JP2021165240A - Plant patch - Google Patents
Plant patch Download PDFInfo
- Publication number
- JP2021165240A JP2021165240A JP2020068532A JP2020068532A JP2021165240A JP 2021165240 A JP2021165240 A JP 2021165240A JP 2020068532 A JP2020068532 A JP 2020068532A JP 2020068532 A JP2020068532 A JP 2020068532A JP 2021165240 A JP2021165240 A JP 2021165240A
- Authority
- JP
- Japan
- Prior art keywords
- sensitive adhesive
- pressure
- plant
- base material
- patch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
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Images
Abstract
Description
本発明は、植物用貼付剤に関する。 The present invention relates to a patch for plants.
現在日本で生育している外来植物は、街路樹や防砂林などの土地開発によって移植されたもの、又は材木の輸入によってその種子が持ち込まれたものである。近年、外来植物には、成長が早く、やせ地でも生育するものがあり、野生化して在来種の植生を乱すことが問題となっている。また、外来植物に限らず、クズ、竹等の繁殖力の強い植物が生育し続けると、周辺の植物の生育を阻害する。
繁殖力の強い大型の植物の駆除方法としては、伐採、除草剤の散布、巻き枯らし及び除草剤の樹幹注入等が挙げられる。しかしながら、伐採はチェーンソーを用いた大掛かりな作業となる。また、除草剤散布では、枯らしたくない有用植物まで枯らしてしまう場合がある。さらに、除草剤の巻き枯らし又は樹幹注入では、予め、樹皮をチェーンソーで剥ぐ、又は幹に切り目や穴を開ける必要があり、作業が煩雑である。
The exotic plants currently growing in Japan are those transplanted by land development such as roadside trees and sand-proof forests, or those whose seeds are brought in by importing timber. In recent years, some exotic plants grow fast and grow even in thin areas, and it has become a problem that they become wild and disturb the vegetation of native species. Moreover, if not only exotic plants but also plants with strong fertility such as scraps and bamboo continue to grow, the growth of surrounding plants is inhibited.
Methods for exterminating large plants with strong fertility include logging, spraying herbicides, weeding, and injecting herbicides into trunks. However, logging is a large-scale operation using a chainsaw. In addition, spraying herbicides may kill useful plants that you do not want to die. Further, in the case of winding up the herbicide or injecting the trunk, it is necessary to peel off the bark with a chainsaw or make a cut or a hole in the trunk in advance, which is complicated.
一方、公知の除草剤には、種々のタイプがあり、少量で効果が発現するものと一定量が必要なものとが存在する。少量で効果が発現するものは、効率は良いが、除草剤の飛散(ドリフト)によって有用植物まで枯死させるので散布には向かない。また、一定量の除草剤が必要なものは、繁殖力の強い大型の植物を駆除するには、大量の農薬が必要となるため、有用植物に影響する場合がある。さらに、土壌への残留性が高い農薬を使用した場合には、ドリフトにより有用植物を枯死させるだけでなく、その後、一定期間、植物が繁殖できない状況となる危険性もある。またさらに、除草剤の散布は、作業者の除草剤の被曝は避けられず、近隣住民に配慮すると、夜間など人の往来が減少した時間帯に作業しなければならず、作業者の負荷も大きい。 On the other hand, there are various types of known herbicides, some of which exert an effect in a small amount and some of which require a certain amount. Those that exert their effects in a small amount are efficient, but they are not suitable for spraying because useful plants are killed by the scattering (drift) of the herbicide. In addition, those that require a certain amount of herbicide may affect useful plants because a large amount of pesticides are required to exterminate large plants with strong fertility. Furthermore, when pesticides with high persistence in soil are used, there is a risk that not only useful plants will die due to drift, but also plants will not be able to reproduce for a certain period of time thereafter. Furthermore, when spraying herbicides, it is inevitable that workers will be exposed to herbicides, and in consideration of neighboring residents, it is necessary to work during times when traffic is reduced, such as at night, which also imposes a burden on workers. big.
そこで、上記の方法とは異なる除草方法として、特許文献1に、ガムシートの粘着剤層面にインドール酢酸様活性の除草剤であるピクロラムをラノリンに混合させて基材に塗布した除草シートが提案されている。
また、粘着剤層を備える貼付剤においては、支持体として、様々な性質を有するプラスチックを用いることが提案されている。例えば、特許文献2には、ポリエチレンテレフタレート、ポリエチレン、ポリプロピレン、又はポリ塩化ビニルからなる植物処理用貼付剤が開示されている。
Therefore, as a weeding method different from the above method, Patent Document 1 proposes a weeding sheet in which picloram, which is an indoleacetic acid-like active herbicide, is mixed with lanolin and applied to a base material on the pressure-sensitive adhesive layer surface of the gum sheet. There is.
Further, in a patch having an adhesive layer, it has been proposed to use a plastic having various properties as a support. For example, Patent Document 2 discloses a patch for plant treatment made of polyethylene terephthalate, polyethylene, polypropylene, or polyvinyl chloride.
除草シートにおいては、通常、紫外線による薬剤の分解を防止するため、例えば金属膜層を積層したフィルムなどを基材としており、その外観は不透明となっている。しかしながら、基材を不透明とすると、貼付剤を貼付した直下の植物の幹や枝の色相や状態を知ることができないという問題がある。また、植物に除草シートを適用し、薬物の効果が認められたかどうか除草シートの評価を行うときに、植物に貼付剤を適用した当時は確実に植物が生きていたかどうかについて知る機能は、従来の除草シートにはなかった。
また、使用後に除草シートの様子を見る際、基材が透明であると、樹木の色と区別がつきにくく、除草シートを貼付した箇所を探すのに手間がかかっていた。
本発明は、上記事情に鑑みてなされたものであり、使用中及び使用後に貼付箇所が判明しやすく、農薬の効果を把握しやすい植物用貼付剤を提供することを目的とする。
The herbicidal sheet is usually made of, for example, a film in which a metal film layer is laminated in order to prevent decomposition of the chemicals by ultraviolet rays, and its appearance is opaque. However, if the base material is opaque, there is a problem that the hue and state of the trunk and branches of the plant directly under the patch cannot be known. In addition, when applying a herbicidal sheet to a plant and evaluating whether or not the effect of the drug was observed, the function of knowing whether or not the plant was alive at the time when the patch was applied to the plant has been conventionally available. It was not on the weeding sheet.
In addition, when observing the state of the weeding sheet after use, if the base material is transparent, it is difficult to distinguish it from the color of the tree, and it takes time and effort to find the place where the weeding sheet is attached.
The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a plant patch that makes it easy to identify the sticking location during and after use and to easily grasp the effect of pesticides.
本発明者らは、鋭意検討の結果、薬剤を含有させる粘着剤と基材の材料を、特定の組み合わせとすることによって、耐候性があり、かつ使用中又は使用後に貼付箇所が判明しやすい植物用貼付剤を提供できることを見出し、本発明に至った。 As a result of diligent studies, the present inventors have made a specific combination of the adhesive containing the drug and the material of the base material, so that the plant has weather resistance and the attachment location can be easily found during or after use. We have found that we can provide a patch for use, and have arrived at the present invention.
すなわち、本発明は、透明又は半透明の基材と、基材の一方の面に設けられた粘着剤層とを有し、粘着剤層が、薬剤とエマルジョン系粘着剤又はハイドロコロイド系粘着剤とを含有する植物用貼付剤である。 That is, the present invention has a transparent or translucent base material and a pressure-sensitive adhesive layer provided on one surface of the base material, and the pressure-sensitive adhesive layer is a drug and an emulsion-based pressure-sensitive adhesive or a hydrocolloid-based pressure-sensitive adhesive. It is a patch for plants containing.
基材は、樹脂フィルム、又は、樹脂フィルムの積層体であることが好ましい。 The base material is preferably a resin film or a laminate of resin films.
基材は、ポリオレフィン系材料、アクリル系材料、ポリエステル系材料、及びセルロース系材料の少なくとも1種で構成されることが好ましい。 The base material is preferably composed of at least one of a polyolefin-based material, an acrylic-based material, a polyester-based material, and a cellulosic-based material.
薬剤は、浸透移行性を有する、殺虫剤、殺菌剤、除草剤、及び植物成長調整剤から選ばれる1つ以上であることが好ましい。 The agent is preferably one or more selected from insecticides, fungicides, herbicides, and plant growth regulators having osmotic transferability.
除草剤は、アミノ酸生合成阻害剤であることが好ましい。 The herbicide is preferably an amino acid biosynthesis inhibitor.
本発明の植物用貼付剤によれば、使用中及び使用後に貼付箇所が判明しやすく、農薬の効果を把握しやすい。 According to the plant patch of the present invention, it is easy to identify the sticking point during and after use, and it is easy to grasp the effect of the pesticide.
以下、本発明の実施形態について図面を参照して説明する。以下の実施形態は例示の目的で提示するものであり、本発明は、以下に示す実施形態に何ら限定されるものではない。 Hereinafter, embodiments of the present invention will be described with reference to the drawings. The following embodiments are presented for purposes of illustration, and the present invention is not limited to the embodiments shown below.
[植物用貼付剤]
本発明の実施形態について図1を参照しながら説明する。
図1に示すように、本発明の植物用貼付剤10は、透明又は半透明の基材11と、基材11の一方の面に設けられた粘着剤層12とを有し、粘着剤層は、薬剤とエマルジョン系粘着剤又はハイドロコロイド系粘着剤とを含有する。
以下、植物用貼付剤の各構成の詳細について説明する。
[Plant patch]
An embodiment of the present invention will be described with reference to FIG.
As shown in FIG. 1, the
Hereinafter, details of each configuration of the plant patch will be described.
(基材)
本発明の植物用貼付剤10は、透明又は半透明であり、樹木の幹又は茎に巻き付けて使用するものであるため、基材11としては、可撓性又は柔軟性があり、幹又は茎への密着性を有し、農薬の蒸発及び漏洩を防ぐような物性を有するものである。
本発明において、「透明または半透明」とは、光透過率が、波長400nm以上800nm以下の可視光波長域において、少なくとも30%以上のことであり、好ましくは50%以上であり、より好ましくは70%以上、さらにより好ましくは90%以上のことである。光透過率は、JIS K 7375:2008に規定される「プラスチック-全光線透過率および全光線反射率の求め方」を用いて測定されるものである。
また、基材11の全光線透過率は、30%以上100%以下であることが好ましい。全光透過率は、例えば、JIS K 7375:2008に規定される「プラスチック--全光線透過率および全光線反射率の求め方」を用いて測定されるものである。
(Base material)
Since the
In the present invention, "transparent or translucent" means that the light transmittance is at least 30% or more, preferably 50% or more, and more preferably 50% or more in the visible light wavelength region having a wavelength of 400 nm or more and 800 nm or less. It is 70% or more, and even more preferably 90% or more. The light transmittance is measured using "Plastic-How to determine the total light transmittance and the total light reflectance" specified in JIS K 7375: 2008.
Further, the total light transmittance of the base material 11 is preferably 30% or more and 100% or less. The total light transmittance is measured by using, for example, "Plastic--How to determine the total light transmittance and the total light reflectance" specified in JIS K 7375: 2008.
基材11は、樹脂フィルムが好ましい。また、基材11は、ポリオレフィン系材料、アクリル系材料、ポリエステル系材料、及びセルロース系材料の少なくとも1種で構成されることが好ましい。
ポリオレフィン系材料としては、例えば、ポリエチレン、ポリプロピレン、エチレンプロピレン共重合体、エチレンブテン−1共重合体、エチレンオクテン共重合体、エチレン酢酸ビニル共重合体、エチレンビニルアルコール共重合体等が挙げられる。アクリル系材料としては、ポリビニルアルコール系材料、ポリメチルメタクリレート等が挙げられる。ポリエステル系材料としては、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリカーボネート、脂肪族ポリエステル等が挙げられる。セルロース系材料としては、アセテート、セロファン等が挙げられる。基材11は、エコロージュ(登録商標)(三菱ケミカル(株)製)などのポリ乳酸が主成分の生分解性プラスチックであってもよい。さらに、上記各種材料の1種又は2種以上の混合物又は積層構造を用いることができる。
これらの中でも、アクリル系材料は、UV(紫外線)を反射することから、紫外線による薬剤の分解を防止することができるので、好ましい。また、セロファンや生分解性プラスチックの場合は、貼付剤を対象となる植物に貼付したままでも、土壌とともに自然に分解されるため、好ましい。
The base material 11 is preferably a resin film. Further, the base material 11 is preferably composed of at least one of a polyolefin-based material, an acrylic-based material, a polyester-based material, and a cellulosic-based material.
Examples of the polyolefin-based material include polyethylene, polypropylene, ethylene propylene copolymer, ethylene butene-1 copolymer, ethylene octene copolymer, ethylene vinyl acetate copolymer, ethylene vinyl alcohol copolymer and the like. Examples of the acrylic material include polyvinyl alcohol-based materials and polymethylmethacrylate. Examples of polyester-based materials include polyethylene terephthalate, polybutylene terephthalate, polycarbonate, and aliphatic polyesters. Examples of the cellulosic material include acetate and cellophane. The base material 11 may be a biodegradable plastic containing polylactic acid as a main component, such as Ecologue (registered trademark) (manufactured by Mitsubishi Chemical Corporation). Further, one kind or a mixture of two or more kinds of the above-mentioned various materials or a laminated structure can be used.
Among these, the acrylic material is preferable because it reflects UV (ultraviolet rays) and can prevent the decomposition of the chemicals by the ultraviolet rays. Further, in the case of cellophane or biodegradable plastic, it is preferable because the patch is naturally decomposed together with the soil even if the patch is still attached to the target plant.
−基材の厚さ−
基材11の厚さは、伸び、引張り強さ、作業性などの物理的性質、及び幹又は茎の表面への追随性を考慮して適宜選択可能であるが、5μm以上200μm以下であることが好ましく、20μm以上100μm以下であることがより好ましい。基材11の厚さが5μm未満であると、植物用貼付剤10の強度及び取り扱い性が低下して、幹や茎への貼付が困難になり、樹皮との接触によって破れる場合がある。また、基材11の厚さが200μmを超えると、植物用貼付剤10を幹や茎に巻く際、幹や茎に追随しにくくなり、剥がれやすくなる。
また、基材11が樹脂フィルムの場合は、その厚さは、5μm以上200μm以下であることが好ましく、10μm以上200μm以下であることがより好ましく、10μm以上100μm以下であることが更に好ましい。
-Base material thickness-
The thickness of the base material 11 can be appropriately selected in consideration of physical properties such as elongation, tensile strength, workability, and followability to the surface of the trunk or stem, but must be 5 μm or more and 200 μm or less. Is preferable, and more preferably 20 μm or more and 100 μm or less. If the thickness of the base material 11 is less than 5 μm, the strength and handleability of the
When the base material 11 is a resin film, its thickness is preferably 5 μm or more and 200 μm or less, more preferably 10 μm or more and 200 μm or less, and further preferably 10 μm or more and 100 μm or less.
なお、基材11の厚さが、ごく薄い場合は、基材11の粘着剤層12が設けられている面(一方の面ともいう)とは反対の面(他方の面ともいう)に、後述するキャリアフィルムを設けてもよい。
When the thickness of the base material 11 is very thin, the surface of the base material 11 opposite to the surface on which the pressure-
基材11の大きさは、対象植物の大きさ及び除草剤の濃度によって適宜選択することができる。 The size of the base material 11 can be appropriately selected depending on the size of the target plant and the concentration of the herbicide.
なお、基材11が樹脂フィルムである場合は、粘着剤層12と基材11の投錨性を向上することを目的に、基材11の一方の面及び他方の面の少なくとも一方にサンドブラスト処理、コロナ処理等の処理を行ってもよい。
When the base material 11 is a resin film, sandblasting is performed on at least one surface of the base material 11 and at least one of the other surfaces for the purpose of improving the anchoring property of the pressure-
基材11は、フェノールやアミン類等の酸化防止剤又はベンゾフェノン類、ベンゾトリアゾール類、ベンゾエート類等の紫外線吸収剤、ヒンダードアミン系の光安定剤を本発明の効果を阻害しない程度に含有してもよい。 Even if the base material 11 contains an antioxidant such as phenol or amines, an ultraviolet absorber such as benzophenone, benzotriazole or benzoate, or a hindered amine-based light stabilizer to the extent that the effect of the present invention is not impaired. good.
(粘着剤層)
粘着剤層12は、薬剤とエマルジョン系粘着剤又はハイドロコロイド系粘着剤とを含有するものであり、植物から蒸散する水分を吸収して白濁化するものである。
エマルジョンは界面活性剤を含んでおり、水との親和性が高い。また、ハイドロコロイドは吸収性のある物質を粘着剤層中に含んでおり、水を吸収する性質がある。これらの粘着剤は、水を含むことにより、白濁化する。
ここで、「白濁化する」とは、粘着剤が水分を吸収して直接的に貼付した直下を正確に確認できないまで、粘着剤が白色に着色したものをいう。さらに具体的には、植物に貼付した貼付剤が、例えば1m離れた箇所から目視したときに、貼付剤が白く濁って見え、貼付剤の下の植物の茎や幹の色、状態を正確に確認できない場合をいう。
(Adhesive layer)
The pressure-
The emulsion contains a surfactant and has a high affinity for water. Further, the hydrocolloid contains an absorbable substance in the pressure-sensitive adhesive layer and has a property of absorbing water. These pressure-sensitive adhesives become cloudy when they contain water.
Here, "whitening" means that the adhesive is colored white until the adhesive absorbs moisture and it is not possible to accurately confirm the area directly under the adhesive. More specifically, when the patch attached to the plant is viewed from a distance of, for example, 1 m, the patch appears white and muddy, and the color and condition of the stem and trunk of the plant under the patch are accurately determined. When it cannot be confirmed.
−エマルジョン系粘着剤−
「エマルジョン系粘着剤」とは、水性溶媒に非水溶性粘着剤(粘着性高分子化合物)が微粒子状に分散したエマルジョンを意味する。
非水溶性粘着剤としては、例えば、アクリル系粘着剤、ゴム系粘着剤、シリコーン系粘着剤、ビニルアルキルエーテル系粘着剤、ポリエステル系粘着剤、ポリアミド系粘着剤、ウレタン系粘着剤、フッ素系粘着剤、エポキシ系粘着剤、ラテックス、その他の合成樹脂を含有する粘着剤などが挙げられる。エマルジョン系粘着剤は、粘着剤(粘着性高分子化合物)のモノマーを乳化重合することにより好適に製造することができる。乳化重合においては、水性溶媒中でモノマーとともに乳化剤(界面活性剤)、重合開始剤を混合して、重合反応を進行させることにより水分散型の重合体(エマルジョン)を得ることができる。中でも、農薬の幹や茎への浸透性が良いという観点から、アクリルエマルジョン系粘着剤、ラテックスが好ましい。これら粘着剤は1種を単独で、又は2種以上を混合して用いてもよい。
-Emulsion adhesive-
The "emulsion-based pressure-sensitive adhesive" means an emulsion in which a water-insoluble pressure-sensitive adhesive (adhesive polymer compound) is dispersed in fine particles in an aqueous solvent.
Examples of the water-insoluble adhesive include acrylic adhesives, rubber adhesives, silicone adhesives, vinyl alkyl ether adhesives, polyester adhesives, polyamide adhesives, urethane adhesives, and fluorine adhesives. Examples thereof include agents, epoxy-based pressure-sensitive adhesives, latexes, and pressure-sensitive adhesives containing other synthetic resins. The emulsion-based pressure-sensitive adhesive can be suitably produced by emulsion polymerization of the monomer of the pressure-sensitive adhesive (adhesive polymer compound). In emulsion polymerization, an aqueous dispersion type polymer (emulsion) can be obtained by mixing an emulsifier (surfactant) and a polymerization initiator together with a monomer in an aqueous solvent and advancing the polymerization reaction. Of these, acrylic emulsion-based adhesives and latex are preferable from the viewpoint of good penetration of pesticides into the trunk and stem. These pressure-sensitive adhesives may be used alone or in combination of two or more.
エマルジョン系粘着剤を構成するアクリル系共重合体は、例えば、2種以上のアクリル系重合性化合物を乳化重合して共重合体を得ることによって製造することができる。
アクリル系重合性化合物としては、例えば、ブチルアクリレート、n−ヘキシルアクリレート、2−エチルヘキシルアクリレート、メチル(メタ)アクリレート、エチルアクリレート、イソオクチルアクリレート、ラウリルメタクリレート、2−メトキシエチルアクリレート、2−(2−エトキシエトキシ)エチルアクリレート、イソデシルアクリレート、トリデシルアクリレート、トリデシルメタクリレート、シクロヘキシルアクリレート、イソボルニルアクリレート、(メタ)アクリル酸、クロトン酸、フマル酸、イタコン酸、マレイン酸、シトラコン酸、2−カルボキシエチルメタクリレート、2−ヒドロキシエチル(メタ)アクリレート、2−ヒドロキシプロピル(メタ)アクリレート、3−ヒドロキシプロピル(メタ)アクリレート、2−ヒドロキシブチル(メタ)アクリレート、3−ヒドロキシブチル(メタ)アクリレート、4−ヒドロキシブチル(メタ)アクリレート、ビニルアルコール、アリルアルコール、(メタ)アクリルアミド、N,N−ジメチル(メタ)アクリルアミド、N−ブチル(メタ)アクリルアミド、N−メチロール(メタ)アクリルアミド、N−メチロールプロパン(メタ)アクリルアミド、N−メトキシメチル(メタ)アクリルアミド、N−ブトキシメチル(メタ)アクリルアミド、(メタ)アクリレートモノマー、第2級アミノ基含有(メタ)アクリレートモノマー、第3級アミノ基含有(メタ)アクリレートモノマー、アミド基を形成する窒素原子上に3級アミノ基を含有する置換基が結合した第3級アミノ基含有N−置換(メタ)アクリルアミドモノマー、グリシジル(メタ)アクリレート、メチルグリシジル(メタ)アクリレート、アリルグリシジルエーテル、アクリロニトリル、メタクリロニトリル、ジアセトン(メタ)アクリルアミド、アセトン(メタ)アクリレート、ビニルメチルケトン、ビニルエチルケトン、アリルアセトアセテート、ビニルアセテート、スチレン、アセトアセチル(メタ)アクリレート、N−ビニル−2−ピロリドン、N−メチルビニルピロリドン、N−ビニルピペリドン、N−ビニルピペラジン、N−ビニルピラジン、N−ビニルピロール、N−ビニルイミダゾール、N−ビニルモルホリン、N−ビニルカプロラクタム、N−(メタ)アクリロイルモルホリン、3−(メタ)アクリロキシプロピルトリメトキシシラン、3−(メタ)アクリロキシプロピルトリエトキシシラン、3−アクリロキシプロピルトリエトキシシラン、3−(メタ)アクリロキシプロピルメチルジメトキシシラン、3−(メタ)アクリロキシプロピルメチルジエトキシシラン2−(アセトアセトキシ)エチル(メタ)アクリレート、2−(メタ)アクリロキシエチルトリメトキシシラン、2−(メタ)アクリロキシエチルトリエトキシシラン、γ−(メタ)アクリロキシプロピルトリクロロシラン、γ−(メタ)アクリロキシプロピルメチルジクロロシラン、γ−(メタ)アクリロキシプロピルジメチルクロロシラン、γ−(メタ)アクリロキシプロピルトリプロピオキシシラン、γ−(メタ)アクリロキシプロピルメチルジプロピオキシシラン、γ−(メタ)アクリロキシプロピルトリブトキシシラン、(メタ)アクリロキシペンチルトリメトキシシラン、(メタ)アクリロキシヘキシルトリメトキシシラン、(メタ)アクリロキシヘキシルトリエトキシシラン、(メタ)アクリロキシオクチルトリメトキシシラン、(メタ)アクリロキシデシルトリメトキシシラン、(メタ)アクリロキシドデシルトリメトキシシラン、(メタ)アクリロキシオクタデシルトリメトキシシラン、ビニルトリメトキシシラン、ビニルトリエトキシシラン、ビニルトリプロポキシシラン、ビニルメチルジメトキシシラン、ビニルメチルジエトキシシラン、ビニルメチルジプロポキシシラン、アジピン酸ジヒドラジド、トリメチロールプロパン、エチレンジオキシメタンフェタミン等が挙げられる。
これらの中でも(メタ)アクリル酸アルキルエステル、特定の官能基を有するモノマーまたは親水性モノマー、共重合可能な他の不飽和結合を有するモノマーを1種類以上共重合させたもので、ブチルアクリレート、イソノニルアクリレート、2−エチルヘキシルアクリレートを含むものが好ましい。
The acrylic copolymer constituting the emulsion-based pressure-sensitive adhesive can be produced, for example, by emulsion-polymerizing two or more kinds of acrylic polymerizable compounds to obtain a copolymer.
Examples of the acrylic polymerizable compound include butyl acrylate, n-hexyl acrylate, 2-ethylhexyl acrylate, methyl (meth) acrylate, ethyl acrylate, isooctyl acrylate, lauryl methacrylate, 2-methoxyethyl acrylate, and 2- (2- (2-). Ethoxyethoxy) ethyl acrylate, isodecyl acrylate, tridecyl acrylate, tridecyl methacrylate, cyclohexyl acrylate, isobornyl acrylate, (meth) acrylic acid, crotonic acid, fumaric acid, itaconic acid, maleic acid, citraconic acid, 2-carboxy Ethyl methacrylate, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate, 3-hydroxybutyl (meth) acrylate, 4- Hydroxybutyl (meth) acrylate, vinyl alcohol, allyl alcohol, (meth) acrylamide, N, N-dimethyl (meth) acrylamide, N-butyl (meth) acrylamide, N-methylol (meth) acrylamide, N-methylol propane (meth) ) Acrylate, N-methoxymethyl (meth) acrylamide, N-butoxymethyl (meth) acrylamide, (meth) acrylate monomer, secondary amino group-containing (meth) acrylate monomer, tertiary amino group-containing (meth) acrylate monomer , Tertiary amino group-containing N-substituted (meth) acrylamide monomer in which a substituent containing a tertiary amino group is bonded to a nitrogen atom forming an amide group, glycidyl (meth) acrylate, methyl glycidyl (meth) acrylate, Allylglycidyl ether, acrylonitrile, methacrylate, diacetone (meth) acrylamide, acetone (meth) acrylate, vinyl methyl ketone, vinyl ethyl ketone, allyl acetoacetate, vinyl acetate, styrene, acetoacetyl (meth) acrylate, N-vinyl- 2-Pyrrolidone, N-Methylvinylpyrrolidone, N-vinylpiperidone, N-vinylpiperazine, N-vinylpyrazine, N-vinylpyrrole, N-vinylimidazole, N-vinylmorpholin, N-vinylcaprolactam, N- (meth) acryloyl Morphorin, 3- (meth) acryloxipropyltrimethoxysilane, 3- (meth) acryloxy Propyltriethoxysilane, 3-acryloxypropyltriethoxysilane, 3- (meth) acryloxypropylmethyldimethoxysilane, 3- (meth) acryloxypropylmethyldiethoxysilane 2- (acetoacetoxy) ethyl (meth) acrylate, 2- (Meta) acryloxiethyltrimethoxysilane, 2- (meth) acryloxiethyltriethoxysilane, γ- (meth) acryloxipropyltrichlorosilane, γ- (meth) acryloxipropylmethyldichlorosilane, γ-( Meta) acryloxypropyl dimethylchlorosilane, γ- (meth) acryloxipropyltripropoxysilane, γ- (meth) acryloxipropylmethyldipropioxysilane, γ- (meth) acryloxipropyltributoxysilane, (meth) Acryloxipentyltrimethoxysilane, (meth) acryloxihexyltrimethoxysilane, (meth) acryloxihexyltriethoxysilane, (meth) acryloxyoctyltrimethoxysilane, (meth) acryloxidecyltrimethoxysilane, (meth) Acryloxydodecyltrimethoxysilane, (meth) acryloxioctadecyltrimethoxysilane, vinyltrimethoxysilane, vinyltriethoxysilane, vinyltripropoxysilane, vinylmethyldimethoxysilane, vinylmethyldiethoxysilane, vinylmethyldipropoxysilane, adipine Examples thereof include acid dihydrazide, trimethylolpropane, and ethylenedioxymethanephthalamine.
Among these, one or more kinds of (meth) acrylic acid alkyl esters, monomers having a specific functional group or hydrophilic monomers, and monomers having other copolymerizable unsaturated bonds are copolymerized, and butyl acrylate and iso Those containing nonyl acrylate and 2-ethylhexyl acrylate are preferable.
粘着剤層中の共重合体の含有量は、粘着剤の安定性、薬物の保持性などの観点から、60質量%以上97質量%以下であることが好ましく、70質量%以上90質量%以下であることがより好ましい。
また、共重合体の粒子の平均粒径は、樹木の幹や茎への粘着力を確保する観点から、30nm以上1000nm以下であることが好ましい。
The content of the copolymer in the pressure-sensitive adhesive layer is preferably 60% by mass or more and 97% by mass or less, and 70% by mass or more and 90% by mass or less, from the viewpoint of the stability of the pressure-sensitive adhesive and the retention of the drug. Is more preferable.
The average particle size of the copolymer particles is preferably 30 nm or more and 1000 nm or less from the viewpoint of ensuring the adhesive force to the trunk and stem of the tree.
エマルジョン系粘着剤には、公知の適宜な架橋剤を含有し得る。その架橋剤としては、例えば、イソシアネート架橋剤、エポキシ架橋剤、アジリジン系化合物、キレート系架橋剤等が挙げられる。それらの架橋剤の含有量は特に限定されない。また、必要に応じて、ロジン樹脂、テルペン樹脂、脂肪系炭化水素樹脂、脂環炭化水素樹脂、芳香族炭化水素樹脂、クマロン樹脂、これらの共重合体、変性物、水添物等の粘着付与剤を添加してもよい。 The emulsion-based pressure-sensitive adhesive may contain a known appropriate cross-linking agent. Examples of the cross-linking agent include isocyanate cross-linking agents, epoxy cross-linking agents, aziridine-based compounds, chelate-based cross-linking agents and the like. The content of these cross-linking agents is not particularly limited. In addition, if necessary, adhesion of rosin resin, terpene resin, aliphatic hydrocarbon resin, alicyclic hydrocarbon resin, aromatic hydrocarbon resin, kumaron resin, their copolymers, modified products, hydrogenated products, etc. Agents may be added.
−ハイドロコロイド系粘着剤−
「ハイドロコロイド系粘着剤」は、可塑性ゴムからなる連続相(母材)に吸水性のコロイド粒子(吸水剤)が分散して存在している構造を有し、その多くは、一定時間で自重の3〜5倍程度の水を吸収し得るように調製されている。水等を吸水してもその母材が一体性を失うことがないように調整される。ハイドロコロイド系粘着剤は、一般的にエラストマー、粘着付与樹脂、可塑剤、その他の成分で構成される。
-Hydrocolloid adhesive-
The "hydrocolloid adhesive" has a structure in which water-absorbing colloidal particles (water-absorbing agent) are dispersed in a continuous phase (base material) made of plastic rubber, and most of them have their own weight in a certain period of time. It is prepared so that it can absorb about 3 to 5 times as much water. It is adjusted so that the base material does not lose its integrity even if it absorbs water. Hydrocolloid adhesives are generally composed of elastomers, tackifier resins, plasticizers and other components.
粘着剤を構成するエラストマーとしては、植物へ接着性を付与できるものであれば特に限定されるものではなく、その例としては、天然又は合成の粘性ゴム状物質、例えば、ポリイソブチレン、ポリイソプレン、ポリブタジエン、スチレン・ブタジエン・スチレンブロック共重合体、スチレン・イソプレン・スチレンブロック共重合体(SIS)等の合成ゴムやアクリル系エラストマー、ウレタン系エラストマー、及びシリコーン系エラストマー等のエラストマーなどから選ばれた少なくとも1種が挙げられる。これらのうち、スチレン・イソプレン・スチレンブロック共重合体(SIS)や粘度平均分子量(Flory法による。以下同じ。)が、分子量が約30000〜120000の中分子量ポリイソブチレンゴムが特に望ましい。これらの材料は、1種または2種以上を用いることができる。SISの市販品として、クインタック3421(登録商標、日本ゼオン株式会社製)等がある。 The elastomer constituting the pressure-sensitive adhesive is not particularly limited as long as it can impart adhesiveness to plants, and examples thereof include natural or synthetic viscous rubber-like substances such as polyisobutylene and polyisoprene. At least selected from synthetic rubbers such as polybutadiene, styrene / butadiene / styrene block copolymers, styrene / isoprene / styrene block copolymers (SIS), acrylic elastomers, urethane elastomers, and elastomers such as silicone elastomers. One type can be mentioned. Of these, styrene / isoprene / styrene block copolymer (SIS) and medium molecular weight polyisoprene rubber having a viscosity average molecular weight (according to the Flory method; the same applies hereinafter) having a molecular weight of about 30,000 to 120,000 are particularly desirable. These materials may be used alone or in combination of two or more. Commercially available SIS includes Quintac 3421 (registered trademark, manufactured by Nippon Zeon Corporation) and the like.
また、吸水性及び/又は水膨張性のポリマーからなるハイドロコロイド粉末としては、特に限定されないが、吸液能の大きいポリマーが望ましい。例えば、ポリアクリル酸及び/又はその塩、アクリル酸/ビニルアルコールポリマー、架橋カルボキシメチルセルロース(ナトリウム塩やカルシウム塩を含む。)、メチルビニルエーテル/マレイン酸の長鎖ポリマー、カルボキシメチルセルロース(CMC,ナトリウム塩やカルシウム塩を含む。)、澱粉−アクリル酸塩グラフトポリマー、アクリル酸−アクリルアミドコポリマー、アルギン酸及び/又はそのナトリウム塩、メチルビニルエーテル/無水マレイン酸コポリマー、ゼラチン、ペクチン、カラギーナン、ポリビニルピロリドン等のハイドロコロイド粒子(親水性ポリマー)が挙げられ、これらから選ばれた少なくとも1種あるいは1種以上を混合して用いてもよい。CMCの市販品としては、セロゲンF−3H(登録商標、第一工業製薬株式会社製)等がある。 The hydrocolloid powder composed of a water-absorbent and / or water-expandable polymer is not particularly limited, but a polymer having a large liquid-absorbing ability is desirable. For example, polyacrylic acid and / or salts thereof, acrylic acid / vinyl alcohol polymer, crosslinked carboxymethyl cellulose (including sodium salt and calcium salt), long chain polymer of methyl vinyl ether / maleic acid, carboxymethyl cellulose (CMC, sodium salt and the like. Hydrocolloid particles such as calcium salts), starch-acrylic acid graft polymers, acrylic acid-acrylamide copolymers, alginic acid and / or sodium salts thereof, methyl vinyl ether / maleic anhydride copolymers, gelatin, pectin, carrageenan, polyvinylpyrrolidone, etc. Hydrophilic polymer), and at least one selected from these or one or more thereof may be mixed and used. Commercially available products of CMC include Cellogen F-3H (registered trademark, manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.) and the like.
これらハイドロコロイド粉末の配合量は、適度な吸水速度と吸水量を得るために、例えばカルボキシメチルセルロース・ナトリウムやカルボキシメチルセルロースであれば、粘着剤組成物全成分の総質量に対して10質量%以上50質量%以下、好ましくは20質量%以上40質量%以下の割合で使用することが、吸液性、特に吸水性、創傷部位との接着性、及び適度な保形性の観点から望ましい。 In order to obtain an appropriate water absorption rate and water absorption amount, for example, in the case of carboxymethyl cellulose sodium or carboxymethyl cellulose, the blending amount of these hydrocolloid powders is 10% by mass or more and 50% by mass with respect to the total mass of all the components of the pressure-sensitive adhesive composition. It is desirable to use it in a proportion of% or less, preferably 20% by mass or more and 40% by mass or less, from the viewpoint of liquid absorption, particularly water absorption, adhesion to the wound site, and appropriate shape retention.
−粘着付与樹脂−
粘着剤を構成する粘着付与樹脂としては、一般に疎水性ゴムベース成分と相溶して粘着性を発現させる疎水性の樹脂であり、具体的にはロジン樹脂、ロジンエステル樹脂、テルペン樹脂、テルペンフェノール樹脂、C5系石油系樹脂、C5/C9系石油系樹脂、DCPD系石油系樹脂、クマロン・インデン樹脂、またこれらの水添物などが挙げられる。
粘着付与樹脂の具体例としては、例えば、脂環族飽和炭化水素樹脂のアルコン(登録商標)P−125(荒川化学工業株式会社)、水添テルペン樹脂のクリアロン(登録商標)P150(ヤスハラケミカル株式会社)などが挙げられる。
上記粘着付与樹脂は、例えば、上記クリアロンP150であれば、粘着剤組成物の全エラストマー成分の100質量部に対して20質量部以上200質量部以下、好ましくは50質量部以上180質量部以下の量で存在していることが好ましい。
-Adhesive-imparting resin-
The tackifier resin constituting the pressure-sensitive adhesive is generally a hydrophobic resin that is compatible with a hydrophobic rubber base component to develop adhesiveness, and specifically, a rosin resin, a rosin ester resin, a terpene resin, and a terpene phenol. Examples thereof include resins, C5-based petroleum-based resins, C5 / C9-based petroleum-based resins, DCPD-based petroleum-based resins, Kumaron-Inden resins, and hydrogenated products thereof.
Specific examples of the tackifier resin include alicyclic saturated hydrocarbon resin Archon (registered trademark) P-125 (Arakawa Chemical Industry Co., Ltd.) and hydrogenated terpene resin Clearon (registered trademark) P150 (Yasuhara Chemical Co., Ltd.). ) And so on.
For example, in the case of the Clearon P150, the tackifier resin is 20 parts by mass or more and 200 parts by mass or less, preferably 50 parts by mass or more and 180 parts by mass or less with respect to 100 parts by mass of all the elastomer components of the pressure-sensitive adhesive composition. It is preferably present in quantity.
−可塑剤−
粘着剤を構成する可塑剤(軟化剤)としては、パラフィン系、ナフテン系、等の石油系プロセスオイルやひまし油、大豆油などの植物油、及び植物油由来の脂肪酸エステルなどの軟化剤を使用してもよい。また、フタル酸、イソフタル酸、テレフタル酸等の芳香族ジカルボン酸や、コハク酸、グルタル酸、アジピン酸、ピメリン酸、スベリン酸、アゼライン酸、セバシン酸等の脂肪族ジカルボン酸と、例えば、炭素原子数8以上10以下程度のアルキル基を有するモノアルコールとの二塩基酸エステル系可塑剤;前記香族ジカルボン酸や脂肪族ジカルボン酸とエチレングリコール、プロピレングリコール、ブチレングリコール、ネオペンチルグリコール、ジエチレングリコール等のグリコールとの重縮合により得られるポリエステル系可塑剤;ポリエチレングリコール、クエン酸エステル等のその他の可塑剤なども使用することができる。これら2つ以上を併用することもできる。
本発明において、可塑剤は、粘着剤の総質量に対して、0.5質量%以上60質量%以下であることが好ましく、11質量%以上45質量%以下であることがより好ましい。
-Plasticizer-
As the plasticizer (softener) constituting the pressure-sensitive adhesive, petroleum-based process oils such as paraffin-based and naphthen-based oils, vegetable oils such as castor oil and soybean oil, and softeners such as fatty acid esters derived from vegetable oils may be used. good. In addition, aromatic dicarboxylic acids such as phthalic acid, isophthalic acid and terephthalic acid, aliphatic dicarboxylic acids such as succinic acid, glutaric acid, adipic acid, pimelli acid, suberic acid, azelaic acid and sebacic acid, and carbon atoms, for example. A dibasic acid ester-based plasticizer with a monoalcohol having an alkyl group of several 8 or more and 10 or less; the perfume dicarboxylic acid or aliphatic dicarboxylic acid and ethylene glycol, propylene glycol, butylene glycol, neopentyl glycol, diethylene glycol, etc. Polyester-based plasticizers obtained by polycondensation with glycol; other plasticizers such as polyethylene glycol and citrate ester can also be used. Two or more of these can be used together.
In the present invention, the plasticizer is preferably 0.5% by mass or more and 60% by mass or less, and more preferably 11% by mass or more and 45% by mass or less, based on the total mass of the pressure-sensitive adhesive.
−その他成分−
さらに粘着剤には、一般的なゴム系粘着剤で使用する、酢酸トコフェロール及び/又はその誘導体、アスコルビン酸及び/又はその誘導体、亜硫酸ナトリウム、ジブチルヒドロキシトルエン等の酸化防止剤、ビスフェノール系、ヒンダードアミン系、ベンゾイミダゾール系などの老化防止剤や紫外線吸収剤、光安定剤などを1種又は複数の組合せで適宜添加してもよい。
また粘着剤には、例えば充填剤、脱臭剤、芳香剤などを配合してもよく、或いは内部凝集力を高めるために架橋剤を適宜配合させてもよい。
これらの任意成分の配合量は、通常、粘着剤全成分の総質量に対して5質量%以下である。
-Other ingredients-
Further, the pressure-sensitive adhesive includes tocopherol acetate and / or its derivative, ascorbic acid and / or its derivative, antioxidants such as sodium sulfite and dibutylhydroxytoluene, bisphenol-based and hindered amine-based, which are used in general rubber-based pressure-sensitive adhesives. , Benzimidazole-based anti-aging agents, ultraviolet absorbers, light stabilizers and the like may be appropriately added in one or a combination of two or more.
Further, the pressure-sensitive adhesive may be blended with, for example, a filler, a deodorant, an fragrance, or the like, or may be appropriately blended with a cross-linking agent in order to enhance the internal cohesive force.
The blending amount of these optional components is usually 5% by mass or less with respect to the total mass of all the components of the pressure-sensitive adhesive.
植物用貼付剤は、粘着剤あるいは支持体の粘着剤層側を着色するものとして、着色剤を用いることもできる。この場合、着色剤は、植物から蒸散される水分を粘着剤が吸収して、着色剤が水分を含むことにより変色して着色するものである。
ここで、「着色する」とは、粘着剤あるいは基材上にある着色剤が植物からの水分の存在により色が変化して貼付剤の外観に変化を与えるものであり、貼付剤を植物への適用する前と後を比較して色が変化していることを視覚的に認識できることを意味する。
As the plant patch, a colorant can also be used as a pressure-sensitive adhesive or a colorant for coloring the pressure-sensitive adhesive layer side of the support. In this case, the colorant is one in which the pressure-sensitive adhesive absorbs the water evaporated from the plant, and the colorant is discolored and colored by containing the water.
Here, "coloring" means that the adhesive or the coloring agent on the base material changes its color due to the presence of water from the plant and changes the appearance of the patch, and the patch is applied to the plant. It means that it is possible to visually recognize that the color is changing by comparing before and after applying.
着色剤としては、食用色素、酸性染料、塩基性染料、直接染料、酸性媒染染料、反応染料から選ばれる少なくとも一種類であることが好ましい。例えば市販の青色1号、青色4号、青色404号、黄色4号、赤色102号等である。酸性染料は、例えばカヤノールレッドNBR、ブリリアントスカーレット3B、アシッドファストオレンジ SG、アマランス、アシッドローダミン B、エオシン G、アシッドミリングレッド RS、アリザリンダイレクトブルーAGG、インジゴカルミンブルー G、アシッドミリングシアニン 5Rが挙げられる。塩基性染料は、例えばカチオンレッド 6B、カチオンピンク FG、クリスタルバイオレット、メチレンブルー Bが挙げられる。直接染料は、例えばカヤノールライトレッドF5B、ダイレクトファストスカーレット4BS、ベンゾパープリン4B、ダイレクトファストオレンジS、ダイレクトロージュリンレッドB、クロランチファストレッド6BLL、シリアスレッド4B、シリアススプラレッドバイオレットRL、シリアススプラバイオレットBL、ダイレクトスカイブルー5Bが挙げられる。酸性媒染染料は、例えばクロムオレンジA、クロムオレンジGR、クロムレッドB、クロムブリリアントレッドB、クロムブリリアントバイオレットR、クロムブラウンPGが挙げられる。反応染料は、例えばリアクトンレッド2B−F、プロシオンルビンBS、シバクロンバイオレットF2R−A、プロシオンブリリアントブルーRSが挙げられる。水溶性染料は単独または複数がインキに配合される。 The colorant is preferably at least one selected from edible dyes, acid dyes, basic dyes, direct dyes, acid mordant dyes, and reactive dyes. For example, commercially available blue No. 1, blue No. 4, blue No. 404, yellow No. 4, red No. 102 and the like. Examples of acid dyes include Kayanol Red NBR, Brilliant Scarlet 3B, Acid Fast Orange SG, Amaranth, Acid Rhodamine B, Eosin G, Acid Milling Red RS, Alizarin Direct Blue AGG, Indigo Carmine Blue G, and Acid Milling Cyanine 5R. .. Examples of the basic dye include cation red 6B, cation pink FG, crystal violet, and methylene blue B. The direct dyes are, for example, Kayanol Light Red F5B, Direct Fast Scarlet 4BS, Benzo Purpurin 4B, Direct Fast Orange S, Direct Rogerin Red B, Chloranchi Fast Red 6BLL, Serious Red 4B, Serious Splatoon Violet RL, Serious Splat Violet. BL and Direct Sky Blue 5B can be mentioned. Examples of the acidic mordant dye include chrome orange A, chrome orange GR, chrome red B, chrome brilliant red B, chrome brilliant violet R, and chrome brown PG. Examples of the reactive dye include Riacton Red 2BF, Procyon Rubin BS, Cibacron Violet F2RA, and Procyon Brilliant Blue RS. The water-soluble dye may be used alone or in combination in the ink.
バインダは、例えば水溶性の微粉末であるデキストリン等が使用され、例えばデキストリンに着色剤を混合して粘着剤中に配合するか、基材の粘着剤層積層側にインクジェット法や塗布などの方法によって基材に全面あるいは格子状などのパターンで積層されていることが好ましい。着色剤は、水に溶解して発色するものであり、不可逆的な色変化である。 For the binder, for example, dextrin, which is a water-soluble fine powder, or the like is used. It is preferable that the substrate is laminated on the entire surface or in a grid pattern. A colorant dissolves in water to develop a color, and is an irreversible color change.
−粘着剤層の厚さ−
粘着剤層12の厚さは、エマルジョンの場合は10μm以上300μm以下、ハイドロコロイド粘着剤の場合は、100μm以上3000μm以下であることが好ましい。
-Thickness of adhesive layer-
The thickness of the pressure-
粘着剤層12は、単一の粘着剤層からなる構成としてもよく、複数の粘着剤層を積層した構成としてもよい。粘着剤層12が複数の粘着剤層を積層して形成された構成である場合、種類の異なる粘着剤層を積層したものとすることができる。
The pressure-
−植物用貼付剤全体の厚さ−
さらに、植物用貼付剤10全体の厚さは、幹又は茎への追随性を考慮すると、15μm以上500μm以下であることが好ましく、25μm以上250μm以下であることが、より好ましい。
-Overall thickness of plant patch-
Further, the thickness of the
(薬剤)
本発明の植物用貼付剤に用いる薬剤としては、浸透移行性を有する、殺虫剤、殺菌剤、除草剤、又は植物成長調整剤であることが好ましい。
殺虫剤としては、例えばピリプロキシフェン、フェノキシカルブ、メソプレン、ジフルベンズロン、クロルフルアズロン、テフルベンズロン、トリフルムロン、フルフェノクスロン、フルシクロクスロン、ヘキサフルムロン等のベンゾイルウレア化合物、イミダクロプリド、ニテンピラム、アセタミプリド、チアメトキサム、チアクロプリド、クロチアニジン、ジノテフランのネオニコチノイド系殺虫剤、ブプロフェジン、ピリフルキナゾン、及びメチダチオンが挙げられる。中でも、ブプロフェジン、ピリフルキナゾン、及びメチダチオンが好ましい。
(Drug)
The agent used for the plant patch of the present invention is preferably an insecticide, a fungicide, a herbicide, or a plant growth regulator having osmotic transferability.
Insecticides include, for example, benzoylurea compounds such as pyriproxyfen, phenoxycarb, methoprene, diflubenzuron, chlorfluazuron, teflubenzuron, triflumuron, fluphenoxuron, flucycloxuron, hexaflumron, imidacloprid, nitenpyram, acetamiprid, etc. Examples include thiamethoxam, thiacloprid, clothianidin, dinotefuron neonicotinoid insecticides, buprofezin, pyrifluquinazone, and metidathion. Of these, buprofezin, pyrifluquinazone, and methidathion are preferred.
殺菌剤としては、一般的な防黴剤又は抗細菌剤として知られている化合物及び抗菌作用を有するとして知られている天然製油類等を例示することができる。防黴剤又は抗細菌剤としては、例えば、5−クロロ−2−メチル−4−イソチアゾリン−3−オン、2−メチル−4−イソチアゾリン−3−オン、4,5−ジクロロ−3−n−オクチル−イソチアゾリン−3−オン、1,2−ベンズイソチアゾリン−3−オン、2−メトキシカルボニルベンズイミダゾール、2,3,5,6−テトラクロロ−4−メタンスルホニルピリジン、2−チオシアノメチベンゾチアゾール、2,2−ジチオ−ビス−(ピリジン−1−オキサイド)、3,3,4,4−テトラハイドロチオフェン−1,1−ジオキサイド、4,5−ジクロロ−1,2−ジチオラン−3−オン、5−クロロ−4−フェニル−1,2−ジチオラン−3−オン、N−メチルピロリドン、フェニル−(2−シアノ−2−クロロビニル)スルホン、メチレンビスチオシアネート、2−ブロモ−2−ニトロプロパン−1,3−ジオール、2,2−ジブロモ−2−エタノール、2−ブロモ−4′−ヒドロキシアセトフェノン、ジブロモニトリルプロピオンアミド、2−ブロモ−2−ブロモメチルグルタルニトリル、過炭酸ナトリウム、過硫酸カリウム、過ほう酸ナトリウム、オルトフェニルフェノール、ジフェニル、2−イソプロピル−5−メチルフェノール、パラクロロメタキシレノール、パラヒドロキシ安息香酸n−ブチル、パラヒドロキシ安息香酸エチル、パラヒドロキシ安息香酸メチル、塩化ベンザルコニウム、塩化ベンゼトニウム、塩酸クロロへキシジン、グルコン酸クロロヘキシジン、2−ピリジンチオール−1−オキサイド、2−ピリジンチオール−1−オキシド亜鉛塩、2−ピリジンチオール−1−オキシドナトリウム、N,N′−ヘキサメチレンビス(4−カルバモイル−1−デシルピリジニウムブロマイド)、4,4′−(テトラメチレンジアミノ)ビス(1−デシルピリジニウムブロマイド)等を具体的に挙げることができる。 Examples of the bactericidal agent include compounds known as general fungicides or antibacterial agents, natural oils known to have antibacterial activity, and the like. Examples of the antifungal agent or antibacterial agent include 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, and 4,5-dichloro-3-n-. Octyl-isothiazolin-3-one, 1,2-benzisothiazolin-3-one, 2-methoxycarbonylbenzimidazole, 2,3,5,6-tetrachloro-4-methanesulfonylpyridine, 2-thiocyanomethibenzothiazole , 2,2-Dithio-bis- (pyridin-1-oxide), 3,3,4,5-tetrahydrothiophene-1,1-dioxide, 4,5-dichloro-1,2-dithiolan-3-3 On, 5-chloro-4-phenyl-1,2-dithiolan-3-one, N-methylpyrrolidone, phenyl- (2-cyano-2-chlorovinyl) sulfone, methylenebisthiocyanate, 2-bromo-2-nitro Propane-1,3-diol, 2,2-dibromo-2-ethanol, 2-bromo-4'-hydroxyacetophenone, dibromonitrile propionamide, 2-bromo-2-bromomethylglutalnitrile, sodium percarbonate, persulfate Potassium, sodium peroxide, orthophenylphenol, diphenyl, 2-isopropyl-5-methylphenol, parachloromethoxylenol, n-butyl parahydroxybenzoate, ethyl parahydroxybenzoate, methyl parahydroxybenzoate, benzalconium chloride , Benzethonium chloride, chlorohexidine hydrochloride, chlorohexidine gluconate, 2-pyridinethiol-1-oxide, 2-pyridinthiol-1-oxide zinc salt, 2-pyridinethiol-1-sodium oxide, N, N'-hexamethylene Specific examples thereof include bis (4-carbamoyl-1-decylpyridinium bromide) and 4,4'-(tetramethylenediamino) bis (1-decylpyridinium bromide).
また、天然製油類としては、例えば、シネオール、ヒノキチオール、メントール、テルピネオール、ボルネオール、ノポール、シトラール、シトロネラール、シトロネロール、ゲラニオール、リナロール、ジメチルオクタノール、チモール等を例示することができる。 Examples of natural oils include cineole, hinokithiol, menthol, terpineol, borneol, nopol, citral, citronellal, citronellol, geraniol, linalool, dimethyloctanol, and thymol.
さらに、ヨード系抗菌剤も例示することができ、例えば、2,3,3−トリヨードアリルアルコール類、2,3,3−トリヨードアリルエーテル類、2,3,3−トリヨードアリルアゾール類、3−ヨード−2−プロパギルブチルカルバミン酸、4−クロロフェニル(3−ヨードプロパギル)ホルマール、ヨードプロパギルアゾール類、ジヨード−パラ−トリスルホン、ポピドンヨード、ベンジルヨード酢酸エステル及びパラニトロベンジルヨード酢酸エステルを挙げることができる。 Further, iodine-based antibacterial agents can also be exemplified, for example, 2,3,3-triiodoallyl alcohols, 2,3,3-triiodoallyl ethers, 2,3,3-triiodoallylazoles. , 3-Iodo-2-propagilbutylcarbamic acid, 4-chlorophenyl (3-iodopropagil) formal, iodopropagilazoles, diiodo-para-trisulfone, popidone iodine, benzyliodoacetic acid ester and paranitrobenzyliodoacetic acid Esther can be mentioned.
除草剤は、浸透移行性を有すること、人への安全性が高いことが必要である。これらの要件を満たし、効率よく被着体を枯死させることができる除草剤としては、アミノ酸生合成阻害剤が挙げられる。アミノ酸生合成阻害剤には、グルタミンの生合成を阻害するグルタミン合成酵素阻害剤、必須アミノ酸である分枝アミノ酸の生合成を阻害する分枝アミノ酸生合成阻害剤(アセト乳酸合成酵素(ALS)阻害剤)、及び芳香族アミノ酸の生合成を阻害する芳香族アミノ酸生合成阻害剤(5−エノールピルボイルシキミ酸−3−リン酸(EPSP)合成酵素活性阻害剤)がある。その中でも、アセト乳酸合成酵素(ALS)阻害剤及び5−エノールピルボイルシキミ酸−3−リン酸(EPSP)合成酵素活性阻害剤が好ましい。これらの除草剤は、いずれか1種で用いてもよく、生合成を抑制するアミノ酸の種類を問わず、複数を混合して使用してもよい。 Herbicides need to be osmotic and transferable and highly safe for humans. Examples of herbicides that satisfy these requirements and can efficiently kill adherends include amino acid biosynthesis inhibitors. Amino acid biosynthesis inhibitors include glutamine synthase inhibitors that inhibit glutamine biosynthesis and branched amino acid biosynthesis inhibitors (acetolactic synthase (ALS) inhibitors) that inhibit the biosynthesis of branched amino acids, which are essential amino acids. Agents) and aromatic amino acid biosynthesis inhibitors (5-enolpyruvoyl simimic acid-3-phosphate (EPSP) synthase activity inhibitors) that inhibit the biosynthesis of aromatic amino acids. Among them, an acetolactic acid synthase (ALS) inhibitor and a 5-enol pyruvoyl shikimic acid-3-phosphate (EPSP) synthase activity inhibitor are preferable. Any one of these herbicides may be used, or a plurality of these herbicides may be mixed and used regardless of the type of amino acid that suppresses biosynthesis.
アセト乳酸合成酵素(ALS)阻害剤としては、スルホニルウレア系、イミダゾリノン系、トリアゾロピリミジン系、ピリミジニル(チオ)ベンゾエート系、スルホニルアミノカルボニルトリアゾリノン系を挙げることができる。
スルホニルウレア系の有効成分は、アミドスルフロン、アジムスルフロン、ベンスルフロンメチル、クロリムロンエチル、クロルスルフロン、シノスルフロン、シクロスルファムロン、エタメトスルフロンメチル、エトキシスルフロン、フラザスルフロン、フルピルスルフロン、ホラムスルフロン、ハロスルフロンメチル、イマゾスルフロン、ヨードスルフロン、メソスルフロン、メトスルフロンメチル、ニコスルフロン、オキサスルフロン、プリミスルフロン、プロスルフロン、ピラゾスルフロンエチル、リムスルフロン、スルホメツロンメチル、スルホスルフロン、チフェンスルフロンメチル、トリアスルフロン、トリフロキシスルフロン、トリフルスルフロンメチル、トリトスルフロンが挙げられる。
イミダゾリノン系の有効成分は、イマザピック、イマザメタベンズメチル、イマザモックス、イマザピル、イマザキン、イマゼタピルが挙げられる。
トリアゾロピリミジン系の有効成分は、クロランスラムメチル、ジクロスラム、フロラスラム、フルメツラム、メトスラム、ペノキススラムが挙げられる。
ピリミジニル(チオ)ベンゾエート系の有効成分は、ビスピリバック−ナトリウム塩、ピリベンゾキシム、ピリフタリド、ピリチオバック−ナトリウム塩、ピリミノバックメチルが挙げられる。
スルホニルアミノカルボニルトリアゾリノン系の有効成分は、フルカルバゾン−ナトリウム塩、プロポキシカルバゾン−ナトリウム塩が挙げられる。
Examples of the acetolactic acid synthase (ALS) inhibitor include sulfonylureas, imidazolinones, triazolopyrimidines, pyrimidinyl (thio) benzoates, and sulfonylaminocarbonyltriazolinones.
The active ingredients of the sulfonylurea system are amide sulfurone, azim sulfurone, benzulfuron methyl, chlorimlon ethyl, chlorsulfuron, sinosulfuron, cyclosulfamron, etamethosulfuron methyl, ethoxysulfuron, frazasulfone, flupyrsulfurone. , Holamsulfuron, Halosulfuron Methyl, Imazosulfuron, Iodosulfuron, Mesosulfuron, Methosulfuron Methyl, Nicosulfuron, Oxasulfuron, Primisulfuron, Prosulfuron, Pyrazosulfuron Ethyl, Lithulfuron, Sulfomethuron Methyl, Sulfos Examples thereof include rufuron, thifensulfuron-methyl, triasulfuron, trifloxysulfuron, triflusulfuron-methyl, and tritosulfuron.
Examples of the imidazolinone-based active ingredient include imazapic, imazametabenzmethyl, imazamox, imazapill, imazakin, and imazetapill.
Examples of the active ingredient of the triazolopyrimidine system include chloranthrammethyl, dicroslam, floraslam, flumethuram, metoslam, and penokislam.
Examples of the active ingredient of the pyrimidinyl (thio) benzoate system include bispyridac-sodium salt, pyribenzoxim, pyriphthalide, pyrithiobac-sodium salt, and pyriminobacmethyl.
Examples of the active ingredient of the sulfonylaminocarbonyltriazolinone system include flucarbazone-sodium salt and propoxycarbazone-sodium salt.
5−エノールピルボイルシキミ酸−3−リン酸(EPSP)合成酵素活性阻害剤としては、グリシン系が挙げられる。有効成分としては、グリホサート、グリホサートトリメシウム塩(スルホサート)が挙げられる。 Examples of the 5-enol pyruvoyl shikimic acid-3-phosphate (EPSP) synthase activity inhibitor include glycine type. Examples of the active ingredient include glyphosate and glyphosate trimesium salt (sulfosate).
除草剤の量は、有用植物への影響を考慮して、樹皮5cm2に対して、1μg以上4500μg以下であることが好ましく、3μg以上3000μg以下であることがより好ましい。このような除草剤の量となるように、濃度と量を調整することが好ましい。 The amount of the herbicide is preferably 1 μg or more and 4500 μg or less, and more preferably 3 μg or more and 3000 μg or less, with respect to 5 cm 2 of the bark, in consideration of the influence on useful plants. It is preferable to adjust the concentration and amount so that the amount of the herbicide is such.
植物成長調整剤化合物としては、1−メチルシクロプロペン、1,3−ジフェニルウレア、2,3,5−トリヨード安息香酸、IAA、IBA、MCPA、MCPB、4-CPA、5−アミノレブリン酸塩酸塩、6−ベンジルアミノプリン、アブシシン酸、AVG、アンシミドール、炭酸カルシウム、塩化カルシウム等のカルシウム類、クロルメコートクロリド、クロロプロファム、塩化コリン、クロプロップ、シアナミド、シクラニリド、ダミノジッド、デカン−1−オール、ジクロプロップ、ジケグラック、ジメチピン、ジクワット、エテホン、エチクロゼート、フルメトラリン、フルルプリミドール、ホルクロルフェヌロン、ホルモノネチン、ジベレリンA、ジベレリンA3、ヒメキサゾール、イナベンフィド、イソプロチオラン、カイネチン、リポキトオリゴ糖、メフルイジド、酸化型グルタチオン、ペンディメタリン、シントフェン、シアン酸ナトリウム、ストレプトマイシン、チジアズロン、トリアペンテノール、ウニコナゾールP、3−[(6−クロロ−4−フェニルキナゾリン−2−イル)アミノ]プロパン−1−オールなどが挙げられる。 Plant growth regulator compounds include 1-methylcyclopropene, 1,3-diphenylurea, 2,3,5-triiodobenzoic acid, IAA, IBA, MCPA, MCPB, 4-CPA, 5-aminolevphosphate, 6-Cylins such as benzylaminopurine, abscisic acid, AVG, ansimidol, calcium carbonate, calcium chloride, chlormecot chloride, chloroprofem, choline chloride, cloprop, cyanamide, cyclanilide, daminozide, decane-1- All, dicloprop, dikeglack, dimethipin, diquat, etephone, ethicrozeto, flumethoralin, furluprimidol, forchlorphenurone, formononetin, diberelin A, dibererin A3, himexazole, inabenfide, isoprothiolane, kinetin, lipochito-oligosaccharide Examples thereof include pendimethalin, syntophen, sodium cyanate, streptomycin, tidiazulone, triapentenol, uniconazole P, 3-[(6-chloro-4-phenylquinazoline-2-yl) amino] propan-1-ol and the like.
これらの薬剤の含有量は、通常0.01質量%以上99質量%以下、好ましくは1質量%以上80質量%以下、より好ましくは2質量%以上50質量%以下、さらに好ましくは10質量%以上30質量%以下の範囲である。 The content of these agents is usually 0.01% by mass or more and 99% by mass or less, preferably 1% by mass or more and 80% by mass or less, more preferably 2% by mass or more and 50% by mass or less, still more preferably 10% by mass or more. The range is 30% by mass or less.
−薬剤濃度−
粘着剤層中の農薬濃度としては、粘着剤層用組成物100質量%に対して、0.1質量%以上20質量%以下であることが好ましく、1質量%以上10質量%以下であることがより好ましい。
-Drug concentration-
The pesticide concentration in the pressure-sensitive adhesive layer is preferably 0.1% by mass or more and 20% by mass or less, and 1% by mass or more and 10% by mass or less, based on 100% by mass of the composition for the pressure-sensitive adhesive layer. Is more preferable.
粘着剤層12は、任意成分として、液状ゴム、架橋剤、軟化剤(可塑剤)、pH調整剤、酸化防止剤(抗酸化剤、防腐剤)、充填剤、紫外線吸収剤、光安定剤及び着色料等の、粘着剤層に通常配合され得る添加剤を含有してもよい。
The pressure-
(剥離紙)
本発明の植物用貼付剤10は、ロール状あるいはシート状として提供するために、粘着剤層側の表面に剥離紙を貼付してもよい。貼付される剥離紙としては、例えば、ポリエチレンテレフタレート(PET)、ポリブチレンテレフタレート、ポリエチレンナフタレート、無延伸ポリプロピレン、延伸ポリプロピレン、ポリエチレン、ポリウレタン、ポリ塩化ビニル、ポリスチレン等のプラスチックフィルム;上記のプラスチックフィルムに離型処理を施した加工シート;紙;紙に、ポリエチレンやポリプロピレンなどのプラスチックフィルムやそれらに離型処理を施した加工シートを積層したラミネート加工紙;これらのフィルム又はシートを相互に積層させた積層フィルム又はシートなどの、無色又は着色したシートを用いることができる。
剥離紙の厚さは、特に限定されないが、10μm以上500μm以下が好ましく、20μm以上300μm以下がより好ましく、40μm以上200μm以下が更に好ましい。
(Release paper)
In order to provide the
The thickness of the release paper is not particularly limited, but is preferably 10 μm or more and 500 μm or less, more preferably 20 μm or more and 300 μm or less, and further preferably 40 μm or more and 200 μm or less.
また、本発明の植物用貼付剤10は、製品の保存安定性の観点から、例えば遮光性のあるアルミ袋に密閉されていてもよい。
Further, the
本発明の植物用貼付剤10の製造方法は特に限定されないが、一例として、粘着剤層12及び農薬を混合して粘着剤層用組成物を調製し、これを基材11上に塗布し、乾燥工程を経ることによって得ることができる。本実施形態で使用する粘着剤層の中には、粘着剤層中での農薬の安定化、貼付したときの農薬の浸透性を促進させるために添加剤を混合することができる。
The method for producing the
[植物用貼付剤の使用方法]
本発明の植物用貼付剤10は、植物又は樹木の茎又は幹に粘着剤層12を密着させるように巻き付け、枯死するまで、所望の日数、放置して使用するものである。
例えば、一年性及び多年性の広葉雑草、クズなどのつる性類、雑かん木の場合は、30日以上放置することが好ましい。ササ類、大型の樹木の場合は、45日以上放置することが好ましい。
茎又は幹の植物用貼付剤10を巻き付ける場所は、特に制限はなく、適宜選択してよい。
[How to use plant patches]
The
For example, in the case of annual and perennial broad-leaved weeds, vines such as kudzu, and weeds, it is preferable to leave them for 30 days or more. In the case of bamboo grass and large trees, it is preferable to leave them for 45 days or more.
The place where the
本発明の植物用貼付剤は、除草剤が設けられた粘着性シートを幹又は茎に巻き付けるだけであるため、除草剤を希釈して散布する手間が省かれ、有用植物に影響を及ぼすことなく対象植物のみを枯死させることができる。
また、本発明の植物用貼付剤は、従来の散布方法と同程度の濃度の農薬溶液に比べ少量で効率よく作用するため、土壌の汚染や、周囲へのドリフト、作業者への被曝を抑えることができる。
Since the patch for plants of the present invention simply wraps an adhesive sheet provided with a herbicide around the trunk or stem, the trouble of diluting and spraying the herbicide is saved, and it does not affect useful plants. Only the target plant can be killed.
In addition, the plant patch of the present invention works efficiently with a small amount as compared with the pesticide solution having the same concentration as the conventional spraying method, so that soil contamination, drift to the surroundings, and exposure to workers are suppressed. be able to.
また、本発明の植物用貼付剤は、粘着剤にエマルジョン系粘着剤又はハイドロコロイド系粘着剤を用いることにより、植物の茎や葉の貼付された部分が密閉され、植物から放出される水分が大気中に放出されず、粘着剤層と植物の間の湿度が上昇する。この水分(湿度)が、粘着剤層の農薬を効率的に植物へ放出及び浸透させると推測する。また、蒸散された水分によって、粘着剤層のエマルジョン系粘着剤又はハイドロコロイド系粘着剤が時間経過とともに白濁する。本発明の植物用貼付剤は、粘着剤層が白濁すると、基材が透明又は半透明であるため、使用中又は使用後に植物用貼付剤を貼付した位置を見つけやすいという利点がある。着色剤を用いた場合は、貼付前と貼付後で色調が異なるため、効果は同様に発現する。 Further, in the plant patch of the present invention, by using an emulsion-based pressure-sensitive adhesive or a hydrocolloid-based pressure-sensitive adhesive, the stems and leaves of the plant are sealed, and the moisture released from the plant is released to the atmosphere. Not released into, the humidity between the adhesive layer and the plant rises. It is presumed that this moisture (humidity) efficiently releases and permeates the pesticides in the pressure-sensitive adhesive layer into the plants. Further, the vaporized water causes the emulsion-based pressure-sensitive adhesive or the hydrocolloid-based pressure-sensitive adhesive in the pressure-sensitive adhesive layer to become cloudy with the passage of time. The plant patch of the present invention has an advantage that when the pressure-sensitive adhesive layer becomes cloudy, the base material is transparent or translucent, so that it is easy to find the position where the plant patch is applied during or after use. When a colorant is used, the color tone is different before and after application, so that the effect is exhibited in the same manner.
特に、粘着剤層中に薬剤を添加して粘着機能と除草機能の両方を持たせようとすると、薬剤と粘着剤層を構成する材料との相性から、除草剤を所望の量添加できない場合があるため、貼付剤中の薬物の放出性を考慮して粘着剤を選択する必要がある。本発明の植物用貼付剤は、適用時に植物が生きていたことを確認することができ、対象植物を確実に枯死させることが可能であり、土壌の汚染や、周囲へのドリフト、作業者への被曝を抑えることができる。また生分解性のフィルムを基材に用いた場合は、土壌中に廃棄した場合に分解されて自然に還るため好ましい。 In particular, when an agent is added to the pressure-sensitive adhesive layer to have both an adhesive function and a herbicidal function, the herbicide may not be added in a desired amount due to the compatibility between the agent and the material constituting the pressure-sensitive adhesive layer. Therefore, it is necessary to select the pressure-sensitive adhesive in consideration of the release property of the drug in the patch. The plant patch of the present invention can confirm that the plant was alive at the time of application, can surely kill the target plant, pollute the soil, drift to the surroundings, and to the worker. Exposure can be suppressed. Further, when a biodegradable film is used as a base material, it is preferable because it is decomposed and naturally returns when it is discarded in soil.
以下、本発明の実施例について説明する。
実施例及び比較例に用いる、基材、粘着剤層の材料、対象植物、及び農薬(除草剤)を以下に示す。
(1)基材:
・ポリオレフィン系材料(ポリエチレンフィルム、厚さ100μm)
・ポリエステル系材料(ポリ乳酸フィルム、厚さ50μm)
・セルロース系材料(セロファンフィルム、厚さ35μm)
・蒸着アルミポリエチレンテレフタレート(蒸着アルミPET、厚さ25μm)
(2)粘着剤層:
・アクリルエマルジョン系粘着剤(2−エチルヘキシルアクリレート(2-EHA)をベースにした粘着剤)
・溶剤系アクリル粘着剤(2−エチルヘキシルアクリレート(2-EHA)をベースにした粘着剤)
・ハイドロコロイド系粘着剤(SIS/LIR30/水添テルペン樹脂/CMC)
なお、SISは、スチレン・イソブチレン・スチレンを意味し、LIR30は、株式会社クラレ製のポリイソプレンを意味し、CMCは、カブボキシメチルセルロースを意味する。
(3)対象植物:ツバキ
(4)農薬:除草剤(イマザピル(ALS阻害剤))
Hereinafter, examples of the present invention will be described.
The base material, the material of the pressure-sensitive adhesive layer, the target plant, and the pesticide (herbicide) used in Examples and Comparative Examples are shown below.
(1) Base material:
-Polyolefin-based material (polyethylene film, thickness 100 μm)
-Polyester-based material (polylactic acid film, thickness 50 μm)
・ Cellulose-based material (cellophane film, thickness 35 μm)
-Evaporated aluminum polyethylene terephthalate (deposited aluminum PET, thickness 25 μm)
(2) Adhesive layer:
-Acrylic emulsion adhesive (adhesive based on 2-ethylhexyl acrylate (2-EHA))
-Solvent-based acrylic adhesive (adhesive based on 2-ethylhexyl acrylate (2-EHA))
-Hydrocolloid adhesive (SIS / LIR30 / hydrogenated terpene resin / CMC)
In addition, SIS means styrene, isobutylene, styrene, LIR30 means polyisoprene manufactured by Kuraray Co., Ltd., and CMC means cubboxymethyl cellulose.
(3) Target plants: Camellia (4) Pesticides: Herbicides (Imazapill (ALS inhibitor))
[実施例1]
アクリルエマルジョン系粘着剤(2−EHA系)に農薬濃度が5質量%となるように除草剤を添加して、粘着剤層用組成物を調製した。この粘着剤層用組成物を、シリコーン系剥離剤を塗布した剥離シート上に、粘着剤厚が30μmとなるように塗布及び乾燥し、紫外線吸収剤であるチヌビン0.01%を含有したポリエチレンフィルム基材(100μm)とラミネートして裁断し、植物用貼付剤を作製した。
[Example 1]
A herbicide was added to the acrylic emulsion-based pressure-sensitive adhesive (2-EHA-based) so that the pesticide concentration was 5% by mass to prepare a composition for the pressure-sensitive adhesive layer. This pressure-sensitive adhesive layer composition is applied and dried on a release sheet coated with a silicone-based release agent so that the pressure-sensitive adhesive thickness is 30 μm, and a polyethylene film containing 0.01% of tinubin, which is an ultraviolet absorber, is contained. It was laminated with a base material (100 μm) and cut to prepare a plant patch.
[実施例2]
基材として、生分解性のあるポリ乳酸フィルム(厚さ50μm)を用い、粘着剤厚を50μmとした以外は、実施例1と同様に植物用貼付剤を作製した。
[Example 2]
A biodegradable polylactic acid film (thickness 50 μm) was used as a base material, and a plant patch was prepared in the same manner as in Example 1 except that the pressure-sensitive adhesive thickness was 50 μm.
[実施例3]
アクリルエマルジョン系粘着剤の代わりに、粘着剤として、ハイドロコロイド系粘着剤(組成比:SIS/LIR30/水添テルペン樹脂/CMC/農薬=27/9/23/10/26)を用いて、粘着剤層の厚さを200μmとし、支持体をセロファンフィルム(厚さ35μm)とした以外は実施例1と同様に植物用貼付剤を作製した。
[Example 3]
Instead of the acrylic emulsion adhesive, a hydrocolloid adhesive (composition ratio: SIS / LIR30 / hydrogenated terpene resin / CMC / pesticide = 27/9/23/10/26) is used as the adhesive. A plant patch was prepared in the same manner as in Example 1 except that the layer thickness was 200 μm and the support was a cellophane film (thickness 35 μm).
[比較例1]
基材として、蒸着アルミPETを用いた以外は、実施例1と同様に、植物用貼付剤を作製した。
[Comparative Example 1]
A plant patch was prepared in the same manner as in Example 1 except that the vapor-deposited aluminum PET was used as the base material.
[比較例2]
実施例1の植物用貼付剤をアルミパネルに貼付して、野外で放置した。
[Comparative Example 2]
The plant patch of Example 1 was attached to an aluminum panel and left in the open air.
[比較例3]
実施例1のアクリルエマルジョン系粘着剤(2−EHA系)を、溶剤系アクリル粘着剤(2−EHA系)とした以外は、実施例1と同様に、植物用貼付剤を作製した。
[Comparative Example 3]
A plant patch was prepared in the same manner as in Example 1 except that the acrylic emulsion-based pressure-sensitive adhesive (2-EHA-based) of Example 1 was used as a solvent-based acrylic pressure-sensitive adhesive (2-EHA-based).
次に、本発明の植物用貼付剤の実用試験を行った。 Next, a practical test of the plant patch of the present invention was conducted.
[実用試験]
上記実施例及び比較例について、以下のようにして実用試験を行い、試験前後に後述の評価を行った。
1.上記実施例、比較例の植物用貼付剤をツバキの土面から約2〜3cm離した箇所に巻きつけた。
2.試験期間:2019年6月16日から2019年9月5日まで
[Practical test]
Practical tests were conducted on the above Examples and Comparative Examples as follows, and the evaluations described below were performed before and after the tests.
1. 1. The plant patches of the above Examples and Comparative Examples were wrapped around a place about 2 to 3 cm away from the soil surface of camellia.
2. Examination period: From June 16, 2019 to September 5, 2019
[評価]
上記実施例及び比較例について、以下の評価項目について評価した。評価結果を表1に示す。
[evaluation]
The following evaluation items were evaluated for the above Examples and Comparative Examples. The evaluation results are shown in Table 1.
(残葉の状態)
ツバキの葉の状況を観察し、以下の基準で評価した。
A:樹木全体の葉の80%以上が落葉している
B:樹木全体の50%以上80%未満が落葉している
C:樹木全体の50%未満が落葉している
(State of remaining leaves)
The condition of camellia leaves was observed and evaluated according to the following criteria.
A: More than 80% of the leaves of the whole tree are deciduous B: 50% or more and less than 80% of the whole tree is deciduous C: Less than 50% of the whole tree is deciduous
(粘着剤の着色(白濁)の状態)
期間終了時に、粘着剤が着色(白濁)し、基材を通して粘着剤の着色が確認できるかどうか調べた。
A:基材を通して粘着剤が白濁又は着色していることを確認した
B:基材を通して粘着剤の色を確認できなかったため、貼付剤を剥離したところ粘着剤が白濁又は着色していた
C:粘着剤は白濁又は着色していなかった
(Adhesive coloring (white turbidity))
At the end of the period, it was examined whether the adhesive was colored (white turbid) and the coloring of the adhesive could be confirmed through the base material.
A: It was confirmed that the adhesive was cloudy or colored through the base material B: The color of the adhesive was not confirmed through the base material, so when the patch was peeled off, the adhesive was cloudy or colored C: Adhesive was not cloudy or colored
表1に示すように、透明なフィルムを用いた実施例1から3については、樹木全体の80%以上の葉が落葉しており、農薬の効き目が良好であることがわかった。また、透明な基材を用いているので、基材を通して粘着剤の着色又は白濁状態を観察できた。
一方、基材として蒸着アルミPETフィルムを用いた比較例1では、農薬の効き目は良好であったが、基材を通して、粘着剤の着色又は白濁の状況を観察できなかった。
また、比較例2では、粘着剤の着色又は白濁がなかった。
さらに、溶剤系アクリル粘着剤を用いた比較例3では、農薬の効き目は確認できたが、粘着剤は着色又は白濁しなかった。
As shown in Table 1, in Examples 1 to 3 using the transparent film, 80% or more of the leaves of the whole tree had fallen, and it was found that the effect of the pesticide was good. Moreover, since a transparent base material was used, it was possible to observe the coloring or cloudiness of the pressure-sensitive adhesive through the base material.
On the other hand, in Comparative Example 1 in which the vapor-deposited aluminum PET film was used as the base material, the effect of the pesticide was good, but the state of coloring or cloudiness of the adhesive could not be observed through the base material.
Further, in Comparative Example 2, there was no coloring or cloudiness of the pressure-sensitive adhesive.
Further, in Comparative Example 3 using the solvent-based acrylic pressure-sensitive adhesive, the effect of the pesticide was confirmed, but the pressure-sensitive adhesive was not colored or clouded.
以上より、本発明の植物用貼付剤は、エマルジョン系粘着剤又はハイドロコロイド系粘着剤を用いることにより、粘着剤が、樹木からの水分を吸収して着色又は白濁することがわかった。また、透明又は半透明の基材を用いていることにより、使用中から使用後にかけて薬剤の効果を確認することができ、使用後には貼付箇所が判明しやすい。 From the above, it was found that, in the plant patch of the present invention, by using an emulsion-based pressure-sensitive adhesive or a hydrocolloid-based pressure-sensitive adhesive, the pressure-sensitive adhesive absorbs water from trees and becomes colored or clouded. Further, by using a transparent or translucent base material, the effect of the drug can be confirmed from during use to after use, and the attachment location can be easily identified after use.
10 植物用貼付剤
11 基材
12 粘着剤層
10 Plant patch 11
Claims (5)
前記粘着剤層が、薬剤とエマルジョン系粘着剤又はハイドロコロイド系粘着剤とを含有する植物用貼付剤。 It has a transparent or translucent base material and an adhesive layer provided on one surface of the base material.
A plant patch in which the pressure-sensitive adhesive layer contains a drug and an emulsion-based pressure-sensitive adhesive or a hydrocolloid-based pressure-sensitive adhesive.
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