JP2022536528A - 固体洗濯物柔軟剤組成物 - Google Patents
固体洗濯物柔軟剤組成物 Download PDFInfo
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- JP2022536528A JP2022536528A JP2021574262A JP2021574262A JP2022536528A JP 2022536528 A JP2022536528 A JP 2022536528A JP 2021574262 A JP2021574262 A JP 2021574262A JP 2021574262 A JP2021574262 A JP 2021574262A JP 2022536528 A JP2022536528 A JP 2022536528A
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- Prior art keywords
- composition
- solid
- quaternary ammonium
- alkyl
- softening
- Prior art date
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- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 209
- 239000007787 solid Substances 0.000 title claims abstract description 137
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims abstract description 87
- 239000008247 solid mixture Substances 0.000 claims abstract description 74
- 239000004094 surface-active agent Substances 0.000 claims abstract description 62
- 150000003839 salts Chemical class 0.000 claims abstract description 36
- 239000004615 ingredient Substances 0.000 claims abstract description 32
- 239000000843 powder Substances 0.000 claims abstract description 28
- 230000009969 flowable effect Effects 0.000 claims abstract description 19
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 14
- -1 magnesium cations Chemical class 0.000 claims description 90
- 125000000217 alkyl group Chemical group 0.000 claims description 46
- 125000004432 carbon atom Chemical group C* 0.000 claims description 43
- 235000002639 sodium chloride Nutrition 0.000 claims description 43
- 238000000034 method Methods 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 229910001868 water Inorganic materials 0.000 claims description 33
- 239000004744 fabric Substances 0.000 claims description 32
- 229920001296 polysiloxane Polymers 0.000 claims description 28
- 150000002148 esters Chemical class 0.000 claims description 21
- 150000001412 amines Chemical class 0.000 claims description 18
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 18
- 239000003945 anionic surfactant Substances 0.000 claims description 15
- 150000001450 anions Chemical group 0.000 claims description 15
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical group [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- 239000000839 emulsion Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 244000060011 Cocos nucifera Species 0.000 claims description 7
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 7
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 7
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 7
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 7
- 239000003760 tallow Substances 0.000 claims description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 6
- 239000007900 aqueous suspension Substances 0.000 claims description 6
- 150000001768 cations Chemical class 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 4
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 125000005227 alkyl sulfonate group Chemical group 0.000 claims description 3
- 125000005131 dialkylammonium group Chemical group 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 229920013822 aminosilicone Polymers 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- RCTOVWPTGOZSPJ-UHFFFAOYSA-N benzyl(ethyl)azanium;chloride Chemical compound Cl.CCNCC1=CC=CC=C1 RCTOVWPTGOZSPJ-UHFFFAOYSA-N 0.000 claims description 2
- XKXHCNPAFAXVRZ-UHFFFAOYSA-N benzylazanium;chloride Chemical compound [Cl-].[NH3+]CC1=CC=CC=C1 XKXHCNPAFAXVRZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000011449 brick Substances 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 239000002775 capsule Substances 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 3
- 150000002462 imidazolines Chemical class 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 23
- 238000011068 loading method Methods 0.000 abstract description 11
- 239000000969 carrier Substances 0.000 abstract description 8
- 238000007711 solidification Methods 0.000 abstract description 8
- 230000008023 solidification Effects 0.000 abstract description 8
- 229920000642 polymer Polymers 0.000 description 26
- 125000002091 cationic group Chemical group 0.000 description 22
- 150000001875 compounds Chemical class 0.000 description 22
- 239000000463 material Substances 0.000 description 20
- 238000009472 formulation Methods 0.000 description 19
- 229920002472 Starch Polymers 0.000 description 17
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 17
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
- 239000000194 fatty acid Substances 0.000 description 16
- 229930195729 fatty acid Natural products 0.000 description 16
- 150000004665 fatty acids Chemical class 0.000 description 16
- 235000019698 starch Nutrition 0.000 description 16
- 239000008107 starch Substances 0.000 description 14
- 230000008901 benefit Effects 0.000 description 12
- 229920006395 saturated elastomer Polymers 0.000 description 12
- 239000002979 fabric softener Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 125000001453 quaternary ammonium group Chemical group 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 9
- 239000002280 amphoteric surfactant Substances 0.000 description 9
- 150000007942 carboxylates Chemical class 0.000 description 9
- 239000002270 dispersing agent Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 9
- 229910052740 iodine Inorganic materials 0.000 description 9
- 239000011630 iodine Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 244000303965 Cyamopsis psoralioides Species 0.000 description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- 238000007664 blowing Methods 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 239000003093 cationic surfactant Substances 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 7
- 150000001735 carboxylic acids Chemical class 0.000 description 7
- 125000000623 heterocyclic group Chemical group 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 230000000087 stabilizing effect Effects 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- 229920000289 Polyquaternium Polymers 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000012265 solid product Substances 0.000 description 6
- 125000000547 substituted alkyl group Chemical group 0.000 description 6
- 230000008961 swelling Effects 0.000 description 6
- 239000003826 tablet Substances 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 6
- 238000004383 yellowing Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 125000002877 alkyl aryl group Chemical group 0.000 description 5
- 150000003868 ammonium compounds Chemical group 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 230000029936 alkylation Effects 0.000 description 4
- 238000005804 alkylation reaction Methods 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 235000019197 fats Nutrition 0.000 description 4
- 125000001165 hydrophobic group Chemical group 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 229940100486 rice starch Drugs 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- 125000003107 substituted aryl group Chemical group 0.000 description 4
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 4
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 3
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229920002261 Corn starch Polymers 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 229920006317 cationic polymer Polymers 0.000 description 3
- 239000008120 corn starch Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000003752 hydrotrope Substances 0.000 description 3
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 240000003183 Manihot esculenta Species 0.000 description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
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- 239000004952 Polyamide Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 125000002015 acyclic group Chemical group 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
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- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 2
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- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 2
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- 238000004132 cross linking Methods 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- PGZPBNJYTNQMAX-UHFFFAOYSA-N dimethylazanium;methyl sulfate Chemical compound C[NH2+]C.COS([O-])(=O)=O PGZPBNJYTNQMAX-UHFFFAOYSA-N 0.000 description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
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- 239000000417 fungicide Substances 0.000 description 2
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/62—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0069—Laundry bars
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
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- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/10—Carbonates ; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/75—Amino oxides
-
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Abstract
Description
本願は、米国特許法第119条のもと、2019年6月28日に出願された仮出願第62/868,089号に対する優先権を主張するものであり、本明細書では、参照によってその全体が組み込まれる。
本開示による固体洗濯物柔軟化組成物は、四級アンモニウム化合物および無機担体を含み、これらからなり、かつ/またはこれらから本質的になる。実施形態では、固体組成物は、無機担体を含む固体組成物中に高濃度または高充填量の四級アンモニウム化合物を有することが有益である。一実施形態では、固体組成物は、少なくとも約15重量%、少なくとも約20重量%、または少なくとも約25重量%の四級アンモニウム化合物を有する。固体組成物はまた、柔軟化促進剤(例えば、シリコーン、ポリマー)、安定化界面活性剤、および/またはさらなる機能性成分を含み得る。
本明細書に記載の固体洗濯物柔軟化組成物は、少なくとも1つの四級アンモニウム化合物を含む。単一の四級アンモニウム化合物または2つ以上の四級アンモニウム化合物の組み合わせは、本発明による固体組成物の実施形態に含まれ得る。四級アンモニウム化合物は、以下の一般式:
無機担体は、固体洗濯物柔軟化組成物中に、すなわち、四級アンモニウム化合物の凝固剤として含まれる。無機担体は、無機塩を含み、四級アンモニウム化合物と組み合わせるための中性塩を提供するために、アニオン(負イオン)とともに様々なカチオン(正電荷イオン)を含み得る。本発明の特定の作用機序または理論に限定されるものではないが、無機塩は、四級アンモニウム化合物からの高いレベルの液体を吸収して、従来的に利用可能であるより高い固体組成物への充填速度を可能にするために、固体洗濯物柔軟化組成物中で有益に使用され、また一方で、流し込みされる固体組成物のために従来的に製造される溶融液体と比較して加工温度がより低いことを理由に、凝固プロセスを有益に受けることができる。
固体洗濯物柔軟化組成物の構成要素は、洗濯物の柔軟化用途に、ならびに/または固体洗濯物柔軟化組成物の加工および形成での使用に好適な様々な機能性構成要素とさらに組み合わされてもよい。いくつかの実施形態では、四級アンモニウム化合物および無機担体を含む固体組成物は、固体組成物の総重量の大部分または実質的にすべてさえを構成する。例えば、いくつかの実施形態では、さらなる機能性成分は、ほとんどまたは全く、その中に配置されていない。
固体洗濯物柔軟化組成物は、任意選択的に柔軟化促進剤を含み得る。柔軟化促進剤としては、シリコーン化合物およびポリマー、堆積助剤、例えば、カチオン性セルロースおよびカチオン性荷電ポリマー、例えば、ポリクオタニウム、グアー誘導体、ならびに柔軟剤として単独では機能しないが、代わりに四級アンモニウム化合物の柔軟性を促進する他の促進剤が挙げられる。
(a)Lは、二価アルキレン結合ラジカルであり、R2はそれぞれ、独立して、H、C1~C4アルキル、置換アルキル、アリール、置換アリール、およびそれらの組み合わせからなる群から選択され、sはそれぞれ、独立して、2~約12の整数であり、yはそれぞれ、独立して、1~約100の整数であり、
(b)X1およびX2はそれぞれ、独立して、
(c)R1はそれぞれ、独立して、H、OH、C1~C32アルキル、C1~C32置換アルキル、C6~C32アリール、C5~C32置換アリール、C6~C32アルキルアリール、C6~C32置換アルキルアリール、C1~C32アルコキシ、およびC1~C32置換アルコキシからなる群から選択され、
(d)R3はそれぞれ、独立して、C1~C32アルキレン、C1~C32置換アルキレン、C6~C32アリール、C5~C32置換アリール、C6~C32アルキレンアリール、およびC5~C32置換アルキレンアリールからなる群から選択され、
(e)指数mはそれぞれ、1または0であり、
(f)qはそれぞれ、1または0であり、
(g)指数pはそれぞれ、約2~約1000の整数であり、かつ
(h)指数nは、約1~約50の整数である。
好ましい実施形態では、界面活性剤は、四級アンモニウム化合物および無機担体を有する安定した固形物を配合するために、アニオン性界面活性剤および/または両親媒性(例えば、アミンオキシド)界面活性剤を含む。固体組成物中の界面活性剤濃度は、約1重量%~約30重量%、約5重量%~約30重量%、約5重量%~約25重量%、約5重量%~約20重量%、または約5重量%~約15重量%の範囲にあり得る。
アニオン性界面活性剤は、疎水性物質に対して負の電荷を有するか、またはpHが中性以上に上昇しない限り、分子の疎水性部分は電荷を帯びない(例えば、カルボン酸)。カルボキシレート、スルホネート、スルフェート、およびホスフェートは、アニオン性界面活性剤中に見出される極性(親水性)可溶化基である。これらの極性基と関連したカチオン(対イオン)のうち、ナトリウム、リチウム、およびカリウムは、水溶性を付与し、アンモニウムおよび置換アンモニウムイオンは、水溶性および油溶性の両方を提供し、カルシウム、バリウム、およびマグネシウムは、油溶性を促進する。
R-O-(CH2CH2O)n(CH2)m-CO2X(3)
式中、Rは、C8~C22アルキル基であるか、または
また、本発明において有用なのは、両親媒性界面活性剤として分類される表面活性物質である。両親媒性(または両性)界面活性剤は、塩基性親水性基および酸性親水性基の両方、ならびに有機疎水性基を含有する。これらのイオン性実体は、他の種類の界面活性剤について本明細書に記載されるアニオン性またはカチオン性基のいずれかであり得る。塩基性窒素および酸性カルボキシレート基は、塩基性および酸性親水基として用いられる典型的な官能基である。いくつかの界面活性剤では、スルホネート、スルフェート、ホスホネート、またはホスフェートは、負電荷を提供する。
分子のヒドロトロープ部分の電荷が正である場合、カチオン性界面活性剤として分類される表面活性物質もまた、組成物において有用である。ヒドロトロープがpHが中性近くまたはそれ以下まで下げられない限り電荷を帯びないが、その場合カチオン性(例えば、アルキルアミン)である界面活性剤も、この群に含まれる。理論的には、カチオン性界面活性剤は、「オニウム」構造RnX+Y--を含有する要素の任意の組み合わせから合成され得て、リン(ホスホニウム)および硫黄(スルホニウム)のような窒素(アンモニウム)以外の化合物を含み得る。実際には、カチオン性界面活性剤分野は、恐らく、窒素性カチオン性物質への合成経路が、単純かつ容易であり、高収率の生成物を生じるため、窒素含有化合物により支配されており、このことが、それらをより安価にすることができる。
組成物の有効性および/または組成物の凝固を改善するために、任意選択的に他の活性成分を使用することができる。そのようなさらなる機能性成分の非限定的な例としては、さらなる界面活性剤(柔軟性のためのものを含む)、防食剤、酵素、発泡防止剤、増粘剤、再付着防止剤、抗エッチング剤、抗菌剤、漂白剤、触媒、凝固助剤、導電性のための塩、分散剤、香料、加工助剤、および組成物に所望の特性または機能性を付与するのに有用な他の成分が挙げられる。以下に、そのような成分のいくつかの例を記載する。
加工助剤は、有利な特徴を固体組成物に提供することができる。一実施形態では、凝固のための加工助剤は、1つ以上の非潮解性物質を含む。有益なことに、非潮解性物質を含むことにより非吸湿性物質が形成され、そのため、(固体組成物の分配中などに)固体組成物が湿気に曝されたときに、組成物は、水を吸収しないか、または液体になるのに十分な水を吸収しない。これは、分配の課題を理由として、すなわち、固体組成物が曝される湿った環境を理由として重要である。
固体組成物はまた、少なくとも1つのさらなる塩をさらなる加工助剤として含み得る。一実施形態では、さらなる塩は、導電性のための塩であり、かつ/または洗浄液の導電性の標準的な測定を可能にするための無機アニオンもしくは非封鎖有機アニオン(non-sequestering organic anion)である。塩化ナトリウムを使用することが好ましいが、多種多様なイオン化可能な塩を使用してもよい。好適な塩の例は、元素周期表の第IA族の金属のハロゲン化物および酢酸塩、例えば、塩化リチウム、塩化ナトリウム、塩化カリウム、塩化アンモニウム、臭化ナトリウム、臭化カリウム、臭化カルシウム、ヨウ化ナトリウム、ヨウ化カリウム、酢酸ナトリウム、酢酸カリウム、またはそれらの混合物である。塩化ナトリウムが好ましい。イオン化可能な塩は、成分を混合して本明細書の組成物を作製して、後に柔軟化組成物の分散速度を測定するための所望の導電性を得るプロセス中に、特に有用である。使用されるイオン化可能な塩の量は、組成物に使用される活性成分の量に応じており、配合者の要望に応じて調整することが可能である。
物品および表面から汚れおよび微生物を除去するのを補助するために、分散剤が含まれ得る。分散剤の例としては、水溶性ポリマー、界面活性剤、ヒドロトロープ、および湿潤剤が挙げられるが、これらに限定されることはない。好ましい実施形態では、分散剤は、アニオン性界面活性剤である。組成物は、分散剤を含む必要はないが、分散剤が含まれる場合、これは、所望の分散特性をもたらす量で含まれ得る。組成物中の分散剤の好適な範囲は、約20重量%まで、約0.5~約15重量%、または約2~約9重量%であり得る。
固体組成物はまた、任意の柔軟剤相溶性の香料/芳香物質を含み得る。好適な芳香物質は、米国特許第5,500,138号に開示されており、当該特許は、参照によって本明細書に組み込まれる。
固体組成物はまた、性能の利益のためのさらなる界面活性剤を、これらのさらなる界面活性剤が、アニオン性界面活性剤および/または両親媒性(例えば、アミンオキシド)界面活性剤が本明細書で示すような固体配合物または安定性の利益を提供することができなくても含み得る。一実施形態では、アニオン性および/または両親媒性界面活性剤に加えて、非イオン性界面活性剤を含めることができる。
表1A~1Bに示される固体洗濯物柔軟化組成物を凝固させることができる。固体組成物は、一般に入手可能な混合装置内で製造することが可能である。実施形態では、凝固剤、すなわち、無機塩を組成物に組み込むことによって、液体材料を固体に適合させることができる。
固体洗濯物柔軟化組成物は、好ましくは、本明細書に開示される重量パーセンテージおよび比の構成要素を組み合わせることにより形成される多目的固体組成物である。固体組成物は固体として提供され、使用溶液が懸濁液である場合の使用溶液は、分配および/または洗濯プロセス中に形成される。
固体洗濯物柔軟化組成物は、消費者用および工業用の洗濯用途に適している。したがって、本明細書に記載の実施形態によると、1回使用および多目的の固体組成物を提供することができる。
Stepan Companyから入手可能なアミンカルボキシレート界面活性剤
固体担体上への四級アンモニウム化合物の充填/吸収
四級アンモニウム化合物を評価して、四級アンモニウム化合物を固体担体上に充填することができるかどうか、およびどの程度まで充填することができるかを特定した。評価した四級アンモニウム化合物は、TEAエステルクワットであった。四級アンモニウム化合物を、表2に従って配合物に組み込んだ。
固体担体上への四級アンモニウム化合物の充填/吸収
四級アンモニウム柔軟剤化合物を無機塩担体(硫酸マグネシウム)と組み合わせて評価し、プレスされる固体柔軟化組成物へと配合すべき組成物の安定性を決定した。プレスされる柔軟化組成物を表3に従って配合した。
界面活性剤を有する固体担体への四級アンモニウム化合物の充填
先の実施例で示したように、四級アンモニウム化合物が多く充填された固体配合物は、固体組成物のための吸湿性材料が含まれているため、特に高湿度の存在下で安定性を失う可能性がある。したがって、四級アンモニウム化合物を含有する固体柔軟化組成物を、様々なタイプの界面活性剤を用いて評価して、固体四級柔軟化組成物を安定化させる様々な界面活性剤の能力を試験した。
例示的な固体四級アンモニウム柔軟剤組成物を、無機担体およびアミンオキシド界面活性剤の両方と一緒に配合して、プレスされた固形物を形成するための組成物の寸法安定性を評価した。例示的な配合物を表7に記載する。
四級アンモニウム化合物の柔軟化評価
綿タオルのサンプルを柔軟剤配合物で処理し、柔軟性をphabrometerで評価した。約28ポンドの充填重量で綿タオルを5回の二重汚れ落としサイクル(double scouring cycles)にかけ、各サイクルの間に乾燥させることによって、綿タオルのサンプルを用意した。11.3cmの円形ダイを有するダイプレスを使用して、サンプル見本を汚れ落としされたハンドタオルから切り取って、評価される配合物ごとに少なくとも4つのサンプル見本が存在するようにした。見本をそれらの試験条件に従ってラベル付けした。
Claims (25)
- 前記四級アンモニウム化合物のR1およびR2が、12~18個の炭素原子を有する同じまたは異なるヒドロカルビル基を表し、R3およびR4が、1~約4個の炭素原子を含有する同じまたは異なるヒドロカルビル基を表す、請求項1に記載の組成物。
- 前記四級アンモニウム化合物が、アルキルベンジルアンモニウムクロリド、アルキルエチルベンジルアンモニウムクロリド、またはジアルキルアンモニウム塩を含む、請求項1または2に記載の組成物。
- 前記四級アンモニウム化合物が、アルキルC12~C18ベンジルアンモニウムクロリド、アルキルC12~C18エチルベンジルアンモニウムクロリド、またはジアルキルC12~C18ジアルキルC1~C4アンモニウム塩を含む、請求項3に記載の組成物。
- 前記四級アンモニウム化合物が、エステルクワット、アミドアミン、イミダゾリン、エステルアミド塩、またはそれらの組み合わせを含む、請求項1に記載の組成物。
- 前記無機塩担体および前記四級アンモニウム化合物が組み合わさって流動性粉末を提供し、前記流動性粉末がプレスされて固体組成物にされた、請求項1~5のいずれか一項に記載の組成物。
- 前記無機塩担体が、マグネシウムカチオン、ナトリウムカチオン、カリウムカチオン、カルシウムカチオン、アンモニウムカチオン、および/またはアミンカチオンを含む、無機塩のためのカチオンを含み、さらに、塩化物アニオン、硫酸アニオン、カルボン酸アニオン、ポリカルボン酸アニオン、炭酸アニオン、重炭酸アニオン、カルボン酸アニオン、リン酸アニオン、および/または水酸化物アニオンを含む、無機塩のためのアニオンを含む、請求項6に記載の組成物。
- 前記無機塩が、硫酸マグネシウム、硫酸ナトリウム、塩化ナトリウム、クエン酸塩、エチレンジアミン四酢酸塩(EDTA)、炭酸ナトリウム、重炭酸ナトリウム、カルボン酸ナトリウム、水酸化ナトリウム、塩化カリウム、水酸化カリウム、塩化カルシウム、および/またはカルボン酸アンモニウムを含む、請求項7に記載の組成物。
- 前記四級アンモニウム化合物が、前記固体洗濯物柔軟化組成物の約15重量%~約80重量%、または約25重量%~約60重量%を占め、有機担体が、前記固体洗濯物柔軟化組成物の約40重量%~約80重量%、約50重量%~約80重量%、または約50重量%~約70重量%を占める、請求項1~8のいずれか一項に記載の組成物。
- 前記固体組成物の約0.1重量%~約20重量%の量の柔軟化促進剤をさらに含む、請求項1~9のいずれか一項に記載の組成物。
- 前記柔軟化促進剤が、堆積助剤またはシリコーン、好ましくは、ポリアルキルシリコーン、アミノシリコーン、シロキサン、ポリジメチルシロキサン、エトキシル化有機シリコーン、プロポキシル化有機シリコーン、エトキシル化/プロポキシル化有機シリコーン、またはそれらの混合物を含む有機シリコーンである、請求項10に記載の組成物。
- 前記シリコーンがシリコーンエマルションであり、前記固体組成物を作製するためにさらなる水が添加されない、請求項11に記載の組成物。
- アニオン性界面活性剤および/またはアミンオキシド界面活性剤を含む有効量の界面活性剤をさらに含む、請求項1~12のいずれか一項に記載の組成物。
- 前記アニオン性界面活性剤が、アルキルスルホネート、直鎖および分岐鎖一級および二級アルキルスルホネート、置換基を有する若しくは有しない芳香族スルホネート、またはそれらの組み合わせを含む、請求項13に記載の組成物。
- 前記アニオン性界面活性剤が、アルキルエーテルスルフェート、アルキルスルフェート、直鎖および分岐鎖一級および二級アルキルスルフェート、またはそれらの組み合わせを含む、請求項13に記載の組成物。
- 前記アミンオキシド界面活性剤が、ココナッツまたはタローアルキルジ-(低級アルキル)アミンオキシドを含む、請求項13に記載の組成物。
- 前記界面活性剤が、前記固体組成物の約1重量%~約30重量%、約5重量%~約25重量%、または約5重量%~約20重量%を占める、請求項13~16のいずれか一項に記載の組成物。
- 加工助剤、界面活性剤、酸(すなわち、酸味料)、および/または他のさらなる機能性成分をさらに含む、請求項1~17のいずれか一項に記載の組成物。
- 前記固体組成物が、少なくとも250グラムの多目的組成物であり、かつ/または前記固形物が、流し込みもしくは押出された固形物であり、前記固形物が、カプセル、タブレット、パック、ブリック、もしくはブロックである、請求項1~18のいずれか一項に記載の組成物。
- ウォッシュホイール内で布地を処理するための方法であって、前記方法は、
(a)請求項1~19のいずれか一項に記載の固体洗濯物柔軟化組成物を提供することであって、前記固体洗濯物柔軟化組成物が、流動性粉末から形成された安定した固体組成物である、提供することと、
(b)前記固体洗濯物柔軟化組成物と水とを接触させて水性懸濁液を形成することと、
(c)前記水性懸濁液をウォッシュホイールに分配することであって、前記水性懸濁液が前記処理すべき布地と接触する、分配することと、を含む、方法。 - 安定した固体洗濯物柔軟化組成物を形成する方法であって、前記方法は、
(a)無機塩担体と、以下の式:
(b)自由流動性粉末を形成することと、
(c)前記流動性粉末をプレスすることによって、または前記流動性粉末から押出された固形物を形成することによって、安定した固体洗濯物柔軟化組成物を形成することと、を含み、
前記固体組成物が、少なくとも約15重量%の前記四級アンモニウム化合物を含む、方法。 - アニオン性界面活性剤および/またはアミンオキシド界面活性剤を含む界面活性剤を、前記無機塩担体および前記四級アンモニウム化合物と組み合わせることをさらに含む、請求項20または21に記載の方法。
- 前記アニオン性界面活性剤が、アルキルスルホネート、直鎖および分岐鎖一級および二級アルキルスルホネート、置換基を有する若しくは有しない芳香族スルホネート、またはそれらの組み合わせを含む、請求項22に記載の方法。
- 前記アニオン性界面活性剤が、アルキルエーテルスルフェート、アルキルスルフェート、直鎖および分岐鎖一級および二級アルキルスルフェート、またはそれらの組み合わせを含む、請求項22に記載の方法。
- 前記アミンオキシド界面活性剤が、ココナッツまたはタローアルキルジ-(低級アルキル)アミンオキシドを含む、請求項22に記載の方法。
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