JP2530785B2 - Method for manufacturing electric fusion joint - Google Patents
Method for manufacturing electric fusion jointInfo
- Publication number
- JP2530785B2 JP2530785B2 JP3320363A JP32036391A JP2530785B2 JP 2530785 B2 JP2530785 B2 JP 2530785B2 JP 3320363 A JP3320363 A JP 3320363A JP 32036391 A JP32036391 A JP 32036391A JP 2530785 B2 JP2530785 B2 JP 2530785B2
- Authority
- JP
- Japan
- Prior art keywords
- mandrel
- heating element
- electric
- thermoplastic resin
- fusion joint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D23/00—Producing tubular articles
- B29D23/001—Pipes; Pipe joints
- B29D23/003—Pipe joints, e.g. straight joints
- B29D23/005—Pipe joints, e.g. straight joints provided with electrical wiring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/34—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
- B29C65/3404—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint
- B29C65/342—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising at least a single wire, e.g. in the form of a winding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
- B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
- B29C66/1222—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a lapped joint-segment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
- B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
- B29C66/1224—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a butt joint-segment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/522—Joining tubular articles
- B29C66/5221—Joining tubular articles for forming coaxial connections, i.e. the tubular articles to be joined forming a zero angle relative to each other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/522—Joining tubular articles
- B29C66/5229—Joining tubular articles involving the use of a socket
- B29C66/52291—Joining tubular articles involving the use of a socket said socket comprising a stop
- B29C66/52292—Joining tubular articles involving the use of a socket said socket comprising a stop said stop being internal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/522—Joining tubular articles
- B29C66/5229—Joining tubular articles involving the use of a socket
- B29C66/52291—Joining tubular articles involving the use of a socket said socket comprising a stop
- B29C66/52294—Joining tubular articles involving the use of a socket said socket comprising a stop said stop being heated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/34—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
- B29C65/3472—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint
- B29C65/3476—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint being metallic
- B29C65/348—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint being metallic with a polymer coating
Description
【0001】[0001]
【産業上の利用分野】本発明は、液体の輸送ライン、特
に食品・医薬等の製造に用いられる水や、超純水等の輸
送ラインに好適に使用される電気融着継手の製造方法に
関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing an electric fusion joint, which is suitable for use in a liquid transportation line, particularly in a water or ultrapure water transportation line for producing foods, medicines and the like. It is a thing.
【0002】[0002]
【従来の技術】従来、ポリエチレン、ポリプロピレン等
の熱可塑性樹脂管の接合に使用される電気融着継手とし
ては、通電発熱体よりなる溶接手段が管受口の内周部に
埋設されていて、熱可塑性樹脂管を管受口に挿入後、通
電発熱体に通電してこれを発熱させ、管受口の内周部及
びこれに接する熱可塑性樹脂管の外周部の樹脂を溶融、
融着することによって、熱可塑性樹脂管と電気融着継手
とを「スリーブ接合」するものが使用されている。2. Description of the Related Art Conventionally, as an electric fusion joint used for joining a thermoplastic resin pipe of polyethylene, polypropylene or the like, welding means composed of an electric heating element is buried in the inner peripheral portion of the pipe receiving port. After inserting the thermoplastic resin tube into the pipe receiving port, energize the current-carrying heating element to generate heat, and melt the resin on the inner peripheral part of the pipe receiving port and the outer peripheral part of the thermoplastic resin pipe in contact with it.
A "sleeve joint" is used in which a thermoplastic resin tube and an electric fusion joint are fused to each other.
【0003】このような電気融着継手を製造するには、
基本的に、 金型のマンドレル(コアー)の外周面に線状の通電発
熱体を直接螺旋状に巻きつけたものを金型の外型内に挿
入し、その間に形成されたキャビティに溶融樹脂を射出
充填し、前記マンドレルを抜き去る方法(特開昭63−
71323号公報参照)、 電気融着継手の内面を形成する成形体(ボビン)を予
め成形し、ボビンの外周面に線状の通電発熱体を螺旋状
に巻きつけた後ボビンをマンドレル上にセットし、と
同様にして射出成形する方法(特開昭59−13180
号公報参照)、 の二通りの方法が行われている。In order to manufacture such an electric fusion joint,
Basically, a linear mandrel (core) with a linear electric heating element directly wound around the outer periphery of the mold is inserted into the outer mold of the mold, and the molten resin is inserted into the cavity formed between them. Injection-filling and removing the mandrel (JP-A-63-
No. 71323), a molded body (bobbin) forming the inner surface of the electric fusion joint is preliminarily molded, and a linear electric heating element is spirally wound around the outer peripheral surface of the bobbin, and then the bobbin is set on the mandrel. And injection molding in the same manner as described above (Japanese Patent Application Laid-Open No. 59-13180).
(Refer to the official gazette), and two methods are used.
【0004】上記の製造方法の中で、通電発熱体をマン
ドレルあるいはボビンに巻く工程は、いずれも通電発熱
体が円筒状の管受口の内周部のみに螺旋状に埋設された
簡単な構造であるため、マンドレルあるいはボビンを回
転させつつ、マンドレルあるいはボビン、もしくは巻付
機のドラムを軸方向に移動させることによって、容易に
目的を達成することができる。In the above manufacturing method, the step of winding the electric heating element around the mandrel or bobbin has a simple structure in which the electric heating element is spirally embedded only in the inner peripheral portion of the cylindrical pipe receiving port. Therefore, the object can be easily achieved by moving the mandrel or the bobbin or the drum of the winding machine in the axial direction while rotating the mandrel or the bobbin.
【0005】[0005]
【発明が解決しようとする課題】しかし、上記従来の電
気融着継手は、通電発熱体が電気融着継手の管受口の円
筒状内周部のみに設けられているので、熱可塑性樹脂管
の端面と電気融着継手のストッパが当接していても、熱
可塑性樹脂管あるいは電気融着継手の端面部の樹脂は融
着するのに充分なほど溶融されず、当接面でのいわゆる
「バット接合(突き合わせ接合)」は不完全な状態で行
われる。その結果、この突き合わせ部に樹脂の溶融不良
による間隙ができて水が滞留し、腐敗や細菌の生息・増
殖によって水質が低下する。このため、食品・医薬・半
導体等の製造ライン等、きわめて純度の高い水質が要求
される用途には、上記従来のような電気融着継手を使用
することは不可能であった。However, in the above-mentioned conventional electric fusion joint, since the electric heating element is provided only on the cylindrical inner peripheral portion of the pipe receptacle of the electric fusion joint, a thermoplastic resin pipe is provided. Even if the end surface of the electric fusion joint is in contact with the stopper of the electric fusion joint, the resin at the end surface portion of the thermoplastic resin pipe or the electric fusion joint is not melted enough to cause fusion, and the so-called " The butt joint (butt joint) is performed in an incomplete state. As a result, a gap is formed in the abutting portion due to poor melting of the resin, water is retained, and the water quality is deteriorated due to putrefaction and inhabitation / proliferation of bacteria. For this reason, it has been impossible to use the above-described conventional electric fusion splicing joints in applications such as production lines for foods, pharmaceuticals, semiconductors, etc., where extremely high quality water is required.
【0006】そこで発明者は、このようなきわめて高純
度の水を取扱う用途に使用可能な電気融着継手を提案し
た(平成3年特許願第250647号)。この新規な電
気融着継手は、管受口の内周部のみならずストッパにも
通電発熱体が埋設されていて、スリーブ接合は勿論、当
接面でのバット接合も完全に行われることを特徴とする
ものである。Therefore, the inventor has proposed an electric fusion splicing joint which can be used for handling such extremely high-purity water (Japanese Patent Application No. 250647 in 1991). In this new electric fusion joint, the electric heating element is embedded not only in the inner peripheral portion of the pipe receiving port but also in the stopper, and not only the sleeve joining but also the butt joining at the abutting surface is completely performed. It is a feature.
【0007】しかるに、この新規な電気融着継手の場
合、ストッパにも通電発熱体が埋設されているために、
従来の電気融着継手と異なり、ストッパ部分で通電発熱
体を電気融着継手の軸と垂直な面内で渦巻き状に巻付け
ることが必要であるが、前記従来の製造方法では不可能
であった。However, in the case of this new electric fusion-bonding joint, since the electric heating element is buried in the stopper,
Unlike the conventional electric fusion joint, it is necessary to wind the energization heating element in a spiral shape in the plane perpendicular to the axis of the electric fusion joint at the stopper portion, but this is not possible with the conventional manufacturing method. It was
【0008】本発明は、このような問題点に鑑みてなさ
れたものであり、上記の新規な電気融着継手の製造方法
を提供することを目的とするものである。The present invention has been made in view of the above problems, and an object of the present invention is to provide a method for manufacturing the above-mentioned novel electric fusion joint.
【0009】[0009]
【課題を解決するための手段】上記の目的を達成するた
めに、本発明の電気融着継手の製造方法は、熱可塑性樹
脂からなる管受口の内周部及びストッパに通電発熱体が
埋め込まれた電気融着継手を製造する方法であって、 熱可塑性樹脂の電気絶縁層で被覆された通電発熱体
を、軸方向に分割される一対のマンドレルによって形成
されるストッパ部成形環状溝に、該環状溝の底部からマ
ンドレルの外周面の高さまで巻き重ねる工程、 上記通電発熱体を、マンドレルの外周面に螺旋状に
巻く工程、 上記通電発熱体を巻きつけたマンドレルを金型内に
固定し、上記マンドレルと外型で形成されるキャビティ
に、溶融した熱可塑性樹脂を射出充填する工程、 金型を開いて製品の電気融着継手を取り出し、マン
ドレルを抜く工程、 を含むことを要旨とするものである。In order to achieve the above object, in the method for manufacturing an electric fusion joint of the present invention, an electric heating element is embedded in an inner peripheral portion of a pipe receiving port made of a thermoplastic resin and a stopper. A method for manufacturing an electric fusion-bonded joint, wherein an electric heating element covered with an electric insulating layer of a thermoplastic resin is formed in a stopper portion molding annular groove formed by a pair of axially divided mandrels, A step of winding from the bottom of the annular groove to the height of the outer peripheral surface of the mandrel, a step of spirally winding the electric heating element on the outer peripheral surface of the mandrel, and fixing the mandrel wound with the electric heating element in a mold. , A step of injecting and filling a molten thermoplastic resin into the cavity formed by the mandrel and the outer mold, a step of opening the mold to take out the electric fusion joint of the product, and pulling out the mandrel are summarized. It is intended to.
【0010】また、通電発熱体を一対のマンドレルによ
って形成されるストッパ部成形環状溝の側壁に沿って巻
き重ねる方法として、一対のマンドレルによって形成さ
れるストッパ部成形環状溝に支持リングを装着し、該支
持リングとマンドレルによって形成される環状隙間に、
上記の通電発熱体を巻き重ねることを要旨とするもので
ある。Further, as a method of winding the electric heating element along the side wall of the stopper portion forming annular groove formed by the pair of mandrels, a support ring is attached to the stopper portion forming annular groove formed by the pair of mandrels. In the annular gap formed by the support ring and the mandrel,
The gist of the present invention is to wind up the above-mentioned energization heating element.
【0011】また、熱可塑性樹脂の射出充填工程に先立
って、上記電気絶縁層をその溶融温度以上に加熱し、表
面を溶融・融着することを要旨とするものである。本発
明に用いられる熱可塑性樹脂としては、ポリエチレン、
ポリプロピレン、ポリ塩化ビニル、ABS、ポリアミド
等の汎用熱可塑性樹脂、ポリ弗化ビニリデン、ポリエチ
レンテレフタレート、ポリブチレンテレフタレート、ポ
リフェニレンサルファイド、ポリサルファイド、ポリエ
ーテルサルフォン、ポリエーテルエーテルケトン、ポリ
イミド等の結晶性または非晶性の熱可塑性エンジニアリ
ング樹脂等が用いられるが、接合される熱可塑性樹脂管
と同じか、あるいはこれと相溶性の良い樹脂であること
が好ましい。Further, the gist of the present invention is to heat and fuse the surface of the electrically insulating layer above its melting temperature prior to the thermoplastic resin injection filling step. As the thermoplastic resin used in the present invention, polyethylene,
General-purpose thermoplastic resin such as polypropylene, polyvinyl chloride, ABS, polyamide, polyvinylidene fluoride, polyethylene terephthalate, polybutylene terephthalate, polyphenylene sulfide, polysulfide, polyether sulfone, polyether ether ketone, crystalline or non-crystalline such as polyimide A crystalline thermoplastic engineering resin or the like is used, but it is preferably the same as the thermoplastic resin pipe to be joined or a resin having a good compatibility with this.
【0012】本発明に用いられる熱可塑性樹脂の電気絶
縁層で被覆された通電発熱体(以下「被覆通電発熱体」
と称する)は、ニクロム線、炭素繊維のモノフィラメン
トあるいはその縒り線等の電熱線の周囲に、上記のよう
な熱可塑性樹脂による電気絶縁層を被覆したものであっ
て、断面形状は円形、正方形、長方形等いずれでもよ
く、押出成形(電線被覆成形)、溶融樹脂中を通過させ
る等の方法で製造することができる。An electric heating element coated with an electrically insulating layer of a thermoplastic resin used in the present invention (hereinafter referred to as "coated electric heating element").
Refers to a heating wire such as a nichrome wire, a monofilament of carbon fiber or a twisted wire thereof, which is covered with an electrically insulating layer made of the above-mentioned thermoplastic resin, and has a circular or square cross section. It may be rectangular or the like, and can be manufactured by a method such as extrusion molding (electric wire coating molding) or passing through a molten resin.
【0013】なお、本発明の方法で製造される電気融着
継手は、通電発熱体がストッパの側面(熱可塑性樹脂管
々端の当接面)に露出して埋設されているものでもよ
く、また、ストッパの巾の中心付近の肉内に埋設されて
いるものでもよい。The electric fusion joint manufactured by the method of the present invention may be one in which the electric heating element is exposed and embedded in the side surface of the stopper (the contact surface of the ends of the thermoplastic resin tube). Further, it may be embedded in the meat near the center of the width of the stopper.
【0014】以下、詳細については実施例の中で説明す
る。Details will be described below in the embodiments.
【0015】[0015]
【作用】二つ割りのマンドレルを組立てて電気融着継手
のストッパ部を成形する環状溝を形成し、その環状溝
に、電気融着継手の軸と垂直方向に、環状溝の底部から
マンドレルの外周面の高さまで被覆通電発熱体を渦巻き
状に巻き重ねることによって、電気融着継手のストッパ
部に埋設される通電発熱体を配設することができる。電
熱線は周囲に熱可塑性樹脂の電気絶縁層で被覆された被
覆通電発熱体を巻くので、裸の電熱線が接触して短絡を
おこすことがない。Function: Assembling the mandrel into two parts to form an annular groove for forming the stopper portion of the electric fusion joint, and in the annular groove, in the direction perpendicular to the axis of the electric fusion joint, from the bottom of the annular groove to the outer peripheral surface of the mandrel. By winding the coated electric heating element in a spiral shape up to the height of, the electric heating element embedded in the stopper portion of the electric fusion joint can be arranged. Since the heating wire is wrapped around the energized heating element covered with an electrically insulating layer of thermoplastic resin, a bare heating wire does not come into contact with the heating wire to cause a short circuit.
【0016】また、上記環状溝内に支持リングを装着し
て環状溝の側壁と支持リングの間に環状隙間を設け、こ
の環状隙間に被覆通電発熱体を渦巻き状に巻き重ねるよ
うにしたので、被覆通電発熱体の巾に合わせて巻き重ね
のための環状隙間巾を適正に保つことができ、巻き作業
を容易に行うことができる。Further, since the support ring is mounted in the annular groove, an annular gap is provided between the side wall of the annular groove and the support ring, and the coated electric heating element is spirally wound in the annular gap. The annular gap width for winding can be appropriately maintained according to the width of the coated electric heating element, and the winding operation can be easily performed.
【0017】また、熱可塑性樹脂の射出充填工程に先立
って電気絶縁層をその溶融温度以上に加熱し、表面を溶
融・融着することによって被覆通電発熱体はマンドレル
上で一定の形状に保たれ、熱可塑性樹脂射出充填の際の
射出圧によって移動したり、形崩れすることがない。Prior to the thermoplastic resin injection filling step, the electrically insulating layer is heated to a temperature above its melting temperature to melt and fuse the surface, whereby the coated electric heating element is kept in a constant shape on the mandrel. Also, it does not move or lose its shape due to the injection pressure at the time of thermoplastic resin injection filling.
【0018】[0018]
【実施例】以下、本発明を、実施例により図面を参照し
て説明する。図1は、本発明によって製造された電気融
着継手の実施例を示す断面図であって、概ね円筒状の電
気融着継手1には、両側の管受け口2a,2bの内周部
及びストッパ3の両側面、即ち熱可塑性樹脂管々端の当
接面の近傍に、通電発熱体4が埋設されていて、その両
端は端子5,5に接続されている。より詳しく説明する
と、通電発熱体4は、左の管受け口2a側と右の管受け
口2b側とでは反対方向に螺旋状に巻かれており、また
ストッパ3の両側面近傍では、両側面に沿ってストッパ
3の内面付近から管受け口2a,2bの内周部まで、渦
巻き状に巻かれている。そして通電発熱体4の渡り線部
41がストッパ3の一箇所を横切って、左の管受け口2
a側から、右の管受け口2b側へ連続した構造となって
いる。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below with reference to the drawings by embodiments. FIG. 1 is a cross-sectional view showing an embodiment of an electric fusion joint manufactured according to the present invention, in which a substantially cylindrical electric fusion joint is provided with inner peripheral portions of tube receiving ports 2a and 2b on both sides and stoppers. An energization heating element 4 is embedded in both side surfaces of 3, that is, in the vicinity of the contact surfaces of the ends of the thermoplastic resin tube, and both ends thereof are connected to terminals 5 and 5. More specifically, the electric heating element 4 is spirally wound in the opposite direction on the left pipe receiving port 2a side and the right pipe receiving port 2b side, and in the vicinity of both side faces of the stopper 3, along the both side faces. Spirally wound from the vicinity of the inner surface of the stopper 3 to the inner peripheral portions of the pipe receiving ports 2a and 2b. Then, the crossover portion 41 of the electric heating element 4 crosses one portion of the stopper 3 and the left pipe receiving port 2
The structure is continuous from the a side to the right pipe receiving port 2b side.
【0019】次に、本発明に使用する主な製造装置につ
いて説明する。図2は図1の電気融着継手1の製造方法
に使用されるマンドレルと支持リングの組立体の説明
図、図3は支持リングの説明図である。Next, the main manufacturing equipment used in the present invention will be described. FIG. 2 is an explanatory view of an assembly of a mandrel and a support ring used in the method for manufacturing the electric fusion joint 1 of FIG. 1, and FIG. 3 is an explanatory view of the support ring.
【0020】図2において、一対の鋼製のマンドレル6
は、軸方向に左右二つ割りとされたマンドレル半体6
a,6bを連結して組立てられている。マンドレル半体
6a,6bには、これらを連結及び解体するためのボル
ト・ナット等の接続手段、ガイドピン等の位置決め手段
が設けられているが、図では省略されている。In FIG. 2, a pair of steel mandrels 6 are provided.
Is the mandrel half 6 divided into left and right in the axial direction.
It is assembled by connecting a and 6b. The mandrel halves 6a and 6b are provided with connecting means such as bolts and nuts for connecting and disassembling them and positioning means such as guide pins, but they are omitted in the figure.
【0021】マンドレル半体6a,6bの外周面6s,
6sは、電気融着継手1の管受け口2a,2bを成形す
るために概ね円筒状に形成されている。また、マンドレ
ル半体6aと6bが突合わせ接続されることによって、
図1に示される電気融着継手1のストッパ3を成形する
ストッパ部成形環状溝7が形成され、ストッパ部成形環
状溝7の底部7c、即ちマンドレル半体6aの最小外径
部には支持リング8が固定されている(但し、図2では
支持リング8の上側半分のみが示されている)。The outer peripheral surfaces 6s of the mandrel halves 6a, 6b,
6s is formed in a substantially cylindrical shape in order to form the tube receiving ports 2a, 2b of the electric fusion joint 1. In addition, since the mandrel halves 6a and 6b are butt-connected,
A stopper portion forming annular groove 7 for forming the stopper 3 of the electric fusion joint 1 shown in FIG. 1 is formed, and a support ring is formed on the bottom portion 7c of the stopper portion forming annular groove 7, that is, the minimum outer diameter portion of the mandrel half 6a. 8 is fixed (although only the upper half of the support ring 8 is shown in FIG. 2).
【0022】支持リング8は鋼、真鍮等の金属で作られ
ていて、図3に示されるように、直径方向に二つ割りの
支持リング半体8a,8bよりなり、突起と穴による嵌
合、ねじ、その他適当な接続手段で相互に接続及び解体
でき、且つマンドレル半体6aのストッパ部成形環状溝
7の底部7cに固定できるように形成されている。ま
た、支持リング半体8a,8bを接続した時に、一方の
合わせ面の全長にわたり、被覆通電発熱体10が通過可
能な隙間9が形成されている。更に、支持リング8をマ
ンドレル6に固定した時に、ストッパ部成形環状溝7の
側壁7a,7bと支持リング8の両側面によって形成さ
れる二つの環状隙間Ha,Hb内には被覆通電発熱体が
収容でき、しかも被覆通電発熱体と環状隙間Ha,Hb
の間には「遊び」があまりないことが肝要である。この
ため、支持リング8の巾rは、ストッパ部成形環状溝7
の巾をh、被覆通電発熱体の断面の巾をmとすると、h
−2mよりも若干小さい寸法に形成されている。The support ring 8 is made of a metal such as steel or brass, and as shown in FIG. 3, it is composed of support ring halves 8a and 8b which are diametrically divided into two parts. It is formed so that they can be connected to each other and disassembled by other suitable connecting means and can be fixed to the bottom portion 7c of the stopper-forming annular groove 7 of the mandrel half 6a. Further, when the support ring halves 8a and 8b are connected, a gap 9 through which the coated electric heating element 10 can pass is formed over the entire length of one mating surface. Further, when the support ring 8 is fixed to the mandrel 6, the coating energization heating element is present in the two annular gaps Ha, Hb formed by the side walls 7a, 7b of the stopper portion forming annular groove 7 and both side surfaces of the support ring 8. It can be accommodated, and furthermore, the coated electric heating element and the annular gaps Ha, Hb
It is essential that there is not much "play" between the two. Therefore, the width r of the support ring 8 is determined by the stopper portion forming annular groove 7
Where h is the width and m is the width of the cross-section of the energized heating element, h
-It is formed in a size slightly smaller than -2 m.
【0023】かくして、ストッパ部成形環状溝7の側壁
7a,7b、底部7c及び支持リング8の両側面によっ
て二つの環状隙間Ha,Hbが形成され、支持リング8
の隙間9によって連絡されている。Thus, the two annular gaps Ha and Hb are formed by the side walls 7a and 7b of the stopper-forming annular groove 7, the bottom portion 7c and both side surfaces of the support ring 8, and the support ring 8 is formed.
They are communicated by the gap 9.
【0024】次に、被覆通電発熱体を巻く方法につき説
明する。図4は、マンドレル6と支持リング8の組立体
に被覆通電発熱体10を巻いた状態を示す説明図であ
る。Next, a method of winding the coated electric heating element will be described. FIG. 4 is an explanatory view showing a state in which the coated electric heating element 10 is wound around the assembly of the mandrel 6 and the support ring 8.
【0025】上記のようにして組立てられたマンドレル
6と支持リング8の組立体を巻線機Mに装着し、巻線機
Mの左右2台のドラムの間に掛け渡した被覆通電発熱体
10の中央部を、支持リング8の隙間9に挿入し、巻線
機によって上記のマンドレル6と支持リング8の組立体
を1/2回転させると、被覆通電発熱体10は隙間9内
をストッパ部成形環状溝7の底部7cに達して前記の渡
り線部41が形成される。引き続きマンドレル6と支持
リング8の組立体を回転させると、被覆通電発熱体10
は二つの環状隙間Ha,Hb内で底部7cからストッパ
部成形環状溝7の側壁7a,7bに沿ってマンドレル6
の外周面6s,6sの高さまで巻き重ねられる。The assembly of the mandrel 6 and the support ring 8 assembled as described above is mounted on the winding machine M, and the coated electric heating element 10 is provided between the two drums on the left and right of the winding machine M. When the central portion of the above is inserted into the gap 9 of the support ring 8 and the assembly of the mandrel 6 and the support ring 8 is rotated by 1/2 by the winding machine, the coated energization heat generating element 10 has a stopper portion inside the gap 9. The crossover portion 41 is formed by reaching the bottom portion 7c of the molding annular groove 7. When the assembly of the mandrel 6 and the support ring 8 is subsequently rotated, the coated electric heating element 10
In the two annular gaps Ha, Hb along the side walls 7a, 7b of the stopper forming annular groove 7 from the bottom 7c.
Is wound up to the height of the outer peripheral surfaces 6s, 6s.
【0026】被覆通電発熱体10が環状隙間Ha,Hb
内で巻き重ねられて外周面6s,6sの高さに達する
と、巻線機の2台のドラムを外周面6s,6sに沿って
両端(左右)方向へ一定の速度で移動させて、被覆通電
発熱体10を外周面6s,6sに所定のピッチで所定の
巻き数螺旋状に巻付け、しかる後巻き動作を停止し、両
端子に接続し固定する。The coated electric heating element 10 has annular gaps Ha, Hb.
When it reaches the height of the outer peripheral surfaces 6s, 6s after being wound inside, the two drums of the winding machine are moved along the outer peripheral surfaces 6s, 6s at both ends (left and right) at a constant speed to cover. The energization heating element 10 is wound around the outer peripheral surfaces 6s, 6s in a predetermined number of turns in a spiral shape, after which the winding operation is stopped, and the terminals are connected and fixed.
【0027】上記のようにして巻付けられた被覆通電発
熱体10は、溶融樹脂の射出圧によって移動したり形崩
れすることがないように、電気融着継手1成形のため熱
可塑性樹脂を射出充填する工程に先立って、被覆通電発
熱体10の電気絶縁層をその溶融温度以上に加熱し、表
面を溶融・融着することが極めて好ましく、また、被覆
通電発熱体10を巻き終わったマンドレル6と支持リン
グ8の組立体から支持リング8を取り去る前に行うこと
が好ましい。The coated electric heating element 10 wound as described above injects a thermoplastic resin for molding the electric fusion joint 1 so that it does not move or lose its shape due to the injection pressure of the molten resin. Prior to the step of filling, it is extremely preferable to heat the electric insulating layer of the coated electric heating element 10 to a melting temperature or higher to melt and fuse the surface, and the mandrel 6 after the coated electric heating element 10 has been wound. And preferably before removing the support ring 8 from the support ring 8 assembly.
【0028】その方法としては、被覆通電発熱体10の
電気絶縁層を形成する熱可塑性樹脂の溶融温度以上に、
マンドレル6の表面、特にストッパ部成形環状溝7の側
壁7a,7b部分の表面を、予熱しておいて巻く、加熱
しながら巻く、被覆通電発熱体10の表面を熱風等で加
熱しながら巻く、あるいは被覆通電発熱体10を巻き終
わった後(金型に装入する前)に被覆通電発熱体10に
通電して加熱する、等があげられる。As a method for this, at a temperature not lower than the melting temperature of the thermoplastic resin forming the electric insulating layer of the coated electric heating element 10,
The surface of the mandrel 6, in particular, the surfaces of the side walls 7a and 7b of the stopper-forming annular groove 7 are preheated and wound, and wound while heating, and the surface of the coated electric heating element 10 is wound while heating with hot air or the like. Alternatively, it is possible to energize the coated energization heating element 10 to heat it after the coated energization heating element 10 has been wound (before charging into the mold).
【0029】次いで、このようにして被覆通電発熱体1
0が巻き付けられ、電気絶縁層の表面が溶融・融着され
たマンドレル6と支持リング8の組立体から支持リング
8を取り去り、図5のように、軸を含む面で二つ割り構
造とされた金型の外型11内に装入し、被覆通電発熱体
10を巻き付けたマンドレル6と外型11で形成される
キャビティC内に溶融した熱可塑性樹脂を注入孔12よ
り射出充填し、次いで冷却固化し、外型11を型開きし
てマンドレル6が挿入されたままの電気融着継手1を取
り出し、しかる後マンドレル6をマンドレル半体6aと
6bとに解体して取り去り、製品を得る。なお、外型1
1には端子5,5を成形するためのスリーブ13,13
が装着されているが、樹脂を射出充填後に取り去られ
る。Then, in this manner, the coated electric heating element 1
The support ring 8 is removed from the assembly of the mandrel 6 and the support ring 8 in which the surface of the electrical insulation layer is melted and fused, and the metal having a structure divided into two in the plane including the shaft is formed as shown in FIG. The molten thermoplastic resin is injected into the cavity C formed by the mandrel 6 around which the energization heating element 10 is wound around and the outer mold 11 from the injection hole 12 and then solidified by cooling. Then, the outer mold 11 is opened to take out the electric fusion splicing joint 1 in which the mandrel 6 is still inserted, and then the mandrel 6 is disassembled into mandrel halves 6a and 6b and removed to obtain a product. Outer mold 1
1, sleeves 13, 13 for molding the terminals 5, 5
Is attached, but is removed after injection filling the resin.
【0030】上記の実施例では、支持リング8を金属製
としたが、支持リング8を電気融着継手1と同じ、ある
いはこれと相溶性の良い熱可塑性樹脂製のものとして、
マンドレル6に固定したまま取り去ることなく溶融樹脂
を射出充填し、電気融着継手1中に埋め込んでしまうよ
うにしてもよい。In the above embodiment, the support ring 8 is made of metal. However, the support ring 8 is made of the same thermoplastic resin as the electric fusion joint 1 or a thermoplastic resin having good compatibility therewith.
The molten resin may be injected and filled without being removed while being fixed to the mandrel 6 and embedded in the electric fusion joint 1.
【0031】また、熱可塑性樹脂製とするとともに、図
3のような二つ割り構造でなく、図6に示されるように
ストッパ部成形環状溝7の巾hより若干長いボス81a
と、隙間9aを持つ一体構造としてもよい。このような
構造とすることによって、ボス81aをマンドレル半体
6a,6bで挟んで固定することができ、また、環状隙
間Ha,Hbの巾も均一且つ容易に設定することができ
る。Further, the boss 81a is made of a thermoplastic resin and is not a two-divided structure as shown in FIG. 3, but is slightly longer than the width h of the stopper portion forming annular groove 7 as shown in FIG.
And a gap 9a may be formed as an integral structure. With such a structure, the boss 81a can be sandwiched and fixed by the mandrel halves 6a and 6b, and the widths of the annular gaps Ha and Hb can be set uniformly and easily.
【0032】また、図2のマンドレルは、平滑な外面を
持った円筒状のものとしたが、被覆通電発熱体10の巻
付けを容易にし、あるいは射出充填時に溶融樹脂の射出
圧によって被覆通電発熱体10が動くのを防ぐ目的で、
円筒面に所定ピッチの螺旋溝を設けたものとしてもよ
い。The mandrel of FIG. 2 has a cylindrical shape with a smooth outer surface, but it facilitates winding of the energized coating heating element 10 or the energization heating of the coating by injection pressure of the molten resin during injection filling. In order to prevent the body 10 from moving,
A spiral groove having a predetermined pitch may be provided on the cylindrical surface.
【0033】上記の実施例は、通電発熱体がストッパの
両側面(熱可塑性樹脂管々端の当接面)近傍に埋設され
ている電気融着継手の場合について述べたが、通電発熱
体がストッパの中心付近の肉内に埋設されている電気融
着継手の場合についても、同様の製造方法で製造するこ
とができる。In the above embodiment, the electric heating element is buried in the vicinity of both side surfaces of the stopper (contact surfaces of the ends of the thermoplastic resin tube), but the electric heating element is The same manufacturing method can be applied to the case of the electric fusion joint embedded in the meat near the center of the stopper.
【0034】[0034]
【発明の効果】以上の説明から明らかなように、本発明
の電気融着継手の製造方法によれば、管受け口の内周部
だけでなく、ストッパにも通電発熱体が埋設された電気
融着継手の製造が容易にでき、きわめて高純度の水を取
扱う用途等に適した電気融着継手の製造等に利用でき
る。As is apparent from the above description, according to the method of manufacturing the electric fusion joint of the present invention, the electric fusion member in which the electric heating element is embedded not only in the inner peripheral portion of the pipe receiving port but also in the stopper is provided. It is possible to easily manufacture a fusion splicing joint, and it can be used for manufacturing an electric fusion splicing joint suitable for use in handling extremely high-purity water.
【図1】本発明によって製造された電気融着継手の実施
例を示す断面図である。FIG. 1 is a cross-sectional view showing an embodiment of an electric fusion joint manufactured according to the present invention.
【図2】マンドレルと支持リングの組立体の説明図であ
る。FIG. 2 is an explanatory view of an assembly of a mandrel and a support ring.
【図3】支持リングの説明図である。FIG. 3 is an explanatory diagram of a support ring.
【図4】マンドレルと支持リングの組立体に被覆通電発
熱体を巻いた状態を示す説明図である。FIG. 4 is an explanatory view showing a state in which a coated electric heating element is wound around an assembly of a mandrel and a support ring.
【図5】被覆通電発熱体を巻いたマンドレルと支持リン
グの組立体を射出成形金型に装着した状態を示す説明図
である。FIG. 5 is an explanatory view showing a state in which an assembly of a mandrel wound with a coated electric heating element and a support ring is mounted on an injection molding die.
【図6】支持リングの他の実施例を示す説明図である。
(A)は正面図である。(B)は(A)のX−X線で切
断した断面図である。FIG. 6 is an explanatory view showing another embodiment of the support ring.
(A) is a front view. (B) is a sectional view taken along line XX of (A).
1 電気融着継手 2a,2b 管受口 3 ストッパ 4 通電発熱体 41 渡り線部 6 マンドレル 6a,6b マンドレル半体 6s 外周面 7 ストッパ部成形環状溝 7a,7b 側壁 7c 底部 8,81 支持リング 8a,8b 支持リング半体 81a ボス 9,9a 隙間 10 被覆通電発熱体 11 外型 Ha,Hb 環状隙間 DESCRIPTION OF SYMBOLS 1 Electrofusion joint 2a, 2b Pipe socket 3 Stopper 4 Electric heating element 41 Crossover part 6 Mandrel 6a, 6b Mandrel half 6s Outer peripheral surface 7 Stopper molding annular groove 7a, 7b Side wall 7c Bottom 8,81 Support ring 8a , 8b Support ring half body 81a Boss 9,9a Gap 10 Coated electric heating element 11 Outer type Ha, Hb Annular gap
Claims (3)
びストッパに通電発熱体が埋め込まれた電気融着継手を
製造する方法であって、 熱可塑性樹脂の電気絶縁層で被覆された通電発熱体
を、軸方向に分割される一対のマンドレルによって形成
されるストッパ部成形環状溝に、該環状溝の底部からマ
ンドレルの外周面の高さまで巻き重ねる工程、 上記通電発熱体を、マンドレルの外周面に螺旋状に
巻く工程、 上記通電発熱体を巻きつけたマンドレルを金型内に
固定し、上記マンドレルと外型で形成されるキャビティ
に、溶融した熱可塑性樹脂を射出充填する工程、 金型を開いて製品の電気融着継手を取り出し、マン
ドレルを抜く工程、 を含むことを特徴とする、電気融着継手の製造方法。1. A method of manufacturing an electric fusion joint in which an electric heating element is embedded in an inner peripheral portion of a pipe receiving port made of a thermoplastic resin and a stopper, which is coated with an electric insulating layer of a thermoplastic resin. A step of winding the energization heating element in a stopper portion forming annular groove formed by a pair of mandrels divided in the axial direction from the bottom of the annular groove to the height of the outer peripheral surface of the mandrel, Spirally winding the outer peripheral surface, fixing the mandrel wound with the electric heating element in a mold, and injecting a molten thermoplastic resin into a cavity formed by the mandrel and the outer mold by injection, A method for producing an electric fusion joint, comprising the steps of opening the mold, taking out the electric fusion joint of the product, and pulling out the mandrel.
トッパ部成形環状溝に支持リングを装着し、該支持リン
グとマンドレルによって形成される環状隙間に、熱可塑
性樹脂の電気絶縁層で被覆された通電発熱体を巻き重ね
ることを特徴とする、請求項1記載の電気融着継手の製
造方法。2. A support ring is mounted in an annular groove for forming a stopper portion formed by a pair of mandrels, and an annular gap formed by the support ring and the mandrel is coated with an electrically insulating layer of thermoplastic resin to generate heat. The method for producing an electric fusion joint according to claim 1, wherein the body is rolled up.
て、上記電気絶縁層をその溶融温度以上に加熱し、表面
を溶融・融着することを特徴とする、請求項1もしくは
2記載の電気融着継手の製造方法。3. The electricity according to claim 1, wherein the electric insulating layer is heated to a temperature equal to or higher than its melting temperature to melt and fuse the surface prior to the thermoplastic resin injection filling step. Manufacturing method of fusion spliced joint.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3320363A JP2530785B2 (en) | 1991-12-04 | 1991-12-04 | Method for manufacturing electric fusion joint |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3320363A JP2530785B2 (en) | 1991-12-04 | 1991-12-04 | Method for manufacturing electric fusion joint |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH05157190A JPH05157190A (en) | 1993-06-22 |
JP2530785B2 true JP2530785B2 (en) | 1996-09-04 |
Family
ID=18120644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3320363A Expired - Lifetime JP2530785B2 (en) | 1991-12-04 | 1991-12-04 | Method for manufacturing electric fusion joint |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2530785B2 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5466916A (en) * | 1993-09-24 | 1995-11-14 | Hidec Co., Ltd. | Method and apparatus for joint resin pipes using high-frequency electric induction heating |
DE4422372A1 (en) * | 1994-06-27 | 1996-01-04 | Gruber Alois Agru Gmbh | Process for welding plastic pipes and sleeves to carry out the process |
JP2003056782A (en) | 2001-08-09 | 2003-02-26 | Nissan Motor Co Ltd | Connecting structure between resin-made connector and resin-made tube |
DE102007042806A1 (en) * | 2007-09-07 | 2009-03-12 | Egeplast Werner Strumann Gmbh & Co. Kg | Method for welding plastic pipes |
JP2011149503A (en) * | 2010-01-22 | 2011-08-04 | Mitsui Kagaku Sanshi Kk | Electric fusion joint |
EP3019710A4 (en) | 2013-07-09 | 2017-05-10 | United Technologies Corporation | Plated polymer fan |
US10227704B2 (en) | 2013-07-09 | 2019-03-12 | United Technologies Corporation | High-modulus coating for local stiffening of airfoil trailing edges |
WO2015006487A1 (en) | 2013-07-09 | 2015-01-15 | United Technologies Corporation | Erosion and wear protection for composites and plated polymers |
EP3019711B1 (en) | 2013-07-09 | 2023-11-01 | RTX Corporation | Plated polymer nosecone |
US9789664B2 (en) * | 2013-07-09 | 2017-10-17 | United Technologies Corporation | Plated tubular lattice structure |
WO2015006438A1 (en) | 2013-07-09 | 2015-01-15 | United Technologies Corporation | Plated polymer compressor |
JP7427693B2 (en) * | 2020-01-24 | 2024-02-05 | 積水化学工業株式会社 | Electric fusion joints and fusion methods |
WO2023054699A1 (en) * | 2021-09-30 | 2023-04-06 | 積水化学工業株式会社 | Piping member and method for manufacturing piping member |
-
1991
- 1991-12-04 JP JP3320363A patent/JP2530785B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH05157190A (en) | 1993-06-22 |
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