JP2546754B2 - Method for manufacturing golf club shaft - Google Patents

Method for manufacturing golf club shaft

Info

Publication number
JP2546754B2
JP2546754B2 JP3258333A JP25833391A JP2546754B2 JP 2546754 B2 JP2546754 B2 JP 2546754B2 JP 3258333 A JP3258333 A JP 3258333A JP 25833391 A JP25833391 A JP 25833391A JP 2546754 B2 JP2546754 B2 JP 2546754B2
Authority
JP
Japan
Prior art keywords
fiber
shaft
resin
thermoplastic resin
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP3258333A
Other languages
Japanese (ja)
Other versions
JPH0568726A (en
Inventor
久徳 吉田
隆志 伊藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mizuno Corp
Original Assignee
Mizuno Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mizuno Corp filed Critical Mizuno Corp
Priority to JP3258333A priority Critical patent/JP2546754B2/en
Publication of JPH0568726A publication Critical patent/JPH0568726A/en
Application granted granted Critical
Publication of JP2546754B2 publication Critical patent/JP2546754B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】 本発明は、繊維強化熱可塑性樹
脂製のゴルフクラブ用シャフト(以下シャフトという)
の製造方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a golf club shaft made of fiber reinforced thermoplastic resin (hereinafter referred to as shaft).
The present invention relates to a manufacturing method of.

【0002】[0002]

【従来の技術】 従来より繊維強化合成樹脂(以下FR
Pと省略する。)製シャフトとしては、強化繊維として
炭素繊維、ガラス繊維、アラミド繊維、ボロン繊維、ア
ルミナ繊維、炭化珪素繊維等各種繊維が単独あるいは組
み合わせて使用されている。マトリックス樹脂として
は、エポキシ樹脂が主で、それ以外には不飽和ポリエス
テル樹脂、フェノール樹脂など熱硬化性樹脂を使用した
ものがほとんどである。マトリックス樹脂に求められる
性能としては、繊維に含浸しやすく、界面の濡れ性が良
く接着力の大きいことが要求される。さらに強化繊維よ
りも伸びが大きく繊維の特性を充分に発揮させるもので
なくてはならない。又靭性が大きく、耐衝撃性を有する
ものが要求されている。上記のFRP製のシャフトは、
強化繊維に比弾性率、比強度が大きい材料を用いたこと
により、金属製のシャフトに比べ重量が軽く、設計の自
由度も大きくする事が出来た。しかし、マトリックス樹
脂については、熱硬化性樹脂では繊維にサイジング処理
をする事によって濡れ性、接着性を、適当に樹脂を加熱
することによって含浸性を改善することは出来るもの
の、伸び、靭性、耐衝撃性といった性質については熱可
塑性樹脂には及ばない。又、熱硬化性樹脂を用いる場合
にはプリプレグの保管に問題があった。プリプレグを長
期に保管しようとする場合には、−10℃以下の条件で
保管する必要があり、常温では1カ月以内であってもプ
リプレグのタック、ドレープ性は温度に影響され易いた
め保管には十分注意を要し、保管設備が不可欠である。
そのうえ、工程中の硬化に要する時間が約2時間と長
く、この短縮化が望まれていた。
2. Description of the Related Art Conventionally, fiber reinforced synthetic resin (hereinafter FR
Abbreviated as P. As the reinforcing shaft, various fibers such as carbon fiber, glass fiber, aramid fiber, boron fiber, alumina fiber and silicon carbide fiber are used alone or in combination as the reinforcing fiber. Epoxy resin is mainly used as the matrix resin, and most of the other matrix resins are thermosetting resins such as unsaturated polyester resin and phenol resin. As the performance required for the matrix resin, it is required that the fibers are easily impregnated, the interface has good wettability, and the adhesive strength is large. Further, it must have a larger elongation than the reinforcing fiber and can fully exhibit the characteristics of the fiber. Further, a material having high toughness and impact resistance is required. The above FRP shaft is
By using a material with a large specific elastic modulus and specific strength for the reinforcing fiber, the weight is lighter than that of a metal shaft, and the degree of freedom in design can be increased. However, regarding the matrix resin, the thermosetting resin can improve the wettability and adhesiveness by subjecting the fiber to sizing treatment, and the impregnability by heating the resin appropriately, but the elongation, toughness and resistance The impact resistance is inferior to that of thermoplastic resins. Further, when a thermosetting resin is used, there is a problem in storing the prepreg. If you want to store the prepreg for a long period of time, it is necessary to store it under the condition of -10 ° C or less, and the tack and drape property of the prepreg are easily affected by the temperature even if it is less than one month at room temperature. Careful attention is required and storage facilities are essential.
In addition, the time required for curing during the process is as long as about 2 hours, and this reduction has been desired.

【0003】そこでこれらの問題点を解決する方法とし
て、特開平1−185274号公報には、炭素繊維と熱
可塑性樹脂を用いて金属製のシャフトのフィーリングに
近づけたものが開示されている。また特開平2−317
70号公報には、マトリックス樹脂として熱可塑性樹脂
を用い、振動減衰性が良く、耐衝撃を向上させたシャフ
トが開示されている。
As a method for solving these problems, Japanese Patent Laid-Open No. 185274/1990 discloses a method of using carbon fibers and a thermoplastic resin to approximate the feeling of a metallic shaft. In addition, JP-A-2-317
Japanese Unexamined Patent Publication No. 70 discloses a shaft using a thermoplastic resin as a matrix resin, which has good vibration damping properties and improved impact resistance.

【0004】[0004]

【発明が解決しようとする課題】 上記の熱可塑性樹脂
製のシャフトを成形する方法としては、マトリックス樹
脂である熱可塑性樹脂を連続した強化繊維に含浸させて
形成したヤーン状の中間成形材料を、シャフト成形用の
芯金に巻き付けるフィラメントワインディング法、強化
繊維より成るUDあるいはクロスに樹脂を含浸させて形
成した中間成形材料を、シート状あるいはテープ状にし
て芯金に巻き付けるシートワインディング法やテープワ
インディング法によって成形されるのであるが、これら
樹脂含浸した強化繊維は常温において、すでに強化繊維
の剛性を発現しており、剛いため作業がしづらい。特
に、シャフトの先端部では、芯金の直径が5mm以下と
細いため、巻き付けることに非常に手間がかかった。
As a method of molding the above thermoplastic resin shaft, a yarn-shaped intermediate molding material formed by impregnating continuous reinforcing fibers with a thermoplastic resin that is a matrix resin, Filament winding method for wrapping around a core metal for shaft molding, sheet winding method or tape winding method for winding a UD or cloth made of reinforcing fibers into a sheet or tape, and forming an intermediate molding material into a sheet or tape around the core metal. The resin-impregnated reinforcing fibers have already developed the rigidity of the reinforcing fibers at room temperature and are difficult to work because they are rigid. In particular, since the diameter of the core metal at the tip of the shaft is as small as 5 mm or less, it takes a lot of time and effort to wind it.

【0005】そこで本発明は、これら従来の欠点に鑑
み、熱可塑性樹脂をマトリックス樹脂とした作業性の良
いシャフトの製造方法を提供しようとするものである。
In view of these conventional drawbacks, the present invention is intended to provide a method of manufacturing a shaft which uses a thermoplastic resin as a matrix resin and has good workability.

【0006】[0006]

【課題を解決するための手段】 本発明は、連続した強
化繊維と、熱可塑性樹脂繊維とを束ねて混繊糸を形成
し、前記混繊糸をシャフト成形用の芯金にフィラメント
ワインディングした後、シャフト成形用の金型内に配置
し加圧、加熱することによりシャフトを製造するもので
ある。
Means for Solving the Problems In the present invention, continuous reinforcing fibers and thermoplastic resin fibers are bundled to form a mixed fiber, and the mixed fiber is filament-wound onto a core metal for shaft molding. Placed in the mold for shaft molding
Then, the shaft is manufactured by pressurizing and heating .

【0007】[0007]

【作用】 上記のように、本発明の方法によれば、強化
繊維と熱可塑性樹脂繊維を束ねた混繊糸として用い、
混繊糸を構成している熱可塑性樹脂繊維をマトリック
スとなるように、シャフト成形用の芯金にフィラメント
ワインディングした後、シャフト成形用の金型内に配置
し加圧、加熱するので、前記混繊糸は常温で軟らかく、
形の小さいシャフトの先端部であっても巻き付け作業が
容易となり生産性を向上させる作用を奏する。
[Action] As described above, according to the method of the present invention, used as a combined filament yarn obtained by bundling a reinforcing fiber and a thermoplastic resin fiber, before
A filament is formed on the core metal for shaft molding so that the thermoplastic resin fibers forming the mixed fiber become a matrix.
Placed in the mold for shaft molding after winding
Since it is pressed and heated, the mixed yarn is soft at room temperature ,
Even if the tip of the shaft is small in shape, the winding work is facilitated and the productivity is improved.

【0008】[0008]

【実施例】 本発明を実施例に基づいて説明する。連続
した強化繊維として炭素繊維を用い、熱可塑性樹脂繊維
としてポリアミド繊維を用い、強化繊維と熱可塑性樹脂
繊維の比率を重量比で65:35になるように混繊糸を
形成し、シャフト成形用の芯金にフィラメントワインデ
ィングする直前に加熱して熱可塑性繊維を溶融させなが
ら巻き付け、シャフト成形用の芯金にフィラメントワイ
ンディングし、所定の形状にフィラメントワインディン
グした後、前記混繊糸の熱可塑性樹脂繊維がマトリック
スとなるように、250゜Cに加熱した金型内に配置し
加圧、加熱したのち、100゜Cまで冷却して脱型脱芯
し、表面を研磨してシャフトを形成した。本発明に用い
る混繊糸の強化繊維としては、前記炭素繊維の他、ガラ
ス繊維、アラミド繊維やこれ等と同効質の連続繊維を用
い、熱可塑性樹脂繊維としては、前記ポリアミド樹脂の
他、ポリエーテルエーテルケトン樹脂、ポリエチレンテ
レフタレート樹脂、ポリプロピレン樹脂やこれ等と同効
質の熱可塑性樹脂を用いる。混繊糸の強化繊維と熱可塑
性樹脂繊維の比率は任意であるが、好ましくは強化繊維
が30〜70体積%と成るように束ねて混繊糸とする。
EXAMPLES The present invention will be described based on examples. Carbon fiber is used as continuous reinforcing fiber, polyamide fiber is used as thermoplastic resin fiber, and mixed fiber is formed so that the weight ratio of the reinforcing fiber and the thermoplastic resin fiber is 65:35. Immediately before filament winding of the core metal, the thermoplastic fibers are melted and wound while being melted, the filament winding is performed on the core metal for shaft molding, the filament winding is performed into a predetermined shape, and then the thermoplastic resin fiber of the mixed fiber Is matric
To a temperature of 250 ° C., pressurizing and heating, cooling to 100 ° C., demolding and decoreing, and polishing the surface to form a shaft. As the reinforcing fibers of the mixed yarn used in the present invention, in addition to the carbon fibers, glass fibers, aramid fibers and continuous fibers having the same effect as these are used, and as the thermoplastic resin fibers, other than the polyamide resin, A polyether ether ketone resin, a polyethylene terephthalate resin, a polypropylene resin or a thermoplastic resin having the same effect as these is used. The ratio of the reinforcing fiber and the thermoplastic resin fiber of the mixed fiber is arbitrary, but preferably, the reinforcing fiber is bundled so as to be 30 to 70% by volume to form a mixed fiber.

【0009】[0009]

【発明の効果】 先ず、本発明シャフトの物性を従来の
シャフトと比較する。比較品として、炭素繊維に重量比
で65:35となるようにエポキシ樹脂を含浸させたヤ
ーンをマンドレルにフィラメントワインディングし、ポ
リプロピレン製のラッピングテープでラッピングした
後、硬化炉内で150゜C、2時間の条件で硬化させ
る。硬化後ラッピングテープを除去してシャフトとし
た。上記2種類のシャフトの物性について比較した結果
を、表1に示す。
First, the physical properties of the shaft of the present invention will be compared with those of the conventional shaft. As a comparative product, a yarn in which a carbon fiber was impregnated with an epoxy resin at a weight ratio of 65:35 was filament-wound on a mandrel, lapped with polypropylene wrapping tape, and then heated at 150 ° C in a curing furnace for 2 hours. It is cured under the condition of time. After curing, the wrapping tape was removed to obtain a shaft. The results of comparison of the physical properties of the above two types of shafts are shown in Table 1.

【0010】[0010]

【表1】 [Table 1]

【0011】表1からわかるように、本発明品は、比較
品と重量、トルク、剛さについて同等に設定しても、曲
げ強度、衝撃強度、振動減衰性について優れている。以
上のように本発明の方法は、連続した強化繊維と、熱可
塑性樹脂繊維とを束ねて混繊糸を形成し、前記混繊糸の
熱可塑性樹脂繊維がマトリックスとなるように、シャフ
ト成形用の芯金に前記混繊糸をフィラメントワインディ
ングし、所定の形状にフィラメントワインディングした
後、加熱した金型内に配置し加圧、加熱したのち、冷却
して脱型脱芯し、表面を研磨してシャフトを形成したも
のであるから、従来の熱可塑性樹脂を含浸して形成し
た、ヤーン状やUDあるいはクロス状の中間成形材料に
よる成形方法に比べて、常温で剛性が付与されておら
ず、強化繊維に張力がかけ易い。従って、シャフトの先
端部のような細い部分であっても容易に巻き付けること
が出来るので、作業性が良く設計通りのシャフトが製造
でき、品質も安定したものとなる。さらに、従来の方法
のように、強化繊維をUDあるいはクロス状に加工した
り、強化繊維に樹脂を含浸させるといった中間成形材料
を形成するための工程が省略出来るので、安価となり、
又加熱、加圧、硬化といった工程が連続的に行われ、成
形サイクルが短く製造時間が短縮できるのでコストも低
減できる。
As can be seen from Table 1, the product of the present invention is excellent in bending strength, impact strength, and vibration damping even when the weight, torque, and rigidity are set to be the same as those of the comparative product. INDUSTRIAL APPLICABILITY As described above, the method of the present invention forms a mixed fiber by bundling continuous reinforcing fibers and a thermoplastic resin fiber, and the thermoplastic resin fiber of the mixed fiber serves as a matrix for forming a shaft. After the filament winding of the mixed fiber to the core metal of the above, after filament winding into a predetermined shape, it is placed in a heated mold, pressurized and heated, then cooled and demolded and decoreed, and the surface is polished. Since the shaft is formed by a conventional method, rigidity is not imparted at room temperature as compared with a conventional molding method using a yarn-shaped, UD or cloth-shaped intermediate molding material that is formed by impregnating a thermoplastic resin. strengthening tension is applied not easy to fiber. Therefore, even a thin portion such as the tip of the shaft can be easily wound, so that the workability is good and the shaft as designed can be manufactured, and the quality is stable. Further, as in the conventional method, the process for forming the intermediate molding material such as processing the reinforcing fiber into the UD or the cloth shape or impregnating the reinforcing fiber with the resin can be omitted, so that the cost is reduced,
Further, since the steps of heating, pressurizing and curing are continuously performed, the molding cycle is short and the manufacturing time can be shortened, so that the cost can be reduced.

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 連続した強化繊維と、熱可塑性樹脂繊維
を束ねて混繊糸を形成し、前記混繊糸をシャフト成形
用の芯金にフィラメントワインディングした後、シャフ
ト成形用の金型内に配置し加圧、加熱してなることを特
徴とするFRP製ゴルフクラブ用シャフトの製造方法。
1. A continuous fiber and a thermoplastic resin fiber are bundled to form a mixed fiber, and the mixed fiber is filament-wound onto a core metal for forming a shaft , and then shuffled.
Placed bets in a mold for molding the pressure method of the FRP golf club shaft, characterized in Rukoto such heated.
JP3258333A 1991-09-09 1991-09-09 Method for manufacturing golf club shaft Expired - Lifetime JP2546754B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3258333A JP2546754B2 (en) 1991-09-09 1991-09-09 Method for manufacturing golf club shaft

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3258333A JP2546754B2 (en) 1991-09-09 1991-09-09 Method for manufacturing golf club shaft

Publications (2)

Publication Number Publication Date
JPH0568726A JPH0568726A (en) 1993-03-23
JP2546754B2 true JP2546754B2 (en) 1996-10-23

Family

ID=17318790

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3258333A Expired - Lifetime JP2546754B2 (en) 1991-09-09 1991-09-09 Method for manufacturing golf club shaft

Country Status (1)

Country Link
JP (1) JP2546754B2 (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0231770A (en) * 1988-07-20 1990-02-01 Mizuno Corp Shaft for golf club
MX172438B (en) * 1989-04-28 1993-12-16 Hoechst Celanese Corp ORGANIC POLYMERS THAT HAVE A MODIFIED SURFACE AND PROCEDURE FOR THEIR OBTAINING

Also Published As

Publication number Publication date
JPH0568726A (en) 1993-03-23

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