JP2022132531A - Gelatinous food and method for producing the same - Google Patents
Gelatinous food and method for producing the same Download PDFInfo
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- JP2022132531A JP2022132531A JP2022114925A JP2022114925A JP2022132531A JP 2022132531 A JP2022132531 A JP 2022132531A JP 2022114925 A JP2022114925 A JP 2022114925A JP 2022114925 A JP2022114925 A JP 2022114925A JP 2022132531 A JP2022132531 A JP 2022132531A
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- gel
- food
- mass
- gelling agent
- pea protein
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Abstract
Description
本発明は、ゲル状食品およびその製造方法に関する。 TECHNICAL FIELD The present invention relates to a gel-like food and a method for producing the same.
ゲル状食品は、蛋白等のゲル化力を利用した食品であり、例えば、チーズ、ヨーグルト等の発酵食品、ゼリー、プリン等のデザート類等が挙げられる。ゲル状食品は、工業的には、ゲル化剤や呈味成分等の原料を、ゲル化剤のゲル化温度よりも高い温度に加温、混合して原料液を調製し、容器に充填して冷却し、ゲル化剤の作用によりゲル化させる方法で製造されている。 Gelled foods are foods that utilize the gelling power of protein or the like, and include, for example, fermented foods such as cheese and yogurt, and desserts such as jelly and pudding. Gel foods are produced industrially by heating and mixing raw materials such as gelling agents and taste components to a temperature higher than the gelling temperature of the gelling agent to prepare a raw material liquid, which is then filled in a container. It is manufactured by a method of cooling with heat and gelling by the action of a gelling agent.
特許文献1、2には、ゲル化剤及び乳タンパク質を含むゲル状食品が開示されている。ゲル状食品の多くには、乳蛋白、卵蛋白、ゼラチン等の動物性蛋白が利用されている。これらの動物性蛋白は主要な食物アレルギー原因食品であるため、これらの原料を用いない植物性ゲル状食品について多く検討されている。アレルギー性物質を含まないゲル状食品として、例えば、特許文献3には、ゲル化剤および大豆タンパク質のサーモリシン加水分解物を含むゲル状食品が開示されている。 Patent Literatures 1 and 2 disclose gel food containing a gelling agent and milk protein. Animal proteins such as milk protein, egg protein, and gelatin are used in many gel-like foods. Since these animal proteins are major foods that cause food allergies, vegetable gel-like foods that do not use these raw materials have been extensively studied. As a gel-like food containing no allergenic substances, for example, Patent Document 3 discloses a gel-like food containing a gelling agent and thermolysin hydrolyzate of soy protein.
しかしながら、特許文献1~3に記載のゲル状食品は硬度が低く、硬度の高く、かつ動物性蛋白を含まないゲル状食品の開発が求められていた。 However, the gel-like foods described in Patent Documents 1 to 3 have low hardness, and there has been a demand for the development of gel-like foods that have high hardness and do not contain animal protein.
本発明は、硬度の高いゲル状食品およびその製造方法を提供することを目的とする。 An object of the present invention is to provide a gel-like food with high hardness and a method for producing the same.
本発明は以下の態様を有する。
<1> エンドウ豆タンパク質と、ゲル化剤とを含むゲル状食品であって、前記ゲル化剤が、カラギナン及びローカストビーンガムからなり、前記ゲル状食品の総質量に対して、水の含有量が75~98質量%である、ゲル状食品。
<2> 前記エンドウ豆タンパク質の含有量が、前記ゲル状食品の総質量に対して0.1~4質量%である、<1>のゲル状食品。
<3> エンドウ豆タンパク質と、ゲル化剤とを含むゲル状食品であって、前記ゲル化剤が、カラギナン及びローカストビーンガムからなり、前記エンドウ豆タンパク質の含有量が、前記ゲル状食品の総質量に対して0.1~4質量%である、ゲル状食品。
<4> 前記ゲル化剤の含有量が、前記ゲル状食品の総質量に対して0.1~1質量%である、<1>~<3>のいずれかのゲル状食品。
<5> 前記ゲル状食品が、プリン、ゼリー、茶わん蒸し、ゴマ豆腐、卵豆腐、水羊羹、煮こごり、アスピックゼリー、又はトコロテンである、<1>~<4>のいずれかのゲル状食品。
<6> エンドウ豆タンパク質と、ゲル化剤と、水とを含む混合液をゲル化させ、ゲル状食品を得る方法であって、前記ゲル化剤が、カラギナン及びローカストビーンガムからなり、前記水の含有量が、前記混合液の総質量に対して75~98質量%である、ゲル状食品の製造方法。
<7> 前記エンドウ豆タンパク質の含有量が、前記混合液の総質量に対して0.1~4質量%である、<6>のゲル状食品の製造方法。
<8> エンドウ豆タンパク質と、ゲル化剤と、水とを含む混合液をゲル化させ、ゲル状食品を得る方法であって、前記ゲル化剤が、カラギナン及びローカストビーンガムからなり、前記エンドウ豆タンパク質の含有量が、前記混合液の総質量に対して0.1~4質量%である、ゲル状食品の製造方法。
<9> 前記ゲル化剤の含有量が、前記混合液の総質量に対して0.1~1質量%である、<6>~<8>のいずれかのゲル状食品の製造方法。
<10> 前記ゲル状食品が、プリン、ゼリー、茶わん蒸し、ゴマ豆腐、卵豆腐、水羊羹、煮こごり、アスピックゼリー、又はトコロテンである、<6>~<9>のいずれかのゲル状食品の製造方法。
また本発明は以下の側面を有する。
[1] エンドウ豆タンパク質と、寒天、ゼラチンおよび増粘多糖類からなる群より選ばれる1種以上のゲル化剤とを含む、ゲル状食品。
[2] 前記エンドウ豆タンパク質の含有量が、ゲル状食品の総質量に対して0.1~4質量%である、[1]のゲル状食品。
[3] 前記ゲル化剤の含有量が、ゲル状食品の総質量に対して0.01~10質量%である、[1]または[2]のゲル状食品。
[4] 前記増粘多糖類が、カラギナン、ローカストビーンガム、ジェランガムからなる群より選ばれる1種以上である、[1]~[3]のいずれかのゲル状食品。
[5] エンドウ豆タンパク質と、寒天、ゼラチンおよび増粘多糖類からなる群より選ばれる1種以上のゲル化剤とを含む混合液をゲル化させ、ゲル状食品を得る、ゲル状食品の製造方法。
[6] 前記エンドウ豆タンパク質の含有量が、前記混合液の総質量に対して0.1~4質量%である、[5]のゲル状食品の製造方法。
[7] 前記ゲル化剤の含有量が、前記混合液の総質量に対して0.01~10質量%である、[5]または[6]のゲル状食品の製造方法。
[8] 前記増粘多糖類が、カラギナン、ローカストビーンガム、ジェランガムからなる群より選ばれる1種以上である、[5]~[7]のいずれかのゲル状食品の製造方法。
The present invention has the following aspects.
<1> A gel-like food containing pea protein and a gelling agent, wherein the gelling agent consists of carrageenan and locust bean gum, and the content of water with respect to the total mass of the gel-like food is 75 to 98% by mass, gel food.
<2> The gel-like food of <1>, wherein the content of the pea protein is 0.1 to 4% by mass relative to the total mass of the gel-like food.
<3> A gel-like food containing pea protein and a gelling agent, wherein the gelling agent comprises carrageenan and locust bean gum, and the content of the pea protein is the total amount of the gel-like food 0.1 to 4% by mass of gel-like food.
<4> The gelled food according to any one of <1> to <3>, wherein the content of the gelling agent is 0.1 to 1% by mass with respect to the total mass of the gelled food.
<5> The gel-like food according to any one of <1> to <4>, wherein the gel-like food is pudding, jelly, chawanmushi, sesame tofu, egg tofu, mizu-yokan, nikogori, aspic jelly, or tokoroten. .
<6> A method for obtaining a gelled food by gelling a mixture containing pea protein, a gelling agent, and water, wherein the gelling agent comprises carrageenan and locust bean gum, and the water content is 75 to 98% by mass with respect to the total mass of the mixed liquid, a method for producing a gel-like food.
<7> The method for producing a gel-like food according to <6>, wherein the content of the pea protein is 0.1 to 4% by mass with respect to the total mass of the mixture.
<8> A method for obtaining a gelled food by gelling a mixture containing pea protein, a gelling agent, and water, wherein the gelling agent comprises carrageenan and locust bean gum, A method for producing a gel-like food, wherein the content of bean protein is 0.1 to 4% by mass with respect to the total mass of the mixture.
<9> The method for producing a gel-like food according to any one of <6> to <8>, wherein the content of the gelling agent is 0.1 to 1% by mass with respect to the total mass of the mixed liquid.
<10> The gel-like food according to any one of <6> to <9>, wherein the gel-like food is pudding, jelly, chawanmushi, sesame tofu, egg tofu, mizu-yokan, nikogori, aspic jelly, or tokoroten. manufacturing method.
The present invention also has the following aspects.
[1] A gel food containing pea protein and one or more gelling agents selected from the group consisting of agar, gelatin and polysaccharide thickeners.
[2] The gelled food of [1], wherein the pea protein content is 0.1 to 4% by mass relative to the total mass of the gelled food.
[3] The gelled food of [1] or [2], wherein the content of the gelling agent is 0.01 to 10% by mass relative to the total mass of the gelled food.
[4] The gel-like food according to any one of [1] to [3], wherein the polysaccharide thickener is one or more selected from the group consisting of carrageenan, locust bean gum and gellan gum.
[5] Manufacture of a gel-like food by gelling a mixture containing a pea protein and one or more gelling agents selected from the group consisting of agar, gelatin, and thickening polysaccharides to obtain a gel-like food. Method.
[6] The method for producing a gel-like food according to [5], wherein the content of the pea protein is 0.1 to 4% by mass with respect to the total mass of the mixture.
[7] The method for producing a gelled food according to [5] or [6], wherein the content of the gelling agent is 0.01 to 10% by mass with respect to the total mass of the mixture.
[8] The method for producing a gel-like food according to any one of [5] to [7], wherein the polysaccharide thickener is one or more selected from the group consisting of carrageenan, locust bean gum and gellan gum.
本発明によれば、硬度の高いゲル状食品およびその製造方法を提供できる。 ADVANTAGE OF THE INVENTION According to this invention, the gel-like foodstuff with high hardness and its manufacturing method can be provided.
<ゲル状食品>
本発明のゲル状食品は、エンドウ豆タンパク質と、ゲル化剤とを含む。
<Gel food>
The gelled food of the present invention contains pea protein and a gelling agent.
(エンドウ豆タンパク質)
エンドウ豆タンパク質は、エンドウ豆由来のタンパク質である。
本発明において、用語「エンドウ豆」は、全ての野生種の平滑なエンドウ豆ならびにしわの寄ったエンドウ豆、および全ての変異種の平滑なエンドウ豆ならびにしわの寄ったエンドウ豆、例えば、Proceedings of the Symposium of the Industrial Biochemistry and Biotechnology Group of the Biochemical Society、1996年、pp.77-87でのC-L Heydleyらによる標題「Developing novel pea starches」の論文に記載されているものを使用することができる。
エンドウ豆タンパク質は、マメ科植物の全てのタンパク質同様、3つの主なタンパク質群:グロブリン類、アルブミン類およびいわゆる「不溶性」タンパク質からなる。
なお、エンドウ豆タンパク質は、エンドウ豆そのものから得られたタンパク質であってもよいし、エンドウ豆タンパク質の加水分解物であってもよいが、エンドウ豆を酸性化して凝集させて得られたエンドウ豆タンパク質加水分解物は、エンドウ豆タンパク質の酵素的加水分解により、化学的加水分解により、または同時の、または連続的な双方の経路により得られた調製物として定義される。タンパク質加水分解物は、異なるサイズのペプチドの混合物および遊離アミノ酸の混合物からなる。この加水分解はタンパク質の溶解性に影響を与え得る。酵素的加水分解および/または化学的加水分解は、例えば、特許出願国際公開第2008/001183号パンフレットに記載されている。
(pea protein)
Pea protein is protein derived from peas.
In the present invention, the term "pea" refers to all wild types of smooth and shriveled peas and all mutant types of smooth and shriveled peas, e.g. Those described in the paper entitled "Developing novel pea starches" by CL Heydley et al., the Symposium of the Industrial Biochemistry and Biotechnology Group of the Biochemical Society, 1996, pp.77-87 can be used.
Pea protein, like all legume proteins, consists of three main protein groups: globulins, albumins and so-called "insoluble" proteins.
The pea protein may be a protein obtained from the pea itself or a hydrolyzate of the pea protein. A protein hydrolyzate is defined as a preparation obtained by enzymatic hydrolysis of pea protein, by chemical hydrolysis, or by both simultaneous or sequential routes. Protein hydrolysates consist of a mixture of different sized peptides and a mixture of free amino acids. This hydrolysis can affect protein solubility. Enzymatic hydrolysis and/or chemical hydrolysis are described, for example, in patent application WO2008/001183.
エンドウ豆タンパク質としては、より硬度の高いゲル状食品が得られやすい観点から、下記破断試験において硬度と破断点を測定したときにゲルが破断しないエンドウ豆タンパク質を用いることが好ましい。ここで、「破断しない」とは、以下の方法で破断点を検出しないことを意味する。
破断試験:エンドウ豆タンパク質を濃度が25質量%になるように水に分散させてスラリーを調製する。得られたスラリーを容量200mlのステンレス製バットに150g分注し、90℃の恒温槽に60分間浸漬させ、加熱ゲルを形成させる。その後、加熱ゲルを冷蔵庫にて10℃で10時間静置冷却して、ゲルの芯温を一定にする。レオメーターを用い、治具として直径10mmの円形プランジャー(D10)を陥入速度80mm/min、HOLD6g、測定温度10℃の条件で、芯温が一定となったゲルに陥入させたときのゲルの硬度と破断点を測定する。ここで、HOLDとは、ゲルが破断する前の測定値と破断した後の測定値の差が一定以上(この場合6g)開いた時点の荷重量を表示するモードである。この場合、破断する前の測定値と破断した後の測定値の差が6g以上開いた時点の治具の陥入量を破断点(mm)とする。さらに、破断時点の測定値(g)(6g落ちる直前)を硬度(g)とする。
As the pea protein, it is preferable to use a pea protein that does not break the gel when hardness and breaking point are measured in the breaking test described below, from the viewpoint of easily obtaining a gel-like food with a higher hardness. Here, "does not break" means that no breaking point is detected by the following method.
Breaking Test: A slurry is prepared by dispersing pea protein in water to a concentration of 25% by weight. 150 g of the resulting slurry is dispensed into a stainless vat having a capacity of 200 ml and immersed in a constant temperature bath at 90° C. for 60 minutes to form a heated gel. After that, the heated gel is left to cool at 10° C. for 10 hours in a refrigerator to keep the core temperature of the gel constant. Using a rheometer, a circular plunger (D10) with a diameter of 10 mm was used as a jig at an invagination speed of 80 mm / min, HOLD 6 g, and a measurement temperature of 10 ° C., and the gel with a constant core temperature was invaded. Measure the hardness and breaking point of the gel. Here, HOLD is a mode for displaying the amount of load when the difference between the measurement value before the gel breaks and the measurement value after the breakage exceeds a certain value (in this case, 6 g). In this case, the rupture point (mm) is the indentation amount of the jig when the difference between the measured value before breaking and the measured value after breaking is 6 g or more. Further, the measured value (g) at the time of breaking (immediately before dropping by 6 g) is defined as hardness (g).
エンドウ豆タンパク質の分子量は、10KDa~116KDaが好ましく、10KDa~90KDaがより好ましい。
なお、エンドウ豆タンパク質の分子量はSDS-PAGEで分析できる。
The molecular weight of the pea protein is preferably between 10 KDa and 116 KDa, more preferably between 10 KDa and 90 KDa.
The molecular weight of pea protein can be analyzed by SDS-PAGE.
エンドウ豆タンパク質の窒素溶解度指数(NSI)は15~100質量%が好ましく、30~95質量%がより好ましい。
窒素溶解度指数は、全窒素量に占める水溶性窒素の比率(質量%)を表したものであり、以下のようにして求められる。
エンドウ豆タンパク質2.5gを水100mlに分散させて得られた分散液のpHが3~10になるように、塩酸または水酸化ナトリウムで調整した後、30℃で2時間放置する。その後、分散液を遠心分離し、上澄み液について水溶性窒素含有量を測定し、下記式より窒素溶解度指数を求める。
窒素溶解度指数=(水溶性窒素含有量/エンドウ豆タンパク質に含まれる全窒素含有量)×100
The nitrogen solubility index (NSI) of the pea protein is preferably 15-100% by mass, more preferably 30-95% by mass.
The nitrogen solubility index represents the ratio (% by mass) of water-soluble nitrogen to the total amount of nitrogen, and is obtained as follows.
A dispersion obtained by dispersing 2.5 g of pea protein in 100 ml of water is adjusted to pH 3 to 10 with hydrochloric acid or sodium hydroxide, and allowed to stand at 30° C. for 2 hours. Thereafter, the dispersion is centrifuged, the water-soluble nitrogen content of the supernatant is measured, and the nitrogen solubility index is obtained from the following formula.
Nitrogen solubility index = (water-soluble nitrogen content/total nitrogen content in pea protein) x 100
エンドウ豆タンパク質は、原料となるエンドウ豆を粉砕した後、粉砕物に水を加えてタンパク質成分を抽出し、得られた抽出液を濃縮、乾燥することで得られる。
エンドウ豆タンパク質は、市販品から入手可能である。
エンドウ豆タンパク質は1種でもよく2種以上を併用してもよい。
The pea protein is obtained by pulverizing peas as a raw material, adding water to the pulverized product to extract protein components, and concentrating and drying the resulting extract.
Pea protein is commercially available.
One type of pea protein may be used, or two or more types may be used in combination.
ゲル状食品の総質量に対するエンドウ豆タンパク質の含有量は、0.1~4質量%が好ましく、0.5~3質量%がより好ましい。エンドウ豆タンパク質の含有量が上記下限値以上であれば、ゲル状食品の硬度がより高まる。エンドウ豆タンパク質の含有量が上記上限値以下であれば、エンドウ豆特有の風味が抑えられ、ゲル状食品の風味を妨げにくくなる。加えて、ゲル状食品を製造するに際して、予めエンドウ豆タンパク質を水に分散させておく場合、分散液のゲル化を抑制できるので、ハンドリング性を良好に維持できる。 The pea protein content is preferably 0.1 to 4% by mass, more preferably 0.5 to 3% by mass, relative to the total mass of the gelled food. If the pea protein content is at least the above lower limit, the hardness of the gel-like food is further increased. If the pea protein content is equal to or less than the above upper limit, the pea-specific flavor is suppressed, and the flavor of the gel-like food is less likely to be disturbed. In addition, when the pea protein is dispersed in water in advance when producing the gelled food, gelling of the dispersion can be suppressed, so that good handleability can be maintained.
(ゲル化剤)
ゲル化剤は、寒天、ゼラチンおよび増粘多糖類からなる群より選ばれる1種以上である。
(Gelling agent)
The gelling agent is one or more selected from the group consisting of agar, gelatin and thickening polysaccharides.
寒天としては特に限定されず、市販品から適宜選択して用いることができる。寒天は1種でもよく2種以上を併用してもよい。
寒天のゼリー強度は、日寒水式によって測定される値である。すなわち、日本寒天製造水産組合が採用した日寒水式ゼリー強度測定器を用いて測定される値であり、濃度1.5質量%の寒天水溶液を調製し、20℃で15時間放置して凝固させたゲルについて、その表面1cm2当たり20秒間耐えうる最大荷重(g)をゼリー強度(単位:g/cm2)とする。寒天のゼリー強度は10~1500g/cm2程度が好ましい。
寒天の凝固点および寒天の融点は特に限定されない。通常、寒天の凝固点は40~50℃程度、融点は80~90℃程度である。
寒天を2種以上併用する場合、各寒天のゼリー強度、凝固点および融点が、それぞれ上記の好ましい範囲内となるように選択して用いることが好ましい。なお寒天は、ゼラチン、増粘多糖類と併用してもよい。
The agar is not particularly limited, and can be appropriately selected and used from commercially available products. One type of agar may be used, or two or more types may be used in combination.
The jelly strength of agar is a value measured by the Hikansui method. That is, it is a value measured using a Nikkansui type jelly strength measuring instrument adopted by the Nippon Kanten Manufacturing Fisheries Association. An aqueous agar solution with a concentration of 1.5% by mass is prepared and allowed to stand at 20 ° C. for 15 hours to solidify. The jelly strength (unit: g/cm 2 ) is defined as the maximum load (g) that the gel can withstand for 20 seconds per 1 cm 2 of its surface. The jelly strength of agar is preferably about 10 to 1500 g/cm 2 .
The freezing point of agar and the melting point of agar are not particularly limited. Generally, agar has a freezing point of about 40-50°C and a melting point of about 80-90°C.
When two or more agars are used in combination, it is preferable to select and use the agars so that the jelly strength, freezing point and melting point of each agar are within the preferred ranges described above. Agar may be used in combination with gelatin and polysaccharide thickener.
ゼラチンは、動物の皮や骨に多く含まれる不溶性タンパク質を、酸処理またはアルカリ処理して可溶化したものである。ゼラチンとしては特に限定されず、市販品から適宜選択して用いることができる。ゼラチンは1種でもよく2種以上を併用してもよい。
ゼラチンのゼリー強度は、JIS K 6503「にかわおよび工業用ゼラチン」に規定されている測定方法で測定されるゼリー強度である。すなわち、濃度6.67質量%のゼラチン水溶液を調製し、規定の容器に入れ10℃の恒温槽で16~18時間冷却して試料を得る。得られた試料の表面を、直径1/2インチ(12.7mm)のプランジャーで4mm押し下げるのに必要な荷重のグラム数をゼリー強度(単位:ブルームまたはg)とする。ゼラチンのゼリー強度は、100~300ブルーム(100~300g)程度が好ましい。
ゼラチンのゲル化温度およびゼラチンゲルの融点は特に限定されない。通常、ゼラチンのゲル化温度は15~20℃程度、融点は25~30℃程度である。
ゼラチンを2種以上併用する場合、各ゼラチンのゼリー強度、ゲル化温度および融点が、それぞれ上記の好ましい範囲内となるように選択して用いることが好ましい。なお、ゼラチンは、寒天、増粘多糖類と併用してもよい。
Gelatin is obtained by solubilizing insoluble protein, which is abundantly contained in animal skins and bones, by acid or alkali treatment. The gelatin is not particularly limited, and can be appropriately selected from commercially available products and used. One type of gelatin may be used, or two or more types may be used in combination.
The jelly strength of gelatin is the jelly strength measured by the measuring method specified in JIS K 6503 "Glue and industrial gelatin". Specifically, an aqueous gelatin solution having a concentration of 6.67% by mass is prepared, placed in a prescribed container and cooled in a constant temperature bath at 10° C. for 16 to 18 hours to obtain a sample. The jelly strength (unit: bloom or g) is defined as the load in grams required to push down the surface of the obtained sample by 4 mm with a plunger having a diameter of 1/2 inch (12.7 mm). The jelly strength of gelatin is preferably about 100 to 300 Bloom (100 to 300 g).
The gelation temperature of gelatin and the melting point of gelatin gel are not particularly limited. Generally, gelatin has a gelation temperature of about 15 to 20°C and a melting point of about 25 to 30°C.
When two or more types of gelatin are used in combination, it is preferable to select and use the gelatin so that the jelly strength, gelation temperature and melting point of each gelatin are within the above preferred ranges. Gelatin may be used in combination with agar and polysaccharide thickener.
増粘多糖類としては、例えばカラギナン、ローカストビーンガム、ジェランガム、キサンタンガム、タマリンドガム等が挙げられる。
カラギナンとしては、カッパ-カラギナン、イオタカラギナンが使用できる。
ジェランガムには、脱アシル型とネイティブ型がある。脱アシル型の方がより固まりやすい。
増粘多糖類としては特に限定されず、市販品から適宜選択して用いることができる。増粘多糖類は1種でもよく2種以上を併用してもよい。これらの中でも、カラギナン、ローカストビーンガム、ジェランガムが好ましく、ローカストビーンガムを用いる場合は、カラギナンを併用することが好ましい。なお、増粘多糖類は、寒天、ゼラチンと併用してもよい。
Examples of thickening polysaccharides include carrageenan, locust bean gum, gellan gum, xanthan gum, tamarind gum and the like.
As carrageenan, kappa-carrageenan and iota carrageenan can be used.
Gellan gum has a deacylated type and a native type. The deacylated form is more likely to set.
The thickening polysaccharide is not particularly limited, and can be appropriately selected from commercially available products and used. Polysaccharide thickeners may be used alone or in combination of two or more. Among these, carrageenan, locust bean gum, and gellan gum are preferred, and when locust bean gum is used, carrageenan is preferably used in combination. The polysaccharide thickener may be used in combination with agar and gelatin.
なお、エンドウ豆タンパク質の凝固性を高める観点から、ゲル化剤の種類に応じて、任意成分として一価のカチオンおよび二価のカチオンの少なくとも一方を併用してもよい。これらカチオンとしては、カルシウム、カリウム、マグネシウム等が挙げられる。以下に、ゲル化剤の好ましい態様の一例を示す。
(g1):ゲル化剤が寒天を含む。任意成分として前記カチオンは併用してもよいし、併用しなくてもよい。
(g2):ゲル化剤がゼラチンを含む。任意成分として前記カチオンは併用してもよいし、併用しなくてもよい。
(g3):ゲル化剤がカラギナンおよびローカストビーンガムを含む。任意成分として前記カチオンは併用してもよいし、併用しなくてもよい。
(g4):ゲル化剤がカラギナンを含み、任意成分として前記カチオンを併用する。
(g5):ゲル化剤がジェランガムを含み、任意成分として前記カチオンを併用する。
これらの中でも、(g1)~(g3)が特に好ましい。
From the viewpoint of enhancing the coagulability of the pea protein, at least one of monovalent cations and divalent cations may be used together as an optional component depending on the type of gelling agent. These cations include calcium, potassium, magnesium and the like. An example of preferred embodiments of the gelling agent is shown below.
(g1): The gelling agent contains agar. The above cations may be used together as optional components, or may not be used together.
(g2): The gelling agent contains gelatin. The above cations may be used together as optional components, or may not be used together.
(g3): The gelling agent contains carrageenan and locust bean gum. The above cations may be used together as optional components, or may not be used together.
(g4): The gelling agent contains carrageenan, and the cation is used as an optional component.
(g5): The gelling agent contains gellan gum, and the cation is used as an optional component.
Among these, (g1) to (g3) are particularly preferred.
ゲル状食品の総質量に対するゲル化剤の含有量は、0.01~10質量%が好ましく、0.02~8質量%がより好ましく、0.05~2質量%がさらに好ましい。ゲル化剤の含有量が上記下限値以上であれば、エンドウ豆タンパク質を充分に凝固できる。ゲル化剤の含有量が上記上限値以下であれば、固くなりすぎて食感が悪くなる、製造適性が悪くなる、ゲル化剤そのものの味が出てきてしまうといった不具合を抑制できる。 The content of the gelling agent is preferably 0.01 to 10% by mass, more preferably 0.02 to 8% by mass, and even more preferably 0.05 to 2% by mass with respect to the total mass of the gelled food. If the content of the gelling agent is at least the above lower limit, the pea protein can be sufficiently coagulated. If the content of the gelling agent is equal to or less than the above upper limit, it is possible to suppress problems such as excessive hardening resulting in poor texture, poor production aptitude, and appearance of the taste of the gelling agent itself.
ゲル化剤が寒天を含む場合、ゲル状食品の総質量に対する寒天の含有量は、0.2~2質量%が好ましく、0.3~1質量%がより好ましい。
エンドウ豆タンパク質と寒天との質量比(エンドウ豆タンパク質:寒天)は、20:1~1:20が好ましく、10:1~1:10がより好ましい。
When the gelling agent contains agar, the content of agar is preferably 0.2 to 2% by mass, more preferably 0.3 to 1% by mass, relative to the total mass of the gelled food.
The mass ratio of pea protein to agar (pea protein:agar) is preferably 20:1 to 1:20, more preferably 10:1 to 1:10.
ゲル化剤がゼラチンを含む場合、ゲル状食品の総質量に対するゼラチンの含有量は、0.4~10質量%が好ましく、0.6~5質量%がより好ましい。
エンドウ豆タンパク質とゼラチンとの質量比(エンドウ豆タンパク質:ゼラチン)は、7:1~1:100が好ましく、5:1~1:10がより好ましい。
When the gelling agent contains gelatin, the gelatin content is preferably 0.4 to 10% by mass, more preferably 0.6 to 5% by mass, relative to the total mass of the gelled food.
The mass ratio of pea protein and gelatin (pea protein:gelatin) is preferably 7:1 to 1:100, more preferably 5:1 to 1:10.
ゲル化剤がカラギナンおよびローカストビーンガムを含む場合、ゲル状食品の総質量に対するカラギナンおよびローカストビーンガムの含有量の合計は、0.1~1質量%が好ましく、0.2~0.8質量%がより好ましい。
エンドウ豆タンパク質とカラギナンおよびローカストビーンガムとの質量比(エンドウ豆タンパク質:カラギナン+ローカストビーンガム)は、40:1~1:10が好ましく、10:1~1:10がより好ましい。
カラギナンとローカストビーンガムとの質量比(カラギナン:ローカストビーンガム)は、10:1~1:10が好ましく、3:7~7:3がより好ましい。
When the gelling agent contains carrageenan and locust bean gum, the total content of carrageenan and locust bean gum relative to the total weight of the gelled food is preferably 0.1 to 1% by mass, and 0.2 to 0.8% by mass. % is more preferred.
The mass ratio of pea protein to carrageenan and locust bean gum (pea protein: carrageenan + locust bean gum) is preferably 40:1 to 1:10, more preferably 10:1 to 1:10.
The mass ratio of carrageenan to locust bean gum (carrageenan: locust bean gum) is preferably 10:1 to 1:10, more preferably 3:7 to 7:3.
ゲル化剤がカラギナンを含む場合、ゲル状食品の総質量に対するカラギナンの含有量は、0.1~1質量%が好ましく、0.2~0.8質量%がより好ましい。
エンドウ豆タンパク質とカラギナンとの質量比(エンドウ豆タンパク質:カラギナン)は、40:1~1:10が好ましく、10:1~1:10がより好ましい。
When the gelling agent contains carrageenan, the content of carrageenan is preferably 0.1 to 1% by mass, more preferably 0.2 to 0.8% by mass, relative to the total mass of the gelled food.
The mass ratio of pea protein to carrageenan (pea protein:carrageenan) is preferably 40:1 to 1:10, more preferably 10:1 to 1:10.
ゲル化剤がジェランガムを含む場合、ゲル状食品の総質量に対するジェランガムの含有量は、0.01~3質量%が好ましく、0.02~1.5質量%がより好ましい。
エンドウ豆タンパク質とジェランガムとの質量比(エンドウ豆タンパク質:ジェランガム)は、400:1~1:30が好ましく、100:1~1:10がより好ましい。
When the gelling agent contains gellan gum, the gellan gum content is preferably 0.01 to 3% by mass, more preferably 0.02 to 1.5% by mass, relative to the total mass of the gelled food.
The mass ratio of pea protein to gellan gum (pea protein:gellan gum) is preferably 400:1 to 1:30, more preferably 100:1 to 1:10.
(水)
ゲル状食品には、通常、水が含まれる。
水としては特に限定されず、水道水や脱イオン水等を用いることができる。
水の含有量は、例えばゲル状食品の総質量に対して、60~98質量%が好ましく、75~90質量%がより好ましい。
(water)
A gel-like food usually contains water.
Water is not particularly limited, and tap water, deionized water, or the like can be used.
The content of water is, for example, preferably 60 to 98% by mass, more preferably 75 to 90% by mass, relative to the total mass of the gel-like food.
(任意成分)
ゲル状食品には、上記の成分(エンドウ豆タンパク質、ゲル化剤および水)以外の任意成分を、必要に応じて、本発明の効果を損なわない範囲内で含有させることができる。
任意成分としては、食品に配合可能な各種成分を用いることができ、例えば一価のカチオンおよび二価のカチオンの少なくとも一方(例えば、カルシウム、カリウム、マグネシウム等)、卵成分、果実由来成分、糖類、植物油脂、呈味成分、増粘剤、保水剤、乳化剤、色素、pH調整剤、酸化防止剤、消泡剤等が挙げられ、製造しようとするゲル状食品の風味や食感、製造適性等を考慮して適宜選択できる。
(Optional component)
The gel-like food may contain optional ingredients other than the above-mentioned ingredients (pea protein, gelling agent and water), if necessary, within a range that does not impair the effects of the present invention.
As optional ingredients, various ingredients that can be blended in foods can be used, for example, at least one of monovalent cations and divalent cations (e.g., calcium, potassium, magnesium, etc.), egg ingredients, fruit-derived ingredients, sugars , vegetable oils and fats, taste components, thickeners, water retention agents, emulsifiers, pigments, pH adjusters, antioxidants, antifoaming agents, etc., and the flavor and texture of the gel food to be produced, production suitability etc., can be selected as appropriate.
前記カチオンは、カラギナン、ローカストビーンガム、ジェランガム等のゲル化剤と反応してゲルの形成を促進させる。ゲル化剤としてカラギナン、ローカストビーンガムまたはジェランガムを用いる場合は、一価のカチオンおよび二価のカチオンの少なくとも一方を併用することが好ましい。
例えばカルシウムは、カルシウムを含む原料(カルシウム原料)としてゲル状食品に配合できる。カルシウム原料の具体例としては、生乳、牛乳、部分脱脂乳、脱脂乳、濃縮乳、脱脂濃縮乳、全脂練乳、脱脂練乳、全脂粉乳、脱脂粉乳、乳清(ホエー)、乳清蛋白質濃縮物(WPC)、乳清蛋白質分離物(WPI)、全乳蛋白質濃縮物(TMP)等の乳類;チーズ、バター、クリーム、無糖れん乳、加糖れん乳、バターオイル、バターミルク、バターミルクパウダー等の乳類を原料とする乳製品;乳酸カルシウム、塩化カルシウム、炭酸カルシウム、硫酸カルシウム、リン酸カルシウム、クエン酸カルシウム、水酸化カルシウム、ステアリン酸カルシウム、ピロリン酸二水素カルシウム、硅酸カルシウム等のカルシウム塩などが挙げられる。
カリウムとしては、例えば塩化カリウム、リン酸1水素2カリウム、海藻エキス由来のもの等を使用できる。
前記カチオンの含有量は、ゲル状食品の総質量に対して、0.001~0.5質量%が好ましく、0.005~0.3質量%がより好ましい。
The cations react with gelling agents such as carrageenan, locust bean gum and gellan gum to promote gel formation. When using carrageenan, locust bean gum or gellan gum as a gelling agent, it is preferable to use at least one of monovalent cations and divalent cations together.
For example, calcium can be blended into a gel-like food as a raw material containing calcium (calcium raw material). Specific examples of calcium raw materials include raw milk, cow milk, partially skimmed milk, skim milk, concentrated milk, skimmed concentrated milk, whole condensed milk, condensed skim milk, whole milk powder, skim milk powder, whey, and whey protein concentrate. (WPC), whey protein isolate (WPI), whole milk protein concentrate (TMP); cheese, butter, cream, unsweetened condensed milk, sweetened condensed milk, butter oil, buttermilk, buttermilk Dairy products made from milk such as powder; calcium salts such as calcium lactate, calcium chloride, calcium carbonate, calcium sulfate, calcium phosphate, calcium citrate, calcium hydroxide, calcium stearate, calcium dihydrogen pyrophosphate, and calcium silicate etc.
Examples of potassium that can be used include potassium chloride, dipotassium monohydrogen phosphate, and those derived from seaweed extracts.
The content of the cation is preferably 0.001 to 0.5% by mass, more preferably 0.005 to 0.3% by mass, relative to the total mass of the gel-like food.
卵成分は、卵黄のみでもよく、全卵でもよい。例えば液卵や粉末など適宜の性状に加工された原料を用いてもよい。
果実由来成分としては、例えばフルーツピューレ、果汁、果実等が挙げられる。
糖類としては、例えば砂糖、蜂蜜、メープルシロップ、水飴、ブドウ糖、果糖、転化糖、異性化糖、黒糖等が挙げられる。
呈味成分としては、例えば糖類以外の甘味料、酸味料、調味料、香料、チョコレート、ココアパウダー、酒類、抹茶、小豆あん、練りゴマ、キャラメル、果汁、ナッツ、いも、栗、かぼちゃ等が挙げられる。
糖類以外の甘味料としては、例えば糖アルコール類(キシリトール、ソルビトール、マルチロール、エリスリトール等)、高甘味度甘味料(サッカリンナトリウム、サイクラメート及びその塩、アセスルファムカリウム、ソーマチン、アスパルテーム、スクラロース、アリテーム、ネオテーム、ステビア抽出物に含まれるステビオサイド等)等が挙げられる。
酸味料としては、例えばリンゴ酸、クエン酸、酒石酸等が挙げられる。
調味料としては、例えばクエン酸ナトリウム等が挙げられる。
増粘剤としては、例えば加工澱粉等が挙げられる。
保水剤としては、例えばセルロース、デキストリン、こんにゃく粉等が挙げられる。
乳化剤としては、一般に食用に用いられている乳化剤を適宜用いることができ、例えば有機酸モノグリセリド、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル等が挙げられる。
色素としては、例えばカロチン、リコピン等が利用できる。
The egg component may be egg yolk only or whole egg. For example, raw materials processed into appropriate properties such as liquid eggs and powders may be used.
Fruit-derived components include, for example, fruit purees, fruit juices, and fruits.
Examples of sugars include sugar, honey, maple syrup, starch syrup, glucose, fructose, invert sugar, isomerized sugar, and brown sugar.
Examples of taste components include sweeteners other than sugars, acidulants, seasonings, flavors, chocolate, cocoa powder, alcoholic beverages, matcha green tea, red bean paste, sesame paste, caramel, fruit juice, nuts, potatoes, chestnuts, pumpkins, and the like. be done.
Examples of sweeteners other than sugars include sugar alcohols (xylitol, sorbitol, maltitol, erythritol, etc.), high-intensity sweeteners (saccharin sodium, cyclamate and its salts, acesulfame potassium, thaumatin, aspartame, sucralose, alitame, neotame, etc.). , stevioside contained in stevia extract, etc.).
Acidulants include, for example, malic acid, citric acid, and tartaric acid.
Seasonings include, for example, sodium citrate.
Examples of thickeners include modified starch and the like.
Examples of water retention agents include cellulose, dextrin, and konjac powder.
As the emulsifier, an emulsifier generally used for food can be appropriately used, and examples thereof include organic acid monoglycerides, glycerin fatty acid esters, polyglycerin fatty acid esters, sucrose fatty acid esters, and the like.
Carotene, lycopene, and the like, for example, can be used as pigments.
(製造方法)
ゲル状食品は、前記エンドウ豆タンパク質と、前記ゲル化剤とを含む混合液をゲル化させ、ゲル状食品を得る工程を有する方法で製造できる。
ゲル化剤としては、寒天、ゼラチン、および増粘多糖類からなる群より選ばれる1種以上が好ましく、当該増粘多糖類としては、カラギナン、ローカストビーンガム、及びジェランガムからなる群から選択されるいずれかが好ましい。なお、ローカストビーンガムを使用する場合はカラギナンを併用することが好ましい。ゲル化剤の好ましい態様としては、前記(g1)~(g5)が挙げられる。
(Production method)
The gelled food can be produced by a method comprising the step of gelling a mixture containing the pea protein and the gelling agent to obtain a gelled food.
The gelling agent is preferably one or more selected from the group consisting of agar, gelatin, and polysaccharide thickeners, and the polysaccharide thickener is selected from the group consisting of carrageenan, locust bean gum, and gellan gum. Either is preferred. In addition, when locust bean gum is used, it is preferable to use carrageenan together. Preferred embodiments of the gelling agent include the above (g1) to (g5).
混合液は、エンドウ豆タンパク質と、ゲル化剤と、水とを含む。
混合液の総質量に対するエンドウ豆タンパク質の含有量は、0.1~4質量%が好ましく、0.5~3質量%がより好ましい。
混合液の総質量に対するゲル化剤の含有量は、0.01~10質量%が好ましく、0.02~8質量%がより好ましく、0.05~2質量%がさらに好ましい。
混合液の総質量に対する水の含有量は、60~98質量%が好ましく、75~90質量%がより好ましい。
The mixture includes pea protein, a gelling agent, and water.
The pea protein content relative to the total mass of the mixture is preferably 0.1 to 4% by mass, more preferably 0.5 to 3% by mass.
The content of the gelling agent is preferably 0.01 to 10% by mass, more preferably 0.02 to 8% by mass, even more preferably 0.05 to 2% by mass, relative to the total mass of the mixture.
The water content relative to the total mass of the mixture is preferably 60 to 98% by mass, more preferably 75 to 90% by mass.
なお、ゲル化剤が寒天を含む場合、混合液の総質量に対する寒天の含有量は、0.2~2質量%が好ましく、0.3~1質量%がより好ましい。
ゲル化剤がゼラチンを含む場合、混合液の総質量に対するゼラチンの含有量は、0.4~10質量%が好ましく、0.6~5質量%がより好ましい。
ゲル化剤がカラギナンおよびローカストビーンガムを含む場合、混合液の総質量に対するカラギナンおよびローカストビーンガムの含有量の合計は、0.1~1質量%が好ましく、0.2~0.8質量%がより好ましい。
ゲル化剤がカラギナンを含む場合、混合液の総質量に対するカラギナンの含有量は、0.1~1質量%が好ましく、0.2~0.8質量%がより好ましい。
ゲル化剤がジェランガムを含む場合、混合液の総質量に対するジェランガムの含有量は、0.01~3質量%が好ましく、0.02~1.5質量%がより好ましい。
エンドウ豆タンパク質と各種ゲル化剤との質量比の好ましい範囲は、上述した通りである。
When the gelling agent contains agar, the content of agar is preferably 0.2 to 2% by mass, more preferably 0.3 to 1% by mass, relative to the total mass of the mixture.
When the gelling agent contains gelatin, the gelatin content is preferably 0.4 to 10% by mass, more preferably 0.6 to 5% by mass, relative to the total mass of the mixture.
When the gelling agent contains carrageenan and locust bean gum, the total content of carrageenan and locust bean gum relative to the total weight of the mixture is preferably 0.1 to 1% by mass, and 0.2 to 0.8% by mass. is more preferred.
When the gelling agent contains carrageenan, the content of carrageenan is preferably 0.1 to 1% by mass, more preferably 0.2 to 0.8% by mass, relative to the total mass of the mixture.
When the gelling agent contains gellan gum, the gellan gum content is preferably 0.01 to 3% by mass, more preferably 0.02 to 1.5% by mass, relative to the total mass of the mixture.
A preferred range of the mass ratio of pea protein and various gelling agents is as described above.
混合液は、必要に応じて任意成分を含んでいてもよい。任意成分としては、ゲル状食品の説明において先に例示した任意成分が挙げられる。
例えば、混合液が前記カチオンを含む場合、混合液の総質量に対する前記カチオンの含有量は、0.001~0.5質量%が好ましく、0.005~0.3質量%がより好ましい。
The mixed liquid may contain optional components as necessary. Optional components include the optional components exemplified above in the description of the gel-like food.
For example, when the mixture contains the cation, the content of the cation is preferably 0.001 to 0.5% by mass, more preferably 0.005 to 0.3% by mass, relative to the total mass of the mixture.
混合液は、エンドウ豆タンパク質と、ゲル化剤と、水(溶解水)と、必要に応じて任意成分とを混合することで得られる。
具体的には、まず水に全原料を投入して撹拌して混合する。撹拌混合しただけでは全成分を溶解できない場合は、加熱処理して全成分を溶解すればよい。水の温度は特に限定されない。例えば常温(20~30℃、以下同様。)の溶解水に全原料を投入した後、殺菌処理を兼ねて加熱処理して原料を溶解させ、混合液とすることが好ましい。
加熱処理温度は80℃以上が好ましい。該加熱処理温度の上限はないが、風味の観点から例えば160℃以下が好ましく、150℃以下がより好ましい。
加熱時間は、混合液中の原料を溶解させることができ、殺菌効果が得られ、かつ混合液中の成分が熱変性を生じない時間に設定することが好ましい。
A mixed solution is obtained by mixing pea protein, a gelling agent, water (dissolution water), and optionally optional ingredients.
Specifically, first, all raw materials are put into water and mixed by stirring. If all the components cannot be dissolved only by stirring and mixing, all the components may be dissolved by heat treatment. The temperature of water is not particularly limited. For example, it is preferable to put all the raw materials into dissolution water at normal temperature (20 to 30° C., hereinafter the same), and then heat-treat the raw materials together with sterilization to dissolve the raw materials to obtain a mixed solution.
The heat treatment temperature is preferably 80° C. or higher. Although there is no upper limit for the heat treatment temperature, it is preferably 160° C. or lower, more preferably 150° C. or lower, from the viewpoint of flavor.
The heating time is preferably set to a time during which the raw materials in the mixed liquid can be dissolved, the sterilization effect is obtained, and the components in the mixed liquid are not thermally denatured.
混合液の加熱処理の前または後に、必要に応じて混合液を均質化することが好ましい。混合液に油脂分が含まれている場合、均質化を行うことで油脂の乳化を促進させることができる。
均質化は10~30MPa程度の圧力下で行われることが好ましい。
Before or after the heat treatment of the mixed liquid, it is preferable to homogenize the mixed liquid as necessary. When fats and oils are contained in the mixture, homogenization can promote emulsification of the fats and oils.
Homogenization is preferably performed under a pressure of about 10 to 30 MPa.
なお、エンドウ豆タンパク質を水に予め分散させて分散液を調製しておき、該分散液とゲル化剤と必要に応じて任意成分とを混合してもよい。また、ゲル化剤等と混合する前に、必要に応じて分散液を均質化しておいてもよい。 A dispersion may be prepared by previously dispersing the pea protein in water, and the dispersion may be mixed with the gelling agent and, if necessary, optional components. Moreover, before mixing with a gelling agent or the like, the dispersion may be homogenized, if necessary.
混合液をゲル化させる方法としては特に制限されず、常温で混合液を放置する方法でもよいし、ゲル化剤のゲル化温度以下に混合液を冷却する方法でもよい。短時間でゲル状食品が得られる観点から、ゲル化温度以下に混合液を冷却して混合液をゲル化させることが好ましい。混合液をゲル化させる前に、必要に応じて混合液を容器等に充填してもよい。
混合液の容器等への充填は、例えば充填機のノズルから吐出する方法で行うことができる。
冷却温度は10℃以下が好ましい。冷却温度の下限値は凍結防止の点から1℃以上が好ましい。冷却時間は、充分にゲル化したゲル状物が得られればよく、例えば10時間以上、好ましくは20時間以上、さらに好ましくは24時間以上である。
The method for gelling the mixed solution is not particularly limited, and may be a method of leaving the mixed solution at normal temperature, or a method of cooling the mixed solution to a temperature not higher than the gelling temperature of the gelling agent. From the viewpoint of obtaining a gelled food in a short period of time, it is preferable to gel the mixed liquid by cooling the mixed liquid to a temperature equal to or lower than the gelling temperature. Before gelling the mixed liquid, the mixed liquid may be filled in a container or the like, if necessary.
Filling of the mixed liquid into a container or the like can be performed by, for example, a method of discharging from a nozzle of a filling machine.
The cooling temperature is preferably 10°C or less. The lower limit of the cooling temperature is preferably 1°C or higher from the viewpoint of anti-freezing. The cooling time is sufficient as long as a sufficiently gelled gel can be obtained, and is, for example, 10 hours or longer, preferably 20 hours or longer, and more preferably 24 hours or longer.
なお、ゲル化の前後において、混合液中の各成分の質量(含有量)は殆ど変化しない。すなわち、混合液中の各成分の含有量と、該混合液をゲル化して得られるゲル状食品中の各成分の含有量は、概ね一致する。 Before and after gelling, the mass (content) of each component in the mixed solution hardly changes. That is, the content of each component in the mixed liquid and the content of each component in the gel-like food obtained by gelling the mixed liquid are generally the same.
(効果)
以上説明した本発明のゲル状食品は、エンドウ豆タンパク質と特定のゲル化剤とを含むので、寒天やゼラチン等を使った場合には乳タンパク質や大豆タンパク質を用いたゲル状食品に比べて硬度が高い。しかも、本発明のゲル状食品は、エンドウ豆タンパク質という、従来のゲル状食品に含まれる乳タンパク質や大豆タンパク質に代わる新たなタンパク質を含んだものであり、しかもアレルゲンが低減されている。
ところで、ゲル状食品の硬度を高めるには、ゲル化剤の含有量を増やせばよい。しかし、ゲル化剤の増量はゲル状食品の風味の低下や、コスト高の原因となる。
本発明のゲル状食品であれば、ゲル化剤の含有量を過度に増やすことなく、高い硬度を発現できるので、良好な風味を維持しつつ、製造コストを抑えることができる。
また、本発明のゲル状食品の製造方法によれば、硬度の高いゲル状食品を、良好な風味を維持しつつ、低コストで容易に製造できる。
(effect)
The gel-like food of the present invention described above contains pea protein and a specific gelling agent. is high. Moreover, the gel-like food of the present invention contains pea protein, a new protein that replaces the milk protein and soybean protein contained in conventional gel-like foods, and has reduced allergens.
By the way, in order to increase the hardness of the gelled food, the content of the gelling agent should be increased. However, increasing the amount of the gelling agent causes deterioration of the flavor of the gelled food and high cost.
With the gel-like food of the present invention, high hardness can be expressed without excessively increasing the content of the gelling agent, so production costs can be reduced while maintaining good flavor.
Moreover, according to the method for producing a gel-like food of the present invention, a gel-like food with high hardness can be easily produced at low cost while maintaining good flavor.
(用途)
本発明のゲル状食品の具体的な製品としては、プリン、ゼリー、茶わん蒸し、ゴマ豆腐、卵豆腐、水羊羹、煮こごり、アスピックゼリー、トコロテン等が挙げられる。
(Application)
Specific products of the gel-like food of the present invention include pudding, jelly, chawanmushi, sesame tofu, egg tofu, mizu-yokan, nikogori, aspic jelly, and tokoroten.
以下に実施例を用いて本発明をさらに詳しく説明するが、本発明はこれら実施例に限定されるものではない。 EXAMPLES The present invention will be described in more detail below using examples, but the present invention is not limited to these examples.
<使用原料>
・植物油脂(やし油、パーム油を含む):太陽油脂社製。
・甜菜糖:ホクレン農業協同組合連合会製、商品名「HBSビートグラニュ糖」。
・加工澱粉:松谷化学工業社製。
・チョコレート:森永製菓社製、商品名「クレオール」。
・ココアパウダー:森永製菓社製、商品名「ローヤルNPCココア」。
・エンドウ豆タンパク質:オルガノフードテック社製、商品名「PP-CS」、タンパク質含有量75質量%。
・乳タンパク質:MILEI GMBH社製、商品名「MILEI TMP」、タンパク質含有量76質量%。
・大豆タンパク質:ダニスコジャパン社製、商品名「SUPRO XT55IP」、タンパク質含有量87質量%。
・乳化剤:花王社製、商品名「ステップSS」、コハク酸モノグリセリド。
・寒天:伊那寒天社製、商品名「ウルトラ寒天AX-100」、日寒水式によるゼリー強度(1.5%濃度)100g/cm2、凝固点45℃、ゲルの融点85℃。
・ゼラチン:ルスロ社製 「Rousselot 250PS」、JIS K 6503によるゼリー強度250ブルーム(250g)、ゲル化温度20℃、ゲルの融点25℃。
・カラギナン:三栄源エフ・エフ・アイ社製、商品名「カラギニンCSK-1」。
・ローカストビーンガム:三栄源エフ・エフ・アイ社製、商品名「ビストップD/2050」。
・ネイティブ型ジェランガム:CPケルコ社製、商品名「ケルコゲルHM」。
<Raw materials used>
・Vegetable oil (including coconut oil and palm oil): manufactured by Taiyo Yushi Co., Ltd.
- Beet sugar: Hokuren Federation of Agricultural Cooperatives, trade name "HBS Beet Granulated Sugar".
・Modified starch: manufactured by Matsutani Chemical Industry Co., Ltd.
・Chocolate: Morinaga Confectionery Co., Ltd., trade name “Creole”.
- Cocoa powder: manufactured by Morinaga & Co., Ltd., trade name "Royal NPC Cocoa".
- Peas protein: manufactured by Organo Foodtech, trade name "PP-CS", protein content 75% by mass.
- Milk protein: manufactured by MILEI GMBH, trade name "MILEI TMP", protein content 76% by mass.
- Soybean protein: manufactured by Danisco Japan Co., Ltd., trade name "SUPRO XT55IP", protein content 87% by mass.
- Emulsifier: Kao Corporation, trade name "Step SS", succinic acid monoglyceride.
- Agar: trade name "Ultra Agar AX-100" manufactured by Ina Kanten Co., Ltd., jelly strength (1.5% concentration) 100 g/cm 2 by Nikkan water formula, freezing point 45°C, gel melting point 85°C.
Gelatin: "Rousselot 250PS" manufactured by Rousselot, jelly strength 250 bloom (250 g) according to JIS K 6503, gelation temperature 20°C, gel melting point 25°C.
- Carrageenan: manufactured by San-Eigen FFI Co., Ltd., trade name "Carrageenin CSK-1".
- Locust bean gum: manufactured by San-Ei Gen FFI Co., Ltd., trade name "Bistop D/2050".
-Native type gellan gum: trade name "Kelcogel HM" manufactured by CP Kelco.
なお、エンドウ豆タンパク質について、前記破断試験において硬度と破断点を測定したときに破断しないことが確認された。 It was confirmed that the pea protein did not break when the hardness and breaking point were measured in the breaking test.
実施例1、2及び4は参考例である。
<実施例1>
表1に示す配合で各原料を混合し、85℃で10分間加熱処理した後、均質機(三丸機械工業社製、製品名「Homogenizer」)を用いて15MPaの圧力で均質化し、混合液を得た。得られた混合液65gをプラスチック容器に充填し、冷蔵庫にて10℃で10時間静置冷却してゲル化させることにより、ゲル状食品を得た。プラスチック容器としては、ポリプロピレンを用いて円錐型に射出成型した容器(シンギ社製、商品名「PP71-110」、容量110ml)を用いた。
得られたゲル状食品について、以下に示す方法により硬度を測定した。結果を表1に示す。
Examples 1, 2 and 4 are reference examples.
<Example 1>
Each raw material was mixed according to the formulation shown in Table 1, heat-treated at 85 ° C. for 10 minutes, and then homogenized at a pressure of 15 MPa using a homogenizer (manufactured by Sanmaru Kikai Kogyo Co., Ltd., product name “Homogenizer”) to obtain a mixed solution. got A plastic container was filled with 65 g of the obtained mixed liquid, and the gel-like food was obtained by standing and cooling at 10° C. for 10 hours in a refrigerator for gelation. As the plastic container, a cone-shaped injection-molded polypropylene container (manufactured by Shingi Co., Ltd., trade name “PP71-110”, capacity 110 ml) was used.
The hardness of the obtained gel-like food was measured by the method described below. Table 1 shows the results.
(硬度の測定)
レオメーター(サン科学社製、製品名「SUN RHEO METER COMPACK-100II」)を用い、治具として直径20mmの円形プランジャー(D20)を陥入速度80mm/min、HOLD6g、測定温度10℃の条件でゲル状食品に陥入させたときのゲル状食品の破断強度(g)を測定した。
測定は1種類のゲル状食品につき3回の測定を行い、3回の破断強度の平均値をそのゲル状食品の硬度とした。
(Measurement of hardness)
Using a rheometer (manufactured by Sun Kagaku Co., Ltd., product name "SUN RHEO METER COMPACK-100II"), a circular plunger (D20) with a diameter of 20 mm was used as a jig at an invagination rate of 80 mm/min, a hold of 6 g, and a measurement temperature of 10°C. The breaking strength (g) of the gel-like food was measured when it was invaginated in the gel-like food.
The measurement was performed three times for one type of gel-like food, and the average value of the breaking strengths of the three times was taken as the hardness of the gel-like food.
<実施例2、3>
表1に示す配合組成となるように混合液を調製した以外は、実施例1と同様にしてゲル状食品を製造し、硬度を測定した。結果を表1に示す。
なお、実施例3では、硬度の測定において、治具として直径10mmの円形プランジャー(D10)を用いた。
<Examples 2 and 3>
A gel-like food was produced in the same manner as in Example 1, except that the mixed liquid was prepared so as to have the composition shown in Table 1, and the hardness was measured. Table 1 shows the results.
In addition, in Example 3, a circular plunger (D10) with a diameter of 10 mm was used as a jig in measuring the hardness.
<比較例1~6>
表2、3に示す配合組成となるように混合液を調製した以外は、実施例1と同様にしてゲル状食品を製造し、硬度を測定した。結果を表2、3に示す。
なお、比較例3、6では、硬度の測定において、治具として直径10mmの円形プランジャー(D10)を用いた。
<Comparative Examples 1 to 6>
A gel-like food was produced in the same manner as in Example 1, except that the mixed liquid was prepared so as to have the formulation shown in Tables 2 and 3, and the hardness was measured. Tables 2 and 3 show the results.
In Comparative Examples 3 and 6, a circular plunger (D10) with a diameter of 10 mm was used as a jig in measuring hardness.
表1~3の結果に示されるように、実施例1~3で得られたゲル状食品は、比較例1~6で得られたゲル状食品に比べて硬度が高かった。 As shown in the results of Tables 1-3, the gel-like foods obtained in Examples 1-3 had higher hardness than the gel-like foods obtained in Comparative Examples 1-6.
<実施例4>
表4に示す配合組成となるように混合液を調製した以外は、実施例1と同様にしてゲル状食品を製造し、硬度を測定した。結果を表4に示す。
また、得られたゲル状食品について、以下に示す方法により風味を評価した。結果を表4に示す。
<Example 4>
A gel-like food was produced in the same manner as in Example 1 except that the mixed liquid was prepared so as to have the composition shown in Table 4, and the hardness was measured. Table 4 shows the results.
In addition, the flavor of the obtained gel-like food was evaluated by the method described below. Table 4 shows the results.
(風味の評価)
ゲル状食品を品温10℃に温度調整し、専門パネラー9名が試食し、風味について下記の評価基準で評価した。9名の平均値を評価結果とする。平均値が高いほど風味の評価が高いことを意味する。
<<評価基準>>
5点:豆感を感じない。
4点:豆感をやや感じる。
3点:豆感を感じる。
2点:豆感を強く感じる。
1点:豆感を非常に強く感じる。
(Evaluation of flavor)
The temperature of the gel-like food was adjusted to 10° C., and tasted by 9 expert panelists, and the flavor was evaluated according to the following evaluation criteria. Let the average value of 9 persons be an evaluation result. A higher average value means a higher flavor evaluation.
<<Evaluation Criteria>>
5 points: Bean feeling is not felt.
4 points: A bean feeling is sensed a little.
3 points: Feels like beans.
2 points: A strong bean feeling is sensed.
1 point: Very strong bean feeling.
<比較例7>
表4に示す配合組成となるように混合液を調製した以外は、実施例1と同様にしてゲル状食品を製造し、硬度を測定した。結果を表4に示す。
また、得られたゲル状食品について、実施例4と同様にして風味を評価した。結果を表4に示す。
<Comparative Example 7>
A gel-like food was produced in the same manner as in Example 1 except that the mixed liquid was prepared so as to have the composition shown in Table 4, and the hardness was measured. Table 4 shows the results.
In addition, the flavor of the obtained gel-like food was evaluated in the same manner as in Example 4. Table 4 shows the results.
表4の結果に示されるように、実施例4で得られたゲル状食品は、比較例7で得られたゲル状食品に比べて硬度が高く、風味も良好であった。 As shown in the results of Table 4, the gel-like food obtained in Example 4 had higher hardness than the gel-like food obtained in Comparative Example 7, and had a good flavor.
Claims (10)
前記ゲル化剤が、カラギナン及びローカストビーンガムからなり、
前記ゲル状食品の総質量に対して、水の含有量が75~98質量%である、ゲル状食品。 A gel-like food comprising pea protein and a gelling agent,
The gelling agent consists of carrageenan and locust bean gum,
A gel-like food having a water content of 75 to 98% by mass with respect to the total mass of the gel-like food.
前記ゲル化剤が、カラギナン及びローカストビーンガムからなり、
前記エンドウ豆タンパク質の含有量が、前記ゲル状食品の総質量に対して0.1~4質量%である、ゲル状食品。 A gel-like food comprising pea protein and a gelling agent,
The gelling agent consists of carrageenan and locust bean gum,
A gel-like food, wherein the pea protein content is 0.1 to 4% by mass relative to the total mass of the gel-like food.
前記ゲル化剤が、カラギナン及びローカストビーンガムからなり、
前記水の含有量が、前記混合液の総質量に対して75~98質量%である、ゲル状食品の製造方法。 A method for obtaining a gel-like food by gelling a mixture containing pea protein, a gelling agent, and water, comprising:
The gelling agent consists of carrageenan and locust bean gum,
A method for producing a gel-like food, wherein the water content is 75 to 98% by mass with respect to the total mass of the mixed liquid.
前記ゲル化剤が、カラギナン及びローカストビーンガムからなり、
前記エンドウ豆タンパク質の含有量が、前記混合液の総質量に対して0.1~4質量%である、ゲル状食品の製造方法。 A method for obtaining a gel-like food by gelling a mixture containing pea protein, a gelling agent, and water, comprising:
The gelling agent consists of carrageenan and locust bean gum,
A method for producing a gel-like food, wherein the content of the pea protein is 0.1 to 4% by mass with respect to the total mass of the mixed liquid.
請求項6~8のいずれか一項に記載のゲル状食品の製造方法。 The content of the gelling agent is 0.1 to 1% by mass with respect to the total mass of the mixture,
A method for producing a gel-like food according to any one of claims 6 to 8.
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