JP2022132229A - 含フッ素共重合体 - Google Patents
含フッ素共重合体 Download PDFInfo
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- JP2022132229A JP2022132229A JP2022029719A JP2022029719A JP2022132229A JP 2022132229 A JP2022132229 A JP 2022132229A JP 2022029719 A JP2022029719 A JP 2022029719A JP 2022029719 A JP2022029719 A JP 2022029719A JP 2022132229 A JP2022132229 A JP 2022132229A
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- Japan
- Prior art keywords
- fluorine
- containing copolymer
- units
- polymerization
- present disclosure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 122
- 239000011737 fluorine Substances 0.000 title claims abstract description 117
- 229920001577 copolymer Polymers 0.000 title claims abstract description 112
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 109
- 239000000178 monomer Substances 0.000 claims abstract description 36
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 35
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims abstract description 34
- 125000001153 fluoro group Chemical group F* 0.000 claims abstract description 17
- 239000000155 melt Substances 0.000 claims abstract description 11
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 17
- 239000011247 coating layer Substances 0.000 claims description 17
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical group FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 claims description 16
- 238000012546 transfer Methods 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 238000000034 method Methods 0.000 abstract description 47
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 46
- -1 fluorine ions Chemical class 0.000 abstract description 34
- 238000001125 extrusion Methods 0.000 abstract description 26
- 239000001569 carbon dioxide Substances 0.000 abstract description 23
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 23
- 230000035699 permeability Effects 0.000 abstract description 19
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 17
- 239000000126 substance Substances 0.000 abstract description 13
- 239000007788 liquid Substances 0.000 abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 57
- 238000006116 polymerization reaction Methods 0.000 description 54
- 239000008188 pellet Substances 0.000 description 48
- 239000007789 gas Substances 0.000 description 43
- 238000012360 testing method Methods 0.000 description 34
- 125000000524 functional group Chemical group 0.000 description 32
- 239000010408 film Substances 0.000 description 31
- 239000010410 layer Substances 0.000 description 27
- 238000000465 moulding Methods 0.000 description 26
- 150000002978 peroxides Chemical class 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 239000000843 powder Substances 0.000 description 21
- 239000000463 material Substances 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 17
- 239000000523 sample Substances 0.000 description 16
- 239000011162 core material Substances 0.000 description 14
- 238000003682 fluorination reaction Methods 0.000 description 14
- 230000000977 initiatory effect Effects 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000005299 abrasion Methods 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000002844 melting Methods 0.000 description 12
- 230000008018 melting Effects 0.000 description 12
- 239000011255 nonaqueous electrolyte Substances 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 238000010521 absorption reaction Methods 0.000 description 11
- 239000000446 fuel Substances 0.000 description 11
- 238000012856 packing Methods 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 10
- 239000003505 polymerization initiator Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 9
- 230000000704 physical effect Effects 0.000 description 9
- 239000004020 conductor Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000007870 radical polymerization initiator Substances 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 235000013305 food Nutrition 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 238000007789 sealing Methods 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 238000000862 absorption spectrum Methods 0.000 description 6
- 125000002252 acyl group Chemical group 0.000 description 6
- 239000012986 chain transfer agent Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000003566 sealing material Substances 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 5
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 5
- 238000005481 NMR spectroscopy Methods 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- QOSATHPSBFQAML-UHFFFAOYSA-N hydrogen peroxide;hydrate Chemical compound O.OO QOSATHPSBFQAML-UHFFFAOYSA-N 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 230000008054 signal transmission Effects 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 230000008033 biological extinction Effects 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- 238000012937 correction Methods 0.000 description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 4
- 229920002313 fluoropolymer Polymers 0.000 description 4
- 239000004811 fluoropolymer Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229910052740 iodine Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- 238000001721 transfer moulding Methods 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000000748 compression moulding Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000010828 elution Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000012778 molding material Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- YSYRISKCBOPJRG-UHFFFAOYSA-N 4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole Chemical compound FC1=C(F)OC(C(F)(F)F)(C(F)(F)F)O1 YSYRISKCBOPJRG-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 125000005587 carbonate group Chemical group 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000006258 conductive agent Substances 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005796 dehydrofluorination reaction Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 235000019439 ethyl acetate Nutrition 0.000 description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000012785 packaging film Substances 0.000 description 2
- 229920006280 packaging film Polymers 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 150000004978 peroxycarbonates Chemical class 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- YPVDWEHVCUBACK-UHFFFAOYSA-N propoxycarbonyloxy propyl carbonate Chemical compound CCCOC(=O)OOC(=O)OCCC YPVDWEHVCUBACK-UHFFFAOYSA-N 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- UJZCJVSSNLSCSR-UHFFFAOYSA-N (15,16,16,17,17,18,18,19,19,20,20-undecachloro-2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,22,22,22-triacontafluorodocosanoyl) 15,16,16,17,17,18,18,19,19,20,20-undecachloro-2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14 Chemical compound FC(F)(F)CC(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)C(F)(Cl)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(=O)OOC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(Cl)C(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)C(Cl)(Cl)CC(F)(F)F UJZCJVSSNLSCSR-UHFFFAOYSA-N 0.000 description 1
- HBGQVKNZGOFLRH-UHFFFAOYSA-N (3,3-dichloro-2,2,4,4,4-pentafluorobutanoyl) 3,3-dichloro-2,2,4,4,4-pentafluorobutaneperoxoate Chemical compound FC(F)(F)C(Cl)(Cl)C(F)(F)C(=O)OOC(=O)C(F)(F)C(Cl)(Cl)C(F)(F)F HBGQVKNZGOFLRH-UHFFFAOYSA-N 0.000 description 1
- QFKDUYDESCLRNT-UHFFFAOYSA-N (4,5,5-trichloro-2,2,3,3,4,6,6,6-octafluorohexanoyl) 4,5,5-trichloro-2,2,3,3,4,6,6,6-octafluorohexaneperoxoate Chemical compound FC(F)(F)C(Cl)(Cl)C(F)(Cl)C(F)(F)C(F)(F)C(=O)OOC(=O)C(F)(F)C(F)(F)C(F)(Cl)C(Cl)(Cl)C(F)(F)F QFKDUYDESCLRNT-UHFFFAOYSA-N 0.000 description 1
- HLTAACNVRUAPLX-UHFFFAOYSA-N (6,6,7,7-tetrachloro-2,2,3,3,4,4,5,5,8,8,8-undecafluorooctanoyl) 6,6,7,7-tetrachloro-2,2,3,3,4,4,5,5,8,8,8-undecafluorooctaneperoxoate Chemical compound FC(F)(F)C(Cl)(Cl)C(Cl)(Cl)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(=O)OOC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(Cl)(Cl)C(Cl)(Cl)C(F)(F)F HLTAACNVRUAPLX-UHFFFAOYSA-N 0.000 description 1
- IDSJUBXWDMSMAR-UHFFFAOYSA-N (7,8,8,9,9-pentachloro-2,2,3,3,4,4,5,5,6,6,7,10,10,10-tetradecafluorodecanoyl) 7,8,8,9,9-pentachloro-2,2,3,3,4,4,5,5,6,6,7,10,10,10-tetradecafluorodecaneperoxoate Chemical compound FC(F)(F)C(Cl)(Cl)C(Cl)(Cl)C(F)(Cl)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(=O)OOC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(Cl)C(Cl)(Cl)C(Cl)(Cl)C(F)(F)F IDSJUBXWDMSMAR-UHFFFAOYSA-N 0.000 description 1
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 1
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 1
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- AYMDJPGTQFHDSA-UHFFFAOYSA-N 1-(2-ethenoxyethoxy)-2-ethoxyethane Chemical compound CCOCCOCCOC=C AYMDJPGTQFHDSA-UHFFFAOYSA-N 0.000 description 1
- LNTDXONIQLFHFG-UHFFFAOYSA-N 1-ethenoxy-2-methylpropan-1-ol Chemical compound CC(C)C(O)OC=C LNTDXONIQLFHFG-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- FLFWDKGWSOCXQK-UHFFFAOYSA-N 1-ethenoxycyclohexan-1-ol Chemical compound C=COC1(O)CCCCC1 FLFWDKGWSOCXQK-UHFFFAOYSA-N 0.000 description 1
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 1
- GBOWGKOVMBDPJF-UHFFFAOYSA-N 1-fluoro-3-(trifluoromethyl)benzene Chemical compound FC1=CC=CC(C(F)(F)F)=C1 GBOWGKOVMBDPJF-UHFFFAOYSA-N 0.000 description 1
- IBTLFDCPAJLATQ-UHFFFAOYSA-N 1-prop-2-enoxybutane Chemical compound CCCCOCC=C IBTLFDCPAJLATQ-UHFFFAOYSA-N 0.000 description 1
- LWJHSQQHGRQCKO-UHFFFAOYSA-N 1-prop-2-enoxypropane Chemical compound CCCOCC=C LWJHSQQHGRQCKO-UHFFFAOYSA-N 0.000 description 1
- JUTIIYKOQPDNEV-UHFFFAOYSA-N 2,2,3,3,4,4,4-heptafluorobutanoyl 2,2,3,3,4,4,4-heptafluorobutaneperoxoate Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(=O)OOC(=O)C(F)(F)C(F)(F)C(F)(F)F JUTIIYKOQPDNEV-UHFFFAOYSA-N 0.000 description 1
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- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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- B29K2995/0026—Transparent
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Abstract
Description
372℃におけるメルトフローレートが、1.0~3.2g/10分であることが好ましい。
フルオロ(アルキルビニルエーテル)単位が、パーフルオロ(プロピルビニルエーテル)単位であることが好ましい。
CF2=CFO(CF2CFY1O)p-(CF2CF2CF2O)q-Rf (1)
(式中、Y1はFまたはCF3を表し、Rfは炭素数1~5のパーフルオロアルキル基を表す。pは0~5の整数を表し、qは0~5の整数を表す。)で表される単量体、および、一般式(2):
CFX=CXOCF2OR1 (2)
(式中、Xは、同一または異なり、H、FまたはCF3を表し、R1は、直鎖または分岐した、H、Cl、BrおよびIからなる群より選択される少なくとも1種の原子を1~2個含んでいてもよい炭素数が1~6のフルオロアルキル基、若しくは、H、Cl、BrおよびIからなる群より選択される少なくとも1種の原子を1~2個含んでいてもよい炭素数が5または6の環状フルオロアルキル基を表す。)で表される単量体からなる群より選択される少なくとも1種を挙げることができる。
I:吸光度
K:補正係数
t:フィルムの厚さ(mm)
ジノルマルプロピルパーオキシジカーボネート、ジイソプロピルパーオキシジカーボネート、ジsec-ブチルパーオキシジカーボネートなどのジアルキルパーオキシカーボネート類;
t-ブチルパーオキシイソブチレート、t-ブチルパーオキシピバレートなどのパーオキシエステル類;
ジt-ブチルパーオキサイドなどのジアルキルパーオキサイド類;
ジ[フルオロ(またはフルオロクロロ)アシル]パーオキサイド類;
などが代表的なものとしてあげられる。
食品包装用フィルム、食品製造工程で使用する流体移送ラインのライニング材、パッキン、シール材、シート等の食品製造装置用流体移送部材;
薬品用の薬栓、包装フィルム、薬品製造工程で使用される流体移送ラインのライニング材、パッキン、シール材、シート等の薬液移送部材;
化学プラントや半導体工場の薬液タンクや配管の内面ライニング部材;
自動車の燃料系統並びに周辺装置に用いられるO(角)リング・チューブ・パッキン、バルブ芯材、ホース、シール材等、自動車のAT装置に用いられるホース、シール材等の燃料移送部材;
自動車のエンジン並びに周辺装置に用いられるキャブレターのフランジガスケット、シャフトシール、バルブステムシール、シール材、ホース等、自動車のブレーキホース、エアコンホース、ラジエーターホース、電線被覆材等のその他の自動車部材;
半導体製造装置のO(角)リング、チューブ、パッキン、バルブ芯材、ホース、シール材、ロール、ガスケット、ダイヤフラム、継手等の半導体装置用薬液移送部材;
塗装設備用の塗装ロール、ホース、チューブ、インク用容器等の塗装・インク用部材;
飲食物用のチューブ又は飲食物用ホース等のチューブ、ホース、ベルト、パッキン、継手等の飲食物移送部材、食品包装材、ガラス調理機器;
廃液輸送用のチューブ、ホース等の廃液輸送用部材;
高温液体輸送用のチューブ、ホース等の高温液体輸送用部材;
スチーム配管用のチューブ、ホース等のスチーム配管用部材;
船舶のデッキ等の配管に巻き付けるテープ等の配管用防食テープ;
電線被覆材、光ファイバー被覆材、太陽電池の光起電素子の光入射側表面に設ける透明な表面被覆材および裏面剤等の各種被覆材;
ダイヤフラムポンプのダイヤフラムや各種パッキン類等の摺動部材;
農業用フィルム、各種屋根材・側壁等の耐侯性カバー;
建築分野で使用される内装材、不燃性防火安全ガラス等のガラス類の被覆材;
家電分野等で使用されるラミネート鋼板等のライニング材;
含フッ素共重合体の各単量体単位の含有量は、NMR分析装置(たとえば、ブルカーバイオスピン社製、AVANCE300 高温プローブ)、または、赤外吸収測定装置(パーキンエルマー社製、Spectrum One)を用いて測定した。
含フッ素共重合体のMFRは、ASTM D-1238に準拠して、メルトインデクサーG-01(東洋精機製作所製)を用い、372℃、5kg荷重下で、内径2mm、長さ8mmのダイから10分間あたりに流出するポリマーの質量(g/10分)を測定することにより、求めた。
含フッ素共重合体の-CF2H基の数は、核磁気共鳴装置AVANCE-300(ブルカーバイオスピン社製)を用い、測定温度を(ポリマーの融点+20)℃として19F-NMR測定を行い、-CF2H基のピーク積分値から求めた。
実施例および比較例で得られた乾燥粉体もしくはペレットを、コールドプレスにより成形して、厚さ0.25~0.3mmのフィルムを作製した。このフィルムをフーリエ変換赤外分光分析装置〔FT-IR(Spectrum One、パーキンエルマー社製)〕により40回スキャンし、分析して赤外吸収スペクトルを得た。得られた赤外吸収スペクトルを、既知のフィルムの赤外吸収スペクトルと比較して末端基の種類を決定した。また、得られた赤外吸収スペクトルと、既知のフィルムの赤外吸収スペクトルとの差スペクトルに現れる特定の官能基の吸収ピークから、下記式(A)に従って試料における炭素原子1×106個あたりの官能基数Nを算出した。
I:吸光度
K:補正係数
t:フィルムの厚さ(mm)
国際公開第2019/220850号に記載の方法にて分析を行った。吸収周波数を1817cm-1、モル吸光度係数を170(l/cm/mol)、補正係数を1426とした以外は、官能基数Nの算出方法と同様にして、-OC(=O)O-R(カーボネート基)の数を算出した。
含フッ素共重合体の融点は、示差走査熱量計(商品名:X-DSC7000、日立ハイテクサイエンス社製)を用いて、昇温速度10℃/分で200℃から350℃までの1度目の昇温を行い、続けて、冷却速度10℃/分で350℃から200℃まで冷却し、再度、昇温速度10℃/分で200℃から350℃までの2度目の昇温を行 い、2度目の昇温過程で生ずる溶融曲線ピークから融点を求めた。
容積174Lの攪拌機付きオートクレーブに脱イオン水40.25kgとメタノール0.240kgを投入し、オートクレーブ内を十分に真空窒素置換した。その後、オートクレーブ内を真空脱気し、真空状態となったオートクレーブ内にHFP40.25kgを投入し、オートクレーブを32.0℃に加温した。続けて、オートクレーブの内部圧力が0.938MPaになるまでTFEを投入し、次に8質量%のジ(ω-ヒドロパーフルオロヘキサノイル)パーオキサイド溶液(以下DHPと略す)0.31kgをオートクレーブ内に投入して重合を開始した。重合開始時点のオートクレーブの内部圧力を0.938MPaに設定し、TFEを連続追加することで設定圧力を保つようにした。重合開始から1.5時間後にメタノール0.240kgを追加投入した。重合開始から2時間後、4時間後、にDHP0.31kgを追加投入するとともに内部圧力を0.001MPa下げ、6時間後に0.24kgを投入するとともに内部圧力を0.001MPa下げた。以降、反応が終了するまで2時間ごとにDHP0.07kgを追加投入した。
容積174Lの攪拌機付きオートクレーブに脱イオン水40.25kgとメタノール0.085kgを投入し、オートクレーブ内を十分に真空窒素置換した。その後、オートクレーブ内を真空脱気し、真空状態となったオートクレーブ内にHFP40.25kgを投入し、オートクレーブを30.0℃に加温した。続けて、オートクレーブの内部圧力が0.906MPaになるまでTFEを投入し、次に8質量%のジ(ω-ヒドロパーフルオロヘキサノイル)パーオキサイド溶液(以下DHPと略す)0.63kgをオートクレーブ内に投入して重合を開始した。重合開始時点のオートクレーブの内部圧力を0.906MPaに設定し、TFEを連続追加することで設定圧力を保つようにした。重合開始から1.5時間後にメタノール0.085kgを追加投入した。重合開始から2時間後、4時間後、にDHP0.63kgを追加投入するとともに内部圧力を0.001MPa下げ、6時間後に0.48kgを投入するとともに内部圧力を0.001MPa下げた。以降、反応が終了するまで2時間ごとにDHP0.13kgを追加投入し、その都度内部圧力を0.001MPa下げた。
重合開始前に投入するメタノールの量を0.106kgに変更し、重合開始後に分割して追加投入するメタノールの量をそれぞれ0.106kgに変更し、重合開始前後のオートクレーブ内部の設定圧力を0.923MPaに変更した以外は、比較例1と同様にして共重合体ペレットを得た。得られたペレットを用いて上記した方法によりHFP含有量とPPVE含有量を測定した。結果を表3に示す。
容積4Lの攪拌機付きオートクレーブに脱イオン水945gを投入し、オートクレーブ内を十分に真空窒素置換した。その後、オートクレーブ内を真空脱気し、真空状態となったオートクレーブ内にHFP945gを投入し、オートクレーブを32.0℃に加温した。続けて、オートクレーブの内部圧力が0.938MPaになるまでTFEを投入し、次に8質量%のジ(ω-ヒドロパーフルオロヘキサノイル)パーオキサイド溶液(以下DHPと略す)5.1gをオートクレーブ内に投入して重合を開始した。重合開始時点のオートクレーブの内部圧力を0.938MPaに設定し、TFEを連続追加することで設定圧力を保つようにした。重合開始から2時間後、4時間後、にDHP5.1gを追加投入し、6時間後に4.0gを投入した。以降、反応が終了するまで2時間ごとにDHP1.1gを追加投入した。
容積174Lの攪拌機付きオートクレーブに脱イオン水40.25kgとメタノール0.066kgを投入し、オートクレーブ内を十分に真空窒素置換した。その後、オートクレーブ内を真空脱気し、真空状態となったオートクレーブ内にHFP40.25kgとPPVE0.32kgを投入し、オートクレーブを32.0℃に加温した。続けて、オートクレーブの内部圧力が0.928MPaになるまでTFEを投入し、次に8質量%のジ(ω-ヒドロパーフルオロヘキサノイル)パーオキサイド溶液(以下DHPと略す)0.31kgをオートクレーブ内に投入して重合を開始した。重合開始時点のオートクレーブの内部圧力を0.928MPaに設定し、TFEを連続追加することで設定圧力を保つようにした。重合開始から1.5時間後にメタノール0.066kgを追加投入した。重合開始から2時間後、4時間後、にDHP0.31kgを追加投入するとともに内部圧力を0.001MPa下げ、6時間後に0.24kgを投入するとともに内部圧力を0.001MPa下げた。以降、反応が終了するまで2時間ごとにDHP0.07kgを追加投入した。
重合開始前に投入するメタノールの量を0.099kgに変更し、重合開始後に分割して追加投入するメタノールの量をそれぞれ0.099kgに変更し、重合開始前後のオートクレーブ内部の設定圧力を0.932MPaに変更した以外は、比較例1と同様にして共重合体ペレットを得た。得られたペレットをフッ素化せずに用いて、上記した方法により各種物性を測定した。結果を表3に示す。
重合開始前に投入するメタノールの量を0.051kgに変更し、重合開始後に分割して追加投入するメタノールの量をそれぞれ0.051kgに変更し、重合開始前後のオートクレーブ内部の設定圧力を0.947MPaに変更した以外は、比較例1と同様にして共重合体ペレットを得た。得られたペレットを用いて上記した方法によりHFP含有量とPPVE含有量を測定した。結果を表3に示す。
重合開始前に投入するメタノールの量を0.112kgに変更し、重合開始後に分割して追加投入するメタノールの量をそれぞれ0.112kgに変更し、重合開始前後のオートクレーブ内部の設定圧力を0.938MPaに変更した以外は、比較例1と同様にして共重合体ペレットを得た。得られたペレットを用いて上記した方法によりHFP含有量とPPVE含有量を測定した。結果を表3に示す。
重合開始前に投入するメタノールの量を0.124kgに変更し、重合開始後に分割して追加投入するメタノールの量をそれぞれ0.124kgに変更し、重合開始前後のオートクレーブ内部の設定圧力を0.928MPaに変更した以外は、比較例1と同様にして共重合体ペレットを得た。得られたペレットを用いて上記した方法によりHFP含有量とPPVE含有量を測定した。結果を表3に示す。
ペレットおよびヒートプレス成形機を用いて、厚さ約0.2mmのシート状試験片を作製し、これから10cm×10cmの試験片を切り出した。テーバー摩耗試験機(No.101 特型テーバー式アブレーションテスター、安田精機製作所社製)の試験台に作製した試験片を固定し、温度25℃、荷重500g、摩耗輪CS-10(研磨紙#240で20回転研磨したもの)、回転速度60rpmの条件で、テーバー摩耗試験機を用いて摩耗試験を行った。1000回転後の試験片重量を計量し、同じ試験片でさらに10000回転試験後に試験片重量を計量した。次式により、摩耗量を求めた。
摩耗量(mg)=M1-M2
M1:1000回転後の試験片重量(mg)
M2:10000回転後の試験片重量(mg)
含フッ素共重合体を、350℃にて0.5MPaの圧力で圧縮成形して厚さ1mmのシートを作製し、これから10×20mmに切出し、オゾン曝露試験用の試料とした。オゾン発生装置(商品名:SGX-A11MN(改)、住友精機工業社製)で発生させたオゾンガス(オゾン/酸素=10/90容量%)をイオン交換水が入ったPFA製の容器に接続し、イオン交換水中にバブリングしてオゾンガスに水蒸気を添加した後、試料が入ったPFA製のセルに0.7リットル/分で室温にて通して試料を湿潤オゾンガスに曝露した。曝露を開始してから135日後に試料を取り出し、表面をイオン交換水で軽くすすいだ後、透過型光学顕微鏡を用いて倍率100倍で試料表面から深さ5~200μmの部分を観察し、標準スケールとともに撮影し、試料表面1mm2あたりの長さ10μm以上のクラックの数を測定した。
評価は、以下の基準で行った。
○:クラック数10個以下
×:クラック数10個超
ペレットおよびヒートプレス成形機を用いて、厚さ約0.1mmのシート状試験片を作製した。得られた試験片を用い、JIS K7126-1:2006に記載の方法に従って、差圧式ガス透過度計(L100-5000型ガス透過度計、Systech illinois社製)を用いて、二酸化炭素透過度の測定を行った。透過面積50.24cm2、試験温度70℃、試験湿度0%RHでの二酸化炭素透過度の数値を得た。得られた二酸化炭素透過度と試験片厚みを用いて、次式より二酸化炭素透過係数を算出した。
二酸化炭素透過係数(cm3・mm/(m2・24h・atm))=GTR×d
GTR:二酸化炭素透過度(cm3/(m2・24h・atm))
d:試験片厚み(mm)
ペレットおよびヒートプレス成形機を用いて、厚さ約2.4mmのシート状試験片を作製し、これから80×10mmの試験片を切り出し、電気炉にて75℃で20時間加熱した。得られた試験片を用いた以外は、JIS K-K 7191-1に記載の方法に準じて、ヒートディストーションテスター(安田精機製作所社製)にて、試験温度30~150℃、昇温速度120℃/時間、曲げ応力1.8MPa、フラットワイズ法の条件にて試験を行った。次式により荷重たわみ率を求めた。75℃での荷重たわみ率が小さいシートは、75℃高温時剛性に優れている。
荷重たわみ率(%)=a2/a1×100
a1:試験前の試験片厚み(mm)
a2:75℃でのたわみ量(mm)
日立ハイテクサイエンス社製TMA-7100を用いて引張クリープ歪を測定した。ペレットおよびヒートプレス成形機を用いて、厚さ約0.1mmのシートを作製し、シートから幅2mm、長さ22mmのサンプルを作製した。サンプルを治具間距離10mmで測定治具に装着した。サンプルに対して、断面荷重が4.49N/mm2になるように荷重を負荷し、110℃に放置し、試験開始後90分の時点から試験開始後900分の時点までのサンプルの長さの変位(mm)を測定し、初期のサンプル長(10mm)に対する長さの変位(mm)の割合(引張クリープ歪(%))を算出した。110℃、900分間の条件で測定する引張クリープ歪(%)が小さいシートは、高温の環境中で引張荷重が長時間負荷されても伸びにくく、高温耐引張クリープ特性(110℃)に優れている。
島津製作所社製疲労試験機MMT-250NV-10を用いて3万回サイクル後引張強度を測定した。ペレットおよびヒートプレス成形機を用いて、厚さ約2.4mmのシートを作製し、ASTM D1708マイクロダンベル用いて、ダンベル形状(厚み2.4mm、幅5.0mm、測定部長さ22mm)のサンプルを作製した。サンプルを測定治具に装着し、サンプルを装着した状態で測定治具を110℃の恒温槽中に設置した。ストローク0.2mm、周波数100Hzで、一軸方向への引張りを繰り返し、引張り毎の引張強度(ストロークが+0.2mmの時の引張強度、単位:N)を測定した。
ペレットおよびヒートプレス成形機を用いて、厚さ約0.2mmのシートを作製し、15mm四方の試験片を作製した。50mLポリプロピレン製ボトルに、試験片10枚と3質量%過酸化水素水溶液15gを入れ、電気炉にて95℃で20時間加熱後、室温まで冷却した。過酸化水素水溶液から試験片を取り出し、残った過酸化水素水溶液にTISAB溶液(10)(関東化学社製)を添加し、得られた過酸化水素水溶液中のフッ素イオン濃度を、フッ素イオンメーターにて測定した。得られた測定値から、下記式にしたがって、シート重量当たりのフッ素イオン濃度(溶出フッ素イオン濃度)を算出した。
溶出フッ素イオン濃度(質量ppm)=測定値(ppm)×過酸化水素水溶液量(g)/試験片重量(g)
φ14mm押出機(井元製作所製)およびTダイを用いて、ペレットを成形し、フィルムを作製した。押出成形条件は以下の通りである。
a)巻き取り速度:0.4m/分
b)ロール温度:120℃
c)フィルム幅:70mm
d)厚み:0.25mm
e)押出条件:
・シリンダー軸径=14mm,L/D=20の単軸押出成形機
押出機の設定温度:バレル部C-1(330℃)、バレル部C-2(350℃)、バレル部C-3(365℃)、Tダイ部(370℃)
φ30mm押出機(田辺プラスチックス機械製)を用いて、ペレットを押出成形し、外径10.0mm、肉厚1.0mmのチューブを得た。押出成形条件は以下の通りである。
a)ダイ内径:25mm
b)マンドレル外径:13mm
c)サイジングダイ内径:10.5mm
d)引取り速度:0.4m/分
e)外径:10.0mm
f)肉厚:1.0mm
g)押出条件:
・シリンダー軸径=30mm,L/D=22の単軸押出成形機
押出機の設定温度:バレル部C-1(350℃)、バレル部C-2(370℃)、バレル部C-3(380℃)、ヘッド部H-1(390℃)、ダイ部D-1(390℃)、ダイ部D-2(390℃)
得られたチューブを観察し、以下の基準により評価した。チューブの外観は、目視により確認した。
〇:外観が良好である
×:断面が円形になっておらず、扁平していたり偏肉が観られるなど、外観が不良である
30mmφ電線被覆成形機(田辺プラスチック機械社製)を用いて、導体径1.00mmの銅導体上に、下記被覆厚みで含フッ素共重合体を押出被覆し、被覆電線を得た。電線被覆押出成形条件は以下の通りである。
a)心導体:導体径1.00mm
b)被覆厚み:0.70mm
c)被覆電線径:2.40mm
d)電線引取速度:3m/分
e)押出条件:
・シリンダー軸径=30mm,L/D=22の単軸押出成形機
・ダイ(内径)/チップ(外形)=24.0mm/10.0mm
押出機の設定温度:バレル部C-1(340℃)、バレル部C-2(375℃)、バレル部C-3(390℃)、ヘッド部H(400℃)、ダイ部D-1(400℃)、ダイ部D-2(400℃)。心線予備加熱は80℃に設定した。
外径測定器(Zumbach社製ODAC18XY)を用いて、得られた被覆電線の外径を1時間連続で測定した。測定された外径値のうち、所定の外径値(2.40mm)よりも最も大きく乖離した外径値の小数点3桁目を四捨五入することにより、外径の変動値を求めた。所定の外径(2.40mm)に対する、所定の外径と、外径の変動値との差の絶対値の割合(外径の変動率)を算出し、以下の基準により評価した。
(外径の変動率(%))=|(外径の変動値)-(所定の外径)|/(所定の外径)×100
±1%:外径の変動率が1%以下である
±2%:外径の変動率が1%超2%以下である
×:外径の変動率が2%超である
Claims (8)
- テトラフルオロエチレン単位、ヘキサフルオロプロピレン単位およびフルオロ(アルキルビニルエーテル)単位を含有する含フッ素共重合体であって、
ヘキサフルオロプロピレン単位の含有量が、全単量体単位に対して、11.5~12.5質量%であり、
フルオロ(アルキルビニルエーテル)単位の含有量が、全単量体単位に対して、0~0.5質量%であり、
372℃におけるメルトフローレートが、0.8~4.0g/10分であり、
-CF2H、カルボニル基含有末端基、-CF=CF2および-CH2OHの合計数が、主鎖炭素数106個あたり、50個以下である
含フッ素共重合体。 - フルオロ(アルキルビニルエーテル)単位の含有量が、全単量体単位に対して、0~0.1質量%である請求項1に記載の含フッ素共重合体。
- 372℃におけるメルトフローレートが、1.0~3.2g/10分である請求項1または2に記載の含フッ素共重合体。
- フルオロ(アルキルビニルエーテル)単位が、パーフルオロ(プロピルビニルエーテル)単位である請求項1~3のいずれかに記載の含フッ素共重合体。
- 請求項1~4のいずれかに記載の含フッ素共重合体を含有する押出成形体。
- 請求項1~4のいずれかに記載の含フッ素共重合体を含有するトランスファー成形体。
- 請求項1~4のいずれかに記載の含フッ素共重合体を含有する被覆層を備える被覆電線。
- 請求項1~4のいずれかに記載の含フッ素共重合体を含有する成形体であって、前記成形体が、ボトル、バック、チューブ、フィルムまたは電線被覆である成形体。
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CN116888174A (zh) | 2023-10-13 |
JP7193767B2 (ja) | 2022-12-21 |
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US20230399433A1 (en) | 2023-12-14 |
JP2022132217A (ja) | 2022-09-07 |
CN117043205A (zh) | 2023-11-10 |
CN116917348A (zh) | 2023-10-20 |
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US20230391914A1 (en) | 2023-12-07 |
CN116897169A (zh) | 2023-10-17 |
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CN116888164A (zh) | 2023-10-13 |
CN116848160A (zh) | 2023-10-03 |
CN116997582A (zh) | 2023-11-03 |
CN116940605A (zh) | 2023-10-24 |
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