JP2021147720A - cotton - Google Patents

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JP2021147720A
JP2021147720A JP2020048207A JP2020048207A JP2021147720A JP 2021147720 A JP2021147720 A JP 2021147720A JP 2020048207 A JP2020048207 A JP 2020048207A JP 2020048207 A JP2020048207 A JP 2020048207A JP 2021147720 A JP2021147720 A JP 2021147720A
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fiber
cotton
fibers
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JP7513408B2 (en
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亮多 宮越
Ryota Miyakoshi
亮多 宮越
守 櫛野
Mamoru Kushino
守 櫛野
周平 井原
Shuhei Ihara
周平 井原
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Asahi Kasei Advance Corp
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Abstract

To provide environment-friendly granular cotton that has moisture-absorptive heat generation, moisture absorbing/releasing and heat-retaining properties.SOLUTION: Cotton is formed by mixing hygroscopic fibers at the blending ratio of 20 wt.% to 60 wt.% and hydrophobic fibers at the blending ratio of 80 wt.% to 40 wt.%. The hygroscopic fiber is at least one or more types selected from a group of vegetable fiber kapok, animal fiber, and cellulose fiber. The blending ratio of the vegetable fiber kapok is 0.1 wt.% to 40 wt.%. The hydrophobic fiber is a synthetic fiber. The granular cotton is substantially spherical cotton having a circular or oval shaped appearance with a diameter of 0.5 mm to 30 mm.SELECTED DRAWING: Figure 1

Description

本発明は、主に衣料及び寝装寝具等に用いられる、吸湿発熱性、吸放湿性、及び保温性に優れた環境配慮型の粒状のわたに関する。 The present invention relates to an environment-friendly granular cotton that is mainly used for clothing, bedding, etc., and has excellent hygroscopic heat generation, moisture absorption / desorption, and heat retention.

従来から、冬の寒冷時期には身体の保温性を得るために、表地布帛などの間に、羽毛や中入れわたといった保温材などを使用した、外気と内衣や肌との間に空気層を有する断熱構造とした防寒衣類、寝具を使用している。
このように保温性を持たせる目的で使用される素材形態としては、羽毛、わた、最近では、粒状わたといった素材が使用されているのが一般的になってきている。
他方、吸放湿性、吸湿発熱性を有するアクリル系繊維やセルロース系繊維が開発されている。これらの繊維をわたに適用して温かさや軽さの機能を発現することも試みられているが、単に混用するだけでは、わた内の緻密な空気層が得られないことから、保温性に関して十分満足できるものは得られていない。
また、近年では、世界的に地球環境への意識が高まっており、廃プラスチック化や二酸化炭素の排出量の削減といった課題が企業に課せられている。また、この取り組みは。企業イメージにも大きく左右されるところである。
Conventionally, in order to obtain heat retention of the body in the cold winter season, an air layer is provided between the outside air and the inner garment or skin by using a heat insulating material such as feathers or inner cloth between the outer fabric and the like. We use cold-weather clothing and bedding that have a heat insulating structure.
As a material form used for the purpose of providing heat retention in this way, materials such as feathers, cotton, and recently, granular cotton have become common.
On the other hand, acrylic fibers and cellulosic fibers having hygroscopicity and heat absorption and heat generation have been developed. Attempts have been made to apply these fibers to the cotton to develop the functions of warmth and lightness, but simply mixing them does not provide a dense air layer inside the cotton, so heat retention is sufficient. I haven't got anything that I'm happy with.
Moreover, in recent years, awareness of the global environment has been increasing worldwide, and companies have been faced with issues such as waste plasticization and reduction of carbon dioxide emissions. Also, what is this initiative? It is also greatly influenced by the corporate image.

これらの問題を解決するため、一手法として、天然繊維素材を選定することが挙げられる。例えば、わた、麻、カポック、パンヤ、亜麻、大麻、芋麻、羊毛、アルパカ、カシミヤ、モヘヤなどが代表的であるが、その中でも最近一注目を浴びているのが植物繊維のカポックである。
一般に、植物繊維カポックは、これまで、軽量、撥水性、繊維が緻密な特性を持つ素材であることから、救命胴衣などの資材分野、枕やぬいぐるみなどの寝具、雑貨品の単なる詰めわたとして使用されていた。
しかしながら、植物繊維カポックのわた生産における加工に関しては、いくつかの問題点があった。その一つは、わた状にするとき、繊維長が短いため繊維が脱落し易いことである、また、製品のドライクリーニング後の繊維のへたりが発生し、高品質なわたを提供する上ではカポックの使用は敬遠されていた。
In order to solve these problems, one method is to select a natural fiber material. For example, cotton, hemp, kapok, panya, flax, cannabis, potato hemp, wool, alpaca, cashmere, mohair, etc. are typical, but among them, the plant fiber kapok has recently attracted a lot of attention.
In general, plant fiber kapok has been used as a material field such as life jackets, bedding such as pillows and stuffed animals, and mere stuffing of miscellaneous goods because it is a material that is lightweight, water repellent, and has dense fibers. It had been.
However, there are some problems with the processing of plant fiber kapok in cotton production. One of them is that the fibers are easy to fall off due to the short fiber length when they are made into cotton, and the fibers are settled after dry cleaning of the product, so that high quality cotton can be provided. The use of kapok was shunned.

以下の特許文献1では、繊維の粒状体を大きく丸く作るための方法が記載されているが、風合いが硬かったり、へたり易いという問題がある。
また、以下の特許文献2では、ポリトリメチレンテレフタレート短繊維を一定混率以上含ませることで風合い、弾力性を向上させる方法が開示されているが、吸湿発熱性、吸放湿性を謳えるものではない。
また、以下の特許文献3では、カポック綿の脱落を防止するために他の素材と結合剤を介して不均一に混合結合されている複合基材が開示されているが、結合剤を付与した後にキュアリングする工程が必要であり、風合いが低下、生産性も悪化することから実用化は進んでいない。
The following Patent Document 1 describes a method for making fiber granules into a large round shape, but there is a problem that the texture is hard or easily settled.
Further, Patent Document 2 below discloses a method of improving texture and elasticity by containing polytrimethylene terephthalate short fibers in a certain mixing ratio or more, but it does not claim hygroscopic heat generation and moisture absorption / desorption. No.
Further, in Patent Document 3 below, a composite base material that is non-uniformly mixed and bonded to another material via a binder in order to prevent the kapok cotton from falling off is disclosed, but a binder is added. A process of curing is required later, and the texture is lowered and the productivity is also deteriorated, so that the practical use has not progressed.

特許3990350号Patent No. 3990350 特開2018−178304号公報JP-A-2018-178304 特開昭54−88368号公報Japanese Unexamined Patent Publication No. 54-88368

かかる従来技術の問題点に鑑み、本発明が解決しようとする課題は、吸湿発熱性、吸放湿性、及び保温性を兼ね備えた環境配慮型の粒状のわたを提供することである。 In view of the problems of the prior art, an object to be solved by the present invention is to provide an environment-friendly granular wadding that has hygroscopic heat generation, moisture absorption and desorption, and heat retention.

本願発明者らは、かかる課題を解決すべく鋭意検討し実験を重ねた結果、軽くて、緻密であるうえに、中空率約80%という高中空天然繊維であるという植物繊維カポックの特徴を生かして、保温性、断熱効果の特性を発現させるために、主にこの植物繊維カポックを使用し、羊毛、アルパカ、カシミヤなどの動物繊維とセルロース繊維と合成繊維を適正な混率で用いてわたを作ることで、わた本来の必要とされる特性(吸湿発熱性、吸放湿性、保温率)が得られることを予想外に見出し、本願発明を完成するに至ったものである。 As a result of diligent studies and experiments to solve this problem, the inventors of the present application have taken advantage of the characteristics of plant fiber Capoc, which is a highly hollow natural fiber with a hollow ratio of about 80%, in addition to being light and dense. In order to develop the characteristics of heat retention and heat insulation effect, this plant fiber capoc is mainly used, and animal fibers such as wool, alpaca, and cashmere, cellulose fibers, and synthetic fibers are used in an appropriate mixing ratio to make cotton. As a result, it was unexpectedly found that the originally required characteristics (moisture absorption and heat generation, moisture absorption and desorption, heat retention rate) of the fiber could be obtained, and the present invention was completed.

すなわち、本発明は以下のとおりのものである。
[1]混率20wt%〜60wt%の吸湿性繊維と混率80wt%〜40wt%の疎水性繊維が混合されてなるわたであって、該吸湿性繊維は、植物繊維カポック、動物繊維、及びセルロース繊維から成る群から選ばれる少なくとも1種以上であり、該植物繊維カポックの混率は、0.1wt%〜40wt%であり、該疎水性繊維は、合成繊維であり、かつ、該粒状のわたは、直径が0.5〜30mmの円形又は楕円形の外観を呈することを特徴とする略球状形態のわた。
[2]吸湿発熱値が3℃〜8℃であり、吸放湿性が3%〜15%であり、かつ、保温性が60%〜85%である、前記[1]に記載のわた。
[3]前記植物繊維カポックの単繊維繊度が、0.15dtex以上0.30dtex以下である、前記[1]又は[2]に記載のわた。
[4]前記合成繊維の単繊維繊度が、1.0dtex以上10dtex以下である、前記[1]〜[3]のいずれかに記載のわた。
[5]前記動物繊維の混率が0.1wt%以上40wt%以下であり、かつ、単繊維直径が10μm以上25μm以下である、前記[1]〜[4]のいずれかに記載のわた。
[6]前記セルロース繊維の混率が0.1wt%以上40wt%以下であり、かつ、単繊維繊度が、1.0dtex以上10dtex以下である、前記[1]〜[5]のいずれかに記載のわた。
That is, the present invention is as follows.
[1] Moisture-absorbing fibers having a mixing ratio of 20 wt% to 60 wt% and hydrophobic fibers having a mixing ratio of 80 wt% to 40 wt% are mixed, and the hygroscopic fibers are plant fiber capoc, animal fiber, and cellulose fiber. At least one selected from the group consisting of, the mixing ratio of the plant fiber capoc is 0.1 wt% to 40 wt%, the hydrophobic fiber is a synthetic fiber, and the granular wadding is. A substantially spherical wadding characterized by exhibiting a circular or oval appearance with a diameter of 0.5 to 30 mm.
[2] The cotton according to the above [1], wherein the heat absorption and heat generation value is 3 ° C to 8 ° C, the hygroscopicity is 3% to 15%, and the heat retention is 60% to 85%.
[3] The cotton according to the above [1] or [2], wherein the single fiber fineness of the plant fiber kapok is 0.15 dtex or more and 0.30 dtex or less.
[4] The cotton according to any one of [1] to [3] above, wherein the single fiber fineness of the synthetic fiber is 1.0 dtex or more and 10 dtex or less.
[5] The item according to any one of [1] to [4] above, wherein the mixing ratio of the animal fibers is 0.1 wt% or more and 40 wt% or less, and the single fiber diameter is 10 μm or more and 25 μm or less.
[6] The above-mentioned [1] to [5], wherein the mixing ratio of the cellulose fibers is 0.1 wt% or more and 40 wt% or less, and the single fiber fineness is 1.0 dtex or more and 10 dtex or less. cotton.

本発明に係るわたは、吸湿性繊維としての植物繊維カポック及び疎水性繊維としての合成繊維を適正な混率でバランスよく混綿することで、わた本来の特性である吸湿発熱性、吸放湿性、及び保温性に優れる環境配慮型の粒状わたであるため、例えば、防寒衣類、布団やクッションなどの寝装寝具、スポーツ・アウトドア用品等に好適に利用可能である。 The cotton according to the present invention is made by blending plant fiber Capoc as a hygroscopic fiber and synthetic fiber as a hydrophobic fiber in a well-balanced manner at an appropriate mixing ratio, so that the original characteristics of the cotton are hygroscopic heat generation, moisture absorption and desorption, and moisture absorption and desorption. Since it is an environment-friendly granular cotton having excellent heat retention, it can be suitably used for, for example, cold-weather clothing, bedding such as futons and cushions, sports / outdoor equipment, and the like.

図1は、本実施形態のわたの外観写真である。FIG. 1 is an external photograph of the cotton of the present embodiment. 図2は、本実施形態のわたの概略図である。FIG. 2 is a schematic view of the cotton of the present embodiment.

以下、本発明の実施形態について詳細に説明する。
本実施形態のわたは、混率20wt%〜60wt%の吸湿性繊維と混率80wt%〜40wt%の疎水性繊維が混合されてなるわたであって、該吸湿性繊維は、植物繊維カポック、動物繊維、及びセルロース繊維から成る群から選ばれる少なくとも1種以上であり、該植物繊維カポックの混率は、0.1wt%〜40wt%であり、該疎水性繊維は、合成繊維であり、かつ、該粒状のわたは、直径が0.5mm〜30mmの円形又は楕円形の外観を呈することを特徴とする略球状形態のわたである。
Hereinafter, embodiments of the present invention will be described in detail.
The cotton of the present embodiment is a cotton obtained by mixing a hygroscopic fiber having a mixing ratio of 20 wt% to 60 wt% and a hydrophobic fiber having a mixing ratio of 80 wt% to 40 wt%, and the hygroscopic fiber is a plant fiber capoc or an animal fiber. , And at least one selected from the group consisting of cellulose fibers, the mixing ratio of the plant fiber capoc is 0.1 wt% to 40 wt%, and the hydrophobic fibers are synthetic fibers and the granules. The wadding is a substantially spherical wadding characterized by exhibiting a circular or oval appearance having a diameter of 0.5 mm to 30 mm.

本実施形態のわたは、吸湿発熱値が3℃〜8℃であり、吸放湿性が3%〜15%であり、かつ、保温性が60%〜85%であることが好ましい。
前記植物繊維カポックの単繊維繊度は0.15dtex以上0.30dtex以下であることが好ましい。
前記合成繊維の単繊維繊度は1.0dtex以上10dtex以下であることが好ましい。
前記動物繊維の混率は0.1wt%以上40wt%以下であり、かつ、単繊維直径が10μm以上25μm以下であることが好ましい。
前記セルロース繊維の混率は0.1wt%以上40wt%以下であり、かつ、単繊維繊度が、1.0dtex以上10dtex以下であることが好ましい。
It is preferable that the cotton of the present embodiment has a heat absorption and heat generation value of 3 ° C. to 8 ° C., a hygroscopicity of 3% to 15%, and a heat retention property of 60% to 85%.
The single fiber fineness of the plant fiber kapok is preferably 0.15 dtex or more and 0.30 dtex or less.
The single fiber fineness of the synthetic fiber is preferably 1.0 dtex or more and 10 dtex or less.
The mixing ratio of the animal fibers is preferably 0.1 wt% or more and 40 wt% or less, and the single fiber diameter is preferably 10 μm or more and 25 μm or less.
It is preferable that the mixing ratio of the cellulose fibers is 0.1 wt% or more and 40 wt% or less, and the single fiber fineness is 1.0 dtex or more and 10 dtex or less.

本実施形態のわたは、吸湿性繊維と疎水性繊維が混合されてなり、吸湿性繊維の少なくとも一部に植物繊維カポック(以下、カポック繊維ともいう。)が含有されている。
本明細書中、用語「吸湿性繊維」とは、天然植物繊維カポック、動物繊維、セルロース繊維等の公定水分率6%以上の繊維をいう。
カポックとは、東南アジアを中心に広く生育されるパンヤ科の木であり、その種子から採れる繊維(わた毛)を利用する目的で広く栽培されている。天然植物繊維カポックは、繊維長2mm〜7mmほどの環境負荷が小さい植物繊維であり、極めて軽くて、緻密であるうえに、中空率約80%という高中空構造であることを特徴とする。
The cotton of the present embodiment is a mixture of hygroscopic fibers and hydrophobic fibers, and at least a part of the hygroscopic fibers contains plant fiber kapok (hereinafter, also referred to as kapok fiber).
In the present specification, the term "hygroscopic fiber" refers to a fiber having an official moisture content of 6% or more, such as natural plant fiber kapok, animal fiber, and cellulose fiber.
Kapok is a tree of the Panya family that grows widely mainly in Southeast Asia, and is widely cultivated for the purpose of utilizing the fiber (fluff) obtained from its seeds. The natural plant fiber Kapok is a plant fiber having a fiber length of about 2 mm to 7 mm and having a small environmental load, and is characterized by being extremely light and dense, and having a high hollow structure having a hollow ratio of about 80%.

本実施形態のわたには、吸湿性繊維である、植物繊維カポック、動物繊維、及びセルロース繊維が、合計混率20wt%〜60wt%で含まれていることを特徴とする。合計混率が20wt%未満であると、わたに必要とされる吸湿発熱性、吸放湿性、及び/又は保温性が損なわれる。他方、合計混率が60wt%を超えると、疎水性繊維である合成繊維、例えば、ポリエステル繊維の混率が低下することから、かさ高性や洗濯耐久性が著しく低下し、わた形態が保持されず、商品性が失われる。吸湿性繊維である、植物繊維カポック、動物繊維、及びセルロース繊維の合計混率は、好ましくは25wt%〜50wt%である。 The cotton of the present embodiment is characterized by containing plant fiber kapok, animal fiber, and cellulose fiber, which are hygroscopic fibers, in a total mixing ratio of 20 wt% to 60 wt%. If the total mixing ratio is less than 20 wt%, the heat absorption and heat absorption, moisture absorption and desorption, and / or heat retention required for cotton are impaired. On the other hand, when the total mixing ratio exceeds 60 wt%, the mixing ratio of the synthetic fiber which is a hydrophobic fiber, for example, polyester fiber is lowered, so that the bulkiness and washing durability are remarkably lowered, and the wadding form is not maintained. Commerciality is lost. The total mixing ratio of the hygroscopic fibers, such as plant fiber kapok, animal fiber, and cellulose fiber, is preferably 25 wt% to 50 wt%.

本実施形態のわたには、カポック繊維が0.1wt%以上40wt%以下の混率で含まれる必要がある。カポック繊維の混率が40wt%を超えると、わた製品でのカポック繊維の脱落が多くなり、縫製時でのカポック繊維の飛散などで作業環境を悪化させることや、衣料製品の着用時や洗濯などでのカポック繊維の脱落により、わたとしての機能低下や、わたを縫い合わした衣料表面の外見が悪くなる。他方、0.1wt%未満では所望の効果が発現されない。カポック繊維の混率は、好ましくは1.0wt%以上35wt%以下であり、より好ましくは10wt%以上30wt%以下である。 The cotton of the present embodiment needs to contain kapok fibers in a mixing ratio of 0.1 wt% or more and 40 wt% or less. If the mixing ratio of kapok fibers exceeds 40 wt%, the kapok fibers will fall off more often in the cotton products, which will worsen the working environment due to the scattering of the kapok fibers during sewing, and when wearing clothing products or washing. Due to the shedding of the Kapok fibers, the function of the wadding deteriorates and the appearance of the garment surface on which the wadding is sewn deteriorates. On the other hand, if it is less than 0.1 wt%, the desired effect is not exhibited. The mixing ratio of the kapok fibers is preferably 1.0 wt% or more and 35 wt% or less, and more preferably 10 wt% or more and 30 wt% or less.

本実施形態のわたには、吸湿性繊維として、カポック繊維以外に動物繊維が40wt%以下の混率で含まれていてもよい。動物繊維としては、羊毛、アンゴラ、カシミヤなどが挙げられる。カポック繊維、セルロース繊維は、捲縮が少ないため、繊維同士が絡みにくく加工が難しいとされているが、動物繊維は捲縮性があるため絡みやすく、繊維がかさ高になり、かつ弾力性も出るためへたり性にも効果が得られる。動物繊維の混率が0.1wt%以上であることが好ましく、より好ましくは1.0wt%以上30wt%以下である。 The cotton of the present embodiment may contain animal fibers in addition to kapok fibers at a mixing ratio of 40 wt% or less as hygroscopic fibers. Examples of animal fibers include wool, angora, and cashmere. Kapok fibers and cellulose fibers are said to be difficult to process because they have little crimping, so they are difficult to entangle with each other. Since it comes out, it is also effective for sagging. The mixing ratio of animal fibers is preferably 0.1 wt% or more, more preferably 1.0 wt% or more and 30 wt% or less.

本実施形態のわたには、吸湿性繊維として、カポック繊維以外にセルロース繊維が40wt%以下の混率で含まれていてもよい。セルロース繊維としては、天然繊維の綿、麻や、再生セルロース繊維のキュプラ・アンモニウム・レーヨン、ビスコース・レーヨン、溶剤紡糸セルロース繊維などが挙げられる。セルロース繊維の混率が0.1wt%以上であることがより好ましく、特に好ましくは1.0wt%以上30wt%以下である。 In addition to the kapok fiber, the cotton of the present embodiment may contain cellulose fiber in a mixing ratio of 40 wt% or less as the hygroscopic fiber. Examples of the cellulose fiber include natural fibers such as cotton and linen, recycled cellulose fibers such as cupra ammonium rayon, biscous rayon, and solvent-spun cellulose fibers. The mixing ratio of the cellulose fibers is more preferably 0.1 wt% or more, and particularly preferably 1.0 wt% or more and 30 wt% or less.

本実施形態のわたには、疎水性繊維である合成繊維が40wt%〜80wt%の混率で含まれる。混率がこの範囲であれば、吸湿性繊維の効果を下げずに、わたとしての強度等の特性を付与でき、かさ高性や洗濯耐久性に優れ、特にドライクリーニング後のへたりやわたの偏りを抑制し、必要とされるわた形態を保持することができる。合成繊維としてはポリエステル繊維、ポリアミド繊維(ナイロン)などが挙げられるが、植物由来のポリ乳酸繊維であれば、エコ商品として謳うことができ、好ましい。 The cotton of the present embodiment contains synthetic fibers, which are hydrophobic fibers, in a mixing ratio of 40 wt% to 80 wt%. If the mixing ratio is within this range, characteristics such as strength as wadding can be imparted without deteriorating the effect of hygroscopic fibers, and it is excellent in bulkiness and washing durability. Can be suppressed and the required morphology can be retained. Examples of synthetic fibers include polyester fibers and polyamide fibers (nylon), but plant-derived polylactic acid fibers can be sung as eco-friendly products and are preferable.

本実施形態のわたの直径とは、図2に示すように、粒状わた毛羽部分中心の粒わた部分の直径D(mm)と、一方から飛び出している毛羽部分の長さをL1(mm)、さらに粒状わた部分を挟んで反対側から飛び出している毛羽部分の長さをL2(mm)としたとき、それぞれの値の和(D+L1+L2)をわたの直径とする。これらは拡大顕微鏡等を用いて容易に測定可能であり、例えば以下の実施例においてはKEYENCE社製デジタルマイクロスコープVHX―2000を用いて測定を行った。 As shown in FIG. 2, the diameter of the fluff of the present embodiment is the diameter D (mm) of the fluff portion at the center of the granular fluff portion and the length of the fluff portion protruding from one side is L 1 (mm). Further, when the length of the fluff portion protruding from the opposite side across the granular cotton portion is L 2 (mm), the sum of the respective values (D + L 1 + L 2 ) is defined as the diameter of the cotton. These can be easily measured using a magnifying microscope or the like. For example, in the following examples, the measurement was performed using a digital microscope VHX-2000 manufactured by KEYENCE.

本実施形態のわたは、粒状わた表面から飛び出した毛羽部分を有しており、粒状わた毛羽部分中心の粒わた部分の直径をD(mm)、一方から飛び出している毛羽部分の長さをL1(mm)としたとき、毛羽部分の長さL1と粒の直径Dとの比率が、0.2≦L1/D≦3の範囲であれば、毛羽部分同士が絡むことにより、わたの膨らみを保持し、偏りを軽減し、保温性をより良好なものにすることができる。L2についても同様であり、L1とL2を併せてLと表記した時に、0.2≦L/D≦3の範囲であれば好ましく、より好ましくは0.5≦L/D≦2である。 The cotton of the present embodiment has a fluff portion protruding from the surface of the granular fluff, the diameter of the fluff portion at the center of the granular fluff portion is D (mm), and the length of the fluff portion protruding from one side is L. When it is set to 1 (mm), if the ratio of the length L 1 of the fluff portion to the diameter D of the grain is in the range of 0.2 ≦ L 1 / D ≦ 3, the fluff parts are entangled with each other and cotton is cottoned. It can retain the bulge of the cotton, reduce the bias, and improve the heat retention. The same applies to L 2 , and when L 1 and L 2 are collectively expressed as L, the range of 0.2 ≦ L / D ≦ 3 is preferable, and more preferably 0.5 ≦ L / D ≦ 2. Is.

本実施形態のわたは、粒状であって、その直径が0.5mm〜30mmの円形又は楕円形の外観を呈する略球状形態にあることを特徴とする。本明細書中、用語「粒状のわた」とは、繊維を開繊、混綿させた後、粒わた生成機にてボール状に生成されたものである。
本実施形態のわたの直径が0.5mm未満であると粒状わたを充填させた際に粒わた部分同士が密になり商品として重く、膨らみの無い風合いとなり、他方、直径が30mmを超えると十分な充填率を満たせず、審美性、機能性が損なわれる。本実施形態の粒わたの直径は好ましくは5mm以上15mm以下である。
The cotton of the present embodiment is characterized in that it is granular and has a substantially spherical shape having a circular or elliptical appearance having a diameter of 0.5 mm to 30 mm. In the present specification, the term "granular cotton" is produced in a ball shape by a grain cotton generator after the fibers are opened and mixed with cotton.
When the diameter of the cotton of the present embodiment is less than 0.5 mm, when the granular cotton is filled, the grained parts become dense and the product is heavy and has no bulge. On the other hand, when the diameter exceeds 30 mm, it is sufficient. The filling rate is not satisfied, and the aesthetics and functionality are impaired. The diameter of the grain of the present embodiment is preferably 5 mm or more and 15 mm or less.

本実施形態のわたを構成する各繊維は、わたの性能を満足させるために、それぞれ以下の形状であることが好ましい。
カポック繊維は、繊維長7mm〜15mm、単繊維繊度0.15dtex以上0.30dtex以下であることが好ましい。
動物繊維は、天然繊維であるため不均一な形状であるが、繊維長30mm〜100mm、単繊維直径10μm以上25μm以下であることが好ましい。
セルロース繊維は、繊維長36mm〜51mm、単繊維繊度1.0dtex以上10dtex以下であることが好ましい。
合成繊維は、繊維長30mm〜60mm、単繊維繊度1.0dtex以上10dtex以下であることが好ましい。
Each fiber constituting the cotton of the present embodiment preferably has the following shape in order to satisfy the performance of the cotton.
The kapok fiber preferably has a fiber length of 7 mm to 15 mm and a single fiber fineness of 0.15 dtex or more and 0.30 dtex or less.
Since the animal fiber is a natural fiber, it has a non-uniform shape, but it is preferably a fiber length of 30 mm to 100 mm and a single fiber diameter of 10 μm or more and 25 μm or less.
The cellulose fibers preferably have a fiber length of 36 mm to 51 mm and a single fiber fineness of 1.0 dtex or more and 10 dtex or less.
The synthetic fiber preferably has a fiber length of 30 mm to 60 mm and a single fiber fineness of 1.0 dtex or more and 10 dtex or less.

本実施形態のわたは、後述する方法で測定される吸湿発熱値が3℃〜8℃、吸放湿性が3〜15%、及び保温性が60%〜85%という優れた性能を発現することができる。 The cotton of the present embodiment exhibits excellent performance such that the heat absorption and heat generation value measured by the method described later is 3 ° C to 8 ° C, the moisture absorption and desorption property is 3 to 15%, and the heat retention property is 60% to 85%. Can be done.

以下、実施例、比較例により本発明を具体的に説明する。
尚、以下の実施例では、具体的な材料名や数値等を挙げて説明しているが、本発明はこれらに限定されるものではないことは言うまでもない。
各繊維の公定水分率としては、JIS 0105 繊維製品の物理試験方法通則記載の測定方法で測定した値を採用した。
わたの直径は、前述のKEYENCE社製デジタルマイクロスコープVHX―2000を用いてD、L1、及びL2の測定を行った。このとき、サンプルから粒を6点選択し、それぞれの顕微鏡視野における水平方向、垂直方向に計2回測定を行い、あわせて12回の測定平均を求めた。L/Dは各測定におけるL1/DとL2/Dの、あわせて24回の測定平均を求めた。
Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples.
In the following examples, specific material names, numerical values, and the like are given for explanation, but it goes without saying that the present invention is not limited thereto.
As the official moisture content of each fiber, the value measured by the measuring method described in the general rules of the physical test method for JIS 0105 textile products was adopted.
The diameter of the cotton was measured for D, L 1 , and L 2 using the above-mentioned digital microscope VHX-2000 manufactured by KEYENCE. At this time, 6 grains were selected from the sample, and measurements were performed twice in total in the horizontal and vertical directions in each microscope field of view, and a total of 12 measurement averages were obtained. For L / D, the average of 24 measurements of L 1 / D and L 2 / D in each measurement was calculated.

(実施例1)
天然植物繊維カポック(繊度0.15dtex〜0.30dtex、繊維長9mm〜15mm、公定水分率6%以上)、動物繊維カシミヤ(繊維長25mm〜90mm、単繊維直径12μm〜20μm、公定水分率15%)、ポリエステル繊維(繊度3.3dtex、繊維長51mm、公定水分率0.4%)を20:10:70の比率で、開繊、混綿させた後、粒わた生成機にてボール状に生成し、直径が9.5mm、L/Dが0.8である円形又は楕円形の外観を有する略球状形態に形成されたわたを得た。
(Example 1)
Natural plant fiber capoc (fineness 0.15 dtex to 0.30 dtex, fiber length 9 mm to 15 mm, official moisture content 6% or more), animal fiber cashmere (fiber length 25 mm to 90 mm, single fiber diameter 12 μm to 20 μm, official moisture content 15%) ), Polyester fiber (fineness 3.3dtex, fiber length 51mm, official moisture content 0.4%) was opened and mixed at a ratio of 20:10:70, and then formed into a ball shape with a grain generator. A wadding formed in a substantially spherical shape having a circular or oval appearance having a diameter of 9.5 mm and an L / D of 0.8 was obtained.

(実施例2)
植物繊維カポックとセルロース繊維(繊度1.4dtex、繊維長51mm、公定水分率11%)とポリエステル繊維を20:30:50の比率で、含有させる以外は、実施例1と同様にして開繊、混綿させた後、粒わた生成機にてボール状に生成し、直径が9.8mm、L/Dが0.7である円形又は楕円形の外観を有する略球状形態に形成されたわたを得た。
(Example 2)
Opened in the same manner as in Example 1 except that the plant fiber Kapok, the cellulose fiber (fineness 1.4 dtex, fiber length 51 mm, official moisture content 11%) and polyester fiber are contained at a ratio of 20:30:50. After the cotton was mixed, the cotton was formed into a ball shape by a grain wadding generator to obtain a wadding formed into a substantially spherical shape having a circular or oval appearance having a diameter of 9.8 mm and an L / D of 0.7. rice field.

(実施例3)
植物繊維カポックとポリエステル繊維を30:70の比率で含有させる以外は、実施例1と同様にして開繊、混綿させた後、粒わた生成機にてボール状に生成し、直径が10.0mm、L/Dが1.0である円形又は楕円形の外観を有する略球状形態に形成されたわたを得た。
(Example 3)
After opening and mixing cotton in the same manner as in Example 1 except that the plant fiber kapok and polyester fiber are contained in a ratio of 30:70, the fibers are formed into balls by a grain generator and have a diameter of 10.0 mm. , A wadding formed in a substantially spherical shape having a circular or elliptical appearance having an L / D of 1.0 was obtained.

(比較例1)
ポリエステル繊維(繊度3.3dtex、繊維長51mm、公定水分率0.4%)を開繊、混綿させた後、粒わた生成機にてボール状に生成し、直径が13.8mm、L/Dが0.5である円形又は楕円形の外観を有する略球状形態に形成されたわたを得た。
(Comparative Example 1)
Polyester fibers (fineness 3.3 dtex, fiber length 51 mm, official moisture content 0.4%) are opened and mixed, and then formed into balls by a grain generator to have a diameter of 13.8 mm and L / D. A wadding formed in a substantially spherical shape having a circular or elliptical appearance having a value of 0.5 was obtained.

以上のようにして作成された実施例、比較例のわたについて、吸湿発熱性、吸放湿性、保温性を以下のようにして測定、評価した。評価結果を以下の表1に示す。 With respect to the cotton of Examples and Comparative Examples prepared as described above, the hygroscopic heat generation property, the hygroscopic heat absorption property, and the heat retention property were measured and evaluated as follows. The evaluation results are shown in Table 1 below.

(1)吸湿発熱値(℃)
わた試料5gを恒温乾燥機内で105℃、1時間放置させた後、一般に言う環境試験室にて、温度20℃、湿度5%RHの環境下6時間放置させた後、温度20℃、湿度65%RHの環境下に5分間放置したときのわたの表面変化温度のピーク値を赤外線サーモグラフィーにて測定して、高湿度環境による温度上昇(℃)を算出した。
(1) Hygroscopic heat generation value (° C)
After leaving 5 g of the cotton sample in a constant temperature dryer at 105 ° C. for 1 hour, it was left in an environment of a temperature of 20 ° C. and a humidity of 5% RH for 6 hours in a so-called environmental test room, and then the temperature was 20 ° C. and the humidity was 65. The peak value of the surface change temperature of the cotton when left in an environment of% RH for 5 minutes was measured by infrared thermography, and the temperature rise (° C.) due to a high humidity environment was calculated.

(2)吸放湿性(%)
わた試料5gを恒温乾燥機内で105℃、2時間放置させて絶乾状態にした後、このわた重量を基に、温度30℃、湿度95%RHの初期環境下に5時間放置させた後、温度30℃、湿度30%RH環境下に5時間放置した時のわたの重量変化を経時的に測定していき、わたの絶乾重量から算出される吸湿された初期の環境下での水分率の最大値から、その後の環境下で放出された水分率の最小値の差を算出した。
(2) Moisture absorption and desorption (%)
5 g of the cotton sample was left in a constant temperature dryer at 105 ° C. for 2 hours to be in an absolute dry state, and then based on the weight of the cotton, it was left to stand in an initial environment of a temperature of 30 ° C. and a humidity of 95% RH for 5 hours, and then the temperature. The change in the weight of the wadding when left in an RH environment at 30 ° C. and a humidity of 30% for 5 hours is measured over time, and the moisture content in the initial moisture-absorbed environment calculated from the absolute dry weight of the wadding is measured. From the maximum value, the difference between the minimum values of the moisture content released in the subsequent environment was calculated.

(3)保温性(%)及びclo値
JIS L 1096 A法(恒温法)に準じて測定するものであり、外気温度は、23.0℃、発熱体表面温度は、36.0℃とした。
(3) Heat retention (%) and clo value Measured according to the JIS L 1096 A method (constant temperature method), the outside air temperature was 23.0 ° C, and the heating element surface temperature was 36.0 ° C. ..

Figure 2021147720
Figure 2021147720

本発明に係るわたは、天然繊維カポック、動物繊維、セルロース繊維、及び合成繊維を適正な混率でバランスよく混綿することで、吸湿発熱性、吸放湿性、保温性などの高い機能を有する、環境配慮型の粒状わたであるため、例えば、防寒衣類に好適に利用可能である。 The cotton according to the present invention has high functions such as moisture absorption and heat generation, moisture absorption and desorption, and heat retention by mixing natural fiber kapok, animal fiber, cellulose fiber, and synthetic fiber in a well-balanced manner at an appropriate mixing ratio. Since it is a consideration type granular wadding, it can be suitably used for, for example, cold weather clothing.

Claims (6)

混率20wt%〜60wt%の吸湿性繊維と混率80wt%〜40wt%の疎水性繊維が混合されてなるわたであって、該吸湿性繊維は、植物繊維カポック、動物繊維、及びセルロース繊維から成る群から選ばれる少なくとも1種以上であり、該植物繊維カポックの混率は、0.1wt%〜40wt%であり、該疎水性繊維は、合成繊維であり、かつ、該粒状のわたは、直径が0.5mm〜30mmの円形又は楕円形の外観を呈することを特徴とする略球状形態のわた。 It is a mixture of hygroscopic fibers with a mixing ratio of 20 wt% to 60 wt% and hydrophobic fibers with a mixed ratio of 80 wt% to 40 wt%, and the hygroscopic fibers are a group consisting of plant fiber capoc, animal fiber, and cellulose fiber. At least one selected from the above, the mixing ratio of the plant fiber capoc is 0.1 wt% to 40 wt%, the hydrophobic fiber is a synthetic fiber, and the granular wadding has a diameter of 0. Approximately spherical wadding characterized by exhibiting a circular or oval appearance of .5 mm to 30 mm. 吸湿発熱値が3℃〜8℃であり、吸放湿性が3%〜15%であり、かつ、保温性が60%〜85%である、請求項1に記載のわた。 The cotton according to claim 1, wherein the heat absorption and heat generation value is 3 ° C. to 8 ° C., the moisture absorption and desorption property is 3% to 15%, and the heat retention property is 60% to 85%. 前記植物繊維カポックの単繊維繊度が、0.15dtex以上0.30dtex以下である、請求項1又は2に記載のわた。 The cotton according to claim 1 or 2, wherein the single fiber fineness of the plant fiber kapok is 0.15 dtex or more and 0.30 dtex or less. 前記合成繊維の単繊維繊度が、1.0dtex以上10dtex以下である、請求項1〜3のいずれか1項に記載のわた。 The cotton according to any one of claims 1 to 3, wherein the single fiber fineness of the synthetic fiber is 1.0 dtex or more and 10 dtex or less. 前記動物繊維の混率が0.1wt%以上40wt%以下であり、かつ、単繊維直径が10μm以上25μm以下である、請求項1〜4のいずれか1項に記載のわた。 The item according to any one of claims 1 to 4, wherein the mixing ratio of the animal fibers is 0.1 wt% or more and 40 wt% or less, and the single fiber diameter is 10 μm or more and 25 μm or less. 前記セルロース繊維の混率が0.1wt%以上40wt%以下であり、かつ、単繊維繊度が、1.0dtex以上10dtex以下である、請求項1〜5のいずれか1項に記載のわた。 The item according to any one of claims 1 to 5, wherein the mixing ratio of the cellulose fibers is 0.1 wt% or more and 40 wt% or less, and the single fiber fineness is 1.0 dtex or more and 10 dtex or less.
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