JP2023049042A - Animal protein-containing oil-in-water type emulsion - Google Patents

Animal protein-containing oil-in-water type emulsion Download PDF

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JP2023049042A
JP2023049042A JP2022155054A JP2022155054A JP2023049042A JP 2023049042 A JP2023049042 A JP 2023049042A JP 2022155054 A JP2022155054 A JP 2022155054A JP 2022155054 A JP2022155054 A JP 2022155054A JP 2023049042 A JP2023049042 A JP 2023049042A
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water emulsion
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真梨子 武田
Mariko Takeda
昌伸 柳澤
Masanobu Yanagisawa
紗更 星川
Sara Hoshikawa
詢大 永渕
Junta Nagafuchi
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Fuji Oil Co Ltd
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Abstract

To provide a highly versatile method capable of suppressing odd flavor derived from an animal protein, without spoiling the whole flavor, in food and drink containing the animal protein.SOLUTION: Oil-in-water type emulsion can suppress odd flavor derived from an animal protein, while maintaining excellent whole flavor, by adding random transesterification oil prepared to a specific fatty acid composition, to food and drink containing the animal protein.SELECTED DRAWING: None

Description

本発明は、動物性蛋白質を含有する水中油型乳化物に関する。 The present invention relates to an oil-in-water emulsion containing animal protein.

昨今の健康志向の高まりにより、プロテイン(蛋白質)を含む飲食品を積極的に摂取する人が増えている。また、機能性を強調して牛乳などの乳製品や飲料にプロテインを添加した新商品も登場している。 With the recent rise in health consciousness, more and more people are actively taking in foods and drinks containing protein. In addition, new products that emphasize functionality by adding protein to dairy products such as milk and beverages are also appearing.

しかしながら、動物性蛋白質の中には、不快な臭いや不快な味を有するものがある。例えば、製造工程で濃縮や乾燥の加工を経た乳タンパク質は、カゼイン臭やホエイ臭として知られる特有の異風味(オフフレーバー)を有し、摂取する際の味の悪さ、不快感という欠点がある。そのため、飲食時の嗜好性が悪いという問題があった。 However, some animal proteins have unpleasant odors and unpleasant tastes. For example, milk protein that has undergone concentration and drying processes in the manufacturing process has a unique off-flavor known as casein odor or whey odor, and has the drawback of being unpleasant and unpleasant when ingested. . Therefore, there is a problem of poor palatability during eating and drinking.

上記課題を解決するため、従来、種々の方法が提案されている。カゼインが有する臭いを除去する方法としては、例えば、カゼインナトリウム類に乳清ミネラルを添加する方法(特許文献1)、カゼイン分散溶液を所定の剪断速度で攪拌洗浄して、カゼインの有する臭気物質をアルカリ水等に移行させて除去する方法(特許文献2)、クロロゲン酸を使用する方法(特許文献3)が提案されている。 In order to solve the above problems, various methods have been conventionally proposed. Methods for removing the odor of casein include, for example, a method of adding whey minerals to sodium caseinate (Patent Document 1), and stirring and washing a casein dispersion solution at a predetermined shear rate to remove odorous substances of casein. A method of removing by transferring to alkaline water or the like (Patent Document 2) and a method of using chlorogenic acid (Patent Document 3) have been proposed.

特開平8-56583号公報JP-A-8-56583 特開2000-270782号公報JP-A-2000-270782 特開2003-210119号公報Japanese Patent Application Laid-Open No. 2003-210119

特許文献1~3に提案された乳蛋白質に由来する異風味の改善方法は、ある程度の効果を発揮するものの、多くの消費者が十分満足できるものではなく、また、汎用性に欠けるといった課題もある。そこで、乳タンパク質が有する異味異臭のさらなる改善方法が要望されている。 Although the method for improving the off-flavor derived from milk protein proposed in Patent Documents 1 to 3 exhibits a certain amount of effect, it is not sufficiently satisfactory for many consumers, and also has the problem of lacking versatility. be. Therefore, there is a demand for a method for further improving offensive taste and offensive odor of milk protein.

本発明は、動物性蛋白質を含む飲食品において、全体の風味が損なわれることがなく、汎用性高く、動物性蛋白質由来の異風味を抑制する方法を提供することを課題とする。 An object of the present invention is to provide a highly versatile method for suppressing off-flavours derived from animal proteins without impairing the overall flavor of foods and drinks containing animal proteins.

本発明者らは、上記課題を解決すべく鋭意研究を行ったところ、動物性蛋白質を含む飲食品に対し、所定の油脂を特定量添加することにより、全体の良好な風味を維持しつつ、動物性蛋白質由来の異風味を抑制する効果を見出し、上記課題を解決するに至った。 The present inventors have conducted intensive research to solve the above problems, and found that by adding a specific amount of predetermined fats and oils to food and drink containing animal protein, while maintaining a good overall flavor, The inventors have found an effect of suppressing off-flavours derived from animal proteins, and have solved the above problems.

すなわち本発明は、下記にかかるものである。
(1)下記(A)及び(B)を満たす、ランダムエステル交換油脂、ならびに動物性蛋白質を含む、水中油型乳化物、
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
(2)該ランダムエステル交換油脂が(A)、(B)、及び(C)を満たす、(1)に記載の水中油型乳化物、
(C)構成脂肪酸組成中、オレイン酸含量が10重量%以下
(3)該ランダムエステル交換油脂が(A)、(B)、及び(D)を満たす、(1)に記載の水中油型乳化物、
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0
(4)該ランダムエステル交換油脂が(A)、(B)、(C)、及び(D)を満たす、(2)に記載の水中油型乳化物、
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0
(5)上記(A)が1~35重量%である、(1)又は(2)に記載の水中油型乳化物、
(6)上記(A)が1~35重量%である、(3)又は(4)に記載の水中油型乳化物、
(7)水中油型乳化物中の蛋白質含量100重量部あたり、該ランダムエステル交換油脂を1.9重量部以上添加する、(5)に記載の水中油型乳化物、
(8)水中油型乳化物中の蛋白質含量100重量部あたり、該ランダムエステル交換油脂を1.9重量部以上添加する、(6)に記載の水中油型乳化物、
(9)水中油型乳化物の蛋白質含量が2.2重量%以上である、(5)に記載の水中油型乳化物、
(10)水中油型乳化物の蛋白質含量が2.2重量%以上である、(6)に記載の水中油型乳化物、
(11)該動物性蛋白質が乳蛋白質である、(5)に記載の水中油型乳化物、
(12)該動物性蛋白質が乳蛋白質である、(6)に記載の水中油型乳化物、
(13)水中油型乳化物が飲料、ホイップクリーム、ホワイトナーである、(5)に記載の水中油型乳化物、
(14)水中油型乳化物が飲料、ホイップクリーム、ホワイトナーである、(6)に記載の水中油型乳化物、
(15)下記(A)及び(B)を満たす、ランダムエステル交換油脂を1.9重量%以上(水中油型乳化物中の蛋白質含量100重量部あたり)、ならびに動物性蛋白質を混合し乳化する、水中油型乳化物の製造方法、
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
(16)下記(A)及び(B)を満たす、ランダムエステル交換油脂、ならびに動物性蛋白質を含む水中油型乳化物における、異風味を抑制させる方法、
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
また、換言すれば、下記にかかるものである。
(21)下記(A)及び(B)を満たすランダムエステル交換油、ならびに動物性蛋白質を含む、水中油型乳化物、
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~30質量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が45~80質量%
(22)水中油型乳化物中の蛋白質含量100部あたり、該ランダムエステル交換油を1.9重量部以上添加する、(21)記載の水中油型乳化物、
(23)該ランダムエステル交換油がさらに下記(C)を満たす、(21)または(22)記載の水中油型乳化物、
(C)構成脂肪酸組成中、オレイン酸の含有量が10質量%以下
(24)水中油型乳化物の蛋白質含量が2.2重量%以上である、(21)~(23)何れか1項記載の水中油型乳化物、
(25)該動物性蛋白質が乳蛋白質である、(21)~(24)何れか1項記載の水中油型乳化物、
(26)水中油型乳化物が飲料、ホイップクリーム、ホワイトナーである、(21)~(25)何れか1項記載の水中油型乳化物、
(27)(21)~(26)何れか1項記載の水中油型乳化物の製造方法、
(28)該ランダムエステル交換油、ならびに該動物性蛋白質を含むことを特徴とする、(21)~(26)何れか1項記載の水中油型乳化物における、異風味を抑制させる方法。
That is, the present invention involves the following.
(1) An oil-in-water emulsion containing random transesterified fat and animal protein that satisfies the following (A) and (B),
(A) In the constituent fatty acid composition, the content of saturated fatty acids with 6 to 10 carbon atoms is 0.3 to 40% by weight
(B) The content of saturated fatty acids with 12 to 14 carbon atoms in the constituent fatty acid composition is 40 to 80% by weight
(2) The oil-in-water emulsion according to (1), wherein the random transesterified fat satisfies (A), (B), and (C),
(C) The oil-in-water emulsion according to (1), wherein the oleic acid content is 10% by weight or less in the constituent fatty acid composition (3) The random transesterified fat satisfies (A), (B), and (D) thing,
(D) (Content of saturated fatty acid with 12 to 14 carbon atoms)/(Content of saturated fatty acid with 6 to 10 carbon atoms) ratio is 1.0 to 6.0
(4) The oil-in-water emulsion according to (2), wherein the random transesterified fat satisfies (A), (B), (C), and (D),
(D) (Content of saturated fatty acid with 12 to 14 carbon atoms)/(Content of saturated fatty acid with 6 to 10 carbon atoms) ratio is 1.0 to 6.0
(5) The oil-in-water emulsion according to (1) or (2), wherein (A) is 1 to 35% by weight,
(6) The oil-in-water emulsion according to (3) or (4), wherein (A) is 1 to 35% by weight,
(7) The oil-in-water emulsion according to (5), wherein 1.9 parts by weight or more of the random transesterified fat is added per 100 parts by weight of the protein content in the oil-in-water emulsion,
(8) The oil-in-water emulsion according to (6), wherein 1.9 parts by weight or more of the random transesterified fat is added per 100 parts by weight of the protein content in the oil-in-water emulsion.
(9) The oil-in-water emulsion according to (5), wherein the protein content of the oil-in-water emulsion is 2.2% by weight or more,
(10) The oil-in-water emulsion according to (6), wherein the protein content of the oil-in-water emulsion is 2.2% by weight or more,
(11) The oil-in-water emulsion according to (5), wherein the animal protein is milk protein,
(12) The oil-in-water emulsion according to (6), wherein the animal protein is milk protein,
(13) The oil-in-water emulsion according to (5), wherein the oil-in-water emulsion is a beverage, whipped cream, or whitener.
(14) The oil-in-water emulsion according to (6), wherein the oil-in-water emulsion is a beverage, whipped cream, or whitener.
(15) Mix and emulsify 1.9% by weight or more of random transesterified fat and oil (per 100 parts by weight of protein content in oil-in-water emulsion) that satisfies the following (A) and (B), and animal protein. , a method for producing an oil-in-water emulsion,
(A) In the constituent fatty acid composition, the content of saturated fatty acids with 6 to 10 carbon atoms is 0.3 to 40% by weight
(B) The content of saturated fatty acids with 12 to 14 carbon atoms in the constituent fatty acid composition is 40 to 80% by weight
(16) A method of suppressing off-flavours in an oil-in-water emulsion containing random transesterified fat and animal protein that satisfies the following (A) and (B),
(A) In the constituent fatty acid composition, the content of saturated fatty acids with 6 to 10 carbon atoms is 0.3 to 40% by weight
(B) The content of saturated fatty acids with 12 to 14 carbon atoms in the constituent fatty acid composition is 40 to 80% by weight
Also, in other words, the following applies.
(21) An oil-in-water emulsion containing a random transesterified oil that satisfies the following (A) and (B) and an animal protein,
(A) In the constituent fatty acid composition, the content of saturated fatty acids with 6 to 10 carbon atoms is 0.3 to 30% by mass
(B) In the constituent fatty acid composition, the content of saturated fatty acids with 12 to 14 carbon atoms is 45 to 80 mass%
(22) The oil-in-water emulsion according to (21), wherein 1.9 parts by weight or more of the random transesterified oil is added per 100 parts of the protein content in the oil-in-water emulsion.
(23) The oil-in-water emulsion according to (21) or (22), wherein the random transesterified oil further satisfies the following (C),
(C) In the constituent fatty acid composition, the content of oleic acid is 10% by mass or less (24) The protein content of the oil-in-water emulsion is 2.2% by weight or more, (21) to (23) any one item the described oil-in-water emulsion,
(25) The oil-in-water emulsion according to any one of (21) to (24), wherein the animal protein is milk protein,
(26) The oil-in-water emulsion according to any one of (21) to (25), wherein the oil-in-water emulsion is a beverage, whipped cream, or whitener,
(27) The method for producing the oil-in-water emulsion according to any one of (21) to (26),
(28) A method for suppressing off-flavours in the oil-in-water emulsion according to any one of (21) to (26), characterized by containing the random transesterified oil and the animal protein.

本発明に用いられる特定の油脂を、動物性蛋白質を含む飲食品に添加することにより、全体の風味を阻害することなく、動物性蛋白質由来の異風味を抑制することができる。 By adding the specific fats and oils used in the present invention to foods and drinks containing animal proteins, it is possible to suppress the off-flavours derived from animal proteins without impairing the overall flavor.

(水中油型乳化物)
本発明における水中油型乳化物は、油脂、蛋白質、炭水化物、水などの基礎原料を混合し、水中油型に乳化して得られるクリーム様の組成物をいう。
(Oil-in-water emulsion)
The oil-in-water emulsion in the present invention refers to a cream-like composition obtained by mixing basic raw materials such as oils and fats, proteins, carbohydrates and water and emulsifying the mixture into an oil-in-water type.

(動物性蛋白質)
本発明における動物性蛋白質の種類は限定されないが、コラーゲン、ゼラチン、乳蛋白質、微生物発酵由来の乳蛋白質などが挙げられ、特に製造方法問わず乳蛋白質が好ましい。これらを適当な割合で混合して使用することも可能である。また、これらの分解物を使用することも可能である。例えば、乳蛋白質は、乳汁に含まれる各種のタンパク質およびそれらを含む組成物であり、カゼイン、α-ラクトアルブミン、β-ラクトグロブリン、ラクトフェリン、ホエープロテインコンセントレート(WPC)、トータルミルクプロテイン(TMP)、乳タンパクペプチド等が挙げられる。カゼインには、乳酸カゼイン、酸カゼイン、レンネットカゼイン、カゼイネート、カゼイン分解物を含む。これらを含む原材料としては、生乳、牛乳、脱脂乳、生クリーム、濃縮乳、無糖練乳、加糖練乳、全脂粉乳、脱脂粉乳、バターミルクパウダー、ホエー蛋白、酸カゼイン、レンネットカゼイン、若しくはカゼインナトリウム、カゼインカルシウム、カゼインカリウム等のカゼイン類、またはトータルミルクプロテイン乳が例示できる。
本発明の水中油型乳化物の蛋白質含量は限定されないが、蛋白質含量がより高い方が本発明の効果が奏しやすく、2.2重量%以上が好ましく、より好ましくは2.5重量%、さらに好ましくは3重量%、さらにより好ましくは4重量%である。上限は20重量%以下、より好ましくは15重量%以下、さらに好ましくは13重量%以下が好ましい。
(animal protein)
The type of animal protein in the present invention is not limited, but examples include collagen, gelatin, milk protein, milk protein derived from microbial fermentation, etc. Milk protein is particularly preferred regardless of the production method. It is also possible to use them by mixing them in an appropriate ratio. It is also possible to use these decomposition products. For example, milk proteins are various proteins found in milk and compositions containing them, including casein, α-lactalbumin, β-lactoglobulin, lactoferrin, whey protein concentrate (WPC), total milk protein (TMP). , milk protein peptides, and the like. Casein includes lactic casein, acid casein, rennet casein, caseinate, and casein hydrolyzate. Raw materials containing these include raw milk, milk, skim milk, fresh cream, concentrated milk, unsweetened condensed milk, sweetened condensed milk, whole milk powder, skim milk powder, buttermilk powder, whey protein, acid casein, rennet casein, or casein. Examples include caseins such as sodium, calcium caseinate, potassium caseinate, and total milk protein milk.
The protein content of the oil-in-water emulsion of the present invention is not limited, but the higher the protein content, the easier the effect of the present invention is, and it is preferably 2.2% by weight or more, more preferably 2.5% by weight, and further. Preferably 3% by weight, even more preferably 4% by weight. The upper limit is preferably 20% by weight or less, more preferably 15% by weight or less, and even more preferably 13% by weight or less.

(ランダムエステル交換油脂)
本発明に用いるランダムエステル交換油脂は、下記(A)及び(B)を満たすランダムエステル交換油脂であることを特徴とするが、好ましくは下記(A)、(B)及び(C)、または下記(A)、(B)及び(D)を満たすランダムエステル交換油脂、さらに好ましくは下記(A)、(B)、(C)、(D)を全て満たすランダムエステル交換油脂が良い。
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
(C)構成脂肪酸組成中、オレイン酸の含有量が10重量%以下
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0
(random transesterified fat)
The random transesterified fat used in the present invention is characterized by being a random transesterified fat that satisfies the following (A) and (B), preferably the following (A), (B) and (C), or the following A random transesterified fat that satisfies (A), (B) and (D), more preferably a random transesterified fat that satisfies all of (A), (B), (C) and (D) below.
(A) In the constituent fatty acid composition, the content of saturated fatty acids with 6 to 10 carbon atoms is 0.3 to 40% by weight
(B) The content of saturated fatty acids with 12 to 14 carbon atoms in the constituent fatty acid composition is 40 to 80% by weight
(C) The content of oleic acid in the constituent fatty acid composition is 10% by weight or less (D) (content of saturated fatty acid with 12 to 14 carbon atoms) / (content of saturated fatty acid with 6 to 10 carbon atoms) ratio is 1.0 to 6.0

本発明のランダムエステル交換油脂は、好ましくは(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が1~35重量%、より好ましくは3~35重量%、さらに好ましくは5~25重量%、さらにより好ましくは5~20重量%である。 The random transesterified fat of the present invention preferably contains 1 to 35% by weight, more preferably 3 to 35% by weight, and still more preferably 5 ~25 wt%, even more preferably 5-20 wt%.

本発明のランダムエステル交換油脂は、好ましくは(B)構成脂肪酸組成中、炭素数12~14の 飽和脂肪酸の含有量が50~80重量%、より好ましくは60~75重量%である。 The random transesterified fat of the present invention preferably contains 50 to 80% by weight, more preferably 60 to 75% by weight, of saturated fatty acids having 12 to 14 carbon atoms in the constituent fatty acid composition (B).

本発明のランダムエステル交換油脂は、好ましくは(C)構成脂肪酸組成中、オレイン酸の含有量が10重量%以下、より好ましくは9重量%以下、さらに好ましくは8重量%以下、さらにより好ましくは6重量%以下である。 The random transesterified fat of the present invention preferably has an oleic acid content of 10% by weight or less, more preferably 9% by weight or less, still more preferably 8% by weight or less, still more preferably 8% by weight or less in the (C) constituent fatty acid composition. 6% by weight or less.

本発明のランダムエステル交換油脂は、好ましくは(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0、より好ましくは1.0~5.0、さらに好ましくは1.3~4.5、さらにより好ましくは1.5~4.0である。 The random transesterified fat of the present invention preferably has a ratio of (D) (content of saturated fatty acid having 12 to 14 carbon atoms)/(content of saturated fatty acid having 6 to 10 carbon atoms) of 1.0 to 6.0. 0, more preferably 1.0 to 5.0, still more preferably 1.3 to 4.5, still more preferably 1.5 to 4.0.

上記ランダムエステル交換油脂の原料としては、前記構成を満たせば、種々の油脂類の配合量を調整して使用することができる。使用することができる油脂類として、ナタネ油、大豆油、ひまわり油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、胡麻油、月見草油、パーム油、シア脂、サル脂、カカオ脂、ヤシ油、パーム核油、中鎖脂肪酸結合油脂(MCT)等の植物性油脂及び乳脂、牛脂、豚脂、魚油、鯨油等の動物性油脂、藻類油、微生物発酵により生産された油脂が例示でき、上記油脂類の単独または混合油あるいはそれらの硬化、分別、エステル交換等を施した加工油脂が例示できる。 As the raw material for the random transesterified fat, various fats and oils can be used by adjusting the blending amount thereof as long as the above-mentioned constitution is satisfied. Oils and fats that can be used include rapeseed oil, soybean oil, sunflower oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil, shea butter, sal Fat, cocoa butter, coconut oil, palm kernel oil, medium-chain fatty acid binding fat (MCT) and other vegetable oils and fats, milk fat, beef tallow, lard, fish oil, whale oil and other animal fats and oils, algae oil, produced by microbial fermentation The oils and fats mentioned above can be exemplified, and the above-mentioned oils and fats can be exemplified by single or mixed oils, or processed oils and fats obtained by hardening, fractionating, transesterifying, or the like.

上記ランダムエステル交換油脂の原材料として、好ましくはヤシ油、パーム核油、中鎖脂肪酸結合油脂(MCT)、乳脂等が例示でき、上記油脂類の単独または混合油あるいはそれらの硬化、分別、エステル交換等を施した加工油脂が例示できる。
本発明の冷菓用ランダムエステル交換油の特徴としては、原料油脂に非ラウリン系油脂を必須成分として含有する必要がない。本発明の効果を阻害しない範囲内で、非ラウリン系油脂を使用しても良いが、より望ましい態様としては、原料油脂に非ラウリン系油脂を使用しないことが好ましい。
Examples of raw materials for the random transesterified fat include coconut oil, palm kernel oil, medium chain fatty acid binding fat (MCT), milk fat, and the like. Processed oils and fats that have been subjected to, etc. can be exemplified.
A feature of the random transesterified oil for frozen desserts of the present invention is that it is not necessary to contain a non-lauric fat as an essential ingredient in the raw fat. Non-lauric fats and oils may be used as long as the effects of the present invention are not impaired, but in a more desirable mode, it is preferable not to use non-lauric fats and oils as raw material fats and oils.

本発明のランダムエステル交換油脂の原材料に、ラウリン酸を含む油脂を必須成分として使用するのが好ましい。その際、好ましくは該ラウリン酸を含む油脂のヨウ素価(IV)が10以下、より好ましくは5以下、さらに好ましくは1以下のラウリン酸を含む油脂を使用することが好ましい。 It is preferable to use fats and oils containing lauric acid as an essential ingredient for the raw materials of the random transesterified fats and oils of the present invention. In this case, it is preferable to use a lauric acid-containing oil whose iodine value (IV) is preferably 10 or less, more preferably 5 or less, and still more preferably 1 or less.

上記ランダムエステル交換油脂の添加量は、水中油型乳化物中の蛋白質含量100重量部に対して、1.9重量部以上であり、好ましくは9~2000重量部以上より好ましくは45~500重量部、更に好ましくは45~200重量部である。これにより、効果的に乳蛋白質由来の異風味を抑制することができる。ここで、水中油型乳化物に含まれる油脂は必ずしも上記ランダムエステル交換油脂のみである必要はなく、上記ランダムエステル交換油脂を少なくとも水中油型乳化物中の蛋白質含量あたり1.9重量部以上含まれていれば他の油脂を併用してもよい。 The amount of the random transesterified oil added is 1.9 parts by weight or more, preferably 9 to 2000 parts by weight or more, more preferably 45 to 500 parts by weight, with respect to 100 parts by weight of the protein content in the oil-in-water emulsion. parts, more preferably 45 to 200 parts by weight. Thereby, the off-flavour derived from milk protein can be suppressed effectively. Here, the oil contained in the oil-in-water emulsion does not necessarily have to be only the random transesterified oil, and at least 1.9 parts by weight or more of the random transesterified oil per protein content in the oil-in-water emulsion is included. Other fats and oils may be used together if they are used.

本発明の異風味を抑制させる方法は、水中油型乳化物において、前記ランダムエステル交換油脂、ならびに前記動物性蛋白質を含有することで、動物性蛋白質由来の異風味を抑制することができる。前記ランダムエステル交換油脂、動物性蛋白質の含量、水中油型乳化物の調製方法は、他項に記載の通りである。 The method for suppressing off-flavours of the present invention can suppress off-flavours derived from animal proteins by including the random transesterified fat and the animal protein in the oil-in-water emulsion. The random transesterified fat, the animal protein content, and the preparation method of the oil-in-water emulsion are as described in other sections.

本発明の水中油型乳化物には、蛋白質、油脂以外に副原料を含んでもよい。副原料としては、必要な食品原料(果汁、果肉、野菜、糖類、乳製品、穀粉類、澱粉類、カカオマス、鳥獣魚肉製品、調味料等)や食品添加物(乳化剤、塩類、ミネラル、ビタミン、増粘安定剤、酸味料、香料等)を適宜使用することができる。 The oil-in-water emulsion of the present invention may contain auxiliary raw materials in addition to proteins and fats. Auxiliary raw materials include necessary food raw materials (fruit juice, fruit pulp, vegetables, sugars, dairy products, cereal flours, starches, cacao mass, game products, seasonings, etc.) and food additives (emulsifiers, salts, minerals, vitamins, Thickening stabilizers, acidulants, perfumes, etc.) can be used as appropriate.

以下、本発明の水中油型乳化物の一つの製造態様を示すが、あくまで例示であってかかる態様のみに限定されるものではない。 One production mode of the oil-in-water emulsion of the present invention is shown below, but it is only an example and is not limited to this mode.

〇混合・均質化
水相部については、任意の温度範囲で調製できる。より具体的な実施形態では、加熱により溶解性が向上する親水性乳化剤や炭水化物などを含む場合は、例えば20~70℃、好ましくは55~65℃の温度範囲で溶解又は分散させて調製できる。水相部に添加する原料は当業者が適宜決定できる。例えば、塩類や水溶性の香料等を加える場合には、水相部に添加する。
油相部については、油脂を含む油溶性の材料を混合して、例えば50~80℃、好ましくは55~70℃の温度範囲で溶解又は分散させて調製できる。油相部に添加する原料は当業者が適宜決定できる。例えば、親油性乳化剤を用いる場合には、原料油脂の一部または油相部に添加する。
得られた油相部と水相部は、例えば40~80℃、好ましくは55~70℃に加温し、混合して予備乳化を行う。予備乳化はホモミキサー等の回転式攪拌機を用いて行うことができる。予備乳化後、ホモジナイザー等の均質化装置にて均質化する。ホモジナイザーによる均質化の際の圧力は2~20Mpaとすることができ、好ましくは3~10Mpaとすることができる。
〇Mixing and homogenization The water phase can be prepared in any temperature range. In a more specific embodiment, when a hydrophilic emulsifier or carbohydrate whose solubility is improved by heating is included, it can be prepared by dissolving or dispersing at a temperature range of 20 to 70°C, preferably 55 to 65°C. Raw materials to be added to the aqueous phase can be appropriately determined by those skilled in the art. For example, when adding salts, water-soluble fragrances, etc., they are added to the aqueous phase.
The oil phase can be prepared by mixing oil-soluble materials containing oils and fats and dissolving or dispersing them at a temperature range of, for example, 50 to 80°C, preferably 55 to 70°C. Raw materials to be added to the oil phase can be appropriately determined by those skilled in the art. For example, when a lipophilic emulsifier is used, it is added to part of the raw fat or oil or to the oil phase.
The obtained oil phase and water phase are heated to, for example, 40 to 80° C., preferably 55 to 70° C., and mixed for preliminary emulsification. Preliminary emulsification can be performed using a rotary stirrer such as a homomixer. After preliminary emulsification, the mixture is homogenized with a homogenizer such as a homogenizer. The pressure during homogenization by a homogenizer can be 2-20 Mpa, preferably 3-10 Mpa.

○加熱殺菌
得られた組成物は、必要により加熱殺菌処理を行ってもよいし、行わなくてもよい。加熱殺菌処理を行う場合、例えば間熱加熱方式又は直接加熱方式によるUHT滅菌処理法などにて処理し、必要により再度ホモジナイザーにて均質化し、2~15℃などに冷却する。加熱殺菌の温度は例えば110~150℃、好ましくは120~148℃で行い、加熱殺菌の時間は例えば1~10秒間、好ましくは3~7秒間で行うことができる。
○ Heat sterilization The obtained composition may or may not be subjected to heat sterilization as necessary. When heat sterilization is performed, for example, the mixture is treated by a UHT sterilization method using an intermediate heating method or a direct heating method, and if necessary, homogenized again with a homogenizer and cooled to 2 to 15°C. The heat sterilization temperature is, for example, 110 to 150° C., preferably 120 to 148° C., and the heat sterilization time is, for example, 1 to 10 seconds, preferably 3 to 7 seconds.

以上により得られた本発明の水中油型乳化物は、異風味が抑制されており風味良好なため、各種飲食品の製造原料として利用することができる。使用用途については特に限定されず、例えば、プロテイン飲料、乳飲料や清涼飲料等の飲料、プリン、ババロア、ゼリー、ホイップクリーム及びフィリング等の生菓、ホワイトナー、ヨーグルト、チーズ及び発酵飲料等の発酵食品、ビスケット、クッキー、パン類及びケーキ等のベーカリー製品、チョコレート、マーガリン、バター、スプレッドやマヨネーズ等の調味料、ソース、スープ、フライ食品、水産練製品、鳥獣魚肉製品等の製品形態に使用できる。 Since the oil-in-water emulsion of the present invention obtained as described above has suppressed off-flavor and good flavor, it can be used as a raw material for producing various foods and drinks. The intended use is not particularly limited, and examples include beverages such as protein drinks, milk drinks and soft drinks, fresh confectionery such as pudding, bavarois, jellies, whipped cream and fillings, whiteners, yogurt, cheese and fermented beverages such as fermented beverages. It can be used for food, bakery products such as biscuits, cookies, breads and cakes, seasonings such as chocolate, margarine, butter, spreads and mayonnaise, sauces, soups, fried foods, fish paste products, game products, and other products. .

以下に実施例を示し、本発明の詳細をより具体的に説明する。なお、例中、「部」あるいは「%」はいずれも重量基準を表すものとする。 EXAMPLES The details of the present invention will be explained more specifically by showing examples below. In the examples, "parts" and "%" are all based on weight.

(分析方法)
(脂肪酸組成)
日本油化学協会基準油脂分析試験法(1996年版)2.4.1.2メチルエステル化法(三フッ化ホウ素メタノール法)に規定の方法に準じて測定した。
(analysis method)
(Fatty acid composition)
It was measured in accordance with the method specified in 2.4.1.2 Methyl esterification method (boron trifluoride methanol method) of the Japan Oil Chemistry Society standard oil analysis test method (1996 version).

表1に記載の配合割合にて調合した原料油脂1.0kgに、触媒としてナトリウムメチラートを1.5g添加し、80℃にて30分ランダムエステル交換反応を行った後、常法に従い水洗/脱色/脱臭を行いエステル交換油脂を得た。前記脂肪酸組成分析方法に従い脂肪酸組成を分析した結果を表2に示す。なお 、表1において使用した原料油脂のヨウ素価(IV)を表記した。
中鎖脂肪酸結合油脂として、n-オクタン酸(炭素数8)、n -デカン酸(炭素数10)を構成脂肪酸とし、これらの重量比が60:40であるMCT-64(不二製油株式会社製)を使用した。また、原料油脂のヨウ素価(IV)を表1に記載した。
1.5 g of sodium methylate as a catalyst was added to 1.0 kg of the raw material oil and fat prepared at the blending ratio shown in Table 1, and a random transesterification reaction was performed at 80 ° C. for 30 minutes. Decolorization/deodorization was performed to obtain a transesterified fat. Table 2 shows the results of fatty acid composition analysis according to the fatty acid composition analysis method. In Table 1, the iodine value (IV) of the raw material oils and fats used is shown.
MCT-64 (Fuji Oil Co., Ltd.) having a weight ratio of 60:40 with n-octanoic acid (8 carbon atoms) and n-decanoic acid (10 carbon atoms) as the medium-chain fatty acid-binding oil and fat ) was used. Table 1 also shows the iodine value (IV) of the raw material fats and oils.

(表1)単位:重量%

Figure 2023049042000001
(Table 1) Unit: % by weight
Figure 2023049042000001

(表2)単位:重量%

Figure 2023049042000002
(Table 2) Unit: % by weight
Figure 2023049042000002

脂肪酸組成の比較結果を表3に記載した。
(表3)単位:重量%

Figure 2023049042000003
Table 3 shows the comparative results of fatty acid composition.
(Table 3) Unit: % by weight
Figure 2023049042000003

(表3の考察)
・エステル交換油E1~E7は、下記(A)、(B)を全て満たすランダムエステル交換油脂であった。
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
・エステル交換油E1~E3、E5~E7は、さらに下記(C)を満たすランダムエステル交換油脂であった。
(C)構成脂肪酸組成中、オレイン酸の含有量が10重量%以下
・エステル交換油E1~E2、E5、E7は、(A)、(B)に加えて(D)を満たすランダムエステル交換油脂であった。
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0
(Consideration of Table 3)
- The transesterified oils E1 to E7 were random transesterified oils and fats satisfying both the following (A) and (B).
(A) In the constituent fatty acid composition, the content of saturated fatty acids with 6 to 10 carbon atoms is 0.3 to 40% by weight
(B) The content of saturated fatty acids with 12 to 14 carbon atoms in the constituent fatty acid composition is 40 to 80% by weight
The transesterified oils E1 to E3 and E5 to E7 were random transesterified oils and fats that further satisfied (C) below.
(C) The content of oleic acid in the constituent fatty acid composition is 10% by weight or less ・Transesterified oils E1 to E2, E5, and E7 are random transesterified oils and fats that satisfy (D) in addition to (A) and (B). Met.
(D) (Content of saturated fatty acid with 12 to 14 carbon atoms)/(Content of saturated fatty acid with 6 to 10 carbon atoms) ratio is 1.0 to 6.0

(比較例1)基本配合
「乳蛋白」(商品名:Promilk85、Ingredia社製、全固形分95.0%、蛋白質含量81.5%)を9.5部、「脱脂粉乳」(よつ葉乳業株式会社製、全固形分95.9%、蛋白質含量35.6%)を7部、「生クリーム」(タカナシ乳業株式会社製、蛋白質含量1.7%)を3.4部、乳化剤0.2部、pH調整剤0.4部、水79.5部とし、30分間ホモミキサーで調合後、3Mpaの均質化圧力で均質化して、直ちに5℃に冷却した。
(Comparative Example 1) Basic formulation "Milk protein" (trade name: Promilk 85, manufactured by Ingredia, total solid content 95.0%, protein content 81.5%) 9.5 parts, "skimmed milk powder" (Yotsuba Milk Industry Co., Ltd. Company product, total solid content 95.9%, protein content 35.6%) 7 parts, "Fresh cream" (manufactured by Takanashi Milk Products Co., Ltd., protein content 1.7%) 3.4 parts, emulsifier 0.2 0.4 parts of the pH adjuster and 79.5 parts of water were mixed with a homomixer for 30 minutes, homogenized under a homogenization pressure of 3 Mpa, and immediately cooled to 5°C.

(実施例1~12、比較例2)ランダムエステル交換油脂の種類と油脂の添加量
比較例1の配合をベースとし、水の一部を表4~5に記載したランダムエステル交換油脂に置き換え、比較例1と同様の方法で水中油型乳化物を調製し、各油脂の添加効果を確認した。更に、油脂の添加量の増減を水の添加量にて調整し、油脂の添加量の効果も確認した。
(Examples 1 to 12, Comparative Example 2) Types of random transesterified fats and added amounts of fats Based on the formulation of Comparative Example 1, part of the water was replaced with the random transesterified fats and oils shown in Tables 4 and 5, An oil-in-water emulsion was prepared in the same manner as in Comparative Example 1, and the effect of adding each oil was confirmed. Furthermore, the effect of the amount of oil added was also confirmed by adjusting the amount of oil added by adjusting the amount of water added.

(比較例3~4、実施例13)他の油脂との併用
比較例1の配合をベースとし、水の一部を精製ヤシ油、菜種油に置き換え、比較例1と同様の方法で水中油型乳化物を調製し、各油脂の添加効果を確認した。更に、精製ヤシ油の一部を表6に記載したランダムエステル交換油脂に置き換え、比較例1と同様の方法で水中油型乳化物を調製し、添加効果を確認した。
添加効果は、得られた水中油型乳化物を5℃にて1日間冷蔵保存したタイミングにて、乳の分野に熟練した嗜好パネラー5名に依頼し、官能評価を行うことにより確認した。官能評価の点数は、下記の評価基準に従って、パネラーの合議により1点から5点を付け、3点以上を合格とした。
(評価基準)
5点:乳蛋白質由来の異風味を感じず、非常に良好な風味である。
4点:乳蛋白質由来の異風味を殆ど感じず、良好な風味である。
3点:乳蛋白質由来の異風味を少し感じるが、良好な風味である。
2点:乳蛋白質由来の異風味を感じ、悪い風味である。
1点:乳蛋白質由来の異風味を最も感じ、非常に悪い風味である。
(Comparative Examples 3 to 4, Example 13) Combination with other oils and fats Based on the formulation of Comparative Example 1, part of the water was replaced with refined coconut oil and rapeseed oil, and the same method as in Comparative Example 1 was performed to obtain an oil-in-water type. Emulsions were prepared and the effect of adding each oil was confirmed. Furthermore, a part of the refined coconut oil was replaced with the random transesterified oil shown in Table 6, an oil-in-water emulsion was prepared in the same manner as in Comparative Example 1, and the effect of addition was confirmed.
The effect of addition was confirmed by conducting a sensory evaluation by requesting five taste panelists skilled in the field of milk at the timing of refrigerating the obtained oil-in-water emulsion at 5° C. for 1 day. Sensory evaluation scores were given on a scale of 1 to 5 according to the following evaluation criteria, and 3 or more points were accepted.
(Evaluation criteria)
5 points: Very good flavor with no off-flavour derived from milk protein.
4 points: Almost no off-flavour derived from milk protein is felt, and the flavor is good.
3 points: A slightly different flavor derived from milk protein is sensed, but the flavor is good.
2 points: A strange flavor derived from milk protein is sensed, and the flavor is bad.
1 point: The off-flavour derived from the milk protein is felt most, and the flavor is very bad.

(表4)

Figure 2023049042000004
(Table 4)
Figure 2023049042000004

(表5)

Figure 2023049042000005
(Table 5)
Figure 2023049042000005

(表6)

Figure 2023049042000006
(Table 6)
Figure 2023049042000006

(考察)
表4~6の結果より、特定の脂肪酸組成に調製したランダムエステル交換油脂を少なくとも水中油型乳化物中の蛋白質含量100重量部に対し、1.9重量部以上添加することで、乳蛋白質由来の異風味を抑制する効果があった。
(Discussion)
From the results of Tables 4 to 6, by adding 1.9 parts by weight or more to 100 parts by weight of the protein content in the oil-in-water emulsion, the random transesterified oil prepared to have a specific fatty acid composition was added. had the effect of suppressing the off-taste of

(実施例14~15)その他の原材料配合と油脂の添加
比較例1の配合をベースとし、原材料の配合を変更し、比較例1と同様の方法で水中油型乳化物を調製し、ランダムエステル交換油脂の添加効果を確認した。各配合量は表7に示した通りとした添加効果に関しても、表4~6と同様に評価した。
(Examples 14-15) Blending of other raw materials and addition of fats Based on the blending of Comparative Example 1, the blending of raw materials was changed, an oil-in-water emulsion was prepared in the same manner as in Comparative Example 1, and random esters were prepared. The effect of adding replacement oil was confirmed. The effects of addition of each compounding amount as shown in Table 7 were also evaluated in the same manner as in Tables 4-6.

(表7)

Figure 2023049042000007
(Table 7)
Figure 2023049042000007

(考察)
表7の結果より、乳蛋白質由来原料の違いに関わらず、特定の脂肪酸組成に調製したランダムエステル交換油脂を特定量添加することで、乳蛋白質由来の異風味を抑制する効果があった。
(Discussion)
From the results in Table 7, regardless of the difference in milk protein-derived raw materials, the addition of a specific amount of random transesterified fat prepared with a specific fatty acid composition had the effect of suppressing the off-flavour derived from milk protein.

(実施例16~18)蛋白質含量
比較例1の配合をベースとし、原材料由来の蛋白質含量を変更し、比較例1と同様の方法で水中油型乳化物を調製し、ランダムエステル交換油脂の添加効果を確認した。各配合量は表8に示した通りとした。添加効果に関しても、表4~6と同様に評価した。
(Examples 16 to 18) Protein content Based on the formulation of Comparative Example 1, the protein content derived from the raw materials was changed, an oil-in-water emulsion was prepared in the same manner as in Comparative Example 1, and a random transesterified oil was added. We confirmed the effect. Each compounding amount was as shown in Table 8. The effect of addition was also evaluated in the same manner as in Tables 4-6.

(表8)

Figure 2023049042000008
(Table 8)
Figure 2023049042000008

(考察)
表8の結果より、蛋白質含量2.2%以上の水中油型乳化物に対して、特定の脂肪酸組成に調製したランダムエステル交換油脂を特定量添加することで、乳蛋白質由来の異風味を抑制することができた。
(Discussion)
From the results in Table 8, by adding a specific amount of random transesterified oil prepared to a specific fatty acid composition to an oil-in-water emulsion with a protein content of 2.2% or more, the off-flavour derived from milk protein is suppressed. We were able to.

(比較例5)ホイップクリームへの応用
パーム核油20部、硬化パーム核油5部、酵素エステル交換油(パーム油とパーム核オレイン油の酵素エステル交換油)1部、パーム核ステアリン酸4部に乳化剤0.24部を添加混合溶解し油相を調製した。
水59.795部、脱脂粉乳8.5部、乳蛋白(カゼインカリウム/商品名Tatua500:タツア社製、全固形分96.0%、蛋白質91.2%)1部、乳化剤0.24部、pH調整剤0.2部、増粘多糖類0.025部をホモミキサーにより攪拌しながら混合し、水相を調製した。
調製した油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、144℃において4秒間の直接加熱方式による滅菌処理を行った後、40Mpaの均質化圧力で均質化して、直ちに10℃に冷却した。冷却後約24時間エージングして、ホイップクリームを得た。
(実施例19)ランダムエステル交換油の添加
比較例5の配合をベースとし、パーム核油の5部をランダムエステル交換油E1に置き換え、比較例1と同様の方法でホイップクリームを調製し、油脂の添加効果を確認した。
添加効果は、得られたホイップクリーム1kgをホバードミキサー(HOBART CORPORATION製MODEL N-5)3速(300rpm)にて最高起泡状態に達するまでホイップし、乳の分野に熟練した嗜好パネラー5名に依頼し、官能評価を行うことにより確認した。官能評価の点数は、下記の評価基準に従って、パネラーの合議により1点から5点を付け、3点以上を合格とした。
(評価基準)
5点:乳蛋白質由来の異風味を感じず、非常に良好な風味である。
4点:乳蛋白質由来の異風味を殆ど感じず、良好な風味である。
3点:乳蛋白質由来の異風味を少し感じるが、良好な風味である。
2点:乳蛋白質由来の異風味を感じ、悪い風味である。
1点:乳蛋白質由来の異風味を最も感じ、非常に悪い風味である。
(Comparative Example 5) Application to whipped cream 20 parts of palm kernel oil, 5 parts of hydrogenated palm kernel oil, 1 part of enzymatic transesterified oil (enzymatic transesterified oil of palm oil and palm kernel olein oil), 4 parts of palm kernel stearic acid 0.24 part of an emulsifier was added to and mixed and dissolved to prepare an oil phase.
59.795 parts of water, 8.5 parts of skimmed milk powder, 1 part of milk protein (potassium caseinate/trade name Tatua 500: manufactured by Tatua, total solid content 96.0%, protein 91.2%), 0.24 parts of emulsifier, 0.2 parts of a pH adjuster and 0.025 parts of a polysaccharide thickener were mixed with stirring by a homomixer to prepare an aqueous phase.
The prepared oil phase and water phase were stirred at 65°C for 30 minutes with a homomixer for pre-emulsification, and then sterilized by direct heating at 144°C for 4 seconds using an ultra-high temperature sterilizer (manufactured by Iwai Kikai Kogyo Co., Ltd.). was homogenized at a homogenization pressure of 40 Mpa and immediately cooled to 10°C. After cooling, it was aged for about 24 hours to obtain a whipped cream.
(Example 19) Addition of random transesterified oil Based on the formulation of Comparative Example 5, 5 parts of palm kernel oil was replaced with random transesterified oil E1, whipped cream was prepared in the same manner as in Comparative Example 1, and fats and oils was confirmed.
For the effect of addition, 1 kg of the resulting whipped cream was whipped with a Hobard mixer (MODEL N-5 manufactured by HOBART CORPORATION) at 3rd speed (300 rpm) until the maximum foaming state was reached, and 5 tasteful panelists skilled in the field of milk were tested. It was confirmed by requesting and performing a sensory evaluation. Sensory evaluation scores were given on a scale of 1 to 5 according to the following evaluation criteria, and 3 or more points were accepted.
(Evaluation criteria)
5 points: Very good flavor with no off-flavour derived from milk protein.
4 points: Almost no off-flavour derived from milk protein is felt, and the flavor is good.
3 points: A slightly different flavor derived from milk protein is sensed, but the flavor is good.
2 points: A strange flavor derived from milk protein is sensed, and the flavor is bad.
1 point: The off-flavour derived from the milk protein is felt most, and the flavor is very bad.

(表9)

Figure 2023049042000009
(Table 9)
Figure 2023049042000009

(考察)
表9の結果より、得られたホイップクリームは、特定の脂肪酸組成に調製したランダムエステル交換油脂を特定量添加することで、乳蛋白質由来の異風味を抑制することができた。
(Discussion)
From the results in Table 9, the obtained whipped cream was able to suppress the off-flavour derived from milk protein by adding a specific amount of random transesterified fat prepared to have a specific fatty acid composition.

Claims (16)

下記(A)及び(B)を満たす、ランダムエステル交換油脂、ならびに動物性蛋白質を含む、水中油型乳化物。
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
An oil-in-water emulsion containing random transesterified fat and animal protein that satisfies the following (A) and (B).
(A) In the constituent fatty acid composition, the content of saturated fatty acids with 6 to 10 carbon atoms is 0.3 to 40% by weight
(B) The content of saturated fatty acids with 12 to 14 carbon atoms in the constituent fatty acid composition is 40 to 80% by weight
該ランダムエステル交換油脂が(A)、(B)、及び(C)を満たす、請求項1に記載の水中油型乳化物。
(C)構成脂肪酸組成中、オレイン酸含量が10重量%以下
The oil-in-water emulsion according to claim 1, wherein the random transesterified fat satisfies (A), (B), and (C).
(C) oleic acid content of 10% by weight or less in the constituent fatty acid composition
該ランダムエステル交換油脂が(A)、(B)、及び(D)を満たす、請求項1に記載の水中油型乳化物。
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0
The oil-in-water emulsion according to claim 1, wherein the random transesterified fat satisfies (A), (B), and (D).
(D) (Content of saturated fatty acid with 12 to 14 carbon atoms)/(Content of saturated fatty acid with 6 to 10 carbon atoms) ratio is 1.0 to 6.0
該ランダムエステル交換油脂が(A)、(B)、(C)、及び(D)を満たす、請求項2に記載の水中油型乳化物。
(D)(炭素数12~14の飽和脂肪酸の含有量)/(炭素数6~10の飽和脂肪酸の含有量)の比が1.0~6.0
3. The oil-in-water emulsion according to claim 2, wherein the random transesterified fat satisfies (A), (B), (C) and (D).
(D) (Content of saturated fatty acid with 12 to 14 carbon atoms)/(Content of saturated fatty acid with 6 to 10 carbon atoms) ratio is 1.0 to 6.0
上記(A)が1~35重量%である、請求項1又は請求項2に記載の水中油型乳化物。 The oil-in-water emulsion according to claim 1 or claim 2, wherein (A) is 1 to 35% by weight. 上記(A)が1~35重量%である、請求項3又は請求項4に記載の水中油型乳化物。 The oil-in-water emulsion according to claim 3 or claim 4, wherein (A) is 1 to 35% by weight. 水中油型乳化物中の蛋白質含量100重量部あたり、該ランダムエステル交換油脂を1.9重量部以上添加する、請求項5に記載の水中油型乳化物。 The oil-in-water emulsion according to claim 5, wherein 1.9 parts by weight or more of the random transesterified fat is added per 100 parts by weight of the protein content in the oil-in-water emulsion. 水中油型乳化物中の蛋白質含量100重量部あたり、該ランダムエステル交換油脂を1.9重量部以上添加する、請求項6に記載の水中油型乳化物。 The oil-in-water emulsion according to claim 6, wherein 1.9 parts by weight or more of the random transesterified fat is added per 100 parts by weight of the protein content in the oil-in-water emulsion. 水中油型乳化物の蛋白質含量が2.2重量%以上である、請求項5に記載の水中油型乳化物。 6. The oil-in-water emulsion according to claim 5, wherein the protein content of the oil-in-water emulsion is 2.2% by weight or more. 水中油型乳化物の蛋白質含量が2.2重量%以上である、請求項6に記載の水中油型乳化物。 7. The oil-in-water emulsion according to claim 6, wherein the protein content of the oil-in-water emulsion is 2.2% by weight or more. 該動物性蛋白質が乳蛋白質である、請求項5に記載の水中油型乳化物。 6. The oil-in-water emulsion according to claim 5, wherein said animal protein is milk protein. 該動物性蛋白質が乳蛋白質である、請求項6に記載の水中油型乳化物。 7. The oil-in-water emulsion according to claim 6, wherein said animal protein is milk protein. 水中油型乳化物が飲料、ホイップクリーム、ホワイトナーである、請求項5に記載の水中油型乳化物。 The oil-in-water emulsion according to claim 5, wherein the oil-in-water emulsion is a beverage, whipped cream, or whitener. 水中油型乳化物が飲料、ホイップクリーム、ホワイトナーである、請求項6に記載の水中油型乳化物。 7. The oil-in-water emulsion according to claim 6, wherein the oil-in-water emulsion is a beverage, whipped cream or whitener. 下記(A)及び(B)を満たす、ランダムエステル交換油脂を1.9重量%以上(水中油型乳化物中の蛋白質含量100重量部あたり)、ならびに動物性蛋白質を混合し乳化する、水中油型乳化物の製造方法。
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
1.9% by weight or more of random transesterified fat and oil (per 100 parts by weight of protein content in the oil-in-water emulsion) that satisfies the following (A) and (B), and animal protein is mixed and emulsified, oil-in-water method for producing a type emulsion.
(A) In the constituent fatty acid composition, the content of saturated fatty acids with 6 to 10 carbon atoms is 0.3 to 40% by weight
(B) The content of saturated fatty acids with 12 to 14 carbon atoms in the constituent fatty acid composition is 40 to 80% by weight
下記(A)及び(B)を満たす、ランダムエステル交換油脂、ならびに動物性蛋白質を含む水中油型乳化物における、異風味を抑制させる方法。
(A)構成脂肪酸組成中、炭素数6~10の飽和脂肪酸の含有量が0.3~40重量%
(B)構成脂肪酸組成中、炭素数12~14の飽和脂肪酸の含有量が40~80重量%
A method for suppressing off-flavor in an oil-in-water emulsion containing random transesterified fat and animal protein, which satisfies the following (A) and (B).
(A) In the constituent fatty acid composition, the content of saturated fatty acids with 6 to 10 carbon atoms is 0.3 to 40% by weight
(B) The content of saturated fatty acids with 12 to 14 carbon atoms in the constituent fatty acid composition is 40 to 80% by weight
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