JP2023120684A - Soft food product and composition for producing same - Google Patents

Soft food product and composition for producing same Download PDF

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JP2023120684A
JP2023120684A JP2022023665A JP2022023665A JP2023120684A JP 2023120684 A JP2023120684 A JP 2023120684A JP 2022023665 A JP2022023665 A JP 2022023665A JP 2022023665 A JP2022023665 A JP 2022023665A JP 2023120684 A JP2023120684 A JP 2023120684A
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由莉 行光
Yuri Yukimitsu
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Matsutani Chemical Industries Co Ltd
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Abstract

To provide: a formed and heated food product using a pasty or minced food material which remains soft even after becoming cool or frozen and thawed unlike conventional formed and heated food products, which becomes hard when becoming cool; a composition for preparing such a food product; and a production method of such a food product.SOLUTION: The problem to be solved can be solved by a formed and heated food product provided by the present invention, and being a soft food product having hardness of 50,000 N/m2 or less at 45°C and 20°C and produced by adding 2-10 pts.mass of waxy tapioca starch modified by hyroxypropylation or acetylation and 1-5 pts.mass of dextrin of DE 1-7 with respect to 100 pts.mass of a minced or pasty food material.SELECTED DRAWING: None

Description

本発明は、調理後又は冷凍解凍後の冷めた状態において、調理直後のやわらかさを維持した成形加熱食品、及びそのような食品を調製するための組成物に関する。 FIELD OF THE INVENTION The present invention relates to a molded heated food product that retains its freshly cooked softness in a cooled state after cooking or after freezing and thawing, and compositions for preparing such food products.

食品咀嚼・嚥下困難者は摂食時に窒息・誤嚥しやいため、咀嚼・嚥下困難者に食事を提供する際は、固形状食品であれば十分に柔らかくなるまで加熱し、マッシャーなどで舌や歯茎で容易につぶすことができるミンチ状にするか、ミキサーなどで飲み込みやすいペースト状にすることがほとんどである。そして、それが液分離する状態であれば、気管に流入しないようゲル化剤でゲル化又はゾル化させて、咀嚼・嚥下困難者の咀嚼・嚥下に適切な物性とすることもある。しかし、ミンチやペーストをゲル化剤でゲル化又はゾル化させた場合であっても、経時的に又は冷凍解凍を繰り返すなどにより離水を生じるため、これを誤嚥し、誤嚥性肺炎の危険が生じる。したがって、そのような離水を極力抑える必要がある。 People with difficulty chewing or swallowing food are more likely to choke or aspirate when eating. In most cases, it is minced so that it can be easily crushed with the gums, or it is made into a paste that is easy to swallow with a mixer. Then, if it is in a liquid-separable state, it may be gelled or sol-formed with a gelling agent so as to prevent it from flowing into the trachea, so that it has physical properties suitable for chewing and swallowing by people with difficulty chewing and swallowing. However, even if minced meat or paste is gelled or solified with a gelling agent, syneresis occurs over time or due to repeated freezing and thawing. occurs. Therefore, it is necessary to suppress such separation of water as much as possible.

咀嚼・嚥下困難者用の食品を簡便に調製するための補助剤等がこれまでに提案されている。例えば、加熱不可逆性のゲルを形成可能なカードランとセルロースを併用したゼリー状食品用ゲル化剤(特許文献1)や、カードランと加工デンプンを併用した咀嚼困難者用食品の離水抑制剤(特許文献2)が開示されている。また、温かい状態でも冷たい状態でも良好な物性を得るために、熱可逆性のある加熱凝固ゲル化剤(メチルセルロース又はヒドロキシピロピルメチルセルロース)と熱可逆性のある冷却凝固ゲル化剤(寒天、カラギナン、ファーセレラン、ジェランガム、ゼラチン、ローカストビーンガム及びキサンタンガム、グルコマンナン及びキサンタンガム、タラガム及びキサンタンガム、並びにカシアガム及びキサンタンガムより選ばれる1以上)を併用した摂食・嚥下補助剤が開示されている(特許文献3)。 Adjuvants and the like for conveniently preparing foods for people with difficulty in chewing and swallowing have been proposed so far. For example, a jelly-like food gelling agent using curdlan and cellulose capable of forming a heat-irreversible gel (Patent Document 1), and a syneresis inhibitor for food for people with difficulty chewing using curdlan and modified starch in combination ( Patent document 2) is disclosed. In order to obtain good physical properties in both warm and cold conditions, a thermoreversible heat-setting gelling agent (methylcellulose or hydroxypyropyrmethylcellulose) and a heat-reversible cooling-setting gelling agent (agar, carrageenan, One or more selected from furcelleran, gellan gum, gelatin, locust bean gum and xanthan gum, glucomannan and xanthan gum, tara gum and xanthan gum, and cassia gum and xanthan gum) in combination has been disclosed (Patent Document 3). .

しかし、カードランとセルロース、カードランと加工澱粉の各組み合わせ、加熱凝固ゲル化剤(置換型セルロース)では、ペースト食品に保形性を与えるものの硬さを生じるため食感が好ましくない。これは、タンパク質を多く含む食材、たとえば畜肉や魚肉をペースト状又はミンチ状としたものに対して使用したときに顕著であり、冷めた状態や冷凍解凍後にはさらに硬くなるため、より食感に違和感を生じることとなる。 However, each combination of curdlan and cellulose, curdlan and modified starch, and heat-coagulating gelling agent (substituted cellulose) imparts shape retention to the paste food, but causes hardness, resulting in poor texture. This is remarkable when used for ingredients containing a large amount of protein, such as pasty or minced livestock meat or fish meat, and becomes even harder in a cold state or after freezing and thawing, resulting in a better texture. It causes discomfort.

特開2007-319048号公報Japanese Patent Application Laid-Open No. 2007-319048 国際公開WO2017/017953号International publication WO2017/017953 特開2014-236700号公報Japanese Unexamined Patent Application Publication No. 2014-236700

本発明の目的は、ペースト状又はミンチ状とした食材を利用した成形加熱食品について、冷たい状態で又は冷凍解凍しても、硬くなることなくやわらかい性状のままとすること、及びそのような食品を調製するための組成物を提供することにある。 It is an object of the present invention to provide molded heated foods using pasty or minced food materials that remain soft without becoming hard even when cold or frozen and thawed, and to provide such foods. It is to provide a composition for preparing.

本発明者らは、ワキシータピオカを原料とする加工澱粉と低DEデキストリンを併用することにより、上記課題を解決できることを見出し、本発明を完成するに至った。 The present inventors have found that the above problems can be solved by using a combination of modified starch made from waxy tapioca and low DE dextrin, and have completed the present invention.

すなわち、本発明は、以下[1]~[5]からなるものである。
[1]ヒドロキシプロピル化又はアセチル化の加工を施してなるワキシータピオカ澱粉2~10質量部に対し、DE1~7のデキストリンを1~5質量部の割合で含む、ミンチ状又はペースト状の食材を加熱成形するための組成物。
[2]澱粉が、さらにアジピン酸又はリン酸により架橋された澱粉である、[1]記載の組成物。
[3]ミンチ状又はペースト状の食材100質量部に対し、ヒドロキシプロピル化又はアセチル化の加工を施してなるワキシータピオカ澱粉を2~10質量部とDE1~7のデキストリンを1~5質量部の割合で含み、45℃及び20℃における硬さが50,000N/m以下である、成形加熱食品。
[4]ミンチ状又はペースト状の食材100質量部に対し、ヒドロキシプロピル化又はアセチル化の加工を施してなるワキシータピオカ澱粉2~10質量部とDE1~7のデキストリン1~5質量部を、(A)そのまま混合する、又は(B)水若しくは調味液に懸濁若しくは溶解してから混合する、45℃及び20℃における硬さが50,000N/m以下である成形加熱食品の製造方法。
[5]ミンチ状又はペースト状の食材100質量部に対し、ヒドロキシプロピル化又はアセチル化の加工を施してなるワキシータピオカ澱粉2~10質量部とDE1~7のデキストリン1~5質量部を添加する、成形加熱食品の20℃におけるやわらかさを維持する方法。
That is, the present invention consists of the following [1] to [5].
[1] A minced or pasty food material containing 2 to 10 parts by mass of waxy tapioca starch processed by hydroxypropylation or acetylation and 1 to 5 parts by mass of dextrin having a DE of 1 to 7. A composition for thermoforming.
[2] The composition of [1], wherein the starch is further crosslinked with adipic acid or phosphoric acid.
[3] 2 to 10 parts by mass of waxy tapioca starch processed by hydroxypropylation or acetylation and 1 to 5 parts by mass of dextrin with a DE of 1 to 7 are added to 100 parts by mass of minced or pasty food ingredients. A molded heated food product containing in proportion and having a hardness of 50,000 N/m 2 or less at 45°C and 20°C.
[4] 2 to 10 parts by mass of waxy tapioca starch processed by hydroxypropylation or acetylation and 1 to 5 parts by mass of dextrin with a DE of 1 to 7 are added to 100 parts by mass of minced or paste-like ingredients ( A method for producing a molded heated food having a hardness of 50,000 N/m 2 or less at 45° C. and 20° C. by A) mixing as it is, or (B) mixing after suspending or dissolving in water or a seasoning liquid.
[5] 2 to 10 parts by mass of waxy tapioca starch processed by hydroxypropylation or acetylation and 1 to 5 parts by mass of dextrin having a DE of 1 to 7 are added to 100 parts by mass of minced or pasty food material. , A method for maintaining the softness of molded heated foods at 20°C.

ミンチ状又はペースト状の食材を成形調理する際に、本発明の組成物を使用すれば、調理後の冷めた状態又は冷凍解凍後にも硬くなることなく、やわらかい性状のままの食品(介護食)を提供することができる。 If the composition of the present invention is used in molding and cooking minced or pasty foodstuffs, the foodstuffs remain soft without hardening even after being cooled after cooking or after freezing and thawing (nursing care foods). can be provided.

本発明における「成形加熱食品」とは、野菜、果物、豆、穀類、肉、魚介、卵、乳製品、若しくはこれらの加工食品などの食材をそのまま又は加熱してからマッシャーやミキサーなどで破砕、磨砕、裏ごしなどして得た破砕物、磨砕物若しくはペースト(以下、ミンチ、ペーストとも呼ぶ)に対し、必要に応じて調味料や助剤等を混合し、加熱により保形又は成形した食品であり、介護食、やわらか食などを含む。なお、本発明にいう「成形加熱食品」は、製造時の成形と加熱の順は問わず、「加熱成形食品」と同義であり、以降、単に「本発明の食品」などということもある。 The "formed heated food" in the present invention means vegetables, fruits, beans, grains, meat, seafood, eggs, dairy products, or processed foods such as these, as they are or after heating, crushing them with a masher or mixer, Foods obtained by grinding, straining, etc., crushing, grinding, or paste (hereinafter also referred to as mince or paste), mixed with seasonings, auxiliary agents, etc. as necessary, and shaped or molded by heating. , which includes care food and soft food. In addition, the "molded heated food" referred to in the present invention has the same meaning as "heated molded food" regardless of the order of molding and heating at the time of production, and hereinafter may be simply referred to as "the food of the present invention".

介護食とは、一般に、(1)健康増進法第43条第1項に基づく消費者庁長官の許可を受けて表示販売が可能となる「特別用途食品」の範疇にある「えん下困難者用食品」、(2)日本介護食品協議会が策定する自主規格「ユニバーサルデザインフード」(区分1~4)に該当する「高齢者食品」又は「そしゃく困難者食品」のいずれかをいう。本明細書で用いる「介護食」は、具体的には、上記(2)の「ユニバーサルデザインフード」における「区分2」の物性規格「かたさ上限値50000N/m」(ゲル)を満たす食品群を意図する(当該かたさ値は、直径20mm円柱型プランジャーを10mm/秒の速度でサンプル厚みの70%まで押し込んだ際の荷重値)。 Nursing care food is generally defined as: (1) "persons with difficulty swallowing" in the category of "food for special dietary use" that can be labeled and sold with the permission of the Director-General of the Consumer Affairs Agency based on Article 43, Paragraph 1 of the Health Promotion Act. (2) either “food for the elderly” or “food for people who have difficulty chewing” that falls under the voluntary standard “universal design food” (Categories 1 to 4) established by the Japan Nursing Care Food Council. The “nursing care food” used herein specifically refers to a food group that satisfies the physical property standard “upper limit of hardness 50000 N/m 2 ” (gel) of “Category 2” in “universal design food” in (2) above. (The hardness value is the load value when a cylindrical plunger with a diameter of 20 mm is pushed into 70% of the thickness of the sample at a speed of 10 mm/sec).

本発明の組成物の必須成分のひとつは、澱粉である。澱粉は、ワキシー種の澱粉を用いることを必須とし、ワキシー種のなかでも、ワキシータピオカを原料とする澱粉を用いるのが好ましい。また、当該ワキシー種の澱粉は、エーテル化又はエステル化のいずれか一以上の加工が施されたものが好ましく、エーテル化の処理は、澱粉の水酸基をエーテル化できる基剤であればどのようなものを用いても行うことができるが、酸化プロピレンを用いたヒドロキシプロピル化が好ましく、エステル化は、酢酸ビニルや無水酢酸を用いたアセチル化のほか、オクテニルコハク酸基やリン酸基を導入するのでもよいが、アセチル化のほうがより好ましい。以上のエーテル化又はエステル化の処理に際しては、同時又は異時に架橋化剤のトリメタリン酸ナトリウムやオキシ塩化リンなどを作用させて架橋してもよく、そのようにして得られる加工澱粉は、ヒドロキシプロピル化リン酸架橋澱粉、アセチル化アジピン酸架橋澱粉、アセチル化リン酸架橋澱粉である。 One of the essential ingredients of the composition of the invention is starch. As the starch, it is essential to use starch of waxy species, and among waxy species, it is preferable to use starch made from waxy tapioca. In addition, the waxy starch is preferably subjected to one or more of etherification and esterification, and the etherification treatment may be any base that can etherify the hydroxyl groups of the starch. Hydroxypropylation using propylene oxide is preferred, and esterification can be performed by acetylation using vinyl acetate or acetic anhydride, or by introducing an octenylsuccinic acid group or a phosphoric acid group. , but acetylation is more preferred. In the above etherification or esterification treatment, a cross-linking agent such as sodium trimetaphosphate or phosphorus oxychloride may be allowed to act simultaneously or at different times to cross-link. phosphate-crosslinked starch, acetylated adipic acid-crosslinked starch, and acetylated phosphate-crosslinked starch.

以上のとおり、本発明の組成物の一として用いる澱粉は、ワキシータピオカ澱粉を原料とするヒドロキシプロピル澱粉、ヒドロキシプロピル化リン酸架橋澱粉、酢酸澱粉、アセチル化アジピン酸架橋澱粉のいずれか一以上を選択することが好ましく、そのなかでもヒドロキシプロピル化リン酸架橋澱粉がもっとも好ましい。なお、そのヒドロキシプロピル化の程度はとくに限定するものではないが、ヒドロキシプロピルによる置換度(澱粉を構成するグルコース残基の3つのフリーの水酸基すべてが置換されたときの置換度を3とする)が、0.03~0.2のものが好ましく、0.07~0.18、さらには0.09~0.16のものがより好ましい。また、リン酸による架橋度(後述する方法で測定される沈降積)は、8~10mlが好ましく、9~10ml、10ml程度がさらに好ましい。 As described above, the starch used as one of the compositions of the present invention is any one or more of hydroxypropyl starch made from waxy tapioca starch, hydroxypropylated phosphate-crosslinked starch, acetate starch, and acetylated adipic acid-crosslinked starch. It is preferred to select, among which hydroxypropylated phosphate cross-linked starch is most preferred. The degree of hydroxypropylation is not particularly limited, but the degree of substitution with hydroxypropyl (the degree of substitution is 3 when all three free hydroxyl groups of glucose residues constituting starch are substituted). is preferably 0.03 to 0.2, more preferably 0.07 to 0.18, more preferably 0.09 to 0.16. The degree of crosslinking with phosphoric acid (sedimentation volume measured by the method described later) is preferably 8-10 ml, more preferably 9-10 ml, more preferably about 10 ml.

加工澱粉の架橋度の一般的な測定方法(以降、「定法」という。)は、以下である。まず、塩化アンモニウム26質量部、塩化亜鉛10質量部及び水64質量部からなる溶液15mlを、澱粉試料0.15gが秤量された試験管に注いで懸濁液とする。次に、これを沸騰浴中で10分間加熱後、流水で冷却し、10ml容メスシリンダーの10mlの目盛りまで流し込む。そして、25℃で20時間静置後、沈降物の目盛りを沈降積とする。 A general method for measuring the degree of cross-linking of modified starch (hereinafter referred to as the “regular method”) is as follows. First, 15 ml of a solution consisting of 26 parts by mass of ammonium chloride, 10 parts by mass of zinc chloride and 64 parts by mass of water is poured into a test tube in which 0.15 g of a starch sample has been weighed to form a suspension. Next, it is heated in a boiling bath for 10 minutes, cooled with running water, and poured into a 10-ml graduated cylinder up to the 10-ml mark. Then, after standing at 25° C. for 20 hours, the scale of the sediment is taken as sediment volume.

本発明の組成物における上記澱粉の使用割合は、食品における内部離水防止の観点及びやわらかさ維持の観点から、ペースト状又はミンチ状とした食材100質量部に対し、少なくとも2質量部以上であることが好ましく、やわらかい食感をより重視する場合は、3質量部以上、4質量部以上、6質量部以上とするのがよい。もっとも、過剰に添加するとコスト面から好ましくなく、効果とのバランスを考慮して10質量部までにとどめるのがよい。 The proportion of the starch used in the composition of the present invention should be at least 2 parts by mass or more per 100 parts by mass of pasty or minced food from the viewpoint of preventing internal syneresis and maintaining softness of the food. is preferred, and when more emphasis is placed on soft texture, the content is preferably 3 parts by mass or more, 4 parts by mass or more, or 6 parts by mass or more. However, if it is added in excess, it is not preferable from the viewpoint of cost, and considering the balance with the effect, it is preferable to limit the amount to 10 parts by mass.

本発明の組成物のもうひとつの必須成分は、低DEのデキストリンである。 デキストリンとは、澱粉を酵素又は酸により分解した澱粉分解物であり、冷水可溶である。本発明で用いるデキストリンは、DE(Dextrose Equivalentの略。完全に分解されてすべてグルコースとなった場合はDE100となる。)の値が低い、具体的には、DEが0.5以上19未満であることが好ましく、1以上9未満、さらには1以上7未満がより好ましい。デキストリンの原料となる澱粉種はとくに限定されず、タピオカ、甘藷、コーン、米、馬鈴薯、小麦、及びこれらの糯種など、どのような種であってもよいが、本発明の効果を効率よく得る観点からはタピオカ、甘藷、コーンから選ばれる一種以上であることが好ましい。 Another essential component of the compositions of the present invention is a low DE dextrin. Dextrin is a starch hydrolyzate obtained by hydrolyzing starch with enzymes or acids, and is soluble in cold water. The dextrin used in the present invention has a low DE (abbreviation of Dextrose Equivalent. When it is completely decomposed into glucose, it becomes DE100). It is preferably 1 or more and less than 9, and more preferably 1 or more and less than 7. Starch species that are raw materials for dextrin are not particularly limited, and may be any species such as tapioca, sweet potato, corn, rice, potato, wheat, and glutinous seeds thereof. From the viewpoint of obtaining, it is preferably one or more selected from tapioca, sweet potato, and corn.

本発明の組成物におけるデキストリンの使用割合は、ペースト状又はミンチ状とした食材100質量部に対し少なくとも1質量部以上であることを要するが、多用すると生地粘度の低下における成形不良及び糊感(滑る食感)が出現するため、10質量部を超えないことが望ましい。すなわち、デキストリンの好ましい添加量は、1~10質量部であり、より好ましくは2~8質量部、さらに好ましくは3~5質量部である。デキストリンは、粉状のまま材料に混ぜ込んでもよいが、材料のひとつである水や調味液といった液体に予め溶解しておき、これを他の材料(ミンチ肉や魚肉ペーストなど)に混ぜ込むほうがより均一に分散され、本発明の効果が効率よく発揮される。 The proportion of dextrin used in the composition of the present invention must be at least 1 part by mass or more per 100 parts by mass of the paste-like or minced food material. It is desirable not to exceed 10 parts by mass because a slippery texture appears. That is, the amount of dextrin added is preferably 1 to 10 parts by mass, more preferably 2 to 8 parts by mass, and still more preferably 3 to 5 parts by mass. Dextrin can be mixed into the ingredients as it is in powder form, but it is better to dissolve it in a liquid such as water or a seasoning liquid, which is one of the ingredients, and then mix it with other ingredients (minced meat, fish paste, etc.). It is dispersed more uniformly, and the effects of the present invention are exhibited efficiently.

本発明の食品の特徴は、調理後冷めてもやわらかい、又は冷凍解凍後にもやわらかいまま保形されることにあり、具体的には、20℃及び45℃のいずれにおいても硬さが5,000N/m以下であることをいう。この硬さは、食感計測器、例えば、CREEPMETER RE-33005B((株)山電)のテクスチャー解析ソフトを用い、20mmプランジャー、圧縮速度10mm/sec、及びクリアランス30%の条件で2回圧縮し、測定することができる。一方、凝集性及び付着性は、硬さ測定と同様の機器及び条件で測定することができ、硬さが1 回目の圧縮ピークの高さ(N/m)で表されるのに対し、付着性は1回目の圧縮直後の引っ張り過程の負の応力を示すピーク面積(J/m)、凝集性は2回目の圧縮ピークと1回目の圧縮ピークの面積比で表される。 The feature of the food of the present invention is that it is soft even after being cooked and cooled, or that it maintains its shape while being soft even after being frozen and thawed. / m2 or less. This hardness is measured by using a texture measuring instrument such as CREEPMETER RE-33005B (Yamaden Co., Ltd.) texture analysis software, and compressing twice under the conditions of a 20 mm plunger, a compression speed of 10 mm / sec, and a clearance of 30%. and can be measured. On the other hand, cohesion and adhesion can be measured with the same equipment and conditions as hardness measurement, and hardness is expressed by the height of the first compression peak (N/m 2 ), The adhesion is expressed by the peak area (J/m 3 ) indicating the negative stress in the process of tension immediately after the first compression, and the cohesion is expressed by the area ratio between the second compression peak and the first compression peak.

本発明の食品の特徴は、上述のとおり、20℃及び45℃のいずれにおいても硬さが5,000N/m以下であることが必須である。また、食品加熱後に「歩留まり」を測定しておくことは、食品の離水の確認に役立つ。本明細書における歩留まりとは、「加熱前重量に対する加熱後重量の割合(%)」である。歩留まり(%)が高いほど食品が水分を保持しているということであり、歩留まりが高いということは、食感のやわらかさにつながる。 As described above, the food of the present invention must have a hardness of 5,000 N/m 2 or less at both 20°C and 45°C. In addition, measuring the "yield" after heating the food is useful for confirming the syneresis of the food. The yield in this specification is "the ratio (%) of the weight after heating to the weight before heating". A higher yield (%) means that the food retains more moisture, and a higher yield leads to a softer texture.

以下、本発明について具体的に詳述するが、本発明はこれに限定されるものでない。 The present invention will be specifically described in detail below, but the present invention is not limited thereto.

<やわらか鶏だんご>
以下の表1の原料のうち、デキストリンと加工澱粉を水に溶解・懸濁しておき、これを残りの原料とともにミキサーで混合し、20gずつ取り分けて団子状に成形する。次に、蒸気の上がった蒸し器に入れて蒸し上げ(90℃、8分)、-40℃で急速冷凍(数時間)後、-18℃で1晩以上保存する。
<Soft chicken dumpling>
Among the raw materials shown in Table 1 below, dextrin and modified starch are dissolved and suspended in water, mixed with the rest of the raw materials in a mixer, and 20 g each is taken out and formed into a dumpling. Next, put it in a steamer with rising steam, steam (90°C, 8 minutes), quickly freeze at -40°C (several hours), and store at -18°C overnight or longer.

上述の冷凍した鶏だんごを電子レンジ(500W、6個当たり2~2分30秒加熱)で解凍し、一部(比較例8と実施例3)は、冷蔵庫に一晩置いて自然解凍した。その硬さ、凝集性及び付着性は、クリープメーター(山電(株)「RE2-3305B」)とテクスチャー解析ソフトを用い、20mmプランジャー、圧縮速度10mm/sec、及びクリアランス30%の条件で2回圧縮して測定した。また、鶏だんごの加熱前後の重量を測定しておき、歩留まり((加熱後重量÷加熱前重量)×100%)を算出した。以上の測定結果を表1に示す。なお、表中、「PDx#1」及び「PDx#100」は、それぞれ、松谷化学工業(株)の澱粉分解物製品「パインデックス#1」(DE7~9)及び「パインデックス#100」(DE2~5)の略であり、「レアタップST」は、同社のヒドロキシプロピル化リン酸架橋澱粉(ワキシータピオカ原料、DS0.13、沈降積10)、「松谷マリーゴールド」は、同社のヒドロキシプロピル澱粉(タピオカ原料、DS0.16、沈降積10)「WR-1」は同社の漂白もち米澱粉である。 The above-mentioned frozen chicken dumplings were thawed in a microwave oven (500 W, heating for 2 to 2 minutes and 30 seconds per 6 pieces), and some (Comparative Example 8 and Example 3) were placed in a refrigerator overnight to defrost naturally. The hardness, cohesiveness and adhesiveness were evaluated using a creep meter (Yamaden Co., Ltd. "RE2-3305B") and texture analysis software under the conditions of a 20 mm plunger, a compression speed of 10 mm / sec, and a clearance of 30%. Measured by compressing twice. In addition, the weight of the chicken dumpling before and after heating was measured, and the yield ((weight after heating/weight before heating)×100%) was calculated. Table 1 shows the above measurement results. In the table, "PDx#1" and "PDx#100" are the starch hydrolyzate products of Matsutani Chemical Industry Co., Ltd. "Paindex #1" (DE7-9) and "Paindex #100" ( DE 2-5), "Raatap ST" is the company's hydroxypropylated phosphate cross-linked starch (waxy tapioca raw material, DS 0.13, sedimentation product 10), and "Matsutani Marigold" is the company's hydroxypropyl starch. (Tapioca raw material, DS 0.16, sedimentation volume 10) "WR-1" is the company's bleached glutinous rice starch.

鶏モモミンチ100質量部に対してレアタップSTを2質量部添加すると、45℃における硬さが50,000N/mを超え、冷めたときにさらに硬い食感となった(比較例2)。そこで、さらにPDx#1を3質量部添加してみたところ、依然、20℃における硬さは50,000N/mを超え、冷めると硬い食感となった(比較例7)。しかし、PDx#1でなくPDx#100を3質量部さらに添加したときは、20℃における硬さは47,537N/mであり、冷めてもやわらかい食感を維持していた(実施例1)。次に、レアタップSTは添加せずに、PDx#100を3質量部のみ添加してみると、20℃における硬さは50,000N/mを超え、冷めたときにさらに硬い食感となった(比較例1)。ここまでで、PDx#1でなくPDx#100がやわらかさ維持に効果的であることが判明したので、以降、PDx#100を用いた配合でさらに検討することとした。 When 2 parts by mass of rare tap ST was added to 100 parts by mass of minced chicken thighs, the hardness at 45°C exceeded 50,000 N/m 2 , and the texture became even harder when cooled (Comparative Example 2). Therefore, when 3 parts by mass of PDx#1 was further added, the hardness at 20°C still exceeded 50,000 N/m 2 and the texture became hard when cooled (Comparative Example 7). However, when 3 parts by mass of PDx#100 was added instead of PDx#1, the hardness at 20°C was 47,537 N/m 2 , and the soft texture was maintained even after cooling (Example 1). ). Next, when only 3 parts by mass of PDx #100 was added without adding rare tap ST, the hardness at 20°C exceeded 50,000 N/m 2 and the texture became even harder when cooled. (Comparative Example 1). So far, it has been found that PDx#100, not PDx#1, is effective in maintaining softness.

PDx#100がやわらかさ維持に効果的であったので、レアタップSTを2から1質量部に減らして鶏だんごを作製したところ、20℃における硬さは71,087N/mであり、50,000N/mを超えていた(比較例3)。そこで、PDx#100の添加量を3質量部から5質量部に増やしたところ、20℃における硬さは66,740N/mであり、いまだ50,000N/mを超えていた(比較例4)。次に、PDx#100を3質量部のままとし、レアタップSTを6質量部まで増やしたところ、20℃における硬さは38,303N/mであり、レアタップSTの添加量を増やすほどに冷めてもやわらかい食感を維持していた(実施例2)。 PDx #100 was effective in maintaining softness, so when chicken dumplings were produced by reducing rare tap ST from 2 to 1 part by mass, the hardness at 20 ° C. was 71,087 N / m 2 , 000 N/m 2 (Comparative Example 3). Therefore, when the amount of PDx#100 added was increased from 3 parts by mass to 5 parts by mass, the hardness at 20°C was 66,740 N/m 2 , still exceeding 50,000 N/m 2 (comparative example 4). Next, when the amount of PDx#100 was kept at 3 parts by mass and the amount of rare tap ST was increased to 6 parts by mass, the hardness at 20°C was 38,303 N/m 2 . However, the soft texture was maintained (Example 2).

レアタップST以外の各澱粉による効果を検討するため、レアタップSTをヒドロキシルプロ化タピオカ澱粉の「松谷マリーゴールド」(比較例5)、又は漂白もち米澱粉の「WR-1」(比較例6)に置き換えて鶏だんごの硬さを確認したところ、20℃における硬さは50,000N/mを超えており、本発明にいうところの効果は見られなかった。 In order to examine the effect of each starch other than rare tap ST, rare tap ST was added to hydroxylated tapioca starch "Matsutani Marigold" (Comparative Example 5) or bleached glutinous rice starch "WR-1" (Comparative Example 6). When the hardness of the chicken dumpling was checked by replacing it, the hardness at 20° C. exceeded 50,000 N/m 2 , and the effect of the present invention was not observed.

また、以上において本発明にいう効果がみられた実施例1の鶏だんごについて、加熱解凍でなく自然解凍による影響を検討したところ、自然解凍によっても20℃における硬さは50,000N/m未満であり、解凍方法による影響はほとんどみられなかった(実施例3)。 In addition, when examining the effect of natural thawing instead of heat thawing, the chicken dumpling of Example 1, in which the effect of the present invention was observed above, was found to have a hardness of 50,000 N/m 2 at 20°C even with natural thawing. The thawing method had almost no effect (Example 3).

<やわらかから揚げ>
下の表2の原料のうち、デキストリンと加工澱粉を水に溶解・懸濁しておき、これを残りの原料とともにミキサーで混合し、20gずつ取り分けて団子状に成形する。次に、蒸気の上がった蒸し器に入れて蒸し上げ(90℃、2分30秒)、から揚げ粉(日清フーズ株式会社製)をまぶし、油調(170℃、2分30秒)する。その後、-40℃で急速冷凍(数時間)後、-18℃で1晩以上保存する。
<Deep fried chicken>
Among the raw materials shown in Table 2 below, dextrin and modified starch are dissolved and suspended in water, mixed with the rest of the raw materials in a mixer, and 20 g each is taken and formed into a dumpling. Next, it is placed in a steamer with rising steam and steamed (90°C, 2 minutes and 30 seconds), sprinkled with fried chicken powder (manufactured by Nisshin Foods Co., Ltd.), and oiled (170°C, 2 minutes and 30 seconds). It is then flash frozen at -40°C (for several hours) and then stored at -18°C overnight or longer.

上述の冷凍から揚げを電子レンジ(500W、6個当たり2~2分30秒加熱)で解凍した。その硬さ、凝集性及び付着性は、クリープメーター(山電(株)「RE2-3305B」)とテクスチャー解析ソフトを用いて、20mmプランジャー、圧縮速度10mm/sec、及びクリアランス30%の条件で2回圧縮して測定した。測定結果(表2)のとおり、から揚げの場合も、鶏モモミンチ100質量部に対してPDx#100を3質量部及びレアタップSTを2質量部添加しておくと、20℃における硬さは50,000N/m未満となり、冷めてもやわらかい状態が維持されていた。 The above-mentioned frozen karaage was thawed in a microwave oven (500 W, heating for 2 to 2 minutes and 30 seconds per 6 pieces). The hardness, cohesiveness and adhesiveness were measured using a creep meter (Yamaden Co., Ltd. "RE2-3305B") and texture analysis software under the conditions of a 20 mm plunger, a compression speed of 10 mm / sec, and a clearance of 30%. Measured with two compressions. As shown in the measurement results (Table 2), even in the case of fried chicken, if 3 parts by mass of PDx #100 and 2 parts by mass of rare tap ST are added to 100 parts by mass of minced chicken thighs, the hardness at 20 ° C. is 50. ,000 N/m 2 , and the soft state was maintained even after cooling.

<やわらかかまぼこ>
下の表3の配合の冷凍すり身に対し、水(氷)、塩、その他紛体原料、液体原料の順に添加して擂潰したものを団子状に成形し(20g)、蒸気の上がった蒸し器に入れて蒸し上げ(90℃、15分)、冷蔵(4℃)で24時間保存する。
<Soft Kamaboko>
Water (ice), salt, other powder raw materials, and liquid raw materials were added in order to the frozen surimi of the composition shown in Table 3 below, and the mixture was ground and formed into a dumpling shape (20 g). Put it in, steam it (90°C, 15 minutes), and store it in a refrigerator (4°C) for 24 hours.

上述のかまぼこを常温に戻し。その硬さ、凝集性及び付着性を、クリープメーター(山電(株)「RE2-3305B」)及びテクスチャー解析ソフトを用い、20mmプランジャー、圧縮速度10mm/sec、及びクリアランス30%の条件で2回圧縮して測定した。測定結果(表3)のとおり、魚のすり身100質量部に対してPDx#100を3質量部及びレアタップSTを2質量部添加しておくと、20℃における硬さは50,000N/m未満となり、冷めてもやわらかさが維持されていた。一方、いずれも添加しない、又はPDx#100のみを3質量部添加しても、硬さは50,000N/m未満にならなかった。 Return the kamaboko above to room temperature. The hardness, cohesiveness and adhesiveness were measured using a creep meter (Yamaden Co., Ltd. "RE2-3305B") and texture analysis software under the conditions of a 20 mm plunger, a compression speed of 10 mm / sec, and a clearance of 30%. Measured by compressing twice. As shown in the measurement results (Table 3), when 3 parts by mass of PDx#100 and 2 parts by mass of rare tap ST are added to 100 parts by mass of fish surimi, the hardness at 20 ° C. is less than 50,000 N / m 2 , and the softness was maintained even when cooled. On the other hand, the hardness did not become less than 50,000 N/m 2 even when neither of them was added or only 3 parts by mass of PDx#100 was added.

Claims (5)

ヒドロキシプロピル化又はアセチル化の加工を施してなるワキシータピオカ澱粉2~10質量部に対し、DE1~7のデキストリンを1~5質量部の割合で含む、ミンチ状又はペースト状の食材を加熱成形するための組成物。 A minced or pasty food material containing 2 to 10 parts by mass of waxy tapioca starch processed by hydroxypropylation or acetylation and 1 to 5 parts by mass of dextrin having a DE of 1 to 7 is heated and molded. composition for. 澱粉が、さらにアジピン酸又はリン酸により架橋された澱粉である、請求項1記載の組成物。 2. The composition of claim 1, wherein the starch is a starch cross-linked with adipic acid or phosphoric acid. ミンチ状又はペースト状の食材100質量部に対し、ヒドロキシプロピル化又はアセチル化の加工を施してなるワキシータピオカ澱粉を2~10質量部とDE1~7のデキストリンを1~5質量部の割合で含み、45℃及び20℃における硬さが50,000N/m以下である、成形加熱食品。 2 to 10 parts by mass of waxy tapioca starch processed by hydroxypropylation or acetylation and 1 to 5 parts by mass of dextrin with a DE of 1 to 7 are contained in 100 parts by mass of minced or pasty food material. , a molded heated food having a hardness of 50,000 N/m 2 or less at 45°C and 20°C. ミンチ状又はペースト状の食材100質量部に対し、ヒドロキシプロピル化又はアセチル化の加工を施してなるワキシータピオカ澱粉2~10質量部とDE1~7のデキストリン1~5質量部を、(A)そのまま混合する、又は(B)水若しくは調味液に懸濁若しくは溶解してから混合する、45℃及び20℃における硬さが50,000N/m以下である成形加熱食品の製造方法。 2 to 10 parts by mass of waxy tapioca starch processed by hydroxypropylation or acetylation and 1 to 5 parts by mass of dextrin of DE 1 to 7 are added to 100 parts by mass of minced or pasty food material (A) as it is. A method for producing a molded heated food having a hardness of 50,000 N/m 2 or less at 45°C and 20°C by mixing, or (B) suspending or dissolving in water or a seasoning liquid and then mixing. ミンチ状又はペースト状の食材100質量部に対し、ヒドロキシプロピル化又はアセチル化の加工を施してなるワキシータピオカ澱粉2~10質量部とDE1~7のデキストリン1~5質量部を添加する、成形加熱食品の20℃におけるやわらかさを維持する方法。 Add 2 to 10 parts by mass of waxy tapioca starch processed by hydroxypropylation or acetylation and 1 to 5 parts by mass of dextrin with a DE of 1 to 7 to 100 parts by mass of minced or pasty food material, and heat for molding. A method for maintaining the softness of food at 20°C.
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