JP2024046554A - Quality improving agent for frozen vegetables and fruits, frozen vegetables and fruits using the same, and manufacturing method therefor - Google Patents
Quality improving agent for frozen vegetables and fruits, frozen vegetables and fruits using the same, and manufacturing method therefor Download PDFInfo
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- JP2024046554A JP2024046554A JP2022152001A JP2022152001A JP2024046554A JP 2024046554 A JP2024046554 A JP 2024046554A JP 2022152001 A JP2022152001 A JP 2022152001A JP 2022152001 A JP2022152001 A JP 2022152001A JP 2024046554 A JP2024046554 A JP 2024046554A
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- fruits
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- frozen
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Abstract
Description
本発明は、冷凍青果用品質向上剤、ならびにそれを用いた冷凍青果およびその製造方法に関する。 The present invention relates to a quality improver for frozen fruits and vegetables, as well as frozen fruits and vegetables using the same and a method for producing the same.
近年、冷凍食品に対する需要がますます高くなっている。冷凍食品は、種々の食品を冷凍状態で製造、流通、販売および保存することができ、食品の長期保存が可能となっている。また、食品を急速冷凍することによって食品の鮮度を保つことも可能である。さらに、半調理食品や調理済食品の冷凍食品は、電子レンジの普及によって消費者は複雑な調理作業を行うことなく、例えば盛り付けのみで高品質の調理済の食品を味わうこともできる。 In recent years, demand for frozen foods has become increasingly high. Frozen foods allow various foods to be manufactured, distributed, sold, and stored in a frozen state, making it possible to preserve foods for a long period of time. It is also possible to maintain the freshness of food by quickly freezing it. Furthermore, with the spread of microwave ovens, consumers can enjoy high-quality cooked foods by simply plating them, without having to perform complicated cooking operations, for semi-cooked foods and frozen frozen foods.
一方、果実のような青果については、現状、冷凍食品として流通するものはまだ決して多いとは言えない。一般に果実を冷凍すると、解凍後に柔らかくなって食感が損なわれる、変色が進行して見栄えが悪くなるなどの問題が指摘されているためである。 On the other hand, as for fruits and vegetables such as fruits, it cannot be said that there are currently many fruits and vegetables that are distributed as frozen foods. This is because it has been pointed out that when fruits are frozen, they generally become soft after thawing, resulting in loss of texture, and progress in discoloration, resulting in poor appearance.
このような問題に対し、例えば、含有成分であるセロオリゴ糖の含有量を調節することにより、野菜や果実などの植物性飲食品でなる冷凍飲食品からの離水を抑制し、冷凍前後での食感や味質の変化を小さくさせることが提案されている(特許文献1)。ここで、セロオリゴ糖は、植物性の飲食品の細胞壁を安定化させるため発現すると考えられている。 To solve this problem, for example, by adjusting the content of cellooligosaccharide, which is an ingredient, it is possible to suppress syneresis from frozen foods and drinks made of plant-based foods such as vegetables and fruits, and to improve the edibility before and after freezing. It has been proposed to reduce changes in texture and taste (Patent Document 1). Here, cellooligosaccharides are thought to be expressed in order to stabilize the cell walls of plant foods and drinks.
しかし、このような技術を用いたとしても、冷凍青果における食感の低下は未だ十分に改善されたとは言い難い。当該食感の低下は、他の冷凍食品と比較して、冷凍青果の普及を妨げる大きな原因となっている。 However, even if such technology is used, it is still difficult to say that the deterioration in texture of frozen fruits and vegetables has been sufficiently improved. This decrease in texture is a major cause of hindering the spread of frozen fruits and vegetables compared to other frozen foods.
本発明は、上記問題の解決を課題とするものであり、その目的とするところは、冷凍後の食感の低下を抑制することができ、青果本来の歯切れや硬さを保持し得る、冷凍青果用品質向上剤、ならびにそれを用いた冷凍青果およびその製造方法を提供することにある。 The present invention aims to solve the above problems, and its purpose is to provide a quality improver for frozen fruits and vegetables that can suppress deterioration in texture after freezing and retain the original crispness and hardness of the fruits and vegetables, as well as frozen fruits and vegetables using the same and a method for producing the same.
本発明は、水溶性食物繊維および水不溶性食物繊維を含有する、冷凍青果用品質向上剤である。 The present invention is a quality improver for frozen fruits and vegetables that contains water-soluble dietary fiber and water-insoluble dietary fiber.
1つの実施形態では、上記水溶性食物繊維は、イヌリンおよびペクチンからなる群から選択される少なくとも1種の食物繊維である。 In one embodiment, the water-soluble dietary fiber is at least one type of dietary fiber selected from the group consisting of inulin and pectin.
1つの実施形態では、上記水不溶性食物繊維は、微生物およびパルプからなる群から選択される少なくとも1種の材料由来の食物繊維である。 In one embodiment, the water-insoluble dietary fiber is dietary fiber derived from at least one material selected from the group consisting of microorganisms and pulp.
1つの実施形態では、本発明の冷凍青果用品質向上剤はさらに、浸透圧調整助剤を含有する。 In one embodiment, the quality improver for frozen fruits and vegetables of the present invention further contains an osmotic pressure adjusting agent.
さらなる実施形態では、上記浸透圧調整助剤はフルクトース、グルコース、ラクトース、およびトレハロースからなる群から選択される少なくとも1種の糖である。 In a further embodiment, the osmolality adjusting aid is at least one sugar selected from the group consisting of fructose, glucose, lactose, and trehalose.
1つの実施形態では、本発明の冷凍青果用品質向上剤はさらに酸化防止剤を含有する。 In one embodiment, the frozen fruit and vegetable quality improver of the present invention further contains an antioxidant.
1つの実施形態では、本発明の冷凍青果用品質向上剤は冷凍用褐変性青果のために使用される。 In one embodiment, the frozen fruit and vegetable quality improver of the present invention is used for frozen browned fruit and vegetables.
1つの実施形態では、本発明の冷凍青果用品質向上剤は冷凍用褐変性果実のために使用される。 In one embodiment, the quality improver for frozen fruits and vegetables of the present invention is used for browning fruit for freezing.
本発明はまた、青果に上記冷凍青果用品質向上剤が含浸されている、冷凍青果である。 The present invention also provides frozen fruits and vegetables, in which the fruits and vegetables are impregnated with the quality improver for frozen fruits and vegetables.
本発明はまた、冷凍青果の製造方法であって、
(a)青果に、上記冷凍青果用品質向上剤を含有する処理液を付与する工程、および
(b)該処理液が付与された青果を冷凍する工程、
を含む、方法である。
The present invention also provides a method for producing frozen fruits and vegetables, comprising:
(a) a step of applying a treatment liquid containing the quality improver for frozen fruits and vegetables to the fruits and vegetables, and (b) a step of freezing the fruits and vegetables to which the treatment liquid has been applied,
A method including:
1つの実施形態では、上記(a)工程は、上記青果に上記冷凍青果用品質向上剤を含有する処理液を含浸させることにより行われる。 In one embodiment, the step (a) is performed by impregnating the fruits and vegetables with a treatment liquid containing the quality improver for frozen fruits and vegetables.
本発明によれば、解凍後の食感の低下が抑えられた冷凍青果を簡便に製造することができる。得られた冷凍青果は-18℃以下で保存可能であり、製造工場や倉庫、物流トラックでの保存に加え、家庭用冷凍庫のような一般消費者が行う保存にも適している。 According to the present invention, frozen fruits and vegetables that do not lose texture after thawing can be easily produced. The resulting frozen fruits and vegetables can be stored at temperatures below -18°C, and are suitable for storage in manufacturing plants, warehouses, and distribution trucks, as well as in home freezers and other storage facilities used by general consumers.
以下、本発明について詳述する。 The present invention will be explained in detail below.
(冷凍青果用品質向上剤)
本発明の冷凍青果用品質向上剤は、水溶性食物繊維および水不溶性食物繊維を含有する。
(Frozen fruit and vegetable quality enhancer)
The quality improver for frozen fruits and vegetables of the present invention contains water-soluble dietary fiber and water-insoluble dietary fiber.
ここで、本明細書中に用いられる用語「水溶性食物繊維」は、水に対して完全に溶解する性質を有する食物繊維、および水に完全には溶解しないが吸水してゲル化する食満繊維の両方を指していう。これに対し、本明細書中に用いられる用語「不溶性食物繊維」は、食物繊維のうち上記水溶性食物繊維を除いたものであって、例えば水に対して溶解せず、かつ吸水はするものの、ゲル化することなく、たとえ水中に添加しても水中で添加前の形態を保持し得る食物繊維を指して言う。 Here, the term "water-soluble dietary fiber" used herein refers to dietary fiber that has the property of completely dissolving in water, and dietary fiber that does not completely dissolve in water but absorbs water and gels. refers to both. On the other hand, the term "insoluble dietary fiber" used in this specification refers to dietary fibers other than the above-mentioned water-soluble dietary fibers, such as those that do not dissolve in water and absorb water. , refers to dietary fiber that can maintain its original form in water even if added to it without gelling.
水溶性食物繊維は、後述する処理液中で溶解し、青果の内部に浸透して、当該青果中の氷結晶の肥大化を抑制する役割を果たす。水溶性食物繊維の例としては、フラクタン(例えば、イヌリン、レバンおよびグラミナン、ならびにそれらの組み合わせ)、難消化性デキストリン、ポリデキストロース、グルコマンナン、ペクチンおよびアルギン酸、ならびにそれらの組み合わせが挙げられる。 The water-soluble dietary fiber dissolves in the processing solution described below, penetrates into the inside of the fruit or vegetable, and plays the role of suppressing the enlargement of ice crystals in the fruit or vegetable. Examples of water-soluble dietary fibers include fructans (eg, inulin, levan and graminan, and combinations thereof), indigestible dextrins, polydextrose, glucomannan, pectin and alginic acid, and combinations thereof.
本発明においては、後述する冷凍青果を解凍した際の軟化した食感を効果的に抑えることができるとの理由から、水溶性食物繊維はイヌリンおよびペクチン、ならびにそれらの組み合わせであることが好ましい。 In the present invention, the water-soluble dietary fiber is preferably inulin, pectin, or a combination thereof, because it can effectively suppress the softened texture when frozen fruits and vegetables are thawed, which will be described later.
イヌリンはD-フルクトースから構成される多糖類の1種であり、例えばキクイモ(Heilianthus tuberosus L.)の塊根、ダリヤ(Dahlia variabilis Desf.)の球根などのキク科植物が有する炭水化物として知られている。イヌリンはヒトの消化器では分解できず、大腸の腸内細菌叢によって代謝されるため、栄養成分表示では食物繊維として扱われている。イヌリンの分子量は、例えば520~11000、好ましくは2000~8000である。 Inulin is a type of polysaccharide composed of D-fructose, and is known as a carbohydrate found in Asteraceae plants such as the tubers of Jerusalem artichoke (Heilianthus tuberosus L.) and the bulbs of Dahlia (Dahlia variabilis Desf.). . Inulin cannot be broken down by the human digestive system and is metabolized by the intestinal flora of the large intestine, so it is treated as dietary fiber in nutritional information labels. The molecular weight of inulin is, for example, 520 to 11,000, preferably 2,000 to 8,000.
ペクチンは、植物の細胞壁や中葉に含まれる複合多糖類であって、ガラクツロン酸がα-1,4-結合したポリガラクツロン酸を主成分として含有する多糖類である。ペクチンもまたヒトの消化器では分解できず、大腸の腸内細菌叢によって代謝される。ペクチンの重量平均分子量は、例えば50,000~360,000である。ペクチンには、例えば、酸(例えば、pH3.5以下)や糖(Bx55以上)の存在によりゲル化する性質を有するHMペクチン、およびカルシウムやマグネシウムなどのミネラルでゲル化する性質を有するLMペクチンが挙げられる。本発明においては、青果(例えば果実)に含まれる糖によって容易にゲル化が進行し易いとの理由から、ペクチンはHMペクチンであることが好ましい。 Pectin is a complex polysaccharide contained in the cell walls and middle leaves of plants, and is a polysaccharide containing as a main component polygalacturonic acid in which galacturonic acid is α-1,4-linked. Pectin also cannot be broken down by the human digestive system and is metabolized by the intestinal flora of the large intestine. The weight average molecular weight of pectin is, for example, 50,000 to 360,000. Examples of pectin include HM pectin, which has the property of gelling in the presence of acids (for example, pH 3.5 or lower) or sugars (Bx55 or higher), and LM pectin, which has the property of gelling in the presence of minerals such as calcium and magnesium. Can be mentioned. In the present invention, it is preferable that the pectin is HM pectin because gelation easily progresses due to the sugars contained in fruits and vegetables (for example, fruits).
水不溶性食物繊維は、水に溶解しないかまたは水に対して難溶性の食物繊維全般を包含し、後述する冷凍青果を解凍した際に軟化した食感を与えることを抑制する役割を果たす。水不溶性食物繊維はまた、その乾燥体の自重に対して10重量%以上の水を保持することができるという特徴を有する。 The water-insoluble dietary fiber includes all dietary fibers that do not dissolve in water or are sparingly soluble in water, and plays a role in suppressing the soft texture of frozen fruits and vegetables when thawed, which will be described later. Water-insoluble dietary fibers are also characterized by being able to retain water in an amount of 10% by weight or more based on their dry weight.
水不溶性食物繊維の例としては、微生物由来の食物繊維、パルプ由来の食物繊維、不溶性βグルカン、セルロース、ヘミセルロース、リグニン、キチン、およびキトサン、ならびにそれらの組み合わせが挙げられる。 Examples of water-insoluble dietary fibers include microbial-derived dietary fiber, pulp-derived dietary fiber, insoluble beta-glucan, cellulose, hemicellulose, lignin, chitin, and chitosan, and combinations thereof.
微生物由来の食物繊維は、例えば、微生物により菌体外で産生されるもの、および/または微生物の細胞壁などを構成する成分を含み、パウダー、分散体などの任意の形態を有していてもよい。微生物由来の食物繊維の具体的な例としては、酵母、麹菌などの真菌由来の食物繊維、乳酸菌などの細菌由来の食物繊維、ならびにそれらの組み合わせが挙げられる。 Dietary fibers derived from microorganisms include, for example, those produced by microorganisms outside the cells and/or components constituting the cell walls of microorganisms, and may have any form such as powder or dispersion. . Specific examples of dietary fiber derived from microorganisms include dietary fiber derived from fungi such as yeast and koji mold, dietary fiber derived from bacteria such as lactic acid bacteria, and combinations thereof.
ここで、例えば、酵母パウダーは調味料等に使用され得る酵母エキスの製造用に使用した酵母(例えば、トルラ酵母、パン酵母、ビール酵母、および清酒酵母、ならびにそれらの組み合わせ)を加熱処理した後、粉末状に加工したものである。酵母パウダーはβ-グルカンなどで構成された細胞壁を含む粒子であり、水および油を保持し易いという性質を有する。酵母パウダーは市販により入手可能であり、食品分野における安全性が広く知られた材料である。 Here, for example, yeast powder is yeast (e.g., torula yeast, baker's yeast, brewer's yeast, sake yeast, and combinations thereof) used for producing yeast extract that can be used in seasonings, etc., which is then heat-treated and processed into a powder form. Yeast powder is a particle containing a cell wall composed of β-glucan and the like, and has the property of easily retaining water and oil. Yeast powder is commercially available, and is a material whose safety in the food industry is widely known.
パルプ由来の食物繊維は、植物由来のパルプを乾燥して粉末化したものである。パルプ由来の食物繊維の具体的な例としては、バンブーファイバー、アップルファイバー、シトラスファイバー、ビートファイバー、小麦ファイバー、オート麦ファイバー、ポテトファイバー、オート麦ファイバー、およびサトウキビファイバー、ならびにそれらの組み合わせが挙げられる。 Pulp-derived dietary fiber is obtained by drying and powdering plant-derived pulp. Specific examples of pulp-derived dietary fibers include bamboo fiber, apple fiber, citrus fiber, beet fiber, wheat fiber, oat fiber, potato fiber, oat fiber, and sugarcane fiber, and combinations thereof. .
ここで、例えば、バンブーファイバーは竹由来のパルプ部分を乾燥し粉末化したものであり、市販により入手可能であり、食品分野における安全性が広く知られている。バンブーパウダーは吸水性および吸油性に優れており、例えば、30μm~500μmの平均繊維長を有する。バンブーファイバーは市販により入手可能であり、食品分野における安全性が広く知られた材料である。 For example, bamboo fiber is made by drying and powdering the pulp portion derived from bamboo, is commercially available, and is widely known to be safe for use in the food industry. Bamboo powder has excellent water and oil absorption properties, and has an average fiber length of, for example, 30 μm to 500 μm. Bamboo fiber is commercially available, and is a material widely known to be safe for use in the food industry.
本発明においては、冷解凍時の食感の軟化抑制効果に優れ、風味への影響が少ないとの理由から、水不溶性食物繊維は酵母パウダーおよびバンブーファイバー、ならびにそれらの組み合わせであることが好ましい。 In the present invention, the water-insoluble dietary fiber is preferably yeast powder, bamboo fiber, or a combination thereof because it has an excellent effect of suppressing softening of the texture during freezing and thawing and has little effect on flavor.
水不溶性食物繊維の平均粒子径は特に限定されないが、好ましくは0.5μm~600μm、より好ましくは0.5μm~200μmである。水不溶性食物繊維がこのような範囲内の平均粒子径を有していることにより、青果の内部にまで一層浸透することができる。 The average particle size of the water-insoluble dietary fiber is not particularly limited, but is preferably 0.5 μm to 600 μm, and more preferably 0.5 μm to 200 μm. When the water-insoluble dietary fiber has an average particle size within this range, it can penetrate further into the interior of fruits and vegetables.
さらに本発明において、水不溶性食物繊維はまた、その乾燥体の自重に対して10重量%以上の水を保持することができるという特徴を有する。 Furthermore, in the present invention, the water-insoluble dietary fiber is also characterized in that it can retain 10% or more by weight of water relative to its own weight in the dry form.
水不溶性食物繊維の含有量は特に限定されないが、例えば本発明の冷凍青果用品質向上剤に含まれる上記水溶性食物繊維100質量部に対して、好ましくは0.1質量部~1000質量部、より好ましくは5質量部~200質量部である。水不溶性食物繊維の含有量が0.1質量部を下回ると、青果内部に浸透した水不溶性食物繊維の水分保持効果が十分でなく、冷解凍後に多量のドリップを生じることがある。水不溶性食物繊維の含有量が1000質量部を上回ると、水不溶性食物繊維が青果表面に多量に付着し、表面がざらざらとして食感に違和感を与えることがある。 The content of water-insoluble dietary fiber is not particularly limited, but preferably 0.1 parts by mass to 1000 parts by mass, for example, per 100 parts by mass of the water-soluble dietary fiber contained in the quality improver for frozen fruits and vegetables of the present invention. More preferably, it is 5 parts by mass to 200 parts by mass. If the content of water-insoluble dietary fiber is less than 0.1 part by mass, the water-insoluble dietary fiber that has penetrated into the fruit or vegetables will not have a sufficient moisture retention effect, and a large amount of drip may occur after freezing and thawing. When the content of water-insoluble dietary fiber exceeds 1000 parts by mass, a large amount of water-insoluble dietary fiber adheres to the surface of the fruits and vegetables, which may make the surface rough and give an unpleasant texture.
本発明の冷凍青果用品質向上剤はまた、浸透圧調整助剤を含有していてもよい。 The frozen fruit and vegetable quality improver of the present invention may also contain an osmotic pressure adjusting aid.
浸透圧調整助剤は、本発明の冷凍青果用品質向上剤を含む処理液と処理される青果との間の浸透圧の差を利用して、処理液から青果への有効成分(例えば、上記イヌリンおよび/または水不溶性食物繊維)の移動および含浸を助ける役割を果たす。浸透圧調整助剤の例としては、フルクトース、グルコース、ラクトース、トレハロース、還元水飴、粉末還元水飴、イソマルトオリゴ糖、マルトース、ソルビトール、マルチトール、キシロース、スクロース、パラチノース、ガラクトースおよびデキストリン、ならびにそれらの組み合わせが挙げられる。より効果的に有効成分の移動および含浸を行うことができるとの理由から、浸透圧調整助剤はフルクトース、グルコース、ラクトース、およびトレハロース、ならびにそれらの組み合わせであることが好ましい。 The osmotic pressure adjustment aid utilizes the difference in osmotic pressure between the processing liquid containing the quality improver for frozen fruits and vegetables of the present invention and the processed fruits and vegetables, and transfers the active ingredients from the processing liquid to the fruits and vegetables (for example, the above-mentioned It plays a role in assisting the transfer and impregnation of inulin and/or water-insoluble dietary fiber). Examples of osmotic pressure adjusting agents include fructose, glucose, lactose, trehalose, reduced starch syrup, powdered reduced starch syrup, isomaltooligosaccharides, maltose, sorbitol, maltitol, xylose, sucrose, palatinose, galactose and dextrin, and combinations thereof. can be mentioned. Preferably, the osmotic pressure adjusting agent is fructose, glucose, lactose, trehalose, or a combination thereof, since the active ingredient can be transferred and impregnated more effectively.
浸透圧調整助剤の含有量は特に限定されないが、例えば本発明の冷凍青果用品質向上剤に含まれる上記水溶性食物繊維100質量部に対して、好ましくは1質量部~5000質量部、より好ましくは5質量部~1000質量部である。浸透圧調整助剤の含有量が1質量部を下回ると、水溶性食物繊維の青果への浸透が十分でなく、冷解凍時の食感改善効果が弱まることがある。浸透圧調整助剤の含有量が5000質量部を上回ると、浸透圧によって青果の水分が奪われ、食感を損なうことがある。 The content of the osmotic pressure adjusting aid is not particularly limited, but is preferably 1 to 5,000 parts by mass, and more preferably 5 to 1,000 parts by mass, per 100 parts by mass of the water-soluble dietary fiber contained in the frozen fruit and vegetable quality improver of the present invention. If the content of the osmotic pressure adjusting aid is less than 1 part by mass, the water-soluble dietary fiber may not penetrate sufficiently into the fruit and vegetable, and the texture improving effect upon cold thawing may be weakened. If the content of the osmotic pressure adjusting aid exceeds 5,000 parts by mass, moisture may be removed from the fruit and vegetable by osmotic pressure, causing a loss of texture.
本発明の冷凍青果用品質向上剤はまた、酸化防止剤を含有していてもよい。 The frozen fruit and vegetable quality improver of the present invention may also contain an antioxidant.
酸化防止剤は、食品工業において一般に使用されるものであり、後述する冷凍青果の保存中の変色を抑制する役割を果たす。酸化防止剤の例としては、アルコルビン酸、アスコルビン酸ナトリウム、アスコルビン酸カルシウム、精製塩、エリソルビン酸、エリソルビン酸ナトリウム、カテキン、ジブチルヒドロキシトルエン、トコフェロール、ブチルヒドロキシアニソール、アスコルビン酸パルミチン酸エステル、アスコルビン酸ステアリン酸エステル、チャ抽出物、没食子酸、フェルラ酸、ローズマリー抽出物、ブドウ種子抽出物、セージ抽出物、クローブ抽出物、ミックストコフェロール、ルチン、クエルセチン、ヒマワリ種子抽出物、α-リポ酸、アンヒドロフルクトースおよびオリザノール、ならびにそれらの組み合わせが挙げられる。より効果的に冷凍青果の変色を抑制することができるとの理由から、酸化防止剤は、アルコルビン酸、アスコルビン酸ナトリウム、およびアスコルビン酸カルシウム、ならびにそれらの組み合わせが好ましい。 Antioxidants are commonly used in the food industry, and play a role in suppressing discoloration during storage of frozen fruits and vegetables, which will be described later. Examples of antioxidants include ascorbic acid, sodium ascorbate, calcium ascorbate, purified salts, erythorbic acid, sodium erythorbate, catechin, dibutylated hydroxytoluene, tocopherol, butylated hydroxyanisole, ascorbate palmitate, ascorbate stearin. Acid ester, tea extract, gallic acid, ferulic acid, rosemary extract, grape seed extract, sage extract, clove extract, mixed tocopherols, rutin, quercetin, sunflower seed extract, alpha-lipoic acid, anhydro Includes fructose and oryzanol, and combinations thereof. As the antioxidant, ascorbic acid, sodium ascorbate, calcium ascorbate, and combinations thereof are preferred because they can more effectively suppress discoloration of frozen fruits and vegetables.
酸化防止剤の含有量は特に限定されないが、例えば本発明の冷凍青果用品質向上剤に含まれる上記水溶性食物繊維100質量部に対して、好ましくは5質量部~2000質量部、より好ましくは20質量部~1500質量部である。酸化防止剤の含有量が5質量部を下回ると、得られる冷凍青果に対する変色防止効果が低下し、褐変が進行易くなることがある。酸化防止剤の含有量が2000質量部を上回ると、得られる冷凍青果の味質に違和感を生じることがある。 The content of the antioxidant is not particularly limited, but is preferably 5 to 2000 parts by mass, more preferably 5 parts by mass to 100 parts by mass of the water-soluble dietary fiber contained in the quality improver for frozen fruits and vegetables of the present invention. The amount is 20 parts by mass to 1500 parts by mass. When the content of the antioxidant is less than 5 parts by mass, the effect of preventing discoloration on the frozen fruits and vegetables obtained may decrease, and browning may progress more easily. When the content of the antioxidant exceeds 2000 parts by mass, the taste of the frozen fruits and vegetables obtained may be unpleasant.
本発明の冷凍青果用品質向上剤は、上記各成分に悪影響を及ぼさない範囲において他の成分を含有していてもよい。 The quality improver for frozen fruits and vegetables of the present invention may contain other components as long as they do not adversely affect each of the above components.
他の成分の例としては、pH調整剤、乳化剤、ゲル化剤、保存料、増粘剤、安定剤、甘味料、発色剤、着色料、調味料、糖類、および加工用助剤、ならびにそれらの組み合わせが挙げられる。これら他の成分のより具体的な例としては、必ずしも限定されないが、加工デンプン、乾燥卵白、アルギン酸プロピレングリコールエステル、アルコール製剤、酢酸、クエン酸、リンゴ酸、アジピン酸、増粘多糖類(例えば、キサンタンガム、グァーガム、ペクチン、カラギナン)、乳酸カルシウム、乳化油脂、クチナシ色素、カロチノイド色素、アスパラギン酸、グリシン、プロピレングリコール、マルトース、トレハロースなどが挙げられる。他の成分の含有量は特に限定されず、当業者によって適切な量が選択され得る。 Examples of other ingredients include pH adjusters, emulsifiers, gelling agents, preservatives, thickeners, stabilizers, sweeteners, colorants, coloring agents, seasonings, sugars, and processing aids, as well as combinations thereof. More specific examples of these other ingredients include, but are not necessarily limited to, modified starch, dried egg white, propylene glycol alginate, alcohol preparations, acetic acid, citric acid, malic acid, adipic acid, thickening polysaccharides (e.g., xanthan gum, guar gum, pectin, carrageenan), calcium lactate, emulsified oils and fats, gardenia pigments, carotenoid pigments, aspartic acid, glycine, propylene glycol, maltose, trehalose, and the like. The content of the other ingredients is not particularly limited, and an appropriate amount can be selected by one skilled in the art.
本発明の冷凍青果用品質向上剤において、上記水溶性食物繊維および水不溶性食物繊維、ならびに必要に応じて添加され得る浸透圧調整助剤、酸化防止剤、および他の成分は、予め混合されたものであってもよく、あるいは各成分または一部の成分が別々に小分けされ、使用時に一緒に混合されるものであってもよい。 In the quality improver for frozen fruits and vegetables of the present invention, the water-soluble dietary fiber and water-insoluble dietary fiber, as well as the osmotic pressure adjusting aid, antioxidant, and other ingredients that may be added as necessary, may be premixed, or each ingredient or some ingredients may be divided into separate portions and mixed together at the time of use.
本発明の冷凍青果用品質向上剤は、果実、野菜などの青果を冷凍して冷凍青果を製造する際に使用される。青果は、例えば未処理の状態で冷凍すると褐変し易い青果(冷凍用褐変性青果)、特に褐変し易い果実(冷凍用褐変性果実)に対して有効である。 The quality improving agent for frozen fruits and vegetables of the present invention is used when producing frozen fruits and vegetables by freezing fruits and vegetables. The method is effective for fruits and vegetables that are easily browned when frozen in an untreated state (browned fruits and vegetables for freezing), particularly fruits and vegetables that are easily browned (browned fruits and vegetables for freezing).
果実の例としては、リンゴ、桃、ビワ、ブドウ、カリン、ナシ、マルメロ、メドラー、アンズ、ウメ、サクランボ、スモモ、アーモンド、イチョウ、クリ、クルミ、ペカン、アケビ、イチジク、カキ、キイチゴ、キウイフルーツ、グミ、クランベリー、コケモモ、ザクロ、サルナシ、スグリ、ナツメ、ニワウメ、フサスグリ、ブラックベリー、ブルーベリー、ポーポー、ラズベリー、ユスラウメ、イヨカン、ウンシュウミカン、オレンジ、スウィーティー、カボス、カラタチ、キシュウミカン、キンカン、クネンボ、グレープフルーツ、コウジ、サンボウカン、シークヮーサー、シトロン、デコポン、スダチ、ダイダイ、タチバナ、タンカン、ナツミカン、ハッサク、ハナユ、ヒュウガナツ、ブッシュカン、ブンタン、ベルガモット、ポンカン、ミカン、ユズ、ライム、レモン、オリーブ、ヤマモモ、トロピカルフルーツ、アキー、アセロラ、アテモヤ、アボカド、カニステル、カムカム、キワノ、グアバ、ココナッツ、サポジラ、スターフルーツ、タマリロ、チェリモヤ、ドラゴンフルーツ、ドリアン、ナツメヤシ、パイナップル、パッションフルーツ、バナナ、パパイヤ、ババコ、ジャックフルーツ、パンノキ、バンレイシ、ピタンガ、フェイジョア、フトモモ、ペピーノ、ホワイトサポテ、マンゴー、マンゴスチン、ミラクルフルーツ、ランブータン、リュウガン、およびライチ、それらの組み合わせが挙げられる。 Examples of fruits include apples, peaches, loquats, grapes, quinces, pears, quinces, medlars, apricots, plums, cherries, plums, almonds, ginkgos, chestnuts, walnuts, pecans, akebia, figs, persimmons, brambles, and kiwifruit. , gummy, cranberry, lingonberry, pomegranate, monkey pear, currant, jujube, Japanese plum, red currant, blackberry, blueberry, pawpaw, raspberry, Japanese citrus, Japanese perilla, Japanese mandarin orange, orange, sweetie, kabosu, Japanese mandarin orange, Japanese mandarin orange, kumquat, kunembo, Grapefruit, Koji, Samboukan, Shikwasa, Citron, Dekopon, Sudachi, Daidai, Tachibana, Tankan, Natsumikan, Hassaku, Hanayu, Hyuganut, Bushkan, Buntan, Bergamot, Ponkan, Mandarin orange, Yuzu, Lime, Lemon, Olive, Bayberry, Tropical Fruits, ackee, acerola, atemoya, avocado, canistel, camu camu, kiwano, guava, coconut, sapodilla, star fruit, tamarillo, cherimoya, dragon fruit, durian, dates, pineapple, passion fruit, banana, papaya, babaco, jackfruit, Breadfruit, anonyma, pitanga, feijoa, myrtle, pepino, white sapote, mango, mangosteen, miracle fruit, rambutan, longan, and lychee, and combinations thereof.
野菜の例としては、アズキ、イチゴ、インゲンマメ、エンドウ、エダマメ、オクラ、カボチャ、キュウリ、キワノ、ゴマ、ササゲ、シカクマメ、シロウリ、スイカ、ズッキーニ、ソラマメ、ダイズ、タマリロ、ゴーヤー、トウガラシ、トウガン、トウモロコシ、トマト、ナス、ナタマメ、ピーマン、ヘチマ、ペピーノ、マクワウリ、メロン、ユウガオ、ラッカセイ、レンズマメ、アスパラガス、ウド、コールラビ、ザーサイ、サトイモ、ジャガイモ、ショウガ、タケノコ、ニンニク、ユリ根、ヨウサイ、ラッキョウ、レンコン、ワサビ、カラシナ、キャベツ、クレソン、ケール、コマツナ、コルニッション、サイシン、サンチュ、サントウナ、シュンギク、セリ、セロリ、タアサイ、タカナ、タマネギ、チシャ、チンゲンサイ、ニラ、ノザワナ、ネギ、ハクサイ、パセリ、フキ、フダンソウ、ホウレンソウ、ミズナ、ミブナ、ミツバ、メキャベツ、ルッコラ、レタス、ハナッコリー、カブ、ゴボウ、サツマイモ、サトイモ、ジャガイモ、ダイコン、ニンジン、ヤマイモ、レンコン、アーティチョーク、カリフラワー、キク、菜の花、フキノトウ、ブロッコリー、およびミョウガ、ならびにそれらの組み合わせが挙げられる。 Examples of vegetables include azuki beans, strawberries, kidney beans, peas, edamame, okra, pumpkin, cucumber, kiwano, sesame, black-eyed peas, white bean, white bean, watermelon, zucchini, faba bean, soybean, tamarillo, bitter melon, chili pepper, chili pepper, corn, Tomatoes, eggplants, date beans, green peppers, loofahs, pepino, Japanese melons, melons, yamweed, groundnuts, lentils, asparagus, udo, kohlrabi, zha choy, taro, potatoes, ginger, bamboo shoots, garlic, lily root, Japanese cabbage, rakkyo, lotus root, Wasabi, mustard greens, cabbage, watercress, kale, komatsuna, cornichon, saisin, sardines, sardines, Japanese chard, Japanese parsley, celery, Japanese cabbage, takana, onions, chicha, bok choy, chives, white onion, green onions, Chinese cabbage, parsley, Japanese butterbur, Swiss chard, Spinach, Mizuna, Mibu, Mitsuba, Brussels sprouts, arugula, lettuce, Hanakkoli, turnip, burdock, sweet potato, taro, potato, radish, carrot, yam, lotus root, artichoke, cauliflower, chrysanthemum, rape blossoms, fukinotou, broccoli, and Japanese ginger, and Examples include combinations thereof.
本発明においては、解凍後の食感の低下を効果的に抑制することができ、かつ変色の抑制も効果的に得られるという理由から、青果は、リンゴ、桃、ビワ、およびブドウの褐変性果実であることが好ましい。 In the present invention, the fruits and vegetables are preferably browned fruits such as apples, peaches, loquats, and grapes, because this effectively prevents deterioration in texture after thawing and also effectively prevents discoloration.
このように本発明の冷凍青果用品質向上剤は、冷凍青果における食感の低下や変色を抑制することにより当該冷凍青果の品質を向上させることができる。 In this way, the frozen fruit and vegetable quality improver of the present invention can improve the quality of the frozen fruit and vegetables by suppressing deterioration in texture and discoloration of the frozen fruit and vegetables.
(冷凍青果およびその製造方法)
次に、上記冷凍青果用品質向上剤を用いて冷凍青果を得るための方法について説明する。
(Frozen fruits and vegetables and their manufacturing method)
Next, a method for obtaining frozen fruits and vegetables using the above-mentioned frozen fruits and vegetables quality improver will be described.
本発明では、まず青果に上記冷凍青果用品質向上剤を含有する処理液が付与される。 In the present invention, a treatment liquid containing the above-mentioned quality improver for frozen fruits and vegetables is first applied to the fruits and vegetables.
処理液は、水に上記冷凍青果用品質向上剤を添加されてなる液状の分散体である。 The treatment liquid is a liquid dispersion in which the above-mentioned frozen fruit and vegetable quality improver is added to water.
処理液を構成する水は、特に限定されないが、例えば、イオン交換水、蒸留水、RO水、水道水などのいずれであってもよい。処理液における冷凍青果用品質向上剤の濃度は、処理する青果の種類および量によって変動するため特に限定されないが、例えば、処理液中に含まれる上記水溶性食物繊維の含有量が、処理液の全体質量を基準として、好ましくは0.5質量%~15質量%、より好ましくは1質量%~10質量%である。本発明においては処理液がこのような濃度範囲に調製されていることにより、解凍後も良好な食感を提供することができる。 The water constituting the treatment liquid is not particularly limited, and may be, for example, ion exchange water, distilled water, RO water, tap water, or the like. The concentration of the quality improver for frozen fruits and vegetables in the treatment liquid is not particularly limited as it varies depending on the type and amount of fruits and vegetables to be treated, but for example, if the content of the water-soluble dietary fiber contained in the treatment liquid is Based on the total weight, it is preferably 0.5% to 15% by weight, more preferably 1% to 10% by weight. In the present invention, since the treatment liquid is prepared within such a concentration range, it is possible to provide a good texture even after thawing.
青果の処理液への付与は、例えば、処理液の含浸(例えば、処理液を含有する浸漬浴への青果の浸漬)、および/または処理液の噴霧によって行われる。青果内部に処理液を十分に含浸させることができるとの理由から、青果を処理液中に浸漬することが好ましい。 The application of the fruits and vegetables to the treatment liquid is performed, for example, by impregnating the fruits and vegetables with the treatment liquid (for example, immersing the fruits and vegetables in a dipping bath containing the treatment liquid) and/or by spraying the treatment liquid. It is preferable to immerse the fruits and vegetables in the treatment liquid because the inside of the fruits and vegetables can be sufficiently impregnated with the treatment liquid.
青果を処理液に浸漬する場合、処理液を含む浸漬浴の温度は、浸漬する青果の種類および量によって変動するため特に限定されないが、好ましくは3℃~15℃である。処理液を含む浸漬浴への浸漬時間もまた、浸漬する青果の種類および量によって変動するため特に限定されないが、好ましくは10秒間~24時間である。 When the fruit or vegetables are immersed in the treatment liquid, the temperature of the immersion bath containing the treatment liquid is not particularly limited as it varies depending on the type and amount of the fruit or vegetables to be immersed, but is preferably 3°C to 15°C. The immersion time in the immersion bath containing the treatment liquid is also not particularly limited as it varies depending on the type and amount of the fruit or vegetables to be immersed, but is preferably 10 seconds to 24 hours.
なお、処理液の付与にあたり、青果は予め機械作業または手作業により外皮が取り除かれていてもよく、および/または適切なサイズに切断されていてもよい。 Note that, before applying the treatment liquid, the fruits and vegetables may have their outer skins removed by mechanical or manual work and/or may be cut into appropriate sizes.
本発明においては、次に処理液が付与された青果が冷凍される。 In the present invention, the fruits and vegetables to which the treatment liquid has been applied are then frozen.
具体的には、上記処理液が付与された青果は、好ましくは適度に液切りが行われた後、例えば-18℃以下、好ましくは-25℃以下、より好ましくは-80℃~-30℃の冷凍環境下に配置される。冷凍環境下への配置は、青果の種類および量によって変動するため特に限定されないが、少なくとも1分間以上をかけて行われる。 Specifically, the fruits and vegetables to which the treatment liquid has been applied are preferably appropriately drained, and then placed in a freezing environment, for example, at or below -18°C, preferably below -25°C, and more preferably between -80°C and -30°C. The placement in the freezing environment is not particularly limited as this varies depending on the type and amount of the fruits and vegetables, but is carried out for at least one minute.
このようにして、冷凍青果を製造することができる。 In this way, frozen fruits and vegetables can be produced.
得られた冷凍青果は、例えば-18℃以下の冷凍環境下(例えば、冷凍倉庫、ストッカー)に保管され、輸送もまた同様の環境下で行われることが好ましい。 It is preferable that the obtained frozen fruits and vegetables are stored, for example, in a frozen environment of −18° C. or lower (for example, a frozen warehouse or a stocker), and that transportation is also carried out under the same environment.
冷凍青果の解凍には、食感の低下を不用意に促進させることを避けるため、例えば自然解凍が採用される。あるいは、3℃~15℃に温度調節した場所に5時間~24時間静置して解凍が行われてもよい。上記のようにして製造された冷凍青果は、冷凍前の青果が有する食感の低下を抑制またはそのまま保持することができる。 For example, natural thawing is used to thaw frozen fruits and vegetables in order to avoid inadvertently accelerating deterioration of texture. Alternatively, thawing may be carried out by leaving for 5 to 24 hours in a place whose temperature is adjusted to 3°C to 15°C. The frozen fruits and vegetables produced as described above can suppress or maintain the texture of the fruits and vegetables before freezing.
以下、実施例により本発明をより詳細に説明するが、本発明はこれらの実施例により限定されるものではない。 The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples.
実施例および比較例で使用した材料には以下の市販製品を使用した:
(1)「イヌリン」:フジ日本精糖株式会社製フジFF
(2)「HMペクチン」:三晶株式会社製GENU Pectin type BETA BI-J
(3)「酵母パウダー」:富士食品工業株式会社製モイステックスSTD
(4)「バンブーパウダー」:レッテンマイヤージャパン株式会社製VITACEL BAF90
(5)「還元水飴」:物産フードサイエンス株式会社製スイートNT
(6)「粉末還元水飴」:物産フードサイエンス株式会社製スイートP EM 50M
(7)「イソマルトオリゴ糖」:昭和産業株式会社製イソマルトオリゴ糖
(8)「デキストリンDE4」:松谷化学工業株式会社製パインデックス#100
(9)「デキストリンDE17.8」:松谷化学工業株式会社製TK-16
(10)「アップルパウダー」:レッテンマイヤージャパン株式会社製VITACEL AF401/3。
The following commercially available products were used as materials in the examples and comparative examples:
(1) "Inulin": Fuji FF manufactured by Fuji Nippon Sugar Co., Ltd.
(2) "HM pectin": GENU Pectin type BETA BI-J manufactured by Sansho Co., Ltd.
(3) "Yeast powder": Moistex STD manufactured by Fuji Food Industry Co., Ltd.
(4) "Bamboo powder": VITACEL BAF90 manufactured by Rettenmaier Japan Co., Ltd.
(5) "Reduced starch syrup": Sweet NT manufactured by Bussan Food Science Co., Ltd.
(6) "Powdered reduced starch syrup": Sweet P EM 50M manufactured by Bussan Food Science Co., Ltd.
(7) "Isomalto-oligosaccharide": Isomalto-oligosaccharide manufactured by Showa Sangyo Co., Ltd. (8) "Dextrin DE4": Pine index #100 manufactured by Matsutani Chemical Industry Co., Ltd.
(9) “Dextrin DE17.8”: TK-16 manufactured by Matsutani Chemical Industry Co., Ltd.
(10) “Apple powder”: VITACEL AF401/3 manufactured by Rettenmaier Japan Co., Ltd.
(実施例1~4および比較例1~12:製剤(E1)~(E4)および(C1)~(C12)の作製、処理液(SE1)~(SE4)および(SC1)~(SC12)の調製、ならびに冷凍リンゴ(RE1)~(RE4)および(RC1)~(RC12)の作製および評価)
以下の表1に示す材料を用いて製剤(E1)~(E4)および(C1)~(C12)を作製した。
(Examples 1 to 4 and Comparative Examples 1 to 12: Preparation of formulations (E1) to (E4) and (C1) to (C12), preparation of treatment solutions (SE1) to (SE4) and (SC1) to (SC12) preparation, and production and evaluation of frozen apples (RE1) to (RE4) and (RC1) to (RC12))
Preparations (E1) to (E4) and (C1) to (C12) were prepared using the materials shown in Table 1 below.
次いで、得られた製剤(E1)~(E4)および(C1)~(C12)を、それぞれイオン交換水中に添加して、処理液(SE1)~(SE4)および(SC1)~(SC12)を調製した。なお、処理液(SE1)~(SE4)および(SC1)~(SC12)に含まれる各材料の含有量は以下の表2に示す通りであった。 Next, the obtained formulations (E1) to (E4) and (C1) to (C12) were respectively added to ion-exchanged water to form treatment solutions (SE1) to (SE4) and (SC1) to (SC12). Prepared. The contents of each material contained in the treatment solutions (SE1) to (SE4) and (SC1) to (SC12) were as shown in Table 2 below.
上記のように調製した処理液(SE1)~(SE4)および(SC1)~(SC12)を用いて、冷凍リンゴを以下のようにして作製しかつ評価した。 Using the treatment solutions (SE1) to (SE4) and (SC1) to (SC12) prepared as described above, frozen apples were produced and evaluated as follows.
リンゴ(サンふじ)の皮および芯を除去した後、16等分にカットした。次いで、カットしたリンゴおよび上記で調製した処理液を、それらの質量比が1:2となるようにしてジッパー付きの袋に入れた。その後、カットしてリンゴが完全に処理液に浸るように袋から空気を抜き、5℃にて24時間冷蔵保管した。 After removing the skin and core of an apple (Sanfuji), the apple was cut into 16 equal pieces. Next, the cut apples and the treatment liquid prepared above were placed in a zippered bag at a mass ratio of 1:2. Thereafter, the apples were cut, air was removed from the bag so that the apples were completely immersed in the processing liquid, and the bags were stored refrigerated at 5° C. for 24 hours.
次いで、袋から取り出したリンゴを-40℃にて2時間急速冷凍し、-20℃のストッカー内で7日間冷凍保管することにより、冷凍リンゴ(RE1)~(RE4)および(RC1)~(RC12)を得た。 The apples were then removed from the bags, flash frozen at -40°C for 2 hours, and stored frozen for 7 days in a storage unit at -20°C to obtain frozen apples (RE1) to (RE4) and (RC1) to (RC12).
このようにして得られた冷凍リンゴ(RE1)~(RE4)および(RC1)~(RC12)について以下のように解凍し、評価した。 The frozen apples (RE1) to (RE4) and (RC1) to (RC12) obtained in this manner were thawed and evaluated as follows.
冷凍リンゴ(RE1)~(RE4)および(RC1)~(RC12)をストッカーから取り出し、25℃に温度調節した恒温槽に入れて2時間そのまま静置して解凍を行った。 Frozen apples (RE1) to (RE4) and (RC1) to (RC12) were taken out from the stocker, placed in a constant temperature bath controlled at 25°C, and allowed to stand for 2 hours to thaw.
解凍したリンゴを5名のパネラーが実際に食し、歯切れ(シャキシャキ感)の程度、および硬さについて以下の評価基準に従って協議により採点した。これらの冷凍リンゴに加え、処理液の浸漬を行わなかったこと以外は上記と同様にして冷凍したリンゴ(無添加区)についても同様に評価した。 Five panelists tasted the thawed apples and discussed and scored them for crispness (crunchiness) and hardness according to the following criteria. In addition to these frozen apples, apples that were frozen in the same manner as above except that they were not immersed in the treatment solution (additive-free group) were also evaluated in the same way.
<歯切れ(シャキシャキ感)>
「4点」:冷凍前のリンゴと略同等の鮮度のある歯切れ感があった。
「3点」:冷凍前のリンゴよりも僅かに劣る歯切れ感はあるものの、鮮度が低下したようには感じられなかった。
「2点」:冷凍前のリンゴよりも僅かに劣る歯切れ感はあるものの、そのまま商品として十分販売可能なものであった。
「1点」:冷凍前のリンゴよりも歯切れ感が劣っており、そのまま商品として販売することが難しいものであった。
「0点」:冷凍前のリンゴよりも明らかに歯切れ感が失われており、そのまま食することが難しいものであった。
<Crispness (crispy feeling)>
"4 points": The apple had a freshness and crispness almost equivalent to that of an apple before freezing.
"3 points": Although the crispness was slightly inferior to that of the apple before freezing, it did not seem that the freshness had decreased.
"2 points": Although the crispness was slightly inferior to that of the apple before freezing, it could be sold as a product as is.
"1 point": The crispness was inferior to that of the apple before freezing, and it was difficult to sell it as a product as it was.
"0 points": The apple had clearly lost its crispness compared to the apple before freezing, and it was difficult to eat it as it was.
<硬さ>
「4点」:冷凍前のリンゴと略同等の鮮度のある硬さがあった。
「3点」:冷凍前のリンゴよりも硬さが僅かに劣るものの、鮮度が低下したようには感じられなかった。
「2点」:冷凍前のリンゴよりも硬さが僅かに劣るものの、そのまま商品として十分販売可能なものであった。
「1点」:冷凍前のリンゴよりも硬さが劣っており、そのまま商品として販売することが難しいものであった。
「0点」:冷凍前のリンゴよりも明らかに硬さが失われており、そのまま食することが難しいものであった。
<Hardness>
"4 points": The apple had a fresh, firm texture similar to that of the apple before it was frozen.
"3 points": The apples were slightly less firm than before they were frozen, but did not appear to be any less fresh.
"2 points": The apples were slightly less firm than the apples before freezing, but were still good enough to be sold as products as they were.
"1 point": The apples were less firm than before they were frozen, making them difficult to sell as products in their original state.
"0 points": The apples had clearly lost their firmness compared to before they were frozen, and were difficult to eat as is.
<総合評価>
上記歯切れ(シャキシャキ感)および硬さの評価で得られた点数(評価点数)を合計して、以下の基準により分類した。
「最優秀」:合計点数が8点であった。
「優秀」:合計点数が6~7点であった。
「優良」:合計点数が4~5点であった。
「不良」:合計点数が2~3点であった。
「最不良」:合計点数が0~1点であった。
<Overall evaluation>
The scores (evaluation scores) obtained in the evaluation of crispness (crunchiness) and hardness were totaled and classified according to the following criteria.
"Best": Total score was 8 points.
"Excellent": Total score was 6 to 7 points.
"Excellent": The total score was 4 to 5 points.
"Poor": The total score was 2 to 3 points.
"Poorest": Total score was 0 to 1 point.
結果を表3に示す。 The results are shown in Table 3.
表1~3に示すように、実施例1~4で作製した製剤(E1)~(E4)を用いて得られた冷凍リンゴ(RE1)~(RE4)はいずれも、比較例1~12で作製した製剤(C1)~(C12)を用いて得られた冷凍リンゴ(RC1)~(RC12)と比較して、解凍後も歯切れがよくかつ硬さも良好であり、商品として十分流通に値するものであることを確認した。 As shown in Tables 1 to 3, the frozen apples (RE1) to (RE4) obtained using the formulations (E1) to (E4) produced in Examples 1 to 4 were all the same as those obtained in Comparative Examples 1 to 12. Compared to the frozen apples (RC1) to (RC12) obtained using the prepared formulations (C1) to (C12), the apples have good crispness and hardness even after thawing, and are worthy of being distributed as products. It was confirmed that
一方、比較例1~12で作製した製剤(C1)~(C12)を用いて得られた冷凍リンゴ(RC1)~(RC12)は、無添加区の冷凍リンゴと同等または略同等の「最不良」または「不良」の総合評価を受けた。 On the other hand, the frozen apples (RC1) to (RC12) obtained using the formulations (C1) to (C12) produced in Comparative Examples 1 to 12 had the same or almost the same quality as the additive-free frozen apples. ” or received an overall rating of “Poor.”
このことから、実施例1~4で作製した製剤(E1)~(E4)は、冷凍リンゴの歯切れおよび硬さを著しく向上させていることがわかる。 This shows that the formulations (E1) to (E4) prepared in Examples 1 to 4 significantly improved the crispness and hardness of frozen apples.
(実施例5~9および比較例13~19:製剤(E5)~(E9)および(C13)~(C19)の作製、処理液(SE5)~(SE9)および(SC13)~(SC19)の調製、ならびに冷凍リンゴ(RE5)~(RE9)および(RC13)~(RC19)の作製および評価)
以下の表4に示す材料を用いて製剤(E5)~(E9)および(C13)~(C19)を作製した。
(Examples 5 to 9 and Comparative Examples 13 to 19: Preparation of Formulations (E5) to (E9) and (C13) to (C19), Preparation of Treatment Solutions (SE5) to (SE9) and (SC13) to (SC19), and Preparation and Evaluation of Frozen Apples (RE5) to (RE9) and (RC13) to (RC19))
Formulations (E5) to (E9) and (C13) to (C19) were made using the materials shown in Table 4 below.
次いで、得られた製剤(E5)~(E9)および(C13)~(C19)を、それぞれイオン交換水中に添加して、処理液(SE5)~(SE9)および(SC13)~(SC19)を調製した。なお、処理液(SE5)~(SE9)および(SC13)~(SC19)に含まれる各材料の含有量は以下の表5に示す通りであった。 Next, the obtained formulations (E5) to (E9) and (C13) to (C19) were respectively added to ion-exchanged water to form treatment solutions (SE5) to (SE9) and (SC13) to (SC19). Prepared. The contents of each material contained in the treatment solutions (SE5) to (SE9) and (SC13) to (SC19) were as shown in Table 5 below.
上記のように調製した処理液(SE5)~(SE9)および(SC13)~(SC19)を用いて、上記実施例1~4と同様にして、冷凍リンゴを作製し、かつ歯切れ(シャキシャキ感)、硬さおよび総合評価について評価した。結果を表6に示す。 Using the processing solutions (SE5) to (SE9) and (SC13) to (SC19) prepared as described above, frozen apples were prepared in the same manner as in Examples 1 to 4 above, and crispy (crunchy) was obtained. , hardness and overall evaluation. The results are shown in Table 6.
表4~6に示すように、実施例5~9で作製した製剤(E5)~(E9)を用いて得られた冷凍リンゴ(RE5)~(RE9)はいずれも、比較例13~19で作製した製剤(C13)~(C19)を用いて得られた冷凍リンゴ(RC13)~(RC19)と比較して、解凍後も歯切れがよくかつ硬さも良好であり、商品として非常に優れたものであることを確認した。 As shown in Tables 4 to 6, the frozen apples (RE5) to (RE9) obtained using the formulations (E5) to (E9) prepared in Examples 5 to 9 all had good crispness and firmness even after thawing, compared to the frozen apples (RC13) to (RC19) obtained using the formulations (C13) to (C19) prepared in Comparative Examples 13 to 19, and were confirmed to be excellent products.
また、実施例5~9で作製した製剤(E5)~(E9)は、水溶性食物繊維および水不溶性食物繊維に加えて、グルコース、ラクトース、トレハロースおよびフルクトースのような浸透圧調整助剤を併用したことにより、冷凍リンゴ(RE5)~(RE9)の総合評価は、実施例1~4で作製した製剤(E1)~(E4)を用いて得られた冷凍リンゴ(RE1)~(RE4)よりも総合評価が高くなっていた。このことから、浸透圧調整助剤の併用によって、本発明の冷凍青果用品質向上剤の性能が一層高められたことがわかる。 In addition, formulations (E5) to (E9) prepared in Examples 5 to 9 contain osmotic pressure adjustment aids such as glucose, lactose, trehalose, and fructose in addition to water-soluble dietary fiber and water-insoluble dietary fiber. As a result, the overall evaluation of frozen apples (RE5) to (RE9) was higher than that of frozen apples (RE1) to (RE4) obtained using formulations (E1) to (E4) prepared in Examples 1 to 4. The overall evaluation was also high. This shows that the performance of the quality improver for frozen fruits and vegetables of the present invention was further improved by the combined use of the osmotic pressure adjustment aid.
なお、浸透圧調整助剤としてグルコースを使用した製剤(E5)および(C13)を用いて得られた冷凍リンゴ(RE5)および(RC13)はいずれも、グルコースに起因する幾分不自然な甘さが感じられた。 In addition, frozen apples (RE5) and (RC13) obtained using formulations (E5) and (C13) that use glucose as an osmotic pressure adjusting agent both have a somewhat unnatural sweetness due to glucose. was felt.
(実施例10~13:製剤(E10)~(E13)の作製、処理液(SE10)~(SE13)の調製、ならびに冷凍リンゴ(RE10)~(RE13)の作製および評価)
以下の表7に示す材料を用いて製剤(E10)~(E13)を作製した。
(Examples 10 to 13: Preparation of formulations (E10) to (E13), preparation of treatment solutions (SE10) to (SE13), and preparation and evaluation of frozen apples (RE10) to (RE13))
Formulations (E10) to (E13) were prepared using the materials shown in Table 7 below.
次いで、得られた製剤(E10)~(E13)を、それぞれイオン交換水中に添加して、処理液(SE10)~(SE13)を調製した。なお、処理液(SE10)~(SE13)に含まれる各材料の含有量は以下の表8に示す通りであった。 Next, the obtained formulations (E10) to (E13) were respectively added to ion exchange water to prepare treatment solutions (SE10) to (SE13). The contents of each material contained in the treatment liquids (SE10) to (SE13) were as shown in Table 8 below.
上記のように調製した処理液(SE10)~(SE13)を用いて、上記実施例1~4と同様にして冷凍リンゴ(RE10)~(RE13)を作製した。 Using the treatment solutions (SE10) to (SE13) prepared as described above, frozen apples (RE10) to (RE13) were produced in the same manner as in Examples 1 to 4 above.
その後、上記実施例1~4と同様にして解凍したリンゴを5名のパネラーが実際に目視観察し、色調について以下の評価基準に従って協議により採点した。また、同パネラーが実際に食して上記実施例1~4と同様にして歯切れ(シャキシャキ感)の程度、および硬さについて採点した。これらの冷凍リンゴに加え、処理液の浸漬を行わなかったこと以外は上記と同様にして冷凍したリンゴ(無添加区)についても同様に評価した。 Five panelists then visually inspected the apples that had been thawed in the same manner as in Examples 1 to 4 above, and shared a rating for color according to the following evaluation criteria. The same panelists also tasted the apples and rated their crispness (crunchiness) and hardness in the same manner as in Examples 1 to 4 above. In addition to these frozen apples, apples (without additives) that had been frozen in the same manner as above, except that they had not been immersed in the treatment solution, were also evaluated in the same manner.
<色調>
「4点」:冷凍前のリンゴと略同等の鮮度のある色調を有していた。
「3点」:冷凍前のリンゴよりも僅かに変色が確認されたものの、鮮度が低下したようには感じられなかった。
「2点」:冷凍前のリンゴよりも僅かに変色が確認されたものの、そのまま商品として十分販売可能なものであった。
「1点」:冷凍前のリンゴよりも変色が目立ち、そのまま商品として販売することが難しいものであった。
「0点」:冷凍前のリンゴよりも明らかに変色しており、そのまま食することが難しいものであった。
<Color tone>
"4 points": The apple had a fresh color tone almost equivalent to that of an apple before freezing.
"3 points": Although a slight discoloration was observed compared to the apple before freezing, it did not seem that the freshness had decreased.
"2 points": Slight discoloration was observed compared to the apple before freezing, but the apple could still be sold as a product.
"1 point": The discoloration was more noticeable than the apple before freezing, and it was difficult to sell it as a product.
"0 points": The apple was clearly discolored compared to the apple before freezing, and it was difficult to eat it as is.
結果を表9に示す。 The results are shown in Table 9.
表7~9に示すように、実施例10~13で作製した製剤(E10)~(E13)を用いて得られた冷凍リンゴ(RE10)~(RE13)はいずれも解凍後も歯切れがよくかつ硬さも良好であり、商品として非常に優れたものであることを確認した。 As shown in Tables 7 to 9, the frozen apples (RE10) to (RE13) obtained using the formulations (E10) to (E13) prepared in Examples 10 to 13 had a crisp texture even after thawing. It was confirmed that the hardness was good and that it was an excellent commercial product.
また、実施例11~13で作製した製剤(E11)~(E13)は、水溶性食物繊維、水不溶性食物繊維、および浸透圧調整助剤に加えて、アスコルビン酸、アスコルビン酸ナトリウム、およびアスコルビン酸カルシウムのような酸化防止剤を併用したことにより、冷凍リンゴ(RE11)~(RE13)の色調は、実施例10で作製した製剤(E10)を用いて得られた冷凍リンゴ(RE10)よりも優れていた。このことから、酸化防止剤の併用によって、本発明の冷凍青果用品質向上剤の性能がさらに一層高められたことがわかる。 Furthermore, the preparations (E11) to (E13) prepared in Examples 11 to 13 contained antioxidants such as ascorbic acid, sodium ascorbate, and calcium ascorbate in addition to the water-soluble dietary fiber, water-insoluble dietary fiber, and osmotic pressure adjusting aid, and as a result, the color tone of the frozen apples (RE11) to (RE13) was superior to that of the frozen apples (RE10) obtained using the preparation (E10) prepared in Example 10. This shows that the performance of the frozen fruit and vegetable quality improver of the present invention was further improved by the use of antioxidants in combination.
本発明は、例えば、食品添加剤および食品の製造分野、ならびに食品加工分野において有用である。 The present invention is useful, for example, in the field of manufacturing food additives and foods, and in the field of food processing.
Claims (11)
(a)青果に、請求項1から9のいずれかに記載の冷凍青果用品質向上剤を含有する処理液を付与する工程、および
(b)該処理液が付与された青果を冷凍する工程、
を含む、方法。 A method for producing frozen fruits and vegetables,
(a) a step of applying a treatment liquid containing the quality improver for frozen fruits and vegetables according to any one of claims 1 to 9 to fruits and vegetables, and (b) a step of freezing the fruits and vegetables to which the treatment liquid has been applied,
including methods.
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