JP2023120009A5 - - Google Patents
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- JP2023120009A5 JP2023120009A5 JP2022023169A JP2022023169A JP2023120009A5 JP 2023120009 A5 JP2023120009 A5 JP 2023120009A5 JP 2022023169 A JP2022023169 A JP 2022023169A JP 2022023169 A JP2022023169 A JP 2022023169A JP 2023120009 A5 JP2023120009 A5 JP 2023120009A5
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- Prior art keywords
- layer
- thin film
- polymer composite
- composite thin
- film according
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- 239000002131 composite material Substances 0.000 claims 26
- 229920000642 polymer Polymers 0.000 claims 26
- 239000010409 thin film Substances 0.000 claims 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 20
- 239000002041 carbon nanotube Substances 0.000 claims 20
- 229910021393 carbon nanotube Inorganic materials 0.000 claims 20
- 239000007789 gas Substances 0.000 claims 11
- 239000006185 dispersion Substances 0.000 claims 9
- 239000000463 material Substances 0.000 claims 8
- 239000002904 solvent Substances 0.000 claims 6
- 239000002861 polymer material Substances 0.000 claims 5
- 238000004519 manufacturing process Methods 0.000 claims 4
- 239000011259 mixed solution Substances 0.000 claims 4
- 238000001914 filtration Methods 0.000 claims 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 238000007865 diluting Methods 0.000 claims 2
- 238000004898 kneading Methods 0.000 claims 2
- 238000000926 separation method Methods 0.000 claims 2
- 239000000243 solution Substances 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000002075 main ingredient Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000012466 permeate Substances 0.000 claims 1
- -1 polysiloxane Polymers 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
Claims (17)
主に高分子材料で構成され前記第１の層と接するように重畳された第２の層と、を備え、
前記第１の層において、前記カーボンナノチューブは、主に前記第１の層の平面方向に延伸して二次元的なチューブネットワークを構成し、
前記第２の層は、所定のガスに対する選択透過性を有することを特徴とする高分子複合薄膜。 a first layer containing carbon nanotubes;
a second layer mainly composed of a polymeric material and superimposed so as to be in contact with the first layer,
In the first layer, the carbon nanotubes mainly extend in a plane direction of the first layer to form a two-dimensional tube network,
A polymer composite thin film, wherein the second layer has selective permselectivity for a predetermined gas.
前記第１の層の厚み方向に、
複数の前記カーボンナノチューブが存在する第１の領域Ａ１と、
単一の前記カーボンナノチューブが存在する第２の領域Ａ２と、
前記カーボンナノチューブが不在である第３の領域Ａ３と、
を備えることを特徴とする請求項１～請求項５のいずれか一項に記載の高分子複合薄膜。 In the plane A of the first layer,
In the thickness direction of the first layer,
a first region A1 in which a plurality of carbon nanotubes exist;
a second region A2 in which a single carbon nanotube exists;
a third region A3 in which the carbon nanotubes are absent;
The polymer composite thin film according to any one of claims 1 to 5, comprising:
前記カーボンナノチューブは、前記高分子材料に分散され、主に当該高分子複合薄膜の平面方向に延伸して二次元的なチューブネットワークを構成していることを特徴とする高分子複合薄膜。 A polymer composite thin film containing a polymer material and carbon nanotubes and having selective permselectivity for a predetermined gas,
A polymer composite thin film characterized in that the carbon nanotubes are dispersed in the polymer material and mainly extend in a plane direction of the polymer composite thin film to form a two-dimensional tube network.
前記高分子複合薄膜の厚み方向に、
複数の前記カーボンナノチューブが存在する第１の領域Ａ１と、
単一の前記カーボンナノチューブが存在する第２の領域Ａ２と、
前記カーボンナノチューブが不在である第３の領域Ａ３と、
を備えることを特徴とする請求項８に記載の高分子複合薄膜。 In the plane A of the polymer composite thin film,
In the thickness direction of the polymer composite thin film,
a first region A1 in which a plurality of carbon nanotubes exist;
a second region A2 in which a single carbon nanotube exists;
a third region A3 in which the carbon nanotubes are absent;
The polymer composite thin film according to claim 8, comprising:
前記高分子複合薄膜に対してガスを供給するガス供給部と、
を備えるガス分離装置。 The polymer composite thin film according to any one of claims 1 to 11,
a gas supply unit that supplies gas to the polymer composite thin film;
A gas separation device comprising:
前記高分子複合薄膜に対してガスを供給するガス供給部と、
を備え、
前記ガス供給部は、前記第２の層、前記第１の層の順にガスが透過するようにガスを供給することを特徴とするガス分離装置。 The polymer composite thin film according to any one of claims 1 to 7,
a gas supply unit that supplies gas to the polymer composite thin film;
Equipped with
The gas separation device is characterized in that the gas supply unit supplies gas so that the gas passes through the second layer and the first layer in this order.
犠牲層が形成された基材上に前記犠牲層を被覆するように前記カーボンナノチューブ水分散液を塗布・乾燥させて主に前記カーボンナノチューブで構成された第１の層を形成する第２工程と、
前記第１の層を被覆するように前記高分子材料含有溶液を塗布・硬化させて第２の層を形成する第３工程と、
前記犠牲層を溶解させて、前記第１の層及び前記第２の層で構成される高分子複合薄膜を前記基材から剥離する第４工程と、
を含むことを特徴とする高分子複合薄膜の製造方法。 A first step of preparing a carbon nanotube aqueous dispersion containing carbon nanotubes and a polymer material-containing solution containing a polymer material;
a second step of coating and drying the carbon nanotube aqueous dispersion on the base material on which the sacrificial layer is formed so as to cover the sacrificial layer to form a first layer mainly composed of the carbon nanotubes; ,
a third step of coating and curing the polymeric material-containing solution so as to cover the first layer to form a second layer;
a fourth step of dissolving the sacrificial layer and peeling off the polymer composite thin film composed of the first layer and the second layer from the base material;
A method for producing a polymer composite thin film, comprising:
前記水－第１溶剤分散液に高分子材料の主剤を加えて混錬した後に、前記高分子材料を硬化させる硬化剤を加え、これを混錬して混合溶液を得る第２工程と、
前記混合溶液を第２溶剤で希釈して希釈後混合溶液を得る第３工程と、
犠牲層が形成された基材上に前記犠牲層を被覆するように前記希釈後混合溶液を塗布・硬化させて高分子複合薄膜を製膜する第４工程と、
前記犠牲層を溶解させて、前記高分子複合薄膜を前記基材から剥離する第５工程と、
を有することを特徴とする高分子複合薄膜の製造方法。 A first step of preparing a water-first solvent dispersion by diluting a carbon nanotube aqueous dispersion containing carbon nanotubes with a first solvent;
A second step of adding a main ingredient of a polymeric material to the water-first solvent dispersion and kneading it, then adding a curing agent for curing the polymeric material and kneading it to obtain a mixed solution;
a third step of diluting the mixed solution with a second solvent to obtain a diluted mixed solution;
a fourth step of forming a polymer composite thin film by applying and curing the diluted mixed solution so as to cover the sacrificial layer on the base material on which the sacrificial layer is formed;
a fifth step of dissolving the sacrificial layer and peeling the polymer composite thin film from the base material;
A method for producing a polymer composite thin film, comprising:
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2022023169A JP7418758B2 (en) | 2022-02-17 | 2022-02-17 | Polymer composite thin film, gas separation device equipped with this polymer composite thin film, and method for manufacturing the polymer composite thin film |
| PCT/JP2023/005046 WO2023157844A1 (en) | 2022-02-17 | 2023-02-14 | Polymer composite thin film, gas separation device provided with said polymer composite thin film, and method for producing polymer composite thin film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2022023169A JP7418758B2 (en) | 2022-02-17 | 2022-02-17 | Polymer composite thin film, gas separation device equipped with this polymer composite thin film, and method for manufacturing the polymer composite thin film |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2023120009A JP2023120009A (en) | 2023-08-29 |
| JP2023120009A5 true JP2023120009A5 (en) | 2023-09-19 |
| JP7418758B2 JP7418758B2 (en) | 2024-01-22 |
Family
ID=87578332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022023169A Active JP7418758B2 (en) | 2022-02-17 | 2022-02-17 | Polymer composite thin film, gas separation device equipped with this polymer composite thin film, and method for manufacturing the polymer composite thin film |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP7418758B2 (en) |
| WO (1) | WO2023157844A1 (en) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7931838B2 (en) | 2006-08-31 | 2011-04-26 | Virginia Tech Intellectual Properties, Inc. | Method for making oriented single-walled carbon nanotube/polymer nano-composite membranes |
| US7993524B2 (en) | 2008-06-30 | 2011-08-09 | Nanoasis Technologies, Inc. | Membranes with embedded nanotubes for selective permeability |
| JP6679117B2 (en) | 2016-10-26 | 2020-04-15 | 国立大学法人信州大学 | Nanocarbon separation membrane, nanocarbon composite separation membrane, and method for producing nanocarbon separation membrane |
| JP7018661B2 (en) | 2017-06-09 | 2022-02-14 | 国立研究開発法人産業技術総合研究所 | Method for manufacturing carbon nanotube dispersion liquid, carbon nanotube dispersion liquid, and method for manufacturing carbon nanotube composite film |
| EP3672708A4 (en) | 2017-08-21 | 2021-04-28 | Ohio State Innovation Foundation | Membranes for gas separation |
| JP6999958B2 (en) | 2019-12-03 | 2022-02-10 | 国立大学法人信州大学 | Manufacturing method of semipermeable membrane and semipermeable membrane |
-
2022
- 2022-02-17 JP JP2022023169A patent/JP7418758B2/en active Active
-
2023
- 2023-02-14 WO PCT/JP2023/005046 patent/WO2023157844A1/en unknown
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