JP2022141390A5 - Heavy oil recovery method, recovery system, and recovery device - Google Patents

Heavy oil recovery method, recovery system, and recovery device Download PDF

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JP2022141390A5
JP2022141390A5 JP2021041667A JP2021041667A JP2022141390A5 JP 2022141390 A5 JP2022141390 A5 JP 2022141390A5 JP 2021041667 A JP2021041667 A JP 2021041667A JP 2021041667 A JP2021041667 A JP 2021041667A JP 2022141390 A5 JP2022141390 A5 JP 2022141390A5
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本発明は、重質油の回収方法回収システム、及び回収装置に関する。 The present invention relates to a heavy oil recovery method , recovery system , and recovery device .

また、前記界面活性剤は、親水性が低く親油性が高いものであり、前記界面活性剤の前記親水性と前記親油性のバランスを示す数値(HLB)は、20未満であることが好適である Further, the surfactant has low hydrophilicity and high lipophilicity, and a numerical value (HLB) indicating the balance between the hydrophilicity and the lipophilicity of the surfactant is less than 20. suitable .

請求項に対応した重質油をエマルション化して回収する回収システムは、前記重質油が内部を流動する配管と、前記重質油に対して10重量%以上45重量%以下の水と、0.5重量%以上5重量%以下の界面活性剤とを添加する添加手段と、前記重質油と前記水と前記界面活性剤とを撹拌する撹拌手段と、前記撹拌手段で撹拌してエマルション化した前記重質油を回収するポンプ手段とを備えることを特徴とする。 A recovery system for emulsifying and recovering heavy oil according to claim 6 includes: a pipe through which the heavy oil flows; and water in an amount of 10% by weight or more and 45% by weight or less based on the heavy oil; an addition means for adding 0.5% by weight or more and 5% by weight or less of a surfactant; a stirring means for stirring the heavy oil, the water, and the surfactant; and stirring with the stirring means to form an emulsion. and a pump means for recovering the converted heavy oil.

また、前記重質油回収船は、収容した前記重質油をさらに重質油運搬船に移送する移送手段を有することが好適である。
請求項15に対応した重質油の回収装置は、重質油をエマルション化して回収する回収装置であって、前記重質油の入った重質油タンクに取り付けられる配管と、前記配管の先端部に設けたエジェクタと、前記エジェクタに接続される作動流体供給配管と、前記作動流体供給配管を介して前記エジェクタに作動流体として水と界面活性剤を供給する高圧ポンプとを備え、前記エジェクタにより重質油に前記水と前記界面活性剤を添加しエマルション化して前記配管を介して回収することを特徴とする重質油の回収装置である。
ここで、前記重質油に対して10重量%以上45重量%以下の前記水と、0.5重量%以上5重量%以下の前記界面活性剤とを添加する添加手段を備えたことが好適である。
また、前記添加手段は、前記水と前記界面活性剤を予め混合する混合槽を有し、前記混合槽で混合した前記水と前記界面活性剤の混合液を、前記高圧ポンプを介して前記エジェクタに導くことが好適である。
また、前記重質油を吸い込む前記エジェクタに前記作動流体を予め加熱する加熱手段を有することが好適である。
Further, it is preferable that the heavy oil recovery ship has a transfer means for further transferring the stored heavy oil to a heavy oil carrier.
A heavy oil recovery device according to claim 15 is a recovery device that emulsifies and recovers heavy oil, and includes a pipe attached to a heavy oil tank containing the heavy oil, and a tip end of the pipe. an ejector provided in the section, a working fluid supply pipe connected to the ejector, and a high-pressure pump that supplies water and a surfactant as working fluid to the ejector via the working fluid supply pipe; The heavy oil recovery apparatus is characterized in that the water and the surfactant are added to the heavy oil to form an emulsion, and the emulsion is recovered via the piping.
Here, it is preferable to include an addition means for adding 10% by weight or more to 45% by weight of the water and 0.5% to 5% by weight of the surfactant to the heavy oil. It is.
Further, the addition means includes a mixing tank for pre-mixing the water and the surfactant, and supplies the mixed solution of the water and the surfactant mixed in the mixing tank to the ejector via the high-pressure pump. It is preferable to lead to
Further, it is preferable that the ejector that sucks the heavy oil has a heating means for preheating the working fluid.

また、前記重質油回収船は、収容した前記重質油をさらに重質油運搬船に移送する移送手段を有することによって、前記重質油回収船による前記重質油の回収を行いつつ、前記重質油運搬船によって前記重質油を効率的に搬送することができる。
本発明の重質油の回収装置によれば、重質油をエマルション化して回収する回収装置であって、前記重質油の入った重質油タンクに取り付けられる配管と、前記配管の先端部に設けたエジェクタと、前記エジェクタに接続される作動流体供給配管と、前記作動流体供給配管を介して前記エジェクタに作動流体として水と界面活性剤を供給する高圧ポンプとを備え、前記エジェクタにより重質油に前記水と前記界面活性剤を添加しエマルション化して前記配管を介して回収することによって、前記重質油の粘度を低下させ、前記重質油の回収等の処理を容易にすることができる。
ここで、前記重質油に対して10重量%以上45重量%以下の前記水と、0.5重量%以上5重量%以下の前記界面活性剤とを添加する添加手段を備えたことによって、特に、重質油と水と界面活性剤を混合させてエマルション化する場合に、急激に重質油の粘度が低下し転移が生ずる範囲でエマルション化できるため、粘度を有効に低減できる効果が大きい。また、作業の効率化や経費削減、さらに環境保護に繋げることができる。
また、前記添加手段は、前記水と前記界面活性剤を予め混合する混合槽を有し、前記混合槽で混合した前記水と前記界面活性剤の混合液を、前記高圧ポンプを介して前記エジェクタに導くことによって、粘度を低下させた前記重質油の回収等の処理をより迅速に行うことができる。
また、前記重質油を吸い込む前記エジェクタに前記作動流体を予め加熱する加熱手段を有することによって、前記重質油の粘度をより低下させ、前記重質油の回収等の処理をより容易にすることができる。
Further, the heavy oil recovery ship has a transfer means for further transferring the stored heavy oil to a heavy oil carrier, so that the heavy oil can be recovered while the heavy oil is being recovered by the heavy oil recovery ship. The heavy oil can be efficiently transported by the heavy oil carrier.
According to the heavy oil recovery device of the present invention, the recovery device emulsifies and recovers heavy oil, and includes a pipe attached to a heavy oil tank containing the heavy oil, and a tip end of the pipe. a high-pressure pump that supplies water and surfactant as working fluid to the ejector via the working fluid supply piping; Adding the water and the surfactant to the heavy oil to form an emulsion and collecting the emulsion through the piping reduces the viscosity of the heavy oil and facilitates processing such as recovery of the heavy oil. Can be done.
Here, by providing an addition means for adding 10% to 45% by weight of the water and 0.5% to 5% by weight of the surfactant to the heavy oil, In particular, when mixing heavy oil, water, and a surfactant to form an emulsion, the viscosity of the heavy oil can be rapidly reduced and the emulsion can be formed within a range where transition occurs, so it is highly effective in effectively reducing viscosity. . It can also improve work efficiency, reduce costs, and help protect the environment.
Further, the addition means includes a mixing tank for pre-mixing the water and the surfactant, and supplies the mixed liquid of the water and the surfactant mixed in the mixing tank to the ejector via the high-pressure pump. By directing the oil to the oil, it is possible to more quickly recover the heavy oil whose viscosity has been reduced.
Further, by providing the ejector that sucks the heavy oil with a heating means for preheating the working fluid, the viscosity of the heavy oil is further reduced, and processing such as recovery of the heavy oil is made easier. be able to.

ポンプ106は、重質油に圧力を加えるための手段である。ポンプ106は、特に限定さるものではないが、例えば、ジェットポンプやエジェクタ(真空)ポンプとすることができる。エジェクタポンプは、加熱部及びジェット部を含み、加熱された作動流体を蒸気として高速で噴射することによって、高真空側の流体を噴射する蒸気中に巻き込みながら上段のジェット部より下段のジェット部に運ぶことで流体を圧縮しながら排出口より排出させるポンプである。なお、ジェットポンプやエジェクタ(真空)ポンプとした場合は、ポンプ106とエマルションユニット102を兼ねることができ、さらには噴射ノズル14を兼ねることもできる。このように、ジェットポンプやエジェクタ(真空)ポンプを使用することにより、撹拌機能、ポンプ機能、噴射(添加)機能を一体化することも可能である。また、駆動用の流体としては、ポンプ16で加圧される水と界面活性剤の混合液、水と界面活性剤の供給を分けて別途、加圧した水や別途発生させた加熱を兼ねた蒸気等とすることができる。ポンプ106は、重質油の流れ方向に沿ってエマルションユニット102の噴射ノズル14よりも下流側に配置することが好適である。ポンプ106は、例えば、回収配管104の先端又は途中に設けられる。ポンプ106によって重質油に圧力を加えることによって、回収配管104を介してエマルションユニット102から回収船200へ向かう重質油に流れを形成して重質油を回収する。また、ポンプ106は、本体部10内において重質油と水及び界面活性剤を攪拌するための攪拌手段の1つとして利用してもよい。ポンプ106の定格は、回収する重質油の種類、量等に応じて適宜決定すればよい。 Pump 106 is a means for applying pressure to heavy oil. The pump 106 is not particularly limited, but can be, for example, a jet pump or an ejector (vacuum) pump. The ejector pump includes a heating section and a jet section, and by injecting heated working fluid as steam at high speed, the fluid on the high vacuum side is drawn into the injected steam and flows from the upper jet section to the lower jet section. This is a pump that compresses fluid by transporting it and discharges it from the outlet . In addition, when a jet pump or an ejector (vacuum) pump is used, the pump 106 can serve as the emulsion unit 102, and can also serve as the injection nozzle 14. In this way, by using a jet pump or an ejector (vacuum) pump, it is also possible to integrate the stirring function, pump function, and injection (addition) function. In addition, as the driving fluid, a mixed liquid of water and surfactant pressurized by the pump 16, a separate supply of water and surfactant, pressurized water, and a separately generated heating liquid are used. It can be steam, etc. It is preferable that the pump 106 be disposed downstream of the injection nozzle 14 of the emulsion unit 102 along the flow direction of the heavy oil. The pump 106 is provided, for example, at the tip or midway of the recovery pipe 104. By applying pressure to the heavy oil with the pump 106, a flow is formed in the heavy oil heading from the emulsion unit 102 to the recovery vessel 200 via the recovery piping 104, and the heavy oil is recovered. Further, the pump 106 may be used as one of the stirring means for stirring the heavy oil, water, and surfactant within the main body 10. The rating of the pump 106 may be determined as appropriate depending on the type, amount, etc. of heavy oil to be recovered.

Claims (18)

重質油をエマルション化して回収する回収方法であって、
前記重質油に対して10重量%以上45重量%以下の水と、0.5重量%以上5重量%以下の界面活性剤を添加し、撹拌してエマルション化することにより粘度を低下させて回収することを特徴とする重質油の回収方法。
A recovery method for recovering heavy oil by emulsifying it,
The viscosity is lowered by adding 10% to 45% by weight of water and 0.5% to 5% by weight of a surfactant to the heavy oil and stirring to form an emulsion. A method for recovering heavy oil, which is characterized by recovering heavy oil.
請求項1に記載の重質油の回収方法であって、
前記重質油は、前記粘度が50mPa・s以上の物質であることを特徴とする重質油の回収方法。
The heavy oil recovery method according to claim 1 ,
A method for recovering heavy oil, wherein the heavy oil is a substance having a viscosity of 50 mPa·s or more.
請求項1又は2に記載の重質油の回収方法であって、
前記水と前記界面活性剤を添加する前に、前記重質油を予め加熱して前記粘度を低下させることを特徴とする重質油の回収方法。
The heavy oil recovery method according to claim 1 or 2 ,
A method for recovering heavy oil, comprising heating the heavy oil in advance to lower the viscosity before adding the water and the surfactant.
請求項1~のいずれか1項に記載の重質油の回収方法であって、
前記界面活性剤は、親水性が低く親油性が高いものであり、前記界面活性剤の前記親水性と前記親油性のバランスを示す数値(HLB)は、20未満であることを特徴とする重質油の回収方法。
The method for recovering heavy oil according to any one of claims 1 to 3 , comprising:
The surfactant has low hydrophilicity and high lipophilicity, and a numerical value (HLB) indicating the balance between the hydrophilicity and the lipophilicity of the surfactant is less than 20. A method for recovering heavy oil.
請求項1~のいずれか1項に記載の重質油の回収方法であって、
前記重質油を前記水と前記界面活性剤の噴射により微細化した後、撹拌を行うことを特徴とする重質油の回収方法。
The method for recovering heavy oil according to any one of claims 1 to 4 , comprising:
A method for recovering heavy oil, the method comprising: agitating the heavy oil after the heavy oil is pulverized by spraying the water and the surfactant.
重質油をエマルション化して回収する回収システムであって、
前記重質油が内部を流動する配管と、
前記重質油に対して10重量%以上45重量%以下の水と、0.5重量%以上5重量%以下の界面活性剤とを添加する添加手段と、
前記重質油と前記水と前記界面活性剤とを撹拌する撹拌手段と、
前記撹拌手段で撹拌してエマルション化した前記重質油を回収するポンプ手段とを備えることを特徴とする重質油の回収システム。
A recovery system that emulsifies and recovers heavy oil,
a pipe through which the heavy oil flows;
Addition means for adding 10% to 45% by weight of water and 0.5% to 5% by weight of a surfactant to the heavy oil;
a stirring means for stirring the heavy oil, the water, and the surfactant;
A heavy oil recovery system comprising: pump means for recovering the heavy oil that has been stirred and emulsified by the stirring means.
請求項に記載の重質油の回収システムであって、
前記添加手段は、前記配管の内部を流動する前記重質油に向けて、前記水と前記界面活性剤を噴射する高圧噴射ノズルを有することを特徴とする重質油の回収システム。
The heavy oil recovery system according to claim 6 ,
A heavy oil recovery system, wherein the addition means includes a high-pressure injection nozzle that injects the water and the surfactant toward the heavy oil flowing inside the pipe.
請求項に記載の重質油の回収システムであって、
前記添加手段は、前記水と前記界面活性剤を予め混合する混合槽を有し、前記混合槽で混合した前記水と前記界面活性剤の混合液を、高圧ポンプを介して前記高圧噴射ノズルに導くことを特徴とする重質油の回収システム。
The heavy oil recovery system according to claim 7 ,
The addition means includes a mixing tank for pre-mixing the water and the surfactant, and supplies the liquid mixture of the water and the surfactant mixed in the mixing tank to the high-pressure injection nozzle via a high-pressure pump. A heavy oil recovery system characterized by
請求項のいずれか1項に記載の重質油の回収システムであって、
前記撹拌手段として、前記添加手段より下流側の前記配管の内部にプロペラが配置された撹拌機を有することを特徴とする重質油の回収システム。
The heavy oil recovery system according to any one of claims 6 to 8 ,
A heavy oil recovery system characterized in that the stirring means includes a stirrer in which a propeller is disposed inside the pipe downstream of the addition means.
請求項のいずれか1項に記載の重質油の回収システムであって、
前記撹拌手段として、前記ポンプ手段が撹拌機能を兼ねていることを特徴とする重質油の回収システム。
The heavy oil recovery system according to any one of claims 6 to 9 ,
A heavy oil recovery system characterized in that, as the stirring means, the pump means also has a stirring function.
請求項10のいずれか1項に記載の重質油の回収システムであって、
前記重質油を吸い込む前記配管の先端部に前記重質油を予め加熱する予熱手段を備えることを特徴とする重質油の回収システム。
The heavy oil recovery system according to any one of claims 6 to 10 ,
A heavy oil recovery system, characterized in that a preheating means for preheating the heavy oil is provided at the tip of the pipe that sucks the heavy oil.
請求項11のいずれか1項に記載の重質油の回収システムであって、
前記配管の内部を通る前記重質油の流量を検出する流量検出手段と、
前記添加手段による前記水と前記界面活性剤の添加量を、前記流量検出手段で検出した前記重質油の前記流量に応じて制御する制御手段を備えることを特徴とする重質油の回収システム。
The heavy oil recovery system according to any one of claims 6 to 11 ,
Flow rate detection means for detecting the flow rate of the heavy oil passing through the inside of the piping;
A heavy oil recovery system comprising a control means for controlling the amounts of the water and the surfactant added by the addition means in accordance with the flow rate of the heavy oil detected by the flow rate detection means. .
請求項12のいずれか1項に記載の重質油の回収システムであって、
前記配管は、水面下に存在する沈船における前記重質油の入った重質油タンクに取り付けられ、
前記添加手段と前記撹拌手段と前記ポンプ手段は、前記重質油タンク側の前記配管の先端部に設けられ、
回収した前記重質油を前記水面に臨んだ重質油回収船へ搬送して収容することを特徴とする重質油の回収システム。
The heavy oil recovery system according to any one of claims 6 to 12 ,
The piping is attached to a heavy oil tank containing the heavy oil in a sunken ship located below the water surface,
The addition means, the stirring means, and the pump means are provided at the tip of the piping on the heavy oil tank side,
A heavy oil recovery system characterized in that the recovered heavy oil is transported to and stored in a heavy oil recovery vessel facing the water surface.
請求項13に記載の重質油の回収システムであって、
前記重質油回収船は、収容した前記重質油をさらに重質油運搬船に移送する移送手段を有することを特徴とする重質油の回収システム。
The heavy oil recovery system according to claim 13 ,
A heavy oil recovery system, wherein the heavy oil recovery ship has a transfer means for further transferring the stored heavy oil to a heavy oil carrier.
重質油をエマルション化して回収する回収装置であって、 A recovery device that emulsifies and recovers heavy oil,
前記重質油の入った重質油タンクに取り付けられる配管と、前記配管の先端部に設けたエジェクタと、前記エジェクタに接続される作動流体供給配管と、前記作動流体供給配管を介して前記エジェクタに作動流体として水と界面活性剤を供給する高圧ポンプとを備え、前記エジェクタにより重質油に前記水と前記界面活性剤を添加しエマルション化して前記配管を介して回収することを特徴とする重質油の回収装置。 A pipe attached to the heavy oil tank containing the heavy oil, an ejector provided at the tip of the pipe, a working fluid supply pipe connected to the ejector, and the ejector via the working fluid supply pipe. and a high-pressure pump that supplies water and a surfactant as working fluids to the heavy oil, and the ejector adds the water and the surfactant to the heavy oil, emulsifies the oil, and collects the emulsion through the piping. Heavy oil recovery equipment.
請求項15に記載の重質油の回収装置であって、 The heavy oil recovery device according to claim 15,
前記重質油に対して10重量%以上45重量%以下の前記水と、0.5重量%以上5重量%以下の前記界面活性剤とを添加する添加手段を備えたことを特徴とする重質油の回収装置。 The heavy oil is characterized by being equipped with an addition means for adding 10% to 45% by weight of the water and 0.5% to 5% by weight of the surfactant to the heavy oil. Quality oil recovery equipment.
請求項16に記載の重質油の回収装置であって、 The heavy oil recovery device according to claim 16,
前記添加手段は、前記水と前記界面活性剤を予め混合する混合槽を有し、前記混合槽で混合した前記水と前記界面活性剤の混合液を、前記高圧ポンプを介して前記エジェクタに導くことを特徴とする重質油の回収装置。 The addition means includes a mixing tank for pre-mixing the water and the surfactant, and guides the liquid mixture of the water and the surfactant mixed in the mixing tank to the ejector via the high-pressure pump. A heavy oil recovery device characterized by:
請求項15~17のいずれか1項に記載の重質油の回収装置であって、The heavy oil recovery device according to any one of claims 15 to 17,
前記重質油を吸い込む前記エジェクタに前記作動流体を予め加熱する加熱手段を有することを特徴とする重質油の回収装置。 A heavy oil recovery device characterized in that the ejector that sucks the heavy oil has heating means for preheating the working fluid.
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CN110573154A (en) 2017-02-06 2019-12-13 卡斯西部储备大学 Compositions and methods for modulating short-chain dehydrogenase activity

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