JP2021186735A - Filtering device - Google Patents
Filtering device Download PDFInfo
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- JP2021186735A JP2021186735A JP2020093896A JP2020093896A JP2021186735A JP 2021186735 A JP2021186735 A JP 2021186735A JP 2020093896 A JP2020093896 A JP 2020093896A JP 2020093896 A JP2020093896 A JP 2020093896A JP 2021186735 A JP2021186735 A JP 2021186735A
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- screen
- sliding member
- filtration
- rotating shaft
- filtration tank
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- 238000001914 filtration Methods 0.000 title claims abstract description 78
- 239000002002 slurry Substances 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 12
- 239000011550 stock solution Substances 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 8
- 230000002093 peripheral effect Effects 0.000 claims description 3
- 238000007790 scraping Methods 0.000 abstract description 6
- 239000010802 sludge Substances 0.000 abstract description 2
- 101150114468 TUB1 gene Proteins 0.000 abstract 1
- 239000007787 solid Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
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Abstract
Description
本発明は、油脂等を包含する難ろ過性原液を、スクリーンで固液分離あるいはスラリーを抽出するろ過装置に関し、特に、ろ過操作中にスクリーン表面を摺動部材で摺動しつつ運転を行うろ過装置に関する。 The present invention relates to a filtration device for solid-liquid separation or slurry extraction of a difficult-to-filter undiluted solution containing oils and fats with a screen, and in particular, filtration in which the screen surface is slid by a sliding member during a filtration operation. Regarding the device.
従来、微細粒子を含有する混合液から微細粒子を分離するろ過機は、様々な分野で適用されており、微細孔を有するスクリーンを介してろ過する技術は周知である。しかし、油脂等を包含する難ろ過性原液をろ過する際には、ろ過面(スクリーン)が早期に目詰まりしてろ過抵抗が上昇し、継続的なろ過操作が困難となっていた。 Conventionally, a filter for separating fine particles from a mixed solution containing fine particles has been applied in various fields, and a technique for filtering through a screen having fine pores is well known. However, when filtering a difficult-to-filter stock solution containing oils and fats, the filtration surface (screen) is clogged at an early stage and the filtration resistance increases, making continuous filtration operation difficult.
そこで、版状フィルターの表面にスクレーパなどの清拭具を稼働自在に配設し、ろ過操作時版状フィルター表面を清拭に保持するろ過装置が特許文献1に記載されている。
Therefore,
先行文献1に開示されているろ過装置は、版状フィルターの表面が清拭具の回転によって常に浄化され目詰まりを防止できるので、濾カスが多く溜まってもろ過作用が支障なく行われるものである。
In the filtration device disclosed in
しかし、処理槽の上方から被処理流体を供給するので、時間の経過とともに濾カスが版状フィルターの上方へと層を成して堆積する。そのため、新たに供給される被処理流体は、まず版状フィルターの表面に形成された濾カス層でろ過され、その後、カス層を通過した液分が版状フィルターのろ過孔を透過して下方へ排出される。 However, since the fluid to be treated is supplied from above the treatment tank, the filter residue is deposited in a layer on the upper part of the plate-like filter with the passage of time. Therefore, the newly supplied fluid to be treated is first filtered by the filter residue layer formed on the surface of the plate-shaped filter, and then the liquid that has passed through the residue layer permeates the filter holes of the plate-shaped filter and moves downward. Is discharged to.
清拭具の回転による濾カス層の攪拌効果も不明であり、被処理流体が難ろ過性原液の場合、濾カス層で早期に目詰まりする可能性が高く、長期のろ過操作時間を維持できない。また、堆積した濾カス層の除去には、版状フィルターを取り外す必要があり、手間が掛かるとともに、運転停止時間が長くなるという問題があった。 The effect of stirring the filter residue layer by rotating the cleaning tool is also unknown, and if the fluid to be treated is a difficult-to-filter undiluted solution, there is a high possibility that the filter residue layer will be clogged at an early stage, and a long-term filtration operation time cannot be maintained. .. Further, in order to remove the accumulated filter residue layer, it is necessary to remove the plate-shaped filter, which is troublesome and has a problem that the operation stop time becomes long.
本発明は、摺動部材でスクリーン表面のろ過槽を掻き除きつつ運転を行い、摺動部材の進行方向後方のスクリーン表面に汚泥を供給するろ過装置を提供する。 The present invention provides a filtration device that operates while scraping off a filtration tank on the screen surface with a sliding member and supplies sludge to the screen surface behind the sliding member in the traveling direction.
本発明は、円筒状のろ過槽に被処理原液を供給し、内部に張設するスクリーンにて固液分離するろ過装置において、電動機と連結する回転軸と、回転軸を回動自在に軸支して供給管から被処理原液を回転軸に供給する回転継手と、回転軸と連通してろ過槽の直径方向に向かって延設される摺動部材と、スクリーン近傍の上方に位置するスラリー管と、を備え、摺動部材の回転方向前面にスクリーン上方のろ過面を摺動するスクレーパと、回転方向後面に供給孔を有するもので、スクリーンの目詰まりを解消しつつ、目詰まりを解消したスクリーン表面に原液を供給するのでろ過抵抗が少なく長期に亘ってろ過操作を継続可能である。 INDUSTRIAL APPLICABILITY The present invention is a filtration device in which a stock solution to be processed is supplied to a cylindrical filtration tank and solid-liquid separation is performed by a screen stretched inside, and a rotary shaft connected to an electric motor and a rotary shaft are rotatably supported. A rotary joint that supplies the undiluted solution to be processed from the supply pipe to the rotary shaft, a sliding member that communicates with the rotary shaft and extends toward the diameter of the filtration tank, and a slurry pipe located above the screen. With a scraper that slides the filtration surface above the screen on the front surface of the sliding member in the rotation direction and a supply hole on the rear surface in the rotation direction, the clogging of the screen is eliminated and the clogging is eliminated. Since the undiluted solution is supplied to the screen surface, the filtration resistance is low and the filtration operation can be continued for a long period of time.
ろ過槽の上部に給気管を設けると、さらに固形物をスクリーンの表面に押圧し、固液分離を促進するとともにろ過時間を短縮することが可能となる。 If an air supply pipe is provided in the upper part of the filtration tank, the solid matter can be further pressed against the surface of the screen to promote solid-liquid separation and shorten the filtration time.
スラリー管を摺動部材の回転方向に沿ってろ過槽周壁に接線状に連通すると、摺動部材5の回転作用によりスラリーを容易に排出可能となる。 When the slurry pipe is tangentially communicated with the peripheral wall of the filtration tank along the rotation direction of the sliding member, the slurry can be easily discharged by the rotational action of the sliding member 5.
本発明は、スクリーンの目詰まりを解消しつつ、目詰まりを解消したスクリーン表面に原液を供給するのでろ過抵抗が少なく長期に亘ってろ過操作を継続可能である。また、排出管がスクリーン近傍の上方に位置しているので、運転操作を継続した状態で連続的にスクリーン表面に堆積するスラリーを排出できる。さらに、高圧気体によりろ過槽内を加圧すると、ろ過作用が促進して含水率を低減させることができる。 INDUSTRIAL APPLICABILITY The present invention supplies the undiluted solution to the screen surface where the clogging is cleared while clearing the clogging of the screen, so that the filtration resistance is low and the filtration operation can be continued for a long period of time. Further, since the discharge pipe is located above the vicinity of the screen, the slurry that is continuously deposited on the screen surface can be discharged while the operation operation is continued. Further, when the inside of the filtration tank is pressurized with a high-pressure gas, the filtration action is promoted and the water content can be reduced.
図1はろ過装置の縦断面図である。
円筒状のろ過槽1に、固形物を含有する被処理原液を固液分離するスクリーン2を張設している。スクリーン2の材質、目開き等は被処理原液の性状や含まれる固形物の粒子径により適宜決定する。
FIG. 1 is a vertical cross-sectional view of the filtration device.
A screen 2 for solid-liquid separation of the undiluted solution to be treated containing a solid substance is attached to the
ろ過槽1の上方に電動機3を配設し、動力伝達手段を介して電動機3と連結した回転軸4をスクリーン2表面近傍まで内挿する。回転軸4の下端はスクレーパ6を設けた摺動部材5と接続する。摺動部材5は、ろ過槽1の直径方向に向かって延設され、回転作用によりスクリーン2上方のろ過面を摺動する。
An electric motor 3 is arranged above the
ろ過槽1の外方にて回転軸4の上端を回動自在に回転継手7に接続しており、回転継手7に被処理原液の供給管8を連結する。
The upper end of the rotary shaft 4 is rotatably connected to the rotary joint 7 on the outside of the
回転軸4および摺動部材5は中空状で内部が連通しており、供給管8から回転継手7を介して回転軸4に供給された被処理原液は、管内の原液供給路から摺動部材5に形成された供給孔9からスクリーン2表面に供給される。 The rotary shaft 4 and the sliding member 5 are hollow and communicate with each other, and the undiluted solution to be processed supplied from the supply pipe 8 to the rotary shaft 4 via the rotary joint 7 is a sliding member from the undiluted solution supply path in the pipe. It is supplied to the surface of the screen 2 through the supply hole 9 formed in 5.
ろ過槽1のスクリーン2近傍の上方にはスクリーン2でろ過・濃縮したスラリーを外部に排出するスラリー管10を設けている。ろ過槽1底部にはスクリーン2で分離したろ過液を排出する排液管11と、ろ過槽1上部には高圧気体を供給する給気管12を設ける。
A slurry pipe 10 for discharging the slurry filtered and concentrated by the screen 2 to the outside is provided above the vicinity of the screen 2 of the
図2は図1のA−A断面図である。
摺動部材5は、ろ過槽1中心に内挿した回転軸4と直交して連結しており、両端部はろ過槽1の内壁近傍まで延設する。
FIG. 2 is a cross-sectional view taken along the line AA of FIG.
The sliding member 5 is connected orthogonally to the rotation shaft 4 inserted in the center of the
電動機3を始動させると、回転軸4と摺動部材5は同期回転する。摺動部材5の回転方向前面にはそれぞれスクレーパ6,6を取り付け、回転方向後面にはそれぞれ被処理原液の供給孔9,9を設けている。 When the electric motor 3 is started, the rotating shaft 4 and the sliding member 5 rotate synchronously. Scrapers 6 and 6 are attached to the front surface of the sliding member 5 in the rotation direction, respectively, and supply holes 9 and 9 for the stock solution to be processed are provided on the rear surface in the rotation direction, respectively.
スクレーパ6は、摺動部材5の回転によりスクリーン2表面を摺動しながら堆積する固形物を掻き除くことでスクリーン2の目詰まりを解消する。 The scraper 6 clears the clogging of the screen 2 by scraping off the solid matter accumulated while sliding on the surface of the screen 2 by the rotation of the sliding member 5.
供給孔9は、供給量やろ過面積等からスクリーン2に均等に供給するよう所定の間隔で複数形成している。 A plurality of supply holes 9 are formed at predetermined intervals so as to evenly supply the screen 2 from the supply amount, the filtration area, and the like.
スラリー管10は、摺動部材5の回転方向に沿って、ろ過槽1周壁に接線状に連通している。
The slurry pipe 10 communicates tangentially with the peripheral wall of the
図1に示すように、被処理原液は供給管8から回転継手7を介して回転軸4および摺動部材5に供給している。本実施例では、回転継手7の両端に管を接続し、一方の菅のみが回動可能な公知の技術を採用している。回転軸4の近傍に配設した電動機3により回転軸4を回転させており、動力伝達手段はベルト、ギア等の公知の技術を適用できる。 As shown in FIG. 1, the undiluted solution to be processed is supplied from the supply pipe 8 to the rotary shaft 4 and the sliding member 5 via the rotary joint 7. In this embodiment, a known technique is adopted in which pipes are connected to both ends of the rotary joint 7 and only one tube can rotate. The rotating shaft 4 is rotated by an electric motor 3 arranged in the vicinity of the rotating shaft 4, and known techniques such as belts and gears can be applied to the power transmission means.
電動機3を始動させると回転軸4のみが回転し、回転継手7は供給管8に支持された状態で固定される。 When the electric motor 3 is started, only the rotary shaft 4 rotates, and the rotary joint 7 is fixed in a state of being supported by the supply pipe 8.
なお、回転継手7に回転軸4を貫通させ、延設した回転軸4の軸端に電動機3を直結するとともに、回転継手7の側面に供給管8を連結してもよい。 The rotary shaft 4 may be passed through the rotary joint 7, the electric motor 3 may be directly connected to the shaft end of the extended rotary shaft 4, and the supply pipe 8 may be connected to the side surface of the rotary joint 7.
図3は摺動部材の断面図である。
本実施例では摺動部材5の基材として中空管を用いており、中空管の中央上部には導入孔13を設け、その導入孔13を囲繞するように回転軸4の下端を接続している。回転軸4から導入孔13を通じて摺動部材5の中空管に供給される被処理原液は、供給孔9からスクリーン2表面に供給される。
FIG. 3 is a cross-sectional view of the sliding member.
In this embodiment, a hollow tube is used as the base material of the sliding member 5, an
中空管の回転方向前面にスクレーパ6を取り付け、回転方向後面に供給孔9を形成している。スクレーパ6はスクリーン2より硬度の低い合成樹脂等を用いることで、スクリーン2の摩耗を防止できる。また、固形物を掻き除いた後、容易に摺動部材5の上方から後方に移動させるために、前方斜め下に傾斜するように取り付けている。 A scraper 6 is attached to the front surface of the hollow tube in the rotation direction, and a supply hole 9 is formed on the rear surface in the rotation direction. The scraper 6 can prevent the screen 2 from being worn by using a synthetic resin or the like having a hardness lower than that of the screen 2. Further, after scraping off the solid matter, the sliding member 5 is attached so as to be inclined diagonally forward and downward so as to be easily moved from above to the rear.
なお、本実施例では板状のスクレーパを用いているが、スクリーンに堆積する固形物を掻き除く作用を奏するものであれば、例えばブラシ状等の他の形状でも適用できる。 Although a plate-shaped scraper is used in this embodiment, other shapes such as a brush-shaped scraper can be applied as long as it has an effect of scraping off solid matter accumulated on the screen.
被処理原液をスクリーン上に供給する供給孔9の径あるいは角度等は、被処理原液の仕様や回転速度等から適宜決定する。 The diameter or angle of the supply hole 9 for supplying the undiluted solution to be processed on the screen is appropriately determined from the specifications of the undiluted solution to be processed, the rotation speed, and the like.
本実施例では中空管に板状のスクレーパ6を取り付けているが、これに限らず一辺がスクレーパの役割が可能な台形状の中空部材等、同様の作用効果を奏し得るものであれば適用できる。 In this embodiment, the plate-shaped scraper 6 is attached to the hollow tube, but the present invention is not limited to this, and is applicable as long as it can exhibit the same effect, such as a trapezoidal hollow member whose one side can serve as a scraper. can.
図4は他の実施例のろ過装置の縦断面図である。
回転軸4が摺動部材5の上部、下部で分割してろ過槽1に内挿されており、上部回転軸4aにはろ過槽1上方の電動機3が連結し、下部回転軸4bはスクリーン2を貫通してろ過槽1下方で回転継手7を介して供給管8と連通している。
FIG. 4 is a vertical cross-sectional view of the filtration device of another embodiment.
The rotary shaft 4 is divided into upper and lower parts of the sliding member 5 and inserted into the
上部回転軸4aは、摺動部材5を回転させるためのもので、中実管であってもよい。 The upper rotation shaft 4a is for rotating the sliding member 5, and may be a solid pipe.
下部回転軸4bは、被処理原液を供給するためのもので、中空管で形成されている。このとき、摺動部材5の導入孔13は中央下部に設けられており、その導入孔13を囲繞するように下部回転軸4bの上端を接続している。
The lower rotary shaft 4b is for supplying the stock solution to be processed, and is formed of a hollow tube. At this time, the
回転継手7は、一端に下部回転軸4bを接続し、他端に供給管8を接続する。被処理原水は、供給管8から下部回転軸4bを介して摺動部材5に流入し、スクリーン2上方のろ過面に供給される。 In the rotary joint 7, the lower rotary shaft 4b is connected to one end, and the supply pipe 8 is connected to the other end. The raw water to be treated flows into the sliding member 5 from the supply pipe 8 via the lower rotary shaft 4b, and is supplied to the filtration surface above the screen 2.
図5は実施例に係るろ過運転中の摺動部材近傍の概念図である。
スクリーン2表面に堆積した固形物を掻き除きながら摺動部材5が図左方向へと回転移動する。このときスクリーン2表面の固形物は、スクレーパ6に沿って摺動部材の上方まで搬送される。ろ過運転中は、摺動部材5の回転移動により、常時スクリーン2の目詰まりを防止することができる。
FIG. 5 is a conceptual diagram of the vicinity of the sliding member during the filtration operation according to the embodiment.
The sliding member 5 rotates and moves to the left in the figure while scraping off the solid matter accumulated on the surface of the screen 2. At this time, the solid matter on the surface of the screen 2 is conveyed to the upper part of the sliding member along the scraper 6. During the filtration operation, the sliding member 5 can be rotated to prevent clogging of the screen 2 at all times.
固形物を除去した後のスクリーン2上に、摺動部材5の供給孔9から被処理原液を供給する。スクリーン2の目詰まりおよびスクリーン2表面の固形物を除去しているため、ろ過抵抗が少なく、供給直後から固液分離が促進される。 The undiluted solution to be treated is supplied from the supply hole 9 of the sliding member 5 onto the screen 2 after the solid matter has been removed. Since the screen 2 is clogged and the solid matter on the surface of the screen 2 is removed, the filtration resistance is low and the solid-liquid separation is promoted immediately after the supply.
その後、摺動部材5の上方まで掻き除かれた固形物が重力作用により下方に落下する。この上下運動により固形物は攪拌され、新たに形成された水道から液分が排出され易くなる。また、スクリーン2の表面に新たに供給された被処理原液の上部に落下してくることで、被処理原液を押圧して固液分離を促進する。 After that, the solid matter scraped up to the upper part of the sliding member 5 falls downward due to the action of gravity. By this vertical movement, the solid matter is agitated, and the liquid content is easily discharged from the newly formed water service. Further, by falling onto the upper part of the undiluted solution to be treated newly supplied to the surface of the screen 2, the undiluted solution to be treated is pressed to promote solid-liquid separation.
ろ過槽1に設けた給気管12から高圧気体を供給し、ろ過槽1内部を高圧に維持することで、さらに固形物をスクリーン2の表面に押圧し、固液分離を促進するとともにろ過時間を短縮することが可能となる。なお、高圧気体によるろ過圧力は、被処理原液の仕様やろ過面積等により適宜決定する。
By supplying high-pressure gas from the air supply pipe 12 provided in the
スクリーン2により液分を分離されたスラリーは、摺動部材5の回転作用により、連続的にスラリー管10より排出される。ろ過槽1の接線状にスラリー管10を接続することで、摺動部材5の回転作用によりスラリーを容易に排出可能となる。なお、スクリーン2上に堆積した固形物のスラリー層は上層ほど含水率が低いため、スラリー管10を摺動部材5より上方に位置させると、ろ過作用が進行して含水率が低下したスラリーを率先して排出できる。
The slurry from which the liquid component has been separated by the screen 2 is continuously discharged from the slurry pipe 10 by the rotational action of the sliding member 5. By connecting the slurry pipe 10 in a tangential manner to the
この発明に係るろ過装置は、常時スクリーンの目詰まりを解消しつつ連続的にろ過運転を継続できるもので、ろ過性能の低下を可能な限り減少させることが可能となる。したがって、製薬分野、化粧品分野や、微生物を用いるバイオ分野等の粒子径が小さい固形物を含有する原液や、溶液中に油脂が分散している食品分野等の難ろ過性の原液に非常に有効である。
The filtration device according to the present invention can continuously continue the filtration operation while constantly clearing the clogging of the screen, and can reduce the deterioration of the filtration performance as much as possible. Therefore, it is very effective for stock solutions containing small particle size solids such as pharmaceutical fields, cosmetics fields, and biotechnology fields that use microorganisms, and difficult-to-filter stock solutions in the food field where fats and oils are dispersed in the solution. Is.
1 ろ過槽
2 スクリーン
3 電動機
4 回転軸
5 摺動部材
6 スクレーパ
7 回転継手
8 供給管
9 供給孔
10 スラリー管
12 給気管
1 Filtration tank 2 Screen 3 Motor 4 Rotating shaft 5 Sliding member 6 Scraper 7 Rotating joint 8 Supply pipe 9 Supply hole 10 Slurry pipe 12 Air supply pipe
Claims (3)
電動機(3)と連結する回転軸(4)と、
回転軸(4)を回動自在に軸支して供給管(8)から被処理原液を回転軸(4)に供給する回転継手(7)と、
回転軸(4)と連通してろ過槽(1)の直径方向に向かって延設される摺動部材(5)と、
スクリーン(2)近傍の上方に位置するスラリー管(10)と、を備え、
摺動部材(5)は、回転方向前面にスクリーン(2)上方のろ過面を摺動するスクレーパ(6)と、回転方向後面に供給孔(9)を有する
ことを特徴とするろ過装置。 In a filtration device in which a stock solution to be processed is supplied to a cylindrical filtration tank (1) and solid-liquid separation is performed by a screen (2) stretched inside.
The rotating shaft (4) connected to the motor (3) and
A rotary joint (7) that rotatably supports the rotary shaft (4) and supplies the undiluted solution to be processed from the supply pipe (8) to the rotary shaft (4).
A sliding member (5) that communicates with the rotating shaft (4) and extends in the radial direction of the filtration tank (1).
A slurry tube (10) located above the vicinity of the screen (2) is provided.
The sliding member (5) is a filtration device having a scraper (6) that slides a filtration surface above the screen (2) on the front surface in the rotation direction and a supply hole (9) on the rear surface in the rotation direction.
ことを特徴とする請求項1に記載のろ過装置。 The filtration device according to claim 1, wherein an air supply pipe (12) is provided above the filtration tank (1).
ことを特徴とする請求項1または2に記載のろ過装置。 The filtration device according to claim 1 or 2, wherein the slurry pipe (10) is communicated tangentially with the peripheral wall of the filtration tank (1) along the rotation direction of the sliding member (5).
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CN116586374A (en) * | 2023-05-18 | 2023-08-15 | 江苏鑫亿鼎石英科技股份有限公司 | Quartz sand pickling and purifying process and purifying device |
Citations (1)
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JPS63310611A (en) * | 1988-05-17 | 1988-12-19 | Yamamoto Koki Kk | Strainer |
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JPS63310611A (en) * | 1988-05-17 | 1988-12-19 | Yamamoto Koki Kk | Strainer |
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CN116586374A (en) * | 2023-05-18 | 2023-08-15 | 江苏鑫亿鼎石英科技股份有限公司 | Quartz sand pickling and purifying process and purifying device |
CN116586374B (en) * | 2023-05-18 | 2024-03-19 | 江苏鑫亿鼎石英科技股份有限公司 | Quartz sand pickling and purifying process and purifying device |
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