JP2875780B2 - Inorganic paint and rock wool building materials - Google Patents

Inorganic paint and rock wool building materials

Info

Publication number
JP2875780B2
JP2875780B2 JP8164987A JP16498796A JP2875780B2 JP 2875780 B2 JP2875780 B2 JP 2875780B2 JP 8164987 A JP8164987 A JP 8164987A JP 16498796 A JP16498796 A JP 16498796A JP 2875780 B2 JP2875780 B2 JP 2875780B2
Authority
JP
Japan
Prior art keywords
rock wool
inorganic paint
weight
inorganic
acrylic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP8164987A
Other languages
Japanese (ja)
Other versions
JPH107987A (en
Inventor
行雄 戸辺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Electric Works Co Ltd
Original Assignee
Matsushita Electric Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Works Ltd filed Critical Matsushita Electric Works Ltd
Priority to JP8164987A priority Critical patent/JP2875780B2/en
Publication of JPH107987A publication Critical patent/JPH107987A/en
Application granted granted Critical
Publication of JP2875780B2 publication Critical patent/JP2875780B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、建築の内外装材の
表面化粧に使用される無機系塗料及び、天井材や壁材等
に使用されるロックウール建築材に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an inorganic paint used for surface decoration of interior and exterior materials of buildings and a rock wool building material used for ceiling materials and wall materials.

【0002】[0002]

【従来の技術】軒天井など雨水の作用し易い部位に使用
される建築材は耐水性が要求されるために、塗装に用い
られる塗料には酢酸ビニル樹脂系やアクリル樹脂系の有
機バインダーが15〜30重量%(固形分)程度配合さ
れているが、このように有機バインダーの配合量が多い
と準不燃にしかかならない。
2. Description of the Related Art Since building materials used in places where rainwater easily acts, such as eaves ceilings, are required to be water-resistant, organic paints such as vinyl acetate resin and acrylic resin are used in paints used for painting. About 30% by weight (solid content) is blended, but when the blending amount of the organic binder is large in this way, it becomes only semi-flammable.

【0003】一方、ロックウール建築材は不燃性が重視
される。このために、その塗装に用いられる塗料には酢
酸ビニル樹脂系やアクリル樹脂系の有機バインダーを1
0重量%以下(固形分)の少量しか配合することができ
ない。
On the other hand, non-combustibility is important for rock wool building materials. For this reason, the paint used for the coating should be made of an organic binder such as vinyl acetate resin or acrylic resin.
Only a small amount of 0% by weight or less (solid content) can be blended.

【0004】[0004]

【発明が解決しようとする課題】しかし有機バインダー
の配合がこのように少量であると塗膜はその耐水性や耐
摩耗性が悪く、しかも塗膜硬度が高くて脆く、ロックウ
ール建築材を軒天井など雨水の作用し易い部位に使用す
ることはできないという問題があった。本発明は上記の
点に鑑みてなされたものであり、有機バインダーの配合
が少なくても耐水性に優れると共に柔軟性に優れた塗膜
を形成する無機系塗料を提供することを目的とし、また
雨水が作用し易い部位においても問題なく使用すること
ができるロックウール建築材を提供することを目的とす
るものである。
However, when the amount of the organic binder is such a small amount, the coating film has poor water resistance and abrasion resistance, and has a high coating film hardness and is brittle. There was a problem that it could not be used on a part such as a ceiling where rainwater easily acts. The present invention has been made in view of the above points, an object of the present invention to provide an inorganic paint that forms a coating film having excellent water resistance and excellent flexibility even with a small amount of an organic binder, and An object of the present invention is to provide a rock wool building material that can be used without problems even in a portion where rainwater easily acts.

【0005】[0005]

【課題を解決するための手段】本発明に係る無機系塗料
は、無機質の顔料及びフィラーを含有すると共に、珪酸
リチウムとシリコン変性アクリル樹脂とをバインダーと
して含有して成ることを特徴とするものである。
The inorganic paint according to the present invention is characterized by containing an inorganic pigment and a filler and containing lithium silicate and a silicon-modified acrylic resin as a binder. is there.

【0006】また、上記のシリコン変性アクリル樹脂
は、含有量を無機系塗料の固形分中3重量%以上、10
重量%以下に設定するのが好ましい。また、本発明に係
るロックウール建築材は、上記の無機系塗料をロックウ
ール板の表面に塗装して成ることを特徴とするものであ
る。
[0006] The content of the silicone-modified acrylic resin is 3% by weight or more based on the solid content of the inorganic paint.
It is preferably set to not more than weight%. Further, a rock wool building material according to the present invention is characterized in that the above inorganic paint is applied to the surface of a rock wool plate.

【0007】[0007]

【発明の実施の形態】以下、本発明の実施の形態を説明
する。本発明に係る無機系塗料は、無機質の顔料やフィ
ラーにバインダーとして珪酸リチウムとシリコン変性樹
脂とを配合することによって調製されるものである。無
機質バインダーである珪酸リチウムの配合量は特に限定
されるものではないが、無機系塗料の固形分中5〜30
重量%になるように配合するが好ましい。また有機質バ
インダーであるシリコン変性樹脂の配合量は、無機系塗
料の不燃性を確保するために、無機系塗料の固形分中1
0重量%以下、より好ましくは8重量%以下に設定する
必要がある。シリコン変性樹脂の配合量の下限は特に設
定されるものではないが、塗膜の耐水性や柔軟性を高め
る効果を十分に得るためには、無機系塗料の固形分中3
重量%以上になるように配合するのが好ましい。
Embodiments of the present invention will be described below. The inorganic paint according to the present invention is prepared by mixing lithium silicate and a silicon-modified resin as a binder with an inorganic pigment or filler. The blending amount of lithium silicate as an inorganic binder is not particularly limited, but may be 5 to 30 in the solid content of the inorganic paint.
It is preferable to mix them so as to be in a weight%. In order to ensure the nonflammability of the inorganic coating, the amount of the silicone-modified resin, which is an organic binder, is 1% of the solid content of the inorganic coating.
It must be set to 0% by weight or less, more preferably 8% by weight or less. Although the lower limit of the amount of the silicone-modified resin is not particularly set, in order to sufficiently obtain the effect of increasing the water resistance and flexibility of the coating film, it is necessary to set the amount of the solid content of the inorganic paint to 3%.
It is preferable to mix them so as to be not less than% by weight.

【0008】本発明において有機質バインダーとして用
いるシリコン変性樹脂としては、アクリル樹脂にシリコ
ン樹脂を混合あるいは反応させて得られるシリコン変性
アクリル樹脂を用いるのが好ましい。そしてロックウー
ル吸音板の表面に上記の本発明に係る無機系塗料を塗装
することによって、本発明に係るロックウール建築材を
得ることができるものである。ここで、上記のようにし
て得られる本発明の無機系塗料は、バインダーとして珪
酸リチウムとシリコン変性樹脂を含有するものであり、
シリコン変性樹脂は10重量%以下の少ない配合でも無
機系塗料による塗膜の耐水性を高めることができると共
に柔軟性を高めて脆さを改質することができる。従っ
て、この無機系塗料を塗装したロックウール建築材は軒
先など水が作用し易い部位においても問題なく使用する
ことができるものである。
In the present invention, as the silicon-modified resin used as the organic binder, it is preferable to use a silicon-modified acrylic resin obtained by mixing or reacting an acrylic resin with a silicon resin. The rock wool building material according to the present invention can be obtained by applying the above-mentioned inorganic paint according to the present invention to the surface of the rock wool sound absorbing plate. Here, the inorganic paint of the present invention obtained as described above contains lithium silicate and a silicon-modified resin as a binder,
The silicon-modified resin can improve the water resistance of the coating film made of the inorganic paint and improve the flexibility to improve the brittleness even with a small amount of 10% by weight or less. Therefore, the rock wool building material coated with the inorganic paint can be used without problem even in a part where water is likely to act, such as an eaves.

【0009】[0009]

【実施例】次に本発明を実施例によって具体的に説明す
る。 (実施例1〜6)顔料及びフィラーとして、酸化チタ
ン、炭酸カルシウム、カオリンクレーを表1の配合量で
配合し、これにバインダーとして珪酸リチウムとシリコ
ン変性アクリル樹脂(昭和高分子社製)を表1の配合量
で配合すると共に添加剤(シリコン系消泡剤1重量部、
カルボン酸型界面活性剤2重量部、テキサノール及びブ
チルセロソルブ造膜助剤5重量部からなる)を配合し、
これを水に分散することによって固形分が60重量%の
無機系塗料を調製した。
Next, the present invention will be described specifically with reference to examples. (Examples 1 to 6) As pigments and fillers, titanium oxide, calcium carbonate, and kaolin clay were blended in the amounts shown in Table 1, and lithium silicate and a silicon-modified acrylic resin (manufactured by Showa Polymer Co., Ltd.) were used as binders. 1 and the additives (1 part by weight of a silicon-based defoamer,
2 parts by weight of a carboxylic acid type surfactant, 5 parts by weight of texanol and butyl cellosolve film-forming auxiliary), and
This was dispersed in water to prepare an inorganic paint having a solid content of 60% by weight.

【0010】次に、この無機系塗料を厚み9.0mm、
密度380Kのロックウール吸音板の表面に250g/
2 (ウエット)の塗布量で塗布し、150℃、3分間
の条件で乾燥することによって、表面を塗装したロック
ウール建築材を得た。 (比較例1)シリコン変性アクリル樹脂を使用しない表
1の配合で固形分が60重量%の無機系塗料を調製し
た。後はこの無機系塗料を用い、上記の(実施例1〜
6)と同様に塗装してロックウール建築材を得た。
Next, this inorganic paint is coated with a thickness of 9.0 mm,
250g / on the surface of a rock wool sound absorbing plate with a density of 380K
It was applied at a coating amount of m 2 (wet) and dried at 150 ° C. for 3 minutes to obtain a rock wool building material having a coated surface. (Comparative Example 1) An inorganic paint having a solid content of 60% by weight was prepared using the composition shown in Table 1 without using a silicon-modified acrylic resin. Thereafter, using this inorganic paint, the above (Examples 1 to
Painted in the same manner as in 6) to obtain a rock wool building material.

【0011】上記のようにして得たロックウール建築材
の表面の塗膜について、耐洗浄性、塗膜の柔軟性、撥水
性、塗膜の硬さを測定した。耐洗浄性は、塗膜が耐えら
れる洗浄回数として評価した。塗膜の柔軟性の評価は、
切断・釘打ち時に塗膜が全く剥離しないものを「◎」、
釘打ち時に釘の周囲の塗膜が欠けるときがあるものを
「○」、切断時に木口の塗膜が欠けるものを「△」、切
断・釘打ち時に塗膜が剥離するものを「×」とした。撥
水性の評価は、水滴の接触角度が90°以上のものを
「◎」、水滴の接触角度が90°のものを「○」、水滴
の接触角度が90°〜45°のものを「△」、水滴の接
触角度が45°以下のものを「×」とした。これらの結
果を表1に示す。また塗膜の硬さは鉛筆引っかき試験で
測定を行ない、鉛筆硬度として表1に示した。
With respect to the coating film on the surface of the rock wool building material obtained as described above, the washing resistance, the flexibility of the coating film, the water repellency, and the hardness of the coating film were measured. Washing resistance was evaluated as the number of washings that the coating film could withstand. Evaluation of the flexibility of the coating film,
If the coating film does not peel at all when cutting or nailing, "◎"
も の indicates that the coating around the nail may be missing when nailing, △ indicates that the coating on the tip of the nail is missing when cutting, and × indicates that the coating peels off when cutting or nailing. did. The evaluation of water repellency was “◎” when the contact angle of the water droplet was 90 ° or more, “○” when the contact angle of the water droplet was 90 °, and “△” when the contact angle of the water droplet was 90 ° to 45 °. And those having a contact angle of water droplets of 45 ° or less were evaluated as “×”. Table 1 shows the results. The hardness of the coating film was measured by a pencil scratch test and is shown in Table 1 as pencil hardness.

【0012】[0012]

【表1】 [Table 1]

【0013】表1にみられるように、バインダーとして
シリコン変性アクリル樹脂を配合しなかった比較例1の
塗膜は耐洗浄性が悪く、塗膜の柔軟性や撥水性が低いと
共に硬くて脆いものであった。一方、バインダーとして
珪酸リチウムとシリコン変性アクリル樹脂とを配合した
各実施例のものでは耐洗浄性が良好であり、塗膜の柔軟
性が高いと共に撥水性が高いものであった。また各実施
例のものはシリコン変性アクリル樹脂の配合量が10重
量%以下であるので不燃性を確保することができ、特に
実施例1,2,4,5はシリコン変性アクリル樹脂の配
合量が8重量%以下であり、不燃性が高く不燃天井材と
しての性能を満足するものであった。
As shown in Table 1, the coating film of Comparative Example 1 which did not contain a silicone-modified acrylic resin as a binder had poor washing resistance, low flexibility and water repellency, and was hard and brittle. Met. On the other hand, in each of the examples in which lithium silicate and silicon-modified acrylic resin were blended as the binder, the washing resistance was good, the flexibility of the coating film was high, and the water repellency was high. Further, in each of the examples, the compounding amount of the silicon-modified acrylic resin is 10% by weight or less, so that nonflammability can be ensured. In particular, in Examples 1, 2, 4, and 5, the compounding amount of the silicon-modified acrylic resin is small. The content was 8% by weight or less, and the nonflammability was high and the performance as a nonflammable ceiling material was satisfied.

【0014】[0014]

【発明の効果】上記のように本発明に係る無機系塗料
は、無機質の顔料及びフィラーを含有すると共に、珪酸
リチウムとシリコン変性アクリル樹脂とをバインダーと
して含有するものであり、シリコン変性アクリル樹脂
は、無機系塗料の固形分中3重量%以上、10重量%以
下の少ない配合でも無機系塗料による塗膜の耐水性を高
める事ができると共に柔軟性を高めて脆さを改善するこ
とができるものである。
Inorganic coating material according to the present invention as described above according to the present invention, together with a pigment and filler of inorganic, a lithium silicate and silicone-modified acrylic resin are those containing as a binder, silicone-modified acrylic resin In addition, it is possible to improve the water resistance of a coating film made of an inorganic paint and to improve the brittleness by increasing the flexibility even with a small amount of 3% by weight or more and 10% by weight or less in the solid content of the inorganic paint. It is.

【0015】さらにシリコン変性アクリル樹脂の含有量
無機系塗料の固形分中3重量%以上、10重量%以下
にすることによって、有機質バインダーの量を少なくし
て塗膜の不燃性を確保することができるものである。
Further, by making the content of the silicone-modified acrylic resin 3% by weight or more and 10% by weight or less based on the solid content of the inorganic paint, the amount of the organic binder is reduced and the non-flammability of the coating film is ensured. Can be done.

【0016】また、本発明に係るロックウール建築材
は、上記の無機系塗料をロックウール板の表面に塗装し
て成ることを特徴とするものであり、この無機系塗料の
塗膜は耐水性が高く柔軟性に優れるものであって、軒先
など水のかかり易い部位でもロックウール建築材を支障
なく使用することができるものである。
The rock wool building material according to the present invention is characterized in that the above-mentioned inorganic paint is applied to the surface of a rock wool plate, and the coating film of the inorganic paint is water-resistant. The rock wool building material can be used without hindrance even in areas where water is likely to splash, such as the eaves.

Claims (3)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 無機質の顔料及びフィラーを含有すると
共に、珪酸リチウムとシリコン変性アクリル樹脂とをバ
インダーとして含有して成ることを特徴とする無機系塗
料。
Claims: 1. An inorganic pigment and filler are contained.
An inorganic paint comprising both lithium silicate and a silicon-modified acrylic resin as a binder.
【請求項2】 シリコン変性アクリル樹脂の含有量が
機系塗料の固形分中3重量%以上、10重量%以下であ
ることを特徴とする請求項に記載の無機系塗料。
2. The content of the silicone-modified acrylic resin is zero.
The inorganic paint according to claim 1 , wherein the content is 3% by weight or more and 10% by weight or less in the solid content of the mechanical paint.
【請求項3】 請求項1又は2に記載の無機系塗料をロ
ックウール板の表面に塗装して成ることを特徴とするロ
ックウール建築材。
3. A rock wool building material obtained by applying the inorganic paint according to claim 1 on a surface of a rock wool plate.
JP8164987A 1996-06-25 1996-06-25 Inorganic paint and rock wool building materials Expired - Fee Related JP2875780B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8164987A JP2875780B2 (en) 1996-06-25 1996-06-25 Inorganic paint and rock wool building materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8164987A JP2875780B2 (en) 1996-06-25 1996-06-25 Inorganic paint and rock wool building materials

Publications (2)

Publication Number Publication Date
JPH107987A JPH107987A (en) 1998-01-13
JP2875780B2 true JP2875780B2 (en) 1999-03-31

Family

ID=15803690

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8164987A Expired - Fee Related JP2875780B2 (en) 1996-06-25 1996-06-25 Inorganic paint and rock wool building materials

Country Status (1)

Country Link
JP (1) JP2875780B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3572040B2 (en) * 2001-11-09 2004-09-29 株式会社Neomax Rare earth permanent magnet having corrosion resistant film, method for producing the same, and corrosion resistant film forming treatment liquid
CN102702907B (en) * 2012-06-22 2014-08-13 山东乐化漆业股份有限公司 Nanometer silicon wall paint for external wall

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5693772A (en) * 1979-12-27 1981-07-29 Otsuka Chem Co Ltd Coating composition

Also Published As

Publication number Publication date
JPH107987A (en) 1998-01-13

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