g of a polycarbonate resin (weight average molecular weight of 80,000) as chlorobenzene 70 g as charge transport materials This solution was applied on an aluminum sheet with a Meyer bar to form a charge transport layer having a dry film thickness of 18 μm.

Next, 2 g of a disazo pigment having the following structural formula was dispersed in a sand mill for 20 hours together with a solution of 1.5 g of polyvinyl butyral (butyralization degree: 80 mol%) in 50 ml of cyclohexanone to prepare a coating solution.

After diluting this coating solution, it was applied on the previous charge transporting layer with a Meyer bar so that the film thickness after drying was 0.5 μm to form a charge generating layer, thereby producing an electrophotographic photoreceptor.

The electrophotographic photoreceptor was -5 KV statically using Kawaguchi Electric Co., Ltd. electrostatic copying paper tester EPA-8100.
After charging for 1 second in a dark place, exposure was performed at an illuminance of 20 lux, and charging characteristics were examined.

As the charging characteristics, the exposure amount (E1 / 2) required to attenuate the surface potential (V ₀ ) and the potential (V ₁ ) when darkly attenuated for 1 second (V ₁ ) and the amount of light of 100 lux-seconds It was measured residual potential after irradiation of (V _R).

 The results are shown.

V ₀ : −700 V V ₁ : −690 V E _1/2 : 3.8 lex · sec V _R : −50 V [Effect of the Invention] The electrophotographic photoreceptor of the present invention is obtained by using a compound having a specific structure in the photosensitive layer. The electrophotographic photoreceptor has high sensitivity in electrophotographic properties, and is effective in exhibiting a remarkable effect that the fluctuation of the light portion potential and the dark portion potential is small and the durability is excellent in continuous image formation by repeated charging and exposure. It is.

The same effect can be obtained in an electrophotographic apparatus and a facsimile equipped with the electrophotographic photosensitive member.

[Brief description of the drawings]

FIG. 1 is a schematic configuration diagram of a general transfer type electrophotographic apparatus using a drum type photoreceptor of the present invention. Reference numeral 1 denotes a drum-type photoconductor as an image carrier (electrophotographic photoconductor of the present invention), 2 denotes a corona charging device, 3 denotes an exposure unit,
Is a developing means, 5 is a transferring means, 6 is a cleaning means, 7
Denotes a pre-exposure unit, 8 denotes an image fixing unit, L denotes a light image exposure, and P denotes a transfer material that has undergone image transfer. FIG. 2 is a block diagram of a facsimile using the electrophotographic apparatus as a printer. Reference numeral 9 denotes an image reading unit, 10 denotes a controller, 11 denotes a receiving circuit, 12 denotes a transmitting circuit, 13 denotes a telephone, 14 denotes a line, 15 denotes an image memory, 16 denotes a CPU, 17 denotes a printer controller, and 18 denotes a printer.

────────────────────────────────────────────────── ─── Continuation of the front page (72) Noriko Otani, Inventor 3-30-2 Shimomaruko, Ota-ku, Tokyo Inside Canon Inc. (56) References JP-A-1-152461 (JP, A) (58) Survey Field (Int.Cl. ⁶ , DB name) G03G 5/06 316

Claims (3)

(57) [Claims] 1. An electrophotographic photosensitive member having a photosensitive layer on a conductive support, wherein the photosensitive layer contains a charge transporting substance having an electron transporting ability represented by the following general formula (1). Electrophotographic photoreceptor. General formula In the formula, R ₁ , R ₂ , R ₃ and R _{4 each} represent an alkyl group, an aralkyl group, an aromatic ring group, a heterocyclic group, — (CH ＝ CH) _n —NO ₂ or a cyano group; Or an integer of 2. However, at least two or more of R _{1 to} R ₄ represent a nitrothiophene group or a dinitrothiophene group. 2. An electrophotographic apparatus comprising the electrophotographic photosensitive member according to claim 1. 3. A facsimile comprising: an electrophotographic apparatus provided with the electrophotographic photosensitive member according to claim 1; and a receiving means for receiving image information from a remote terminal.