JP2023006665A - Makeup cosmetic - Google Patents

Abstract

To provide a makeup cosmetic that contains an oil-soluble dye to develop a color very vividly, with its vividness to last for a long time.SOLUTION: A makeup cosmetic contains following components (A), (B), (C) and (D): (A) 5-50 mass% of a polyglyceryl fatty acid ester, which is formed by esterifying a polyglycerol with an average degree of polymerization of 4-15 calculated from a hydroxyl value, with a C12-22 linear or branched fatty acid, (B) an oil-soluble dye, (C) a volatile oil, and (D) an organic oil gelator 4-25 mass%. The mass ratio of the component (A) to the total amount of a nonvolatile oil phase including the component (A), ((A)/total amount of nonvolatile oil phase), is 0.15-0.95.SELECTED DRAWING: None

Description

The present invention relates to make-up cosmetics.

Lip cosmetics such as lipsticks and lip glosses, and makeup cosmetics such as eye shadows and cheeks are required to have bright colors.
For example, Patent Literature 1 describes that a makeup cosmetic containing an oil-soluble dye, a higher fatty acid metal salt, and an oil component exhibits vivid fluorescent coloration and provides excellent transparency.

JP 2016-132650 A

However, the makeup cosmetic of Cited Document 1 was not sufficiently satisfactory in terms of vividness of color development.

The present inventors have found that by blending a specific polyglycerol fatty acid ester in a non-volatile oil phase at a high concentration together with an oil-soluble dye, extremely vivid color development can be obtained.

The present invention provides the following components (A), (B), (C) and (D):
(A) 5 to 50% by mass of polyglycerin fatty acid ester obtained by esterifying polyglycerol having an average degree of polymerization of 4 to 15 calculated from the hydroxyl value with a linear or branched fatty acid having 12 to 22 carbon atoms,
(B) an oil-soluble dye,
(C) a volatile oil;
(D) Organic oil gelling agent 4-25% by mass
and the mass ratio of component (A) to the total amount of non-volatile oil phase containing component (A) ((A)/total amount of non-volatile oil phase) is 0.15 to 0.95.

Further, the present invention provides (A) a polyglycerin fatty acid ester obtained by esterifying polyglycerin having an average degree of polymerization of 4 to 15 calculated from the hydroxyl value with a linear or branched fatty acid having 12 to 22 carbon atoms, and (B) Contact with an oil-soluble dye so that the mass ratio of component (A) to the total amount of non-volatile oil phase containing component (A) ((A)/total amount of non-volatile oil phase) is 0.15 to 0.95. It relates to a coloring method.
Furthermore, in the present invention, in the presence of (C) a volatile oil and (D) an organic oil gelling agent, (A) polyglycerol having an average degree of polymerization of 4 to 15 calculated from the hydroxyl value is A polyglycerin fatty acid ester esterified with a linear or branched fatty acid and (B) an oil-soluble dye are added to the total amount of the non-volatile oil phase containing the component (A). total amount of phases) is 0.15 to 0.95.

The make-up cosmetic of the present invention exhibits extremely vivid coloration due to the oil-soluble dye.

Component (A) used in the present invention is a polyglycerin fatty acid ester obtained by esterifying polyglycerin having an average degree of polymerization of 4 to 15 calculated from the hydroxyl value with a linear or branched fatty acid having 12 to 22 carbon atoms.
The fatty acid preferably has 12 to 18 carbon atoms from the viewpoint of obtaining a more vivid color without hindering the color development of the dye, and the transparency is low due to the low crystallinity. The fatty acid is preferably a branched fatty acid, and more preferably isostearic acid, from the viewpoint that the fatty acid is high and the color development of the dye is not hindered and more vivid color development can be obtained.
In the component (A), the fatty acid to be esterified may be one or two or more, and esters of a plurality of types of fatty acids having different numbers of carbon atoms and whether or not they are branched may be used.

Component (A) suppresses the decrease in transparency, does not interfere with the color development of oil-soluble dyes, and obtains vivid color development. (N×0.5)≦n≦(N+2), where n is the average number of (average number of added moles of fatty acid per 1 mol of polyglycerin). Here, the average degree of polymerization N of polyglycerol can be calculated from the hydroxyl value obtained by the neutralization titration method, for example.
Component (A) is preferably a polyglycerin fatty acid ester obtained by esterifying polyglycerol having an average degree of polymerization N of 8 to 12 with a branched fatty acid having 12 to 18 carbon atoms at an average number of added moles n of 5 to 12. A polyglycerin fatty acid ester obtained by esterifying polyglycerin having an average degree of polymerization N of 8 to 12 with isostearic acid at an average addition mole number n of 8 to 12 is more preferable.

Component (A) can be used alone or in combination of two or more, and the content is 5% by mass or more, preferably 10% by mass or more, in the total composition from the viewpoint of obtaining vivid color development. It is more preferably 12% by mass or more, and from the viewpoint of properly adjusting the finish and feeling in use, it is 50% by mass or less, preferably 40% by mass or less, and more preferably 35% by mass or less. The content of component (A) is 5 to 50% by mass, preferably 10 to 40% by mass, more preferably 12 to 35% by mass in the total composition.

In the present invention, the mass ratio of component (A) to the total amount of non-volatile oil phase containing component (A) ((A)/total amount of non-volatile oil phase) is 0.15 or more from the viewpoint of obtaining vivid color development. It is preferably 0.2 or more, more preferably 0.27 or more, and is 0.95 or less, preferably 0.9 or less, and more preferably 0.7 or less from the viewpoint of properly adjusting the finish and feeling of use. Further, the mass ratio of component (A) to the total amount of non-volatile oil phase containing component (A) ((A) / total amount of non-volatile oil phase) is 0.15 to 0.95, and 0.2 to 0.9 Preferably, 0.27 to 0.7 is more preferable.
By blending the component (A) in the non-volatile oil phase at a high concentration in this way, extremely vivid color development can be obtained.
Here, the non-volatile oil phase containing the component (A) refers to an oily component in which the oil-soluble dye of the component (B) can be dissolved and dispersed at the blending temperature, and not only the component (A) but also the component (D) organic oil gelling agents, liquid oils and paste oils other than component (A) (excluding component (C)), surfactants, polyhydric alcohols and other oily components. On the other hand, the oil phase does not contain components in which the oil-soluble dye does not dissolve or disperse at the blending temperature, such as water and powder.

The oil-soluble dye of component (B) is used in ordinary cosmetics, and preferably one or more selected from Red No. 218, Red No. 223 and Orange No. 201.
The oil-soluble dye of component (B) can be used alone or in combination of two or more. 0.01% by mass or more is more preferable, 0.02% by mass or more is more preferable, and from the viewpoint of obtaining transparent color development, it is preferably 3% by mass or less, more preferably 2% by mass or less, and further preferably 1% by mass or less. preferable. The content of component (B) is preferably 0.001 to 3% by mass, more preferably 0.01 to 2% by mass, even more preferably 0.02 to 1% by mass in the total composition.

Volatile oils of component (C) include volatile silicone oils and volatile hydrocarbon oils. Here, volatile means having a flash point of 35-87°C.
Examples of volatile silicone oils include linear dimethylpolysiloxanes such as dimethylpolysiloxane (1cs), dimethylpolysiloxane (1.5cs), and dimethylpolysiloxane (2cs); methyltrimethicone, tris(trimethylsilyl)methylsilane, Branched siloxanes such as tetrakis(trimethylsilyl)silane; cyclic dimethylsiloxanes such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane;

Volatile hydrocarbon oils include, for example, paraffinic hydrocarbon oils such as n-decane, n-undecane and n-dodecane; isoparaffinic hydrocarbon oils such as isodecane, isododecane and hydrogenated polyisobutene; Cyclic paraffin hydrocarbon oils are mentioned. Among these, hydrocarbon oils having 8 to 16 carbon atoms are preferred, hydrocarbon oils having 10 to 16 carbon atoms are more preferred, and hydrocarbon oils having 12 carbon atoms are even more preferred.

The volatile oil of component (C) preferably contains a volatile hydrocarbon oil, more preferably an isoparaffinic hydrocarbon oil, from the viewpoint of obtaining a finish with good color development.
Commercially available products thereof include Markasol R (manufactured by Maruzen Petrochemical Co., Ltd.; flash point: 47°C) and Pearl Ream 3 (manufactured by NOF Corporation: flash point: 61°C).

The volatile oil of component (C) can be used alone or in combination of two or more. From the viewpoint of increasing the non-volatile oil phase concentration change, the total composition is preferably 20% by mass or more, more preferably 30% by mass or more, and even more preferably 40% by mass or more. 70% by mass or less is preferable, 65% by mass or less is more preferable, and 60% by mass or less is even more preferable. The content of component (C) is preferably 20 to 70% by mass, more preferably 30 to 65% by mass, and even more preferably 40 to 60% by mass in the total composition.

In the present invention, the mass ratio of component (A) to component (C) ((A)/(C)) is determined by volatilization of component (C) from the viewpoint of controlling color development after coating and obtaining vivid color development. , is preferably 0.1 or more, more preferably 0.15 or more, still more preferably 0.2 or more, preferably 1 or less, more preferably 0.8 or less, and even more preferably 0.7 or less. Further, the mass ratio of component (A) to component (C) ((A)/(C)) is preferably 0.1 to 1, more preferably 0.15 to 0.8, and 0.2 to 0.8. 7 is more preferred.

The organic oil gelling agent of component (D) is an oil gelling agent containing an organic component as a main component, and may be any oil gelling agent that is used in ordinary cosmetics. Examples thereof include dextrin fatty acid esters, amino acid-based gelling agents, and waxes having a melting point of 61°C or higher.

The dextrin fatty acid ester is not limited as long as it is used in ordinary cosmetics, and from the viewpoint of feeling during use, storage stability and oil gelation, esters of fatty acids having 8 to 24 carbon atoms and dextrin are preferable. Esters of fatty acids having 14 to 20 carbon atoms and dextrins are more preferred. Also, the average degree of polymerization of dextrin is preferably 3-150.
Specific examples include dextrin palmitate, dextrin stearate, dextrin palmitate/stearate, dextrin oleate, dextrin isopalmitate, dextrin isostearate, dextrin myristate, dextrin palmitate/2-ethylhexanoate, and the like. .
Among these, dextrin palmitate, dextrin myristate, and dextrin palmitate/2-ethylhexanoate are preferred, and those containing at least dextrin palmitate are more preferred from the viewpoint of sustaining vividness.

Any amino acid-based gelling agent that is commonly used in cosmetics can be used without limitation. Specifically, dibutyl lauroyl glutamide and dibutylethylhexanoyl glutamide are preferred.
Commercially available products thereof include dibutyl lauroyl glutamide (GP-1) and dibutyl ethyl hexanoyl glutamide (EB-21) manufactured by Ajinomoto Co., Inc.

An amino acid-based gelling agent can also be used as a premixed gel that has been diluted and dissolved in advance with a solvent in terms of improving workability and being excellent in gelling oil.
The solvent is not limited as long as it can gel the oil with an amino acid-based gelling agent, but from the viewpoint of gelling the oil, octyldodecanol, isostearic acid, and the like are preferable. The content of the amino acid-based gelling agent in the premix gel is preferably 10 to 45% by mass, from the viewpoint of improving workability, gelling oil, and suppressing oil separation of the premix gel itself. 40% by mass is more preferable, and 20 to 36% by mass is even more preferable.
As the premix gel, commercially available products such as AJK-OD2046 containing 20% by mass of amino acid-based gelling agent and AJK-IS3613 containing 36% by mass of amino acid gelling agent (manufactured by Higher Alcohol Co., Ltd.) can be used.

Waxes with a melting point of 61°C or higher exhibit solid properties at 25°C.
In the present invention, the melting point is measured by one of the general test methods 1, 2, or 3 in the Standards for Quasi-drug Ingredients. As for which method to use, if there is a measurement method described in the standards for quasi-drug raw materials for each component, follow that method. If there is no description, select the measurement method in consideration of the melting point. Specifically, Method 1 is used when the melting point is much higher than 80°C, Method 2 is used for solid fats with a lower melting point, and Method 3 is used for what is called paste oil in catalogs. be able to.

Such waxes are not limited as long as they are commonly used in cosmetics. Examples include mineral waxes such as ozokerite and ceresin; petroleum waxes such as paraffin and microcrystalline wax; Fischer-Tropsch wax, polyethylene wax, Synthetic hydrocarbons such as synthetic hydrocarbon waxes; plant waxes such as carnauba wax, candelilla wax, rice wax and sunflower wax; animal waxes such as beeswax and whale wax; synthetic waxes such as silicone wax and synthetic beeswax. be done.
Among these, paraffin, microcrystalline wax, and synthetic hydrocarbon wax are preferred from the viewpoints of shape retention, feeling in use, storage stability, oil gelation, and persistence of vividness.
The wax having a melting point of 61° C. or higher preferably has a melting point of 65° C. or higher and 140° C. or lower, more preferably 70° C. or higher and 105° C. or lower, from the viewpoint of improving storage stability at high temperatures and improving workability. In addition, it is preferable not to contain a wax having a melting point of more than 105° C. in order to provide a smooth feeling in use without unevenness.

As the oil gelling agent of component (D), dextrin palmitate, dibutyl lauroyl glutamide, dibutyl ethyl hexanoyl glutamide, and a melting point of 61 ° C. or higher are used from the viewpoint of maintaining oil gelling, feeling of use, and vividness. is preferably one or more selected from waxes of

Component (D) can be used alone or in combination of two or more. It is 4% by mass or more in the composition, preferably 4.5% by mass or more, more preferably 5% by mass or more, and from the viewpoint of uniform coating and obtaining vivid color development, it is 25% by mass or less, and 22% by mass. The following is preferable, and 19% by mass or less is more preferable. The content of component (D) is 4 to 25% by mass, preferably 4.5 to 22% by mass, more preferably 5 to 19% by mass in the total composition.

The make-up cosmetic of the present invention may further contain (E) an organic acid. The organic acid functions as a pH adjuster and can suppress separation of the oil-soluble dye. In addition, the dyeing power during application can be controlled.
Any organic acid that is used in ordinary cosmetics can be used without limitation. Specifically, one or more selected from citric acid, malic acid, succinic acid, acetic acid, lactic acid, tartaric acid, and fumaric acid are preferred, and citric acid is more preferred.
The organic acid content is preferably 0.001 to 2% by mass, more preferably 0.002 to 1% by mass, and even more preferably 0.005 to 0.5% by mass in the total composition.

The make-up cosmetic of the present invention contains, in addition to the above components, components used in ordinary cosmetics, such as oily components other than components (A) and (C), colorants other than component (B), powder, Surfactants, lower alcohols, polyhydric alcohols, polymer compounds, ultraviolet absorbers, antioxidants, fragrances, antifouling agents, moisturizing agents, water and the like can be contained.

The make-up cosmetic of the present invention can be produced by a conventional method, and can be in either solid or non-solid form.
The make-up cosmetic of the present invention is preferably an oil-based cosmetic having an oily agent as a continuous phase. It can be used as makeup cosmetics such as eye shadows and cheek colors. Among them, it is suitable as a lip cosmetic selected from lipstick, lip balm, lip gloss and lip liner because of its effective bright color development.

The make-up cosmetic of the present invention may be in the form of a make-up cosmetic containing components (A) and (B) in advance in the same cosmetic, or may contain at least component (A) before use. The first cosmetic can be mixed with the second cosmetic containing the component (B), and used in the form of a makeup cosmetic containing the components (A) and (B) finally. That is, components (A) and (B) may not necessarily be contained in the same cosmetic composition, and may be divided into two or more agents and blended. Then, the first cosmetic containing at least the component (A) and the second cosmetic containing at least the component (B) are mixed so that the mass ratio of the component (A) to the total amount of the non-volatile oil phase is 0. By adjusting the ratio to 0.15 to 0.95, the component (B), the oil-soluble dye, can develop color or improve its color developability. A cosmetic containing component (A) functions as a coloring agent.
In the aspect of mixing before use, the mass ratio of component (A) to the total amount of non-volatile oil phase of component (C) and component (D) is within the above range, and it is applied with an appropriate viscosity or hardness. As long as it becomes easier, it may be contained in either one or both of the cosmetics, and by volatilizing the component (C) from the mixed cosmetic, it is possible to improve color development and color development. .

As a mode in which such a first cosmetic containing the component (A) is mixed with the second cosmetic containing the component (B), in addition to being mixed before use, the user can mix the first cosmetic The cosmetic and the second cosmetic may be mixed by applying the cosmetic and the second cosmetic in layers on the skin or the like. In this case, the components (A) and (B) are mixed at the applied site (eg, on the skin or lips), and the mass ratio of the component (A) to the total amount of the non-volatile oil phase is 0.15 to 0.95. and the order of application may be any. In addition, the component (C) and the component (D) may be contained in either or both of the cosmetics, and the volatilization of the component (C) from the coating film after application results in color development, You can enjoy the change in color, such as improved color development.
Further, each of the cosmetics may be colored by containing coloring agents other than oil-soluble dyes, specifically, organic pigments, inorganic pigments, luster pigments, and the like. In this case, when the user mixes these, the color of the oil-soluble dye develops, so that the color can be changed to a color different from that of the various pigments before mixing.

As described above, in the present invention, the user can use the first cosmetic containing the polyglycerin fatty acid ester as the component (A) and the second cosmetic containing the oil-soluble dye as the component (B). is mixed on the skin, etc., and the mass ratio of component (A) to the total amount of non-volatile oil phase containing component (A) is set to 0.15 to 0.95 at the mixed site. A soluble dye can be colored or its color development can be improved. In this way, it is possible to enjoy changes in color, such as expression of color and improvement of color development.
For example, two or more cosmetics may be mixed so that the mass ratio of component (A) to the total amount of non-volatile oil phase is 0.15 to 0.95, and two or more cosmetics with different contents of component (A) may be mixed. ingredients may be mixed so that the mass ratio of component (A) is 0.15 to 0.95. (B) The oil-soluble dye may be contained in any cosmetic.
In addition, the part where the mass ratio of the component (A) is 0.15 to 0.95 does not need to be the entire range of the makeup object, but a part (for example, when mixing on the makeup object, the part ) may be

Test example 1
By measuring the color of compositions No. 1 to No. 8 having the compositions shown in Table 1, when the content of component (A) was changed from 0 to 50% by mass, the oil-soluble dye of component (B) was evaluated for color development. The results are also shown in Table 1.

(Production method)
A total amount of 300 g was blended using a 1 L container with a diameter of 130 mm and a disper blade with a diameter of 30 mm (rotation speed was 2500 r/min in the entire process). First, the base materials (other than the colorant) were heated to 110° C. and uniformly mixed for 5 minutes while maintaining the temperature. Colorant was then added and homogenized for an additional 2 minutes. After defoaming, the mixture was cooled to room temperature and solidified to prepare a composition.

(Evaluation method for colorimetry)
A sample for colorimetry was obtained by heating and dissolving each composition at 80°C using a microwave oven, filling a transparent resin container with an inner diameter of 42 mm and a height of 12 mm to a height of 9 mm, and with the container covered. It was prepared by cooling and solidifying to room temperature.
Colorimetry is carried out using a color difference meter CR-300 manufactured by Minolta Camera Co., Ltd., placing the measurement sample on the attached standard white plate so that the bottom faces upward, and measuring L ^* , a ^* , and b ^* was measured, and chroma C ^* =√(a ^*2 +b ^*2 ) was calculated using a ^* and b ^* .
The chroma C ^* , which is a colorimetric value, is a value representing the vividness of the color, and the larger the value, the more vivid the color.

From the results in Table 1, it was confirmed that the color development gradually improved from 20% by mass of the component (A), and sufficient color development was obtained when the content was 30% by mass or more.

Examples 1-11, Comparative Examples 1-2 (lip gloss)
A lip gloss having the composition shown in Table 2 was produced. For the obtained lip glosses, the feeling of change in brilliance of the agent applied and the persistence of the brilliance of the agent two hours after application were evaluated. The results are also shown in Table 2.

(Production method)
A total amount of 300 g was blended using a 1 L container with a diameter of 130 mm and a disper blade with a diameter of 30 mm (rotation speed was 2500 r/min in the entire process). First, the base material raw materials (other than component (C) and the colorant) were heated to 110° C. and uniformly mixed for 5 minutes while maintaining the temperature. Next, the colorant was added and mixed for an additional 2 minutes, and finally the component (C) was added and mixed for 1 minute. After defoaming, it was cooled to room temperature and solidified. A required amount was cut out from this bulk, heated and melted at 80° C. using a microwave oven, poured into a transparent dipping container, cooled and solidified to obtain a lip gloss. The cosmetic applicator (tip) used had a flat applicator portion and a flocked surface.

(Evaluation method)
(1) Sense of change in vividness of the applied agent:
10 expert panelists took each lip gloss as a chip and compared the finish immediately after application to the lips and 5 minutes after application, and evaluated the change in vividness of the applied agent according to the following criteria. The results were shown as the total score of 10 expert panelists.
5; Brightness of the applied agent changed considerably.
4; Brightness of the applied agent changed.
3; The vividness of the applied agent slightly changed.
2; The vividness of the applied agent did not change much.
1; the vividness of the applied agent did not change

(2) Persistence of agent vividness 2 hours after application:
Ten expert panelists took each lip gloss as a tip and applied it to the lips, and evaluated the persistence of the vividness of the agent 2 hours after application according to the following criteria. The results were shown as the total score of 10 expert panelists. Samples with an evaluation result of less than 20 for "(1) change in vividness of applied agent" were not evaluated because they lacked lasting vividness and were difficult to evaluate.
5; Vividness lasts 5 minutes after application.
4; Vividness persists 5 minutes after application.
3; Vividness persists for 5 minutes after application.
2; Vividness 5 minutes after application does not last long.
1; Vividness does not last 5 minutes after application.

*1: S face IS-1009P (manufactured by Sakamoto Pharmaceutical Co., Ltd.)
(Glycerin average degree of polymerization 10, average added mole number 10, fatty acid carbon chain length 18 (branched))
*2: S face IS-1005P (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.)
(Glycerin average polymerization degree 10, average added mole number 5, fatty acid carbon chain length 18 (branched))
*3: S face IS-401P (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.)
(Glycerin average polymerization degree 4, average added mole number 1, fatty acid carbon chain length 18 (branched))
*4: S face L-1001 (manufactured by Sakamoto Pharmaceutical Co., Ltd.)
(Glycerin average polymerization degree 10, average added mole number 1, fatty acid carbon chain length 12 (branched))
*5: S face S-1001P (manufactured by Sakamoto Pharmaceutical Co., Ltd.)
(Glycerin average degree of polymerization 10, average added mole number 1, fatty acid carbon chain length 18 (straight chain))
*6: Cosmol 42V (manufactured by Nisshin OilliO Group)
(Glycerin average degree of polymerization 2, average added mole number 2, fatty acid carbon chain length 18 (branched))

Test example 2
Regarding Example 1, the composition after preparation and the composition after volatilization of the volatile oil were measured in the same manner as in Test Example 1.
Regarding the agent after volatilization, spread the agent thinly on a glass plate to a thickness of about 1 mm and leave it at room temperature in a dark place for about 1 hour to volatilize the volatile oil. After defoaming, a transparent resin container having an inner diameter of 42 mm and a height of 12 mm was filled up to a height of 9 mm to prepare a sample for colorimetry.

The results are as follows.
As-prepared composition values: L ^* =48.88, C ^* =6.62
Component (C) values after volatilization: L ^* =40.73, C ^* =41.44
The composition after preparation (component (A) 18% by mass, component (B) 0.1% by mass) cannot sufficiently develop the color of Red No. 218, but after volatilization of component (C) By setting the concentration of component (A) in the non-volatile oil phase to 40% by mass, it was possible to sufficiently develop the color of Red No. 218.

Example 12 (two-part lip gloss)
In the same manner as in Examples 1 to 11, the first agent (B1) having the composition shown in Table 3 and the second agent (C1) as a coloring agent containing the component (A) were produced.
The first agent B1 and the second agent C1 were mixed at a ratio of 1:1 (B:C=1:1). Regarding the lip gloss (Example 12) after mixing at 1:1, in the same manner as in Examples 1 to 11, the feeling of change in the vividness of the applied agent and the persistence of the vividness of the agent 2 hours after application evaluated. In addition, colorimetry was performed in the same manner as in Test Example 1 for each agent and lip gloss before and after mixing. The results are also shown in Table 3.
From the results shown in Table 3, it can be seen that in the lip gloss after mixing, a vivid color completely different from each agent before mixing and the appearance color after mixing was developed in the agent after application over time.

Claims (8)

The following components (A), (B), (C) and (D):
(A) 5 to 50% by mass of polyglycerin fatty acid ester obtained by esterifying polyglycerol having an average degree of polymerization of 4 to 15 calculated from the hydroxyl value with a linear or branched fatty acid having 12 to 22 carbon atoms,
(B) an oil-soluble dye,
(C) a volatile oil;
(D) Organic oil gelling agent 4-25% by mass
and wherein the mass ratio of component (A) to the total amount of non-volatile oil phase containing component (A) ((A)/total amount of non-volatile oil phase) is 0.15 to 0.95. 2. The makeup according to claim 1, wherein (N×0.5)≦n≦(N+2), where N is the average degree of polymerization of polyglycerol and n is the average number of moles of added fatty acid in component (A). cosmetics. 3. The makeup cosmetic according to claim 1, wherein the fatty acid in component (A) is isostearic acid. The makeup cosmetic according to any one of claims 1 to 3, wherein component (B) is one or more selected from Red No. 218, Red No. 223 and Orange No. 201. The makeup cosmetic according to any one of claims 1 to 4, further comprising (E) an organic acid. The makeup cosmetic according to any one of claims 1 to 5, which is a lip cosmetic. (A) Polyglycerin fatty acid ester obtained by esterifying polyglycerin having an average degree of polymerization of 4 to 15 calculated from the hydroxyl value with a linear or branched fatty acid having 12 to 22 carbon atoms, and (B) an oil-soluble dye, A color-developing method in which the mass ratio of component (A) to the total amount of non-volatile oil phase containing component (A) ((A)/total amount of non-volatile oil phase) is 0.15 to 0.95. (C) In the presence of a volatile oil and (D) an organic oil gelling agent, (A) polyglycerol having an average degree of polymerization of 4 to 15 calculated from the hydroxyl value is treated with a linear or branched fatty acid having 12 to 22 carbon atoms. Esterified polyglycerol fatty acid ester and (B) an oil-soluble dye are added so that the mass ratio of component (A) to the total amount of non-volatile oil phase containing component (A) ((A)/total amount of non-volatile oil phase) is 0 .15 to 0.95.