JP2024003781A - Pulp-type desiccant and manufacturing method thereof - Google Patents
Pulp-type desiccant and manufacturing method thereof Download PDFInfo
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- 239000002274 desiccant Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 230000001954 sterilising effect Effects 0.000 claims abstract description 21
- 238000001035 drying Methods 0.000 claims abstract description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 16
- 229920006280 packaging film Polymers 0.000 claims abstract description 16
- 239000012785 packaging film Substances 0.000 claims abstract description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011780 sodium chloride Substances 0.000 claims abstract description 8
- 238000004806 packaging method and process Methods 0.000 claims abstract description 7
- 238000005520 cutting process Methods 0.000 claims abstract description 6
- 239000001110 calcium chloride Substances 0.000 claims abstract description 5
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 5
- 239000010408 film Substances 0.000 claims abstract description 5
- 239000010409 thin film Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 11
- 239000001913 cellulose Substances 0.000 claims description 10
- 229920002678 cellulose Polymers 0.000 claims description 10
- 238000004659 sterilization and disinfection Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 8
- -1 polybutylene terephthalate Polymers 0.000 claims description 6
- 230000006835 compression Effects 0.000 claims description 5
- 238000007906 compression Methods 0.000 claims description 5
- 239000008213 purified water Substances 0.000 claims description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims description 4
- 229960005070 ascorbic acid Drugs 0.000 claims description 4
- 239000011668 ascorbic acid Substances 0.000 claims description 4
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 claims description 4
- 229940075506 behentrimonium chloride Drugs 0.000 claims description 4
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 229920002050 silicone resin Polymers 0.000 claims description 4
- ALRYNTSLFYRKGF-UHFFFAOYSA-N (4-methylphenyl) octanoate Chemical compound CCCCCCCC(=O)OC1=CC=C(C)C=C1 ALRYNTSLFYRKGF-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 108010069013 Phenylalanine Hydroxylase Proteins 0.000 claims description 3
- 102100038223 Phenylalanine-4-hydroxylase Human genes 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229960001927 cetylpyridinium chloride Drugs 0.000 claims description 3
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims description 3
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 3
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 3
- BSYNRYMUTXBXSQ-FOQJRBATSA-N 59096-14-9 Chemical compound CC(=O)OC1=CC=CC=C1[14C](O)=O BSYNRYMUTXBXSQ-FOQJRBATSA-N 0.000 claims description 2
- 108010068370 Glutens Proteins 0.000 claims description 2
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 claims description 2
- 108010043005 Prolyl Hydroxylases Proteins 0.000 claims description 2
- 102000004079 Prolyl Hydroxylases Human genes 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- NJVOZLGKTAPUTQ-UHFFFAOYSA-M fentin chloride Chemical compound C=1C=CC=CC=1[Sn](C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 NJVOZLGKTAPUTQ-UHFFFAOYSA-M 0.000 claims description 2
- 235000021312 gluten Nutrition 0.000 claims description 2
- 238000009423 ventilation Methods 0.000 claims description 2
- 229940077239 chlorous acid Drugs 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 229940001474 sodium thiosulfate Drugs 0.000 claims 1
- 229960004418 trolamine Drugs 0.000 claims 1
- 238000007791 dehumidification Methods 0.000 abstract description 7
- 238000003912 environmental pollution Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 2
- 238000010793 Steam injection (oil industry) Methods 0.000 description 2
- 229960001138 acetylsalicylic acid Drugs 0.000 description 2
- 229910001919 chlorite Inorganic materials 0.000 description 2
- 229910052619 chlorite group Inorganic materials 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010981 drying operation Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- KBTJYNAFUYTSNN-UHFFFAOYSA-N [Na].OO Chemical compound [Na].OO KBTJYNAFUYTSNN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229960002218 sodium chlorite Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- SBXWFLISHPUINY-UHFFFAOYSA-N triphenyltin Chemical compound C1=CC=CC=C1[Sn](C=1C=CC=CC=1)C1=CC=CC=C1 SBXWFLISHPUINY-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Engineering & Computer Science (AREA)
- Drying Of Gases (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Packages (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Food Science & Technology (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
本発明は、除湿剤に関し、より詳しくは、木材や纎維植物で得られる天然パルプを材料として、除湿効率を向上させることができるパルプ型除湿剤、およびその製造方法に関する。 The present invention relates to a dehumidifier, and more particularly to a pulp-type dehumidifier that is made from natural pulp obtained from wood or fiber plants and can improve dehumidification efficiency, and a method for producing the same.
一般に、除湿剤は、大気中の水分を吸収して、周辺湿度を低減することができる物質で、湿気を取り除くべき場所や湿気から特定製品を保護するために広く用いられている。 In general, dehumidifiers are substances that can absorb moisture from the atmosphere and reduce ambient humidity, and are widely used to remove moisture from areas or protect certain products from moisture.
各種物質が除湿剤として用いられており、その中でもシリカゲルが最も代表的な潮解性物質であり、近来には、活性アルミナ（ＡＬ２Ｏ３）、珪藻土、ゼオライトなどを利用した除湿剤が開発されて一緒に用いられている。 Various substances are used as dehumidifiers, and among them, silica gel is the most typical deliquescent substance, and recently dehumidifiers using activated alumina (AL 2 O 3 ), diatomaceous earth, zeolite, etc. have been developed. are used together.
このような形態の除湿剤は、多孔性微細構造を有していて、毛細管現象によって水分を吸収し、初期吸湿が早いという長所があるが、微細構造の大部分を水分が満たしてからはこれ以上水分が吸収されにくいという短所がある。 This type of dehumidifier has a porous microstructure that absorbs moisture through capillary action, and has the advantage of rapid initial moisture absorption, but once most of the microstructure is filled with moisture, this The disadvantage is that it is difficult to absorb water.
特に、除湿剤として広く利用されているシリカゲルの場合、ケイ酸ナトリウム（ＮＡ２ＳＩＯ３）を強酸処理して生産するため、製造過程が環境にやさしくなく、使用後、廃棄時に腐敗されなくて、環境汚染を誘発するという問題がある。 In particular, in the case of silica gel, which is widely used as a dehumidifier, sodium silicate (NA 2 SIO 3 ) is produced by treating it with strong acids, so the manufacturing process is not environmentally friendly, and it does not decompose when disposed of after use. There is a problem that it causes environmental pollution.
本発明は、上記の従来技術における問題点を改善するために提案されたもので、環境にやさしい材料であるパルプを利用したパルプ除湿剤、およびその製造方法を提供することにより、環境汚染の発生を防止するとともに、除湿効率がさらに向上されることができるようにすることを目的とする。 The present invention was proposed in order to improve the problems in the prior art described above, and by providing a pulp dehumidifier using pulp, which is an environmentally friendly material, and a method for producing the same, the present invention eliminates the problem of environmental pollution. The purpose is to prevent this and further improve dehumidification efficiency.
上記目的を達するための本発明のパルプ除湿剤製造過程は、薄膜形態に成形加工されたパルプを用意するパルプ用意ステップと；前記パルプをカルシウムおよび塩化ナトリウムを含む乾燥溶液に浸漬させる溶液処理ステップと；前記溶液処理が行われたパルプを多層形態に積載する積載ステップと；前記積載が行われたパルプを高温で殺菌処理を実施する高温殺菌乾燥ステップと；前記殺菌処理が行われたパルプをプレス加圧によって圧縮を実施する圧縮ステップと；前記圧縮が行われたパルプを所定の大きさおよび形状に裁断する裁断ステップと；前記裁断が行われたパルプを乾燥させる乾燥ステップと；前記乾燥が行われたパルプを通気性の包装フィルムに包装する包装ステップ；によって製造が行われることを特徴とする。 The pulp dehumidifier manufacturing process of the present invention to achieve the above object includes a pulp preparation step of preparing a pulp molded into a thin film; a solution treatment step of immersing the pulp in a drying solution containing calcium and sodium chloride. ; a loading step of stacking the solution-treated pulp in a multi-layered form; a high-temperature sterilization drying step of sterilizing the loaded pulp at high temperature; and pressing the sterilized pulp. a compression step in which compression is performed by applying pressure; a cutting step in which the compressed pulp is cut into a predetermined size and shape; a drying step in which the cut pulp is dried; The method is characterized in that the production is carried out by a packaging step of packaging the pulp in an air-permeable packaging film.
また、前記溶液処理ステップで用いられる乾燥溶液は、精製水、カルシウム、塩化ナトリウム、ナトリウム過酸化水素、ベヘントリモニウムクロリド、エチレンジアミン、オレイン酸アミド、アセチルサリチル酸、アスコルビン酸の混合組成をなすことを特徴とする。 Further, the drying solution used in the solution treatment step has a mixed composition of purified water, calcium, sodium chloride, sodium hydrogen peroxide, behentrimonium chloride, ethylenediamine, oleic acid amide, acetylsalicylic acid, and ascorbic acid. shall be.
このような本発明のパルプ除湿剤は、天然植物成分であるパルプを主材料とする乾燥剤が包装材の内部に備えられることにより、生産費用を節減させるとともに、除湿効率を向上させ、使用後、製品の廃棄時に環境汚染の発生を防止することができるという効果を奏する。 The pulp dehumidifier of the present invention has a desiccant mainly made of pulp, which is a natural plant ingredient, inside the packaging material, thereby reducing production costs, improving dehumidification efficiency, and improving the dehumidification efficiency after use. This has the effect of preventing environmental pollution when the product is disposed of.
特に、本発明のパルプ除湿剤は、人体に無害な天然成分であるので、一般の衣類だけでなく、かばんや帽子などのような多様な生活用品の除湿用途に活用可能な利点を有する。 In particular, since the pulp dehumidifier of the present invention is a natural ingredient that is harmless to the human body, it has the advantage that it can be used to dehumidify not only general clothing but also various daily necessities such as bags and hats.
以下、本発明の具体的な実施形態を添付図面を参照して詳しく説明する。 Hereinafter, specific embodiments of the present invention will be described in detail with reference to the accompanying drawings.
本発明の実施形態は様々な形態に変形されることができ、本発明の範囲が以下で詳しく説明する実施形態に限定されることに解釈されてはならない。本実施形態は当業界で平均的な知識を有する者に本発明をより完全に説明するために提供されるのである。 The embodiments of the present invention may be modified in various forms, and the scope of the present invention should not be construed as being limited to the embodiments described in detail below. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art.
したがって、図面で表現した構成要素の形状などはより明確な説明を強調するために誇張されて表現されてもよい。各図面において、同じ構成は同じ参照符号で示す場合があることに留意すべきである。また、本発明の要旨を不必要に曖昧にする虞があると判断される公知技術の機能および構成に関する詳細な説明は省略されてもよい。 Accordingly, the shapes of components depicted in the drawings may be exaggerated to emphasize clearer explanation. It should be noted that the same features may be designated by the same reference numerals in the drawings. Furthermore, detailed explanations regarding the functions and configurations of known techniques that may unnecessarily obscure the gist of the present invention may be omitted.
まず、本発明の一実施形態によるパルプ型除湿剤の製造過程を図１および図２によって説明すれば、次の通りである。 First, the manufacturing process of a pulp type dehumidifier according to an embodiment of the present invention will be explained with reference to FIGS. 1 and 2 as follows.
＜パルプ用意ステップ＞（ＳＴ１） <Pulp preparation step> (ST1)
まず、薄い薄膜形態に成形加工されたパルプ１１をロール状に巻き取って用意する、パルプ用意ステップを実施する。 First, a pulp preparation step is performed in which the pulp 11 formed into a thin film is wound up into a roll.
＜溶液処理ステップ＞（ＳＴ２） <Solution treatment step> (ST2)
その後、前記パルプ１１をカルシウムおよび塩化ナトリウムを含む乾燥溶液に図２のように浸漬させる。 Thereafter, the pulp 11 is immersed in a drying solution containing calcium and sodium chloride as shown in FIG.
この時、浸漬槽１００内に用いられる本発明の乾燥溶液は、精製水とカルシウム、塩化ナトリウム成分を主要混合物としており、溶液の機能性を向上させるために、機能性成分が混合されてもよい。 At this time, the dry solution of the present invention used in the immersion tank 100 mainly contains purified water, calcium, and sodium chloride components, and functional components may be mixed in order to improve the functionality of the solution. .
一例として、本実施形態では、精製水４０～７０重量％、カルシウム１０～３０重量％、塩化ナトリウム５～２０重量％、ポリエチレンワックス５～１０重量％、ベヘントリモニウムクロリド１～１０重量％、セルロース１～１０重量％、エチレンジアミン１～１０重量％、オレイン酸アミド１～５重量％、アセチルサリチル酸１～５重量％、アスコルビン酸０．５～３重量％の割合で混合組成をなすようにした。 As an example, in this embodiment, purified water 40-70% by weight, calcium 10-30% by weight, sodium chloride 5-20% by weight, polyethylene wax 5-10% by weight, behentrimonium chloride 1-10% by weight, cellulose The mixed composition was made to have a ratio of 1 to 10% by weight, ethylenediamine 1 to 10% by weight, oleic acid amide 1 to 5% by weight, acetylsalicylic acid 1 to 5% by weight, and ascorbic acid 0.5 to 3% by weight.
このような組成からなる乾燥溶液には、アセチルサリチル酸およびベヘントリモニウムクロリド成分が混合されているので、後処理過程で積載されたパルプ相互間の粘着力の向上による圧縮効率が極大化され、ポリエチレンワックスおよびアスコルビン酸は、乾燥溶液の変質を防止し、セルロースおよびエチレンジアミンは、パルプの吸収がより速かに行われることができるようにする機能を果たす。また、オレイン酸アミドは、パルプの密度を向上させることにより、耐久性を向上させる進歩された作用効果を有する。 Since the drying solution with this composition contains acetylsalicylic acid and behentrimonium chloride components, the compression efficiency is maximized by improving the adhesion between the loaded pulps in the post-treatment process, and the polyethylene Wax and ascorbic acid serve to prevent deterioration of the drying solution, and cellulose and ethylenediamine allow absorption of the pulp to occur more quickly. In addition, oleic acid amide has an advanced effect of improving durability by improving pulp density.
また、前記組成物におけるセルロースは、α型アノマー（ａｎｏｍｅｒ）よりも安定性を向上させることができるβ型アノマーがより多いことを特徴とする。 In addition, the cellulose in the composition is characterized by having more β-type anomer, which can improve stability, than α-type anomer.
すなわち、本実施形態において、パルプを原料とする乾燥剤１０は、湿気を吸収した後、水分を含んでいる必要があり、本実施形態における乾燥剤１０は、セルロースが２つの役割を同時に果たす。セルロースが湿気を吸収して保管する時、セルロースの分解を防止し、水分をよく含んでいるようにするためには、安定性の向上されたセルロースが必要となり、この時、β型アノマーが相対的に多いセルロースを用いると、水分を含む場合、乾燥剤１０が柔くなるだけであり、割れたり砕ける現象が防止されることができる。 That is, in this embodiment, the desiccant 10 made from pulp must contain moisture after absorbing moisture, and in the desiccant 10 in this embodiment, cellulose plays two roles at the same time. When cellulose absorbs moisture and is stored, cellulose with improved stability is required to prevent cellulose from degrading and to retain moisture. If cellulose with a large amount of water is used, the desiccant 10 will only become soft when it contains moisture, and cracking or shattering can be prevented.
上記と反対に、α型アノマーがβ型アノマーよりも多い場合には、水分などによって分解されやすくて、モノマー形態が増加されてべたつく可能性があり、これによって、乾燥剤１０が板状を保持できず、形状が変形される可能性がある。 Contrary to the above, if the α-type anomer is larger than the β-type anomer, it is likely to be decomposed by moisture etc., and the monomer form may increase and become sticky, thereby causing the desiccant 10 to maintain its plate shape. Otherwise, the shape may be deformed.
＜積載ステップ＞（ＳＴ３） <Loading step> (ST3)
次に、前記溶液処理が行われたパルプ１１を多層形態に積載する積載ステップが実施される。 Next, a stacking step is performed in which the pulp 11 subjected to the solution treatment is stacked in a multilayered manner.
＜高温殺菌乾燥ステップ＞（ＳＴ４） <High temperature sterilization drying step> (ST4)
このように積載が行われたパルプ１１を高温で殺菌処理を実施する。 The pulp 11 loaded in this way is sterilized at high temperature.
この時には、殺菌の効率を向上させるために、真空チャンバ内で、１～５時間、１００～１５０℃の温度で乾燥作業が実施されることが好ましい。 At this time, in order to improve the efficiency of sterilization, the drying operation is preferably performed in a vacuum chamber at a temperature of 100 to 150° C. for 1 to 5 hours.
＜圧縮ステップ＞（ＳＴ５） <Compression step> (ST5)
その後、前記殺菌処理が行われたパルプをプレス加圧によって圧縮を実施するステップが行われる。 Thereafter, a step is performed in which the sterilized pulp is compressed by pressurization.
＜裁断ステップ＞（ＳＴ６） <Cutting step> (ST6)
その次、前記圧縮が行われたパルプを四角形の所定の大きさおよび形状に裁断することによって、本実施形態の乾燥剤１０の成形製作が行われる。 Next, the desiccant 10 of this embodiment is manufactured by cutting the compressed pulp into a predetermined rectangular size and shape.
＜乾燥ステップ＞（ＳＴ７） <Drying step> (ST7)
前記裁断が行われた乾燥剤１０を、常温で、３～７時間乾燥させる乾燥作業を実施する。 A drying operation is performed in which the cut desiccant 10 is dried at room temperature for 3 to 7 hours.
＜包装ステップ＞（ＳＴ８） <Packaging step> (ST8)
前記乾燥が行われた乾燥剤１０を通気性の包装フィルム２０に包装する過程によって、図３に示すような本発明のパルプ除湿剤製品が完成される。 By packaging the dried desiccant 10 in a breathable packaging film 20, the pulp dehumidifier product of the present invention as shown in FIG. 3 is completed.
この時、用いる包装フィルム２０は、通気性のために、連続する気孔がフィルムの表面に均一に分布された構造を有するもので、気孔の大きさは数マイクロメートル以下で、気体および水蒸気は通過し、水玉のような液体は通過できない透湿、防水機能を有する通常の通気性フィルムを用いる。 The packaging film 20 used at this time has a structure in which continuous pores are uniformly distributed on the surface of the film for breathability, and the pores are several micrometers or less in size, allowing gas and water vapor to pass through. However, a normal breathable film with moisture permeable and waterproof functions is used, which prevents liquids such as water droplets from passing through.
このような過程によって製造された本発明のパルプ除湿剤は、吸湿性に優れた天然植物纎維であるパルプ１１を材料とする乾燥剤１０が包装フィルム２０の内部に備えられる構造を有することによって、使用時に、人体に無害で、環境にやさしい吸湿性気質の特性を現わすようになる。 The pulp dehumidifier of the present invention manufactured by such a process has a structure in which the desiccant 10 made of pulp 11, which is a natural plant fiber with excellent hygroscopicity, is provided inside the packaging film 20. When used, it exhibits the characteristics of hygroscopic temperament, which is harmless to the human body and environmentally friendly.
特に、包装フィルム２０の内部に備えられる乾燥剤１０は、パルプ１１が多数の積層形態に圧縮積載された平坦な板状構造を有するので、吸湿効率の持続時間が従来のシリカゲルに比べて増大されることができる進歩された作用効果を奏することができる。 In particular, since the desiccant 10 provided inside the packaging film 20 has a flat plate-like structure in which the pulp 11 is compressed and stacked in a large number of layers, the duration of moisture absorption efficiency is increased compared to conventional silica gel. It is possible to achieve advanced functions and effects.
したがって、本発明のパルプ除湿剤は、パルプを材料とする乾燥剤が包装材の内部に備えられることによって、生産費用を節減させるとともに、除湿効率を向上させ、使用後、製品廃棄時に環境汚染の発生を防止することができるという効果を奏する。 Therefore, the pulp dehumidifier of the present invention has a desiccant made of pulp inside the packaging material, thereby reducing production costs, improving dehumidification efficiency, and reducing environmental pollution when disposing of the product after use. This has the effect of being able to prevent this from occurring.
特に、本発明のパルプ除湿剤は、人体に無害な天然成分であるので、一般の衣類だけでなく、かばんや帽子などのような多様な生活用品の除湿用途に活用可能な利点を有する。 In particular, since the pulp dehumidifier of the present invention is a natural ingredient that is harmless to the human body, it has the advantage that it can be used to dehumidify not only general clothing but also various daily necessities such as bags and hats.
一方、図４は、本発明の他の実施形態による除湿剤の構造を示し、包装フィルム２０の内側には乾燥剤１０との密着を防止して、所定の通気空間が保持されることができるように弾力性を有する多数の緩衝突部２１が所定間隔を保持して点状に形成される。 Meanwhile, FIG. 4 shows the structure of a dehumidifier according to another embodiment of the present invention, in which a predetermined ventilation space can be maintained inside the packaging film 20 by preventing close contact with the desiccant 10. A large number of resilient gentle collision parts 21 are formed in a dot shape with predetermined intervals.
この時、前記緩衝突部２１は、マグネシウムクロロフェニサイト１～１０重量％、ｐ－トリルオクタノエート１～５重量％、シリコン樹脂２０～４０重量％、ポリブチレンテレフタレート１０～３０重量％、塩化トリフェニルスズ５～２０重量％、プロリン１～１０重量％、フェニルアラニンヒドロキシラーゼ１～１５重量％、活性グルテン１～５重量％の割合で混合組成をなすことが好ましい。 At this time, the gentle collision part 21 contains 1 to 10% by weight of magnesium chlorophenisite, 1 to 5% by weight of p-tolyl octanoate, 20 to 40% by weight of silicone resin, 10 to 30% by weight of polybutylene terephthalate, and chloride. It is preferable to form a mixed composition containing 5 to 20% by weight of triphenyltin, 1 to 10% by weight of proline, 1 to 15% by weight of phenylalanine hydroxylase, and 1 to 5% by weight of active gluten.
このような構成を有する場合、緩衝突部２１の構成によって包装フィルム２０と乾燥剤１０との密着が防止されることができるようになり、それによる除湿剤の内部の通気性が確保されることにより、除湿効率をより向上させるという利点を有する。 When having such a configuration, the configuration of the gentle collision part 21 can prevent the packaging film 20 and the desiccant 10 from coming into close contact with each other, thereby ensuring air permeability inside the dehumidifier. This has the advantage of further improving dehumidification efficiency.
特に、緩衝突部２１には弾力性のシリコン樹脂以外にも、マグネシウムクロロフェニサイトおよびポリブチレンテレフタレート成分が混合されているので、空気接触によるシリコン樹脂の硬化現象を防止し、活性グルテンは、シリコン樹脂の弾力性を安定的に保持させることができ、ｐ－トリルオクタノエートおよび塩化トリフェニルスズは、それぞれ組成物相互間の結合力を向上させるとともに、緩衝突部２１の変色発生を防止する機能を実行する。 In particular, in addition to the elastic silicone resin, the gentle collision part 21 contains magnesium chlorophenicite and polybutylene terephthalate components, which prevents the hardening phenomenon of the silicone resin due to air contact. The elasticity of the resin can be stably maintained, and p-tolyl octanoate and triphenyltin chloride each improve the bonding force between the compositions and prevent discoloration of the gentle collision part 21. perform a function.
また、追加添加されたプロリンおよびフェニルアラニンヒドロキシラーゼは、それぞれ緩衝突部２１を点状に包装フィルム２０の表面に形成した時、フィルム面と迅速な接着のための触媒作用をする進歩された作用効果を表すようになる。 In addition, the additionally added proline and phenylalanine hydroxylases have an advanced effect of acting as a catalyst for rapid adhesion to the film surface when the gentle collision areas 21 are formed on the surface of the packaging film 20 in the form of dots. It comes to represent
また、本発明のまた他の実施形態としては、高温殺菌乾燥ステップ（ＳＴ４）では、真空状態を保持する前記真空チャンバの入口側には、殺菌蒸気噴射ノズルが備えられて、チャンバの内部に引入されるパルプ１１の表面に殺菌蒸気が供給されることができるようになる。 Further, in another embodiment of the present invention, in the high temperature sterilization drying step (ST4), a sterilization steam injection nozzle is provided on the inlet side of the vacuum chamber that maintains a vacuum state, and a sterilization steam injection nozzle is provided to draw into the inside of the chamber. Sterilizing steam can be supplied to the surface of the pulp 11 to be treated.
この時、前記供給される殺菌蒸気は、精製水４０～６０重量％、チオ硫酸ナトリウム１０～３０重量％、亜塩素酸５～２０重量％、トリーエタノールアミン１０～２０重量％、セチルピリジニウムクロリド１～１０重量％の割合で混合組成をなすことが好ましい。 At this time, the supplied sterilizing steam contains 40-60% by weight of purified water, 10-30% by weight of sodium thiosulfate, 5-20% by weight of chlorite, 10-20% by weight of triethanolamine, and 1% by weight of cetylpyridinium chloride. It is preferable to form a mixed composition in a proportion of ~10% by weight.
このような混合組成を有する殺菌蒸気の供給が真空チャンバに引入されるパルプの表面に振り撤かれると、パルプ１１の殺菌効率が向上されるとともに、殺菌乾燥時間を短縮させることができる。 When the supply of sterilizing steam having such a mixed composition is shaken off on the surface of the pulp drawn into the vacuum chamber, the sterilizing efficiency of the pulp 11 is improved and the sterilizing drying time can be shortened.
特に、殺菌蒸気にはチオ硫酸ナトリウムおよび亜塩素酸が混合されているので、抗菌機能性が向上され、セチルピリジニウムクロリドは、殺菌蒸気薬液の変質を防止して、殺菌機能の持続性を強化させる機能を実行するようになる。 In particular, the sterilizing steam contains sodium thiosulfate and chlorite, which improves antibacterial functionality, and cetylpyridinium chloride prevents deterioration of the sterilizing vapor chemical solution and strengthens the sustainability of the sterilizing function. begins to perform the function.
以上、本発明の特定の実施形態が説明および図示されたが、本発明のパルプ除湿剤の構造および製造過程が当業者によって多様に変形されて実施され得ることは自明である。 Although specific embodiments of the present invention have been described and illustrated above, it is obvious that the structure and manufacturing process of the pulp dehumidifier of the present invention may be variously modified and implemented by those skilled in the art.
例えば、前記実施形態では、乾燥剤が四角形に形成されたことで説明されたが、必要によっては、円形や多角形に乾燥剤の裁断および成形が行われてもよい。 For example, in the embodiment described above, the desiccant is formed into a rectangular shape, but if necessary, the desiccant may be cut and formed into a circular or polygonal shape.
したがって、このような変形された実施形態は、本発明の技術的思想や範囲から個別的に理解されてはならなく、このような変形された実施形態は、本発明の特許請求範囲内に含まれるべきである。 Therefore, such modified embodiments should not be understood separately from the technical spirit and scope of the present invention, and such modified embodiments are not included within the scope of the claims of the present invention. Should be.
１０ 乾燥剤
１１ パルプ
２０ 包装フィルム
10 Desiccant 11 Pulp 20 Packaging film
Claims (6)
前記包装フィルム（２０）の内部に備えられ、パルプ（１１）が多数の積層形態に圧縮積載された平坦な板状構造を有する乾燥剤（１０）；
を含む構成をなす、ことを特徴とするパルプ型除湿剤。 A packaging film (20) made of a breathable film material; and a desiccant (10) provided inside the packaging film (20) and having a flat plate-like structure in which pulp (11) is compressed and stacked in a large number of layers. ;
A pulp type dehumidifier comprising:
前記パルプをカルシウムおよび塩化ナトリウムを含む乾燥溶液に浸漬させる溶液処理ステップ（ＳＴ２）；
前記溶液処理が行われたパルプを多層形態に積載する積載ステップ（ＳＴ３）；
前記積載が行われたパルプを高温で殺菌処理を実施する高温殺菌乾燥ステップ（ＳＴ４）；
前記殺菌処理が行われたパルプをプレス加圧によって圧縮を実施する圧縮ステップ（ＳＴ５）；
前記圧縮が行われたパルプを所定の大きさおよび形状に裁断する裁断ステップ（ＳＴ６）；
前記裁断が行われたパルプを乾燥させる乾燥ステップ（ＳＴ７）；および
前記乾燥が行われたパルプを通気性の包装フィルムに包装する包装ステップ（ＳＴ８）；によって製造が行われる、ことを特徴とするパルプ型除湿剤製造方法。 Pulp preparation step (ST1) of preparing pulp molded into a thin film form;
a solution treatment step (ST2) of immersing the pulp in a drying solution containing calcium and sodium chloride;
a loading step (ST3) of loading the pulp subjected to the solution treatment in a multilayered form;
a high temperature sterilization drying step (ST4) in which the loaded pulp is sterilized at high temperature;
a compression step (ST5) of compressing the sterilized pulp by pressurization;
a cutting step (ST6) of cutting the compressed pulp into a predetermined size and shape;
The production is characterized in that the production is performed by a drying step (ST7) of drying the pulp that has been cut; and a packaging step (ST8) of packaging the dried pulp in an air-permeable packaging film. Pulp type dehumidifier manufacturing method.
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| KR1020220078187A KR102464347B1 (en) | 2022-06-27 | 2022-06-27 | Pulp-type desiccant manufacturing method thereof |
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| JPS6384617A (en) * | 1986-09-26 | 1988-04-15 | Nippon Synthetic Chem Ind Co Ltd:The | Laminating type humidity conditioning material |
| WO2002068193A1 (en) * | 2001-02-23 | 2002-09-06 | Idemitsu Petrochemical Co., Ltd. | Laminate for packaging and package |
| KR101755131B1 (en) | 2015-12-24 | 2017-07-06 | 오씨아이 주식회사 | Composition of dehumidifying agent and manufacturing the same |
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| KR101998070B1 (en) | 2017-12-05 | 2019-07-09 | 인제대학교 산학협력단 | Dehumidifying Agent Using Grain and Method Thereof |
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