JP2850689B2 - Exhaust gas purification device - Google Patents

Exhaust gas purification device

Info

Publication number
JP2850689B2
JP2850689B2 JP5022151A JP2215193A JP2850689B2 JP 2850689 B2 JP2850689 B2 JP 2850689B2 JP 5022151 A JP5022151 A JP 5022151A JP 2215193 A JP2215193 A JP 2215193A JP 2850689 B2 JP2850689 B2 JP 2850689B2
Authority
JP
Japan
Prior art keywords
exhaust gas
fuel
catalytic converter
exhaust
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP5022151A
Other languages
Japanese (ja)
Other versions
JPH06212952A (en
Inventor
真治 中山
洋一郎 河野
保昭 熊谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Motors Corp
Original Assignee
Mitsubishi Motors Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Motors Corp filed Critical Mitsubishi Motors Corp
Priority to JP5022151A priority Critical patent/JP2850689B2/en
Publication of JPH06212952A publication Critical patent/JPH06212952A/en
Application granted granted Critical
Publication of JP2850689B2 publication Critical patent/JP2850689B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066Selective catalytic reduction [SCR]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/30Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a fuel reformer
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/03Adding substances to exhaust gases the substance being hydrocarbons, e.g. engine fuel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas After Treatment (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明はディーゼルエンジン等の
原動機から排出される排気ガス中の窒素酸化物(以下N
x という)を除去する排気ガス浄化装置、特にNOx
還元触媒に還元用炭化水素を添加してNOx 浄化効率を
向上させる排気ガス浄化装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to nitrogen oxides (hereinafter referred to as N) in exhaust gas discharged from a prime mover such as a diesel engine.
O x hereinafter) exhaust gas purification device for removing, in particular, NO x
By adding a reducing for hydrocarbons in the reducing catalyst to an exhaust gas purifying apparatus to improve the NO x purification efficiency.

【0002】[0002]

【従来の技術】通常、供給酸素量が多い状態で運転され
るディーゼルエンジンではNOx の排出量が高レベルと
なる。このためディーゼルエンジンの排気系には酸素過
剰下でNOx を還元処理できる窒素酸化物還元触媒を内
蔵したNOx 触媒コンバータが装着される傾向にある。
BACKGROUND ART Normally, emissions of the NO x becomes high level in the diesel engine is operated in a state the supply amount of oxygen is large. Therefore the exhaust system of a diesel engine tends to the NO x catalyst converter with an internal nitrogen oxide reduction catalyst capable of reducing processing NO x in oxygen-excessive under is mounted.

【0003】ところで、ディーゼルエンジンの排気系に
NOx を還元処理できるNOx 触媒が装着された場合、
該NOx 触媒は、図4に示すような活性化温度Tsoを
上回るとその浄化効率を向上させる事が知られており、
図5に示すような触媒活性域Aを有している。ここで横
軸にはHC/NOx の体積比であるモル比が取られ、縦
軸には排気ガスの温度が取られており、ここでの触媒活
性域はHC/NOx モル比が1以上ある場合と成ってい
る。NOx 触媒の浄化効率を高める手段としては、排気
路のNOx 触媒の上流側に還元用炭化水素HCを添加す
ることが有効であることが知られている。
Meanwhile, if the NO x catalyst capable of reducing processing NO x in an exhaust system of a diesel engine is mounted,
It is known that the NO x catalyst improves its purification efficiency when it exceeds an activation temperature Tso as shown in FIG.
It has a catalyst active area A as shown in FIG. Here the horizontal axis molar ratio is the volume ratio of HC / NO x is taken, the vertical axis is taken the temperature of the exhaust gas, catalytic activity zone where HC / NO x molar ratio is 1 The above is the case. As a means to enhance the purification efficiency of the NO x catalyst, is adding a reducing for hydrocarbons HC at the upstream side of the NO x catalyst in the exhaust passage is known to be effective.

【0004】前記還元用炭化水素(以下HCと称する)
を添加する手段として、軽油を加熱分解して還元用HC
を得、これを排気ガス浄化用触媒コンバータの上流に注
入する手段がある。
[0004] The reducing hydrocarbon (hereinafter referred to as HC)
As a means to add, heat decomposition of light oil to reduce HC
There is a means for injecting this upstream of the catalytic converter for purifying exhaust gas.

【0005】図3に前記還元用HC生成する燃料改質装
置を備えたディーゼルエンジン用排気ガス浄化装置の従
前の1例を示す。図において、1はディーゼルエンジ
ン、2は該エンジン1の排気マニホールド、3は排気
管、4は排気ガス浄化用触媒コンバータである。該触媒
コンバータ4は、ゼオライト系等のNOx 還元用触媒を
備えた公知のNOx 還元触媒コンバータである。
FIG. 3 shows a conventional example of an exhaust gas purifying apparatus for a diesel engine provided with the fuel reforming apparatus for producing the reducing HC. In the figure, 1 is a diesel engine, 2 is an exhaust manifold of the engine 1, 3 is an exhaust pipe, and 4 is a catalytic converter for purifying exhaust gas. The catalytic converter 4 is known of the NO x reduction catalytic converter with the NO x reduction catalyst for zeolite and the like.

【0006】5は軽油を加熱、分解してNOx 還元用H
Cを生成する燃料改質装置であり、エンジンの燃料タン
ク6から燃料ポンプ7により送給された燃料の軽油を加
熱分解してNOx 還元用HCを生成する。このHCはH
C供給管8を経て触媒コンバータ4の上流側の排気管3
内に注入される。前記燃料改質装置の詳細な構成、機能
については後述する。9は前記燃料改質装置5と燃料タ
ンク6とを接続する軽油供給管である。
[0006] 5 is heating the light oil, decomposition to NO x reduction for H
This is a fuel reformer that generates C, and heat-decomposes light oil of fuel supplied from a fuel tank 6 of an engine by a fuel pump 7 to generate HC for NO x reduction. This HC is H
Exhaust pipe 3 upstream of catalytic converter 4 via C supply pipe 8
Injected into. The detailed configuration and function of the fuel reformer will be described later. 9 is a light oil supply pipe connecting the fuel reformer 5 and the fuel tank 6.

【0007】[0007]

【発明が解決しようとする課題】前記従来の還元用HC
を生成する燃料改質装置においては、該燃料改質装置5
内に軽油加熱用ヒータを収納し、エンジン用燃料タンク
6から送給される燃料油即ち軽油を該ヒータにより加熱
し、軽油改質触媒の作用により軽油を分解せしめて、N
x 還元用HCを得ている。
The above-mentioned conventional reducing HC
In the fuel reformer that generates the fuel, the fuel reformer 5
A heater for heating light oil is housed therein, and the fuel oil, that is, light oil, supplied from the engine fuel tank 6 is heated by the heater, and the light oil is decomposed by the action of the light oil reforming catalyst.
To obtain the O x reduction for HC.

【0008】しかしながら、加熱用ヒータ及び軽油改質
触媒により、燃料用の軽油を加熱分解して得られるNO
x還元用HCは含有酸素量が少ないため、NOx 浄化用
触媒コンバータ4におけるNOx 浄化効率が低いという
問題点がある。
[0008] However, NO obtained by heating and decomposing gas oil for fuel by the heater for heating and the gas oil reforming catalyst is used.
Since x reduction for HC containing a small amount of oxygen, there is a problem of low the NO x purification efficiency in the NO x purification catalyst converter 4.

【0009】本発明は、前記問題点を解消し、NOx
化用触媒コンバータ内におけるHCによる還元機能を向
上することにより、NOx 浄化効率を向上せしめた排気
ガス浄化装置を提供する事を目的とする。
[0009] The present invention is to solve the above problems, by enhancing the reduction function by HC in the NO x purification for the catalytic converters, intended to provide an exhaust gas purifying apparatus was allowed improved the NO x purification efficiency And

【0010】[0010]

【課題を解決するための手段】本発明は、前記課題を解
決するため、次のように構成したことを特徴とする。 (1)エンジン等の原動機により駆動される空気圧縮機
(過給機のコンプレッサ等)又は別置きの空気圧縮機に
より生成される圧縮空気を燃料改質装置内に導入して、
軽油等の燃料改質用触媒に作用させて含酸素のHCを得
る。
Means for Solving the Problems The present invention is characterized by the following constitution in order to solve the above problems. (1) Compressed air generated by an air compressor (such as a supercharger compressor) driven by a prime mover such as an engine or a separately installed air compressor is introduced into a fuel reformer,
Oxygen-containing HC is obtained by acting on a fuel reforming catalyst such as light oil.

【0011】(2)エンジンの排気ガス路から分岐抽出
した排気ガスを燃料改質装置内に導入し、排気ガス中の
残存酸素を利用することにより前記(1)と同様に、含
酸素のHCを得る。
(2) The exhaust gas branched and extracted from the exhaust gas passage of the engine is introduced into the fuel reformer, and the residual oxygen in the exhaust gas is utilized to thereby provide the oxygen-containing HC similarly to the above (1). Get.

【0012】[0012]

【作用】空気圧縮機により生成した圧縮空気又は排気管
路から分岐抽出した排気ガスを燃料改質装置内に導入し
て、燃料改質用触媒に作用させる。この際において、圧
縮空気中及び排気ガス中に含有する酸素により含酸素H
Cが得られる。この含酸素HCをNOx 浄化用触媒コン
バータの排気ガス入口の上流側に注入することにより、
NOx 還元作用を促進させる。
The compressed air generated by the air compressor or the exhaust gas branched and extracted from the exhaust pipe is introduced into the fuel reformer to act on the fuel reforming catalyst. At this time, oxygen contained in the compressed air and the exhaust gas is
C is obtained. By injecting the oxygen-containing HC at the upstream side of the exhaust gas inlet of the catalytic converter the NO x purification,
Promotes NO x reduction action.

【0013】特に抽出排気ガスを使用する場合は、排気
ガスが高温、高圧であるので、これ自体の加熱、加圧作
用により、HCの生成を促進させることができる。
Particularly when using the extracted exhaust gas, since the exhaust gas has a high temperature and a high pressure, the generation of HC can be promoted by its own heating and pressurizing action.

【0014】[0014]

【実施例】以下、図面に基づいて本発明の実施例を例示
的に詳しく説明する。但しこの実施例に記載されている
構成部品の寸法、材質、形状、その相対配置などは特に
特定的な記載がない限りは、この発明の範囲をそれのみ
に限定する趣旨ではなく単なる説明例に過ぎない。図
1、図2を参照して本発明の実施例につき詳細に説明す
ると、図1は本発明の第1実施例を示す系統図、図2は
第2実施例を示す系統図である。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a block diagram showing an embodiment of the present invention; However, unless otherwise specified, the dimensions, materials, shapes, relative arrangements, and the like of the components described in this embodiment are not intended to limit the scope of the present invention, but are merely illustrative examples. Not just. The embodiment of the present invention will be described in detail with reference to FIGS. 1 and 2. FIG. 1 is a system diagram showing a first embodiment of the present invention, and FIG. 2 is a system diagram showing a second embodiment.

【0015】図1において、1はディーゼルエンジン、
2は該ディーゼルエンジンの排気マニホールド、3は排
気管、4は排気ガス浄化用触媒コンバータである。
In FIG. 1, 1 is a diesel engine,
2 is an exhaust manifold of the diesel engine, 3 is an exhaust pipe, and 4 is a catalytic converter for purifying exhaust gas.

【0016】該触媒コンバータ4は、そのケーシング内
にモノリシス型の触媒担持体を備え、同触媒保持体には
ゼオライト系のNOx 触媒が担持されている。ここでゼ
オライト系のNOx 触媒としては、例えば銅系ゼオライ
ト触媒(CU/ZSM−5)が採用される。この触媒の
特性は、HCの供給を受けることにより、このHC成分
を還元剤としてより活性化し、NOx を効果的にN2
2 に分解すると共に、HCを効果的にH2O 、CO2
に分解することができる。なお、ゼオライト系のNOx
触媒9は上述の図に示したような触媒活性域Aを有す
る。
The catalytic converter 4 has a monolithic catalyst carrier in its casing, and the catalyst carrier carries a zeolite-based NO x catalyst. Here, as the zeolite-based NO x catalyst, for example, a copper-based zeolite catalyst (CU / ZSM-5) is employed. The characteristic of this catalyst is that, by receiving the supply of HC, the HC component is more activated as a reducing agent, and NO x is effectively decomposed into N 2 and O 2 , and HC is effectively converted into H 2 O, CO 2
Can be decomposed into Note that zeolite NO x
The catalyst 9 has a catalytically active region A as shown in the above-mentioned figure.

【0017】5は、燃料用の軽油を加熱分解してNOx
還元用含酸素HCを生成する燃料改質装置であり、該燃
料改質装置5にはエンジンの燃料タンク6から燃料ポン
プ7により軽油が送給されている。8は燃料改質装置に
より生成された含酸素HCを排気ガス浄化用触媒コンバ
ータ4上流の排気管路3中に導入するためのHC供給管
である。9は前記燃料改質装置5と燃料タンク6とを接
続する軽油供給管である。
5 is a method for thermally decomposing light oil for fuel to obtain NO x
This is a fuel reformer that generates oxygen-containing HC for reduction. Light oil is supplied to the fuel reformer 5 from a fuel tank 6 of an engine by a fuel pump 7. Reference numeral 8 denotes an HC supply pipe for introducing oxygen-containing HC generated by the fuel reformer into the exhaust pipe 3 upstream of the exhaust gas purifying catalytic converter 4. 9 is a light oil supply pipe connecting the fuel reformer 5 and the fuel tank 6.

【0018】10はエンジン1により駆動される空気圧
縮機で、例えば過給機のコンプレッサ等であり、12は
該空気圧縮機10と前記燃料改質装置とを接続する空気
管、11は該空気管12の圧縮機10出口を開閉する開
閉弁である。
Reference numeral 10 denotes an air compressor driven by the engine 1, for example, a compressor of a supercharger, 12 denotes an air pipe connecting the air compressor 10 and the fuel reformer, and 11 denotes the air pipe. This is an on-off valve for opening and closing the outlet of the compressor 10 of the pipe 12.

【0019】前記燃料改質装置5は、筒状で、二重壁の
中間部にヒータを有する改質触媒収容器を備え、その内
部に軽油改質触媒が充填されている。前記軽油改質触媒
としては、通常ゼオライト系の軽油改質触媒が適用され
る。
The fuel reforming apparatus 5 has a cylindrical reforming catalyst container having a heater in the middle of a double wall, and is filled with a light oil reforming catalyst. As the light oil reforming catalyst, a zeolite-based light oil reforming catalyst is usually applied.

【0020】以上のように構成された排気ガス浄化装置
において、ディーゼルエンジン1が運転されると、これ
に連動される空気圧縮機10が運転され、圧縮空気が空
気管12を通って燃料改質装置5に送給される。
In the exhaust gas purifying apparatus configured as described above, when the diesel engine 1 is operated, the air compressor 10 is operated in conjunction therewith, and the compressed air passes through the air pipe 12 to perform the fuel reforming. It is sent to the device 5.

【0021】前記燃料改質装置5においては、軽油を軽
油改質触媒によって比較的低温(約280°C程度)で
生成物の分布比率を、より低分子化されたものに変化さ
せる。即ち軽油を炭素数12以下のHC(炭化水素)を
主成分とするように改質してHC供給管8内に送給す
る。
In the fuel reformer 5, the distribution ratio of light oil is changed by a light oil reforming catalyst at a relatively low temperature (about 280 ° C.) to a lower molecular weight distribution ratio. That is, light oil is reformed so that it contains HC (hydrocarbon) having 12 or less carbon atoms as a main component, and is fed into the HC supply pipe 8.

【0022】その際において、空気圧縮機10から送給
されてきた圧縮空気中の酸素がHCに混入され、燃料改
質装置5からは酸素を相当量含有したHCが、排気ガス
浄化用触媒コンバータ4の排気ガス管路3中に注入され
る。従って前記NOx 浄化用の触媒コンバータ4内には
含酸素HCが還元剤として導入されることとなり、従来
のものよりもNOx 還元作用が促進される。
At this time, the oxygen in the compressed air supplied from the air compressor 10 is mixed into the HC, and the HC containing a considerable amount of oxygen is supplied from the fuel reformer 5 to the catalytic converter for purifying the exhaust gas. 4 into the exhaust gas line 3. Therefore, oxygen-containing HC is introduced as a reducing agent into the catalytic converter 4 for purifying NO x, and the NO x reducing action is promoted more than the conventional one.

【0023】尚、前記第1実施例においては、エンジン
により駆動される空気圧縮機により圧縮空気を得ている
が、例えばモーター駆動のようなエンジンとは別置きの
独立型空気圧縮機でもよいのは勿論である。
In the first embodiment, compressed air is obtained by an air compressor driven by an engine. However, for example, a stand-alone air compressor separate from the engine such as a motor drive may be used. Of course.

【0024】図2に示す第2実施例において、21は排
気管路3から分岐して燃料改質装置5に接続される排気
抽出管、22は該排気抽出管路21を開閉する開閉弁で
ある。
In the second embodiment shown in FIG. 2, reference numeral 21 denotes an exhaust extraction pipe branched from the exhaust pipe 3 and connected to the fuel reformer 5, and reference numeral 22 denotes an on-off valve for opening and closing the exhaust extraction pipe 21. is there.

【0025】この実施例の場合は、前記第1実施例の圧
縮空気に代えて、排気ガスの一部を抽気して燃料改質装
置5に導き、排気ガス中の残存酸素をHCに混入させて
含酸素HCとしNOx 還元作用を促進させる。この場合
は、排気ガス自体が高温、高圧であるので、触媒の加熱
作用をなし、ヒータの消費電力を低減できるという効果
を有する。その他の構成、機能は前記第1実施例と同様
であり、同一の部材には同一の符号を付して示す。
In this embodiment, instead of the compressed air of the first embodiment, a part of the exhaust gas is extracted and led to the fuel reformer 5, and the remaining oxygen in the exhaust gas is mixed with HC. to promote the NO x reduction effect as the oxygen-containing HC Te. In this case, since the exhaust gas itself has a high temperature and a high pressure, the catalyst has a heating effect and the power consumption of the heater can be reduced. Other configurations and functions are the same as those of the first embodiment, and the same members are denoted by the same reference numerals.

【0026】[0026]

【発明の効果】本発明は以上のように構成されており、
本発明によれば、燃料改質装置内に圧縮空気又は排気ガ
スの一部を注入することにより、含酸素の炭化水素を得
ることができ、これをNOx 浄化触媒コンバータに供給
することにより、従来のものよりもNOx 還元作用を促
進することができる。
The present invention is configured as described above.
According to the present invention, by injecting a portion of the compressed air or exhaust gas to the fuel reformer in the apparatus, it is possible to obtain the hydrocarbon oxygenates, by supplying it to the NO x purification catalytic converter, it is possible to promote the NO x reduction effect than the prior art.

【0027】また、排気ガスの一部を利用する場合は、
該排気ガスの加熱作用により燃料改質装置内のヒータの
消費電力を低減することができる。等の種々の著効を有
す。
Further, when a part of the exhaust gas is used,
The power consumption of the heater in the fuel reformer can be reduced by the heating action of the exhaust gas. And so on.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の第1実施例を示す系統図。FIG. 1 is a system diagram showing a first embodiment of the present invention.

【図2】本発明の第2実施例を示す系統図。FIG. 2 is a system diagram showing a second embodiment of the present invention.

【図3】従来例を示す図1応当図。FIG. 3 is a diagram showing a conventional example.

【図4】NOx 還元用触媒コンバータの性能説明用線
図。
FIG. 4 is a diagram for explaining the performance of a catalytic converter for NO x reduction.

【図5】NOx 還元用触媒コンバータの性能説明用線
図。
FIG. 5 is a diagram for explaining the performance of a catalytic converter for NO x reduction.

【符号の説明】[Explanation of symbols]

1 ディーゼルエンジン 2 排気マニホールド 3 排気管 4 排気ガス浄化用触媒コンバータ 5 燃料改質装置 6 燃料タンク 8 HC供給管 10 空気圧縮機 12 空気管 21 排気抽出管 DESCRIPTION OF SYMBOLS 1 Diesel engine 2 Exhaust manifold 3 Exhaust pipe 4 Exhaust gas purifying catalytic converter 5 Fuel reformer 6 Fuel tank 8 HC supply pipe 10 Air compressor 12 Air pipe 21 Exhaust extraction pipe

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平4−19317(JP,A) 特開 平6−137135(JP,A) 特開 平4−214918(JP,A) (58)調査した分野(Int.Cl.6,DB名) F01N 3/08 F02M 27/02────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-4-19317 (JP, A) JP-A-6-137135 (JP, A) JP-A-4-214918 (JP, A) (58) Field (Int.Cl. 6 , DB name) F01N 3/08 F02M 27/02

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 ディーゼルエンジン等の原動機から排出
される排気ガス中の窒素酸化物(NOx )を除去する排
気ガス浄化用触媒コンバータと、燃料改質触媒を介して
燃料を加熱、分解し、炭化水素(HC)を生成する燃料
改質装置と、該燃料改質装置で生成されたHCを前記触
媒コンバータの排気ガス入口の上流側に注入するHC供
給管路とを備えた排気ガス浄化装置において、圧縮空気
を生成する空気圧縮機と、該空気圧縮機と前記燃料改質
装置とを接続し、圧縮空気を燃料改質装置内に供給する
空気管路とを備えた事を特徴とする排気ガス浄化装置。
An exhaust gas purifying catalytic converter for removing nitrogen oxides (NO x ) in exhaust gas discharged from a prime mover such as a diesel engine and a fuel reforming catalyst for heating and decomposing fuel, An exhaust gas purifying apparatus comprising: a fuel reforming device that generates hydrocarbons (HC); and an HC supply pipe that injects the HC generated by the fuel reforming device upstream of an exhaust gas inlet of the catalytic converter. Wherein an air compressor for generating compressed air, and an air pipe connecting the air compressor and the fuel reformer and supplying compressed air into the fuel reformer are provided. Exhaust gas purification device.
【請求項2】 ディーゼルエンジン等の原動機から排出
される排気ガス中の窒素酸化物(NOx )を除去する排
気ガス浄化用触媒コンバータと、燃料改質触媒を介して
燃料を加熱、分解して炭化水素(HC)を生成する燃料
改質装置と、該燃料改質装置で生成されたHCを前記触
媒コンバータの排気ガス入口の上流側に注入するHC供
給管路とを備えた排気ガス浄化装置において、前記原動
機からの排気管路から分岐されて前記燃料改質装置に接
続され、排気ガスの一部を前記燃料改質装置内に供給す
排気抽出管を備えたことを特徴とする排気ガス浄化装
置。
2. An exhaust gas purifying catalytic converter for removing nitrogen oxides (NO x ) in exhaust gas discharged from a prime mover such as a diesel engine and a fuel reforming catalyst for heating and decomposing fuel. An exhaust gas purifying apparatus comprising: a fuel reforming device that generates hydrocarbons (HC); and an HC supply line that injects the HC generated by the fuel reforming device upstream of an exhaust gas inlet of the catalytic converter. in the branches from the exhaust pipe from the engine is connected to the fuel reformer, the exhaust gas, wherein a part of the exhaust gas with an exhaust extraction pipe for supplying the fuel reformer in the apparatus Purification device.
JP5022151A 1993-01-14 1993-01-14 Exhaust gas purification device Expired - Fee Related JP2850689B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5022151A JP2850689B2 (en) 1993-01-14 1993-01-14 Exhaust gas purification device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5022151A JP2850689B2 (en) 1993-01-14 1993-01-14 Exhaust gas purification device

Publications (2)

Publication Number Publication Date
JPH06212952A JPH06212952A (en) 1994-08-02
JP2850689B2 true JP2850689B2 (en) 1999-01-27

Family

ID=12074857

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2850689B2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3565035B2 (en) 1998-07-10 2004-09-15 三菱ふそうトラック・バス株式会社 NOx reduction system for combustion exhaust gas
US6176078B1 (en) * 1998-11-13 2001-01-23 Engelhard Corporation Plasma fuel processing for NOx control of lean burn engines
WO2001034950A1 (en) * 1999-11-10 2001-05-17 Engelhard Corporation METHOD AND APPARATUS TO PROVIDE REDUCTANT FOR NO¿x?
JP5030343B2 (en) * 2001-08-31 2012-09-19 三菱重工業株式会社 Exhaust gas purification apparatus and exhaust gas treatment method
JP3945335B2 (en) * 2002-07-31 2007-07-18 トヨタ自動車株式会社 Exhaust gas purification device for internal combustion engine
DE602004003215T2 (en) * 2004-02-19 2007-09-27 General Motors Corp., Detroit Extremely low power plasma reactor system for automotive nitrogen oxide emissions monitoring
US7879295B2 (en) 2005-06-30 2011-02-01 General Electric Company Conversion system for reducing NOx emissions
KR100782134B1 (en) * 2007-01-03 2007-12-05 한국에너지기술연구원 Fuel and air feeding device for hydrocarbon reforming/combustion
US20100251700A1 (en) * 2009-04-02 2010-10-07 Basf Catalysts Llc HC-SCR System for Lean Burn Engines

Also Published As

Publication number Publication date
JPH06212952A (en) 1994-08-02

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