JP2023096146A - Packaging paper - Google Patents

Abstract

To provide packaging paper that achieves a reduced amount of use of plastic, and is excellent in processing suitability.SOLUTION: This invention relates to packaging paper having at least one heat seal layer on at least one side of a paper substrate, the heat seal layer containing an ionomer, and a total amount of dry coating of the heat seal layer being 2-10 g/m2. The packaging paper has a basis weight of 80 g/m2 to 500 g/m2, and the packaging paper has a degree of Stockigt sizing of 5 seconds or more.SELECTED DRAWING: None

Description

TECHNICAL FIELD The present invention relates to a packaging paper that uses a reduced amount of plastic and is excellent in processability. In particular, the present invention relates to packaging paper that is suitable for folding and gluing, and has excellent heat-sealing properties for thick containers such as boxes and cartons.

In recent years, the problem of plastic waste has become more serious. The world's plastic production is said to exceed 400 million tons/year, and among them, plastic production in the packaging and container sector is large, causing plastic waste. Plastic does not decompose semi-permanently, and its garbage turns into microplastics in the natural environment, which has a serious adverse effect on the ecosystem. The most commonly used plastics for packaging containers are polyethylene terephthalate (PET), which is used for beverage bottles, etc., and polyethylene (PE) and polypropylene (PP), which are used for laminating plastic bags and containers. . In particular, the pollution of the ocean is remarkable, and it is said that the plastic garbage cannot be collected. In the future, it is necessary for the global environment to reduce the use of plastics.

On the other hand, the application of biodegradable plastics that can be completely decomposed by microorganisms has been proposed all over the world as a countermeasure against plastic waste. Biodegradable plastics decompose in the natural world within a certain period of time, but they are still garbage until they are decomposed. See Patent Documents 1 and 2).

Substituting paper for plastic has been proposed as an immediate countermeasure, but when processing paper into bags and containers, a large amount of polyethylene or polypropylene is laminated and used as a heat sealing agent. be. The amount of these plastics to be laminated varies depending on the product concept, but is generally 20 to 50 g/m ² , and may be as large as 300 g/m ² . Therefore, even in packaging containers in which paper is substituted for plastic, there is still the problem that the amount of plastic used is not sufficiently reduced, and means for directly reducing the use of plastic is urgently needed.

JP 2012-148444 A JP 2013-141763 A

SUMMARY OF THE INVENTION An object of the present invention is to provide a packaging paper that can reduce the amount of plastic used and has excellent processability. In particular, the present invention relates to packaging paper that is suitable for folding and gluing, and that is suitable for thick containers such as boxes and cartons, and has excellent heat-sealing properties.

In the present invention, an ionomer is used in order to reduce the amount of polyethylene or polypropylene used in conventional plastic-laminated paper (hereinafter sometimes abbreviated as poly-laminated paper). That is, the packaging paper according to the present invention is a packaging paper having at least one or more heat-sealing layers on at least one surface of a paper substrate, wherein the heat-sealing layer contains an ionomer, and the coating amount of the heat-sealing layer is is 2 to 10 g/m ² . Compared to the amount of polyethylene or polypropylene used in the heat seal layer of conventional polylaminated paper, which exceeds 20 g/m ² , the amount of plastic used for the heat seal layer can be reduced to about 10 to 50% of the conventional amount. can be reduced. Here, the ionomer is a synthetic resin in which macromolecules are aggregated by utilizing the cohesive force of metal ions, and is a synthetic resin in which acrylic acid or methacrylic acid is combined with ethylene or the like. For example, it is produced by intermolecular bonding of an acrylic polymer and ethylene by adding a metal cation such as sodium or zinc.

Further, in the present invention, it is necessary that the Stockigt sizing degree of the wrapping paper is 5 seconds or more. If the Stockigt sizing degree is less than 5 seconds, the glue is absorbed by the paper during pasting, resulting in poor adhesiveness. In addition, the ionomer melted by heat during heat-sealing is absorbed by the paper substrate, resulting in poor adhesive strength. In addition, since the heat-seal layer is thinner than the polyethylene layer, the wrapping paper is broken, especially during folding.

In addition, since the basis weight of the packaging paper of the present invention is 80 g/m ² to 500 g/m ² , tearing and cracking during the folding process during processing into boxes, cartons, etc. (potato cartons, etc.) can be eliminated. , a packaging paper having an appearance suitable for boxes, cartons, etc. can be obtained.

With the present invention, it is possible to produce packaging paper with reduced plastic usage. If the container product uses the packaging paper of the present invention, even if it is inappropriately discharged into the natural world as garbage, it is possible to reduce the adverse effect of plastic garbage on the natural environment. It will help solve the garbage problem. In addition, the wrapping paper in the present invention is processed into general packaging containers such as bags, food cups such as ice cream, beverage cups such as coffee, food containers such as hot snacks, and trays, boxes, cases, vessels, envelopes, etc. It is possible. In particular, the packaging paper in the present invention is preferably processed into a thick container (tray, box, case, vessel, carton).

Next, the present invention will be described in detail with reference to embodiments, but the present invention should not be construed as being limited to these descriptions. Various modifications may be made to the embodiments as long as the effects of the present invention are achieved.

In the present embodiment, the ionomer is a general term for synthetic resins in which macromolecules are aggregated by utilizing the cohesive force of metal ions, and is a resin obtained by combining acrylic acid or methacrylic acid with ethylene or the like. That is, metal salts of ethylene/methacrylic acid copolymers, metal salts of ethylene/acrylic copolymers, metal salts of ethylene/urethane copolymers, metal salts of ethylene/fluoropolymer copolymers, etc. All are called ionomers. Salt-forming metals include, for example, alkali metal ions and alkaline earth metal ions, specifically sodium, potassium, calcium, magnesium and zinc ions. In the present invention, the ionomer is preferably a self-emulsifying emulsion that is a metal salt of an ethylene/methacrylic acid copolymer. A heat-sealing layer having a sufficient heat-sealing strength can be provided with a relatively small coating amount of the heat-sealing layer.

In the present embodiment, a heat seal layer can be provided by applying a heat seal layer coating liquid containing an ionomer emulsion to at least one surface of a paper substrate and drying the coating liquid. By using an ionomer emulsion, it is possible to control the amount of coating to a relatively low level, and by using a water-based ionomer emulsion, VOC emissions are eliminated and the load on the natural environment can be reduced. The coating amount of the heat seal layer is 2 to 10 g/m ² , preferably 3 to 8 g/m ² in terms of solid content, per one side of the paper substrate. If it is less than 2 g/m ² , sufficient heat seal strength cannot be achieved. Conversely, if it exceeds 10 g/m ² , the quality is excessive in terms of heat seal strength, and the plastic reduction effect is poor. In addition, in the packaging paper of the present invention, the heat seal layer is usually provided not only on a part of the surface of the paper substrate but also on the entire surface. That is, the heat-seal layer is provided not only in a portion necessary for adhesion by heat-sealing, such as in a network shape, an island shape, or a linear shape, but is provided so as to cover the entire surface of the paper base material. and good.

In addition to the ionomer emulsion, various auxiliary agents may be added to the heat seal layer coating solution. Examples thereof include viscosity modifiers, antifoaming agents, leveling agents such as surfactants and alcohols, coloring pigments, and coloring dyes. However, the addition of these auxiliaries tends to cause a decrease in the heat seal strength, so when they are added, they are preferably added in small amounts. In the present embodiment, it is preferable that the heat-sealing layer coating liquid consists only of the ionomer emulsion.

The method of applying the heat-sealing layer coating liquid is not particularly limited, and a generally used coating apparatus can be used. Air knife coater, blade coater, gravure coater, rod blade coater, roll coater, reverse roll coater, bar coater, curtain coater, die slot coater, Champlex coater, metering blade type size press coater, short dwell coater, spray Various known coating devices such as a coater, gate roll coater and lip coater can be used.

Further, in the present invention, it is necessary that the Stockigt sizing degree of the wrapping paper is 5 seconds or more. If the Stockigt sizing degree is less than 5 seconds, the glue is absorbed by the paper during pasting, resulting in poor adhesiveness. In addition, the ionomer melted by heat during heat-sealing is absorbed by the paper substrate, resulting in poor adhesive strength. In addition, since the heat-seal layer is thinner than the polyethylene layer, the wrapping paper is broken, especially during folding. In order to appropriately adjust the Stockigt sizing degree, it is preferable in the present invention to add a sizing agent, particularly to add the sizing agent internally to the substrate. As the sizing agent, any sizing agent may be used as long as the Stockigt sizing degree can be less than 5 seconds. For example, it is preferable to use a rosin sizing agent, particularly an acidic rosin sizing agent. It is preferred to use an acidic rosin size.

Further, the basis weight of the wrapping paper of the present invention is 80 g/m ² to 500 g/m ² . As a result, it is possible to obtain packaging paper that is free from tearing and cracking during the folding process, especially when processed into boxes, cartons, etc. (potato cartons, etc.), and that has an appearance suitable for boxes, cartons, etc.

In this embodiment, the heat seal layer may be formed of two or more layers. By using two or more layers, the air permeability of the packaging paper can be increased, water repellency and oil repellency can be imparted, and properties similar to or close to those of plastic film laminated paper can be obtained. It is from. When the number of heat-seal layers is two or more, it is preferable that the coating amount of the lowest heat-sealing layer closest to the paper substrate is larger than the total coating amount of the other heat-sealing layers. This is because the air permeability of the wrapping paper can be further improved, and the water repellency and oil repellency are further improved.

In this embodiment, the Z-axis strength of the wrapping paper (JPAPAN TAPPI No. 18-1, strength in the thickness direction of the paper) is preferably 150 kN/m ² or more. Eliminates tearing and cracking during folding. Preferably, it is 200 kN/m ² or more.

In this embodiment, the tensile elongation at break of the wrapping paper in the longitudinal direction of the wrapping paper is preferably 1% or more (JIS P-8113). It is possible to reduce tearing and cracking during folding of thick containers (trays, boxes, cases, containers, cartons). Preferably, the longitudinal tensile elongation at break is 1.5% or more.

In this embodiment, the longitudinal tensile strength of the wrapping paper is preferably 5 kN/m or more (JIS P-8113). It is possible to reduce tearing and cracking during folding of thick containers (trays, boxes, cases, containers, cartons). Preferably, the longitudinal tensile strength is 8 kN/m or more. In the present invention, the vertical direction means the long grain direction (MD), and the horizontal direction means the cross grain direction (CD).

In this embodiment, it is preferable that the air permeability of the wrapping paper exceeds 10000 seconds. It is more preferably 12000 seconds or more, and still more preferably 15000 seconds or more. By setting the air permeability of the wrapping paper to 10,000 seconds or more, the barrier property in the sense of blocking air is further enhanced, and the water repellency and oil repellency are further improved. The method for increasing the air permeability of the packaging paper to 10000 seconds or more is not particularly limited, but it can be achieved, for example, by using a paper base material with high air permeability. Furthermore, the air permeability of the packaging paper can also be increased by increasing the smoothness of the surface to which the heat seal coating liquid is applied. This is because it is possible to further reduce pinholes, cracks, and the like in the heat seal layer formed thereafter. For example, by providing a pigment coating layer and then performing calendering or the like, the smoothness of the surface to be coated with the heat seal coating liquid can be increased. In addition, coating two or more heat seal layers has the effect of increasing the air permeability. In the two-layer coating of the heat seal layer, the fine pinholes and cracks present in the first coating layer (lower layer) are replaced by the second coating layer (upper layer) provided on the first layer. It is thought that the air permeability increases by covering with Also, increasing the coating amount of the heat seal layer is effective in improving the air permeability. In terms of film formation of the heat seal layer, air permeability is likely to be improved by setting the drying temperature after coating of the heat seal layer coating liquid to a temperature equal to or higher than the melting point of the ionomer.

In this embodiment, it is preferable that the smoothness of the surface of the paper substrate to be coated with the heat seal coating liquid is 10 seconds or more. More preferably, it is 20 seconds or longer. The higher the smoothness of the paper substrate, the more uniform the film thickness of the heat-sealing layer provided by coating (the less likely the occurrence of fine unevenness), and as a result, the less likely the variation in heat-sealing strength will occur. A uniform heat seal strength can be imparted on a flat surface. The method for increasing the smoothness of the paper substrate is not particularly limited, and examples thereof include calendering using known calendering devices such as super calender, gross calender, shoe nip calender, and soft calender. . Also, paper on which the specular surface of the Yankee dryer is transferred, such as single-gloss kraft paper, is suitable as a paper base material with high smoothness. The heat-sealing layer may have pinholes or cracks invisible to the naked eye. In addition, a leveling agent for preventing pinholes may be added to the heat-sealing layer coating liquid as long as the effects of the present invention are not impaired.

The paper substrate used in the present embodiment is not particularly limited, and known paper substrates containing pulp as a main component can be used. Pulp, which is the main component of the paper base material, includes chemical pulp such as LBKP (bleached hardwood kraft pulp), NBKP (bleached softwood kraft pulp), GP (groundwood pulp), PGW (pressurized groundwood pulp), RMP (refiner mechanical pulp). mechanical pulp such as pulp), TMP (thermomechanical pulp), CTMP (chemithermomechanical pulp), CMP (chemi-mechanical pulp), CGP (chemigrand pulp), wood pulp such as DIP (deinked pulp), kenaf, and bagasse , bamboo, cotton, etc. can be used. These can be used alone or mixed in any ratio. In addition, synthetic fibers can be further blended within a range that does not impair the intended effects of the present invention. From the viewpoint of environmental conservation, ECF (Elemental Chlorine Free) pulp, TCF (Total Chlorine Free) pulp, waste paper pulp, and pulp obtained from planted trees are preferred. An appropriate freeness of pulp is 200 to 700 ml CSF, for example, 450 to 620 ml CSF in terms of Canadian standard freeness (JIS P 8121: 1995 "Pulp freeness test method"). Generally, it is preferable to use 90 to 100 parts by weight of hardwood pulp and 0 to 10 parts by weight of softwood pulp in the total pulp. Further, in addition to hardwood pulp, it is preferable to blend softwood pulp for enhancing the strength of folding. For example, it is preferable to use 50 to 100 parts by mass of softwood pulp and 0 to 50 parts by mass of hardwood pulp in the total pulp. Alternatively, only softwood pulp may be used as the pulp.

Paper substrates containing fillers can also be used. Examples of fillers include light calcium carbonate, heavy calcium carbonate, talc, clay, kaolin, calcined clay, titanium dioxide, and aluminum hydroxide. The filler content in the paper substrate is, for example, 1 to 30 parts by weight with respect to 100 parts by weight of dry pulp. For example, 1 to 10 parts by mass of light calcium carbonate may be included with respect to 100 parts by mass of dry pulp.

The paper substrate may also contain various known papermaking additives in addition to the pulp and filler. Examples of papermaking additives include sizing agents, internal strength agents such as wet strength agents, bulking agents, retention aids, drainage improvers, coloring dyes, coloring pigments, fluorescent whitening agents, fluorescent Decoloring agents, pitch control agents, etc. Also, a water-soluble polymer such as starch, polyvinyl alcohol or polyacrylamide may be applied.

The paper-making method for the paper substrate is not particularly limited, and includes a fourdrinier paper machine, a fourdrinier multi-layer paper machine, a cylinder paper machine, a fourdrinier multi-layer paper machine, a fourdrinier cylinder combi multi-layer paper machine, and a twin wire paper machine. It can be manufactured by various paper machines such as Further, in the present invention, the paper base material may be a single-layer paper, a multi-layer paper, or a laminate of multiple layers.

The paper substrate may be provided with one or more coating layers other than the heat seal layer, for example, a pigment coating layer containing a pigment and an adhesive may be provided. As the pigment in the pigment coating layer, known pigments used in the coating layer of general coated printing paper can be used. Examples include calcium carbonate (heavy calcium carbonate, light calcium carbonate, etc.), Kaolin (including clay), calcined clay, talc, magnesium carbonate, barium sulfate, calcium sulfate, titanium dioxide, zinc oxide, zinc sulfate, zinc carbonate, calcium silicate, aluminum silicate, magnesium silicate, diatomaceous earth, aluminum hydroxide, hydroxide Examples include inorganic pigments such as magnesium, acryl, styrene, vinyl chloride, nylon itself, and organic pigments obtained by copolymerizing these (so-called plastic pigments). For example, a combination of 20 to 40 parts by weight of kaolin and 60 to 80 parts by weight of ground calcium carbonate can be used as the pigment. As the adhesive, known adhesives used for the coating layer of general coated printing paper can be used. Starches such as esterified starch, etherified starch, cationic starch and amphoteric starch, water-soluble polymers such as gelatin, casein, soybean protein, polyvinyl alcohol, vinyl acetate, ethylene vinyl acetate, polyurethane resin, acrylic resin, Synthetic resins such as polyester-based resins and polyamide-based resins can be exemplified. The mixing ratio of the pigment and the adhesive in the pigment coating layer is not particularly limited, but it is preferable to use 5 to 50 parts by weight of the adhesive per 100 parts by weight of the pigment. For example, as the adhesive, a combination of 1 to 5 parts by weight of phosphate esterified starch and 5 to 15 parts by weight of styrene-butadiene latex can be used with respect to 100 parts by weight of the pigment. The pigment coating layer may contain various auxiliary agents within a range that does not impair the intended effects of the present invention, such as viscosity modifiers, softening agents, gloss imparting agents, waterproofing agents, dispersants, and flow modifiers. , ultraviolet absorbers, stabilizers, antistatic agents, cross-linking agents, sizing agents, fluorescent whitening agents, colorants, pH adjusters, antifoaming agents, plasticizers, and preservatives. The coating amount of such a pigment coating layer is, for example, 2 to 40 g/m ² in terms of solid content per side of the paper substrate. As one embodiment of the wrapping paper of the present invention, the heat seal layer may be provided on such a pigment coating layer, and as another embodiment, only one side has a pigment coating layer. A heat seal layer may be provided on the side of the paper substrate provided with the non-pigment coating layer.

EXAMPLES Next, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples. In addition, "parts" and "%" in the examples indicate "mass parts" and "mass%", respectively, unless otherwise specified. The number of parts to be added is a value in terms of solid content.

(Example 1)
(Preparation of paper substrate)
100 parts of bleached hardwood kraft pulp of Canadian standard freeness 500mlcsf, 5 parts of light calcium carbonate (trade name: TP-221BM, manufactured by Okutama Kogyo Co., Ltd.), 0.3 parts of cationized starch (trade name: Neotac 20T, manufactured by Nihon Shokuhin Kako Co., Ltd.) A modified rosin sizing agent (acidic sizing agent) (trade name: Hersize NES-500, manufactured by Harima Kasei Co., Ltd.) was added to 0.2 parts of water to prepare a paper stock, and a fourdrinier multi-cylinder paper machine was used. A base paper having a basis weight of 193 g/m ² was prepared. This base paper was coated with oxidized starch (trade name: M-200, manufactured by Sansho Co., Ltd.) by a size press so that the dry coating amount per both sides was 2 g/m ² , and dried to give a basis weight of 195 g/m ² . was obtained.

(Preparation of wrapping paper)
On one side of the paper substrate obtained above, an aqueous ionomer emulsion (trade name: Chemipearl S-300, manufactured by Mitsui Chemicals, composition: metal salt of ethylene/methacrylic acid copolymer, self-emulsifying emulsion, microtrack method average particle diameter of 0.5 μm) was applied using an air knife coater so that the dry coating amount was 5 g/m ² , dried to form a heat seal layer, and a packaging paper having a basis weight of 200 g/m ² was prepared. made. The Stockigt sizing degree was 50 seconds.

(Example 2)
A wrapping paper was prepared in the same manner as in Example 1, except that 100 parts of softwood unbleached kraft pulp was used as the pulp. The Stockigt sizing degree was 60 seconds.

(Example 3)
A wrapping paper was prepared in the same manner as in Example 1, except that the amount of the rosin sizing agent added was changed to 0.05 parts. The Stockigt sizing degree was 10 seconds.

(Example 4)
A packaging paper was prepared in the same manner as in Example 1, except that the modified rosin sizing agent was changed to 0.5 part. The Stockigt sizing degree was 250 seconds.

(Example 5)
A packaging paper was prepared in the same manner as in Example 1, except that the cationized starch was changed to 0.1 part. The Stockigt sizing degree was 51 seconds.

(Example 6)
A wrapping paper was prepared in the same manner as in Example 1, except that 40 parts of softwood kraft pulp and 60 parts of hardwood kraft pulp were used. The Stockigt sizing degree was 54 seconds.

(Example 7)
A packaging paper was prepared in the same manner as in Example 1, except that the amount of the cationized starch was changed to 0.6 parts. The Stockigt sizing degree was 54 seconds.

(Comparative example 1)
On one side of the paper substrate prepared in Example 1, low-density polyethylene (Petrosen DLZ19A manufactured by Tosoh Corporation) was laminated using an extrusion coater (melt extruder) so that the coating amount was 30 g/m ² . A heat-sealing layer was provided to prepare a wrapping paper. Stockigt sized was not measurable (impervious to water).

(Comparative example 2)
Packaging paper was prepared in the same manner as in Example 1, except that no modified rosin sizing agent was added. The Stockigt sizing degree was 0 seconds.

The packaging paper obtained in each example and comparative example was evaluated by the methods shown below. Table 1 shows the results obtained.

Stockigt size degree
Measured according to JIS P 8122.

(2) Z-axis strength (JPAPAN TAPPI No. 18-1)
JAPAN TAPPI No. 18-1.

(3) Tensile elongation at break in the machine direction Measured according to JIS P-8113.

(4) Tensile strength in longitudinal direction Measured according to JIS P-8113.

(5) Heat sealing strength The obtained packaging paper is cut into two pieces of 8 mm in width and 15 cm in length, and the front and back sides of the packaging paper are overlapped, and a heat sealing device (manufactured by Palmec, model number: PTS- 100) under certain conditions (adhesion width: 4 mm, temperature: 180°C, pressure: 0.4 MPa, pressing time: 0.5 seconds, pitch: 4 mm). Next, the peel strength of the heat-sealed sample was measured using a peel strength tester (manufactured by Shimadzu Corporation, model number: Autograph AGS-X) under constant conditions (peel speed: 100 mm/min, peel length: 10 cm). was taken as the heat seal strength (gf/4 mm). A higher number is better.

(6) Appropriateness for pasting A carton was manufactured using a potato carton manufacturing machine. The adhesiveness of the pasted portion was visually inspected and evaluated as follows.
⊚: Completely adhered ◯: Slightly non-adhered portions, but at a practical level.
Δ: Some portions are not adhered, and cannot be used practically.
x: Not adhered at all, impractical.

(7) Folding Suitability Cartons were made on a potato carton making machine. Cracks and tears in the folded portion were visually inspected and evaluated as follows.
⊚: Practical with no cracks at the bent portion.
◯: Slight cracks at the bent portion, but practical.
Δ: Not practical due to cracks in the bent portion.
x: Remarkable cracks at the bent portion, impractical.

As shown in Table 1, Examples 1 to 8 are preferable because the heat-sealing aptitude and the aptitude for pasting are at the same level as the poly-laminated paper of Comparative Example 1. In Comparative Example 2, since the Stockigt sizing degree of the wrapping paper was less than 5 seconds, it was inferior in suitability for sheet sealing and suitability for pasting.

In this embodiment, the Z-axis strength ( JA PAN TAPPI No. 18-1, strength in the thickness direction of the paper) of the packaging paper is preferably 150 kN/m ² or more. Eliminates tearing and cracking during folding. Preferably, it is 200 kN/m ² or more.

(2) Z-axis strength ( JA PAN TAPPI No. 18-1)
JAPAN TAPPI No. 18-1.

Claims (5)

A packaging paper having at least one or more heat-seal layers on at least one surface of a paper substrate, wherein the heat-seal layers contain an ionomer, and the dry coating amount of the heat-seal layers is 2 to 10 g for all layers. /m ² , the basis weight of the packaging paper is 80 g/m ² to 500 g/m ² , and the Stockigt sizing degree of the packaging paper is 5 seconds or more. The wrapping paper according to claim 1, wherein the Z-axis strength (JPAPAN TAPPI No. 18-1) of the wrapping paper is 150 kN/m ² or more. 3. The wrapping paper according to claim 1, wherein the longitudinal tensile elongation at break of the wrapping paper is 1% or more (JIS P-8113). The wrapping paper according to any one of claims 1 to 3, characterized in that the longitudinal tensile strength (JIS P-8113) of the wrapping paper is 5 kN/m or more. The packaging paper according to any one of claims 1 to 4, wherein the base material contains 0.01 to 1.0 part of an acidic rosin sizing agent per 100 parts by mass of pulp.