JP2581785B2 - Crystallized glass building material and method for producing the same - Google Patents
Crystallized glass building material and method for producing the sameInfo
- Publication number
- JP2581785B2 JP2581785B2 JP63305919A JP30591988A JP2581785B2 JP 2581785 B2 JP2581785 B2 JP 2581785B2 JP 63305919 A JP63305919 A JP 63305919A JP 30591988 A JP30591988 A JP 30591988A JP 2581785 B2 JP2581785 B2 JP 2581785B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- building material
- crystallized glass
- mica
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/16—Halogen containing crystalline phase
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は、通常の金属加工用工具により切削加工が容
易にできる結晶化ガラス建材およびその製造方法に関す
るものである。Description: TECHNICAL FIELD The present invention relates to a crystallized glass building material that can be easily cut by a normal metal working tool, and a method for producing the same.
（従来の技術） 従来、建築用の建材として好適な結晶化ガラスとし
て、特開昭60−27622号公報において、集積法、ロール
アウト法等で作製された結晶化ガラスが開示されてい
る。(Prior Art) Conventionally, as a crystallized glass suitable as a building material for building, JP-A-60-27622 discloses a crystallized glass produced by an integration method, a roll-out method, or the like.
一方、切削加工性の良好なガラスセラミックスとし
て、特公昭54−34775号公報において、マトリックス中
に弗素金雲母固溶体の結晶を含有させたものを、所定の
形状に成形したガラスを再熱処理することで結晶化をさ
せガラスセラミックスを得る技術が開示されている。On the other hand, as glass ceramics having good machinability, Japanese Patent Publication No. 54-34775 discloses that a glass containing a crystal of a fluorophlogopite mica solid solution in a matrix is formed into a predetermined shape and then reheat-treated. There is disclosed a technique for obtaining glass ceramics by crystallization.
（発明が解決しようとする課題） しかしながら、特開昭60−27622号公報で開示された
結晶化ガラスでは、結晶相がウォラストナイト、フォル
ステライトを主とするものであるため、建材として使用
する場合、建築現場等での寸法変更などに際して切削加
工が非常に難しい問題があった。(Problems to be Solved by the Invention) However, in the crystallized glass disclosed in JP-A-60-27622, the crystal phase is mainly wollastonite and forsterite, so that it is used as a building material. In such a case, there has been a problem that cutting is very difficult when dimension is changed at a construction site or the like.
また、特公昭54−34775号公報で開示されたガラスセ
ラミックスでは、切削加工は容易にできるものの、所定
の形状にガラスを形成した後、再加熱処理を実施して雲
母固溶体の結晶化を図っているため、ガラス成形後の冷
却時に成形体に割れが生じやすく、大型のものや複雑な
形状のものは作り難い問題があり、建材として使用する
には不向きであった。Further, in the glass ceramics disclosed in Japanese Patent Publication No. 54-34775, although cutting can be easily performed, after forming glass into a predetermined shape, reheating is performed to crystallize the mica solid solution. Therefore, there is a problem that a molded body is easily cracked at the time of cooling after glass molding, and it is difficult to produce a large-sized one or a complicated-shaped one, and it is not suitable for use as a building material.
本発明の目的は上述した課題を解消して、大型のもの
を容易に作製できるとともに、通常の金属加工用工具に
て切削加工が容易な結晶化ガラス建材およびその製造法
を提供しようとするものである。An object of the present invention is to solve the above-mentioned problems and provide a crystallized glass building material which can be easily manufactured in a large size and which can be easily cut by a normal metal working tool, and a method for manufacturing the same. It is.
（課題を解決するための手段） 本発明の結晶化ガラス建材は、少くともK2O 10〜30重
量％、BaO 5〜25重量％、MgO 10〜30重量％、Al2O3 3〜
15重量％、SiO2 20〜50重量％、F 5〜15重量％からなる
結晶化ガラス中に、30容量％以上の雲母結晶を析出させ
たことを特徴とするものである。(Means for Solving the Problems) crystallized glass building material of the present invention, at least K 2 O 10 to 30 wt%, BaO 5 to 25 wt%, MgO 10 to 30 wt%, Al 2 O 3 3~
15 wt%, SiO 2 20 to 50 wt%, in the crystallized glass consisting of F 5 to 15% by weight, characterized in that to precipitate at least 30% by volume of mica crystals.
また、本発明の結晶化ガラス建材の製造方法は、少く
ともK2O 10〜30重量％、BaO 5〜25重量％、MgO 10〜30
重量％、Al2O3 3〜15重量％、SiO2 20〜50重量％、F 5
〜15重量％を含んだガラスフリットを湿式で粉砕し、粉
砕物を鋳込み成形して乾燥後焼成することを特徴とする
ものである。In addition, the method for producing a crystallized glass building material of the present invention comprises at least 10 to 30% by weight of K 2 O, 5 to 25% by weight of BaO, and 10 to 30% by weight of MgO.
Wt%, Al 2 O 3 3~15 wt%, SiO 2 20 to 50 wt%, F 5
It is characterized in that a glass frit containing up to 15% by weight is wet-pulverized, the pulverized material is cast, dried and fired.
（作 用） 上述した本発明の結晶化ガラス建材の構成において、
所定の組成からなる結晶構造中に所定量の雲母を析出さ
せているため、建材として使用したとき、通常の金属加
工工具により切削加工を容易にすることができる。(Operation) In the configuration of the crystallized glass building material of the present invention described above,
Since a predetermined amount of mica is precipitated in a crystal structure having a predetermined composition, when used as a building material, cutting can be easily performed with a normal metal working tool.
また、本発明の結晶化ガラス建材の製造方法の構成に
おいて、所定組成の雲母結晶化ガラスフリットを湿式粉
砕後、流し込み成形、乾燥、焼成を実施する製造工程を
とることにより、従来法に比べて成形体に割れが生ぜ
ず、大型のものでも容易に作製でき、現場加工の容易な
建材を得ることができる。Further, in the configuration of the method for producing a crystallized glass building material of the present invention, by wet milling a mica crystallized glass frit of a predetermined composition, casting, drying, and firing, a manufacturing process is performed, which is compared with the conventional method. Cracks do not occur in the molded body, and large-sized ones can be easily manufactured, and a building material that can be easily processed on site can be obtained.
本発明において各成分の添加量を限定したのは、以下
の理由による。K2Oは10重量％未満では溶融温度が高く
溶け難くなるとともに、30重量％を越えると雲母の析出
量が少なくなり加工性が悪くなるため、10〜30重量％と
限定した。BaOは５重量％未満では溶融温度が高くなる
とともに、25重量％を越えると雲母の析出量が少なくな
るため、５〜25重量％と限定した。MgOは10重量％未満
では雲母の析出量が少なくなるとともに、30重量％を越
えると溶融温度が高くなるため、10〜30重量％と限定し
た。Al2O3は３重量％未満ではガラスの焼結および結晶
化が悪くなるとともに、15重量％を越えると溶融温度が
高くなるため、３〜15重量％と限定した。SiO2は20重量
％未満ではガラスの焼結および結晶化が悪くなるととも
に、50重量％を越えると溶融温度が高くなるため、20〜
50重量％と限定した。Ｆは５重量％未満では雲母の析出
量が少なくなるとともに、15重量％を越えるとガラスの
焼結および結晶化が悪くなるため、５〜15重量％と限定
した。In the present invention, the addition amount of each component is limited for the following reason. If K 2 O is less than 10% by weight, the melting temperature is high and it is difficult to melt, and if it exceeds 30% by weight, the amount of mica deposited is reduced and workability is deteriorated, so the content is limited to 10 to 30% by weight. If the content of BaO is less than 5% by weight, the melting temperature increases, and if it exceeds 25% by weight, the amount of mica deposited decreases, so that the content is limited to 5 to 25% by weight. When the content of MgO is less than 10% by weight, the precipitation amount of mica decreases, and when it exceeds 30% by weight, the melting temperature becomes high, so that the content is limited to 10 to 30% by weight. If the content of Al 2 O 3 is less than 3% by weight, the sintering and crystallization of the glass deteriorates, and if it exceeds 15% by weight, the melting temperature becomes high, so that the content is limited to 3 to 15% by weight. If the content of SiO 2 is less than 20% by weight, the sintering and crystallization of the glass will be poor, and if it exceeds 50% by weight, the melting temperature will be high.
Limited to 50% by weight. If the content of F is less than 5% by weight, the amount of precipitated mica decreases, and if it exceeds 15% by weight, the sintering and crystallization of the glass deteriorates. Therefore, the content of F is limited to 5 to 15% by weight.
なお、本発明では、溶融温度が高くなると揮発成分の
Ｆが飛散しやすく製造が難しくなるとともに、雲母はKM
g3Si4O10F2〜KMg3（AlSi3O10）F2の固溶体として析出す
るため、BaO、Al2O3を除くすべての成分の下限を正確に
守る必要がある。In the present invention, when the melting temperature is high, the volatile component F is liable to be scattered, making the production difficult, and the mica is KM
Since g 3 Si 4 O 10 F 2 to KMg 3 (AlSi 3 O 10 ) F 2 are precipitated as a solid solution, the lower limits of all components except for BaO and Al 2 O 3 must be accurately maintained.
また、結晶中の雲母結晶量は、30容量％未満であると
十分な加工性が得られないため、30容量％以上である必
要がある。Further, if the amount of mica crystals in the crystal is less than 30% by volume, sufficient workability cannot be obtained, so that the amount must be 30% by volume or more.
さらに、製造法における焼成条件は特に限定するもの
でないが、流し込み成形乾燥後、900〜1100℃の温度で3
0分以上の条件で焼成すると好ましい。Furthermore, the sintering conditions in the production method are not particularly limited, but after casting, drying and drying at a temperature of 900 to 1100 ° C.
It is preferable to bake under the condition of 0 minutes or more.
（実施例） 以下、実際の例について説明する。(Example) Hereinafter, an actual example will be described.
炭酸カリウム、ケイフッ化カリウム、炭酸バリウム、
マグネシア、アルミナ、シリカ等の原料を第１表に示す
所定の組成に調合後、1200〜1400℃の温度で約１時間溶
融し、溶融物を水中急冷してガラスフリットを作製し
た。Potassium carbonate, potassium fluorosilicate, barium carbonate,
After mixing raw materials such as magnesia, alumina, silica and the like into the prescribed compositions shown in Table 1, the materials were melted at a temperature of 1200 to 1400 ° C. for about 1 hour, and the melt was rapidly cooled in water to produce a glass frit.
得られたガラスフリットを湿式にてボールミル粉砕
し、平均粒径10〜20μｍのスリップを作製し、流し込み
成形を行なった。成形体は乾燥後900〜1100℃の温度で3
0分以上の条件で焼成を行なって、本発明試験No.1〜15
と比較例試験No.16〜27の試験体を得た。The obtained glass frit was pulverized in a ball mill by a wet method to produce a slip having an average particle size of 10 to 20 μm, and then subjected to casting. The molded body is dried at a temperature of 900 to 1100 ° C after drying.
Baking under conditions of 0 minutes or more, the present invention test No. 1 ~ 15
And the test body of the comparative example test No. 16-27 was obtained.
得られた試験体に対して雲母の析出量を測定するとと
もに、機械加工性を調べた。雲母の析出量は、Ｘ線回折
により雲母の（009）面のピークの大きさより相対比較
を行なって求めた。標準としては市販の合成雲母粉を10
0％とした。機械加工性は10mmの板状結晶ガラスに対
し、4mmφのHSSドリルにて穴明けに必要な時間を測定し
た。結果を第１表に示す。The amount of mica deposited on the obtained test specimen was measured, and the machinability was examined. The amount of mica deposited was determined by performing a relative comparison from the peak size of the (009) plane of the mica by X-ray diffraction. As standard, commercially available synthetic mica powder is 10
0%. The machinability was measured by measuring the time required for drilling a 10 mm plate-shaped crystal glass with a 4 mm φ HSS drill. The results are shown in Table 1.
第１表の結果から、本発明範囲内の組成を有するとと
もに本発明範囲内の雲母結晶量を有する本発明試験No.1
〜15は、比較例試験No.16〜27と比べて加工性が良好な
ことがわかる。 From the results in Table 1, it can be seen that the test No. 1 of the present invention having a composition within the range of the present invention and having an amount of mica crystals within the range of the present invention.
It can be seen that Nos. ~ 15 have better workability than Comparative Test Nos. 16-27.
（発明の効果） 以上の説明から明らかなように、本発明の結晶化ガラ
ス建材およびその製造方法によれば、結晶中に所定量の
雲母を析出させた結晶化ガラスを、フリットを粉砕後鋳
込み成形して乾燥焼成しているため、大型のものを容易
に作製でき通常の金属加工用工具により切削加工が容易
な結晶化ガラス建材を得ることができる。(Effects of the Invention) As is clear from the above description, according to the crystallized glass building material and the method for producing the same of the present invention, crystallized glass having a predetermined amount of mica precipitated in the crystal is cast after grinding the frit. Since it is molded and dried and fired, a large-sized product can be easily produced, and a crystallized glass building material that can be easily cut by a normal metal working tool can be obtained.
Claims (2)
量％、MgO 10〜30重量％、Al2O3 3〜15重量％、SiO2 20
〜50重量％、F 5〜15重量％からなる結晶化ガラス中
に、30容量％以上の雲母結晶を析出させたことを特徴と
する結晶化ガラス建材。At least 10 to 30% by weight of K 2 O, 5 to 25% by weight of BaO, 10 to 30% by weight of MgO, 3 to 15% by weight of Al 2 O 3 , SiO 2 20
A crystallized glass building material characterized in that 30% by volume or more of mica crystals are precipitated in crystallized glass comprising 50 to 50% by weight and 5 to 15% by weight of F.
量％、MgO 10〜30重量％、Al2O3 3〜15重量％、SiO2 20
〜50重量％、F 5〜15重量％を含んだガラスフリットを
湿式で粉砕し、粉砕物を鋳込み成形して乾燥後焼成する
ことを特徴とする結晶化ガラス建材の製造方法。2. At least 10 to 30% by weight of K 2 O, 5 to 25% by weight of BaO, 10 to 30% by weight of MgO, 3 to 15% by weight of Al 2 O 3 , SiO 2 20
A method for producing a crystallized glass building material, wherein a glass frit containing 5050 wt% and F 5 〜15 wt% is wet-pulverized, the pulverized material is cast, dried and fired.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63305919A JP2581785B2 (en) | 1988-12-05 | 1988-12-05 | Crystallized glass building material and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63305919A JP2581785B2 (en) | 1988-12-05 | 1988-12-05 | Crystallized glass building material and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02153842A JPH02153842A (en) | 1990-06-13 |
| JP2581785B2 true JP2581785B2 (en) | 1997-02-12 |
Family
ID=17950880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63305919A Expired - Lifetime JP2581785B2 (en) | 1988-12-05 | 1988-12-05 | Crystallized glass building material and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2581785B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0788238B2 (en) * | 1991-09-03 | 1995-09-27 | 工業技術院長 | Manufacturing method of ceramic products |
-
1988
- 1988-12-05 JP JP63305919A patent/JP2581785B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02153842A (en) | 1990-06-13 |
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