JP2663055B2 - Wood fiberboard for molding and method for producing the same - Google Patents

Wood fiberboard for molding and method for producing the same

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Publication number
JP2663055B2
JP2663055B2 JP3062755A JP6275591A JP2663055B2 JP 2663055 B2 JP2663055 B2 JP 2663055B2 JP 3062755 A JP3062755 A JP 3062755A JP 6275591 A JP6275591 A JP 6275591A JP 2663055 B2 JP2663055 B2 JP 2663055B2
Authority
JP
Japan
Prior art keywords
thermoplastic resin
temperature
wood
molding
temperature thermoplastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP3062755A
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Japanese (ja)
Other versions
JPH06155421A (en
Inventor
明 島村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NODA KK
Original Assignee
NODA KK
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Filing date
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Priority to JP3062755A priority Critical patent/JP2663055B2/en
Publication of JPH06155421A publication Critical patent/JPH06155421A/en
Application granted granted Critical
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Anticipated expiration legal-status Critical
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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、木質繊維を主体とし、
1次成型された成型用木質繊維板及びその製造方法に関
する。
BACKGROUND OF THE INVENTION The present invention mainly relates to wood fibers,
The present invention relates to a primary molded wood fiber board for molding and a method for producing the same.

【0002】[0002]

【従来技術】従来より木質繊維を主原料とした、成型用
繊維マット及び繊維板の製造方法として種々の方法が知
られている。例えば、チップを解繊し乾燥した木質繊
維に長繊維、熱硬化性樹脂接着剤または熱硬化性樹脂接
着剤を添加混合したものをフォーミングして圧縮乾燥す
るもの。あるいは、軟質繊維板を成型した後、反毛し
て解繊繊維とした後これに長繊維及び樹脂を混合して堆
積し、ニードルパンチにより長繊維を絡み合わせてマッ
トを形成する方法などが知られている。
2. Description of the Related Art Conventionally, various methods have been known as methods for producing a fiber mat for molding and a fiber board using wood fibers as a main raw material. For example, a mixture obtained by adding and mixing a long fiber, a thermosetting resin adhesive, or a thermosetting resin adhesive to a wood fiber obtained by defibrating and drying a chip, followed by forming and compression drying. Alternatively, a method is known in which a soft fiber plate is molded, then defibrated into fibrillated fibers, mixed with a long fiber and a resin, deposited, and entangled with a needle punch to form a mat. Have been.

【0003】しかしながら、の方法は、木質繊維に混
合した熱硬化性樹脂接着剤の硬化温度に達しない温度で
圧縮乾燥する必要があり、圧縮乾燥条件の調整が困難で
あり、また木質繊維に接着剤を添加する際、スプレーに
より添加するため、スプレーによる接着剤の飛散に伴い
ロスが生じ、均一な添加が難しく、また、接着剤が木質
繊維に含浸してしまうため、過剰量の添加が必要である
などの問題点を有し、の方法は、軟質繊維板の製造及
び反毛の工程が余分に必要となり、解繊した木質繊維へ
の樹脂の添加がと同様に過剰量必要であるなどの問題
を有していた。
However, the above method requires compression drying at a temperature below the curing temperature of the thermosetting resin adhesive mixed with the wood fiber, and it is difficult to adjust the compression drying conditions, and it is difficult to adhere to the wood fiber. When adding the agent, it is added by spraying, so the loss occurs due to the scattering of the adhesive by spraying, it is difficult to add uniformly, and since the adhesive impregnates the wood fiber, an excessive amount of addition is necessary The method requires an extra process of producing a soft fiber board and a wool, and requires an excessive amount of resin to be added to the defibrated wood fiber as well. Had the problem of.

【0004】[0004]

【問題点を解決するための手段】このような現状に鑑
み、本発明者は、取り扱いが容易で成型性に優れた成型
用木質繊維板を提供すべく鋭意研究を重ねた結果、本発
明を完成するに至った。すなわち本発明は、次のような
手段を創成した。すなわち、
In view of such circumstances, the present inventors have conducted intensive studies to provide a wood fiber board for molding which is easy to handle and excellent in moldability. It was completed. That is, the present invention has created the following means. That is,

【0005】木質繊維を熱可塑性樹脂にて結合した成型
用木質繊維板において、木質繊維と、高温熱可塑性樹脂
の周囲に該高温熱可塑性樹脂の溶融温度と異なる低温熱
可塑性樹脂がコーティングされた粉状、顆粒状、チップ
状、フレーク状または繊維状物が混合され、高温熱可塑
性樹脂を溶融することなく、低温熱可塑性樹脂の溶融温
度で熱圧することにより、木質繊維同志を低温熱可塑性
樹脂で三次元網目構造に結合してなる成型用木質繊維
板、および、
[0005] In a wood fiber board for molding in which wood fibers are bonded with a thermoplastic resin, a powder obtained by coating wood fibers and a high temperature thermoplastic resin around a low temperature thermoplastic resin different from the melting temperature of the high temperature thermoplastic resin. , Granules, chips, flakes or fibrous materials are mixed, and without heating the high-temperature thermoplastic resin, by hot pressing at the melting temperature of the low-temperature thermoplastic resin, the wood fibers are mixed with the low-temperature thermoplastic resin. Wood fiberboard for molding formed in a three-dimensional network structure, and

【0006】木材を解繊して得られる木質繊維に、高温
熱可塑性樹脂の周囲に該高温熱可塑性樹脂の溶融温度と
異なる低温熱可塑性樹脂がコーティングされた粉状、顆
粒状、チップ状、フレーク状または繊維状物を混合し、
木質繊維をフォーミングして木質繊維マットとした後、
高温熱可塑性樹脂を溶融することなく、低温熱可塑性樹
脂の溶融温度で熱圧成型し、木質繊維同志を低温熱可塑
性樹脂で三次元網目構造に結合してなる成型用木質繊維
板の製造方法。
A powdery, granular, chip-like or flake material obtained by coating wood fiber obtained by defibrating wood around a high-temperature thermoplastic resin and coating it with a low-temperature thermoplastic resin different from the melting temperature of the high-temperature thermoplastic resin. Shape or fibrous material,
After forming wood fiber into wood fiber mat,
A method for producing a wood fiber board for molding, comprising hot-press molding at the melting temperature of a low-temperature thermoplastic resin without melting the high-temperature thermoplastic resin, and bonding the wood fibers to a three-dimensional network structure with the low-temperature thermoplastic resin.

【0007】[0007]

【作用】本発明の成型用木質繊維板は、上記構成によ
り、低温熱可塑性樹脂の溶融温度以上で1次成型してお
き、2次成型する際、高温熱可塑性樹脂の溶融温度以上
で所望の形状に成型できる。
According to the above construction, the wood fiber board for molding of the present invention is firstly molded at a temperature not lower than the melting temperature of the low-temperature thermoplastic resin, and at the time of secondary molding, it is desired to have a desired temperature above the melting temperature of the high-temperature thermoplastic resin. Can be molded into a shape.

【0008】[0008]

【構成】本発明の成型用木質繊維板は、木質繊維とし
て、例えば、ラワン、カポール、栗、ポプラ等の広葉樹
材及び松、杉、 等の針葉樹材をチップにした後、常法
に従い解繊することによって得られた木質繊維を用いる
ことができる。
[Structure] The wood fiber board for molding of the present invention is obtained by cutting, as wood fibers, hardwood such as Rawan, Kapole, chestnut and poplar, and softwood such as pine, cedar, etc. into chips, followed by defibration according to a conventional method. Wood fibers obtained by the above method can be used.

【0009】また、これら木質繊維に添加する熱可塑性
樹脂としては、ポリエチレン、ポリプロピレン、ポリス
チレン、ポリ塩化ビニル、ナイロン、ポリエチレンテレ
フタレート、ポリアクリル酸、ポリアクリロニトリル等
が挙げられる。本願発明では、これら熱可塑性樹脂か
ら、溶融温度の高い高温熱可塑性樹脂と該高温熱可塑性
樹脂より低い溶融温度をもつ低温熱可塑性樹脂との2種
類を選択し組み合わせて用いる。これら熱可塑性樹脂
は、粉状、顆粒状、チップ状、フレーク状または繊維状
の形態で木質繊維に添加する。このような形態で添加す
ることにより、木質繊維と均一に混合することができ、
しかも木質繊維内に含浸されることがなく樹脂のロスが
減少させることができる。特に本発明では、粉状、顆粒
状、チップ状、フレーク状または繊維状の高温熱可塑性
樹脂の周囲を、各々低温熱可塑性樹脂でコーティングし
た形態で添加混合する。コーティングした形態で添加す
るので、高温熱可塑性樹脂と低温熱可塑性樹脂が各々均
等に混合することができる。また、その添加量は、木質
繊維に対し10〜30重量%の割合で熱可塑性樹脂を添
加する。
The thermoplastic resin to be added to these wood fibers includes polyethylene, polypropylene, polystyrene, polyvinyl chloride, nylon, polyethylene terephthalate, polyacrylic acid, polyacrylonitrile and the like. In the present invention, two types of thermoplastic resins, a high-temperature thermoplastic resin having a high melting temperature and a low-temperature thermoplastic resin having a melting temperature lower than the high-temperature thermoplastic resin, are selected and used in combination. These thermoplastic resins are added to the wood fibers in the form of powder, granules, chips, flakes or fibers. By adding in such a form, it can be uniformly mixed with the wood fiber,
In addition, the loss of resin can be reduced without impregnation into the wood fiber. In particular, in the present invention, the periphery of a powdery, granular, chip-like, flake-like or fibrous high-temperature thermoplastic resin is added and mixed in a form coated with a low-temperature thermoplastic resin, respectively. Since it is added in a coated form, the high-temperature thermoplastic resin and the low-temperature thermoplastic resin can be uniformly mixed with each other. The amount of the thermoplastic resin added is 10 to 30% by weight with respect to the wood fiber.

【0010】本発明の成型用木質繊維板の構成は、木質
繊維層1層または、木質繊維層の厚さ方向の内部に少な
くとも1層以上の金属箔層を配した複合板として構成さ
れる。この際用いる金属箔としては、鉄、アルミニウ
ム、ステンレス、銅等の金属で厚さ20〜100μの範
囲のもので必要に応じメッキ処理等の防錆び処理を施し
たものを用いることができる。また、金属箔層として、
金属箔に微小孔を設けたもの又は金属糸を用いて織った
金属織布を用いることができる。このように金属箔層を
配することにより、成型木質繊維板の曲げ強度を向上す
ることができ、2次成型により目的とする形状に加熱圧
締成型する際の取り扱い中に割れが生ずることもなく、
さらに大きな寸法の成型用木質繊維板を製造することが
できる。また、微小孔等により一部的な通気性を有する
金属箔を用いることにより、木質繊維中に残存する水分
が加熱圧締の際に外に逃げようとする動きを、金属箔が
規制することにより生ずるパンクを防止することができ
る。
The structure of the wood fiber board for molding according to the present invention is constituted as one wood fiber layer or as a composite board having at least one metal foil layer disposed inside the wood fiber layer in the thickness direction. The metal foil used at this time may be a metal such as iron, aluminum, stainless steel, or copper having a thickness in the range of 20 to 100 μm and subjected to rust prevention treatment such as plating if necessary. Also, as a metal foil layer,
A metal foil provided with fine holes or a metal woven fabric woven using a metal thread can be used. By arranging the metal foil layer in this manner, the bending strength of the molded wood fiber board can be improved, and cracks may be generated during handling when heating and pressing to a desired shape by secondary molding. Not
It is possible to manufacture a wood fiber board for molding of a larger size. In addition, by using a metal foil having partial air permeability due to micropores or the like, the metal foil regulates the movement of water remaining in the wood fiber to escape to the outside during heating and pressing. Can be prevented from puncturing.

【0011】本発明に従い成型用木質繊維板を製造する
には、針葉樹または広葉樹材のチップを蒸煮することに
より脱脂・軟化処理し、さらに解繊装置により解繊する
ことにより木質繊維を得る。この木質繊維は長さ1〜3
0mm、直径2〜300μ程度のものが大半を占め、導
管及び仮導管又は細胞が束になったような形をしてお
り、繊維外周部の細胞壁は引き裂かれたり割れ目を生じ
たりしているものが多いため湿気や水分を多く吸収す
る。得られた木質繊維は乾燥装置により乾燥する。乾燥
した木質繊維にブレンダー装置内で高温熱可塑性樹脂の
周囲に低温熱可塑性樹脂がコーティングされた粉状、顆
粒状、チップ状、フレーク状または繊維状物を添加混合
する。次いで木質繊維を熱風ダクト中に投入し、風送し
ながら乾燥する。この際の風送速度は約15〜20m/
秒であるが、木質繊維の比重、送り量、前後の工程の処
理能力などにより広範囲に調整される。この熱風による
風送で木質繊維は6〜15%水分量まで乾燥される。
In order to produce a wood fiber board for molding in accordance with the present invention, wood fibers are obtained by steaming chips of softwood or hardwood to degreasing and softening, and then defibrating by a defibrating device. This wood fiber has a length of 1-3
Most of them have a diameter of about 0 mm and a diameter of about 2 to 300 µm, and have a shape like a bundle of conduits and temporary conduits or cells, and the cell wall around the fiber is torn or cracked It absorbs a lot of moisture and moisture because of its high content. The obtained wood fiber is dried by a drying device. A powdery, granular, chip-like, flake-like or fibrous material in which a low-temperature thermoplastic resin is coated around a high-temperature thermoplastic resin in a blender is added to the dried wood fiber in a blender. Next, the wood fibers are put into a hot air duct and dried while blowing. The blowing speed at this time is about 15 to 20 m /
Although it is seconds, it can be adjusted over a wide range depending on the specific gravity of the wood fiber, the feed amount, the processing capacity of the preceding and following processes, and the like. The wood fibers are dried to a water content of 6 to 15% by the blowing by the hot air.

【0012】風送された木質繊維はフォーミング装置に
搬送され、コンベアー上に落下させ、木質繊維及び熱可
塑性樹脂の混合物を堆積した後、仮圧締することにより
木質繊維マットを形成し、この木質繊維マットを適宜寸
法に切断した後、低温熱可塑性樹脂の溶融温度より高
く、高温熱可塑性樹脂が溶融しない温度で加熱圧締する
ことにより成型用木質繊維板が得られる。
The blown wood fibers are conveyed to a forming device and dropped on a conveyor, where a mixture of wood fibers and a thermoplastic resin is deposited, and then temporarily pressed to form a wood fiber mat. After cutting the fiber mat into appropriate dimensions, the wood fiber board for molding can be obtained by heating and pressing at a temperature higher than the melting temperature of the low-temperature thermoplastic resin and not melting the high-temperature thermoplastic resin.

【0013】金属箔層を配する場合は、金属箔の表裏に
仮圧締により得られた木質繊維マットを積層し、以下同
様の方法により圧締することにより得られる。木質繊維
マットと金属箔を積層する際に、金属箔の表裏面に木質
繊維に添加した高温熱可塑性樹脂と同様の接着剤を塗布
したものを用いることにより成型用木質繊維板の接着強
度をさらに向上させることができる。
When a metal foil layer is provided, a wood fiber mat obtained by temporary pressing is laminated on the front and back surfaces of the metal foil, and then pressed by a similar method. When laminating the wood fiber mat and the metal foil, the adhesive strength of the wood fiber board for molding is further increased by using the same adhesive as the high-temperature thermoplastic resin added to the wood fiber on the front and back surfaces of the metal foil. Can be improved.

【0014】[0014]

【効果】本発明の成型用木質繊維板は、高温熱可塑性樹
脂と、低温熱可塑性樹脂とを選択し組み合わせて用いる
ため、低温熱可塑性樹脂の溶融温度以上の温度で圧締す
なわち1次成型することにより、成型用木質板を得るこ
とができる。たとえ、この際の加熱により高温熱可塑性
樹脂の一部が溶融しても熱可塑性樹脂であるため、その
後本発明の成型用木質繊維板を金型により加熱圧締し所
望の形状に2次成型する際にもなんら悪影響を与えるこ
とがなく、一次成型の温度管理が容易に行なうことがで
きる。さらに、該熱可塑性樹脂を粉状、顆粒状、チップ
状、フレーク状または繊維状物の形態で木質繊維に添加
するため、均一に混合することができる。特に本発明で
は高温熱可塑性樹脂の周囲を低温熱可塑性樹脂でコーテ
ィングした粉状顆粒状、チップ状、フレーク状または繊
維状の形態で添加することにより各々の熱可塑性樹脂の
分散混合も均一に行なうことができる。また添加する樹
脂量も従来のスプレー法等に比べロスが少ないため、添
加樹脂量の過剰分を減少させることができる。
The wood fiber board for molding of the present invention is selected from a combination of a high-temperature thermoplastic resin and a low-temperature thermoplastic resin and used in combination. Thereby, a wooden board for molding can be obtained. Even if a part of the high-temperature thermoplastic resin is melted by the heating at this time, it is still a thermoplastic resin. Then, the wood fiber board for molding of the present invention is heated and pressed by a mold and then subjected to secondary molding into a desired shape. In this case, the temperature of the primary molding can be easily controlled without any adverse effect. Furthermore, since the thermoplastic resin is added to the wood fibers in the form of powder, granules, chips, flakes or fibrous materials, they can be uniformly mixed. In particular, in the present invention, the dispersion and mixing of each thermoplastic resin are also uniformly performed by adding in the form of powdery granules, chips, flakes or fibers in which the periphery of the high-temperature thermoplastic resin is coated with the low-temperature thermoplastic resin. be able to. Further, since the loss of the added resin is smaller than that of the conventional spray method, the excess amount of the added resin can be reduced.

【0015】[0015]

【実施例】以下、実施例により本発明をさらに詳細に説
明する。
The present invention will be described in more detail with reference to the following examples.

【0016】実施例1 まづ、木質繊維マットの製造の実施例について述べる。
すなわち、ラジアータパインのチップを160℃、7K
g/cmで5分間煮沸して脱脂、軟化処理を行なっ
た。このチップをデファイブレーター式リファイナーで
解繊し、得られた木質繊維を乾燥した。この木質繊維を
ブレンダーに投入し、該ブレンダー内において、ポリプ
ロピレン樹脂の周囲にポリエチレン樹脂でコーティング
された熱可塑性樹脂を木質繊維量に対して10%のポリ
エチレン樹脂(溶融温度;130℃)、18%ポリプロ
ピレン樹脂(溶融温度180℃)の割合で添加混合した
後、フォーミング装置に搬送した。搬送された木質繊維
をスクリーンコンベアー上に落下させ堆積させた。この
木質繊維を仮圧締した後適当な長さに切断し、ホットプ
レスに挿入して140℃で熱圧し成型用木質繊維板を得
た。
Example 1 First, an example of manufacturing a wood fiber mat will be described.
That is, the radiator pine chips were heated at 160 ° C and 7K.
The mixture was boiled at g / cm 2 for 5 minutes to perform degreasing and softening treatment. The chips were defibrated by a defibrator type refiner, and the obtained wood fibers were dried. The wood fiber is put into a blender, and in the blender, a thermoplastic resin coated with a polyethylene resin around a polypropylene resin is mixed with a 10% polyethylene resin (melting temperature; 130 ° C.) based on the amount of the wood fiber, 18% After being added and mixed at a ratio of a polypropylene resin (melting temperature: 180 ° C.), it was conveyed to a forming device. The conveyed wood fibers were dropped and deposited on a screen conveyor. The wood fiber was temporarily pressed, cut into an appropriate length, inserted into a hot press, and hot-pressed at 140 ° C. to obtain a wood fiber board for molding.

【0017】実施例2 実施例1で仮圧締により得た木質繊維マットと45μm
厚の鉄箔とを、上から木質繊維マット/鉄箔/木質繊維
マットの順で順次積層した後、ホットプレスに挿入して
150℃にて5分間熱圧成形し厚さ13mm、比重0.
7の複合板を得た。
Example 2 The wood fiber mat obtained in Example 1 by pre-pressing and 45 μm
A thick iron foil is sequentially laminated from the top in the order of wood fiber mat / iron foil / wood fiber mat, then inserted into a hot press and hot-pressed at 150 ° C. for 5 minutes to a thickness of 13 mm and a specific gravity of 0.1 mm.
7 was obtained.

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 木質繊維を熱可塑性樹脂にて結合した成
型用木質繊維板において、木質繊維と、高温熱可塑性樹
脂の周囲に該高温熱可塑性樹脂の溶融温度と異なる低温
熱可塑性樹脂がコーティングされた粉状、顆粒状、チッ
プ状、フレーク状または繊維状物が混合され、高温熱可
塑性樹脂を溶融することなく、低温熱可塑性樹脂の溶融
温度で熱圧することにより、木質繊維同志を低温熱可塑
性樹脂で三次元網目構造に結合してなることを特徴とす
る成型用木質繊維板。
1. A wood fiber board for molding in which wood fibers are bonded with a thermoplastic resin, wherein the wood fibers and the high temperature thermoplastic resin are coated with a low temperature thermoplastic resin different from the melting temperature of the high temperature thermoplastic resin. Powdered, granular, chip-like, flake-like or fibrous materials are mixed and hot-pressed at the melting temperature of the low-temperature thermoplastic resin without melting the high-temperature thermoplastic resin. A wood fiber board for molding characterized by being bonded to a three-dimensional network structure with a resin.
【請求項2】 木材を解繊して得られる木質繊維に、高
温熱可塑性樹脂の周囲に該高温熱可塑性樹脂の溶融温度
と異なる低温熱可塑性樹脂がコーティングされた粉状、
顆粒状、チップ状、フレーク状または繊維状物を混合
し、木質繊維をフォーミングして木質繊維マットとした
後、高温熱可塑性樹脂を溶融することなく、低温熱可塑
性樹脂の溶融温度で熱圧成型し、木質繊維同志を低温熱
可塑性樹脂で三次元網目構造に結合してなることを特徴
とする成型用木質繊維板の製造方法。
2. A powdery form in which wood fibers obtained by defibrating wood are coated around a high-temperature thermoplastic resin with a low-temperature thermoplastic resin different from the melting temperature of the high-temperature thermoplastic resin.
After mixing granules, chips, flakes or fibrous materials, forming wood fibers into a wood fiber mat, then hot-press molding at the melting temperature of the low-temperature thermoplastic resin without melting the high-temperature thermoplastic resin And a method of manufacturing a wood fiber board for molding, wherein the wood fibers are bonded to each other in a three-dimensional network structure with a low-temperature thermoplastic resin.
JP3062755A 1991-01-10 1991-01-10 Wood fiberboard for molding and method for producing the same Expired - Lifetime JP2663055B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3062755A JP2663055B2 (en) 1991-01-10 1991-01-10 Wood fiberboard for molding and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3062755A JP2663055B2 (en) 1991-01-10 1991-01-10 Wood fiberboard for molding and method for producing the same

Publications (2)

Publication Number Publication Date
JPH06155421A JPH06155421A (en) 1994-06-03
JP2663055B2 true JP2663055B2 (en) 1997-10-15

Family

ID=13209539

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3062755A Expired - Lifetime JP2663055B2 (en) 1991-01-10 1991-01-10 Wood fiberboard for molding and method for producing the same

Country Status (1)

Country Link
JP (1) JP2663055B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2797922B2 (en) 1993-10-08 1998-09-17 三井木材工業株式会社 Wood-based thermoplastic molding plate

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5829883B2 (en) * 2011-03-31 2015-12-09 永大産業株式会社 Wood board manufacturing method
JP6021071B2 (en) * 2013-05-10 2016-11-02 パナソニックIpマネジメント株式会社 Manufacturing method of wood fiberboard

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61181610A (en) * 1985-02-08 1986-08-14 Noda Plywood Mfg Co Ltd Manufacture of mat to be molded

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2797922B2 (en) 1993-10-08 1998-09-17 三井木材工業株式会社 Wood-based thermoplastic molding plate

Also Published As

Publication number Publication date
JPH06155421A (en) 1994-06-03

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