JP2593840B2 - Pet toilet floor - Google Patents

Pet toilet floor

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Publication number
JP2593840B2
JP2593840B2 JP6240692A JP24069294A JP2593840B2 JP 2593840 B2 JP2593840 B2 JP 2593840B2 JP 6240692 A JP6240692 A JP 6240692A JP 24069294 A JP24069294 A JP 24069294A JP 2593840 B2 JP2593840 B2 JP 2593840B2
Authority
JP
Japan
Prior art keywords
silica gel
odor
acid
organic acid
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP6240692A
Other languages
Japanese (ja)
Other versions
JPH0870725A (en
Inventor
慶一 澤田
Original Assignee
豊田化工株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 豊田化工株式会社 filed Critical 豊田化工株式会社
Priority to JP6240692A priority Critical patent/JP2593840B2/en
Publication of JPH0870725A publication Critical patent/JPH0870725A/en
Application granted granted Critical
Publication of JP2593840B2 publication Critical patent/JP2593840B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Silicon Compounds (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】 本発明は犬、猫等の室内で飼育
されるペットの糞尿を受けるために使用されるペット用
便床に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pet toilet bed used to receive manure of pets kept indoors such as dogs and cats.

【0002】[0002]

【従来の技術】 従来はこの種のペット用便床としては
ゼオライト系の吸着脱臭剤あるいはベントナイト系の吸
着脱臭剤が使用されていた。
2. Description of the Related Art Conventionally, a zeolite-based adsorptive deodorant or a bentonite-based adsorptive deodorant has been used as a pet toilet bed of this type.

【0003】[0003]

【発明が解決しようとする課題】 上記ゼオライト系の
吸着脱臭剤は糞尿の水分の吸収力が小さいために排便時
の臭気が問題となっており、また上記ベントナイト系の
吸着脱臭剤は糞尿を固形化して臭気を吸着封鎖するが、
そのためには吸着脱臭剤が多量に必要であり、したがっ
て不経済であるし、また使用後の吸着脱臭剤を廃棄した
場合には環境汚染の問題もある。
The zeolite-based adsorptive deodorant has a problem of odor at the time of defecation due to the low water absorption capacity of manure, and the bentonite-based adsorptive deodorant forms solids in manure. And absorbs and blocks the odor,
For this purpose, a large amount of the adsorbent deodorant is required, which is uneconomical, and there is a problem of environmental pollution when the used adsorbent deodorant is discarded.

【0004】[0004]

【課題を解決するための手段】 本発明は有機酸含有シ
リカゲル(1A)3〜 10重量%と、銀イオン含有シリカゲ
ル(1B)1〜5重量%と、残余は細孔径 20〜200Åの
可逆的吸湿性を有するシリカゲルとの混合物(1) とから
なるペット用便床(3) を提供するものである。
The present invention relates to an organic acid-containing silica gel (1A) having a content of 3 to 10% by weight, a silver ion-containing silica gel (1B) having a content of 1 to 5% by weight, and a balance having a pore diameter of 20 to 200 mm.
There is provided a mixture pet service floor consisting (1) and (3) the shea Rikageru with reversible hygroscopic.

【0005】 本発明で使用されるシリカゲルは通常細
孔径が20〜200Å程度、粒径が0.02〜10mm程
度の物であり、該細孔径は上記範囲でなるべく広い分布
を有することが望ましい。上記シリカゲルには有機酸含
有シリカゲルと銀イオン含有シリカゲルが混合される。
該有機酸含有シリカゲルとは例えば蓚酸、マロン酸、コ
ハク酸、マイレン酸、フマル酸、グリコール酸、乳酸、
β−オキシ酸、リンゴ酸、酒石酸、クエン酸、タンニン
酸等の望ましくは揮発性の低い有機酸を添加混合したシ
リカゲルであり、銀イオン含有シリカゲルとは塩化銀、
硝酸銀等の無機銀塩、酢酸銀、プロピオン酸銀、ステア
リン酸銀等の有機銀塩等の銀イオンを放出することの出
来る化合物を添加混合したシリカゲルであり、該有機酸
含有シリカゲルは例えば赤、青二色に着色し、該銀イオ
ン含有シリカゲルは例えば緑色に着色しておくことが望
ましい。このようにシリカゲルを着色しておけばおよそ
の配合比率が目視で判別出来るしまた糞尿による着色を
目立たなくさせる利点がある。しかし上記着色は本発明
を限定するものではない。上記シリカゲル混合物中有機
酸含有シリカゲルは通常3〜10重量%、銀イオン含有
シリカゲルは通常1〜5重量%が含有される。
The silica gel used in the present invention generally has a pore size of about 20 to 200 ° and a particle size of about 0.02 to 10 mm, and the pore size desirably has a distribution as wide as possible within the above range. Silica gel containing an organic acid and silica gel containing silver ions are mixed with the above silica gel.
The organic acid-containing silica gel is, for example, oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid, glycolic acid, lactic acid,
β-oxyacid, malic acid, tartaric acid, citric acid, tannic acid and the like is preferably a silica gel mixed with a low volatile organic acid, and silver ion-containing silica gel is silver chloride,
An inorganic silver salt such as silver nitrate, silver acetate, silver propionate, a silica gel mixed with a compound capable of releasing silver ions such as an organic silver salt such as silver stearate, and the organic acid-containing silica gel is, for example, red, It is desirable that the silica gel be colored in two blue colors and that the silica gel containing silver ions be colored, for example, green. If the silica gel is colored in this way, the approximate blending ratio can be visually discriminated, and there is an advantage that coloring due to manure is inconspicuous. However, the coloring does not limit the present invention. In the above silica gel mixture , the organic acid-containing silica gel usually contains 3 to 10% by weight, and the silver ion-containing silica gel usually contains 1 to 5% by weight.

【0006】[0006]

【作用】 本発明の便床に使用される細孔径20〜20
0Åのシリカゲルは高湿時には水分を吸着し、低湿時に
は水分を放出すると云う可逆性を有する。そこで本発明
の便床は糞尿を受けると速やかに臭気成分を含む糞尿の
水分を吸収して臭気を吸着除去し、低湿時には臭気を除
去された水分のみを放出する。したがって本発明の便床
に使用される可逆性シリカゲルは吸着飽和に達するまで
の時間が長く、その結果長い寿命を有するものであり、
その上再生することも出来る。また上記便床に含まれる
有機酸含有シリカゲルは、上記可逆性シリカゲル では吸
着除去されにくい糞尿の臭気成分の一つであるアンモニ
アを吸着中和して無臭化させる。更に銀イオン含有シリ
カゲルは便床に雑菌が繁殖することを抑制して悪臭 即ち
腐敗臭の発生を防止し、可逆性シリカゲルおよび有機酸
含有シリカゲル が吸着飽和に達する時間を更に延長
る。またシリカゲルの主成分はケイ酸であるから土に同
化し易く、使用後廃棄しても環境汚染のおそれはない。
The pore size of the stool bed of the present invention is 20 to 20.
The silica gel of 0 ° has reversibility of adsorbing moisture at high humidity and releasing moisture at low humidity. Therefore feces floor of the present invention absorbs moisture manure to adsorb and remove odors comprising rapidly odor components upon receiving the manure, the low-humidity removing odor
Releases only the water that has been removed . Therefore, the reversible silica gel used in the toilet bed of the present invention has a long time to reach adsorption saturation, and as a result, has a long life,
It can also be played back. The organic acid-containing silica gel contained in the stool bed is absorbed by the reversible silica gel.
Ammonia is one of odor components of hard to wear removed manure Ru is deodorized adsorbed neutralized. Further silver ion-containing silica gel malodor that is, suppress the bacteria are bred Bin'yuka
Prevents the generation of putrefaction odor, reversible silica gel and organic acid
Further extend the time for the containing silica gel to reach adsorption saturation . Further, silica gel is mainly composed of silicic acid, so that it is easily assimilated into soil, and there is no risk of environmental pollution even after disposal after use.

【0007】 以下に本発明の便床に使用されるシリカ
ゲルの性能テストの結果を示す。該性能テストは平均細
孔径60Å、平均粒径2〜5mmのシリカゲルを使用して
行なわれた。 1.吸放水テスト シリカゲルを水に浸漬して飽和状態とし、水切り後鉄板
上に所定の厚さに該シリカゲルを敷き、天日および室内
に交互に放置した時の該シリカゲルの重量変化を測定し
て水分放出状態を観察した。その結果を図1に示す。図
中グラフ1はシリカゲルを厚さ7mmに敷いた場合、グラ
フ2はシリカゲルを厚さ17mmに敷いた場合、グラフ3
はシリカゲルを厚さ30mmに敷いた場合である。図1に
明らかなように低湿下ではシリカゲルは水分を速やかに
放出して吸水能が再生される。 2.消臭テスト 1lのフラスコにシリカゲル、シリカゲル混合物、故紙
粉末、ベントナイト、木粉各0.1ml投入し、更に表1
に示すブランク濃度になるように各臭気成分を含有する
溶液または気体を注入し、30分後にフラスコ内の残留
臭気濃度を北川式検知管で測定して臭気除去率(%)を
算出する。その結果は表1に示される。
The results of the performance test of the silica gel used for the toilet floor of the present invention are shown below. The performance test was performed using silica gel having an average pore size of 60 ° and an average particle size of 2 to 5 mm. 1. Water absorption / desorption test Silica gel is immersed in water to make it saturated, and after draining, laying the silica gel to a predetermined thickness on an iron plate and measuring the weight change of the silica gel when left alternately in the sun and indoors to determine the water content The release state was observed. The result is shown in FIG. In the figure, graph 1 shows a case where silica gel is spread to a thickness of 7 mm, and graph 2 shows a case where silica gel is spread to a thickness of 17 mm.
Is a case where silica gel is spread to a thickness of 30 mm. As is clear from FIG. 1, under low humidity, silica gel rapidly releases water and the water absorbing ability is regenerated. 2. 0.1 ml each of silica gel, silica gel mixture, waste paper powder, bentonite, and wood flour were charged into a 1-liter flask.
A solution or gas containing each of the odor components is injected so as to have a blank concentration as shown in (1), and after 30 minutes, the concentration of the remaining odor in the flask is measured with a Kitagawa type detector tube to calculate an odor removal rate (%). The results are shown in Table 1.

【0008】[0008]

【表1】 表1に明らかなように、シリカゲル混合物は臭気成分の
種類に関わらず他の試料よりも優れた消臭能を有してい
る。
[Table 1] As is evident in Table 1, the silica gel mixture has better deodorizing ability than other samples regardless of the type of odor component.

【0009】[0009]

【実施例】〔実施例1〕 図2に示すようにシリカゲル混合物(1) は容器(2) 内に
充填されて便床(3) を形成する。該シリカゲル混合物
(1) は細孔径範囲20〜200Å、粒径範囲0.02〜
10mmであり、6重量%の有機酸含有シリカゲル(1A)と
3重量%の銀イオン含有シリカゲル(1B)とを含有し、該
有機酸含有シリカゲル(1A)は赤色および青色に着色さ
れ、該銀イオン含有シリカゲル(1B)は緑色に着色されて
いる。上記容器(2) は縦横50×50cm、深さ25cmの
寸法とされ上記シリカゲル混合物(1) は該容器(2) に約
2kg入れられる。
[Example 1] Silica gel as shown in FIG.mixture(1) in container (2)
Filled to form the stool bed (3). The silica gelmixture
(1) has a pore diameter range of 20 to 200 ° and a particle size range of 0.02 to
10mm, 6% by weight silica gel containing organic acid (1A)
3% by weight of silver ion-containing silica gel (1B).
Organic acid-containing silica gel (1A) is colored red and blue
The silver ion-containing silica gel (1B) is colored green.
I have. The container (2) is 50 × 50 cm in length and width and 25 cm in depth.
Dimensions and above silica gelmixture(1) is placed in the container (2).
2 kg can be inserted.

【0010】 上記便床(3) を一匹の成猫を飼っている
室内に置いたところ約25〜30日後に始めて室内に臭
気の発生が感知された。比較として有機酸含有シリカゲ
ル(1A)と銀イオン含有シリカゲル(1B)とを含有しないシ
リカゲルを入れた便床を使用した場合には、15日後に
臭気の発生が感知された。またベントナイト系の吸着脱
臭剤を入れた便床を使用した場合には、3日後に臭気の
発生が感知された。したがって本発明の便床(3) は有機
酸含有シリカゲル(1A)や銀イオン含有シリカゲル(1B)含
まないシリカゲルに比べて約1/2の使用量ですみ、ま
たベントナイト系吸着脱臭剤と比べて約1/9の使用量
ですむ。
When the stool bed (3) was placed in a room where one adult cat was kept, the generation of odor was detected in the room only after about 25 to 30 days. As a comparison, when a toilet bed containing silica gel containing neither the organic acid-containing silica gel (1A) nor the silver ion-containing silica gel (1B) was used, the generation of odor was detected after 15 days. When a stool bed containing a bentonite-based adsorptive deodorant was used, the generation of odor was detected after 3 days. Therefore, the toilet bed (3) of the present invention requires only about half the amount of silica gel containing no organic acid-containing silica gel (1A) or silver ion-containing silica gel (1B). Only about 1/9 of the amount used.

【0011】 〔実施例2〕 図3に示すようにゲージ(4) の床(5) は縦横25×25
cm、深さ2cmであって実施例1で使用したシリカゲル
合物(1) 約100gを該床(5) 上に均一に敷いて便床を
構成する。該ゲージ(4) にて小鳥3匹を飼育した所、約
6〜7日後に始めて臭気の発生が感知され、またハムス
ター2匹を飼育した所、約4〜5日後に始めて臭気の発
生が感知された。比較としてベントナイト系吸着脱臭剤
を用いた場合には小鳥、ハムスター共に即日臭気の発生
が感知された。
[0011] Example 2 bed (5) of the gauge (4) As shown in FIG. 3 the aspect 25 × 25
cm, depth 2 cm, mixed with silica gel used in Example 1.
About 100 g of the compound (1) is evenly spread on the floor (5) to form a toilet bed. Occurrence of odor is sensed only after about 6 to 7 days when three birds are bred by the gauge (4), and odor is sensed only after about 4 to 5 days when two hamsters are bred. Was done. As a comparison, when a bentonite-type adsorbent deodorant was used, generation of odor was detected on the same day in both small birds and hamsters.

【0012】[0012]

【発明の効果】したがって本発明においては、ペットの
糞尿から発生する如何なる種類の 臭気も長期間にわたっ
吸着除去することが出来るしシリカゲルの使用量も
らすことが出来便床の雑菌繁殖を防止し衛生的にも好
ましいものであり また防虫効果も得られる。
Therefore, in the present invention, any kind of odor generated from pet manure can be adsorbed and removed over a long period of time and the amount of silica gel used can be reduced.
It can be Las, good also to hygienic to prevent bacteria breeding of flights floor
It is good and also has an insect repellent effect.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 シリカゲルの吸放水を示すグラフFIG. 1 is a graph showing water absorption and release of silica gel.

【図2】 実施例1の斜視図FIG. 2 is a perspective view of the first embodiment.

【図3】 実施例2の斜視図FIG. 3 is a perspective view of a second embodiment.

【符号の説明】[Explanation of symbols]

1 シリカゲル混合物 1A 有機酸含有シリカゲル 1B 銀イオン含有シリカゲル 2 容器 3 便床 5 ゲージの床1 Silica gel mixture 1A Silica gel containing organic acid 1B Silica gel containing silver ion 2 Container 3 Toilet floor 5 Gauge floor

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】有機酸含有シリカゲル3〜10重量%と、
銀イオン含有シリカゲル1〜5重量%と、残余は細孔径
20〜200Åの可逆的吸湿性を有する リカゲルとの
混合物からなることを特徴とするペット用便床
1. An organic acid-containing silica gel having 3 to 10% by weight,
1-5% by weight of silver ion-containing silica gel , the rest is pore size
The sheet Rikageru with reversible hygroscopic 20~200Å
Pet toilet floor comprising a mixture
JP6240692A 1994-09-07 1994-09-07 Pet toilet floor Expired - Lifetime JP2593840B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6240692A JP2593840B2 (en) 1994-09-07 1994-09-07 Pet toilet floor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6240692A JP2593840B2 (en) 1994-09-07 1994-09-07 Pet toilet floor

Publications (2)

Publication Number Publication Date
JPH0870725A JPH0870725A (en) 1996-03-19
JP2593840B2 true JP2593840B2 (en) 1997-03-26

Family

ID=17063289

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6240692A Expired - Lifetime JP2593840B2 (en) 1994-09-07 1994-09-07 Pet toilet floor

Country Status (1)

Country Link
JP (1) JP2593840B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220149128A (en) 2021-04-30 2022-11-08 서울대학교산학협력단 origami type scaffold
KR20220149131A (en) 2021-04-30 2022-11-08 서울대학교산학협력단 origami type scaffold with locking function

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6543385B2 (en) 2000-12-07 2003-04-08 Nestec, Ltd. Animal litter composition containing silica gel and methods therefor
DK1319332T3 (en) * 2001-12-15 2005-05-30 Arno Knof Consulting Gmbh Cat litter
US7343874B2 (en) 2002-08-07 2008-03-18 The Clorox Company Silica gel based animal litter

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0445849A (en) * 1990-06-11 1992-02-14 Matsushita Electric Ind Co Ltd Deodorant
JP3142666B2 (en) * 1992-11-10 2001-03-07 松下電器産業株式会社 Animal cage

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220149128A (en) 2021-04-30 2022-11-08 서울대학교산학협력단 origami type scaffold
KR20220149131A (en) 2021-04-30 2022-11-08 서울대학교산학협력단 origami type scaffold with locking function

Also Published As

Publication number Publication date
JPH0870725A (en) 1996-03-19

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Effective date: 19961008