JP2544215B2 - Method for producing aluminum alloy base plate for printing plate support - Google Patents
Method for producing aluminum alloy base plate for printing plate supportInfo
- Publication number
- JP2544215B2 JP2544215B2 JP1316810A JP31681089A JP2544215B2 JP 2544215 B2 JP2544215 B2 JP 2544215B2 JP 1316810 A JP1316810 A JP 1316810A JP 31681089 A JP31681089 A JP 31681089A JP 2544215 B2 JP2544215 B2 JP 2544215B2
- Authority
- JP
- Japan
- Prior art keywords
- plate
- aluminum alloy
- treatment
- base plate
- printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000007639 printing Methods 0.000 title claims description 42
- 229910000838 Al alloy Inorganic materials 0.000 title claims description 30
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 229910000765 intermetallic Inorganic materials 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 21
- 229910045601 alloy Inorganic materials 0.000 claims description 10
- 239000000956 alloy Substances 0.000 claims description 10
- 238000005266 casting Methods 0.000 claims description 10
- 238000005097 cold rolling Methods 0.000 claims description 9
- 238000000137 annealing Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000005098 hot rolling Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 238000005242 forging Methods 0.000 claims description 2
- 238000007788 roughening Methods 0.000 description 36
- 239000002585 base Substances 0.000 description 21
- 238000004381 surface treatment Methods 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000005530 etching Methods 0.000 description 6
- 238000002791 soaking Methods 0.000 description 6
- 238000007645 offset printing Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000007743 anodising Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000010407 anodic oxide Substances 0.000 description 2
- 238000003486 chemical etching Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000866 electrolytic etching Methods 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000003504 photosensitizing agent Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910010038 TiAl Inorganic materials 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000012733 comparative method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
- B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
- B41N1/083—Printing plates or foils; Materials therefor metallic for lithographic printing made of aluminium or aluminium alloys or having such surface layers
Description
【発明の詳細な説明】 産業上の利用分野 この発明はオフセット印刷用アルミニウム合金支持体
または平版印刷用アルミニウム合金支持体として使用さ
れるアルミニウム合金素板（圧延板）の製造方法に関す
るものであり、特に電気化学的粗面化処理に適し、粗面
化面の外観が均一で印刷適性に優れ、しかも非画像部の
汚れの生じにくいオフセット印刷用もしくは平版印刷用
のアルミニウム合金支持体用素板を製造する方法に関す
るものである。TECHNICAL FIELD The present invention relates to a method for producing an aluminum alloy base plate (rolled plate) used as an aluminum alloy support for offset printing or an aluminum alloy support for lithographic printing, Particularly suitable for electrochemical roughening treatment, the roughened surface has a uniform appearance and is excellent in printability, and a base plate for aluminum alloy support for offset printing or lithographic printing that does not easily stain the non-image area The present invention relates to a manufacturing method.
従来の技術 一般にオフセット印刷版もしくは平版印刷版として
は、アルミニウム合金素板の表面に粗面化処理、陽極酸
化処理などの表面処理を施して支持体とし、その支持体
上に感光性物質を塗布、乾燥させて所謂PS板とし、その
PS板上に画像露光、現像、ガム引き等の製版処理を施し
たものが使用されている。このような製版処理の過程に
おいて、現像処理により未溶解で残留した感光層は画像
部を形成し、一方感光層が除去されてその下のアルミニ
ウム表面が露出した部分は親水性のため水受容部となっ
て非画像部を形成する。Conventional technology Generally, as an offset printing plate or a lithographic printing plate, the surface of an aluminum alloy base plate is subjected to surface treatment such as surface roughening treatment or anodizing treatment to form a support, and a photosensitive substance is applied onto the support. , Dried into a so-called PS plate,
A PS plate that has been subjected to plate making processing such as image exposure, development, gumming, etc. is used. In such a plate-making process, the photosensitive layer which remains undissolved by the development process forms an image area, while the photosensitive layer is removed and the underlying aluminum surface is exposed to water because it is hydrophilic. To form a non-image portion.
ところでこのようなオフセット印刷用もしくは平版印
刷用の支持体としては、一般に軽量でかつ表面処理性、
加工性に優れたアルミニウム合金板が使用される。この
ような目的のアルミニウム合金板としては、従来は、JI
S A1050,JIS A1100,JIS A303等からなる板厚0.1〜0.5mm
程度のアルミニウム合金圧延板が使用されており、この
ようなアルミニウム圧延板は、表面を粗面化し、その後
必要に応じて陽極酸化処理を施して印刷板に使用されて
いる。具体的には、特開昭48−49501号に記載されてい
る機械的粗面化処理、化学的エッチング処理、陽極酸化
皮膜処理を順に施したアルミニウム平版印刷板、あるい
は特開昭51−146234号に記載されている電気化学的処
理、後処理、陽極酸化処理を順に施したアルミニウム平
版印刷版、特公昭48−28123号に記載されている化学エ
ッチング処理、陽極酸化処理を順に施したアルミニウム
平版印刷版、あるいは機械的粗面化処理後に特公昭48−
28123号に記載されている処理を施したアルミニウム平
版印刷版等が知られている。By the way, as a support for such offset printing or lithographic printing, it is generally lightweight and has a surface treatment property,
An aluminum alloy plate with excellent workability is used. Conventionally, as an aluminum alloy plate for such a purpose, JI
Thickness of S A1050, JIS A1100, JIS A303, etc. 0.1 to 0.5 mm
A rolled aluminum alloy plate of a certain degree is used, and such an aluminum rolled plate is used as a printing plate after roughening the surface and then subjecting it to anodizing treatment as needed. Specifically, an aluminum lithographic printing plate which has been subjected to mechanical roughening treatment, chemical etching treatment, and anodic oxide film treatment in this order as described in JP-A-48-49501, or JP-A-51-146234. Aluminum lithographic printing plate sequentially subjected to the electrochemical treatment, post-treatment and anodizing treatment described in No. 48, and aluminum lithographic printing plate sequentially subjected to the chemical etching treatment and anodizing treatment described in JP-B-48-28123. After printing plate or mechanical surface roughening treatment
Aluminum lithographic printing plates which have been subjected to the treatment described in No. 28123 are known.
発明が解決しようとする課題 前述のような印刷用アルミニウム合金圧延板を実際に
印刷に使用するにあたっては、先ず既に述べたように素
板表面を機械的方法、化学的方法、電気化学的方法のう
ちいずれか１種、または２種以上の組合わされた工程に
よって粗面化した後、必要に応じて印刷性向上のために
厚さ0.5〜３μｍの陽極酸化皮膜を生成し、その後感光
剤を塗布して露光し、現像等の製版処理を行ない、印刷
機の円筒形版胴に巻付け、湿し水の存在下においてイン
クを画像部に付着させ、ゴムブランケットに転写後、紙
面に印刷する。DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention In actually using the rolled aluminum alloy plate for printing as described above in printing, first, as described above, the raw plate surface is subjected to a mechanical method, a chemical method, or an electrochemical method. After roughening by any one of them or a combination of two or more of them, an anodized film with a thickness of 0.5 to 3 μm is formed to improve printability, if necessary, and then a photosensitizer is applied. Then, the plate is exposed to light, subjected to plate making processing such as development, wrapped around a cylindrical plate cylinder of a printing machine, ink is made to adhere to the image portion in the presence of fountain solution, transferred to a rubber blanket, and then printed on a paper surface.
以上のようにして使用される印刷用アルミニウム合金
圧延板には、次のような特性が要求される。The following characteristics are required for the rolled aluminum alloy plate for printing used as described above.
すなわち先ず第１には、粗面化処理によって均一に凹
凸を形成することができ、粗面化処理後に不規則なムラ
が生じたり、圧延方向に沿うストリークスと称される筋
状のムラが生じたりせず、かつ適当な色調を呈すること
が要求される。ここで、粗面化処理によって均一な凹凸
を形成できることを一般的に砂目立て性が良いと言い、
また粗面化後の不規則なムラを面質ムラと称する。この
ように砂目立て性が良好で、面質ムラやストリークスが
生ぜずにかつ適正な色調が得られるように均一かつ適切
に粗面化させ得る性能を以下「表面処理性」と称する。That is, first, unevenness can be uniformly formed by the roughening treatment, and irregular unevenness is generated after the roughening treatment, or streak-like unevenness called streaks along the rolling direction is generated. It is required that it does not occur and that it has an appropriate color tone. Here, it is generally said that being able to form uniform unevenness by roughening treatment has good graining property,
Irregular unevenness after roughening is called surface quality unevenness. In this way, the property that the graining property is good and the surface can be uniformly and appropriately roughened so as to obtain an appropriate color tone without causing unevenness of surface quality and streaks is referred to as "surface treatment property".
次に第２には、印刷中に非画像部にインクが付着しな
いことが要求される。このような非画像部にインクが付
着することに関する性能を以下「インク汚れ性」と称
す。Second, it is required that ink does not adhere to non-image areas during printing. Hereinafter, the performance relating to the adhesion of the ink to the non-image portion is referred to as “ink stain resistance”.
これらの特性のうち、表面処理性が劣る場合には、粗
面化処理後の表面に面質ムラやストリークスが生じて商
品価値が低下する。また粗面化処理後の表面凹凸（砂
目）は耐刷力や画像の鮮明さにも大きな影響を及ぼすか
ら、表面処理性が良好であって粗面化処理後の凹凸が均
一でムラがないことは、印刷版として基本的に重要な条
件である。If the surface treatment property is poor among these characteristics, unevenness in surface quality and streaks occur on the surface after the roughening treatment, and the commercial value is reduced. In addition, since the surface irregularities (grains) after the roughening treatment have a great influence on the printing durability and the sharpness of the image, the surface treatability is good, and the unevenness after the roughening treatment is uniform and uneven. Absence is a fundamentally important condition for printing plates.
ここで、粗面化処理を電解エッチングにより行なう場
合には、電解条件や電解液等によって粗面の状態が変化
することはもちろんであるが、電解エッチングの現象が
アルミニウム表面と電解液との電気化学的反応である以
上、アルミニウム素材自体の特性（表面処理性）も電解
エッチングによる粗面化の状態に当然に影響する。しか
しながら従来の印刷用アルミニウム合金素板において
は、粗面化に適した合金成分や組織状態について深く検
討がなされてはおらず、必ずしも充分な表面処理性が得
られていたとは言えないのが実情である。Here, when the surface-roughening treatment is performed by electrolytic etching, it goes without saying that the state of the rough surface changes depending on the electrolytic conditions, the electrolytic solution, etc. As long as it is a chemical reaction, the characteristics (surface treatability) of the aluminum material itself naturally affect the roughened state by electrolytic etching. However, in the conventional aluminum alloy base plate for printing, the alloy components and the structure state suitable for surface roughening have not been deeply studied, and it cannot be said that sufficient surface treatment properties have necessarily been obtained. is there.
またインク汚れ性に関しては、印刷中に非画像部にイ
ンクが付着して印刷物が汚れることは印刷版として基本
的に避けなければならないことである。Regarding the stain resistance of the ink, it is basically necessary to prevent the printed matter from being stained by the ink adhering to the non-image area during printing.
この発明は以上の事情を背景としてなされたもので、
前述のような表面処理性およびインク汚れ性が良好な印
刷版支持体用アルミニウム合金素板を提供することを目
的とするものである。This invention was made against the background of the above circumstances.
It is an object of the present invention to provide an aluminum alloy base plate for a printing plate support, which has good surface treatment properties and ink stain properties as described above.
課題を解決するための手段 本発明者等は、前述の課題を解決するべく鋭意実験・
検討を重ねた結果、印刷版支持体として用いるアルミニ
ウム合金の成分組成を適切に設定すると同時に、印刷版
支持体用素板の製造プロセス条件を適切に選定すること
を通じて合金マトリックス中の金属間化合物の大きさや
量を適切に規制することによって、表面処理性とインク
汚れ性とが同時に優れた印刷版が得られることを見出
し、この発明をなすに至ったのである。Means for Solving the Problems The present inventors have conducted diligent experiments to solve the above-mentioned problems.
As a result of repeated studies, the composition of the aluminum alloy used as the printing plate support was appropriately set, and at the same time, the manufacturing process conditions of the plate for the printing plate support were appropriately selected to improve the intermetallic compound content in the alloy matrix. The inventors have found that by appropriately controlling the size and the amount, it is possible to obtain a printing plate which is excellent in surface treatment property and ink stain property at the same time, and the present invention has been completed.
具体的には、この発明の印刷版支持体用アルミニウム
合金素板の製造方法は、Fe0.10〜0.60wt％、Si0.04〜0.
15wt％、Cu0.001〜0.1wt％を含有し、残部がAlおよび不
可避的不純物よりなる合金を35mm/min以上の鋳造速度で
DC鍛造法により鋳造し、得られた鋳塊を、500℃以上で
しかもSi量との関係で 加熱温度（℃）≧1.4×103×Si％＋390 を満たす加熱温度で加熱し、さらに熱間圧延および冷間
圧延を行なって所要の板厚とするにあたり、熱間圧延と
冷間圧延との間もしくは冷間圧延の中途において350℃
以上の温度で中間焼鈍を施し、これによってかつ金属間
化合物の量が0.9wt％以下であってしかも金属間化合物
中のSiが素板全重量の0.03wt％以下であり、さらに素板
表面部における円相当径５μｍ以上のサイズの金属間化
合物の個数が素板表面部における全金属間化合物数の１
％以下の素板を得ることを特徴とするものである。Specifically, the manufacturing method of the aluminum alloy base plate for the printing plate support of the present invention, Fe0.10 ~ 0.60wt%, Si0.04 ~ 0.
An alloy containing 15 wt% and Cu 0.001 to 0.1 wt% with the balance Al and inevitable impurities at a casting speed of 35 mm / min or more.
The ingot obtained by casting by the DC forging method is heated at 500 ° C or higher and at a heating temperature (° C) ≥ 1.4 × 10 3 × Si% + 390 in relation to the amount of Si, and further hot 350 ° C between hot rolling and cold rolling or in the middle of cold rolling when rolling and cold rolling to obtain the required sheet thickness.
Intermediate annealing was performed at the above temperature, and the amount of intermetallic compound was 0.9 wt% or less, and Si in the intermetallic compound was 0.03 wt% or less of the total weight of the raw plate. The number of intermetallic compounds having a circle equivalent diameter of 5 μm or more in 1 is 1 of the total number of intermetallic compounds on the surface of the raw plate.
% Or less is obtained.
作用 先ずこの発明の印刷版支持体用アルミニウム合金素板
の製造方法に使用されるアルミニウム合金の成分限定理
由を述べる。Action First, the reasons for limiting the components of the aluminum alloy used in the method for producing an aluminum alloy base plate for a printing plate support of the present invention will be described.
Fe: Fe量が0.10wt％未満では表面処理性が劣るため粗面化
処理後にムラが生じやすくなるとともに、機械的性質も
劣る。一方Fe量が0.60wt％を越えれば、インク汚れ性が
劣り、また粗面化処理後の凹凸が粗く不均一となるとと
もに、粗面化処理後の色調が黒味を帯びて色調不適当と
なる。したがってFeは0.10〜0.60wt％の範囲内とした。Fe: When the Fe content is less than 0.10 wt%, the surface treatment property is poor, so that unevenness is likely to occur after the surface roughening treatment and the mechanical properties are also poor. On the other hand, when the Fe content exceeds 0.60 wt%, the ink stain resistance is poor, and the unevenness after the surface roughening treatment is rough and uneven, and the color tone after the surface roughening treatment becomes blackish and the color tone is unsuitable. Become. Therefore, Fe is set within the range of 0.10 to 0.60 wt%.
Si: Si量が0.04wt％未満では表面処理性が劣り、粗面化処
理後の色調にムラが生じるおそれがあるとともに、耐刷
性が劣る。Siが0.15％を越えると粗面化処理後の色調が
黒味を帯びて色調不適当となり、またインク汚れ性も劣
るようになる。したがってSi量は0.04〜0.15wt％の範囲
内とした。Si: When the amount of Si is less than 0.04 wt%, the surface treatment property is poor, and the color tone after the surface roughening treatment may be uneven, and the printing durability is poor. When Si exceeds 0.15%, the color tone after the surface roughening treatment becomes blackish and the color tone becomes unsuitable, and the ink stain resistance becomes poor. Therefore, the amount of Si is set within the range of 0.04 to 0.15 wt%.
Cu: Cu量が0.001wt％未満では表面処理性が劣り、粗面化
処理後の砂目が粗く、不均一となるとともに色調にもム
ラが生じる。一方Cu量が0.1wt％を越えれば、粗面化処
理後の色調が黒味を帯びて不適当となるとともに、イン
ク汚れ性も劣化する。したがってCuは0.001〜0.1wt％の
範囲内とした。Cu: When the amount of Cu is less than 0.001 wt%, the surface treatability is poor, and the grain after the roughening treatment is rough and uneven, and the color tone is uneven. On the other hand, if the amount of Cu exceeds 0.1 wt%, the color tone after the surface roughening treatment becomes blackish and unsuitable, and the ink stain resistance deteriorates. Therefore, Cu is set within the range of 0.001 to 0.1 wt%.
以上のFe,Si,Cuの残部は、基本的にはAlおよび不可避
的不純物とすれば良い。The balance of Fe, Si, and Cu described above may basically be Al and inevitable impurities.
なお一般にアルミニウム合金の製造においては結晶粒
微細化のために微量のTi、あるいはTiおよびＢを添加す
ることがあるが、この発明の印刷版支持体用アルミニウ
ム合金素板においても微量のTiもしくはTiおよびＢを添
加しても良く、その添加によって結晶粒を微細化して圧
延板のキメ、ストリークスを防止する効果が得られる。
但し、Ti添加量が0.003wt％未満ではその効果が得られ
ず、一方Tiが0.15wt％を越えればTiAl3粗大金属間化合
物が生成されてしまうから、Tiを添加する場合の添加量
は0.003〜0.15wt％とすることが好ましい。またＢはTi
と共存して結晶粒微細化効果を発揮するが、1ppm未満で
はその効果が得られず、一方100ppmを越えればその効果
が飽和するとともに粗大TiB2粒子による線状欠陥が発生
するおそれがあるから、ＢをTiとともに添加する場合の
Ｂ添加量は１〜100ppmとすることが好ましい。In general, in the production of aluminum alloys, a small amount of Ti, or Ti and B may be added to refine the crystal grains, but even in the aluminum alloy base plate for a printing plate support of the present invention, a small amount of Ti or Ti is used. And B may be added, and the addition of B and B has the effect of refining the crystal grains and preventing the texture and streaks of the rolled plate.
However, if the Ti addition amount is less than 0.003 wt%, the effect cannot be obtained, while if Ti exceeds 0.15 wt%, TiAl 3 coarse intermetallic compound is generated, so the addition amount of Ti is 0.003 It is preferable to be 0.15 wt%. B is Ti
Coexisting with the grain refinement effect is exhibited, but if less than 1 ppm, the effect cannot be obtained, while if it exceeds 100 ppm, the effect may be saturated and linear defects due to coarse TiB 2 particles may occur. , B is preferably added in an amount of 1 to 100 ppm when B is added together with Ti.
なおまた、不純物としてはMg,Mn,Cr,Zr,V,Zn,Be等が
含有されることがあるが、これらの不純物は0.05wt％以
下程度の微量であれば大きな悪影響は与えない。In addition, as impurities, Mg, Mn, Cr, Zr, V, Zn, Be, etc. may be contained, but if these impurities are trace amounts of 0.05 wt% or less, they do not have a great adverse effect.
この発明の印刷版支持体用アルミニウム合金素板の製
造方法においては、合金成分組成を前述のように規定す
るのみならず、素板製造プロセス条件を適切に選定し
て、素板中における金属間化合物の量、サイズ等につい
て次の３条件で規制することが特にインク汚れ性の向上
のために必要である。In the method for producing an aluminum alloy base plate for a printing plate support according to the present invention, not only the alloy component composition is specified as described above, but also the base plate manufacturing process conditions are appropriately selected, and the It is particularly necessary to control the amount and size of the compound under the following three conditions in order to improve the ink stain resistance.
すなわち先ず第１に、素板中の金属間化合物の量が0.
9wt％を越えればインク汚れ性が劣化するから、良好な
インク汚れ性を得るためには金属間化合物量を0.9wt％
以下に規制する必要がある。なおここで金属間化合物の
重量％の測定は第１図の方法によって行なった。That is, first of all, the amount of intermetallic compound in the blank is 0.
If it exceeds 9 wt%, the ink stain resistance will deteriorate. Therefore, in order to obtain good ink stain resistance, the amount of intermetallic compound should be 0.9 wt%.
The following needs to be regulated. The weight% of the intermetallic compound was measured by the method shown in FIG.
第２に、金属間化合物中のSi量が素板全体の重量に対
し0.03wt％を越えてもインク汚れ性が劣化するから、良
好なインク汚れ性を得るためには金属間化合物中のSi量
を素板全体の重量に対し0.03wt％以下に規制する必要が
ある。ここで、金属間化合物中のSiの素板全重量に対す
る重量％の測定は、第２図に示す方法によって行なっ
た。Secondly, even if the amount of Si in the intermetallic compound exceeds 0.03 wt% with respect to the weight of the whole base plate, the ink stain resistance deteriorates. It is necessary to regulate the amount to 0.03 wt% or less with respect to the weight of the whole base plate. Here, the weight% of Si in the intermetallic compound with respect to the total weight of the blank was measured by the method shown in FIG.
さらに第３の条件として、素板表面部における５μｍ
以上のサイズの金属間化合物の数が同じ表面部における
全金属間化合物の数の１％を越えればやはりインク汚れ
性が劣化するから、この割合を１％以下に規制すること
がインク汚れ性を改善するために必要である。ここで、
素板表面部とは、素板（圧延板）表面を圧延の粗度が消
滅する程度から、20μｍ程度の深さにまで研磨した表面
を意味する。すなわち、通常の金属組織観察法の範囲内
での研磨後の表面に相当する。また金属間化合物の大き
さは、画像解析装置を用いて測定したものであって、金
属間化合物のサイズは、その金属間化合物の面積と等し
い面積を有する円を仮定し、その円の径（円相当径）で
示した。なお実際の測定にあたって全金属間化合物数と
しては、0.5μｍ未満の金属間化合物を無視した。した
がって実際の測定では、素板表面部において円相当径５
μｍ以上のサイズの金属間化合物の個数が円相当径0.5
μｍ以上の金属間化合物数の１％以下であることを意味
する。As a third condition, 5 μm on the surface of the raw plate
If the number of intermetallic compounds of the above size exceeds 1% of the total number of intermetallic compounds on the same surface portion, the ink stain resistance also deteriorates. Therefore, it is necessary to regulate this ratio to 1% or less. It is necessary to improve. here,
The raw plate surface portion means a surface obtained by polishing the raw plate (rolled plate) surface to a depth of about 20 μm from the extent that the roughness of rolling disappears. That is, it corresponds to the surface after polishing within the range of the ordinary metallographic observation method. The size of the intermetallic compound is measured by using an image analyzer, and the size of the intermetallic compound is assumed to be a circle having an area equal to the area of the intermetallic compound, and the diameter of the circle ( Equivalent diameter). In the actual measurement, the number of intermetallic compounds less than 0.5 μm was ignored. Therefore, in actual measurement, the equivalent circle diameter is 5 at the surface of the blank.
The number of intermetallic compounds with size of μm or more is equivalent circle diameter 0.5
It means 1% or less of the number of intermetallic compounds of μm or more.
以上のように、金属間化合物の量の規制、金属間化合
物中のSiの量の規制、および素板表面部における５μｍ
以上の金属間化合物の割合の規制の３条件が揃ってはじ
めてインク汚れ性を極めて改善することができる。As described above, the regulation of the amount of the intermetallic compound, the regulation of the amount of Si in the intermetallic compound, and 5 μm on the surface of the raw plate
Ink stain resistance can be significantly improved only after the above three conditions for controlling the ratio of the intermetallic compound are met.
次にこの発明の印刷版支持体用アルミニウム合金素板
の製造方法について説明する。Next, a method for manufacturing the aluminum alloy base plate for a printing plate support of the present invention will be described.
先ず前述のような成分を含有するアルミニウム合金を
溶製し、通常のDC鋳造法（半連続鋳造法）によって鋳造
する。ここで、DC鋳造における鋳造速度は35mm/min以上
とする必要がある。鋳造速度が35mm/min未満では、金属
間化合物が大きくなって５μｍ以上のサイズの金属間化
合物が１％を越えるようになってしまうおそれがある。First, an aluminum alloy containing the above components is melted and cast by a normal DC casting method (semi-continuous casting method). Here, the casting speed in DC casting must be 35 mm / min or more. If the casting speed is less than 35 mm / min, the intermetallic compound may become large and the intermetallic compound having a size of 5 μm or more may exceed 1%.
鋳造後は鋳塊に対して均熱処理（均質化処理）を行な
う。この均熱処理は、その加熱温度を、500℃以上とす
るとともに、Si量（重量％）との関係で次の（１）式を
満たさせる必要がある。After casting, the ingot is subjected to soaking treatment (homogenization treatment). In this soaking treatment, it is necessary to set the heating temperature to 500 ° C. or higher and satisfy the following expression (1) in relation to the amount of Si (% by weight).
加熱温度（℃）≧1.4×103×Si％＋390 …（１） 均熱処理における加熱温度が500℃未満では鋳塊の均
質化が不充分で、粗面化処理後にムラが生じるおそれが
あり、また（１）式を外れれば、金属間化合物中のSiが
0.03％を越えてインク汚れ性が低下するおそれがある。
なお均熱処理における加熱時間は２時間以上が好まし
い。Heating temperature (° C) ≥ 1.4 × 10 3 × Si% + 390 (1) If the heating temperature in soaking is less than 500 ° C, homogenization of the ingot may be insufficient and unevenness may occur after roughening treatment. If the formula (1) is not satisfied, Si in the intermetallic compound
If it exceeds 0.03%, the ink stain resistance may decrease.
The heating time in soaking is preferably 2 hours or more.
均熱処理後は常法にしたがって熱間圧延し、さらに冷
間圧延を施して所要の板厚の圧延板とする。ここで、熱
間圧延の直後、あるいは冷間圧延の途中において必要に
応じて１回もしくは２回以上の中間焼鈍を施すが、この
中間焼鈍は、350℃以上で行なうことが必要である。350
℃未満の温度では、金属Siが析出し、金属間化合物中の
Siが0.03％を越えてしまい、その結果インク汚れ性が低
下してしまいおそれがある。なお中間焼鈍は、通常のバ
ッチ焼鈍、連続焼鈍のいずれでも良い。After the soaking treatment, hot rolling is performed according to a conventional method, and further cold rolling is performed to obtain a rolled plate having a required plate thickness. Here, immediately after the hot rolling or during the cold rolling, intermediate annealing is performed once or twice or more as needed, and this intermediate annealing needs to be performed at 350 ° C. or more. 350
At temperatures below ℃, metallic Si precipitates and
Si exceeds 0.03%, and as a result, the ink stain resistance may deteriorate. The intermediate annealing may be either ordinary batch annealing or continuous annealing.
以上のようにして得られるこの発明の印刷版支持体用
アルミニウム合金素板を実際に印刷版支持体として用い
るにあたっては、表面に粗面化処理を施すことが必要で
ある。この発明のアルミニウム合金素板に対して施す粗
面化処理としては、塩酸または硝酸電解水溶液中で電気
化学的に粗面化する方法が好適である。なおこの電気化
学的粗面化処理の前には、アルミニウム表面を金属ワイ
ヤーでひっかくワイヤーグレイニング法、研磨球、研磨
剤でアルミニウム表面を粗面化するボールグレイニング
法、ナイロンブラシと研磨剤で表面を粗面化するブラシ
グレイニング法のような機械的粗面化処理を行なってお
いても良い。更に、機械的粗面化処理の後に酸またはア
ルカリにより化学的な予備エッチングを施しても良い。
酸でエッチングする場合はエッチングに長時間を用する
ため、アルカリでエッチングするのが一般的である。こ
の予備エッチングに好適に要いられるアルカリ剤として
は、苛性ソーダ、炭酸ソーダ、アルミン酸ソーダ、メタ
珪酸ソーダ、燐酸ソーダ、水酸化カリウム、水酸化リチ
ウム等があり、この場合の温度と濃度の好ましい範囲は
それぞれ20〜100℃、１〜50％であり、アルミニウムの
溶解量が５〜20g/m2となるような条件を適用することが
好ましい。When the aluminum alloy base plate for a printing plate support of the present invention obtained as described above is actually used as a printing plate support, it is necessary to subject the surface to a roughening treatment. As the surface-roughening treatment applied to the aluminum alloy base plate of the present invention, a method of electrochemically surface-roughening in a hydrochloric acid or nitric acid electrolytic aqueous solution is suitable. Before this electrochemical surface roughening treatment, the aluminum surface is scratched with a metal wire by a wire graining method, a polishing sphere, a ball graining method for roughening the aluminum surface with an abrasive, a nylon brush and an abrasive. Mechanical roughening treatment such as a brush graining method for roughening the surface may be performed. Furthermore, chemical pre-etching may be performed with an acid or alkali after the mechanical surface roughening treatment.
When etching with an acid, it takes a long time to etch, so it is common to perform etching with an alkali. Suitable alkali agents for this preliminary etching include caustic soda, sodium carbonate, sodium aluminate, sodium metasilicate, sodium phosphate, potassium hydroxide, lithium hydroxide, etc. Are 20 to 100 ° C. and 1 to 50%, respectively, and it is preferable to apply conditions such that the amount of aluminum dissolved is 5 to 20 g / m 2 .
実 施 例 第１表の合金符号Ａ〜Ｅに示す成分組成のアルミニウ
ム合金を溶製し、DC鋳造法によって450×1200×3500mm
の鋳塊を鋳造した。このときの鋳造速度は、第２表中に
示すように一部を30mm/min、60mm/minとし、他は65mm/m
inとした。得られた鋳塊に対し、第２表中に示すような
種々の条件で均熱処理を施した後、片面10mmずつ面削
し、その後450℃で熱間圧延を開始して、4.0mm厚の熱延
板とした。次いで厚さ1.5mmまで冷間圧延した後、中間
焼鈍としてバッチ式にて380℃で３時間保持し、その後
0.3mm厚となるまで最終冷間圧延を施した。Practical example An aluminum alloy having the composition indicated by alloy code A to E in Table 1 was melted and was prepared by DC casting method to produce 450 × 1200 × 3500 mm.
The ingot was cast. The casting speed at this time was 30 mm / min and 60 mm / min for some parts and 65 mm / m for others, as shown in Table 2.
in The obtained ingots were subjected to soaking treatment under various conditions as shown in Table 2, and then each side was chamfered by 10 mm, and then hot rolling was started at 450 ° C. It was a hot rolled plate. Then, after cold rolling to a thickness of 1.5 mm, as an intermediate annealing, the batch type was kept at 380 ° C. for 3 hours, and then
Final cold rolling was performed until the thickness became 0.3 mm.
このようにして得られた各素板について金属間化合物
の晶出状況、すなわち金属間化合物の割合（重量％）、
金属間化合物中のSiの素板全重量に対する割合（重量
％）、および表面部における円相当径５μｍ以上の金属
間化合物の個数割合を調べた結果を第２表中に示す。な
お各測定方法は既に述べた通りである。The crystallized state of the intermetallic compound in each of the blanks thus obtained, that is, the proportion (% by weight) of the intermetallic compound,
Table 2 shows the results of examining the ratio (% by weight) of Si in the intermetallic compound to the total weight of the base plate and the number ratio of the intermetallic compound having a circle-equivalent diameter of 5 μm or more in the surface portion. Each measuring method is as described above.
さらに、各製造工程条件により得られた各素板をブラ
ッシングにより機械的に粗面化した後、10％NaOH水溶液
中で50℃×１分間予備エッチングを施し、続いて３％硝
酸水溶液中で90A/dm2で電気化学的なエッチング（粗面
化処理）を施した。引き続いて30％硫酸水溶液中で55
℃、１分間のデスマット処理を施した後、20％硫酸水溶
液を主成分とする電解液中で陽極酸化処理により１μｍ
の陽極酸化皮膜を形成し、続いて感光剤を塗布して平版
印刷版用PS板を製造した。これに所定の感光処理および
現像処理を施した。このようにして、得られた印刷原版
を用いて湿し水の存在の下に10万部の印刷を行なった。Furthermore, after mechanically roughening each raw plate obtained by each manufacturing process condition by brushing, pre-etching is performed in 10% NaOH aqueous solution at 50 ° C for 1 minute, and then 90% in 3% nitric acid aqueous solution. Electrochemical etching (roughening treatment) was performed at / dm 2 . Followed by 55% in 30% aqueous sulfuric acid
After desmutting at 1 ° C for 1 minute, anodize 1 μm in an electrolyte containing 20% sulfuric acid as a main component.
To form a anodic oxide film, and then a photosensitizer was applied to produce a PS plate for a lithographic printing plate. This was subjected to a predetermined photosensitive treatment and development treatment. In this way, 100,000 copies were printed in the presence of a fountain solution using the printing plate precursor thus obtained.
本発明法、および比較法によって得られた各素板につ
いて、前述のように機械的粗面化−予備エッチング−電
気化学的粗面化処理を行なった後の表面処理性と、前述
の工程により最終的に得られた印刷原版についての10万
部印刷テスト後の非画像のインク汚れ性について調査し
た結果を第３表に示す。For each raw plate obtained by the method of the present invention and the comparative method, the surface treatment property after performing the mechanical surface roughening-preliminary etching-electrochemical surface roughening treatment as described above, and the above-mentioned steps Table 3 shows the results of an examination of the non-image ink stain properties of the finally obtained printing original plate after a printing test of 100,000 copies.
なお第３表において表面処理性のうち画質ムラについ
ては、 ○…良 △…中間 ×…不良 さらに色調については、 ○…良 ×…黒っぽ過ぎて不良 で評価した。また砂目については、粗面の凹凸を観察し
て、 ○…均一 △…やや不均一 ×……不均一 で評価した。さらに、インク汚れ性に関しては、非画像
部のインク汚れを目視で観察して、 ○…インク汚れ無し △…やや汚れ有り ×…不良 で評価した。In Table 3, the unevenness in image quality among the surface treatment properties was evaluated as ◯ ... Good Δ ... Intermediate X ... Poor, and the color tone was evaluated as ◯ ... Good X ... too dark and defective. Regarding the grain, the unevenness of the rough surface was observed and evaluated as ◯ ... uniform Δ ... somewhat nonuniform × ... nonuniform. Further, regarding the ink stain resistance, the ink stain in the non-image area was visually observed, and evaluated as ◯ ... No ink stain Δ: Slight stain X: Poor
第３表に示すように、この発明の実施例による印刷版
支持体用アルミニウム合金素板（資料番号1,2）は、い
ずれも表面処理性が良好で、電気化学的粗面化処理後に
面質ムラや砂目のムラがなく、かつ色調も適当であり、
しかも印刷版に使用した際の非画像部のインク汚れも発
生せず、インク汚れ性が優れていることが判明した。 As shown in Table 3, each of the aluminum alloy base plates for printing plate supports (Document Nos. 1 and 2) according to the examples of the present invention had good surface treatability, and had a surface after electrochemical graining treatment. There is no unevenness in quality or graininess, and the color tone is appropriate,
Moreover, it was found that the ink stain resistance of the non-image portion did not occur when used in the printing plate, and the ink stain resistance was excellent.
一方比較例の試料番号3,4の素板は、合金成分はこの
発明の範囲内であるが金属間化合物の条件がこの発明の
範囲を外れたものであり、この場合表面処理性は比較的
良好ではあったが、インク汚れ性が劣ることが明らかで
ある。また比較例の試料番号５〜７の素板は、合金成分
自体がこの発明の範囲を外れ、また一部は金属間化合物
条件もこの発明の範囲を外れたものであり、これらの場
合は表面処理性とインク汚れ性とのいずれか一方または
双方が劣っていることが明らかである。On the other hand, in the bare plates of Sample Nos. 3 and 4 of Comparative Examples, the alloy components are within the scope of the present invention, but the condition of the intermetallic compound is outside the scope of the present invention. Although good, it is clear that the ink stain resistance is poor. Further, in the base plates of sample Nos. 5 to 7 of the comparative examples, the alloy components themselves are out of the scope of the present invention, and some of the intermetallic compound conditions are out of the scope of the present invention. It is clear that either one or both of the processability and the ink stain resistance are inferior.
したがってこれらの結果から、合金成分条件と金属間
化合物条件との両者がこの発明の範囲を満たした場合に
はじめて表面処理性とインク汚れ性との両者を満足し得
ることが明らかである。Therefore, from these results, it is clear that both the surface treatment property and the ink stain property can be satisfied only when both the alloy component condition and the intermetallic compound condition satisfy the scope of the present invention.
発明の効果 以上の実施例からも明らかなように、この発明の製法
方法により得られた印刷版支持体用アルミニウム合金素
板は、合金成分組成と金属間化合物の晶出状況とが敵切
に規制されているため、表面処理性が良好であって粗面
化処理、特に電気化学的粗面化処理によって均一な粗面
と適切な色調を得ることができ、しかも印刷版に使用し
た際に印刷中に非画像部のインク汚れが生じにくく、し
たがってオフセット印刷もしくは平版印刷用の支持体と
して用いて極めて優れたものである。EFFECTS OF THE INVENTION As is clear from the above examples, the aluminum alloy base plate for a printing plate support obtained by the production method of the present invention has an enormous difference in alloy component composition and crystallization state of intermetallic compounds. Since it is regulated, it has a good surface treatment property, and it is possible to obtain a uniform rough surface and an appropriate color tone by roughening treatment, especially electrochemical roughening treatment. It is unlikely that ink stains on the non-image area will occur during printing, and therefore it is extremely excellent for use as a support for offset printing or lithographic printing.
第１図はアルミニウム合金素板中の金属間化合物の重量
％を測定する方法の一例を示すフローチャート、第２図
はアルミニウム合金素板中の金属間化合物中におけるSi
の素板全重量に対する重量％を測定する方法の一例を示
すフローチャートである。FIG. 1 is a flow chart showing an example of the method for measuring the weight% of the intermetallic compound in the aluminum alloy base plate, and FIG. 2 is the Si in the intermetallic compound in the aluminum alloy base plate.
3 is a flowchart showing an example of a method for measuring the weight% of the total weight of the blank plate.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 滝沢 一成 静岡県榛原郡吉田町川尻4000番地 富士 写真フイルム株式会社内 (72)発明者 榊 博和 静岡県榛原郡吉田町川尻4000番地 富士 写真フイルム株式会社内 (56)参考文献 特開 昭58−221254（ＪＰ，Ａ) 特開 昭64−51992（ＪＰ，Ａ) 特開 昭60−215728（ＪＰ，Ａ) 特開 昭62−148295（ＪＰ，Ａ) 特開 昭60−5861（ＪＰ，Ａ) ─────────────────────────────────────────────────── ─── Continuation of front page (72) Inventor Issei Takizawa 4000 Kawajiri, Yoshida-cho, Haibara-gun, Shizuoka Prefecture, Fuji Photo Film Co., Ltd. Incorporated (56) Reference JP 58-221254 (JP, A) JP 64-51992 (JP, A) JP 60-215728 (JP, A) JP 62-148295 (JP, A) JP-A-60-5681 (JP, A)
Claims (1)
0.001〜0.1wt％を含有し、残部がAlおよび不可避的不純
物よりなる合金を35mm/min以上の鋳造速度でDC鍛造法に
より鋳造し、得られた鋳塊を、500℃以上でしかもSi量
との関係で 加熱温度（℃）≧1.4×103×Si％＋390 を満たす加熱温度で加熱し、さらに熱間圧延および冷間
圧延を行なって所要の板厚とするにあたり、熱間圧延と
冷間圧延との間もしくは冷間圧延の中途において350℃
以上の温度で中間焼鈍を施し、これによってかつ金属間
化合物の量が0.9wt％以下であってしかも金属間化合物
中のSiが素板全重量の0.03wt％以下であり、さらに素板
表面部における円相当径５μｍ以上のサイズの金属間化
合物の個数が素板表面部における全金属間化合物数の１
％以下の素板を得ることを特徴とする印刷版支持体用ア
ルミニウム合金素板の製造方法。1. Fe0.10 to 0.60 wt%, Si0.04 to 0.15 wt%, Cu
An alloy containing 0.001 to 0.1 wt% and the balance Al and unavoidable impurities was cast by DC forging method at a casting speed of 35 mm / min or more. The heating temperature (° C) ≥ 1.4 × 10 3 × Si% + 390 is satisfied at the heating temperature, and hot rolling and cold rolling are performed to obtain the required sheet thickness. 350 ° C during rolling or in the middle of cold rolling
Intermediate annealing was performed at the above temperature, and the amount of intermetallic compound was 0.9 wt% or less, and Si in the intermetallic compound was 0.03 wt% or less of the total weight of the raw plate. The number of intermetallic compounds having a circle equivalent diameter of 5 μm or more in 1 is 1 of the total number of intermetallic compounds on the surface of the raw plate.
% Or less of the base plate is obtained, and a method for producing an aluminum alloy base plate for a printing plate support, the method comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1316810A JP2544215B2 (en) | 1989-12-06 | 1989-12-06 | Method for producing aluminum alloy base plate for printing plate support |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1316810A JP2544215B2 (en) | 1989-12-06 | 1989-12-06 | Method for producing aluminum alloy base plate for printing plate support |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03177529A JPH03177529A (en) | 1991-08-01 |
| JP2544215B2 true JP2544215B2 (en) | 1996-10-16 |
Family
ID=18081178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1316810A Expired - Fee Related JP2544215B2 (en) | 1989-12-06 | 1989-12-06 | Method for producing aluminum alloy base plate for printing plate support |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2544215B2 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06346176A (en) * | 1993-06-08 | 1994-12-20 | Kobe Steel Ltd | Aluminum sheet for printing plate and its production |
| JP3454578B2 (en) * | 1993-08-31 | 2003-10-06 | 日本軽金属株式会社 | Aluminum alloy base plate for lithographic printing plate and method for producing the same |
| JPH07305133A (en) * | 1994-03-17 | 1995-11-21 | Fuji Photo Film Co Ltd | Supporting body for planographic printing plate and its production |
| US5795541A (en) * | 1996-01-05 | 1998-08-18 | Kabushiki Kaisha Kobe Seiko Sho | Aluminum alloy sheet for lithographic printing plates and method for manufacturing the same |
| JP2778663B2 (en) * | 1996-04-08 | 1998-07-23 | 株式会社神戸製鋼所 | Aluminum alloy plate for printing plate and method for producing the same |
| JP2778665B2 (en) * | 1996-04-11 | 1998-07-23 | 株式会社神戸製鋼所 | Aluminum alloy plate for printing plate and method for producing the same |
| JP2778662B2 (en) * | 1996-04-05 | 1998-07-23 | 株式会社神戸製鋼所 | Aluminum alloy plate for printing plate and method for producing the same |
| JP2778666B2 (en) * | 1996-04-16 | 1998-07-23 | 株式会社神戸製鋼所 | Aluminum alloy plate for printing plate and method for producing the same |
| US6337136B1 (en) * | 1998-07-30 | 2002-01-08 | Nippon Light Metal Company, Ltd. | Aluminum alloy support for lithographic printing plate and process for producing substrate for support |
| JP4925248B2 (en) * | 2005-08-30 | 2012-04-25 | 富士フイルム株式会社 | Aluminum alloy plate for lithographic printing plate and method for producing the same |
| JP5116267B2 (en) * | 2005-08-30 | 2013-01-09 | 富士フイルム株式会社 | Method for producing aluminum alloy plate for lithographic printing plate |
| JP4925246B2 (en) * | 2005-08-30 | 2012-04-25 | 富士フイルム株式会社 | Aluminum alloy plate for lithographic printing plate and method for producing the same |
| JP2007070674A (en) * | 2005-09-06 | 2007-03-22 | Fujifilm Holdings Corp | Aluminum alloy sheet for planographic printing plate, and manufacturing method therefor |
| JP4925247B2 (en) * | 2005-08-30 | 2012-04-25 | 富士フイルム株式会社 | Aluminum alloy plate for lithographic printing plate and method for producing the same |
| US20090252642A1 (en) * | 2005-08-30 | 2009-10-08 | Akio Uesugi | Aluminum alloy sheet for lithographic printing plate and method of producing the same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS581047A (en) * | 1981-06-05 | 1983-01-06 | Fuji Photo Film Co Ltd | Backing for lithographic printing plate of aluminum alloy |
| JPS58221254A (en) * | 1982-06-18 | 1983-12-22 | Furukawa Alum Co Ltd | Aluminum blank for offset printing |
| JPS605861A (en) * | 1983-06-22 | 1985-01-12 | Furukawa Alum Co Ltd | Production of base for lithographic printing plate |
| JPS60215728A (en) * | 1984-04-06 | 1985-10-29 | Sukai Alum Kk | Blank aluminum alloy plate for printing |
| JPS62148295A (en) * | 1985-12-23 | 1987-07-02 | Furukawa Alum Co Ltd | Aluminum alloy base for planographic plate and production thereof |
| JPS62146694A (en) * | 1985-12-23 | 1987-06-30 | Nippon Light Metal Co Ltd | Aluminum alloy support for planographic printing |
| DE3714059C3 (en) * | 1987-04-28 | 1995-12-07 | Vaw Ver Aluminium Werke Ag | Material in ribbon or plate form and process for its production and its use as a support for planographic printing forms |
-
1989
- 1989-12-06 JP JP1316810A patent/JP2544215B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03177529A (en) | 1991-08-01 |
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