JP2021120959A - Electric wire with terminal - Google Patents

Electric wire with terminal Download PDF

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JP2021120959A
JP2021120959A JP2021084612A JP2021084612A JP2021120959A JP 2021120959 A JP2021120959 A JP 2021120959A JP 2021084612 A JP2021084612 A JP 2021084612A JP 2021084612 A JP2021084612 A JP 2021084612A JP 2021120959 A JP2021120959 A JP 2021120959A
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resin member
terminal
coated
crimping
electric wire
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JP7146019B2 (en
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泰 木原
Yasushi Kihara
泰 木原
信昭 酒井
Nobuaki Sakai
信昭 酒井
正和 小澤
Masakazu Ozawa
正和 小澤
弘哲 中山
Hirotetsu Nakayama
弘哲 中山
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Furukawa Electric Co Ltd
Furukawa Automotive Systems Inc
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Furukawa Electric Co Ltd
Furukawa Automotive Systems Inc
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Abstract

To provide an electric wire with a terminal, capable of preventing water from entering an inner part of a crimp part.SOLUTION: An electric wire with a terminal 10 is structured by a terminal 1 and a coated electric wire 11, etc. The terminal 1 is formed by a terminal main body 3 and a crimp part 5. The crimp part 5 is a portion crimped to the coated electric wire 11, and includes a substantially U-shaped barrel form in a cross-sectional shape vertical to a longitudinal direction of the terminal 1 before crimping. The crimp part 5 of the terminal 1, is formed by a conducting wire crimp part 7 crimping the electric wire exposed from a coated part on a tip end side of the coated electric wire and a coated crimp part 9 crimping a coated part 15 of the coated electric wire 11. The conducting wire crimp part 7 and the coated crimp part 9 are coated with a resin member 17, and at least an electric wire 13 is not exposed to an external part by the resin member 17. That is, the resin member 17 is coated over an exposure part of the electric wire 13 on the tip end side of the conducting wire crimp part 7 from the coated part 15 in the coated crimp part 9, and is coated with the resin member 17.SELECTED DRAWING: Figure 1

Description

本発明は例えば自動車等に用いられる端子付き電線に関するものである。 The present invention relates to an electric wire with a terminal used in, for example, an automobile.

従来、自動車、OA機器、家電製品等の分野では、電力線や信号線として、電気導電性に優れた銅系材料からなる電線が使用されている。特に、自動車分野においては、車両の高性能化、高機能化が急速に進められており、車載される各種電気機器や制御機器が増加している。したがって、これに伴い、使用される端子付き電線も増加する傾向にある。 Conventionally, in the fields of automobiles, OA equipment, home appliances, etc., electric wires made of copper-based materials having excellent electrical conductivity have been used as power lines and signal lines. In particular, in the field of automobiles, the performance and functionality of vehicles are rapidly increasing, and the number of various electric devices and control devices mounted on vehicles is increasing. Therefore, along with this, the number of electric wires with terminals used tends to increase.

一方、環境問題が注目される中、自動車の軽量化が要求されている。したがって、ワイヤハーネスの使用量増加に伴う重量増加が問題となる。このため、従来使用されている銅線に代えて、軽量なアルミニウム電線が注目されている。 On the other hand, as environmental problems are attracting attention, weight reduction of automobiles is required. Therefore, an increase in weight due to an increase in the amount of wire harness used becomes a problem. For this reason, lightweight aluminum electric wires are attracting attention in place of the conventionally used copper wires.

ここで、このような電線同士を接続する際や機器類等の接続部においては、接続用端子が用いられる。しかし、アルミニウム電線を用いた端子付き電線であっても、接続部の信頼性等のため、端子部には、電気特性に優れる銅が使用される場合がある。このような場合には、アルミニウム電線と銅製の端子とが接合されて使用される。 Here, a connection terminal is used when connecting such electric wires or at a connection portion of equipment or the like. However, even in the case of an electric wire with a terminal using an aluminum electric wire, copper having excellent electrical characteristics may be used for the terminal portion for the sake of reliability of the connecting portion and the like. In such a case, the aluminum electric wire and the copper terminal are joined and used.

しかし、異種金属を接触させると、標準電極電位の違いから、いわゆる電食が発生する恐れがある。特に、アルミニウムと銅との標準電極電位差は大きいため、接触部への水の飛散や結露等の影響により、電気的に卑であるアルミニウム側の腐食が進行する。このため、接続部における電線と端子との接続状態が不安定となり、接触抵抗の増加や線径の減少による電気抵抗の増大、更には断線が生じて電装部品の誤動作、機能停止に至る恐れがある。 However, when dissimilar metals are brought into contact with each other, so-called galvanic corrosion may occur due to the difference in standard electrode potential. In particular, since the standard electrode potential difference between aluminum and copper is large, corrosion on the electrically base aluminum side progresses due to the influence of water scattering and dew condensation on the contact portion. For this reason, the connection state between the electric wire and the terminal at the connection portion becomes unstable, and there is a risk that the electrical resistance will increase due to the increase in contact resistance and the decrease in wire diameter, and further, the disconnection will occur, resulting in malfunction or malfunction of the electrical components. be.

このため、被覆導線と端子との接続部を樹脂部材で被覆する方法が提案されている(例えば特許文献1)。 Therefore, a method of coating the connection portion between the coated conductor and the terminal with a resin member has been proposed (for example, Patent Document 1).

特開2015−153721号公報Japanese Unexamined Patent Publication No. 2015-153721

従来の方法は、端子と被覆導線を圧着した後、接続部の外周に樹脂部材を塗布して、樹脂部材で互いの接触部分を被覆するものである。しかし、被覆導線と端子との微小な隙間に樹脂部材を塗布することは困難である。特に、被覆導線の先端近傍は、被覆部が除去されて内部の導線が露出するが、被覆部の端部と導線露出部の境界部において、外径の変化に伴う微小な隙間が生じやすい。したがって、被覆部と被覆圧着部との隙間を通じて、圧着部内部に水が浸入するおそれがある。 In the conventional method, after crimping the terminal and the coated conducting wire, a resin member is applied to the outer circumference of the connecting portion, and the contact portion between the terminals is covered with the resin member. However, it is difficult to apply the resin member to the minute gap between the coated conductor and the terminal. In particular, in the vicinity of the tip of the coated conductor, the coated portion is removed and the internal conductor is exposed, but at the boundary between the end of the coated conductor and the exposed conductor, a minute gap is likely to occur due to a change in the outer diameter. Therefore, water may infiltrate into the crimping portion through the gap between the covering portion and the coating crimping portion.

本発明は、このような問題に鑑みてなされたもので、圧着部の内部へ水が浸入することを抑制することが可能な端子付き電線を提供することを目的とする。 The present invention has been made in view of such a problem, and an object of the present invention is to provide an electric wire with a terminal capable of suppressing water from entering the inside of a crimping portion.

前述した目的を達するために本発明は、被覆導線と端子とが接続された端子付き電線であって、前記端子は、前記被覆導線が圧着される圧着部と、端子本体とを有し、前記圧着部は、前記被覆導線の被覆部を圧着する被覆圧着部と、前記被覆部から露出する導線を圧着する導線圧着部とを有し、長手方向の少なくとも一部において、前記被覆圧着部に凹溝が形成されることなく、前記被覆圧着部と前記被覆部との間の全周にわたって樹脂部材が塗布されており、前記樹脂部材は、紫外線硬化樹脂であることを特徴とする端子付き電線である。 In order to achieve the above-mentioned object, the present invention is an electric wire with a terminal in which a coated conductor and a terminal are connected, and the terminal has a crimping portion to which the coated conductor is crimped and a terminal body. The crimping portion has a coated crimping portion that crimps the covering portion of the coated conductor wire and a conductor crimping portion that crimps the conductor exposed from the covering portion, and is recessed in the coated crimping portion at least in a part in the longitudinal direction. A resin member is applied over the entire circumference between the coated crimping portion and the coated portion without forming a groove, and the resin member is an electric wire with a terminal characterized by being an ultraviolet curable resin. be.

硬化後の前記樹脂部材の硬度が、前記被覆部の硬度よりも低いことが望ましい。 It is desirable that the hardness of the resin member after curing is lower than the hardness of the coating portion.

本発明によれば、高い防食性を確保することができる。 According to the present invention, high anticorrosion properties can be ensured.

また、この際、硬化後の樹脂部材の硬度が被覆部の硬度よりも低ければ、被覆部の圧着時に、樹脂部材が容易に変形して、被覆部と被覆圧着部との隙間を確実に埋めることができる。 Further, at this time, if the hardness of the cured resin member is lower than the hardness of the coating portion, the resin member is easily deformed at the time of crimping the coating portion, and the gap between the coating portion and the coating crimping portion is surely filled. be able to.

本発明によれば、圧着部の内部へ水が浸入することを抑制することが可能な端子付き電線を提供することができる。 According to the present invention, it is possible to provide an electric wire with a terminal capable of suppressing water from entering the crimping portion.

端子付き電線10を示す斜視図。The perspective view which shows the electric wire 10 with a terminal. 端子付き電線10の圧着前の状態を示す斜視図。The perspective view which shows the state before crimping of the electric wire 10 with a terminal. 端子付き電線10の圧着前の状態を示す断面図。The cross-sectional view which shows the state before crimping of the electric wire 10 with a terminal. 導線圧着部7を圧着した状態を示す断面図。FIG. 5 is a cross-sectional view showing a state in which the conductor crimping portion 7 is crimped. 樹脂部材17を塗布した状態を示す図。The figure which shows the state which applied the resin member 17. 被覆圧着部9を圧着した状態を示す断面図。FIG. 5 is a cross-sectional view showing a state in which the covering crimping portion 9 is crimped. (a)は、図4のA−A線断面図、(b)は、図5のB−B線断面図、(c)は、図6のC−C線断面図。(A) is a sectional view taken along line AA of FIG. 4, (b) is a sectional view taken along line BB of FIG. 5, and (c) is a sectional view taken along line CC of FIG. (a)は、図4のD部拡大、(b)は、図5のE部拡大、(c)は、図6のF部拡大。(A) is an enlargement of the D part of FIG. 4, (b) is an enlargement of the E part of FIG. 5, and (c) is an enlargement of the F part of FIG. さらに樹脂部材17aを塗布した状態を示す図。The figure which shows the state which further applied the resin member 17a. 導線圧着部7を本圧着し、被覆圧着部9を仮圧着した状態を示す図。The figure which shows the state which the conductor crimping part 7 was main crimped, and the covering crimping part 9 was temporarily crimped. 樹脂部材17を塗布した状態を示す図。The figure which shows the state which applied the resin member 17. 端子付き電線10の評価方法を示す図。The figure which shows the evaluation method of the electric wire 10 with a terminal.

以下、図面を参照しながら、本発明の実施形態について説明する。図1は、端子付き電線10を示す斜視図である。なお、図は、樹脂部材17を透視した図である。端子付き電線10は、端子1および被覆導線11等から構成される。端子1は、オープンバレル型であり、銅もしくは黄銅などの銅合金あるいはそれらにスズなどがめっきされたものが使用される。端子付き電線10は、端子1と被覆導線11が接続されて構成される。被覆導線11は、アルミニウム線またはアルミニウム合金線である導線13と、導線13を被覆する被覆部15からなる。すなわち、被覆導線11は、被覆部15と、その先端から露出する導線13とを具備する。 Hereinafter, embodiments of the present invention will be described with reference to the drawings. FIG. 1 is a perspective view showing an electric wire 10 with a terminal. The figure is a perspective view of the resin member 17. The terminal-attached electric wire 10 is composed of a terminal 1, a coated conductor wire 11, and the like. The terminal 1 is an open barrel type, and a copper alloy such as copper or brass or a terminal 1 plated with tin or the like is used. The terminal-equipped electric wire 10 is configured by connecting the terminal 1 and the coated conductor wire 11. The coated conductor 11 includes a conductor 13 which is an aluminum wire or an aluminum alloy wire, and a covering portion 15 which covers the conductor 13. That is, the coated conductor 11 includes a coated portion 15 and a conductor 13 exposed from the tip thereof.

端子1は、端子本体3と圧着部5とからなる。端子本体3は、所定の形状の板状素材を、断面が矩形の筒体に形成したものである。端子本体3は、内部に、板状素材を矩形の筒体内に折り込んで形成される弾性接触片を有する。端子本体3は、前端部から雄端子などが挿入されて接続される。なお、以下の説明では、端子本体3が、雄型端子等の挿入タブ(図示省略)の挿入を許容する雌型端子である例を示すが、本発明において、この端子本体3の細部の形状は特に限定されない。例えば、雌型の端子本体3に代えて例えば雄型端子の挿入タブを設けてもよい。 The terminal 1 includes a terminal body 3 and a crimping portion 5. The terminal body 3 is formed by forming a plate-shaped material having a predetermined shape into a tubular body having a rectangular cross section. The terminal body 3 has an elastic contact piece formed by folding a plate-shaped material into a rectangular cylinder. The terminal body 3 is connected by inserting a male terminal or the like from the front end portion. In the following description, an example is shown in which the terminal body 3 is a female terminal that allows insertion of an insertion tab (not shown) such as a male terminal. In the present invention, the detailed shape of the terminal body 3 is shown. Is not particularly limited. For example, instead of the female terminal body 3, for example, a male terminal insertion tab may be provided.

圧着部5は、被覆導線11と圧着される部位であり、圧着前において、端子1の長手方向に垂直な断面形状が略U字状のバレル形状を有する。端子1の圧着部5は、被覆導線の先端側に被覆部から露出する導線を圧着する導線圧着部7と、被覆導線11の被覆部15を圧着する被覆圧着部9とからなる。 The crimping portion 5 is a portion to be crimped to the coated conducting wire 11, and has a barrel shape having a substantially U-shaped cross section perpendicular to the longitudinal direction of the terminal 1 before crimping. The crimping portion 5 of the terminal 1 includes a lead wire crimping portion 7 that crimps a conductor exposed from the covering portion to the tip end side of the coated conducting wire, and a covering crimping portion 9 that crimps the covering portion 15 of the coated conducting wire 11.

導線圧着部7の内面の一部には、幅方向(長手方向に垂直な方向)には、図示を省略したセレーションが設けられる。このようにセレーションを形成することで、導線を圧着した際に、導線の表面の酸化膜を破壊しやすく、また、導線との接触面積を増加させることができる。 A part of the inner surface of the conductor crimping portion 7 is provided with serrations (not shown) in the width direction (direction perpendicular to the longitudinal direction). By forming the serrations in this way, when the conductor is crimped, the oxide film on the surface of the conductor is easily broken, and the contact area with the conductor can be increased.

被覆導線11の先端は、被覆部15が剥離され、内部の導線13が露出する。被覆導線11の被覆部は、端子1の被覆圧着部9によって圧着される。また、被覆部15が剥離されて露出する導線13は、導線圧着部7により圧着される。導線圧着部7において導線13と端子1とが電気的に接続される。なお、被覆部15の端面は、被覆圧着部9と導線圧着部7の間に位置する。 At the tip of the coated conductor 11, the coated portion 15 is peeled off, and the internal conductor 13 is exposed. The coated portion of the coated conductor 11 is crimped by the coated crimping portion 9 of the terminal 1. Further, the conductor 13 whose covering portion 15 is peeled off and exposed is crimped by the conductor crimping portion 7. At the conductor crimping portion 7, the conductor 13 and the terminal 1 are electrically connected. The end face of the covering portion 15 is located between the covering crimping portion 9 and the conductor crimping portion 7.

本発明では、少なくとも、被覆部15や端子1から露出する導線13が、樹脂部材17で覆われる。本実施形態では、導線圧着部7および被覆圧着部9が樹脂部材17によって被覆され、少なくとも導線13は、樹脂部材17によって外部に露出しない。すなわち、被覆圧着部9における被覆部15から導線圧着部7の先端側の導線13の露出部にわたって樹脂部材17が塗布されて、樹脂部材17によって覆われる。樹脂部材17は、例えば、シリコーンアクリレート、ウレタンアクリレート、アクリルアクリレートなどの紫外線硬化樹脂である。なお、樹脂部材17の詳細については後述する。 In the present invention, at least the conducting wire 13 exposed from the covering portion 15 and the terminal 1 is covered with the resin member 17. In the present embodiment, the conductor crimping portion 7 and the coated crimping portion 9 are covered with the resin member 17, and at least the conductor 13 is not exposed to the outside by the resin member 17. That is, the resin member 17 is applied from the covering portion 15 in the coating crimping portion 9 to the exposed portion of the conducting wire 13 on the tip side of the conducting wire crimping portion 7, and is covered by the resin member 17. The resin member 17 is, for example, an ultraviolet curable resin such as silicone acrylate, urethane acrylate, or acrylic acrylate. The details of the resin member 17 will be described later.

次に、端子付き電線10の製造方法について説明する。図2は、端子1に対して被覆導線11を配置した状態を示す斜視図であり、図3は、端子付き電線10(被覆導線11)の長手方向の断面図である。まず、被覆導線11の先端の所定長さの被覆部15を除去して、導線13を露出させる。次に、圧着部5に被覆導線11を配置する。この際、導線圧着部7には導線13の露出部が位置し、被覆圧着部9には被覆部15が位置する。 Next, a method of manufacturing the electric wire 10 with a terminal will be described. FIG. 2 is a perspective view showing a state in which the coated conductor 11 is arranged with respect to the terminal 1, and FIG. 3 is a cross-sectional view of the electric wire 10 with a terminal (coated conductor 11) in the longitudinal direction. First, the covering portion 15 having a predetermined length at the tip of the coated conducting wire 11 is removed to expose the conducting wire 13. Next, the coated conductor 11 is arranged in the crimping portion 5. At this time, the exposed portion of the conductor 13 is located in the conductor crimping portion 7, and the covering portion 15 is located in the covering crimping portion 9.

次に、図4に示すように、導線圧着部7と導線13を本圧着する(第1圧着工程)。すなわち、この状態においては、導線圧着部7のみが本圧着され、被覆圧着部9は圧着されない。 Next, as shown in FIG. 4, the conductor crimping portion 7 and the conductor 13 are main crimped (first crimping step). That is, in this state, only the conductor crimping portion 7 is main crimped, and the covering crimping portion 9 is not crimped.

次に、図5に示すように、被覆圧着部9における被覆部15から導線圧着部7の先端側の導線13の露出部にわたって樹脂部材17を塗布する(樹脂塗布工程)。すなわち、この状態においては、露出する導線13が完全に樹脂部材17によって被覆される。 Next, as shown in FIG. 5, the resin member 17 is applied from the covering portion 15 in the coating crimping portion 9 to the exposed portion of the conducting wire 13 on the tip side of the conducting wire crimping portion 7 (resin coating step). That is, in this state, the exposed conductor 13 is completely covered with the resin member 17.

なお、導線圧着部7における導線13の表面の樹脂部材17の被覆厚は、20μm以上であることが望ましい。樹脂部材17の被覆厚が十分でないと、防食性が悪くなる。 The coating thickness of the resin member 17 on the surface of the conductor 13 in the conductor crimping portion 7 is preferably 20 μm or more. If the coating thickness of the resin member 17 is not sufficient, the corrosion resistance is deteriorated.

次に、図6に示すように、被覆圧着部9と、樹脂部材17が塗布された被覆部15を本圧着する(第2圧着工程)。すなわち、この状態においては、被覆圧着部9によって、樹脂部材17とともに被覆部15が本圧着される。 Next, as shown in FIG. 6, the covering crimping portion 9 and the covering portion 15 coated with the resin member 17 are main crimped (second crimping step). That is, in this state, the covering crimping portion 9 actually crimps the covering portion 15 together with the resin member 17.

図7(a)は、図4のA−A線断面図、図7(b)は、図5のB−B線断面図、図7(c)は、図6のC−C線断面図である。また、図8(a)は、図4のD部拡大図、図8(b)は、図5のE部拡大図、図8(c)は、図6のF部拡大図である。前述したように、導線圧着部7の本圧着時には、被覆圧着部9は圧着されていない。このため、図7(a)に示すように、被覆圧着部9は、上方に向けて開口し、被覆部15と被覆圧着部9との間には、十分な隙間が生じる。特に、図8(a)に示すように、被覆部15の端部(被覆部15の端部と導線露出部の境界部周辺における導線13と端子(圧着部5)との間の隙間)には、十分な隙間が形成され、上部に開口する。 7 (a) is a sectional view taken along line AA of FIG. 4, FIG. 7 (b) is a sectional view taken along line BB of FIG. 5, and FIG. 7 (c) is a sectional view taken along line CC of FIG. Is. 8 (a) is an enlarged view of the D portion of FIG. 4, FIG. 8 (b) is an enlarged view of the E portion of FIG. 5, and FIG. 8 (c) is an enlarged view of the F portion of FIG. As described above, at the time of the main crimping of the conductor crimping portion 7, the covering crimping portion 9 is not crimped. Therefore, as shown in FIG. 7A, the covering crimping portion 9 opens upward, and a sufficient gap is formed between the covering portion 15 and the covering crimping portion 9. In particular, as shown in FIG. 8A, at the end of the covering portion 15 (the gap between the conducting wire 13 and the terminal (crimping portion 5) around the boundary between the end of the covering portion 15 and the exposed conducting wire portion). Is formed with a sufficient gap and opens at the top.

したがって、図7(b)、図8(b)に示すように、被覆圧着部9の上方から樹脂部材17を容易に塗布することができ、樹脂部材17を被覆部15と被覆圧着部9の隙間(特に、被覆部15の端部と導線露出部の境界部周辺における導線13と端子(圧着部5)との間の隙間)に浸透させることができる。 Therefore, as shown in FIGS. 7 (b) and 8 (b), the resin member 17 can be easily applied from above the coated crimping portion 9, and the resin member 17 is applied to the covering portion 15 and the covering crimping portion 9. It can penetrate into the gap (particularly, the gap between the conductor 13 and the terminal (crimping portion 5) around the boundary between the end of the covering portion 15 and the exposed portion of the conductor).

なお、本実施形態では、樹脂部材17のJIS Z 8803による塗布時(硬化前)の粘度が、10〜2000mPa・s(より望ましくは、樹脂部材17の粘度が、10〜1000mPa・s)であることが望ましい。粘度が10mPa・s未満では、樹脂部材17を塗布した際に、樹脂部材17が圧着部近傍から流れ出し、適切に被覆がされない恐れがある。粘度が1000mPa・sを超えると、樹脂部材17を塗布した際に、樹脂部材17が圧着部の内部まで十分に浸透せず、内部に隙間が生じるおそれがあり、特に粘度が2000mPa・sを超えると、樹脂部材17を被覆部15の下部に浸透させることが困難となる。 In the present embodiment, the viscosity of the resin member 17 at the time of coating (before curing) by JIS Z 8803 is 10 to 2000 mPa · s (more preferably, the viscosity of the resin member 17 is 10 to 1000 mPa · s). Is desirable. If the viscosity is less than 10 mPa · s, when the resin member 17 is applied, the resin member 17 may flow out from the vicinity of the crimping portion and may not be properly coated. If the viscosity exceeds 1000 mPa · s, when the resin member 17 is applied, the resin member 17 may not sufficiently penetrate into the crimping portion, and a gap may be formed inside. In particular, the viscosity exceeds 2000 mPa · s. Then, it becomes difficult to penetrate the resin member 17 into the lower part of the covering portion 15.

このように、樹脂部材17を塗布した状態で、被覆圧着部9を圧着することで、図7(c)、図8(c)に示すように、圧着後には、被覆部15と被覆圧着部9との隙間が狭くなる部分、特に、被覆部15の端部と導線露出部の境界部周辺における導線13と端子(圧着部5)との間の隙間も、確実に樹脂部材17で埋めることができる。 By crimping the coated crimping portion 9 with the resin member 17 coated in this way, as shown in FIGS. 7 (c) and 8 (c), after crimping, the coated portion 15 and the coated crimping portion are crimped. The portion where the gap with 9 is narrowed, particularly the gap between the conductor 13 and the terminal (crimping portion 5) around the boundary between the end of the covering portion 15 and the exposed portion of the conductor is also surely filled with the resin member 17. Can be done.

なお、樹脂部材17は、例えば紫外線硬化樹脂である。この場合、被覆圧着部9の圧着(第2圧着工程)の前に、樹脂部材17を硬化(樹脂硬化工程)させてもよく、被覆圧着部9の圧着(第2圧着工程)の後に、樹脂部材17を硬化(樹脂硬化工程)させてもよい。 The resin member 17 is, for example, an ultraviolet curable resin. In this case, the resin member 17 may be cured (resin curing step) before the coating crimping portion 9 is crimped (second crimping step), and the resin member 17 may be cured after the covering crimping portion 9 is crimped (second crimping step). The member 17 may be cured (resin curing step).

被覆圧着部9の圧着の前に、樹脂部材17を硬化させれば、図7(b)に示すように、被覆圧着部9の上方が開いており、被覆部15と被覆圧着部9の隙間も大きいため、紫外線をより深くまで照射することができる。また、被覆圧着部9の圧着時に、樹脂部材17の飛散などが生じにくい。 If the resin member 17 is cured before the coating crimping portion 9 is crimped, the upper part of the coating crimping portion 9 is open as shown in FIG. 7B, and the gap between the coating portion 15 and the coating crimping portion 9 is open. Because it is also large, it is possible to irradiate ultraviolet rays deeper. Further, when the covering crimping portion 9 is crimped, the resin member 17 is unlikely to scatter.

なお、この場合には、硬化後の樹脂部材17の硬度が、被覆部15の硬度よりも低いことが望ましい。例えば、硬化後の樹脂部材17および被覆部15の樹脂によって、それぞれ2mm厚のシートを作成し、JIS K6253−3による硬度測定を行った場合、被覆部のデュロメータ硬さはA50〜A100であり、硬化後の樹脂部材17のデュロメータ硬さはA20〜A50の範囲である。 In this case, it is desirable that the hardness of the cured resin member 17 is lower than the hardness of the covering portion 15. For example, when a sheet having a thickness of 2 mm is prepared from each of the cured resin member 17 and the resin of the covering portion 15 and the hardness is measured by JIS K6253-3, the durometer hardness of the covering portion is A50 to A100. The durometer hardness of the cured resin member 17 is in the range of A20 to A50.

このように、樹脂部材17の硬度が低いと、被覆部15を圧着した際に、樹脂部材17が容易に変形し、被覆部15と被覆圧着部9との隙間を確実に埋めることができる。 As described above, when the hardness of the resin member 17 is low, the resin member 17 is easily deformed when the covering portion 15 is crimped, and the gap between the covering portion 15 and the covering crimping portion 9 can be reliably filled.

一方、被覆圧着部9の圧着の後に、樹脂部材17を硬化させれば、被覆圧着部9の圧着時において、樹脂部材17の流動性を確保することができる。 On the other hand, if the resin member 17 is cured after the coating crimping portion 9 is crimped, the fluidity of the resin member 17 can be ensured at the time of crimping the covering crimping portion 9.

ここで、前述したように、樹脂部材17は、例えば紫外線硬化樹脂である。この場合、樹脂部材17が塗布された端子付き電線10に上方から紫外線を照射すると、導線13の影が生じる。すなわち、紫外線が、導線13の下部の樹脂部材17へ十分に照射されない恐れがある。しかし、上方から照射された紫外線は、樹脂部材17を透過し、導線13の表面や端子1の内面で反射する。このため、導線13による影部分へも、紫外線が回り込み、樹脂部材17を硬化させることができる。 Here, as described above, the resin member 17 is, for example, an ultraviolet curable resin. In this case, when the electric wire 10 with a terminal coated with the resin member 17 is irradiated with ultraviolet rays from above, the shadow of the conducting wire 13 is generated. That is, there is a possibility that the ultraviolet rays may not sufficiently irradiate the resin member 17 below the conducting wire 13. However, the ultraviolet rays emitted from above pass through the resin member 17 and are reflected on the surface of the conducting wire 13 and the inner surface of the terminal 1. Therefore, the ultraviolet rays wrap around the shadowed portion of the conducting wire 13, and the resin member 17 can be cured.

このため、樹脂部材17は、紫外線が透過しやすい樹脂であれば、より深くまで紫外線を照射することができる。そこで、本発明では、樹脂部材17の厚さ0.2mmにおける波長365nmの分光透過率を60%以上とすることが望ましい。 Therefore, the resin member 17 can be irradiated with ultraviolet rays to a deeper depth as long as it is a resin that easily transmits ultraviolet rays. Therefore, in the present invention, it is desirable that the spectral transmittance of the resin member 17 at a wavelength of 365 nm at a thickness of 0.2 mm is 60% or more.

ここで、厚さ0.2mmにおける分光透過率が60%以上とは、樹脂部材17を構成する樹脂で0.2mm厚さのシートを形成し、シートの一方の側から入射した光(例えば光照射量3000mJ/cm)が、他方へ透過する透過率である。具体的には、紫外線を照射し、所定の距離で分光光度計によって光強度I0を測定する。次に、光源と分光光度計の間に、当該シートを配置して、同様に光強度Iを測定する。この際、I/I0が厚さ0.2mmにおける分光透過率となる。 Here, when the spectral transmittance at a thickness of 0.2 mm is 60% or more, a sheet having a thickness of 0.2 mm is formed of the resin constituting the resin member 17, and light incident from one side of the sheet (for example, light). The irradiation amount of 3000 mJ / cm) is the transmittance of transmission to the other side. Specifically, the light intensity I0 is measured by a spectrophotometer at a predetermined distance by irradiating with ultraviolet rays. Next, the sheet is placed between the light source and the spectrophotometer, and the light intensity I is measured in the same manner. At this time, I / I0 is the spectral transmittance at a thickness of 0.2 mm.

なお、透過率の対数とシート厚みとは比例関係にある。具体的には、シート厚みをtとし、透過率をTとすると、t=−Dp×log10Tとなる。ここで、Dpは、硬化深度であり、シート厚みの増加に伴う透過率の減少(対数)のグラフの傾きとして表せられる。したがって、0.2mm厚以外のシートを用いて評価を行う場合には、上記式によって、そのシートの厚みに応じた透過率の範囲を算出すればよい。 The logarithm of the transmittance and the sheet thickness are in a proportional relationship. Specifically, where t is the sheet thickness and T is the transmittance, t = −Dp × log10T. Here, Dp is the curing depth and is expressed as the slope of the graph of the decrease in transmittance (logarithm) with the increase in sheet thickness. Therefore, when the evaluation is performed using a sheet having a thickness other than 0.2 mm, the range of transmittance according to the thickness of the sheet may be calculated by the above formula.

なお、透過率は、光開始剤の添加量によって調整することができる。ここで、透過率が高すぎると、樹脂部材17を視認することが困難となり、目視での品質確認が困難となるため、透過率は90%以下であることが望ましい。 The transmittance can be adjusted by the amount of the photoinitiator added. Here, if the transmittance is too high, it becomes difficult to visually recognize the resin member 17, and it becomes difficult to visually confirm the quality. Therefore, it is desirable that the transmittance is 90% or less.

なお、樹脂部材17の透過率を向上させたとしても、導線13と端子1との隙間が狭くなりすぎると、反射回数が増えるため、反射に伴う光の減衰によって、紫外線が導線13の影部に十分に回り込みにくくなる。このため、導線13と端子1との隙間を適切に設定することが望ましい。 Even if the transmittance of the resin member 17 is improved, if the gap between the conductor 13 and the terminal 1 becomes too narrow, the number of reflections increases. It becomes difficult to wrap around sufficiently. Therefore, it is desirable to appropriately set the gap between the conductor 13 and the terminal 1.

例えば、被覆圧着部9の圧着の後に、樹脂部材17を硬化する場合において、導線13と端子1との隙間は、被覆部15の端面と導線圧着部7までの距離と、被覆部15の端面における導線13と端子1との距離によって形成される。この場合、端子付き電線10の長手方向の断面における、被覆部15の端面と導線圧着部7までの距離が0.1mm以上であることが望ましく、被覆部15の端面における導線13と端子1との距離が、0.1mm以上であることが望ましい。このようにすることで、光が隙間に回り込みやすく、導線13の影部の樹脂部材17を硬化させることができる。なお、被覆部15の端面における導線13と端子1との距離は、概ね、被覆部15の厚みと言い換えることができる。 For example, when the resin member 17 is cured after the coating crimping portion 9 is crimped, the gap between the conducting wire 13 and the terminal 1 is the distance between the end face of the covering portion 15 and the conducting wire crimping portion 7, and the end face of the covering portion 15. It is formed by the distance between the conducting wire 13 and the terminal 1 in. In this case, it is desirable that the distance between the end face of the covering portion 15 and the conducting wire crimping portion 7 in the longitudinal cross section of the electric wire 10 with a terminal is 0.1 mm or more, and the conducting wire 13 and the terminal 1 on the end face of the covering portion 15 It is desirable that the distance between the two is 0.1 mm or more. By doing so, the light easily wraps around in the gap, and the resin member 17 in the shadow portion of the conducting wire 13 can be cured. The distance between the conducting wire 13 and the terminal 1 on the end surface of the covering portion 15 can be roughly rephrased as the thickness of the covering portion 15.

なお、樹脂部材17は、紫外線硬化のみではなく、紫外線硬化と湿気硬化、嫌気硬化、熱硬化などを組み合わせたハイブリッド硬化型であってもよい。このようにすることで、紫外線の照射困難な部位も容易に硬化させることができる。 The resin member 17 may be a hybrid curing type that combines not only ultraviolet curing but also ultraviolet curing, moisture curing, anaerobic curing, thermosetting, and the like. By doing so, it is possible to easily cure a portion that is difficult to irradiate with ultraviolet rays.

また、硬化させた樹脂部材17の厚さ200μmのシートを作製し、JIS K7113により25℃破断伸びを測定した際の、樹脂部材17の破断伸びは、100%以上が好ましい。このように、樹脂部材17の破断伸びが100%以上であれば、圧着後における温度変化や外力などによる膨張や変形に対して、樹脂部材17を容易に追従させることができる。 Further, when a sheet having a thickness of 200 μm of the cured resin member 17 is prepared and the breaking elongation at 25 ° C. is measured by JIS K7113, the breaking elongation of the resin member 17 is preferably 100% or more. As described above, when the breaking elongation of the resin member 17 is 100% or more, the resin member 17 can be easily made to follow the expansion and deformation due to the temperature change and the external force after crimping.

また、樹脂部材17の、JIS K6850による引張せん断接着強度は1MPa以上であることが望ましい。より詳細には、接着剤の引張せん断接着強さ試験方法により、錫めっき付銅板とアクリル板を重ね合わせて樹脂部材17で接着した際の引張せん断接着強さ、アルミ板とアクリル板を重ね合わせて樹脂部材17で接着した際の引張せん断接着強さ、および、軟質PVC板とアクリル板とを重ね合わせて樹脂部材17で接着した際の引張せん断接着強さの各々に対して、引張せん断接着強度は1MPa以上であることが望ましい。このようにすることで、樹脂部材17が導線圧着部7や被覆部15から剥がれて隙間が生じることを抑制することができる。 Further, it is desirable that the tensile shear adhesive strength of the resin member 17 according to JIS K6850 is 1 MPa or more. More specifically, according to the tensile shear adhesive strength test method of the adhesive, the tensile shear adhesive strength when the tin-plated copper plate and the acrylic plate are overlapped and bonded by the resin member 17, and the aluminum plate and the acrylic plate are overlapped. The tensile shear adhesion strength when the soft PVC plate and the acrylic plate are overlapped and adhered by the resin member 17 and the tensile shear adhesion strength when the soft PVC plate and the acrylic plate are bonded by the resin member 17 are all subjected to the tensile shear adhesion. The strength is preferably 1 MPa or more. By doing so, it is possible to prevent the resin member 17 from peeling off from the conductor crimping portion 7 and the covering portion 15 to form a gap.

また、被覆圧着部9を圧着した後、さらに、図9に示すように、樹脂部材17aを塗布してもよい。このようにすることで、被覆圧着部9の圧着時に生じた隙間等に対しても、樹脂部材17aで被覆することができる。なお、この場合、樹脂部材17と樹脂部材17aは、同じ樹脂であってもよいが、異なる樹脂であってもよい。例えば、樹脂部材17は、浸透性が高い相対的に粘度が低いものを適用し、樹脂部材17aは、被覆厚を確保するために、相対的に粘度の高いものを適用することができる。 Further, after the covering crimping portion 9 is crimped, the resin member 17a may be further applied as shown in FIG. By doing so, the resin member 17a can cover the gaps and the like generated during the crimping of the covering crimping portion 9. In this case, the resin member 17 and the resin member 17a may be the same resin, but may be different resins. For example, a resin member 17 having a high permeability and a relatively low viscosity can be applied, and a resin member 17a having a relatively high viscosity can be applied in order to secure a coating thickness.

また、本実施形態においては、図10に示すように、導線圧着部7の本圧着時に、被覆圧着部9を仮圧着(仮圧着工程)してもよい。すなわち、樹脂塗布工程の前に、被覆圧着部9と被覆部15を仮圧着してもよい。仮圧着では、被覆圧着部9は完全に被覆部15と圧着されず、十分な隙間を維持しつつ、被覆圧着部9の形状を円形に近い形に整えることができる。これにより、導線圧着部7の本圧着時に、被覆圧着部9における電線が端子底面から所定量以上浮き上がってしまい、その後の樹脂塗布工程において樹脂部材17aを適切に塗布できなくなることを防ぐことができる。 Further, in the present embodiment, as shown in FIG. 10, the coated crimping portion 9 may be temporarily crimped (temporarily crimping step) at the time of the main crimping of the conductor crimping portion 7. That is, the coating crimping portion 9 and the covering portion 15 may be temporarily crimped before the resin coating step. In the temporary crimping, the covering crimping portion 9 is not completely crimped to the covering portion 15, and the shape of the covering crimping portion 9 can be adjusted to a shape close to a circle while maintaining a sufficient gap. As a result, it is possible to prevent the electric wire in the coated crimping portion 9 from being lifted by a predetermined amount or more from the bottom surface of the terminal during the main crimping of the conducting wire crimping portion 7, and the resin member 17a cannot be properly coated in the subsequent resin coating step. ..

この状態から、図11に示すように、樹脂部材17を塗布することで、樹脂部材17を効率よく被覆部15と被覆圧着部9との隙間に浸透させることができる。このため、この後の被覆圧着部9の圧着によって、確実に樹脂部材17によって、被覆部15と被覆圧着部9との隙間を埋めることができる。 From this state, as shown in FIG. 11, by applying the resin member 17, the resin member 17 can be efficiently permeated into the gap between the covering portion 15 and the covering crimping portion 9. Therefore, by crimping the covering crimping portion 9 after this, the gap between the covering portion 15 and the covering crimping portion 9 can be surely filled by the resin member 17.

ウレタンアクリルオリゴマー、アクリルモノマー、および光開始剤を主成分とする紫外線硬化と湿気硬化の硬化機構を持つ紫外線硬化型樹脂組成物を作成し、各種条件で端子付き電線に塗布した。この際、本組成物のオリゴマー成分、モノマー成分を調整して粘度の異なる樹脂部材を作成して、防食試験を実施した。 An ultraviolet curable resin composition having a curing mechanism of ultraviolet curing and moisture curing containing urethane acrylic oligomer, acrylic monomer, and a light initiator as main components was prepared and applied to an electric wire with a terminal under various conditions. At this time, the oligomer component and the monomer component of the present composition were adjusted to prepare resin members having different viscosities, and an anticorrosion test was carried out.

防食性能は、図12に示すように、水槽31に塩水33を貯留し、端子付き電線10(端子1)を浸漬した後、端子−電線間の抵抗変動を測定することで評価を行った。塩水33の濃度は、NaCl3.0±0.5%とした。また、端子1の浸漬深さは300±10mmとした。また、水没時間は24時間とし、水没後60±5℃で、95±5%RH雰囲気に48時間の環境で放置した後に、抵抗を測定し、塩水浸漬前の抵抗と比較した。なお、電線は、0.75sqサイズを用いた。 As shown in FIG. 12, the anticorrosion performance was evaluated by storing the salt water 33 in the water tank 31, immersing the electric wire 10 with a terminal (terminal 1), and then measuring the resistance fluctuation between the terminal and the electric wire. The concentration of salt water 33 was determined to be NaCl 3.0 ± 0.5%. The immersion depth of the terminal 1 was set to 300 ± 10 mm. The submersion time was 24 hours, and after being left in an environment of 95 ± 5% RH for 48 hours at 60 ± 5 ° C. after submersion, the resistance was measured and compared with the resistance before immersion in salt water. The electric wire used was 0.75 sq size.

表1は、樹脂部材の粘度を変えて、被覆圧着前に樹脂部材を塗布した結果である。なお、以下の各実施例は、それぞれn=10で評価を行い、表中の、「防食性合否」については、n=10の全ての抵抗変動が、1.0mΩ以下であったものを「◎」とし、2.0mΩ以下であったものを「○」とした。また、n=10の一部の抵抗変動が2.0mΩを超えたものを「△」とし、n=10の全ての抵抗変動が、2.0mΩを超えたものを「×」とした。また、各樹脂部材の粘度は塗布時の粘度である。 Table 1 shows the results of applying the resin member before crimping the coating by changing the viscosity of the resin member. In addition, each of the following examples was evaluated with n = 10, and as for "corrosion-proof pass / fail" in the table, all resistance fluctuations of n = 10 were 1.0 mΩ or less. ⊚ ”and those with 2.0 mΩ or less were marked with“ ○ ”. Further, when a part of the resistance fluctuation of n = 10 exceeded 2.0 mΩ, it was designated as “Δ”, and when all the resistance fluctuations of n = 10 exceeded 2.0 mΩ, it was designated as “x”. The viscosity of each resin member is the viscosity at the time of coating.

Figure 2021120959
Figure 2021120959

樹脂部材を被覆圧着前に塗布した場合には、樹脂部材の粘度が10mPa・s〜2000mPa・sの範囲において良好な結果となり、特に、樹脂部材の粘度が10mPa・s〜1000mPa・sの範囲においては、特に良好な結果となった。粘度が3000mPa・sのものは、樹脂部材が十分に隙間に浸透せずに、防食性が劣った。 When the resin member is applied before the coating crimping, good results are obtained when the viscosity of the resin member is in the range of 10 mPa · s to 2000 mPa · s, and particularly when the viscosity of the resin member is in the range of 10 mPa · s to 1000 mPa · s. Was a particularly good result. When the viscosity was 3000 mPa · s, the resin member did not sufficiently penetrate into the gap, and the corrosion resistance was inferior.

一方、表2は、樹脂部材の粘度を変えて、被覆圧着後に樹脂部材を塗布した結果である。なお、各評価方法は表1と同様である。 On the other hand, Table 2 shows the results of applying the resin member after coating and crimping by changing the viscosity of the resin member. Each evaluation method is the same as in Table 1.

Figure 2021120959
Figure 2021120959

被覆圧着後に樹脂部材を塗布すると、樹脂部材の粘度によらず、防食性が悪い結果となった。 When the resin member was applied after the coating was pressure-bonded, the corrosion resistance was poor regardless of the viscosity of the resin member.

なお、他の径(0.5sq〜2.5sq)の導線に対しても評価を行ったところ、同様の結果となった。 When the evaluation was performed on the conductors having other diameters (0.5 sq to 2.5 sq), the same result was obtained.

以上説明したように、本実施形態によれば、樹脂部材17によって、端子1と被覆導線11との接続部を覆うため、効率良く防食効果を得ることができる。この際、被覆圧着前に樹脂部材17を塗布するため、被覆圧着後における被覆部15と被覆圧着部9との狭い隙間(特に、被覆部15の端部と導線露出部の境界部周辺における導線13と端子(圧着部5)との間の隙間)にも、確実に樹脂部材17を塗布することができる。このため、被覆部15と被覆圧着部9との隙間を伝い、被覆部15の端部と導線露出部の境界部から水が浸入することを防止することができる。したがって、被覆圧着部9の長手方向の少なくとも一部において、被覆部15と被覆圧着部9との間に、全周にわたって樹脂部材17が塗布された、高い防食性を有する端子付き電線を得ることができる。 As described above, according to the present embodiment, since the resin member 17 covers the connecting portion between the terminal 1 and the coated conducting wire 11, the anticorrosion effect can be efficiently obtained. At this time, since the resin member 17 is applied before the coating crimping, a narrow gap between the coating portion 15 and the coating crimping portion 9 after the coating crimping (particularly, the conductor wire around the boundary between the end portion of the coating portion 15 and the exposed conductor wire portion). The resin member 17 can be reliably applied to the gap between the 13 and the terminal (crimping portion 5). Therefore, it is possible to prevent water from entering from the boundary portion between the end portion of the covering portion 15 and the exposed conductor wire portion along the gap between the covering portion 15 and the coating crimping portion 9. Therefore, in at least a part of the covering crimping portion 9 in the longitudinal direction, a resin member 17 is coated between the covering portion 15 and the covering crimping portion 9 over the entire circumference to obtain an electric wire with a terminal having high corrosion resistance. Can be done.

また、被覆圧着前に樹脂部材17を硬化させることで、より深い部位まで紫外線を照射することができ、より確実に樹脂部材17を硬化させることができる。また、被覆圧着時に、樹脂部材17が飛散することを抑制することができる。 Further, by curing the resin member 17 before the coating crimping, it is possible to irradiate a deeper portion with ultraviolet rays, and the resin member 17 can be cured more reliably. In addition, it is possible to prevent the resin member 17 from scattering during coating crimping.

また、この際、硬化後の樹脂部材17の硬度が、被覆部15の硬度よりも低ければ、樹脂部材17が被覆圧着時に容易に変形し、被覆圧着部9および被覆部15の変形に追従して、隙間を埋めることができる。 Further, at this time, if the hardness of the resin member 17 after curing is lower than the hardness of the coating portion 15, the resin member 17 is easily deformed at the time of coating crimping, and follows the deformation of the coating crimping portion 9 and the coating portion 15. Can fill the gap.

また、被覆圧着後に樹脂部材17を硬化させることもできる。この場合には、被覆圧着時における、樹脂部材17の流動性が良好であるため、樹脂部材17を狭い隙間にも確実に塗布することができる。 Further, the resin member 17 can be cured after the coating is pressure-bonded. In this case, since the fluidity of the resin member 17 at the time of coating crimping is good, the resin member 17 can be reliably applied even to a narrow gap.

また、樹脂部材17を塗布する前に、被覆圧着部を仮圧着して、形状を整えることで、樹脂部材17の流れ落ちなどを抑制することができる。 Further, by temporarily crimping the coated crimping portion before applying the resin member 17 to adjust the shape, it is possible to prevent the resin member 17 from flowing down.

また、被覆圧着後にさらに樹脂部材17aを塗布することで、より確実に被覆部15と被覆圧着部9との隙間を埋めることができる。 Further, by further applying the resin member 17a after the coating crimping, the gap between the coating portion 15 and the coating crimping portion 9 can be more reliably filled.

以上、添付図を参照しながら、本発明の実施の形態を説明したが、本発明の技術的範囲は、前述した実施の形態に左右されない。当業者であれば、特許請求の範囲に記載された技術的思想の範疇内において各種の変更例または修正例に想到し得ることは明らかであり、それらについても当然に本発明の技術的範囲に属するものと了解される。 Although the embodiment of the present invention has been described above with reference to the attached drawings, the technical scope of the present invention does not depend on the above-described embodiment. It is clear that a person skilled in the art can come up with various modifications or modifications within the scope of the technical ideas described in the claims, and these are naturally within the technical scope of the present invention. It is understood that it belongs.

1………端子
3………端子本体
5………圧着部
7………導線圧着部
9………被覆圧着部
10………端子付き電線
11………被覆導線
13………導線
15………被覆部
17、17a………樹脂部材
31………水槽
33………塩水
1 ………… Terminal 3 ………… Terminal body 5 ………… Crimping part 7 ………… Conductor crimping part 9 ………… Covered crimping part 10 ………… Wire with terminal 11 ………… Covered conductor 13 ………… Conductor 15 ……… Covering parts 17, 17a ……… Resin member 31 ……… Water tank 33 ……… Salt water

Claims (2)

被覆導線と端子とが接続された端子付き電線であって、
前記端子は、前記被覆導線が圧着される圧着部と、端子本体とを有し、
前記圧着部は、前記被覆導線の被覆部を圧着する被覆圧着部と、前記被覆部から露出する導線を圧着する導線圧着部とを有し、
長手方向の少なくとも一部において、前記被覆圧着部に凹溝が形成されることなく、前記被覆圧着部と前記被覆部との間の全周にわたって樹脂部材が塗布されており、
前記樹脂部材は、紫外線硬化樹脂であることを特徴とする端子付き電線。
An electric wire with a terminal in which a coated conductor and a terminal are connected.
The terminal has a crimping portion to which the coated conductor is crimped and a terminal body.
The crimping portion has a coated crimping portion for crimping the covering portion of the coated conducting wire and a conducting wire crimping portion for crimping a conducting wire exposed from the covering portion.
In at least a part in the longitudinal direction, the resin member is applied over the entire circumference between the coated crimping portion and the covering crimping portion without forming a concave groove in the covering crimping portion.
The resin member is an electric wire with a terminal, which is an ultraviolet curable resin.
硬化後の前記樹脂部材の硬度が、前記被覆部の硬度よりも低いことを特徴とする請求項1記載の端子付き電線。
The electric wire with a terminal according to claim 1, wherein the hardness of the resin member after curing is lower than the hardness of the covering portion.
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