JP2022016945A - Fragrance composition - Google Patents
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- JP2022016945A JP2022016945A JP2020119956A JP2020119956A JP2022016945A JP 2022016945 A JP2022016945 A JP 2022016945A JP 2020119956 A JP2020119956 A JP 2020119956A JP 2020119956 A JP2020119956 A JP 2020119956A JP 2022016945 A JP2022016945 A JP 2022016945A
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- 239000003205 fragrance Substances 0.000 title claims abstract description 78
- 239000000203 mixture Substances 0.000 title claims abstract description 71
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 81
- 239000000194 fatty acid Substances 0.000 claims abstract description 81
- 229930195729 fatty acid Natural products 0.000 claims abstract description 81
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 66
- -1 fatty acid salt Chemical class 0.000 claims abstract description 16
- 241000207923 Lamiaceae Species 0.000 claims abstract description 11
- 241000208150 Geraniaceae Species 0.000 claims abstract description 8
- 239000003599 detergent Substances 0.000 claims description 17
- 239000012459 cleaning agent Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 241000218645 Cedrus Species 0.000 claims description 4
- 241000208152 Geranium Species 0.000 claims description 4
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 4
- 244000246386 Mentha pulegium Species 0.000 claims description 4
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 4
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 4
- 235000011203 Origanum Nutrition 0.000 claims description 4
- 240000000783 Origanum majorana Species 0.000 claims description 4
- 240000002505 Pogostemon cablin Species 0.000 claims description 4
- 235000011751 Pogostemon cablin Nutrition 0.000 claims description 4
- 244000178231 Rosmarinus officinalis Species 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 235000001050 hortel pimenta Nutrition 0.000 claims description 4
- 239000001102 lavandula vera Substances 0.000 claims description 4
- 235000018219 lavender Nutrition 0.000 claims description 4
- 235000002020 sage Nutrition 0.000 claims description 4
- 150000004671 saturated fatty acids Chemical group 0.000 claims description 4
- 235000001053 badasse Nutrition 0.000 claims description 3
- 244000056931 lavandin Species 0.000 claims description 3
- 235000009606 lavandin Nutrition 0.000 claims description 3
- 244000301850 Cupressus sempervirens Species 0.000 claims 1
- 244000178870 Lavandula angustifolia Species 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 abstract description 16
- 241000218691 Cupressaceae Species 0.000 abstract description 11
- 238000005406 washing Methods 0.000 abstract description 6
- 230000002688 persistence Effects 0.000 abstract description 2
- 235000019645 odor Nutrition 0.000 description 38
- 238000011156 evaluation Methods 0.000 description 9
- 230000000873 masking effect Effects 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 235000019482 Palm oil Nutrition 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- 239000002537 cosmetic Substances 0.000 description 6
- 239000002540 palm oil Substances 0.000 description 6
- 239000011591 potassium Substances 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 229960004418 trolamine Drugs 0.000 description 6
- 239000000341 volatile oil Substances 0.000 description 6
- 235000019629 palatability Nutrition 0.000 description 5
- 244000165082 Lavanda vera Species 0.000 description 4
- 235000015278 beef Nutrition 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000004006 olive oil Substances 0.000 description 4
- 235000008390 olive oil Nutrition 0.000 description 4
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 239000003676 hair preparation Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003346 palm kernel oil Substances 0.000 description 3
- 235000019865 palm kernel oil Nutrition 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- 238000001256 steam distillation Methods 0.000 description 2
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 1
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 1
- JFNWWQMIGPYWED-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;16-methylheptadecanoic acid Chemical compound OCCN(CCO)CCO.CC(C)CCCCCCCCCCCCCCC(O)=O JFNWWQMIGPYWED-UHFFFAOYSA-N 0.000 description 1
- FRPAVHFNOFSNDR-UHFFFAOYSA-N 3-(2,4-dioxo-1,3-thiazolidin-3-yl)propanoic acid Chemical compound OC(=O)CCN1C(=O)CSC1=O FRPAVHFNOFSNDR-UHFFFAOYSA-N 0.000 description 1
- 235000019499 Citrus oil Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000002997 Lavandula Nutrition 0.000 description 1
- 241001529735 Melissa Species 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 240000006584 Pelargonium crispum Species 0.000 description 1
- 235000006540 Pelargonium crispum Nutrition 0.000 description 1
- 235000004347 Perilla Nutrition 0.000 description 1
- 244000124853 Perilla frutescens Species 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 241000736892 Thujopsis dolabrata Species 0.000 description 1
- 240000002657 Thymus vulgaris Species 0.000 description 1
- 235000007303 Thymus vulgaris Nutrition 0.000 description 1
- IHUMNXSBUOIDQI-UHFFFAOYSA-N Triethanolamine myristate Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCCC(O)=O IHUMNXSBUOIDQI-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 235000019606 astringent taste Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000010500 citrus oil Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 235000019717 geranium oil Nutrition 0.000 description 1
- 239000010648 geranium oil Substances 0.000 description 1
- WYVGZXIHGGQSQN-UHFFFAOYSA-N hexadecanoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCCCCC(O)=O WYVGZXIHGGQSQN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- ZHALDANPYXAMJF-UHFFFAOYSA-N octadecanoate;tris(2-hydroxyethyl)azanium Chemical compound OCC[NH+](CCO)CCO.CCCCCCCCCCCCCCCCCC([O-])=O ZHALDANPYXAMJF-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000008601 oleoresin Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- NGNZTXNWCGRXKL-UHFFFAOYSA-M potassium;16-methylheptadecanoate Chemical compound [K+].CC(C)CCCCCCCCCCCCCCC([O-])=O NGNZTXNWCGRXKL-UHFFFAOYSA-M 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000005471 saturated fatty acid group Chemical group 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940045845 sodium myristate Drugs 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229940080350 sodium stearate Drugs 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 229940096999 triethanolamine isostearate Drugs 0.000 description 1
- 229940117013 triethanolamine oleate Drugs 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Medicines Containing Plant Substances (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
本発明は、香料組成物に関する。更に詳しくは、高級脂肪酸塩を含む洗浄剤組成物が有する特有の臭気を感じさせることなく、さらには特定の天然香料組み合わせにより良好な香り立ちを呈することを可能とする脂肪酸臭抑制香料組成物、および脂肪酸臭抑制香料組成物を含有することを特徴とする皮膚洗浄剤組成物に関する。 The present invention relates to a fragrance composition. More specifically, a fatty acid odor suppressing fragrance composition, which makes it possible to exhibit a good scent by a specific combination of natural fragrances without feeling the peculiar odor of the cleaning agent composition containing a higher fatty acid salt. And a skin cleaning agent composition comprising a fatty acid odor suppressing fragrance composition.
化粧品などの分野においては、製品を製造する際に好ましくない臭気を様々な香料を用いてマスキングすることは汎用の技術として、広く一般に適用されている（非特許文献１～２参照）。 In the field of cosmetics and the like, masking unfavorable odors when manufacturing products with various fragrances is widely and generally applied as a general-purpose technique (see Non-Patent Documents 1 and 2).
上記マスキングの技術は、シャンプーやボディソープなどの洗浄剤組成物の分野にも応用され、商品の原料臭低減や嗜好性向上において大きな役割を担っている。
特に、皮膚洗浄剤の主成分として用いられている高級脂肪酸塩は特有の脂肪酸臭を有することから、洗浄剤として用いる際には香料を用いて該臭気をマスキングすることが一般的である（特許文献１参照）。
The above masking technology is also applied to the field of detergent compositions such as shampoo and body soap, and plays a major role in reducing the odor of raw materials and improving the palatability of products.
In particular, since the higher fatty acid salt used as the main component of the skin cleanser has a peculiar fatty acid odor, it is common to mask the odor with a fragrance when used as a cleanser (patented). See Document 1).
しかしながら、近年の消費者のナチュラル志向の高まりを受け、天然香料のみからなる脂肪酸臭抑制香料組成物、および当該香料組成物を含有する皮膚洗浄剤組成物が求められるなか、脂肪酸臭を天然香料のみにてマスキングし、かつ良好な香り立ちを呈することを可能とする技術は研究途上であり、今後の技術開発が期待される分野であった。 However, in response to the growing natural orientation of consumers in recent years, a fatty acid odor suppressing fragrance composition consisting only of natural fragrances and a skin cleaning agent composition containing the fragrance composition are required, and the fatty acid odor is limited to natural fragrances. The technology that makes it possible to mask and give a good fragrance is still under research, and it was a field where future technological development is expected.
本発明は、上記に鑑みてなされたものであって、本発明の目的は、高級脂肪酸塩に起因する脂肪酸臭をマスキングするとともに、良好な香り立ちに加え、洗浄中における良好な香りの持続性を有する天然香料のみからなる香料組成物、および当該香料組成物を含有することを特徴とする皮膚洗浄剤を提供することにある。 The present invention has been made in view of the above, and an object of the present invention is to mask the fatty acid odor caused by the higher fatty acid salt, and in addition to having a good scent, the good scent persistence during washing. It is an object of the present invention to provide a fragrance composition comprising only a natural fragrance having the above-mentioned fragrance composition, and a skin cleaning agent containing the fragrance composition.
本発明者らは上記問題点を鋭意研究した結果、（Ａ）フウロソウ科またはヒノキ科の植物から抽出される天然香料 １種または２種以上、および（Ｂ）シソ科の植物から抽出される天然香料 １種または２種以上を組み合わせた場合に、高級脂肪酸塩臭に対し優れたマスキング効果を示すとともに、良好な香り立ちを呈することを見出し、本発明を完成した。 As a result of diligent research on the above problems, the present inventors have (A) one or more natural fragrances extracted from plants of Geraniaceae or Labiatae, and (B) naturals extracted from plants of Labiatae. The present invention has been completed by finding that when one kind or two or more kinds of fragrances are combined, an excellent masking effect is exhibited against the odor of higher fatty acid salt and a good fragrance is exhibited.
本発明は、（Ａ）フウロソウ科またはヒノキ科の植物から抽出される天然香料、および（Ｂ）シソ科の植物から抽出される天然香料 １種または２種以上を含有する脂肪酸臭抑制香料組成物、ならびに脂肪酸と上記天然香料を含有する皮膚洗浄剤組成物に関する。更には該脂肪酸が好ましくは炭素数８～２２の飽和の脂肪酸である皮膚洗浄剤組成物である。 The present invention is a fatty acid odor suppressing fragrance composition containing (A) a natural fragrance extracted from a plant of the family Geraniaceae or Cupressaceae, and (B) a natural fragrance extracted from a plant of the Labiatae family. , As well as skin cleansing compositions containing the above natural fragrances. Further, it is a skin cleansing composition in which the fatty acid is preferably a saturated fatty acid having 8 to 22 carbon atoms.
第一の発明は、（Ａ）フウロソウ科またはヒノキ科の植物から抽出される天然香料 １種または２種以上、および（Ｂ）シソ科の植物から抽出される天然香料 １種または２種以上を含有することを特徴とする脂肪酸臭抑制香料組成物である。 The first invention comprises (A) one or more natural fragrances extracted from Geraniaceae or Cupressaceae plants, and (B) one or more natural fragrances extracted from Labiatae plants. It is a fatty acid odor suppressing fragrance composition characterized by containing.
第二の発明は、（Ａ）成分がゼラニウム、セダーリーフまたはサイプレスから抽出される天然香料である第一の発明に記載の脂肪酸臭抑制香料組成物である。 The second invention is the fatty acid odor suppressing fragrance composition according to the first invention, wherein the component (A) is a natural fragrance extracted from geranium, cedar leaf or cypress.
第三の発明は、（Ｂ）成分がラベンダー、ラバンジン、ローズマリー、パチョリ、マジョラム、ペパーミント、およびセージからなる群から選択される１種または２種以上から抽出される天然香料である第一または第二の発明に記載の脂肪酸臭抑制香料組成物である。 The third invention is the first or a natural fragrance extracted from one or more selected from the group (B) consisting of lavender, lavandin, rosemary, patchouli, marjoram, peppermint, and sage. The fragrance composition for suppressing a fatty acid odor according to the second invention.
第四の発明は、第一乃至第三の発明のいずれかに記載の脂肪酸臭抑制香料組成物、および高級脂肪酸塩を含有する洗浄剤組成物である。 The fourth invention is the fatty acid odor suppressing fragrance composition according to any one of the first to third inventions, and a detergent composition containing a higher fatty acid salt.
第五の発明は、高級脂肪酸塩が炭素数８～２２の飽和脂肪酸である第四の発明に記載の洗浄剤組成物である。 The fifth invention is the cleaning agent composition according to the fourth invention, wherein the higher fatty acid salt is a saturated fatty acid having 8 to 22 carbon atoms.
第六の発明は、（Ａ）成分と（Ｂ）成分の合計含有量が、洗浄剤組成物総量に対し０．０１～１．０質量％である第四または第五の発明に記載の洗浄剤組成物である。 The sixth invention is the cleaning according to the fourth or fifth invention, wherein the total content of the component (A) and the component (B) is 0.01 to 1.0% by mass with respect to the total amount of the detergent composition. It is an agent composition.
第七の発明は、（Ｂ）成分に対する（Ａ）成分の質量比（Ａ）／（Ｂ）が０．５以上２以下である第四乃至第六の発明のいずれかに記載の洗浄剤組成物である。 The seventh invention is the cleaning agent composition according to any one of the fourth to sixth inventions, wherein the mass ratio (A) / (B) of the component (A) to the component (B) is 0.5 or more and 2 or less. It is a thing.
本発明によれば、高級脂肪酸を含む洗浄剤組成物が有する特有の脂肪酸臭を、天然香料のみでマスキングするとともに、良好な香り立ちを呈することを可能とする香料組成物を提供するとともに、当該香料組成物を含有することを特徴する洗浄剤組成物を提供することが可能となる。 According to the present invention, the present invention provides a fragrance composition capable of masking the peculiar fatty acid odor of a cleaning agent composition containing a higher fatty acid with only a natural fragrance and exhibiting a good fragrance. It is possible to provide a cleaning agent composition characterized by containing a fragrance composition.
以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
本発明の脂肪酸臭抑制香料組成物に含有される天然香料とは、例えば植物の葉、花、樹皮、根、小枝、果実、果皮、種実などの植物原料を圧搾、水蒸気蒸留などを行って得られる天然精油、またこれらの原料を有機溶媒で抽出して得られるエキストラクト類、更にこの抽出液から溶媒を除去して得られるオレオレジン、レジノイド類、果汁その他の搾汁液などを濃縮、水蒸気蒸留などを行う際に得られる回収香及び例えば、柑橘油等を含水アルコールで抽出して得られるエッセンス類等を指すものである。 The natural fragrance contained in the fatty acid odor suppressing fragrance composition of the present invention can be obtained by, for example, pressing plant raw materials such as leaves, flowers, bark, roots, twigs, fruits, peels and seeds of plants and steam distillation. Natural essential oils, extracts obtained by extracting these raw materials with an organic solvent, and oleoresin, resinoids, fruit juice and other juices obtained by removing the solvent from this extract are concentrated and steam distilled. It refers to the recovered fragrance obtained when performing the above and the essences obtained by extracting, for example, citrus oil with hydrous alcohol.
本発明の脂肪酸臭抑制香料組成物に含有される成分（Ａ）フウロソウ科の植物から抽出される天然香料は、フウロソウ科由来の天然精油の全草または花を圧搾、溶剤抽出又は水蒸気蒸留することにより得ることができる。市販されているものを使用することもでき、例えば、小川香料株式会社のゼラニウムオイル（Ｇｅｒａｎｉｕｍ Ｏｉｌ）を使用することができる。 Ingredients contained in the fatty acid odor suppressing fragrance composition of the present invention (A) The natural fragrance extracted from a plant of the Geraniaceae family is obtained by pressing, solvent-extracting or steam-distilling the whole plant or flower of a natural essential oil derived from the Geraniaceae family. Can be obtained by Commercially available products can also be used, and for example, geranium oil manufactured by Ogawa & Co., Ltd. can be used.
フウロソウ科の植物としては以下に限定されるものではないが、ゼラニウム、レモンゼラニウムが挙げられる。これらの中でも、皮膚洗浄剤のマスキングの観点からは、特にゼラニウムが好ましい。 The plants of the Geraniaceae family are not limited to the following, and examples thereof include geranium and lemon geranium. Among these, geranium is particularly preferable from the viewpoint of masking the skin cleanser.
本発明の脂肪酸臭抑制香料組成物に含有される成分（Ａ）ヒノキ科の植物から抽出される天然香料としては、ヒノキ科由来の天然精油を挙げることができ、該天然精油はヒノキ科の植物の全草または花を圧搾、溶剤抽出又は水蒸気蒸留することにより得ることができる。また、市販されているものを使用することもでる。 Ingredients contained in the fatty acid odor suppressing fragrance composition of the present invention (A) Examples of the natural fragrance extracted from a plant of the family Cupressaceae include a natural essential oil derived from the family Cupressaceae, and the natural essential oil is a plant of the family Cupressaceae. It can be obtained by pressing, solvent-extracting or steam-distilling the whole plant or flower of Cupressaceae. It is also possible to use commercially available products.
ヒノキ科の植物としては以下に限定されるものではないが、セダーリーフ、サイプレス、ヒバ、セダーウッドが挙げられる。これらの中でも、皮膚洗浄剤のマスキングの観点からは、特にセダーリーフ、サイプレスが好ましい。 The plants of the Cupressaceae family are not limited to the following, but include cedar leaf, cypress, hiba, and cedar wood. Among these, Cedar Leaf and Cypress are particularly preferable from the viewpoint of masking the skin cleanser.
本発明の脂肪酸臭抑制香料組成物に含有される成分（Ｂ）シソ科の植物から抽出される天然香料 １種または２種以上は、シソ科由来の天然精油は植物の全草または花を圧搾、溶剤抽出又は水蒸気蒸留することにより得ることができる。市販されているものを使用することもでき、例えば、小川香料株式会社のラベンダーオイル（Ｌａｖｅｎｄｅｒ Ｏｉｌ）を使用することができる。 Ingredients contained in the fatty acid odor suppressing fragrance composition of the present invention (B) Natural fragrances extracted from Labiatae plants One or more, natural essential oils derived from Labiatae squeeze whole plants or flowers. , Can be obtained by solvent extraction or steam distillation. Commercially available products can also be used, and for example, lavender oil (Lavender Oil) manufactured by Ogawa & Co., Ltd. can be used.
シソ科の植物としては以下に限定されるものではないが、ラベンダー、ラバンジン、ローズマリー、パチョリ、マジョラム、ペパーミント、セージ、シソ、メリッサ、タイムが挙げられる。これらの中でも、皮膚洗浄剤の良好な香り立ちの観点からは、特にラベンダー、ラバンジン、ローズマリー、パチョリ、マジョラム、ペパーミント、セージが好ましい。 Labiatae plants include, but are not limited to, lavender, lavandula, rosemary, patchouli, marjoram, peppermint, sage, perilla, melissa, and thyme. Among these, lavender, lavandin, rosemary, patchouli, marjoram, peppermint, and sage are particularly preferable from the viewpoint of good fragrance of the skin cleanser.
本発明の脂肪酸臭抑制香料組成物において、成分（Ａ）と成分（Ｂ）の合計配合量は、
洗浄剤組成物総量に対し、好ましくは０．００１～５．０質量％であり、より好ましくは０．０１～１．０％である。０．００５％以上であれば、良好なマスキング効果を十分に得ることができ好ましい。配合量が０．００１質量％以上ではマスキング効果を呈し、使用時における嗜好性が良好あり、５．０質量％以下では天然精油の香気が強すぎず、使用時における嗜好性が損なわれない。
In the fatty acid odor suppressing fragrance composition of the present invention, the total blending amount of the component (A) and the component (B) is
It is preferably 0.001 to 5.0% by mass, more preferably 0.01 to 1.0%, based on the total amount of the detergent composition. If it is 0.005% or more, a good masking effect can be sufficiently obtained, which is preferable. When the blending amount is 0.001% by mass or more, a masking effect is exhibited and the palatability at the time of use is good, and when the blending amount is 5.0% by mass or less, the aroma of the natural essential oil is not too strong and the palatability at the time of use is not impaired.
本発明の脂肪酸臭抑制香料組成物において、成分（Ａ）の配合量と成分（Ｂ）の配合量の質量比（Ａ）／（Ｂ）は、香り立ちの良好さの観点から、好ましくは０．１以上４．０以下、より好ましくは０．５以上２以下である。（Ａ）／（Ｂ）が０．１以上では洗浄中における香り立ちの持続があり使用時における嗜好性が良好であり、４．０以下では渋みを呈するシソ科の植物の特有の香り立ちが得られ使用時における嗜好性の低下が起こらない。 In the fatty acid odor suppressing fragrance composition of the present invention, the mass ratio (A) / (B) of the blended amount of the component (A) and the blended amount of the component (B) is preferably 0 from the viewpoint of good fragrance. It is 1.1 or more and 4.0 or less, more preferably 0.5 or more and 2 or less. When (A) / (B) is 0.1 or more, the scent is sustained during washing and the palatability at the time of use is good, and when it is 4.0 or less, the scent is peculiar to Labiatae plants showing astringency. It is obtained and does not cause a decrease in palatability at the time of use.
本発明の脂肪酸臭抑制香料組成物の使用により、高級脂肪酸塩が有する脂肪酸臭の低減が可能となるが、特に炭素数８～２２の飽和脂肪酸に対する脂肪酸臭低減効果は顕著に認められる。炭素数８～２２の飽和脂肪酸の例として、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸などの単一の脂肪酸や、ヤシ油脂肪酸、牛脂脂肪酸、ヒマシ油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸などから誘導される脂肪酸、又はそれらの混合物が挙げられる。また高級脂肪酸塩を構成する塩としては、例えばナトリウム塩、カリウム塩等のアルカリ金属塩、低級アルカノールアミン塩などが挙げられるが、特に限定されるものではない。 By using the fatty acid odor suppressing fragrance composition of the present invention, it is possible to reduce the fatty acid odor of the higher fatty acid salt, and the fatty acid odor reducing effect on saturated fatty acids having 8 to 22 carbon atoms is particularly remarkable. Examples of saturated fatty acids having 8 to 22 carbon atoms include single fatty acids such as lauric acid, myristic acid, palmitic acid, and stearic acid, palm oil fatty acids, beef fat fatty acids, castor oil fatty acids, olive oil fatty acids, palm oil fatty acids, and the like. Fatty acids derived from, or mixtures thereof. Examples of the salt constituting the higher fatty acid salt include, but are not limited to, alkali metal salts such as sodium salt and potassium salt, and lower alkanolamine salts.
本発明の脂肪酸臭抑制香料組成物を添加することにより脂肪酸臭の抑制が可能な高級脂肪酸塩を具体的に例示すれば、ラウリン酸ナトリウム、ミリスチン酸ナトリウム、パルミチ
ン酸ナトリウム、ステアリン酸ナトリウム、イソステアリン酸ナトリウム、オレイン酸ナトリウム、ラウリン酸カリウム、ミリスチン酸カリウム、パルミチン酸カリウム、ステアリン酸カリウム、イソステアリン酸カリウム、オレイン酸カリウム、ラウリン酸トリエタノールアミン、ミリスチン酸トリエタノールアミン、パルミチン酸トリエタノールアミン、ステアリン酸トリエタノールアミン、イソステアリン酸トリエタノールアミン、オレイン酸トリエタノールアミン、ヤシ油脂肪酸ナトリウム、牛脂脂肪酸ナトリウム、ヒマシ油脂肪酸ナトリウム、オリーブ油脂肪酸ナトリウム、パーム油脂肪酸ナトリウム、パーム核油脂肪酸ナトリウム、ヤシ油脂肪酸カリウム、牛脂脂肪酸カリウム、ヒマシ油脂肪酸カリウム、オリーブ油脂肪酸カリウム、パーム油脂肪酸カリウム、パーム核油脂肪酸カリウム、ヤシ油脂肪酸トリエタノールアミン、牛脂脂肪酸トリエタノールアミン、ヒマシ油脂肪酸トリエタノールアミン、オリーブ油脂肪酸トリエタノールアミン、パーム油脂肪酸トリエタノールアミン、パーム核油脂肪酸トリエタノールアミン等が挙げられる。本発明の脂肪酸臭抑制香料組成物を含む洗浄剤組成物には、これら高級脂肪酸塩を１種単独又は２種以上を組み合わせて含有することができる。
Specific examples of higher fatty acid salts capable of suppressing fatty acid odor by adding the fatty acid odor suppressing fragrance composition of the present invention include sodium laurate, sodium myristate, sodium palmitate, sodium stearate, and isostearic acid. Sodium, sodium oleate, potassium laurate, potassium myristate, potassium palmitate, potassium stearate, potassium isostearate, potassium oleate, triethanolamine laurate, triethanolamine myristate, triethanolamine palmitate, stearic acid Triethanolamine, Triethanolamine isostearate, Triethanolamine oleate, Sodium coconut oil fatty acid, Sodium beef fatty acid, Sodium castor oil fatty acid, Sodium olive oil fatty acid, Sodium palm oil fatty acid, Sodium palm kernel oil fatty acid, Potassium coconut oil fatty acid, Beef fatty acid potassium, castor oil fatty acid potassium, olive oil fatty acid potassium, palm oil fatty acid potassium, palm kernel oil fatty acid potassium, palm oil fatty acid triethanolamine, beef fat fatty acid triethanolamine, castor oil fatty acid triethanolamine, olive oil fatty acid triethanolamine, Examples thereof include palm oil fatty acid triethanolamine and palm kernel oil fatty acid triethanolamine. The detergent composition containing the fatty acid odor suppressing fragrance composition of the present invention may contain these higher fatty acid salts alone or in combination of two or more.
本発明の脂肪酸臭抑制香料組成物は、高級脂肪酸塩を含有する皮膚化粧料、毛髪化粧料、トイレタリー製品などへの添加が可能である。
皮膚化粧料としては洗顔料、ボディシャンプーなどの身体洗浄剤、メイク製品、フェイスケア製品、ボディケア製品などを挙げることができ、毛髪化粧料としては、シャンプーなどの毛髪洗浄剤、リンス、コンディショナー、スタイリング剤などを挙げることができる。
The fatty acid odor suppressing fragrance composition of the present invention can be added to skin cosmetics, hair cosmetics, toiletry products and the like containing higher fatty acid salts.
Examples of skin cosmetics include facial cleansers, body cleansers such as body shampoos, makeup products, face care products, body care products, and hair cosmetics include hair cleansers such as shampoos, conditioners, and conditioners. Examples include styling agents.
本発明の脂肪酸臭抑制香料組成物を含有する皮膚化粧料、毛髪化粧料、トイレタリー製品は、所望の剤型に応じて公知の製造技術、処方に基づき製造することができ、脂肪酸臭抑制香料組成物の効果を損なわない範囲で、必要に応じて界面活性剤、油脂類、炭化水素類、ロウ類、高分子化合物、粘度調整剤、防腐剤、キレート剤、安定化剤、顔料、香料などの成分を配合することができる。 The skin cosmetics, hair cosmetics, and toiletry products containing the fatty acid odor suppressing fragrance composition of the present invention can be manufactured based on known manufacturing techniques and formulations according to a desired dosage form, and the fatty acid odor suppressing fragrance composition can be produced. If necessary, surfactants, fats and oils, hydrocarbons, waxes, polymer compounds, viscosity modifiers, preservatives, chelating agents, stabilizers, pigments, fragrances, etc. Ingredients can be blended.
以下、本発明を実施例及び比較例を例示することにより具体的に説明するが、本発明はこれら実施例により何ら限定されるものではない。まず、実施例に用いた評価方法、及び評価基準を示す。 Hereinafter, the present invention will be specifically described by exemplifying Examples and Comparative Examples, but the present invention is not limited to these Examples. First, the evaluation method and evaluation criteria used in the examples are shown.
香気の評価方法について以下に記載する。 The evaluation method of aroma is described below.
＜瓶口及び洗浄中の香りの評価方法＞
洗浄剤組成物の香りを瓶口及び洗浄中について、以下の評価基準に基づき専門パネラー１０人により評価した。
<Evaluation method of scent during bottle mouth and washing>
The scent of the detergent composition was evaluated by 10 expert panelists based on the following evaluation criteria for the bottle mouth and during cleaning.
＜評価基準＞
１点：非常に強く脂肪酸臭が感じられる。
２点：強く脂肪酸臭が感じられる。
３点：脂肪酸臭が感じられる。
４点：脂肪酸臭が微かに感じられる。
５点：全く脂肪酸臭が感じられない。
<Evaluation criteria>
1 point: Very strong fatty acid odor is felt.
2 points: A strong fatty acid odor is felt.
3 points: Fatty acid odor is felt.
4 points: A faint fatty acid odor is felt.
5 points: No fatty acid odor is felt.
瓶口での香り：
洗浄剤組成物２０ｇ を、規格瓶（ＥＤ－４０） に入れ、瓶口の香りを評価した。
Aroma at the mouth of the bottle:
20 g of the detergent composition was placed in a standard bottle (ED-40), and the scent of the bottle mouth was evaluated.
洗浄中の香り：
洗浄剤組成物３ｇ を片方の手に取り、頬部を洗浄し、洗浄中の香りを評価した。
Scent during cleaning:
3 g of the detergent composition was taken in one hand, the cheeks were washed, and the scent during washing was evaluated.
＜香り立ちの評価方法＞
洗浄剤組成物の香り立ちについて、以下の評価基準に基づき専門パネラー１０人により評価した。
<Evaluation method of fragrance standing>
The fragrance of the detergent composition was evaluated by 10 expert panelists based on the following evaluation criteria.
＜評価基準＞
１点：香らない。
２点：やや香る。
３点：香る。
４点：良く香る。
５点：非常に良く香る。
<Evaluation criteria>
1 point: No scent.
2 points: Slightly fragrant.
3 points: Fragrant.
4 points: It smells good.
5 points: Very well scented.
香り立ち：
洗浄剤組成物３ｇ を片方の手に取り、水道水を用いて希釈して泡立てた際の香り立ちならびに洗浄中の香り立ちを評価した。
Fragrance:
3 g of the detergent composition was taken in one hand, diluted with tap water and whipped, and the scent and the scent during washing were evaluated.
（香料組成物の調製）
表１に記載する香料組成物１～２５を常法により調整し、得られた香料組成物を高級脂肪酸塩を含む洗浄剤組成物に添加し、表２に記載する実施例１～１４および比較例１～７の洗浄剤組成物を得た。得られた洗浄剤組成物について脂肪酸臭および香り立ち評価を行い、その結果を表２及び３に併せて示す。
(Preparation of fragrance composition)
The fragrance compositions 1 to 25 shown in Table 1 are prepared by a conventional method, and the obtained fragrance composition is added to the detergent composition containing a higher fatty acid salt, and compared with Examples 1 to 14 shown in Table 2. Detergent compositions of Examples 1-7 were obtained. The obtained detergent composition was evaluated for fatty acid odor and fragrance, and the results are also shown in Tables 2 and 3.
表２及び表３より明らかなように、実施例１～２０の洗浄剤組成物は比較例１～１５の組成物に比べていずれも優れた性能を示した。 As is clear from Tables 2 and 3, the detergent compositions of Examples 1 to 20 all showed excellent performance as compared with the compositions of Comparative Examples 1 to 15.
本発明の洗浄剤組成物は、化粧料、医薬部外品として使用することができる。
The detergent composition of the present invention can be used as a cosmetic or a quasi-drug.
Claims (7)
The cleaning composition according to any one of claims 4 to 6, wherein the mass ratio (A) / (B) of the component (A) to the component (B) is 0.5 or more and 2 or less.
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