JP2021177889A - Spatial sprayer and method for producing disinfection liquid for spatial sprayer - Google Patents

Spatial sprayer and method for producing disinfection liquid for spatial sprayer Download PDF

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JP2021177889A
JP2021177889A JP2020084051A JP2020084051A JP2021177889A JP 2021177889 A JP2021177889 A JP 2021177889A JP 2020084051 A JP2020084051 A JP 2020084051A JP 2020084051 A JP2020084051 A JP 2020084051A JP 2021177889 A JP2021177889 A JP 2021177889A
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atomizer
isocyanuric acid
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JP7082727B2 (en
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功二 佐藤
Koji Sato
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Shinnichi Eng Co Ltd
Shinnichi Engineering Co Ltd
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Shinnichi Engineering Co Ltd
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Abstract

To exhibit bactericidal effect with hypochlorous water at low cost.SOLUTION: A spatial sprayer for disinfection 100 has: a tank part 1 that holds a disinfection liquid containing hypochlorous water, in which powder containing chlorinated isocyanuric acid is dissolved in water; and a nozzle part 2 that sprays the disinfection liquid held in the tank part 1. The nozzle part 2 can spray the disinfection liquid at an effective chlorine level of 10 ppm-50 ppm in the spatial spraying. This structure achieves spatial spraying of hypochlorous water with powder containing chlorinated isocyanuric acid, which is inexpensive and easy to handle, thus exhibiting high disinfection performance safely and inexpensively.SELECTED DRAWING: Figure 1

Description

本発明は、空間噴霧器及び空間噴霧器用の除菌液の製造方法に関する。 The present invention relates to a space atomizer and a method for producing a disinfectant solution for a space atomizer.

近年のCOVID−19、いわゆる新型コロナウィルスの世界的流行により、感染拡大を阻止するための除菌の重要性が叫ばれている。従来より、次亜塩素酸水による殺菌は、厚生労働省により細菌やウイルスに対して殺菌効果のある除菌水(食品添加物)として認められており、安全性が確認されている。 Due to the recent pandemic of COVID-19, the so-called new coronavirus, the importance of sterilization to prevent the spread of infection is being emphasized. Conventionally, sterilization with hypochlorite water has been approved by the Ministry of Health, Labor and Welfare as sterilized water (food additive) having a bactericidal effect against bacteria and viruses, and its safety has been confirmed.

しかしながら、従来は次亜塩素酸水を得るために、塩化ナトリウム水溶液を有隔膜電解槽で電気分解していたため、その製造が面倒で高コストであるという問題があった。また液体の次亜塩素酸水は、運搬コストや管理コストも高くなる。 However, in the past, in order to obtain hypochlorite water, an aqueous solution of sodium chloride was electrolyzed in a septal electrolytic cell, so that there was a problem that the production was troublesome and costly. In addition, liquid hypochlorite water has high transportation costs and management costs.

そこで、粉体状のジクロロイソシアヌル酸ナトリウムなどの塩素化イソシアヌル酸を用いて、これに水を添加して加水分解することで、安価にかつ簡便に次亜塩素酸水を調製することが提案されている。 Therefore, it has been proposed to prepare hypochlorite water inexpensively and easily by using chlorinated isocyanuric acid such as powdered sodium dichloroisocyanurate and adding water to it to hydrolyze it. ing.

しかしながら、本発明者の試験によれば、粉体状のジクロロイソシアヌル酸ナトリウムは均等に水に溶解させることが難しいことが判明した。特に僅かな水が残っているところに粉体状のジクロロイソシアヌル酸ナトリウムを投入すると、粉体が固まって固形化してしまい、溶融が困難になることがあった。 However, according to the test of the present inventor, it has been found that it is difficult to evenly dissolve powdered sodium dichloroisocyanurate in water. In particular, when powdered sodium dichloroisocyanurate is added to a place where a small amount of water remains, the powder may solidify and solidify, making it difficult to melt.

特許6550570号公報Japanese Patent No. 6550570 特許6475903号公報Japanese Patent No. 6475903

本発明は、このような背景に鑑みてなされたものである。本発明の目的の一つは、安価に次亜塩素酸水で殺菌効果を発揮できるようにした空間噴霧器及び空間噴霧器用の除菌液の製造方法を提供することにある。 The present invention has been made in view of such a background. One of an object of the present invention is to provide a space atomizer and a method for producing a disinfectant solution for a space atomizer, which can exert a bactericidal effect with hypochlorite water at low cost.

課題を解決するための手段及び発明の効果Means for Solving Problems and Effects of Invention

本発明の第1の側面に係る空間噴霧器によれば、除菌用の空間噴霧器であって、塩素化イソシアヌル酸を含む粉体を水に溶かした次亜塩素酸水を含む除菌液を保持するタンク部と、前記タンク部内に保持された前記除菌液を噴霧するノズル部と、を含み、前記ノズル部は、前記除菌液を、空間噴霧における有効塩素濃度を10ppm〜50ppmとして噴霧可能に構成している。上記構成により、安価で管理が容易な塩素化イソシアヌル酸を含む粉体を用いて、次亜塩素酸水の空間噴霧を実現でき、高い除菌性能を安全にかつ安価に発揮させることが可能となる。 According to the space sprayer according to the first aspect of the present invention, it is a space sprayer for sterilization and holds a sterilizing solution containing hypochlorite water in which a powder containing chlorinated isocyanuric acid is dissolved in water. A tank portion to be sprayed and a nozzle portion for spraying the disinfectant liquid held in the tank portion are included, and the nozzle portion can spray the disinfectant liquid with an effective chlorine concentration of 10 ppm to 50 ppm in space spraying. It is configured in. With the above configuration, it is possible to realize spatial spraying of hypochlorite water using powder containing chlorinated isocyanuric acid, which is inexpensive and easy to manage, and it is possible to demonstrate high sterilization performance safely and inexpensively. Become.

また、本発明の第2の側面に係る空間噴霧器によれば、上記構成に加えて、さらに、前記タンク部内に保持された前記除菌液をミスト化する超音波振動子を備えており、前記ノズル部は、前記超音波振動子の振動によりミスト化された前記除菌液を噴霧するよう構成できる。 Further, according to the space atomizer according to the second aspect of the present invention, in addition to the above configuration, an ultrasonic vibrator that mistizes the disinfectant solution held in the tank portion is provided. The nozzle portion can be configured to spray the disinfectant liquid mistized by the vibration of the ultrasonic vibrator.

さらに、本発明の第3の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記タンク部内の次亜塩素酸水の濃度を10ppm〜200ppmとできる。 Further, according to the space atomizer according to the third aspect of the present invention, in addition to any of the above configurations, the concentration of hypochlorite water in the tank portion can be set to 10 ppm to 200 ppm.

さらにまた、本発明の第4の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記タンク部内の次亜塩素酸水の塩素濃度を、20%〜90%とすることができる。 Furthermore, according to the space atomizer according to the fourth aspect of the present invention, in addition to any of the above configurations, the chlorine concentration of the hypochlorite water in the tank portion can be set to 20% to 90%. can.

さらにまた、本発明の第5の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記塩素化イソシアヌル酸を、ジクロロイソシアヌル酸ナトリウム又はトリクロロイソシアヌル酸ナトリウムとすることができる。 Furthermore, according to the space atomizer according to the fifth aspect of the present invention, the chlorinated isocyanuric acid can be sodium dichloroisocyanuric acid or sodium trichloroisocyanuric acid in addition to any of the above configurations.

さらにまた、本発明の第6の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記粉体が、前記塩素化イソシアヌル酸を5%〜30%含むことができる。 Furthermore, according to the space atomizer according to the sixth aspect of the present invention, in addition to any of the above configurations, the powder can contain 5% to 30% of the chlorinated isocyanuric acid.

さらにまた、本発明の第7の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記粉体が、無機塩類を含まないものとすることができる。 Furthermore, according to the space atomizer according to the seventh aspect of the present invention, in addition to any of the above configurations, the powder can be free of inorganic salts.

さらにまた、本発明の第8の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記粉体が、さらに中性芒硝を60%〜95%含むことができる。 Furthermore, according to the space atomizer according to the eighth aspect of the present invention, in addition to any of the above configurations, the powder can further contain 60% to 95% of neutral Glauber's salt.

さらにまた、本発明の第9の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記粉体が、さらにアジピン酸を1%〜30%含むことができる。上記構成により、通常であればイソシアヌル酸の無機物残留性によって白い膜が残ることがあるところ、塩素濃度が安定されて均等にイソシアヌル酸残留物が噴霧されるので、このような残留物を低減して目立たなくできる。 Furthermore, according to the space atomizer according to the ninth aspect of the present invention, in addition to any of the above configurations, the powder can further contain 1% to 30% adipic acid. With the above configuration, a white film may normally remain due to the inorganic residue of isocyanuric acid, but the chlorine concentration is stabilized and the isocyanuric acid residue is sprayed evenly, so that such a residue is reduced. It can be made inconspicuous.

さらにまた、本発明の第10の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記タンク部を縦長に延長した形状とすることができる。 Furthermore, according to the space atomizer according to the tenth aspect of the present invention, in addition to any of the above configurations, the tank portion can be formed into a vertically elongated shape.

さらにまた、本発明の第10の側面に係る空間噴霧器用の除菌液の製造方法によれば、除菌液を保持するタンク部に、水を8割以上注水する工程と、前記水が注水されたタンク部に、塩素化イソシアヌル酸を含む粉体を、水に投入して撹拌し、有効塩素濃度が10ppm〜200ppmの除菌液を調製する工程とを含むことができる。これにより、運搬や管理の容易な粉体の塩素化イソシアヌル酸を用いて、除菌液を容易に調整できる。 Furthermore, according to the method for producing a disinfectant solution for a space sprayer according to the tenth aspect of the present invention, a step of injecting 80% or more of water into a tank portion holding the disinfectant solution and a step of injecting the water. A step of adding a powder containing chlorinated isocyanuric acid to water and stirring the mixture to prepare a sterilizing solution having an effective chlorine concentration of 10 ppm to 200 ppm can be included in the tank portion. This makes it possible to easily prepare a sterilizing solution using chlorinated isocyanuric acid, which is a powder that is easy to transport and manage.

さらにまた、本発明の第11の側面に係る空間噴霧器用の除菌液の製造方法によれば、上記に加えて、前記粉体を、マイクロテストチューブに保持することができる。これにより、塩素化イソシアヌル酸を含む粉体を、安定的に長期間保持することが可能となる。 Furthermore, according to the method for producing a disinfectant solution for a space sprayer according to the eleventh aspect of the present invention, in addition to the above, the powder can be held in a microtest tube. This makes it possible to stably hold the powder containing chlorinated isocyanuric acid for a long period of time.

さらにまた、本発明の第12の側面に係る空間噴霧器用の除菌液の製造方法によれば、上記いずれかに加えて、前記塩素化イソシアヌル酸を、ジクロロイソシアヌル酸ナトリウム又はトリクロロイソシアヌル酸ナトリウムとすることができる。 Furthermore, according to the method for producing a sterilizing solution for a space atomizer according to the twelfth aspect of the present invention, in addition to any of the above, the chlorinated isocyanuric acid is combined with sodium dichloroisocyanuric acid or sodium trichloroisocyanuric acid. can do.

実施形態1に係る空間噴霧器を示す模式断面図である。It is a schematic sectional drawing which shows the space atomizer which concerns on Embodiment 1. FIG. 実施形態2に係る空間噴霧器を示す模式断面図である。It is a schematic sectional drawing which shows the space atomizer which concerns on Embodiment 2. FIG. 実施形態3に係る空間噴霧器を示す模式断面図である。It is a schematic sectional drawing which shows the space atomizer which concerns on Embodiment 3. FIG. 図4A〜図4Cは空間噴霧器用の除菌液の製造方法を示す模式図である。4A to 4C are schematic views showing a method for producing a sterilizing solution for a space atomizer.

以下、本発明に係る実施形態及び実施例を、図面に基づいて説明する。ただし、以下に示す実施形態及び実施例は、本発明の技術思想を具体化するための例示であって、本発明は以下のものに限定されるものでない。また各図面が示す部材の大きさや位置関係等は、説明を明確にするため誇張していることがある。さらに以下の説明において、同一の名称、符号については同一もしくは同質の部材を示しており、詳細な説明を適宜省略する。また、複数の図面に表れる同一符号の部分は同一もしくは同等の部分又は部材を示す。さらに、本発明に係る実施形態及び実施例を構成する各要素は、複数の要素を同一の部材で構成して一の部材で複数の要素を兼用する態様としてもよいし、逆に一の部材の機能を複数の部材で分担して実現することもできる。また、一部の実施例、実施形態において説明された内容は、他の実施例、実施形態等に利用可能なものもある。さらに、以下の説明では、必要に応じて特定の方向や位置を示す用語(例えば、「上」、「下」、「右」、「左」および、それらの用語を含む別の用語)を用いるが、それらの用語の使用は図面を参照した発明の理解を容易にするためであって、それらの用語の意味によって本発明の技術的範囲が制限されるものではない。なお、本明細書において「備える」とは、別部材として備えるもの、一体の部材として構成するものの何れをも含む意味で使用する。
[実施形態1]
Hereinafter, embodiments and examples according to the present invention will be described with reference to the drawings. However, the embodiments and examples shown below are examples for embodying the technical idea of the present invention, and the present invention is not limited to the following. In addition, the size and positional relationship of the members shown in each drawing may be exaggerated to clarify the explanation. Further, in the following description, members of the same or the same quality are shown with the same name and reference numeral, and detailed description thereof will be omitted as appropriate. Further, the parts having the same reference numerals appearing in a plurality of drawings indicate the same or equivalent parts or members. Further, each element constituting the embodiment and the embodiment according to the present invention may be configured such that a plurality of elements are composed of the same member and the plurality of elements are combined with one member, or conversely, one member. It is also possible to share the functions of the above with a plurality of members. In addition, the contents described in some examples and embodiments can be used in other embodiments and embodiments. Further, in the following description, terms indicating a specific direction or position (for example, "top", "bottom", "right", "left", and other terms including those terms) are used as needed. However, the use of these terms is to facilitate understanding of the invention with reference to the drawings, and the meaning of those terms does not limit the technical scope of the invention. In addition, in this specification, "providing" is used in the sense of including both those provided as a separate member and those configured as an integral member.
[Embodiment 1]

本実施形態に係る空間噴霧器は、超音波加湿器や超音波噴霧器のような、超音波振動子でミスト化して噴霧する機器、あるいはスプレー式のボトルや霧吹きのような、圧縮した空気で噴霧する機器である。 The space sprayer according to the present embodiment is a device such as an ultrasonic humidifier or an ultrasonic sprayer that atomizes and sprays with an ultrasonic vibrator, or a spray-type bottle or a sprayer that sprays with compressed air. It is a device.

一例として、実施形態1に係る空間噴霧器100として超音波加湿器を図1に示す。この図に示す空間噴霧器100は、除菌液を保持するタンク部1と、このタンク部1に保持された除菌液を噴霧するノズル部2を備える。ノズル部2は、タンク部1の上方に開口して形成されている。またタンク部1の底面には、超音波振動子3が配置されている。超音波振動子は、タンク部1内に保持された前記除菌液をミスト化する。この結果、タンク部1に蓄えられた除菌液は、超音波振動子による超音波振動によって飛散または気化されて、発生した微細粒子がタンク部1の上方に設けられたノズル部2から外部に放散される。 As an example, an ultrasonic humidifier is shown in FIG. 1 as the space atomizer 100 according to the first embodiment. The space sprayer 100 shown in this figure includes a tank portion 1 that holds the sterilizing liquid and a nozzle portion 2 that sprays the sterilizing liquid held in the tank portion 1. The nozzle portion 2 is formed by opening above the tank portion 1. Further, an ultrasonic vibrator 3 is arranged on the bottom surface of the tank portion 1. The ultrasonic transducer turns the disinfectant solution held in the tank portion 1 into a mist. As a result, the disinfectant liquid stored in the tank portion 1 is scattered or vaporized by the ultrasonic vibration of the ultrasonic vibrator, and the generated fine particles are discharged from the nozzle portion 2 provided above the tank portion 1 to the outside. Be dissipated.

このような空間噴霧器100に充填する除菌液として、塩素化イソシアヌル酸を含む粉体を水に溶かした次亜塩素酸水を含むものを用いる。除菌液は、空間噴霧された状態で、空間噴霧における有効塩素濃度を10ppm〜50ppmとする。このような有効塩素濃度の除菌液を、ミスト状にしてノズル部2から放出することで、高い除菌効果を発揮できる。特に、安価で管理が容易な塩素化イソシアヌル酸を含む粉体を用いて、これを溶かして除菌液とすることで、容易に次亜塩素酸水を得ることができる。また高い除菌効果を奏する次亜塩素酸水の空間噴霧によって、ウィルス感染や拡散などの未然防止を図ることが可能となる。 As the disinfectant solution to be filled in such a space sprayer 100, a solution containing hypochlorite water in which a powder containing chlorinated isocyanuric acid is dissolved in water is used. The disinfectant solution has an effective chlorine concentration of 10 ppm to 50 ppm in the space sprayed state. By forming a sterilizing solution having such an effective chlorine concentration into a mist and discharging it from the nozzle portion 2, a high sterilizing effect can be exhibited. In particular, hypochlorite water can be easily obtained by using a powder containing chlorinated isocyanuric acid, which is inexpensive and easy to manage, and dissolving it to prepare a sterilizing solution. In addition, spatial spraying of hypochlorite water, which has a high sterilizing effect, makes it possible to prevent virus infection and diffusion.

タンク部1内の次亜塩素酸水の濃度は、10ppm〜200ppmとすることが好ましい。これによって十分な除菌効果を発揮できる。またタンク部1内の次亜塩素酸水の塩素濃度は、20%〜90%とすることが好ましい。 The concentration of hypochlorite water in the tank portion 1 is preferably 10 ppm to 200 ppm. As a result, a sufficient sterilizing effect can be exhibited. The chlorine concentration of the hypochlorite water in the tank portion 1 is preferably 20% to 90%.

また塩素化イソシアヌル酸は、ジクロロイソシアヌル酸ナトリウム又はトリクロロイソシアヌル酸ナトリウムが利用できる。特にジクロロイソシアヌル酸ナトリウムは入手が容易で安価であり、除菌剤として使用実績もあることから好ましい。 Further, as the chlorinated isocyanuric acid, sodium dichloroisocyanurate or sodium trichloroisocyanurate can be used. In particular, sodium dichloroisocyanurate is preferable because it is easily available, inexpensive, and has been used as a disinfectant.

このような塩素化イソシアヌル酸は、粉体状のものを用いる。粉体状の塩素化イソシアヌル酸は、水道水などに溶かして容易に次亜塩素酸水を得ることができる。次亜塩素酸水の製造方法としては、従来より塩化ナトリウム水溶液の電気分解が知られているが、この方法では製造が面倒な上、高コストという問題があった。また液体の次亜塩素酸水は嵩張り重いため、その運搬コストや管理コストも高騰する。 As such chlorinated isocyanuric acid, a powdery one is used. The powdered chlorinated isocyanuric acid can be easily obtained as hypochlorite water by dissolving it in tap water or the like. As a method for producing hypochlorite water, electrolysis of an aqueous solution of sodium chloride has been conventionally known, but this method has problems that the production is troublesome and the cost is high. In addition, since liquid hypochlorous acid water is bulky and heavy, its transportation cost and management cost also rise.

そこで、粉体状のジクロロイソシアヌル酸ナトリウムなどの塩素化イソシアヌル酸を用いて、これを加水分解することで、安価にかつ簡便に次亜塩素酸水を調製することを実現している。この方法であれば、粉体の状態で維持管理できるので、液体の次亜塩素酸水と比べ、体積及び重量を劇的に極小化できる。また、管理や運搬コストも大幅に削減できる。加えて、液体の次亜塩素酸水は分解されやすく、長期保存が困難であったが、粉体の塩素化イソシアヌル酸であれば、その特性を維持したまま長期保存することができる利点も得られる。なお、一度加水分解すれば、一般の次亜塩素酸水と同様、長期保存はできないが、使用前に、すなわち空間噴霧器100に除菌液を充填する直前に水に溶かすようにすることで、除菌液を使い切ることができるので、この問題を回避できる。 Therefore, by using chlorinated isocyanuric acid such as powdered sodium dichloroisocyanurate and hydrolyzing it, it has been realized that hypochlorite water can be prepared inexpensively and easily. With this method, maintenance can be performed in the form of powder, so the volume and weight can be dramatically minimized as compared with liquid hypochlorite water. In addition, management and transportation costs can be significantly reduced. In addition, liquid hypochlorite water is easily decomposed and difficult to store for a long period of time, but powdered chlorinated isocyanuric acid has the advantage of being able to be stored for a long period of time while maintaining its characteristics. Be done. Once hydrolyzed, it cannot be stored for a long period of time like general hypochlorite water, but by dissolving it in water before use, that is, immediately before filling the space sprayer 100 with the disinfectant solution. This problem can be avoided because the disinfectant solution can be used up.

粉体は、粒径が小さいほど比表面積が大きくなり、溶解されやすくなるため好ましい。ただ粒径が小さくなりすぎると、僅かな風でも巻き上がりやすくなり、水を満たしたタンク部に溶融させる際、風で飛ばされて入れにくくなる。このため、顆粒程度の、ある程度の大きさとすることでハンドリング性を向上できる。なお本明細書において粉体とは、粒径のサイズを規定するものでなく、粉状の他、粒状や顆粒状の形態を含む意味で使用する。 The smaller the particle size of the powder, the larger the specific surface area and the easier it is to dissolve, which is preferable. However, if the particle size is too small, it will easily wind up even with a slight wind, and when it is melted in a tank filled with water, it will be blown away by the wind and difficult to put in. Therefore, the handleability can be improved by setting the size to a certain extent, which is about the size of granules. In the present specification, the term "powder" does not specify the size of the particle size, but is used in the sense of including a granular or granular form in addition to the powder form.

粉体は、塩素化イソシアヌル酸を5%〜30%、中性芒硝を60%〜95%含むことが好ましい。塩素化イソシアヌル酸に加えて中性芒硝を増量剤として添加することで、粉体を適度に増量してハンドリング性を高めることができる。 The powder preferably contains 5% to 30% of chlorinated isocyanuric acid and 60% to 95% of neutral Glauber's salt. By adding neutral Glauber's salt as a bulking agent in addition to chlorinated isocyanuric acid, the amount of powder can be appropriately increased and the handleability can be improved.

中性芒硝は、塩素化イソシアヌル酸に対し不活性な無機塩が好ましい。塩素化イソシアヌル酸の活性塩素の低減を避けるためには、有機物を含まないことが望ましい。さらに水溶性無機塩がより好ましい。水溶性無機塩としては、中性から弱酸性領域(pH4〜7)において可溶性の高い無機塩であることが必要である。この点からは、硫酸ナトリウム(Na2SO4)が好ましい。水溶液が中性(pH7)であり、増量剤として使用しても、塩素化イソシアヌル酸のpHのみに注目しておけば良く、利便性が高いからである。また、塩素化イソシアヌル酸の水溶液における活性塩素の殺菌力は、主に次亜塩素酸の酸化力によるものであり、水溶液が弱酸性(pH4〜6)の場合に次亜塩素酸の存在割合は高くなるため、殺菌効力も高くなる。水溶液が強酸性(pH4未満)の場合には塩素ガスが発生する可能性があるため、酸化力の高い硫酸ナトリウムが好適に利用できる。 The neutral Glauber's salt is preferably an inorganic salt that is inert to the chlorinated isocyanuric acid. In order to avoid the reduction of active chlorine in chlorinated isocyanuric acid, it is desirable that it does not contain organic substances. Further, a water-soluble inorganic salt is more preferable. The water-soluble inorganic salt needs to be a highly soluble inorganic salt in the neutral to weakly acidic region (pH 4 to 7). From this point, sodium sulfate (Na 2 SO 4 ) is preferable. This is because the aqueous solution is neutral (pH 7), and even if it is used as a bulking agent, it is only necessary to pay attention to the pH of the chlorinated isocyanuric acid, which is highly convenient. The bactericidal activity of active chlorine in an aqueous solution of chlorinated isocyanuric acid is mainly due to the oxidizing power of hypochlorous acid, and when the aqueous solution is weakly acidic (pH 4 to 6), the abundance ratio of hypochlorous acid is. As it becomes higher, the bactericidal efficacy also becomes higher. When the aqueous solution is strongly acidic (pH less than 4), chlorine gas may be generated, so sodium sulfate having high oxidizing power can be preferably used.

また粉体は、さらにアジピン酸を1%〜30%含むことが好ましい。例えばタンク部1が図1に示すように縦長の場合は、深さ方向の水圧の変化等の影響により、タンク部1内の塩素濃度を一定に保ちにくくなる。そこで、アジピン酸を添加することで塩素化イソシアヌル酸が溶解されやすくなり、除菌液の濃度を均一化できる。この結果、塩素濃度が安定化されて均等にイソシアヌル酸残留物が噴霧される。なお塩素化イソシアヌル酸が均一に溶解されずに残った場合、噴霧後に無機物残留性によって白い膜が残ることがあるが、アジピン酸の添加によって残留物の発生の低減を図ることが可能となる。
[実施形態2]
Further, the powder preferably further contains 1% to 30% of adipic acid. For example, when the tank portion 1 is vertically long as shown in FIG. 1, it becomes difficult to keep the chlorine concentration in the tank portion 1 constant due to the influence of changes in water pressure in the depth direction and the like. Therefore, by adding adipic acid, the chlorinated isocyanuric acid is easily dissolved, and the concentration of the sterilizing solution can be made uniform. As a result, the chlorine concentration is stabilized and the isocyanuric acid residue is evenly sprayed. If the chlorinated isocyanuric acid remains undissolved, a white film may remain due to the residual inorganic substance after spraying, but the addition of adipic acid makes it possible to reduce the generation of the residue.
[Embodiment 2]

以上の実施形態1では、空間噴霧器100として超音波加湿器を用いた例を説明したが、本発明は除菌液を噴霧する空間噴霧器を超音波加湿器や超音波噴霧器に限定するものでなく、他の空間噴霧器、例えば電気を使用しない手動で噴霧するスプレーボトルや霧吹きのようなものにも適用できる。ここで実施形態2に係る空間噴霧器200として、スプレーボトルに適用した例を、図2に基づいて説明する。この図に示すスプレーボトルも、ボトル型のタンク部1と、その開口端を閉塞するノズル部2を備える。またスプレーボトルには、塩素化イソシアヌル酸を含む粉体を収納する粉体収納容器4が添付される。粉体収納容器4には、ポリプロピレン製のマイクロテストチューブ等が利用できる。これにより、塩素化イソシアヌル酸を含む粉体を、安定的に長期間保持することが可能となる。 In the above-mentioned first embodiment, an example in which an ultrasonic humidifier is used as the space sprayer 100 has been described, but the present invention does not limit the space sprayer that sprays the disinfectant solution to the ultrasonic humidifier or the ultrasonic sprayer. It can also be applied to other space atomizers, such as spray bottles and sprayers that do not use electricity and spray manually. Here, an example applied to a spray bottle as the space sprayer 200 according to the second embodiment will be described with reference to FIG. The spray bottle shown in this figure also includes a bottle-shaped tank portion 1 and a nozzle portion 2 that closes the open end thereof. Further, a powder storage container 4 for storing powder containing chlorinated isocyanuric acid is attached to the spray bottle. As the powder storage container 4, a polypropylene microtest tube or the like can be used. This makes it possible to stably hold the powder containing chlorinated isocyanuric acid for a long period of time.

タンク部1は、不透明な樹脂製とすることが好ましい。特に塩素化イソシアヌル酸は、紫外線で分解が加速し、濃度維持が難しいことから、透明でない着色された樹脂製とすることで、このような劣化を抑制できる。この結果、タンク部1は内部の除菌液が不可視な状態となる。 The tank portion 1 is preferably made of an opaque resin. In particular, chlorinated isocyanuric acid is decomposed by ultraviolet rays and it is difficult to maintain its concentration. Therefore, by using a non-transparent colored resin, such deterioration can be suppressed. As a result, the sterilizing liquid inside the tank portion 1 becomes invisible.

図2のスプレーボトルは、除菌液を収容するタンク部1と、タンク部1の口頚部に嵌合される装着筒と、この装着筒から起立された垂直筒と、この垂直筒の上端部から前方へ突出された射出筒と、この垂直筒の中間部から前方へ突出されたシリンダと、このシリンダ内に摺動可能に嵌合され、前方に付勢されているプランジャと、その上部後面がこのプランジャの前端部に係合し、射出筒の前部に揺動可能に取り付けられたトリガーと、前記筒の前端部に取り付けられたノズル部嵌合筒と、ノズル部孔が形成され、ノズル部嵌合筒の外面に回動可能に取り付けられノズル部2の所定位置では霧状の噴霧が、別の所定位置ではストレートな液流が、それぞれ切り替え可能なノズル部ヘッドとを備える。トリガーを後方に引くことによって、タンク部1に貯蔵された塩素を含む内溶液が吸い上げられ、ノズル部孔を通して噴出される。ノズル部ヘッドの回動により噴出する液体の状態を変えられるので、集中的に殺菌したいときはストレートな液流で、広範囲に殺菌したいときには霧状の液を吹き付けることができ、シーンに応じて使い分けができる。
[実施形態3]
The spray bottle of FIG. 2 has a tank portion 1 for accommodating a disinfectant solution, a mounting cylinder fitted to the mouth and neck of the tank portion 1, a vertical cylinder standing up from the mounting cylinder, and an upper end portion of the vertical cylinder. An injection cylinder protruding forward from, a cylinder protruding forward from the middle part of this vertical cylinder, a plunger slidably fitted in this cylinder and urged forward, and its upper rear surface. Engages with the front end of this plunger to form a trigger swingably attached to the front of the injection tube, a nozzle fitting tube attached to the front end of the tube, and a nozzle hole. It is provided with a nozzle portion head that is rotatably attached to the outer surface of the nozzle portion fitting cylinder and can switch between a mist-like spray at a predetermined position of the nozzle portion 2 and a straight liquid flow at another predetermined position. By pulling the trigger backward, the internal solution containing chlorine stored in the tank portion 1 is sucked up and ejected through the nozzle portion hole. Since the state of the ejected liquid can be changed by rotating the nozzle head, a straight liquid flow can be used when sterilizing intensively, and a mist-like liquid can be sprayed when sterilizing over a wide area. Can be done.
[Embodiment 3]

なおスプレーボトルは、図2に示したようなトリガを備えるピストル式のタイプに限られず、図3に示す実施形態3に係る空間噴霧器300のようなプッシュ式のタイプを用いてもよいことはいうまでもない。このタイプの空間噴霧器300はフィンガースプレー容器等と呼ばれ、除菌液を収容するタンク部1と、タンク部1の開口部から上方付勢状態で上下動可能に起立されたノズル部2と、ノズル部2の上下動に連係して作動するポンプ機構を有する。ノズル部2の基端側にその径方向外側を向けて拡張された押下げ部を指で押下げることにより、ポンプ機構の作用でタンク部1内の除菌液がノズル部2の先端から噴出されるよう構成されている。このような容器は、全体の大きさをコンパクトにすることができ、携帯用に便利である。
(空間噴霧器用の除菌液の製造方法)
The spray bottle is not limited to the pistol type having a trigger as shown in FIG. 2, and a push type such as the space sprayer 300 according to the third embodiment shown in FIG. 3 may be used. Not to mention. This type of space sprayer 300 is called a finger spray container or the like, and has a tank portion 1 for accommodating a disinfectant solution, a nozzle portion 2 standing upright from the opening of the tank portion 1 in an upwardly urged state, and a nozzle portion 2. It has a pump mechanism that operates in conjunction with the vertical movement of the nozzle portion 2. By pushing down the push-down part that is expanded toward the base end side of the nozzle part 2 in the radial direction with a finger, the disinfectant liquid in the tank part 1 is ejected from the tip of the nozzle part 2 by the action of the pump mechanism. It is configured to be. Such a container can be made compact in overall size and is convenient to carry.
(Manufacturing method of disinfectant for space atomizer)

ここで、空間噴霧器用の除菌液の製造方法を、図4A〜図4Bに基づいて説明する。 Here, a method for producing a sterilizing solution for a space atomizer will be described with reference to FIGS. 4A to 4B.

まず、図4Aに示すように除菌液を保持するタンク部1に、水を注水する。例えばタンク部1の内容積の8割以上に水道水を充填する。注水には、水道の蛇口から直接注水してもよいし、また一端コップなどに水を溜めた上で、タンク部1に移し替えるようにしてもよい。 First, as shown in FIG. 4A, water is injected into the tank portion 1 that holds the sterilizing liquid. For example, tap water is filled in 80% or more of the internal volume of the tank portion 1. Water may be injected directly from the faucet of the water supply, or water may be once stored in a cup or the like and then transferred to the tank portion 1.

次に、図4Bに示すように、水が注水されたタンク部1に、塩素化イソシアヌル酸を含む粉体を、水に投入する。このとき、粉体を水に溶かして得られる除菌液の有効塩素濃度が10ppm〜200ppmとなるように、予め粉体の分量を調整しておく。ここでは、タンク部1の内容積に応じて、所望の濃度となるように、予め粉体の量を計算し、これに応じた分量を、粉体収納容器4に充填しておく。これにより、使用者が一々粉体を計量しなくても、スプレーボトル一本分に小分けされた粉体をそのまま粉体収納容器4から投入することで、必要な分量に調整することが可能となる。 Next, as shown in FIG. 4B, the powder containing chlorinated isocyanuric acid is put into water in the tank portion 1 into which water has been injected. At this time, the amount of the powder is adjusted in advance so that the effective chlorine concentration of the disinfectant solution obtained by dissolving the powder in water is 10 ppm to 200 ppm. Here, the amount of powder is calculated in advance so as to have a desired concentration according to the internal volume of the tank portion 1, and the corresponding amount is filled in the powder storage container 4. This makes it possible to adjust the amount to the required amount by directly charging the powder divided into one spray bottle from the powder storage container 4 without the user having to weigh the powder one by one. Become.

ここで、先にタンク内に粉体を投入しておき、次いで水を注水せず、予めタンク内に注水した状態で粉体を投入することで、粉体の溶解を確実に行わしめる効果が得られる。一般に、粉体の溶融に際しては先に粉体を投入してから、水を注水することで撹拌効果を発揮させることが行われている。しかしながら、塩素化イソシアヌル酸の場合は、先に塩素化イソシアヌル酸をタンク内に投入すると、条件によっては溶解が不十分であることが本発明者の試験により判明した。特に、空間噴霧器の場合は、頻繁に水を充填することが必要とされる。例えば図2や図3のようなスプレーボトルの場合、除菌液を補充して再利用できるものがあり、この場合に除菌液がなくなると、新たに水と粉体を混合する必要が生じる。ここで、タンク部の内部が完全に乾燥している場合は問題が少ないものの、多くの場合はスプレー機構の構造上、タンク部内の除菌液を完全に使い切ることができず、一部が残った状態で除菌液の補充が必要となるケースが多い。 Here, by putting the powder in the tank first and then putting the powder in the state where the water is poured into the tank in advance without pouring water, the effect of surely dissolving the powder is obtained. can get. Generally, when the powder is melted, the stirring effect is exhibited by first adding the powder and then injecting water. However, in the case of chlorinated isocyanuric acid, it was found by the test of the present inventor that if chlorinated isocyanuric acid was first put into the tank, the dissolution was insufficient depending on the conditions. In particular, in the case of a space atomizer, it is necessary to fill it with water frequently. For example, in the case of a spray bottle as shown in FIGS. 2 and 3, there are some that can be replenished with a disinfectant solution and reused. In this case, when the disinfectant solution runs out, it becomes necessary to newly mix water and powder. .. Here, although there are few problems when the inside of the tank part is completely dry, in many cases, due to the structure of the spray mechanism, the disinfectant solution in the tank part cannot be completely used up, and a part remains. In many cases, it is necessary to replenish the disinfectant solution in this state.

しかしながら、除菌液が少し残った状態で粉体を投入してしまうと、この僅かな水分によって塩素化イソシアヌル酸を含む粉体が部分的に溶融して、凝固してしまうことがある。一度凝固してしまうと、水を加えても、溶けにくい塊が残った状態となり、均一な状態に溶解させることが困難となり、有効塩素濃度を均一にすることが困難となる。 However, if the powder is added with a small amount of the disinfectant remaining, the powder containing chlorinated isocyanuric acid may be partially melted and solidified due to this slight amount of water. Once solidified, even if water is added, a lump that is difficult to dissolve remains, making it difficult to dissolve in a uniform state, and making it difficult to make the effective chlorine concentration uniform.

また、この問題は図1で示した電動式の空間噴霧器100においても生じる。空間噴霧器を設置した部屋の広さや空間噴霧器のタンク容量等にも依存するが、冬場の乾燥時などにおいては一日に複数回、水を補給する必要が生じることも珍しくない。このような状況において、空間噴霧器に設けられた給水ランプが点灯しても、水が僅かにタンク内に残っている事態が同様に発生する。この状態で粉体を投入すると、同様に固まりの発生する事態を引き起こすことになる。 This problem also occurs in the electric space atomizer 100 shown in FIG. Although it depends on the size of the room where the space atomizer is installed and the tank capacity of the space atomizer, it is not uncommon to need to replenish water multiple times a day when it is dry in winter. In such a situation, even if the water supply lamp provided in the space atomizer is turned on, a situation in which a small amount of water remains in the tank also occurs. If powder is added in this state, it will cause a situation where lumps are generated as well.

さらに、タンク部の内部が完全に乾燥している場合には、先に粉体を投入しても部分的な溶解は生じ難いものの、別の問題が生じることがある。すなわち、図4Aに示すように水道の蛇口から勢いよく水を注水すると、その勢いで粉体が飛び散ってしまうことが考えられる。特に、上述の通り除菌液の劣化を防ぐため、タンク部を不透明な材質で構成した場合、タンク内の様子を外部から視認できないことから、粉体の飛散を防ぐためゆっくりと注水する等、注意して作業を行う必要が生じる。 Further, when the inside of the tank portion is completely dried, even if the powder is charged first, partial dissolution is unlikely to occur, but another problem may occur. That is, as shown in FIG. 4A, when water is poured vigorously from the faucet of the water supply, it is conceivable that the powder is scattered by the force. In particular, as described above, when the tank is made of an opaque material to prevent deterioration of the disinfectant, the inside of the tank cannot be seen from the outside, so water is slowly injected to prevent the powder from scattering. Careful work will be required.

加えて、勢いよく注水すると外部から視認できないことから、水が溢れてしまうことがある。この場合に、粉体の一部が漏れ出して、有効塩素濃度を上述した範囲に維持できなくなることが考えられる。 In addition, if water is poured vigorously, the water may overflow because it cannot be seen from the outside. In this case, it is conceivable that a part of the powder leaks out and the effective chlorine concentration cannot be maintained within the above range.

このような事態を防ぐため、本実施形態においては、敢えて先に水を充填した上で、粉体を投入する手順を採用する。この方法であれば、少量の水で粉体が固まってしまう事態を回避できる。また、先に水を注水するため、仮に水が溢れても水が失われるだけで、有効塩素濃度には影響を与えない。また、タンク部1への給水時に、粉体の舞い上がり等を気にせず、勢いよく注水することができるため、使い勝手が向上される。 In order to prevent such a situation, in the present embodiment, a procedure is adopted in which water is intentionally filled first and then the powder is added. With this method, it is possible to avoid the situation where the powder is solidified with a small amount of water. In addition, since water is injected first, even if the water overflows, only the water is lost and the effective chlorine concentration is not affected. Further, when water is supplied to the tank portion 1, the water can be injected vigorously without worrying about the powder flying up, so that the usability is improved.

以上のようにしてタンク部1内に水と粉体を投入した後、図4Cに示すように撹拌して、タンク部1内で水と粉体が均一に混ざった除菌液を調製する。ここで、撹拌しやすいようにタンク部1内の水は、上述の通り8割程度に抑制することが好ましい。 After the water and the powder are put into the tank portion 1 as described above, the mixture is stirred as shown in FIG. 4C to prepare a sterilizing liquid in which the water and the powder are uniformly mixed in the tank portion 1. Here, it is preferable to suppress the water in the tank portion 1 to about 80% as described above so that the stirring can be easily performed.

このようにして、運搬や管理の容易な粉体の塩素化イソシアヌル酸を用いて、除菌液を容易に調整できる。また、タンクへの投入の順序を規定するという極めて簡単な手法で、塩素化イソシアヌル酸を均一に溶融させる効果を得られる。 In this way, the disinfectant solution can be easily prepared by using the chlorinated isocyanuric acid, which is a powder that is easy to transport and manage. In addition, the effect of uniformly melting the chlorinated isocyanuric acid can be obtained by a very simple method of defining the order of charging into the tank.

なお、上述した粉体は、無機塩類を含んでいる。ただ粉体が、無機塩類を含まないこともできる。無機塩類を含まない場合は、タンク部1に先にジクロロイソシアヌル酸ナトリウムを含む粉体を入れた後に水を入れても、粉体が凝固しないので、使い勝手が向上する。 The above-mentioned powder contains inorganic salts. However, the powder may not contain inorganic salts. When the tank portion 1 does not contain inorganic salts, the powder does not solidify even if water is added after the powder containing sodium dichloroisocyanurate is added to the tank portion 1, so that the usability is improved.

本開示の空間噴霧器及び空間噴霧器用の除菌液の製造方法は、超音波加湿器や超音波噴霧器のような、超音波振動子でミスト化して噴霧する機器、あるいはスプレー式のボトルや霧吹きのような、圧縮した空気で吹き出す機器に充填する除菌液として、好適に利用できる。例えば家庭用や、レストラン、会議室などに設置する加湿器、あるいは施設の入口などに設置する手動式のボトル等に利用して、新型コロナウィルス等の消毒に利用できる。また除菌や滅菌に限らず、消臭にも利用できる。 The method for producing the disinfectant solution for the space atomizer and the space atomizer of the present disclosure is a device such as an ultrasonic humidifier or an ultrasonic atomizer that atomizes and sprays with an ultrasonic vibrator, or a spray-type bottle or a sprayer. It can be suitably used as a disinfectant solution to be filled in a device that blows out with compressed air. For example, it can be used for home use, a humidifier installed in a restaurant, a conference room, or a manual bottle installed at the entrance of a facility, and can be used for disinfecting a new type of coronavirus or the like. It can be used not only for sterilization and sterilization but also for deodorization.

100、200、300…空間噴霧器
1…タンク部
2…ノズル部
3…超音波振動子
4…粉体収納容器
100, 200, 300 ... Spatial atomizer 1 ... Tank part 2 ... Nozzle part 3 ... Ultrasonic oscillator 4 ... Powder storage container

本発明の第1の側面に係る空間噴霧器によれば、除菌用の空間噴霧器であって、塩素化イソシアヌル酸を含む粉体を水に溶かした次亜塩素酸水を含む除菌液を保持するタンク部と、前記タンク部内に保持された前記除菌液を噴霧するノズル部と、を含み、前記ノズル部は、前記除菌液を、空間噴霧における有効塩素濃度を10ppm〜50ppmとして噴霧可能に構成しており、前記粉体中に、中性芒硝を重量比で60%〜95%含んでいる。上記構成により、安価で管理が容易な塩素化イソシアヌル酸を含む粉体を用いて、次亜塩素酸水の空間噴霧を実現でき、高い除菌性能を安全にかつ安価に発揮させることが可能となる。
According to the space sprayer according to the first aspect of the present invention, it is a space sprayer for sterilization and holds a sterilizing solution containing hypochlorite water in which a powder containing chlorinated isocyanuric acid is dissolved in water. A tank portion to be sprayed and a nozzle portion for spraying the disinfectant liquid held in the tank portion are included, and the nozzle portion can spray the disinfectant liquid with an effective chlorine concentration of 10 ppm to 50 ppm in space spraying. The powder contains 60% to 95% of neutral spray bottle by weight . With the above configuration, it is possible to realize spatial spraying of hypochlorite water using powder containing chlorinated isocyanuric acid, which is inexpensive and easy to manage, and it is possible to demonstrate high sterilization performance safely and inexpensively. Become.

さらにまた、本発明の第の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記粉体が、さらにアジピン酸を1%〜30%含むことができる。上記構成により、通常であればイソシアヌル酸の無機物残留性によって白い膜が残ることがあるところ、塩素濃度が安定されて均等にイソシアヌル酸残留物が噴霧されるので、このような残留物を低減して目立たなくできる。
Furthermore, according to the space atomizer according to the seventh aspect of the present invention, in addition to any of the above configurations, the powder can further contain 1% to 30% adipic acid. With the above configuration, a white film may normally remain due to the inorganic residue of isocyanuric acid, but the chlorine concentration is stabilized and the isocyanuric acid residue is sprayed evenly, so that such a residue is reduced. It can be made inconspicuous.

さらにまた、本発明の第の側面に係る空間噴霧器によれば、上記いずれかの構成に加えて、前記タンク部を鉛直方向において縦長に延長した形状とすることができる。
Furthermore, according to the space atomizer according to the eighth aspect of the present invention, in addition to any of the above configurations, the tank portion can be vertically extended in the vertical direction.

さらにまた、本発明の第の側面に係る空間噴霧器用の除菌液の製造方法によれば、除菌液を保持するタンク部に、水注水する工程と、前記水が注水されたタンク部に、塩素化イソシアヌル酸と、中性芒硝を重量比で60%〜95%含む粉体を、水に投入して撹拌し、有効塩素濃度が10ppm〜200ppmの除菌液を調製する工程とを含むことができる。これにより、運搬や管理の容易な粉体の塩素化イソシアヌル酸を用いて、除菌液を容易に調整できる。
Furthermore, according to the method for producing a disinfectant solution for a space sprayer according to the ninth aspect of the present invention, a step of injecting water into a tank portion holding the disinfectant solution and a tank in which the water is injected. A step of preparing a sterilizing solution having an effective chlorine concentration of 10 ppm to 200 ppm by adding chlorinated isocyanuric acid and a powder containing 60% to 95% of neutral glass in a weight ratio to water and stirring the mixture. Can be included. This makes it possible to easily prepare a sterilizing solution using chlorinated isocyanuric acid, which is a powder that is easy to transport and manage.

さらにまた、本発明の第10の側面に係る空間噴霧器用の除菌液の製造方法によれば、上記に加えて、前記粉体を、マイクロテストチューブに保持することができる。これにより、塩素化イソシアヌル酸を含む粉体を、安定的に長期間保持することが可能となる。
Furthermore, according to the method for producing a disinfectant solution for a space sprayer according to the tenth aspect of the present invention, in addition to the above, the powder can be held in a microtest tube. This makes it possible to stably hold the powder containing chlorinated isocyanuric acid for a long period of time.

さらにまた、本発明の第11の側面に係る空間噴霧器用の除菌液の製造方法によれば、上記いずれかに加えて、前記塩素化イソシアヌル酸を、ジクロロイソシアヌル酸ナトリウム又はトリクロロイソシアヌル酸ナトリウムとすることができる。 Furthermore, according to the method for producing a sterilizing solution for a space atomizer according to the eleventh aspect of the present invention, in addition to any of the above, the chlorinated isocyanuric acid is combined with sodium dichloroisocyanuric acid or sodium trichloroisocyanuric acid. can do.

本発明の第1の側面に係る空間噴霧器によれば、除菌用の空間噴霧器であって、塩素化イソシアヌル酸を含む粉体を水に溶かした次亜塩素酸水を含む除菌液を保持するタンク部と、前記タンク部内に保持された前記除菌液を噴霧するノズル部と、を含み、前記ノズル部は、前記除菌液を、空間噴霧における有効塩素濃度を10ppmより高く50ppm未満として噴霧可能に構成しており、前記粉体中に、中性芒硝を重量比で60%〜95%含んでいる。上記構成により、安価で管理が容易な塩素化イソシアヌル酸を含む粉体を用いて、次亜塩素酸水の空間噴霧を実現でき、高い除菌性能を安全にかつ安価に発揮させることが可能となる。
According to the space sprayer according to the first aspect of the present invention, it is a space sprayer for sterilization and holds a sterilizing solution containing hypochlorite water in which a powder containing chlorinated isocyanuric acid is dissolved in water. A tank portion to be sprayed and a nozzle portion for spraying the disinfectant liquid held in the tank portion are included, and the nozzle portion sets the disinfectant liquid to have an effective chlorine concentration of more than 10 ppm and less than 50 ppm in the space spray. It is configured to be sprayable, and the powder contains 60% to 95% of neutral nozzle by weight. With the above configuration, it is possible to realize spatial spraying of hypochlorite water using powder containing chlorinated isocyanuric acid, which is inexpensive and easy to manage, and it is possible to demonstrate high sterilization performance safely and inexpensively. Become.

さらにまた、本発明の第9の側面に係る空間噴霧器用の除菌液の製造方法によれば、除菌液を保持するタンク部に、水を注水する工程と、前記水が注水されたタンク部に、塩素化イソシアヌル酸と、中性芒硝を重量比で60%〜95%含む粉体を、水に投入して撹拌し、前記タンク部内の次亜塩素酸水の濃度が10ppm〜200ppmで、空間噴霧時における有効塩素濃度を10ppmより高く50ppm未満とする除菌液を調製する工程とを含むことができる。これにより、運搬や管理の容易な粉体の塩素化イソシアヌル酸を用いて、除菌液を容易に調整できる。 Furthermore, according to the method for producing a sterilizing liquid for a space atomizer according to the ninth aspect of the present invention, a step of injecting water into a tank portion holding the sterilizing liquid and a tank in which the water is injected. A powder containing chlorinated isocyanuric acid and neutral glazed glass in a weight ratio of 60% to 95% was put into water and stirred, and the concentration of hypochlorite water in the tank part was 10 ppm to 200 ppm . , A step of preparing a sterilizing solution having an effective chlorine concentration of more than 10 ppm and less than 50 ppm at the time of spatial spraying can be included. This makes it possible to easily prepare a sterilizing solution using chlorinated isocyanuric acid, which is a powder that is easy to transport and manage.

Claims (13)

除菌用の空間噴霧器であって、
塩素化イソシアヌル酸を含む粉体を水に溶かした次亜塩素酸水を含む除菌液を保持するタンク部と、
前記タンク部内に保持された前記除菌液を噴霧するノズル部と、
を含み、
前記ノズル部は、前記除菌液を、空間噴霧における有効塩素濃度を10ppm〜50ppmとして噴霧可能に構成してなる空間噴霧器。
A space sprayer for sterilization,
The tank part that holds the disinfectant solution containing hypochlorite water in which powder containing chlorinated isocyanuric acid is dissolved in water, and
A nozzle portion that sprays the disinfectant liquid held in the tank portion, and a nozzle portion.
Including
The nozzle portion is a space sprayer configured to be capable of spraying the disinfectant solution with an effective chlorine concentration of 10 ppm to 50 ppm in space spraying.
請求項1に記載の空間噴霧器であって、さらに、
前記タンク部内に保持された前記除菌液をミスト化する超音波振動子を備えており、
前記ノズル部は、前記超音波振動子の振動によりミスト化された前記除菌液を噴霧するよう構成してなる空間噴霧器。
The space atomizer according to claim 1, further
It is equipped with an ultrasonic vibrator that mistizes the sterilizing liquid held in the tank portion.
The nozzle portion is a space sprayer configured to spray the disinfectant liquid mistized by the vibration of the ultrasonic vibrator.
請求項1又は2に記載の空間噴霧器であって、
前記タンク部内の次亜塩素酸水の濃度が10ppm〜200ppmである空間噴霧器。
The space atomizer according to claim 1 or 2.
A space atomizer having a concentration of hypochlorite water in the tank portion of 10 ppm to 200 ppm.
請求項1〜3のいずれか一項に記載の空間噴霧器であって、
前記タンク部内の次亜塩素酸水の塩素濃度が、20%〜90%である空間噴霧器。
The space atomizer according to any one of claims 1 to 3.
A space atomizer in which the chlorine concentration of the hypochlorite water in the tank portion is 20% to 90%.
請求項1〜4のいずれか一項に記載の空間噴霧器であって、
前記塩素化イソシアヌル酸が、ジクロロイソシアヌル酸ナトリウム又はトリクロロイソシアヌル酸ナトリウムである空間噴霧器。
The space atomizer according to any one of claims 1 to 4.
A space atomizer in which the chlorinated isocyanuric acid is sodium dichloroisocyanuric acid or sodium trichloroisocyanuric acid.
請求項1〜5のいずれか一項に記載の空間噴霧器であって、
前記粉体が、前記塩素化イソシアヌル酸を5%〜30%含んでなる空間噴霧器。
The space atomizer according to any one of claims 1 to 5.
A space atomizer in which the powder contains 5% to 30% of the chlorinated isocyanuric acid.
請求項1〜6のいずれか一項に記載の空間噴霧器であって、
前記粉体が、無機塩類を含まない空間噴霧器。
The space atomizer according to any one of claims 1 to 6.
A space atomizer in which the powder does not contain inorganic salts.
請求項1〜7のいずれか一項に記載の空間噴霧器であって、
前記粉体が、さらに中性芒硝を60%〜95%含んでなる空間噴霧器。
The space atomizer according to any one of claims 1 to 7.
A space atomizer in which the powder further contains 60% to 95% of neutral Glauber's salt.
請求項1〜8のいずれか一項に記載の空間噴霧器であって、
前記粉体が、さらにアジピン酸を1%〜30%含んでなる空間噴霧器。
The space atomizer according to any one of claims 1 to 8.
A space atomizer in which the powder further contains 1% to 30% of adipic acid.
請求項9に記載の空間噴霧器であって、
前記タンク部が縦長に延長されてなる空間噴霧器。
The space atomizer according to claim 9.
A space atomizer in which the tank portion is vertically extended.
空間噴霧器用の除菌液の製造方法であって、
除菌液を保持するタンク部に、水を8割以上注水する工程と、
前記水が注水されたタンク部に、塩素化イソシアヌル酸を含む粉体を、水に投入して撹拌し、有効塩素濃度が10ppm〜200ppmの除菌液を調製する工程と
を含む空間噴霧器用の除菌液の製造方法。
It is a method of manufacturing a disinfectant solution for a space atomizer.
The process of injecting 80% or more of water into the tank that holds the disinfectant solution,
For a space sprayer including a step of adding a powder containing chlorinated isocyanuric acid to the tank portion into which the water is injected and stirring the mixture to prepare a sterilizing solution having an effective chlorine concentration of 10 ppm to 200 ppm. A method for producing a disinfectant solution.
請求項11に記載の空間噴霧器用の除菌液の製造方法であって、
前記粉体が、マイクロテストチューブに保持されてなる空間噴霧器用の除菌液の製造方法。
The method for producing a sterilizing solution for a space atomizer according to claim 11.
A method for producing a disinfectant solution for a space sprayer in which the powder is held in a microtest tube.
請求項11又は12に記載の空間噴霧器用の除菌液の製造方法であって、
前記塩素化イソシアヌル酸が、ジクロロイソシアヌル酸ナトリウム又はトリクロロイソシアヌル酸ナトリウムである空間噴霧器用の除菌液の製造方法。
The method for producing a sterilizing solution for a space atomizer according to claim 11 or 12.
A method for producing a sterilizing solution for a space atomizer in which the chlorinated isocyanuric acid is sodium dichloroisocyanuric acid or sodium trichloroisocyanuric acid.
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* Cited by examiner, † Cited by third party
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JPS61192800A (en) * 1985-02-20 1986-08-27 四国化成工業株式会社 Production of foamable cleanser
JP2016120474A (en) * 2014-12-25 2016-07-07 株式会社トーメーポート Chlorine slow-releasing device and method for producing weak acidic hypochlorite water by using the same, and simple deodorizing-sterilizing apparatus
JP2017131360A (en) * 2016-01-27 2017-08-03 新時代化学株式会社 Chemical liquid spray device sealed with solid chemical
JP2019084506A (en) * 2017-11-08 2019-06-06 株式会社星光技研 Ultrasonic atomization device
JP2019154884A (en) * 2018-03-15 2019-09-19 株式会社グリーンウェル Sterilization/deodorization system using hypochlorite tablet

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61192800A (en) * 1985-02-20 1986-08-27 四国化成工業株式会社 Production of foamable cleanser
JP2016120474A (en) * 2014-12-25 2016-07-07 株式会社トーメーポート Chlorine slow-releasing device and method for producing weak acidic hypochlorite water by using the same, and simple deodorizing-sterilizing apparatus
JP2017131360A (en) * 2016-01-27 2017-08-03 新時代化学株式会社 Chemical liquid spray device sealed with solid chemical
JP2019084506A (en) * 2017-11-08 2019-06-06 株式会社星光技研 Ultrasonic atomization device
JP2019154884A (en) * 2018-03-15 2019-09-19 株式会社グリーンウェル Sterilization/deodorization system using hypochlorite tablet

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