JP2024545069A - そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス - Google Patents

そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス Download PDF

Info

Publication number
JP2024545069A
JP2024545069A JP2024533298A JP2024533298A JP2024545069A JP 2024545069 A JP2024545069 A JP 2024545069A JP 2024533298 A JP2024533298 A JP 2024533298A JP 2024533298 A JP2024533298 A JP 2024533298A JP 2024545069 A JP2024545069 A JP 2024545069A
Authority
JP
Japan
Prior art keywords
monophosphite
catalyst
ligand
hydroformylation
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2024533298A
Other languages
English (en)
Japanese (ja)
Other versions
JP2024545069A5 (https=
Inventor
アール． ラロシュ、クリストフ
Original Assignee
ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー filed Critical ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー
Publication of JP2024545069A publication Critical patent/JP2024545069A/ja
Publication of JP2024545069A5 publication Critical patent/JP2024545069A5/ja
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/186—Mono- or diamide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/10—Non-coordinating groups comprising only oxygen beside carbon or hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
JP2024533298A 2021-12-16 2022-11-02 そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス Pending JP2024545069A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202163265513P 2021-12-16 2021-12-16
US63/265,513 2021-12-16
PCT/US2022/079125 WO2023114578A1 (en) 2021-12-16 2022-11-02 Transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes

Publications (2)

Publication Number Publication Date
JP2024545069A true JP2024545069A (ja) 2024-12-05
JP2024545069A5 JP2024545069A5 (https=) 2025-10-29

Family

ID=84537018

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2024533298A Pending JP2024545069A (ja) 2021-12-16 2022-11-02 そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス

Country Status (7)

Country Link
US (1) US20240399349A1 (https=)
EP (1) EP4448171B1 (https=)
JP (1) JP2024545069A (https=)
CN (1) CN118338965A (https=)
PL (1) PL4448171T3 (https=)
WO (1) WO2023114578A1 (https=)
ZA (1) ZA202404564B (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117399073B (zh) * 2023-10-17 2025-12-02 中国海洋石油集团有限公司 一种耐水解的丙烯氢甲酰化增产异丁醛的催化剂及其应用

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3527809A (en) 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US4148830A (en) 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US4247486A (en) 1977-03-11 1981-01-27 Union Carbide Corporation Cyclic hydroformylation process
US4518809A (en) 1981-06-11 1985-05-21 Monsanto Company Preparation of pentyl nonanols
US4528403A (en) 1982-10-21 1985-07-09 Mitsubishi Chemical Industries Ltd. Hydroformylation process for preparation of aldehydes and alcohols
US4599206A (en) 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US5110990A (en) 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde
US4668651A (en) 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4774361A (en) 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
US5102505A (en) 1990-11-09 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Mixed aldehyde product separation by distillation
US5288918A (en) 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5430194A (en) 1994-06-24 1995-07-04 Union Carbide Chemicals & Plastics Technology Corporation Process for improving enantiomeric purity of aldehydes
KR970703805A (ko) 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
DE19530698A1 (de) 1995-08-21 1997-02-27 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags
US5763680A (en) 1995-12-06 1998-06-09 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed process
US5741942A (en) 1996-11-26 1998-04-21 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5932772A (en) 1998-02-02 1999-08-03 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
CA2729643C (en) 2008-07-03 2016-08-16 Dow Technology Investments Llc Process of controlling heavies in a recycle catalyst stream
CN102574878A (zh) * 2009-10-16 2012-07-11 陶氏技术投资有限责任公司 气相加氢甲酰化方法
DE102014209532A1 (de) * 2014-05-20 2015-11-26 Evonik Degussa Gmbh Neue Monophosphitliganden mit einer tert-Butyloxycarbonyl-Gruppe
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
EP3700882B1 (en) * 2017-10-25 2022-10-26 Dow Technology Investments LLC Process to reduce heavies formation in a solution comprising aldehyde compounds formed during a hydroformylation process
GB201907659D0 (en) 2019-05-30 2019-07-17 Johnson Matthey Davy Technologies Ltd Process

Also Published As

Publication number Publication date
ZA202404564B (en) 2025-12-17
EP4448171A1 (en) 2024-10-23
WO2023114578A1 (en) 2023-06-22
US20240399349A1 (en) 2024-12-05
CN118338965A (zh) 2024-07-12
EP4448171B1 (en) 2025-08-20
PL4448171T3 (pl) 2025-10-20

Similar Documents

Publication Publication Date Title
US9688598B2 (en) Hydroformylation process
JP5603407B2 (ja) 二重オープンエンド型ビスホスファイトリガンドによるヒドロホルミル化方法
JP6571652B2 (ja) ヒドロホルミル化プロセス
TWI766115B (zh) 氫甲醯化方法
JP7447116B2 (ja) ヒドロホルミル化プロセス
CA2943211A1 (en) Hydroformylation process
KR20150060714A (ko) 포스파이트 리간드를 분해에 대해 안정화시키는 방법
JP7269238B2 (ja) ヒドロホルミル化プロセスからロジウムを回収するためのプロセス
CN108698962B (zh) 将烯烃转化成醇、醚或其组合的方法
JP2024545069A (ja) そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス
JP2016503755A (ja) ヒドロホルミル化方法
JP7787809B2 (ja) ヒドロホルミル化プロセスからロジウムを回収するためのプロセス
EP4448170B1 (en) Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes

Legal Events

Date Code Title Description
RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20240614

RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20241011

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20251020

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20251020