JP2826820B2 - Silver halide photographic material - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION [Industrial applications]   The present invention relates to a silver halide photographic light-sensitive material.
Is excellent in photographic performance such as sensitivity and maximum density, and
C with less occurrence of color turbidity and suitable for rapid processing
The present invention relates to a silver halide photographic material. [Background of the Invention]   Generally, a silver halide color photographic material is placed on a support.
To be sensitive to blue light, green light and red light
Three types of silver halide photographic emulsions selectively spectrally sensitized
Layers are applied. For example, photosensitive materials for color negatives
Indicates a blue-sensitive emulsion layer and a green-sensitive emulsion
Layer, red-sensitive emulsion layer, and blue-sensitive emulsion layer.
Between the blue-sensitive emulsion layer and the green-sensitive emulsion layer
A yellow filter layer that can be bleached to absorb color light
Is provided. In addition, each emulsion layer has various special purposes
To provide another intermediate layer and a protective layer as the outermost layer
Is being done. Also, for example, exposure for color photographic paper
The material is generally red-sensitive emulsion layer, green-sensitive from the exposed side
An emulsion layer and a blue-sensitive emulsion layer are applied in this order.
UV light for each special purpose as well as in
An intermediate layer including an absorbing layer, a protective layer, etc. are provided.
You. Each of these emulsion layers is provided in an array different from the above.
It is also known that each emulsion layer is
Consisting of two layers having photosensitivity in substantially the same wavelength range
It is also known to use a photosensitive emulsion layer. These c
In silver halide photographic light-sensitive materials, it is used as a color developing agent.
For example, using an aromatic primary amine color developing agent
To develop the exposed silver halide grains
Reaction of oxidation products of color developing agents with dye-forming couplers
A more dye image is formed. In this method, usually
Form cyan, magenta and yellow dye images
Phenol or naphthol-based shea
Coupler, 5-pyrazolone, pyrazolino benzimida
Zole type, pyrazolotriazole type, indazolone type
Or cyanacetyl magenta couplers and acyl
Acetamide or benzoylmethane yellow yellow
A puller is used. These dye-forming couplers are photosensitive
In a color photographic emulsion layer or a developer.
The present invention relates to a method in which these couplers are contained in an emulsion layer in advance.
Concerning silver halide photographic light-sensitive materials considered to be diffusible
Things.   By the way, in recent years, various methods for rapidly performing color development have been developed.
Measures have been taken. Exposure is one of the ways
Silver halide color photographic light-sensitive material
Accelerates development when developing with color-based color developing agents
It is known to use agents. Such development promotion
Among the agents, those with relatively high activity are
It has the disadvantage of often producing fog. But here
Among these compounds, super additivity in color development
Certain black-and-white developing agents shown have a lower ratio than other development accelerators.
The development acceleration effect can be obtained by relatively low fog generation.
You. Examples of such black and white developing agents include UK Patent No. 81
1-phenyl-3-pyrazolidone described in 1,185, USA
Patent No. 2,417,514 describes N-methyl-p-aminophen
And N, N, N ', N'-tetra as described in JP-A-50-15554.
Methyl-p-phenylenediamine and the like. this
For the mechanism of super additive development in color development, see G.F.Va
Journal of the Photograph by n Veelen
Dick Science, Issue 20, p. 94 (1972)
ing. Such black-and-white developing agents are used as auxiliary developing agents.
In order to obtain the effect of accelerating color development,
When included in silver halide color photographic light-sensitive materials,
This may be included in the color developer.   Of these, the black-and-white developing agent is used to promote color development.
When included in a silver halide photographic material, 1-ant
-3-Pyrazolidones are particularly preferably used.
You. For example, JP-A-56-89739 discloses that
Halogen whose particle size ratio of silver halide grains differs by 50% or more
In silver halide color photographic materials having a silver halide emulsion layer
Addition of 1-aryl-3-pyrazolidone to
It is shown. However, it is not disclosed in this publication.
Halogen containing 1-aryl-3-pyrazolidone
Silver halide color photographic materials are intensifiers such as cobalt complex salts.
It is provided for intensification processing in the presence of
When processed as a color development process
Fruits are extremely insufficient, especially halogenated
When normal color development processing is performed using silver halide emulsion
In this case, almost no effect of accelerating color development can be obtained.
I knew it.   Japanese Patent Application Laid-Open No. Sho 56-64339 has a specific structure.
1-aryl-3-pyrazolidone is converted to silver halide
-A method of adding to a photographic light-sensitive material;
No. 58-50532, No. 58-50533, No. 58-50534,
JP-A-58-50535 and JP-A-58-50536 each disclose 1-ally
Photosensitizing silver-3-pyrazolidones to silver halide
Added to the material and processed within a very short development time.
Is disclosed.   However, each of the technologies described in these publications
Is simply satisfactory in that it has the effect of accelerating development,
Comprehensively considered photographic performance such as sensitivity, gradation, and maximum density
Sometimes it is not always satisfactory.   Furthermore, using such development acceleration technology, color development
When carrying out, it is easy to produce color fog and color turbidity
There is another problem. Conventionally, it prevents color fog and color turbidity.
Use of certain hydroquinone derivatives
Is well known. However, these hydroxy
When non-derivatives are added in large amounts to prevent color development,
Deterioration of sensitivity and maximum density, although effective against yellowtail
Deterioration of photographic performance, such as with some color couplers
Combinations can adversely affect image storability.   Thus, the conventional technology is still satisfactory for rapid processing.
Positive silver halide photographic material has not been obtained.
At present, its development is strongly desired. [Object of the invention]   The purpose of the present invention is to provide good photographic performance such as sensitivity and maximum density.
Color fogging and color turbidity during color development
Color development is accelerated and color development is accelerated
To provide silver halide light-sensitive materials
You. Still other objects will be apparent from the description below.
Would. [Configuration of the invention]   The object of the present invention is to provide a relative coupling reaction speed on a support.
Contains yellow coupler with RM / RN value of 0.5 or more
Silver halide emulsion layer containing a magenta coupler
Halo containing silver halide emulsion layer and cyan coupler
Photograph composed of silver gemide emulsion layer and non-photosensitive layer
In a silver halide photographic material having a true constitution layer,
Each of the silver halide emulsion layers has a silver chloride content.
They also contain silver halide grains of at least 80 mol%, and
At least one of the non-photosensitive layers has the following general formula [I]
Achieved by including at least one of the indicated compounds
Is done.   General formula [I] (Where R₁And R_TwoIs an alkyl having 1 to 5 carbon atoms
N represents an integer of 1 to 20, k represents 1 or
2 is represented. A is And R_ThreeRepresents a hydrogen atom, an alkyl group, an alkenyl group,
Represents a cycloalkyl group or an aryl group,_FourIs hydrogen
Represents an atom, an alkyl group or an aryl group. ), -OY
(Where Y is R_ThreeOr And R_ThreeIs as defined above. ), (Where R_FourIs as defined above, R_FiveIs hydrogen atom, alkyl
Group, aryl group or And R_ThreeIs as defined above. ), (Where l represents 0 or 1, R_ThreeIs as defined above,
R₆Represents a hydrogen atom, an alkyl group, a cycloalkyl group,
Represents a nyl group or an aryl group. ) Or a cyano group
Express. B is an alkyl group, an alkenyl group, a cycloalkyl
Group, aryl group, heterocyclic group or(Where R is₁, R_Two, n, k and A are each
Synonymous with the above. ). ] [Specific configuration of the invention]   In the silver halide photographic light-sensitive material of the present invention, the relative
Yellow coupling with RM / RN value of 0.5 or more
-Containing silver halide emulsion layer, magenta coupler
A silver halide emulsion layer and a cyan coupler.
Containing silver halide emulsion layer and non-photosensitive layer
The constituted photographic constituent layer is provided on a support.   And a silver halide emulsion containing each of the above couplers
In each of the layers, the silver halide composition contains silver chloride
Silver halide grains having a ratio of 80 mol% or more (hereinafter, the present invention)
Silver halide grains).
Halogenated with a silver chloride content of 90 mol% or more
Silver particles.   The silver iodide content is 1 mol% or less, preferably 0.1 mol%.
5 mol% or less. More preferably, the silver bromide content is 1
0% or less of silver chlorobromide grains or silver chloride grains.   The silver halide grains according to the present invention may be used alone.
For mixing with other silver halide grains of different composition
May be. In addition, halogenated silver having a silver chloride content of less than 80 mol%
It may be used by mixing with silver halide particles.   In addition, halogenated compounds having a silver chloride content of 80 mol% or more
Silver particles are halogenated with a silver chloride content of 80 mol% or more.
Total halogenation in silver halide emulsion layer containing silver grains
At least 50% by weight of silver halide grains, preferably at least
Also account for 75% by weight.   The composition of the silver halide grains according to the present invention may be
From the inside to the outside, or inside the particles.
The composition of the part and the outside may be different. Also grain
When the composition inside and outside the child is different, the composition changes continuously
Or discontinuous.   The grain size of the silver halide grains according to the present invention is particularly limited.
No, but consider other photographic performance such as rapid processing and sensitivity
Taking into account, preferably 0.2 to 1.6 μm, more preferably 0.
It is in the range of 25 to 1.2 μm. The above particle size is
Various methods commonly used in the art may be used.
This can be measured. As a typical method
Is a brand name `` particle size analysis method '' A.S.T.M.Symposium
Muon Right Microscopy 1955, 94-122
Page or "Theory of the Photographic Process" Mies and James
Co-authored, Third Edition, Chapter 2 of Macmillan Publishing Company (1966)
It is described in. This particle size is the projected area of the particle,
This can be measured using a diameter approximation. particle
If the particle size is substantially uniform, the particle size distribution
This can be expressed fairly accurately as a shadow area.   The grain size distribution of the silver halide grains according to the present invention is large.
It may be dispersed or monodispersed. Preferred
Or the variation in the size distribution of silver halide grains.
The number of monodisperse particles is 0.22 or less, more preferably 0.15 or less.
Silver halide particles. Here, the coefficient of variation is the particle size distribution
Is a coefficient indicating the width of the area, and is defined by the following equation.   Here, ri represents the particle size of each particle, and ni represents its number. This
The grain size referred to here is a spherical silver halide grain.
Diameter, or particles other than cubes or spheres
Indicates the diameter of the projected image converted to a circular image of the same area.
I forgot.   The shape of the silver halide grains according to the present invention may be any shape.
Can be used. One preferred example is the {100} plane
As a crystal surface. US Patent
No. 4,183,756, No. 4,225,666, JP-A-55-26589
No., Japanese Patent Publication No. 55-42737, etc., and The Journal
・ Photographic Science (J.Photgr.S
ci),twenty one, 39 (1973), etc.
Particles having shapes such as octahedral, tetrahedral, and dodecahedron.
This can be used. Furthermore, it has twin plane
Particles may be used.   The silver halide grains according to the present invention have a single shape.
Particles may be used, or particles of various shapes may be mixed.
May be used.   The silver halide grains according to the present invention can be prepared by an acid method, a neutral method,
Any one obtained by any of the Monmonia methods may be used. The particles
It may be grown at a time, or after growing seed particles,
May be. How to make and grow seed particles
They may be the same or different.   In addition, a form in which a soluble silver salt is reacted with a soluble halogen salt
Formulas include forward mixing, reverse mixing, and simultaneous mixing.
Any combination may be used, but it was obtained by the simultaneous mixing method.
Are preferred. Furthermore, Japanese Patent Application Laid-Open
PAg-Controlled- described in No. 54-48521
The double jet method can also be used.   If necessary, dissolve silver halide such as thioether
Agents or mercapto group-containing compounds or sensitizing dyes
A crystal habit control agent may be used.   The silver halide grains according to the present invention are used for forming grains.
Cadmium salt, zinc during the growing and / or growing process
Salt, lead salt, thallium salt, iridium salt or complex salt, rhodium
Add metal ions using salt or complex salt, iron salt or complex salt
And may be included inside the particle and / or on the particle surface.
And by placing in an appropriate reducing atmosphere,
A reduction sensitization nucleus can be imparted to the part and / or the grain surface.   The silver halide grains according to the present invention are mainly
The particles may be formed on the surface, and may be mainly
The particles may be formed inside the particles. Preferably
Are particles whose latent image is mainly formed on the surface.   Halogenation containing silver halide grains according to the present invention
The silver emulsion (hereinafter referred to as the silver halide emulsion of the present invention) is
Removal of unnecessary soluble salts after the completion of silver logenide grain growth
May be used, or may be kept contained. The salt
If you want to remove the type, research disclosure
It can be performed based on the method described in 17643.   The silver halide emulsion of the present invention is chemically sensitized by an ordinary method.
It is. That is, a compound containing sulfur capable of reacting with silver ions
Or sulfur sensitization using active gelatin, selenium compounds
Selenium sensitization method used, reduction sensitization method using a reducing substance,
Noble metal sensitization using gold or other noble metal compounds
It can be used alone or in combination.   The silver halide emulsion of the present invention is sensitized in the photographic industry.
Using a dye known as a dye, the desired wavelength range
Can be spectrally sensitized. The sensitizing dye may be used alone,
You may combine more than seeds. With the sensitizing dye itself
Dyes that do not have spectral sensitization, or
Is a compound that does not absorb the sensitizing dye.
An intensifying supersensitizer may be included in the emulsion.   The silver halide emulsion of the present invention contains
Prevent fogging during storage or photo processing and / or
Or during chemical ripening for the purpose of keeping photographic performance stable
And / or at the end of chemical ripening and / or at the end of chemical ripening
Later, before the silver halide emulsion is coated,
Compounds known as antifoggants or stabilizers
Can be added.   One of the silver halide emulsion layers of the present invention has a relative capri
Coupler with RM / RN value of 0.5 or more
-(Hereinafter referred to as the high-reactivity yellow coupler according to the present invention)
Is used.   The fast-reacting yellow coupler according to the present invention
A yellow coupler with a pulling reaction rate of 0.5 or more
You.   The coupling kinetics of the couplers are clearly separated from each other.
The two types of couplers M and N that give different dyes to be obtained are mixed.
Combined with silver halide emulsion for color development
Therefore, it is necessary to measure the amount of each dye in the obtained color image.
And can be determined as relative values.   Maximum concentration of coupler M (DM)<sub>max</sub>In the middle stage, DM
The color development and that for coupler N respectively (D
N)<sub>max</sub>, The reaction of both couplers
The activity ratio RM / RN is expressed by the following equation.   That is, a silver halide emulsion containing mixed couplers
To various stages of exposure and color development
Sets of DM and DN into two orthogonal axes From the slope of the straight line obtained by plotting as
The value of the activity ratio RM / RN can be determined.   Here, a certain coupler N is used to connect various couplers.
If the value of RM / RN is calculated as described above,
Relative value of the coupling reaction rate, i.e., relative coupling reaction rate
A value is required.   In the present invention, the following coupler is used as the coupler N.
Is the RM / RN value when the error is used.   The color developer used for the color development is as follows.
is there. Development was performed at 38 ° C. for 3 minutes and 30 seconds. (Color developer composition)   Benzyl alcohol 15ml   Ethylene glycol 15ml   Potassium sulfite 2.0g   Potassium bromide 0.7g   Sodium chloride 0.2g   Potassium carbonate 30.0g   Hydroxylamine sulfate 3.0g   2.5 g of polyphosphoric acid (TPPS)   3-methyl-4-amino-N-ethyl-N- (β-meth
Tansulfonamidoethyl) -aniline sulfate 5.5g   Optical brightener (4,4'-diaminostilbenzosulfone
Acid derivative) 1.0g   Potassium hydroxide 2.0g   Add water to make the total volume 1 and adjust to pH 10.20.   The fast-reacting yellow coupler according to the present invention comprises
As long as the reaction rate value against the cup ring is 0.5 or more,
The structure may be represented by the following general formula (A).
Can be preferably used.   General formula (A)   Where R<sub>1</sub>Represents an alkyl group or an aryl group, and R<sub>Two</sub>
Represents an aryl group, and X represents a hydrogen atom or a color developing agent.
Represents a group which is eliminated during the reaction. R<sub>1</sub>As a linear or
Branched alkyl (eg butyl) or aryl group
(For example, a phenyl group), preferably an alkyl group
(Especially a t-butyl group) and the like.<sub>Two</sub>As ally
A phenyl group (preferably a phenyl group).<sub>1</sub>, R<sub>Two</sub>
The alkyl and aryl groups represented by have a substituent
Also included, R<sub>Two</sub>The aryl group has a halogen atom, an alkyl
It is preferred that the group or the like is substituted. As X
A group represented by the general formula (B) or (C) is preferable.
Further, the group represented by (B) in the general formula (B) is particularly preferred.
New   General formula (B)   Where Z<sub>1</sub>Is a group of non-metallic atoms capable of forming a 4- to 7-membered ring
Express.   General formula (C)     -OR<sub>11</sub>   Where R<sub>11</sub>Represents an aryl group, a heterocyclic group or an acyl group.
In the above, an aryl group is preferred.   General formula (B ') Where Z<sub>Two</sub>Is Represents a non-metallic atomic group capable of forming a 4- to 6-membered ring with
You.   In the above general formula (A), preferred according to the present invention
The low coupler is represented by the following general formula (A ').   General formula (A ')   Where R<sub>14</sub>Is a hydrogen atom, a halogen atom, or
Represents a oxy group, preferably a halogen atom. Also R<sub>Fifteen</sub>,
R<sub>16</sub>And R<sub>17</sub>Are hydrogen, halogen, alkyl
Group, alkenyl group, alkoxy group, aryl group, carbo
Xy, alkoxycarbonyl, carbamyl, sulf
Von group, sulfomyl group, alkyl sulfonamide
Group, acylamide group, ureido group or amino group
Then R<sub>Fifteen</sub>And R<sub>16</sub>Are each a hydrogen atom, and R<sub>17</sub>But
Lucoxycarbonyl group, acylamide group or alkyl
Sulfonamide groups are preferred. X is the general formula
Represents a group having the same meaning as that shown in (A), and is preferably
A compound represented by the general formula (B) or (C),
More preferably, the group represented by the general formula (B ')
Is mentioned.   The relative coupling speed value RM / RN used in the present invention is 0.5
The above yellow coupler (hereinafter simply referred to as the yellow
Low coupler) can be added to any amount of silver halide milk
Layer, but preferably a blue-sensitive silver halide emulsion layer
And the amount of addition was 2 × 10<sup>-3</sup>~ 5 × 10
<sup>-1</sup>Mole, preferably 1 × 10<sup>-2</sup>~ 5 × 10<sup>-1</sup>
Is a mole. Below, of the yellow coupler according to the present invention
A specific example will be described, but the present invention is not limited to this.   In addition, yellow other than the yellow coupler according to the present invention
A coupler may be further added if necessary.
In this case, the present invention relates to the yellow coupler according to the present invention.
The addition amount of the outer yellow coupler is less than 0.5 in a molar ratio.
And preferably less than 0.3.   The yellow coupler according to the present invention is prepared by a solid dispersion method,
Using various methods such as water dispersion method and oil-in-water type emulsification dispersion method
Depending on the chemical structure of the coupler, etc.
You can choose any. The oil-in-water emulsion-dispersion method is
A method of dispersing a hydrophobic additive such as a puller can be applied,
Normally, high boiling organic solvents with a boiling point of about 150 ° C or higher
Dissolve with low boiling point and / or water-soluble organic solvent
Surface activity in a hydrophilic binder such as aqueous gelatin solution
Stirrer, homogenizer, colloid mill,
Using dispersion means such as a flow mixer and an ultrasonic device
After emulsifying and dispersing, the desired hydrophilic
What is necessary is just to add. Low boiling organic after or simultaneously with dispersion
A step of removing the solvent may be included.   As a high boiling organic solvent, it reacts with the oxidized form of the developing agent.
No phenol derivatives, phthalates, phosphates
Ter, citrate, benzoate, alkyl
Boiling of amide, fatty acid ester, trimesic acid ester, etc.
An organic solvent having a point of 150 ° C. or higher is used.   In the present invention, among the above high boiling organic solvents, dielectric
A high boiling point organic solvent having a ratio of 6.0 or less is particularly preferably used.
You. For example, phthalates and phosphates
Ters, organic acid amides, ketones, hydrocarbon compounds, etc.
It is. Preferably at 100 ° C with a dielectric constant of 6.0 or less and 1.9 or more
It is a high-boiling organic solvent with a vapor pressure of 0.5 mmHg or less. Ma
More preferably, phthalic acid ester in the high boiling organic solvent is used.
Ters or phosphates, more preferably
Are phthalates. In addition, two or more organic solvents are used.
May be the above mixture, in which case the dielectric constant of the mixture
Should be 6.0 or less.   The dielectric constant in the present invention indicates the dielectric constant at 30 ° C.
doing.   The dielectric constant of 6.0 or less, which is most advantageously used in the present invention.
Phthalates which are high boiling organic solvents of
What is shown by the following general formula [II] is mentioned.   General formula [II]   Where R<sub>33</sub>And R<sub>34</sub>Represents an alkyl group and an alk
Represents a nyl group or an aryl group. Where R<sub>33</sub>And R<sub>34</sub>
The total number of carbon atoms of the group represented by is 9 to 32.
More preferably, the total number of carbon atoms is 16 to 24.
You.   In the present invention, R in the general formula [II]<sub>33</sub>And R<sub>34</sub>so
The alkyl group represented is linear or branched.
For example, butyl, pentyl, hexyl, heptyl
Group, octyl group, nonyl group, decyl group, undecyl
Group, dodecyl group, tridecyl group, tetradecyl group, pen
Tadecyl, hexadecyl, heptadecyl, octa
Benzyl group and the like. R<sub>33</sub>And R<sub>34</sub>Aryl represented by
The group is a phenyl group, a naphthyl group, etc., and an alkenyl group
Is a hexenyl group, a heptenyl group, an octadecenyl group, etc.
is there. These alkyl, alkenyl and aryl
The aryl group may have one or more substituents.
As a substituent of the alkyl group and the alkenyl group,
For example, halogen atom, alkoxy group, aryl group, ant
-Oxy group, alkenyl group, alkoxycarbonyl group, etc.
Examples of the substituent such as an aryl group include
Logen atom, alkyl group, alkoxy group, aryl group,
Aryloxy group, alkenyl group, alkoxycarbonyl
Groups. Two or more of these substituents
Introduced into an alkyl, alkenyl or aryl group
May be.   Lithium having a dielectric constant of 6.0 or less, which is advantageously used in the present invention.
The acid ester is represented by the following general formula [III]
Things.   General formula [III]   Where R<sub>35</sub>, R<sub>36</sub>And R<sub>37</sub>Is an alkyl group,
Represents an alkenyl group or an aryl group. Where R<sub>35</sub>, R
<sub>36</sub>And R<sub>37</sub>The total number of carbon atoms represented by is 24 to 54
It is.   R of the general formula [III]<sub>35</sub>, R<sub>36</sub>And R<sub>37</sub>Al represented by
The kill group includes, for example, a butyl group, a benzyl group, a hexyl group,
Heptyl, octyl, nonyl, decyl, unde
A sil group, a dodecyl group, a tridecyl group, a tetradecyl group,
Pentadecyl, hexadecyl, heptadecyl,
Cutadecyl group, nonadecyl group, etc.
Are phenyl, naphthyl, etc.
Examples of the alkenyl group include a hexenyl group and a heptenyl
And octadecenyl groups.   These alkyl groups, alkenyl groups and aryl groups
May have one or more substituents. Good
Preferably R<sub>35</sub>, R<sub>36</sub>And R<sub>37</sub>Is an alkyl group, for example
For example, 2-ethylhexyl group, n-octyl group, 3,5,5-
Trimethylhexyl group, n-nonyl group, n-decyl, se
c-decyl group, sec-dodecyl group, t-octyl group and the like.
I can do it.   Examples of high-boiling organic solvents having a dielectric constant of preferably 6.0 or less
Is shown.   In order to enhance the effect of the present invention, the yellow according to the present invention is used.
The weight ratio of coupler / high boiling point organic solvent is 3.5 / 1 or less, 1.5 or less
Above is particularly preferred.   Use hydrophobic compounds alone or in combination with high-boiling solvents
Dissolved in water and disperse in water using mechanical or ultrasonic waves.
As a dispersing aid when dispersing, anionic surfactants,
Use of nonionic surfactant or cationic surfactant
Can be done.   Further, the present invention relates to a silver halide photographic light-sensitive material.
Intermediate coupler and cyan coupler
The silver halide emulsion layer of the present invention having a silver content of 80 mol% or more
It is contained in.   Magenta dye-forming couplers include azole-based couplers.
, 5-pyrazolone coupler, open-chain acylacetonit
Ril couplers and the like can be used.
As the puller, naphthol coupler and phenol
A coupler or the like can be used.   In the silver halide photographic material of the present invention,
The magenta dye image forming coupler has the following general formula
The couplers represented by [a] and [aI] are preferably used.
Can be. General formula [a] Wherein Ar represents an aryl group;<sub>1</sub>Is a hydrogen atom or
Represents a substituent, Ra<sub>Two</sub>Represents a substituent. Y is a hydrogen atom
Or it can be released by reaction with oxidized form of color developing agent
When W is -NH-, -NHCO- (N atom is pyrazolone
(Bonded to a carbon atom of the nucleus) or -NHCONH-, wherein m is
It is an integer of 1 or 2. ]   The general formula [a I]   General formula [a I] In the magenta coupler represented by, Za is a nitrogen-containing complex
Represents a group of non-metallic atoms necessary to form a ring,
The ring formed may have a substituent.   X represents a reaction with a hydrogen atom or an oxidized form of a color developing agent.
Represents a group capable of leaving.   Ra represents a hydrogen atom or a substituent.   Examples of the substituent represented by Ra include a halogen atom,
Alkyl group, cycloalkyl group, alkenyl group, cyclo
Alkenyl group, alkynyl group, aryl group, heterocycle
Group, acyl group, sulfonyl group, sulfinyl group, phospho
Nil group, carbamoyl group, sulfamoyl group, cyano
Group, spiro compound residue, organic hydrocarbon compound residue,
Coxy group, aryloxy group, heterocyclic oxy group, silo
Xy, acyloxy, carbomoyloxy,
No group, acylamino group, sulfonamide group, imide group,
Ureido group, sulfamoylamino group, alkoxycal
Bonylamino group, aryloxycarbonylamino group,
Alkoxycarbonyl group, aryloxycarbonyl
Group, alkylthio group, arylthio group, heterocyclic thio group
Is mentioned.   The compounds represented by the general formulas [a] and [aI] used in the present invention.
Magenta couplers are described, for example, in U.S. Pat.
No. 8, No. 3,061,432, No. 3,062,653, No. 3,127,2
No. 69, No. 3,311,476, No. 3,152,896, No. 3,419,39
No. 1, No. 3,519,429, No. 3,555,318, No. 3,684,5
No. 14, No. 3,888,680, No. 3,907,571, No. 3,928,
No. 044, No. 3,930,861, No. 3,930,866, No. 3,93
3,500 and the like, JP-A-49-29639, JP-A-49-111631
No. 49-129538, No. 50-13041, No. 52-58922,
No. 55-62454, No. 55-118034, No. 56-38043, No. 57
Nos. 35835 and 60-23855, UK Patent 1,247,
No. 493, Belgian Patent Nos. 769,116 and 792,525, West
Each specification of German Patent 2,156,111, JP-B-46-60479,
No.59-125732, No.59-228252, No.59-162548,
59-171956, 60-33552 and 60-43659
Report, West German Patent 1,070,030 and U.S. Patent 3,725,067
It is described in the specification and the like.   A cyan image forming coupler used in the present invention;
In addition, couplers represented by the following general formulas [E] and [F]
Can be preferably used.   General formula [E]   Where R<sub>1E</sub>Is an aryl group, a cycloalkyl group or a
Represents a ring group. R<sub>2E</sub>Represents an alkyl group or a phenyl group
Express. R<sub>3E</sub>Represents a hydrogen atom, halogen atom, alkyl group
Or an alkoxy group. Z<sub>1E</sub>Is hydrogen atom, halogen
Oxidation of atomic or aromatic primary amine color developing agents
Represents a group which can be removed by reaction with the body.   General formula [F]   Where R<sub>4F</sub>Represents an alkyl group (eg, a methyl group, ethyl
Group, propyl group, butyl group, nonyl group, etc.). R
<sub>5F</sub>Represents an alkyl group (eg, a methyl group, an ethyl group, etc.)
You. R<sub>6F</sub>Represents a hydrogen atom, a halogen atom (eg, fluorine, salt
, Bromine, etc.) or alkyl groups (eg, methyl,
Group). Z<sub>2F</sub>Is a hydrogen atom, a halogen atom or
Is the reaction with oxidized aromatic primary amine color developing agent
Represents a group capable of leaving.   The cyan image forming cap used in the present invention is described below.
The present invention is limited to these specific examples.
Not determined.   The compounds of the present invention represented by the general formulas [E] and [F]
Uncouplers are described, for example, in JP-A-59-146050 and JP-A-60-11.
Nos. 7249 and 59-31953. Other original
As the cyan coupler used in the light, for example,
U.S. Patent Nos. 2,306,410, 2,356,475, and 2,362,
No. 598, No. 2,367,531, No. 2,369,929, No. 2,42
No. 3,730, No. 2,474,293, No. 2,476,008, No. 2,4
No. 98,466, No. 2,545,687, No. 2,728,660, No. 2,
No. 772,162, No. 2,895,826, No. 2,976,146, No.
No. 3,002,836, No. 3,419,390, No. 3,446,622, No.
No. 3,476,563, No. 3,737,316, No. 3,758,308,
No. 3,839,044, UK Patent No. 478,991, No. 945,542
No. 1,084,480, No. 1,377,233, No. 1,388,02
No. 4, No. 1,543,040 and JP-A-47-040.
No. 37425, No. 50-10135, No. 50-25228, No. 50-11203
No. 8, No. 50-117422, No. 50-130441, No. 51-6551
No. 51-37647, No. 51-52828, No. 51-108841,
No. 53-109630, No. 54-48237, No. 54-66129, No. 54
Nos. 133191, 55-32071, etc.
Are included.   The magenta and cyan couplers are each green sensitive,
Even if two or more red-sensitive silver halide emulsion layers are contained in the same layer,
Good. Also the same coupler has different color sensitivity
It may be included in two or more layers.   These magenta and cyan couplers are generally
2 × 10 per mole of silver in the layer<sup>-3</sup>Mole to 1 mole, preferred
Or 1 × 10<sup>-2</sup>Mole to 8 × 10<sup>-3</sup>Used in the molar range
You.   Magenta coupler and cyan coupler used in the present invention
Is contained in the emulsion, for example, phthalic acid ester
(Dibutyl phthalate, dioctyl phthalate, etc.)
Acid esters (tricresyl phosphate, triphenyl
Lephosphate, trioctyl phosphate, etc.) or
N, N-dialkyl-substituted amides (N, N-diethyllaurin
Amide, etc.) and ethyl acetate
Of low boiling organic solvents such as butyl or butyl propionate
Each in a single solvent or, if necessary, their solvent
Mix these couplers individually in a mixture of
After dissolving with an aqueous gelatin solution containing a surfactant,
Mix, then high speed rotary mixer, colloid mill,
Or emulsified and dispersed using an ultrasonic disperser, etc.
The silver halide emulsion can be adjusted in addition to silver
Wear.   In the present invention, at least one non-photosensitive layer
It contains the compound represented by the general formula [I].   General formula [I]   In the general formula [I], R<sub>1</sub>And R<sub>Two</sub>Carbon represented by
Examples of the alkyl group of Formulas 1 to 5 include a methyl group and an ethyl group.
Group, n-propyl group, i-propyl group, n-butyl
Group, s-butyl group, n-pentyl group, neopentyl group, etc.
Is mentioned. n represents an integer of 1 to 20, preferably
K represents an integer of 2 to 15, and represents 1 or 2. A is And R<sub>Three</sub>Represents a hydrogen atom, an alkyl group, an alkenyl group,
Represents a cycloalkyl group or an aryl group,<sub>Four</sub>Is hydrogen
Represents an atom, an alkyl group or an aryl group. ), -OY
(Where Y is R<sub>Three</sub>Or And R<sub>Three</sub>Is as defined above. ), (Where R<sub>Four</sub>Is as defined above, R<sub>Five</sub>Is hydrogen atom, alkyl
Group, aryl group or And R<sub>Three</sub>Is as defined above. ), (Where l represents 0 or 1;<sub>Three</sub>Is as defined above, R<sub>6</sub>
Represents a hydrogen atom, an alkyl group, a cycloalkyl group,
Represents an aryl group or an aryl group. ) Or a cyano group
I forgot.   B is an alkyl group, an alkenyl group, a cycloalkyl group,
Aryl group, heterocyclic group or (Where R is<sub>1</sub>, R<sub>Two</sub>, n, k and A are each
Synonymous with the above. ), But R<sub>Three</sub>Alkyl represented by
Group, alkenyl group, cycloalkyl group, aryl group, R<sub>Four</sub>
An alkyl group, an aryl group represented by<sub>Five</sub>Represented by
Alkyl group, aryl group, R<sub>6</sub>An alkyl group represented by
Cycloalkyl group, alkenyl group, aryl group, and
An alkyl group, an alkenyl group, a cycloalkyl group represented by B
The kill, aryl, and heterocyclic groups each have a substituent.
Examples of the substituent of the alkyl group include
For example, a halogen atom, a cycloalkyl group, an alkenyl group,
Aryl group, alkoxy group, aryloxy group, acyl
Group, heterocyclic group, cyano group and the like, and the above alkenyl
Group, cycloalkyl group, aryl group, heterocyclic group substituent
Are, for example, a halogen atom, an alkyl group,
Alkyl, alkenyl, aryl, alkoxy,
Aryloxy group, acyl group, heterocyclic group, cyano group, etc.
No.   R<sub>Three</sub>, R<sub>Four</sub>, R<sub>Five</sub>, R<sub>6</sub>And an alkyl group represented by B
Is, for example, a methyl group, an ethyl group, an n-propyl group, an n-
Butyl group, s-butyl group, n-hexyl group, 2-ethyl
-Hexyl group, n-dodecyl group, n-hexadecyl group,
A benzyl group;<sub>Three</sub>, R<sub>6</sub>And represented by B
Examples of the alkenyl group include an aryl group.
Then R<sub>Three</sub>, R<sub>6</sub>And a cycloalkyl group represented by B
Examples include, for example, a cycloalkyl group and the like,<sub>Three</sub>, R<sub>Four</sub>,
R<sub>Five</sub>, R<sub>6</sub>And the aryl groups represented by B include, for example,
Examples include a phenyl group and a naphthyl group.   The compound represented by the general formula [I] further includes the following one
The compound represented by the general formula [I-1] or a precursor thereof is preferred.
Good.   General formula [I-1](Where R<sub>1</sub>, R<sub>Two</sub>, R<sub>Three</sub>, X and n represent the R of the general formula [I]<sub>1</sub>, R<sub>Two</sub>,
R<sub>Three</sub>, X and n. ]   Hereinafter, the compound represented by the general formula [I] used in the present invention will be described.
Specific examples of the compound are shown, but the present invention is not limited to these.
No.   The compound represented by the above general formula [I] (hereinafter referred to as the present invention)
Such a compound represented by the general formula [I])
Basically includes compounds described in JP-A-58-24141.
And the synthesis method described in the same reference can be referred to.   The compound represented by the general formula [I] according to the present invention is a halo.
Non-photosensitive layer of genated photographic light-sensitive material (for example, interlayer, protection
Layer, undercoat layer, filter layer, etc.)
It can be contained in one layer, and the amount of addition is not particularly limited.
No, but preferably 1 × 10<sup>-6</sup>~ 1 × 10<sup>-2</sup>Mol / m<sup>Two</sup>In
You. One compound represented by the general formula [I] according to the present invention is
May be used alone or in combination of two or more.
No.   In the silver halide photographic light-sensitive material of the present invention,
Halo having a silver chloride content of 80 mol% or more
The silver halide emulsion of the present invention containing silver
Each of the fast-reactive yellow couplers according to the present invention
-, Magenta coupler and cyan coupler
Having a silver halide emulsion layer, further having a non-photosensitive layer,
At least one of the non-photosensitive layers has the general formula [I]
Containing the compound.   The silver halide photographic light-sensitive material having the constitution of the present invention is, for example,
For example, color negative and positive films, and color
It can be photographic paper, but especially for direct appreciation
Of the present invention when applied to color photographic paper
Is effectively exhibited.   And yellow, magenta and cyan couplers
Silver halide emulsion layer of the present invention containing
Structure in which a functional layer is laminated on a support in an appropriate number and order of layers
However, the number and order of the layers depend on
It is out of the scope of the present invention to appropriately change the
Not.   In the silver halide photographic light-sensitive material of the present invention,
As a specific layer configuration, a layer is formed on the support in order from the support side.
Next, yellow dye image forming layer, first intermediate layer, magenta dye image
Image forming layer, second interlayer containing ultraviolet absorber, cyan
Dye image forming layer, intermediate layer containing ultraviolet absorber, protection
Arranged with layers.   The non-photosensitive layer represented by the general formula [I]
Preferred position of addition of compound contained in at least one layer
In other words, in the preferred layer constitution of the present invention,
It is a case where it is contained in the first intermediate layer, more preferably
Is the second intermediate layer containing the first intermediate layer and the ultraviolet absorber.
In the case of containing in the interlayer   The binder (or protective core) of the silver halide emulsion of the present invention.
It is advantageous to use gelatin as Lloyd)
But other than that, gelatin derivatives, gelatin and other polymers
Graft polymer, protein, sugar derivative, cellulose
Synthetic hydrophilic polymer such as conductor, mono- or copolymer
A hydrophilic colloid such as quality can also be used.   Halogen of photosensitive material using silver halide emulsion of the present invention
Of silver halide emulsion layer and / or other hydrophilic colloid layer
A plasticizer can be added for the purpose of increasing the viscosity.   Photographic milk of photosensitive material using silver halide emulsion of the present invention
Improvement of dimensional stability of agent layer and other hydrophilic colloid layers
Dispersion of water-insoluble or poorly soluble synthetic polymers for the purpose of
(Latex) can be contained.   The light-sensitive material using the silver halide emulsion of the present invention has a color
It is possible to use an image stabilizer to prevent deterioration of the raw image.
You.   Protective layer and intermediate layer of the silver halide photographic material of the present invention
The photosensitive material is charged by friction etc. on the hydrophilic colloid layer such as
Prevents fogging due to discharge due to
Contains UV absorbers to prevent deterioration due to
Good.   Photosensitive materials using the silver halide emulsion of the present invention include
Filter layer, antihalation layer, and / or irajie
An auxiliary layer such as a protection layer can be provided. these
Color and / or emulsion layer during development
Contains dyes that are spilled or bleached from the material
You may be.   Silver halide exposure using the silver halide emulsion of the present invention
Silver halide emulsion layer and / or other hydrophilicity of the material
The colloid layer reduces the gloss of the photosensitive material and enhances the brushability
Matting agent to prevent sticking of
Can be added.   Sliding of photosensitive material using silver halide emulsion of the present invention
Lubricants can be added to reduce rubbing.   The photosensitive material using the silver halide emulsion of the present invention is charged.
An antistatic agent for the purpose of prevention can be added. Antistatic agent
Is used for the antistatic layer on the side where the emulsion of the support is not laminated.
May be added to the emulsion layer and / or the support
Protective colloid layers other than the emulsion layer on the side where the layers are laminated
May be used.   Photographic milk of photosensitive material using silver halide emulsion of the present invention
The coatability of the agent layer and / or other hydrophilic colloid layers
Good, antistatic, smoothness improvement, emulsification dispersion, adhesion prevention, and
To improve photographic properties (such as acceleration of development, high contrast, sensitization, etc.)
As a target, various surfactants are used.   The photosensitive material using the silver halide emulsion of the present invention is photographic milk.
Agent and other layers are baryta layer or α-olefin polymer
-Flexible reflective support for paper and synthetic paper laminated
Body, cellulose acetate, cellulose nitrate, polystyrene,
Polyvinyl chloride, polyethylene terephthalate, polycarbonate
-From semi-synthetic or synthetic polymers such as boronate and polyamide
Film or rigid body such as glass, metal, pottery, etc.
Can be clothed.   The silver halide material of the present invention may be used on a support surface if necessary.
After applying corona discharge, ultraviolet irradiation, flame treatment, etc. to the
Contact or (adhesion of substrate surface, antistatic property, dimensional stability
Properties, abrasion resistance, hardness, antihalation properties, friction properties,
And / or one or more to improve other properties
It may be applied via a subbing layer (above).   Coating of a photographic light-sensitive material using the silver halide emulsion of the present invention
When using a thickener to improve applicability,
Good. As a coating method, apply two or more layers simultaneously
Extrusion coating and curtain
Coatings are particularly useful.   The photosensitive material of the present invention comprises a milk constituting the photosensitive material of the present invention.
Using electromagnetic waves in the spectral region where the agent layer has sensitivity
Exposure. Natural light (sunlight), tongue
Stainless electric lamp, fluorescent lamp, mercury lamp, xenon arc lamp, carbon
Arc lamp, xenon flash lamp, cathode ray tube flying
Spot, various laser light, light emitting diode light, electron
Phosphor excited by X-rays, X-rays, γ-rays, α-rays, etc.
Any known light source, such as light emitted from
it can.   Exposure time is 1 millisecond to 1 second usually used for cameras
Exposure time, of course, less than 1 microsecond, for example
100 microseconds to 1 using a cathode ray tube or xenon flashlight
Microsecond exposures can be used,
Longer exposures are also possible. The exposure is performed continuously
May be performed intermittently.   The silver halide photographic light-sensitive material of the present invention may be any of those known in the art.
It is possible to form an image by performing color development processing.
come.   Color developing agent used in color developing solution in the present invention
Is widely used in various color photographic processes
Publicly known ones are included. These developers are
Minophenol and p-phenylenediamine derivatives
Is included. These compounds are more stable than the free state
Used in the form of primary salts, for example hydrochloride or sulfate
It is. In addition, these compounds are generally used in the color developer 1.
About 0.1 g to about 30 g, preferably a color developer 1
Used at a concentration of about 1 g to about 15 g.   Examples of aminophenol-based developers include, for example, o-amido
Nophenol, p-aminophenol, 5-amino-2
-Oxytoluene, 2-amino-3-oxytoluene,
2-oxy-3-amino-1,4-dimethylbenzene
Etc. are included.   Particularly useful primary aromatic amine color developing agents are N, N '
A dialkyl-p-phenylenediamine compound.
Alkyl and phenyl groups can be substituted with any substituents.
It may be. Among them, examples of particularly useful compounds
Is N, N'-diethyl-p-phenylenediamine hydrochloride
Salt, N-methyl-p-phenylenediamine hydrochloride, N,
N'-dimethyl-p-phenylenediamine hydrochloride, 2-
Amino-5- (N-ethyl-N-dodecylamino) -to
Ruene, N-ethyl-N-β-methanesulfonamide
Tyl-3-methyl-4-aminoaniline sulfate, N-ethyl
Ru-N-β-hydroxyethylaminoaniline, 4-A
Mino-3-methyl-N, N'-dimethylaniline, 4-a
Mino-N- (2-methoxyethyl) -N-ethyl-3-
Methylaniline-p-toluenesulfonate and the like
Can be   The pH value of the color developing solution is usually 7 or more, most commonly
10 to about 13.   The silver halide photographic material of the present invention is a hydrophilic colloid.
These color developing agents are contained in the color developing layer itself.
Or as its precursor
The treatment can also be carried out using an activation bath. Color development
The main agent precursor is a color developing agent under alkaline conditions.
And an aromatic aldehyde derivative.
Schiff-based precursor, polyvalent metal ion complex
Precursor, phthalimide derivative precursor, phosphorus
Acid amide derivative precursor, sugar amine reactant
A precursor and a urethane-type precursor. This
Precursors of these aromatic primary amine color developing agents
For example, U.S. Pat.Nos. 3,342,599 and 2,507,114,
Nos. 2,695,234, 3,719,492, UK Patent 803,78
No. 3, each of JP-A-53-185628 and JP-A-54-79035.
Publications, Research Disclosure Magazine No. 15159, 1
Nos. 2146 and 13924.   These aromatic primary amine color developing agents or
When the activation treatment is performed, the racer can
It is necessary to add as much as possible to obtain a good color development. this
The amount varies greatly depending on the type of photosensitive material, but generally
Between 0.1 and 5 moles per mole of silver logenide is preferred
Or 0.5 mol to 3 mol. these
The color developing agent or its precursor may be used alone or in combination.
It can also be used in combination. To incorporate in photosensitive materials
Suitable solvents such as water, methanol, ethanol, acetone, etc.
Can be added by dissolving in dibutyl phthalate,
Dioctyl phthalate, tricresyl phosphate, etc.
As an emulsified dispersion using a high boiling organic solvent
In Research Disclosure Magazine No. 14850
Impregnate latex polymer as described and add
Can be added.   Hydroxylamine is used as a preservative in the color developer.
It is preferable to contain a system compound. Hydroxyl
The amine compound is not particularly limited.
Roxylamine itself or N-methylhydroxyl hydrochloride
N-monoalkylhydroxylamines such as cyamines,
Alternatively, N, N-diethylhydroxyamine, U.S. Pat.
Aminoalkylhydroxylamines described in No. 87,125
Alkoxyhydroxy described in 3,293,034
Lumine, sulfone hydro described in 3,287,124
N, N-dialkylhydroxyl such as xylamine
Heterocycles such as min or N-hydroxypiperidine
Formula N-hydroxylamine as it is or in the form of a salt
It is usually used in a cost-effective, stable, water-soluble,
From the commercial viewpoints such as feedability and suitability for use, hydroxy sulfate
Amine, hydroxylamine hydrochloride, oxalic acid N, N-diethyl
Preferred are hydroxylamine and the like.   The concentration of the hydroxylamine compound used may vary
Depends on the type and concentration of image agent, pH and temperature of color developer
However, the preferred concentration of the hydroxylamine compound is colored.
Preferably 0.01 to 0.2 mol per developer, more preferably
In the range of 0.010 to 1.10 mol. Color development of the present invention
The liquid is sodium hydroxide, hydroxyl as a normal alkaline agent
Potassium chloride, ammonium hydroxide, sodium carbonate, charcoal
Potassium acid, sodium sulfate, sodium metaborate, No.
Appropriately selected from sodium triphosphate, tertiary potassium phosphate, etc.
Is added. Phosphorus to provide alkaline buffering capacity
Disodium hydrogen oxyphosphate, dipotassium hydrogen phosphate, dihydrogen phosphate
Sodium, potassium dihydrogen phosphate, potassium heavy carbon, heavy
Various salts such as sodium carbon are used.   Color developing solutions also include sulfites (eg, sodium sulfite).
Thorium, potassium sulfite), various additives such as
Alcohol, alkali halides such as odor
Potassium chloride or potassium chloride, or a development regulator
As citrazinic acid, etc., as well as various defoamers and surfactants
Activating agent, also methanol, dimethylformamide or
Organic solvents such as dimethyl sulfoxide etc.
Can be   However, benzyl alcohol is used in the color developing solution of the present invention.
Is not always necessary, and is reduced from the viewpoint of low pollution
Alternatively, it is preferable to remove them. Also bromide ion concentration
The degree is converted to potassium bromide and is 0.4 per color developing solution.
2.02.0 g, preferably 0.6-1.5 g.   Color development processing of the silver halide photographic light-sensitive material according to the present invention
Can be applied under any conditions.
Preferably, it is processed at a temperature of 30 ° C or higher and 45 ° C or lower, and the developing time is 40 ° C.
The time is preferably not less than seconds and not more than 120 seconds.   The silver halide photographic light-sensitive material of the present invention, after color development,
Bleaching and fixing are performed. Bleaching and fixing
It may be performed simultaneously. Many compounds are used as bleach
Among them, iron (III), cobalt (III), copper (I
Polyvalent metal compounds such as I), especially those polyvalent metal compounds
Complex salts of thione and organic acids, such as ethylenediaminetetravinegar
Acid, nitrilotritriacetic acid, N-hydroxyethylethylene
Aminopolycarboxylic acids such as diamine diacetate, malo
Acid, tartaric acid, malic acid, diglycolic acid, dithiogly
Metal complex salts such as cholic acid or ferricyanates,
When used alone or in an appropriate combination such as dichromate
It is.   As a fixing agent, solubilizes silver halide as a complex salt
A soluble complexing agent is used. As this soluble complexing agent
Is, for example, sodium thiosulfate, ammonium thiosulfate
System, potassium thiocyanate, thiourea, thioether, etc.
Is mentioned.   After the fixing process, a washing process is usually performed. Also water
As an alternative to the washing process, a stabilizing process may be performed,
May be used together. Stabilizing liquid used for stabilization processing
Contains a pH adjuster, chelating agent, anti-bubble agent, etc.
be able to. These specific conditions are described in JP-A-58-134636.
No. 3 publication can be referred to. [Specific effects of the invention]   As described above, in the present invention, the high developing speed
Not only at high color development speeds,
Highly sensitive silver halide with minimal turbidity
A photographic light-sensitive material could be provided. 〔Example〕   Hereinafter, the present invention will be described in detail with reference to specific examples.
However, the present invention is not limited to these embodiments. [Example 1]   Multilayer silver halide photographic light-sensitive material having the composition shown in Table 1.
It was created. In addition, included in the second layer, the fourth layer, and the sixth layer
An anti-stain agent, and a yellow pigment contained in the first layer.
The puller was changed as shown in Table-2. <Adjustment of silver halide emulsion> (EM-A) (silver chloride)   Inert gelatin aqueous solution of silver nitrate solution and sodium chloride solution
The solution was added for 60 minutes by the double jet method. At this time
The temperature was kept at 50 ° C. and pAg = 7.0.   Next, desalting and washing were performed by a conventional method to obtain EM-A.   EM-A consists of cubic silver chloride grains having an average grain size of 0.8 μm.
You. (EM-B) (silver chlorobromide)   Contains silver nitrate solution and sodium chloride and potassium bromide
Aqueous solution into inert gelatin aqueous solution by double jet method
Was added. At this time, keep the temperature at 60 ° C and pAg = 5.5
I made it.   Next, desalting and washing were performed by a conventional method to obtain EM-B.   EM-B is cubic silver chlorobromide particles having an average particle diameter of 0.8 μm (salt
(Silver halide content: 20 mol%).   The EM-A and EM-B obtained here were subjected to sodium thiosulfate.
Sensitizing dye [SD-1]
Was spectrally sensitized.   The following emulsions were prepared in the same manner as EM-A and EM-B.
Was.   Spectral sensitizing dye used   The structures of the compounds used in the table are shown below.   A sensitometer (Konishi Roku Photo Kogyo Kogyo Co., Ltd.)
Light wedge exposure with white light using KS-7
After that, the following treatment was performed.   Here, the following tests were conducted to examine the effects of the present invention.
Was. Sensitometry   Photoelectric densitometer (Konishi Roku Photographic Industry Co., Ltd.)
(PDA-65 manufactured by Co., Ltd.)
Radiation density was determined, and the obtained results are shown in Table-3. Color turbidity test   Yellow light emission using blue exposure instead of white exposure
After obtaining a color sample, the blue density (DB) of the sample gives 1.0
From the third layer depending on the green density component (DG)
The characteristic of color turbidity of the layer was taken as a representative characteristic.   Similarly, green exposure is performed to obtain a magenta coloring sample,
Red furnace density component (D when green density (DG) gives 1.0
R) as the representative characteristic of color turbidity from the 5th layer to the 3rd layer
Was.   The lower these values are, the better the color turbidity is.         [Treatment process] Temperature Time             Color development 34.7 ± 0.3 ℃ 50 seconds             Bleaching and fixing 34.7 ± 0.5 ℃ 50 seconds               Stabilization 30 to 34 ° C 90 seconds                 Drying 60 to 80 ° C 60 seconds [Color developing solution]   800ml pure water   Ethylene glycol 10ml   N, N-diethylhydroxylamine 10g   Potassium chloride 2g   N-ethyl-N-β-methanesulfonamidoethyl-
3-methyl-4-aminoaniline sulfate 5g   Sodium tetrapolyphosphate 2g   Potassium carbonate 30g   Optical brightener (4,4'-diaminostilbene disulfone
Acid derivative) 1g   Add water to make the total volume 1 and adjust to pH 10.08. (Bleaching fixer)   Ferric ammonium ethylenediaminetetraacetate diwater
60g salt   Ethylenediaminetetraacetic acid 3g   Ammonium thiosulfate (70% solution) 100ml   Ammonium sulfite (40% solution) 27.5ml   Adjust the pH to 7.1 with potassium carbonate or glacial acetic acid and add water.
And the total amount is 1. (Stabilizing solution)   5-chloro-2-methyl-4-isothiazoline-3-
ON 1g   1-hydroxyethylidene-1,1-diphosphonic acid 2 g   Add water to make 1 and add sulfuric acid or potassium hydroxide to pH
Adjust to 7.0.   From the results in Table 3, first, halo with a low silver chloride content ratio
Compare Samples 1 to 4 using silver gemide emulsion
Then, for the sample 1, the stain inhibitor according to the present invention and
The yellow coupler according to the present invention may be used alone or in combination.
Even when the rapid processing as shown in this embodiment is performed,
It is clear that the sensitivity and maximum density do not improve much.
You.   On the other hand, halogen having a high silver chloride content
In Sample 5 using silver halide emulsion, sensitivity and maximum density
Is slightly improved, but color turbidity is significantly deteriorated.
It greatly affects reproduction. In addition, the sample 5
Sample 6 using the stain inhibitor according to the present invention and the present invention
Color turbidity was observed even in Sample 8 using the yellow coupler.
There is no significant improvement in. Further, as in sample 9.
In addition, even if the amount of the stain inhibitor other than the present invention is increased, the color turbidity hardly occurs.
Not only is it not improved, but the desensitization increases.   7, 10 to 13 according to the present invention compared to these comparative samples
In the color turbidity is improved to a level that does not have any problem, and
Sufficient sensitivity and maximum concentration for rapid processing
Was.   Also, as in sample 14, halogenation with a low silver chloride ratio
When silver emulsion is used, relative sensitivity and maximum density or
Deterioration occurs in color turbidity. [Example 2]   The yellow coupler was used in Sample 7 of Example 1.
Samples 15, 16, 17 were changed to Y-3, Y-8, Y-12 and Y-23.
And created 18. Similarly, the stain inhibitor is H-
Changed to 2, H-4, H-10 and H-11, samples 19, 20, 21 and
And 22 were created.   These samples 15 to 22 according to the present invention and
When the same test was performed, the result was almost the same as that of Example 1.
I got [Example 3] <Preparation of silver halide emulsion>   Contains silver nitrate aqueous solution and sodium chloride and potassium bromide
Aqueous solution into inert gelatin aqueous solution by double jet method
Was added. At this time, keep the temperature at 45 ° C and the pAg at 7.0
I made it.   Next, desalting and washing are performed by a conventional method, and the standing is shown in Table-4.
EM-L was obtained from a rectangular silver chlorobromide emulsion EM-G.   From EM-G obtained here, sodium thiosulfate was added to EM-L.
And chloroauric acid were added for chemical sensitization.
Spectral sensitization was performed using a spectral sensitizing dye.   In the same manner as in the configuration shown in Example 1, multilayer silver halide was used.
A photographic light-sensitive material was prepared. The stain prevention of the present invention
, Yellow coupler and silver halide emulsion are shown in Table 1.
5 was changed. Magenta coupler
Table 5 also shows the cyan coupler and the cyan coupler.   In Table 5, the amount of silver coated on the third layer of Sample 37 was 0.2 g / m2.<sup>Two</sup>age
Was.   The obtained samples 30 to 38 were exposed to light in the same manner as in Example 1.
Then, sensitometry and color turbidity test were performed. Get
The results obtained are shown in Table-6.   However, the following processing was performed here. [Development processing step]                     Temperature (° C) Time (second)           Color development 35.0 ± 0.3 45           Bleaching and fixing 35.0 ± 0.5 45           Color development 35.0 ± 0.3 45            Stabilization 35-34 90             Drying 60-80 60   The composition of the processing solution used in each processing step is as follows.
You. "Color developer"   800ml pure water   Triethanolamine 10g   N, N-diethylhydroxyamine 5g   Potassium chloride 2g   Potassium bromide 0.010g   0.3 g of potassium sulfite   1.0 g of 1-hydroxyethylidene-1,1-diphosphonic acid   1.0 g of ethylenediaminetetraacetic acid   Catechol-3,5-disulfonic acid disodium salt 1.0 g   N-ethyl-N-β-methanesulfonamidoethyl-
4.5 g of 3-methyl-4-aminoaniline sulfate   Potassium carbonate 27g   Optical brightener (4-4'-diaminostilbene disulfo
Acid derivative) 1.0g   Add water to bring the total volume to 1 and adjust to pH = 10.10. `` Bleaching fixer ''   Pure water   Ferric ammonium ethylenediaminetetraacetate diwater
salt   Ethylenediaminetetraacetic acid   Ammonium thiosulfate (70% solution)   Ammonium sulfite (40% solution)   Adjust the pH to 6.2 with potassium carbonate or glacial acetic acid,
In addition, the total amount is set to 1. `` Stabilizing liquid ''   5-chloro-2-methyl-isothiazolin-3-one                                               1.0g   1.0 g of ethylene glycol   1-hydroxyethylidene-1,1-diphosphonic acid 20 g   1.0 g of ethylenediaminetetraacetic acid   Ammonium hydroxide (20% aqueous solution) 3.0g   Ammonium sulfite 3.0g   Optical brightener (4-4'-diaminostilbene disulfo
Acid derivative) 1.5g   Add water to make 1 and add sulfuric acid or potassium hydroxide to pH
= 7.0.   From the results in Table-6, it is found that Samples 32 to 38 having the structure of the present invention were used.
Has no color turbidity as compared with Comparative Samples 30 and 31.
Improved bell and sensitivity and highest in rapid processing
It turns out that the concentration is sufficient. [Example 4]   In Sample 32 in Example 3, the yellow coupler was used.
Samples 41, 42, 43 were changed to Y-3, Y-8, Y-12 and Y-23.
And created 44. Similarly, the stain inhibitor is H
−2, H−4, H−10 and H−11 and changed to samples 45, 46, 47 and
And 48 were created.   For these samples 41 to 48 according to the present invention, Example 3
When the same test was performed, the same result as in Example 3 was obtained.
Obtained.

Continuation of front page                   (56) References JP-A-61-80249 (JP, A)                 JP-A-60-19140 (JP, A)                 JP-A-60-60647 (JP, A)

Claims (1)

(57) [Claims] Relative coupling reaction rate ratio RM / RN value of 0.5 on the support
A silver halide emulsion layer containing a yellow coupler, a silver halide emulsion layer containing a magenta coupler and a silver halide emulsion layer containing a cyan coupler,
And a silver halide photographic material having a photographic layer composed of a non-photosensitive layer, wherein the silver halide emulsion layer contains silver halide grains each having a silver chloride content of 80 mol% or more, And a silver halide photographic material wherein at least one of the non-photosensitive layers contains at least one compound represented by the following general formula [I]. General formula [I] [Wherein, R ₁ and R ₂ each represent an alkyl group having 1 to 5 carbon atoms, n represents an integer of 1 to 20, and k represents 1 or 2. A is The stands, R ₃ is a hydrogen atom, an alkyl group, an alkenyl group,
R ₄ represents a hydrogen atom, an alkyl group or an aryl group; ), -OY
(Where Y is R ₃ or And R ₃ is as defined above. ), (Where R ₄ is as defined above, and R ₅ is a hydrogen atom, an alkyl group, an aryl group or And R ₃ is as defined above. ), (Where l represents 0 or 1, R ₃ is as defined above,
R ₆ represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group or an aryl group. ) Or a cyano group. B is an alkyl group, an alkenyl group, a cycloalkyl group,
Aryl group, heterocyclic group or Wherein R ₁ , R ₂ , n, k and A have the same meanings as described above. ]