JP2815137B2 - Synthetic resin laminated film for molding and coloring molding - Google Patents
Synthetic resin laminated film for molding and coloring moldingInfo
- Publication number
- JP2815137B2 JP2815137B2 JP7169437A JP16943795A JP2815137B2 JP 2815137 B2 JP2815137 B2 JP 2815137B2 JP 7169437 A JP7169437 A JP 7169437A JP 16943795 A JP16943795 A JP 16943795A JP 2815137 B2 JP2815137 B2 JP 2815137B2
- Authority
- JP
- Japan
- Prior art keywords
- molding
- colored
- synthetic resin
- resin layer
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Laminated Bodies (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明はモールディング用合成樹
脂積層フィルムに関し、さらに詳しくは、車両のボディ
ーパネル、バンパー、ウインドウトリムなどの保護用お
よび装飾用に取り付けられる合成樹脂製モールディング
を、車両のボディーカラーと同色にもしくはデザイン上
の好適な色に着色するために、モールディングの表面に
被着される合成樹脂着色積層フィルムに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a synthetic resin laminated film for molding and, more particularly, to a synthetic resin molding for protection and decoration of vehicle body panels, bumpers, window trims, etc. The present invention relates to a synthetic resin colored laminated film to be applied to the surface of a molding to be colored in the same color as the color or a suitable color in design.
【0002】[0002]
【従来の技術】車両のボディーパネルやバンパーに取り
付けられる合成樹脂製モールディングは、通常、車両の
ボディーカラーと同色に着色される。従来、この合成樹
脂製モールディングの着色は、モールディングを成形し
た後ウレタン塗料などを塗装することにより行われてき
た。2. Description of the Related Art A synthetic resin molding mounted on a vehicle body panel or a bumper is usually colored in the same color as the vehicle body color. Conventionally, coloring of this synthetic resin molding has been performed by applying a urethane paint or the like after molding the molding.
【0003】金属色調のモールディングの製造法とし
て、金属を蒸着した合成樹脂フィルムを樹脂製モールデ
ィング表面に被着させ、モールディングを金属色調に着
色する方法が採用され始めており、本願出願人は金属蒸
着フィルムにさらに無延伸ポリフッ化ビニル樹脂を被着
積層したモールディング被着用の積層フィルムを開発し
た(実願平3−41711号)。[0003] As a method of manufacturing a metal-tone molding, a method of attaching a synthetic resin film on which a metal is deposited to a resin molding surface and coloring the molding to a metal tone has begun to be adopted. In addition, a laminated film to be coated with a molding was further developed by applying and laminating a non-stretched polyvinyl fluoride resin (Japanese Utility Model Application No. 3-41711).
【0004】[0004]
【発明が解決しようとする課題】塗装モールディングは
曲げ追従などの加工性、塗膜の接着性、耐衝撃性、耐候
性、防汚性などが不十分であり改良が望まれているにも
かかわらず、金属色調以外の色調に着色するためのモー
ルディング被着用の着色積層フィルムが開発されていな
いことから、依然として塗装法が採用されている。[0005] Although the coating molding is insufficient in workability such as bending follow-up, adhesion of coating film, impact resistance, weather resistance, antifouling property and the like, improvement is desired. However, since a colored laminated film to be coated with a molding for coloring to a color tone other than the metal tone has not been developed, a coating method is still employed.
【0005】本発明は、加工性、耐候性、防汚性に優れ
たモールディング被着用合成樹脂着色積層フィルムを提
供することを目的とし、合成樹脂着色積層フィルムを被
着した着色モールディングを提供することを別の目的と
する。SUMMARY OF THE INVENTION An object of the present invention is to provide a colored laminated synthetic resin film which is excellent in processability, weather resistance and antifouling properties. For another purpose.
【0006】[0006]
【課題を解決するための手段】本発明は、無色透明の無
延伸ポリフッ化ビニル樹脂層および着色合成樹脂層を少
なくとも有することを特徴とするモールディング用合成
樹脂着色積層フィルムである。また第2の発明は、前記
合成樹脂着色積層フィルムが、無色透明の無延伸ポリフ
ッ化ビニル樹脂層を外側にしてモールディングに被着し
ていることを特徴とする着色モールディングである。SUMMARY OF THE INVENTION The present invention is a colored synthetic resin laminated film for molding, comprising at least a colorless and transparent unstretched polyvinyl fluoride resin layer and a colored synthetic resin layer. A second invention is a colored molding characterized in that the synthetic resin colored laminated film is attached to the molding with the colorless and transparent unstretched polyvinyl fluoride resin layer facing outside.
【0007】本発明の合成樹脂着色フィルムにおいて、
無色透明の無延伸ポリフッ化ビニル樹脂層は、溶液流延
法、T−ダイ押出し法などにより製造されるが、溶液流
延法により得られる無延伸ポリフッ化ビニル樹脂層が、
方向性がなく、厚みの均一性、平面性、透明性および光
沢の優れたフィルム層であるため好適である。In the synthetic resin colored film of the present invention,
The colorless and transparent unstretched polyvinyl fluoride resin layer is manufactured by a solution casting method, a T-die extrusion method, or the like.
It is suitable because it is a film layer having no directionality and having excellent thickness uniformity, flatness, transparency and gloss.
【0008】無色透明の無延伸ポリフッ化ビニル樹脂層
は、具体的には、ポリフッ化ビニルを有機溶媒に溶解し
ゴミや気泡を完全に除去した溶液を、支持体面上に流延
して得られるフィルム層であり、その厚さには特に制限
はないが、通常、12〜76μmである。[0008] The colorless and transparent unstretched polyvinyl fluoride resin layer is specifically obtained by casting a solution obtained by dissolving polyvinyl fluoride in an organic solvent and completely removing dust and bubbles on the surface of the support. It is a film layer, and its thickness is not particularly limited, but is usually 12 to 76 μm.
【0009】ポリフッ化ビニル溶液の流延に用いる支持
体は、平滑な表面を有し流延後のフィルムを容易に剥離
できるものであればよく、たとえばポリマーフィルム、
スチールベルトなどを使用することができる。好ましい
支持体は、合成樹脂着色積層フィルムのモールディング
への被着時、加工時、運搬時まで、その表面を傷付きか
ら保護する保護フィルムとして利用できるポリマーフィ
ルムであり、特にポリエステルフィルムが好ましい。こ
の保護フィルムは、合成樹脂着色積層フィルムのモール
ディングへの被着後、モールディングを装着した製品の
使用時までの間に剥離される。The support used for casting the polyvinyl fluoride solution may be any one which has a smooth surface and can easily peel off the film after casting.
A steel belt or the like can be used. A preferred support is a polymer film which can be used as a protective film for protecting the surface of the synthetic resin colored laminated film from being damaged until it is applied to a molding, processed, or transported, and a polyester film is particularly preferred. The protective film is peeled off after the synthetic resin-colored laminated film is applied to the molding and before the product equipped with the molding is used.
【0010】無延伸ポリフッ化ビニル樹脂層は、単層構
造であってもよく、また界面に接着剤層の存在しない多
層構造であってもよい。たとえば2層構造の無延伸ポリ
フッ化ビニル樹脂層は、第1のポリフッ化ビニル層を形
成した後、その層上に第2のポリフッ化ビニル溶液を流
延し、第1のポリフッ化ビニル層の融点より低い温度に
おいて第2のポリフッ化ビニル層を合体させることによ
り製造することができる。The non-stretched polyvinyl fluoride resin layer may have a single-layer structure or a multilayer structure having no adhesive layer at the interface. For example, in a two-layer unstretched polyvinyl fluoride resin layer, after forming a first polyvinyl fluoride layer, a second polyvinyl fluoride solution is cast on the first polyvinyl fluoride layer to form a first polyvinyl fluoride layer. It can be manufactured by combining the second polyvinyl fluoride layer at a temperature lower than the melting point.
【0011】着色合成樹脂層は、合成樹脂に顔料を配合
した着色合成樹脂、たとえばポリ塩化ビニル、ポリエス
テル、ポリプロピレン、ポリエチレン、ABS樹脂など
の着色フィルムである。通常、モールディング成形材料
としてはポリ塩化ビニルが使用されるので、合成樹脂着
色積層フィルムの接合性からポリ塩化ビニルが好適であ
る。着色合成樹脂層の厚さには特に制限はないが、通
常、50〜200μmのフィルムである。The colored synthetic resin layer is a colored film of a colored synthetic resin obtained by mixing a pigment with a synthetic resin, for example, polyvinyl chloride, polyester, polypropylene, polyethylene, ABS resin and the like. Normally, polyvinyl chloride is used as the molding material, and thus polyvinyl chloride is preferable from the viewpoint of the bonding property of the synthetic resin colored laminated film. Although the thickness of the colored synthetic resin layer is not particularly limited, it is usually a film of 50 to 200 μm.
【0012】着色合成樹脂層の製造方法には特に制限は
なく、たとえば溶液流延法、カレンダー法などを採用す
ることができる。溶液流延法の場合には、樹脂を有機溶
剤に溶解しさらに顔料を添加分散した分散液を支持体上
に流延して製造する。カレンダー法の場合には、樹脂と
顔料とをブレンダーに入れて混合した後、バンバリーミ
キサー、ミキシングロール、エキストルーダーなどで混
練し、カレンダーに供給し圧延する。これらの方法で
は、使用する顔料への制限がほとんどないため多種多様
な色調を実現でき、また微妙な色調にも十分対応するこ
とができる。The method for producing the colored synthetic resin layer is not particularly limited, and for example, a solution casting method, a calendar method, or the like can be employed. In the case of the solution casting method, a resin is dissolved in an organic solvent, and a dispersion liquid in which a pigment is added and dispersed is cast on a support to produce the resin. In the case of the calendering method, the resin and the pigment are put in a blender and mixed, then kneaded with a Banbury mixer, a mixing roll, an extruder, etc., supplied to a calender and rolled. In these methods, since there is almost no restriction on the pigment to be used, a wide variety of color tones can be realized, and it is possible to sufficiently cope with subtle color tones.
【0013】本発明の合成樹脂着色積層フィルムは、前
記着色合成樹脂層と前記無色透明の無延伸ポリフッ化ビ
ニル樹脂層とをウレタン系、アクリル系などの両層を接
着するのに適した公知の接着剤層を介して接合すること
により製造される。The synthetic resin-colored laminated film of the present invention comprises a known synthetic resin-colored laminated layer and a colorless and transparent unstretched polyvinyl fluoride resin layer, which are suitable for bonding both urethane-based and acrylic-based layers. It is manufactured by bonding via an adhesive layer.
【0014】本発明の合成樹脂着色積層フィルムの別の
態様は、無色透明の無延伸ポリフッ化ビニル樹脂層、着
色した無延伸ポリフッ化ビニル樹脂層からなる着色合成
樹脂層および着色合成樹脂層に接合させた合成樹脂フィ
ルム層を少なくとも有するモールディング用合成樹脂着
色積層フィルムである。Another embodiment of the synthetic resin colored laminated film of the present invention is a colorless and transparent unstretched polyvinyl fluoride resin layer, a colored synthetic resin layer composed of a colored unstretched polyvinyl fluoride resin layer, and a bonding to the colored synthetic resin layer. It is a synthetic resin colored laminated film for molding having at least a synthetic resin film layer formed.
【0015】この態様において、無色透明の無延伸ポリ
フッ化ビニル樹脂層と着色した無延伸ポリフッ化ビニル
樹脂層からなる着色合成樹脂層とは接着剤層を介さずに
接合した2層構造からなり、前記した溶液流延法により
製造した無色透明の無延伸ポリフッ化ビニル樹脂層上
に、顔料を配合したポリフッ化ビニル溶液を流延し、無
色透明の無延伸ポリフッ化ビニル樹脂層の融点より低い
温度で合体させることにより製造される。In this embodiment, the colorless and transparent unstretched polyvinyl fluoride resin layer and the colored synthetic resin layer made of the colored unstretched polyvinyl fluoride resin layer have a two-layer structure joined without an adhesive layer therebetween, On the colorless and transparent unstretched polyvinyl fluoride resin layer produced by the solution casting method described above, a polyvinyl fluoride solution containing a pigment is cast, and the temperature is lower than the melting point of the colorless and transparent unstretched polyvinyl fluoride resin layer. It is manufactured by combining.
【0016】次いで、得られた無色透明の無延伸ポリフ
ッ化ビニル樹脂層と着色合成樹脂層との2層構造からな
る積層フィルムの着色合成樹脂層表面に、前記したウレ
タン系、アクリル系などの接着剤層を介してモールディ
ング成形材料と同種の合成樹脂フィルム層を接合させる
ことにより、合成樹脂着色積層フィルムを製造すること
ができる。Next, the urethane-based or acrylic-based adhesive is adhered to the surface of the colored synthetic resin layer of the laminated film having the two-layer structure of the obtained colorless and transparent unstretched polyvinyl fluoride resin layer and the colored synthetic resin layer. By joining a synthetic resin film layer of the same type as the molding material through the agent layer, a synthetic resin colored laminated film can be manufactured.
【0017】この態様においては、ポリフッ化ビニル溶
液に用いる有機溶剤に制限があり、その有機溶剤との相
性から配合される顔料はある程度の制限を受けるので、
着色した無延伸ポリフッ化ビニル樹脂層の色調の多様性
の点では制限がある。In this embodiment, the organic solvent used for the polyvinyl fluoride solution is limited, and the pigment to be compounded is restricted to some extent due to the compatibility with the organic solvent.
There is a limit in terms of the diversity of the color tone of the colored unstretched polyvinyl fluoride resin layer.
【0018】本発明の合成樹脂着色積層フィルムの無色
透明の無延伸ポリフッ化ビニル樹脂層、着色合成樹脂層
および合成樹脂フィルム層のそれぞれには、所望により
可塑剤、滑剤、紫外線安定剤などの添加剤を得られる着
色積層フィルムの特性を損なわない範囲で配合すること
ができる。The colorless and transparent unstretched polyvinyl fluoride resin layer, the colored synthetic resin layer, and the synthetic resin film layer of the synthetic resin colored laminated film of the present invention may optionally contain a plasticizer, a lubricant, an ultraviolet stabilizer, and the like. It can be blended within a range that does not impair the properties of the colored laminated film from which the agent can be obtained.
【0019】本発明の着色モールディングは、前記合成
樹脂着色積層フィルムを、モールディングへの被着後に
無色透明の無延伸ポリフッ化ビニル樹脂層が外側層とな
るようにモールディング成形用押出し成形機のダイにセ
ットし、モールディングを押出し成形してモールディン
グ表面に合成樹脂着色積層フィルムを被着させることに
より製造することができる。The colored molding according to the present invention is characterized in that the synthetic resin colored laminated film is applied to a die of an extruder for molding molding such that a colorless and transparent unstretched polyvinyl fluoride resin layer becomes an outer layer after being applied to the molding. It can be manufactured by setting, extruding a molding, and applying a synthetic resin colored laminated film to the surface of the molding.
【0020】[0020]
【作用】本発明の合成樹脂着色積層フィルムは、モール
ディングとの被着面をモールディング成形材料と同種の
合成樹脂層としたことにより、合成樹脂着色積層フィル
とモールディング表面との接合性が優れ、加工性が極め
て良好である。The synthetic resin-colored laminated film of the present invention has excellent bonding properties between the synthetic resin-colored laminated fill and the molding surface by forming the surface to be adhered to the molding with a synthetic resin layer of the same type as the molding material. The properties are very good.
【0021】また、本発明の着色モールディングは、最
外層に無色透明の無延伸ポリフッ化ビニル樹脂層を有す
るため、耐候性、防汚性および褪色性に優れ、さらに着
色合成樹脂層に着色した無延伸ポリフッ化ビニル樹脂層
を採用した場合には、さらに優れた褪色性を実現でき
る。Further, the colored molding of the present invention has a colorless and transparent unstretched polyvinyl fluoride resin layer as the outermost layer, so that it has excellent weather resistance, antifouling property and fading property, and furthermore, the colored synthetic resin layer is colored When a stretched polyvinyl fluoride resin layer is employed, more excellent fading can be realized.
【0022】[0022]
【実施例】本発明を実施例および比較例により、さらに
詳細に説明する。 実施例 1 厚さ25μmのポリエステルフィルム上に溶液流延法に
より形成した厚さ25μmの無色透明の無延伸ポリフッ
化ビニルフィルム(デュポン社製テドラーSP)と厚さ
100μmの着色ポリ塩化ビニルフィルム(黄色)と
を、アクリル系接着剤(デュポン社製68080)を介
して重ね合わせ、180℃の熱プレスにより接合し、合
成樹脂着色積層フィルムを調製した。得られた着色積層
フィルムを、モールディング成形用押出し成形機のダイ
に、ポリ塩化ビニル面がモールディングとの被着面とな
るようにセットしてポリ塩化ビニルを押出し成形機から
押出し、表面に着色積層フィルムの被着したモールディ
ングを成形し、ポリエステルフィルムを剥離して実施試
料1を調製した。The present invention will be described in more detail with reference to examples and comparative examples. Example 1 A 25 μm thick colorless and transparent unstretched polyvinyl fluoride film (Tedlar SP manufactured by DuPont) and a 100 μm thick colored polyvinyl chloride film (yellow) formed on a 25 μm thick polyester film by a solution casting method. ) Were overlapped with each other via an acrylic adhesive (68080 manufactured by DuPont) and joined by hot pressing at 180 ° C. to prepare a synthetic resin colored laminated film. The obtained colored laminated film is set on the die of the extruder for molding molding so that the polyvinyl chloride surface becomes the surface to be adhered to the molding, and the polyvinyl chloride is extruded from the extruder and colored and laminated on the surface. The molding on which the film was adhered was formed, and the polyester film was peeled off to prepare Working Sample 1.
【0023】実施例 2 厚さ25μmのポリエステルフィルム上に溶液流延法に
より形成した無色透明の無延伸ポリフッ化ビニル層と着
色した無延伸ポリフッ化ビニル層とからなる厚さ25μ
mの着色フィルム(黄色)(デュポン社製テドラーSP)
と厚さ100μmのポリ塩化ビニルフィルムとを、アク
リル系接着剤(デュポン社製68080)を介して重ね
合わせ、180℃の熱プレスにより接合し、合成樹脂着
色積層フィルムを調製した。得られた着色積層フィルム
を、モールディング成形用押出し成形機のダイに、ポリ
塩化ビニル面がモールディングとの被着面となるように
セットしてポリ塩化ビニルを押出し成形機から押出し、
表面に着色積層フィルムの被着したモールディングを成
形し、ポリエステルフィルムを剥離して実施試料2を調
製した。Example 2 A colorless and transparent unstretched polyvinyl fluoride layer formed on a 25 μm-thick polyester film by a solution casting method and a colored unstretched polyvinyl fluoride layer having a thickness of 25 μm
m colored film (yellow) (Tedlar SP manufactured by DuPont)
And a polyvinyl chloride film having a thickness of 100 μm were overlapped with each other via an acrylic adhesive (68080 manufactured by DuPont) and joined by hot pressing at 180 ° C. to prepare a synthetic resin colored laminated film. The obtained colored laminated film is set on a die of an extruder for molding molding, and is set so that the polyvinyl chloride surface becomes an adherent surface with the molding, and extrudes polyvinyl chloride from the extruder,
A molding having a colored laminated film adhered to the surface thereof was formed, and the polyester film was peeled off to prepare Working Sample 2.
【0024】比較例 1 ポリ塩化ビニルを押出し成形したモールディングに、ウ
レタン系塗料(黄色)を塗装し比較試料1を調製した。Comparative Example 1 A urethane-based paint (yellow) was applied to a molding obtained by extruding polyvinyl chloride to prepare a comparative sample 1.
【0025】比較例 2 厚さ125μmの着色ポリ塩化ビニルフィルム(黄色)
をモールディング成形用押出し成形機のダイにセットし
てポリ塩化ビニルを押出し成形機から押出し、表面に着
色ポリ塩化ビニルフィルムの被着したモールディングを
成形し、比較試料2を調製した。Comparative Example 2 Colored polyvinyl chloride film having a thickness of 125 μm ( yellow )
Was set in a die of an extruder for molding molding, polyvinyl chloride was extruded from the extruder, and a molding having a surface coated with a colored polyvinyl chloride film was molded to prepare Comparative Sample 2.
【0026】〔評価試験〕前記調製した実施試料1およ
び2ならびに比較試料1および2について、下記の方法
により耐候性および防汚性を評価し、結果を表1に示し
た。 耐候性試験方法 アイスーパーUVテスター(岩崎電機(株)製、SUV−W1
3)を使用し、下記の条件で耐候性試験を実施した。 光 源 メタルハライドランプ 放射照度 100mW/cm2 ブラックパネル温度 63±3℃ 槽内湿度 50±10% 照射時間 288時間[Evaluation Test] Weather resistance and antifouling property of the prepared working samples 1 and 2 and comparative samples 1 and 2 were evaluated by the following methods. The results are shown in Table 1. Weather resistance test method Eye Super UV Tester (Iwasaki Electric Co., Ltd., SUV-W1
Using 3), a weather resistance test was performed under the following conditions. Light source Metal halide lamp Irradiance 100mW / cm 2 Black panel temperature 63 ± 3 ℃ Humidity in the tank 50 ± 10% Irradiation time 288 hours
【0027】耐候性評価 外観状態 : 試験前後の試料外観の変化の有無を目視観
察 色 差 : JIS Z−8722および8730に準
拠した測色色差計(スガ試験機(株)製、SM−4型)を用
い、試験前後の試料の色差を測定した。 光沢残存率:JIS Z−8741に準拠した変角光沢
計(スガ試験機(株)製、UGV−5D型)を用い、試験前後
の試料の60°鏡面光沢を測定し残存率を算出した。Evaluation of weather resistance Appearance condition: Visual observation of changes in the appearance of the sample before and after the test Color difference: Colorimetric colorimeter (SM-4, manufactured by Suga Test Instruments Co., Ltd.) in accordance with JIS Z-8722 and 8730 ), The color difference of the sample before and after the test was measured. Gloss residual ratio: A 60 ° specular gloss of the sample before and after the test was measured using a variable angle gloss meter (manufactured by Suga Test Instruments Co., Ltd., type UGV-5D) in accordance with JIS Z-8741, and the residual ratio was calculated.
【0028】防汚性試験方法 前記調製した実施試料および比較試料のそれぞれに水性
黒色塗料、油性黒色塗料を付着させ、24時間放置後洗
浄し、下記の基準で防汚性を評価した。 ◎:流水で全ての汚れが落ちる。 ○:流水+布で拭き取ることにより全て落ちる。 △:洗剤を用い拭き取ることにより全て落ちる。 ×:汚れが落ちない。An antifouling property test method An aqueous black paint and an oily black paint were adhered to each of the prepared working sample and comparative sample, left to stand for 24 hours and washed, and the antifouling property was evaluated according to the following criteria. A: All dirt is removed by running water. :: All fall off by wiping with running water + cloth. Δ: All fall off by wiping with detergent. ×: Dirt is not removed.
【0029】[0029]
【表1】 [Table 1]
【0030】表1に示したように、耐候性試験後の実施
試料1および2は、比較試料1および2に比較して色差
が小さくかつ光沢残存率が優れ、さらに外観変化もなく
極めて優れた耐候性を示し、また優れた防汚性を有して
いる。また実施試料2は、実施試料1よりもさらに褪色
性が優れている。また、各試料の調製においては、実施
試料は比較試料1に較べて加工性が優れていた。As shown in Table 1, the working samples 1 and 2 after the weather resistance test were smaller than the comparative samples 1 and 2 in that the color difference was small, the gloss retention was excellent, and the appearance was not significantly changed. It shows weather resistance and has excellent antifouling properties. Further, the working sample 2 is more excellent in the fading property than the working sample 1. Further, in the preparation of each sample, the working sample was superior to the comparative sample 1 in workability.
【0031】[0031]
【発明の効果】本発明の合成樹脂着色積層フィルムは極
めて加工性が優れ、着色モールディングの製造に用いる
ことにより、モールディングの成形と同時に着色モール
ディングが得られ、モールディング成形後の塗装工程を
省略することができる。また本発明の合成樹脂着色積層
フィルムを被着した着色モールディングは、耐候性およ
び防汚性が極めて優れている。本発明は、塗装に代わる
モールディングの着色手段に用いる合成樹脂着色積層フ
ィルムおよびそれを被着した耐候性および防汚性の優れ
た着色モールディングを提供するものであり、その産業
的意義は極めて大きい。As described above, the synthetic resin colored laminated film of the present invention is extremely excellent in processability, and when used in the production of a colored molding, a colored molding can be obtained simultaneously with the molding of the molding, and the coating step after the molding is omitted. Can be. The colored molding on which the synthetic resin colored laminated film of the present invention is adhered has extremely excellent weather resistance and antifouling property. The present invention provides a synthetic resin colored laminated film used as a coloring means for molding instead of painting, and a colored molding excellent in weather resistance and antifouling property, which is coated with the laminated film, and its industrial significance is extremely large.
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.6,DB名) B32B 1/00 - 35/00 B60R 13/00 - 13/10──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int. Cl. 6 , DB name) B32B 1/00-35/00 B60R 13/00-13/10
Claims (2)
層および着色した無延伸ポリフッ化ビニル樹脂層からな
る着色合成樹脂層を少なくとも有し、着色合成樹脂層の
1面が無色透明の無延伸ポリフッ化ビニル樹脂層と接合
し、さらに他の面にモールディング成形材料と同種の合
成樹脂フィルム層が接合していることを特徴とするモー
ルディング用合成樹脂着色積層フィルム。1. A colorless and transparent unstretched polyvinyl fluoride resin layer and at least a colored synthetic resin layer comprising a colored unstretched polyvinylfluoride resin layer, and one surface of the colored synthetic resin layer is a colorless and transparent unstretched polyvinylfluoride resin layer. A synthetic resin colored laminated film for molding, which is joined to a vinyl chloride resin layer and further joined to another surface with a synthetic resin film layer of the same kind as the molding material.
層および着色した無延伸ポリフッ化ビニル樹脂層からな
る着色合成樹脂層を少なくとも有し、着色合成樹脂層の
1面が無色透明の無延伸ポリフッ化ビニル樹脂層と接合
し、さらに他の面にモールディング成形材料と同種の合
成樹脂フィルム層が接合している合成樹脂着色積層フィ
ルムが、無色透明の無延伸ポリフッ化ビニル樹脂層を外
側にしてモールディングに被着していることを特徴とす
る着色モールディング。2. A non-stretched non-stretched polyvinyl fluoride resin layer comprising at least a colorless and transparent stretched non-stretched polyvinyl fluoride resin layer and a colored synthetic stretched non-stretched polyvinyl resin layer. The synthetic resin colored laminated film, which is joined to the vinyl chloride resin layer and the other side is joined to the same type of synthetic resin film layer as the molding material, is molded with the colorless and transparent unstretched polyvinyl fluoride resin layer outside. A colored molding characterized by being adhered to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7169437A JP2815137B2 (en) | 1995-07-05 | 1995-07-05 | Synthetic resin laminated film for molding and coloring molding |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7169437A JP2815137B2 (en) | 1995-07-05 | 1995-07-05 | Synthetic resin laminated film for molding and coloring molding |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0920185A JPH0920185A (en) | 1997-01-21 |
JP2815137B2 true JP2815137B2 (en) | 1998-10-27 |
Family
ID=15886594
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7169437A Expired - Lifetime JP2815137B2 (en) | 1995-07-05 | 1995-07-05 | Synthetic resin laminated film for molding and coloring molding |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2815137B2 (en) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6343854U (en) * | 1986-09-05 | 1988-03-24 |
-
1995
- 1995-07-05 JP JP7169437A patent/JP2815137B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH0920185A (en) | 1997-01-21 |
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