JP2021097628A - Chocolate for impregnation heating - Google Patents
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- JP2021097628A JP2021097628A JP2019231008A JP2019231008A JP2021097628A JP 2021097628 A JP2021097628 A JP 2021097628A JP 2019231008 A JP2019231008 A JP 2019231008A JP 2019231008 A JP2019231008 A JP 2019231008A JP 2021097628 A JP2021097628 A JP 2021097628A
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- 238000010438 heat treatment Methods 0.000 title claims abstract description 68
- 238000005470 impregnation Methods 0.000 title claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 43
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 23
- 229930195729 fatty acid Natural products 0.000 claims abstract description 23
- 239000000194 fatty acid Substances 0.000 claims abstract description 23
- -1 fatty acid ester Chemical class 0.000 claims abstract description 20
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Landscapes
- Confectionery (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Abstract
Description
本発明は、含浸加熱用チョコレートに関する発明である。 The present invention relates to chocolate for impregnation heating.
チョコレートは、チョコレートのみからなる製品以外に、チョコレートと他の食材とを組み合わせた製品にも利用されている。チョコレートと他の食材とを組み合わせた製品のうち、菓子、パン等の食材にチョコレートを含浸させた複合食品は、非常に人気のある製品であり、需要が高く、広く市場に流通している。 Chocolate is used not only for products made only of chocolate, but also for products that combine chocolate with other ingredients. Among the products that combine chocolate and other ingredients, complex foods in which ingredients such as confectionery and bread are impregnated with chocolate are very popular products, are in high demand, and are widely distributed in the market.
食材にチョコレートを含浸させた複合食品は、通常、食材を融解させたチョコレートに浸漬することで製造することができる。しかしながら、一般的にはチョコレートは食材に浸透しにくくて含浸しにくい。そこで、食材へのチョコレートの含浸のしやすさを改善する方法として、圧力（減圧、加圧）や遠心力等を利用して物理的に含浸のしやすさを改善する方法が提案されている（例えば、特許文献１〜４）。しかしながら、物理的な方法による食材へのチョコレートの含浸のしやすさを改善する方法では、特殊な設備が必要になることがある。そのため、食材に含浸させて使用されるチョコレートは、チョコレート自体が食材に含浸しやすい性質であることも重要である。 A complex food product in which a food material is impregnated with chocolate can usually be produced by immersing the food material in melted chocolate. However, in general, chocolate is difficult to penetrate into foodstuffs and is difficult to impregnate. Therefore, as a method for improving the ease of impregnating chocolate into foodstuffs, a method of physically improving the ease of impregnation by using pressure (decompression, pressurization), centrifugal force, or the like has been proposed. (For example, Patent Documents 1 to 4). However, methods of improving the ease of impregnating chocolate into foodstuffs by physical methods may require special equipment. Therefore, it is also important that the chocolate used by impregnating the foodstuff has the property that the chocolate itself is easily impregnated into the foodstuff.
また、近年はチョコレートを焼いた製品が流行しており、食材にチョコレートを含浸させた複合食品をさらに焼いた製品も存在する。通常、チョコレートが焼かれると、べたつくことがある。そのため、食材に含浸させた後、さらに焼成して使用されるチョコレートは、焼成後にべたつかない性質であることも重要である。 In recent years, products made by baking chocolate have become popular, and there are also products made by further baking complex foods in which ingredients are impregnated with chocolate. Usually, when chocolate is baked, it can be sticky. Therefore, it is also important that the chocolate used by impregnating the food material and then baking it is not sticky after baking.
以上のような背景から、食材に含浸しやすく、加熱後のべたつきが少ない含浸加熱用チョコレートの開発が望まれていた。 From the above background, it has been desired to develop chocolate for impregnation heating, which is easy to impregnate into foodstuffs and has less stickiness after heating.
本発明の課題は、食材に含浸しやすく、加熱後のべたつきが少ない含浸加熱用チョコレートを提供することにある。 An object of the present invention is to provide an impregnated heating chocolate that is easily impregnated into a food material and has less stickiness after heating.
本発明者らは、上記課題を解決すべく鋭意検討を行った結果、チョコレートに特定の乳化剤を特定量配合し、かつ、チョコレートに含まれる油脂の固体脂含量を特定範囲とすると、食材に含浸しやすく、加熱後のべたつきが少ない含浸加熱用チョコレートが得られることを見出し、本発明を完成するに至った。 As a result of diligent studies to solve the above problems, the present inventors have impregnated the food material with a specific amount of a specific emulsifier blended in chocolate and a specific range of solid fat content of fats and oils contained in chocolate. We have found that a chocolate for impregnation heating that is easy to use and has less stickiness after heating can be obtained, and has completed the present invention.
すなわち、本発明の第１の発明は、下記乳化剤Ａを０．０１〜３質量％、下記乳化剤Ｂを０．０１〜３質量％含有し、かつ、チョコレートに含まれる油脂の固体脂含量が１０℃で６０〜８５％、２０℃で３５〜６５％、３０℃で２０％以下である含浸加熱用チョコレートである。
乳化剤Ａ：ＨＬＢが５以下であり、構成脂肪酸がパルミチン酸、ステアリン酸、オレイン酸からなるショ糖混合脂肪酸エステル。
乳化剤Ｂ：ＨＬＢが５以下であるポリグリセリン飽和脂肪酸エステル。
本発明の第２の発明は、第１の発明に記載の含浸加熱用チョコレートを、食材に含浸させて、加熱して得られる複合食品である。
本発明の第３の発明は、前記食材が菓子又はパンである第２の発明に記載の複合食品である。
That is, in the first invention of the present invention, the following emulsifier A is contained in an amount of 0.01 to 3% by mass, the following emulsifier B is contained in an amount of 0.01 to 3% by mass, and the solid fat content of the fat and oil contained in chocolate is 10. It is a chocolate for impregnation heating which is 60 to 85% at ° C., 35 to 65% at 20 ° C., and 20% or less at 30 ° C.
Emulsifier A: A sucrose mixed fatty acid ester in which HLB is 5 or less and the constituent fatty acids are palmitic acid, stearic acid, and oleic acid.
Emulsifier B: Polyglycerin-saturated fatty acid ester having an HLB of 5 or less.
The second invention of the present invention is a complex food obtained by impregnating a food material with the impregnated heating chocolate according to the first invention and heating the food.
The third invention of the present invention is the complex food product according to the second invention, wherein the foodstuff is confectionery or bread.
本発明によると、食材に含浸しやすく、加熱後のべたつきが少ない含浸加熱用チョコレートを提供することができる。 According to the present invention, it is possible to provide chocolate for impregnation heating, which is easily impregnated into foodstuffs and has less stickiness after heating.
本発明の実施の形態の含浸加熱用チョコレートは、下記乳化剤Ａを０．０１〜３質量％、下記乳化剤Ｂを０．０１〜３質量％含有し、かつ、チョコレートに含まれる油脂の固体脂含量が１０℃で６０〜８５％、２０℃で３５〜６５％、３０℃で２０％以下である。
乳化剤Ａ：ＨＬＢが５以下であり、構成脂肪酸がパルミチン酸、ステアリン酸、オレイン酸からなるショ糖混合脂肪酸エステル。
乳化剤Ｂ：ＨＬＢが５以下であるポリグリセリン飽和脂肪酸エステル。
The impregnated heating chocolate according to the embodiment of the present invention contains the following emulsifier A in an amount of 0.01 to 3% by mass and the following emulsifier B in an amount of 0.01 to 3% by mass, and the solid fat content of the fat and oil contained in the chocolate. Is 60 to 85% at 10 ° C, 35 to 65% at 20 ° C, and 20% or less at 30 ° C.
Emulsifier A: A sucrose mixed fatty acid ester in which HLB is 5 or less and the constituent fatty acids are palmitic acid, stearic acid, and oleic acid.
Emulsifier B: Polyglycerin-saturated fatty acid ester having an HLB of 5 or less.
本発明でチョコレートとは、「チョコレート類の表示に関する公正競争規約」（全国チョコレート業公正取引協議会）乃至法規上の規定により限定されるものではなく、食用油脂、糖類を主原料とし、必要によりカカオ成分（カカオマス、ココアパウダー等）、乳製品、香料、乳化剤等を加え、チョコレート製造の工程（混合工程、微粒化工程、精練工程、調温工程、成形工程、冷却工程等の全部乃至一部）を経て製造され、油脂が連続相をなし、実質的に水を含まない（水分が好ましくは３質量％以下、より好ましくは２質量％以下、更に好ましくは１質量％以下である。）食品のことである。また、本発明でチョコレートは、ダークチョコレート、ミルクチョコレート、ホワイトチョコレート、カラーチョコレートのいずれであってもよい。
また、本発明で含浸加熱用チョコレートとは、食材に含浸させた後、加熱して使用されるチョコレートのことである。本発明で含浸とは、食材の表面や内部にチョコレートを浸み込ませることである。
In the present invention, chocolate is not limited by the "Fair Competition Code for Labeling Chocolates" (National Chocolate Industry Fair Trade Council) or the provisions of laws and regulations, but edible fats and oils and sugars are the main raw materials, and if necessary. Add cocoa ingredients (cocoa mass, cocoa powder, etc.), dairy products, fragrances, emulsifiers, etc., and add all or part of the chocolate manufacturing process (mixing process, atomization process, scouring process, temperature control process, molding process, cooling process, etc.) ), The fats and oils form a continuous phase, and substantially free of water (moisture is preferably 3% by mass or less, more preferably 2% by mass or less, still more preferably 1% by mass or less). That is. Further, in the present invention, the chocolate may be dark chocolate, milk chocolate, white chocolate or colored chocolate.
Further, in the present invention, the impregnated heating chocolate is chocolate that is used by impregnating a food material and then heating it. Impregnation in the present invention means impregnating chocolate on the surface or inside of a food material.
本発明の実施の形態の含浸加熱用チョコレートは、下記乳化剤Ａを含有する。
本発明の実施の形態の含浸加熱用チョコレートの製造に使用される乳化剤Ａは、ＨＬＢが５以下であり、構成脂肪酸がパルミチン酸、ステアリン酸、オレイン酸からなるショ糖混合脂肪酸エステルである。前記ショ糖混合脂肪酸エステルのＨＬＢは、好ましくは３以下であり、より好ましくは２以下である。また、前記ショ糖混合脂肪酸エステルは、好ましくは構成脂肪酸としてパルミチン酸を２０〜４０質量％、ステアリン酸を２０〜４０質量％、オレイン酸を３０〜５０質量％含有し、より好ましくは構成脂肪酸としてパルミチン酸を２３〜３７質量％、ステアリン酸を２３〜３７質量％、オレイン酸を３３〜４７質量％含有し、さらに好ましくは構成脂肪酸としてパルミチン酸を２５〜３５質量％、ステアリン酸を２５〜３５質量％、オレイン酸を３５〜４５質量％含有する。
本発明の実施の形態の含浸加熱用チョコレートは、前記乳化剤Ａを０．０１〜３質量％含有し、好ましくは０．０５〜２質量％含有し、より好ましくは０．１〜１質量％含有する。チョコレートが前記乳化剤Ａを前記範囲で含有すると、チョコレートが食材に含浸しやすくなる。
なお、乳化剤を構成する脂肪酸の含有量は、従来公知の方法で測定することができる。
また、ＨＬＢとは、親水性疎水性バランス（Ｈｙｄｒｏｐｈｉｌｅ Ｌｉｐｏｐｈｉｌ
ｅ Ｂａｌａｎｃｅ）の略であって、乳化剤が親水性か親油性かを知る指標となるもので
、０〜２０の値をとる。ＨＬＢ値が小さい程、親油性が強いことを示す。本発明において
、ＨＬＢ値の算出はアトラス法の算出法を用いる。アトラス法の算出法は、
ＨＬＢ＝２０×（１−Ｓ／Ａ）
Ｓ：ケン化価
Ａ：エステル中の脂肪酸の中和価
からＨＬＢの値を算出する方法を言う。
The impregnated heating chocolate according to the embodiment of the present invention contains the following emulsifier A.
The emulsifier A used in the production of the impregnated heating chocolate according to the embodiment of the present invention is a sucrose mixed fatty acid ester having an HLB of 5 or less and a constituent fatty acid consisting of palmitic acid, stearic acid, and oleic acid. The HLB of the sucrose mixed fatty acid ester is preferably 3 or less, more preferably 2 or less. The sucrose mixed fatty acid ester preferably contains 20 to 40% by mass of palmitic acid, 20 to 40% by mass of stearic acid, and 30 to 50% by mass of oleic acid as constituent fatty acids, and more preferably as constituent fatty acids. It contains 23 to 37% by mass of palmitic acid, 23 to 37% by mass of stearic acid, 33 to 47% by mass of oleic acid, and more preferably 25 to 35% by mass of palmitic acid and 25 to 35% by mass of stearic acid as constituent fatty acids. It contains 35% by mass and 35 to 45% by mass of oleic acid.
The impregnated heating chocolate according to the embodiment of the present invention contains the emulsifier A in an amount of 0.01 to 3% by mass, preferably 0.05 to 2% by mass, and more preferably 0.1 to 1% by mass. To do. When chocolate contains the emulsifier A in the above range, the chocolate is easily impregnated into the food material.
The content of fatty acids constituting the emulsifier can be measured by a conventionally known method.
In addition, HLB is a hydrophilic hydrophobic balance (Hydrophile Lipofil).
It is an abbreviation for eBalance), which is an index for knowing whether an emulsifier is hydrophilic or lipophilic, and has a value of 0 to 20. The smaller the HLB value, the stronger the lipophilicity. In the present invention, the calculation method of the Atlas method is used for the calculation of the HLB value. The calculation method of the Atlas method is
HLB = 20 × (1-S / A)
S: Saponification value
A: A method of calculating the HLB value from the neutralization value of fatty acids in the ester.
本発明の実施の形態の含浸加熱用チョコレートは、下記乳化剤Ｂを含有する。
本発明の実施の形態の含浸加熱用チョコレートの製造に使用される乳化剤Ｂは、ＨＬＢが５以下のポリグリセリン飽和脂肪酸エステルである。前記ポリグリセリン飽和脂肪酸エステルのＨＬＢは、好ましくは１〜５であり、より好ましくは２〜４である。また、前記ポリグリセリン飽和脂肪酸エステルは、好ましくはポリグリセリンベヘン酸エステルであり、より好ましくはデカグリセリンベヘン酸エステルである。
本発明の実施の形態の含浸加熱用チョコレートは、前記乳化剤Ｂを０．０１〜３質量％含有し、好ましくは０．０５〜２質量％含有し、より好ましくは０．１〜１質量％含有する。チョコレートが前記乳化剤Ｂを前記範囲で含有すると、加熱後のチョコレートのべたつきが少なくなる。
The impregnated heating chocolate according to the embodiment of the present invention contains the following emulsifier B.
The emulsifier B used in the production of the impregnated heating chocolate according to the embodiment of the present invention is a polyglycerin-saturated fatty acid ester having an HLB of 5 or less. The HLB of the polyglycerin saturated fatty acid ester is preferably 1 to 5, and more preferably 2 to 4. The polyglycerin-saturated fatty acid ester is preferably a polyglycerin behenic acid ester, and more preferably a decaglycerin behenic acid ester.
The impregnated heating chocolate according to the embodiment of the present invention contains the emulsifier B in an amount of 0.01 to 3% by mass, preferably 0.05 to 2% by mass, and more preferably 0.1 to 1% by mass. To do. When the chocolate contains the emulsifier B in the above range, the stickiness of the chocolate after heating is reduced.
本発明の実施の形態の含浸加熱用チョコレートは、前記乳化剤Ａ、乳化剤Ｂ以外のその他の乳化剤を使用することもできる。その他の乳化剤としては、前記乳化剤Ａ以外のショ糖脂肪酸エステル、乳化剤Ｂ以外のポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、レシチン、リゾレシチン、酵素分解レシチン等のレシチン類等が挙げられる。 As the impregnated heating chocolate according to the embodiment of the present invention, other emulsifiers other than the emulsifier A and the emulsifier B can be used. Examples of other emulsifiers include sucrose fatty acid esters other than emulsifier A, polyglycerin fatty acid esters other than emulsifier B, sorbitan fatty acid esters, glycerin fatty acid esters, lecithin, lysolecithin, and lecithins such as enzymatically decomposed lecithin.
本発明の実施の形態の含浸加熱用チョコレートは、好ましくは油脂を含有する。本発明の実施の形態の含浸加熱用チョコレートは、油脂を好ましくは３０〜６５質量％含有し、より好ましくは４０〜６０質量％含有し、更に好ましくは４３〜５５質量％含有する。
なお、本発明で油脂は、チョコレートに含まれる油脂の全てを合わせた全油脂分である。例えば、チョコレートがカカオマス、全脂粉乳、油脂ａを含む場合、油脂は、カカオマスに含まれるココアバターと、全脂粉乳に含まれる乳脂と、油脂ａとの混合油である。すなわち、本発明で油脂は、配合される油脂の他に、含油原料（カカオマス、ココアパウダー、全脂粉乳等）に含まれる油脂（ココアバター、乳脂等）を含む。
The impregnated heating chocolate according to the embodiment of the present invention preferably contains fats and oils. The impregnated heating chocolate according to the embodiment of the present invention preferably contains 30 to 65% by mass, more preferably 40 to 60% by mass, and further preferably 43 to 55% by mass.
In the present invention, the fat and oil is the total fat and oil content of all the fats and oils contained in chocolate. For example, when chocolate contains cocoa mass, whole fat powder milk, and fat a, the fat is a mixed oil of cocoa butter contained in cocoa mass, milk fat contained in whole fat powder milk, and fat a. That is, in the present invention, the fats and oils include fats and oils (cocoa butter, milk fat, etc.) contained in oil-containing raw materials (cocoa mass, cocoa powder, whole fat powdered milk, etc.) in addition to the fats and oils to be blended.
本発明の実施の形態の含浸加熱用チョコレートは、含まれる油脂の固体脂含量（以下、ＳＦＣとする。）が１０℃で６０〜８５％、２０℃で３５〜６０％、３０℃で２０％以下であり、好ましくは１０℃で６５〜８０％、２０℃で４０〜５５％、３０℃で３〜１４％であり、より好ましくは１０℃で６７〜７７％、２０℃で４５〜５３％、３０℃で５〜１２％である。含まれる油脂のＳＦＣが前記範囲にあると、チョコレートは、食品に含浸しやすくなる。
また、油脂のＳＦＣは、社団法人日本油化学会編、「基準油脂分析試験法」の「２．２．９−２００３ 固体脂含量（ＮＭＲ法）」等の従来公知の方法で測定することができる。
The impregnated heating chocolate according to the embodiment of the present invention contains solid fat content (hereinafter referred to as SFC) of fats and oils of 60 to 85% at 10 ° C, 35 to 60% at 20 ° C, and 20% at 30 ° C. It is preferably 65 to 80% at 10 ° C., 40 to 55% at 20 ° C., 3 to 14% at 30 ° C., and more preferably 67 to 77% at 10 ° C. and 45 to 53% at 20 ° C. , 5-12% at 30 ° C. When the SFC of the oil and fat contained is in the above range, the chocolate is easily impregnated into the food.
The SFC of fats and oils can be measured by a conventionally known method such as "2.2.9-2003 solid fat content (NMR method)" of "Standard fats and oils analysis test method" edited by the Japan Oil Chemists' Society. it can.
本発明の実施の形態の含浸加熱用チョコレートの製造に使用される原料油脂は、ＳＦＣが前記範囲であれば、特に制限されることはない。本発明の実施の形態の含浸加熱用チョコレートに使用する原料油脂としては、パーム油、パーム分別油（パーム分別軟質油（パームオレイン、パームスーパーオレイン等）、パーム中融点部、パーム分別硬質油（パームステアリン等）等）、シア脂、シア分別油、サル脂、サル分別油、イリッペ脂、ヤシ油、パーム核油、大豆油、菜種油、綿実油、サフラワー油、ひまわり油、米油、コーン油、ゴマ油、オリーブ油、ココアバター等やこれらの混合油、加工油脂等の通常の食用油脂を使用することができる。本発明の実施の形態においては、これらから選ばれる１種又は２種以上を使用することができる。 The raw material fats and oils used in the production of the impregnated heating chocolate according to the embodiment of the present invention are not particularly limited as long as the SFC is within the above range. The raw material oils and fats used for the impregnated heating chocolate according to the embodiment of the present invention include palm oil, palm fractionated oil (palm fractionated soft oil (palm olein, palm super olein, etc.), palm mid-melting point, palm fractionated hard oil (palm fractionated hard oil). Palm stea, etc.)), shea butter, shea fractionated oil, monkey fat, monkey fractionated oil, ilippe fat, palm oil, palm kernel oil, soybean oil, rapeseed oil, cottonseed oil, saflower oil, sunflower oil, rice oil, corn oil , Sesame oil, olive oil, cocoa butter and the like, mixed oils thereof, processed oils and fats and other ordinary edible oils and fats can be used. In the embodiment of the present invention, one kind or two or more kinds selected from these can be used.
本発明の実施の形態の含浸加熱用チョコレートに使用される原料油脂は、好ましくはラウリン系油脂である。
なお、本発明でラウリン系油脂とは、油脂を構成する脂肪酸のうちラウリン酸が３０質量％以上の油脂のことである。ラウリン系油脂の具体例は、ヤシ油、パーム核油及びこれらの分別油、エステル交換油脂、硬化油等である。本発明の実施の形態においては、これらから選ばれる１種又は２種以上を使用することができる。
The raw material fats and oils used in the impregnated heating chocolate according to the embodiment of the present invention are preferably lauric-based fats and oils.
In the present invention, the lauric-based fat and oil is a fat and oil in which lauric acid is 30% by mass or more among the fatty acids constituting the fat and oil. Specific examples of lauric-based oils and fats are coconut oil, palm kernel oil, fractionated oils thereof, transesterified oils and fats, hydrogenated oils and the like. In the embodiment of the present invention, one kind or two or more kinds selected from these can be used.
本発明の実施の形態の含浸加熱用チョコレートは、含まれる油脂がラウリン系油脂を好ましくは７５質量％以上含有し、より好ましくは８０〜９５質量％含有し、更に好ましくは８３〜９３質量％含有する。 The impregnated heating chocolate according to the embodiment of the present invention contains lauric-based fats and oils in an amount of preferably 75% by mass or more, more preferably 80 to 95% by mass, and further preferably 83 to 93% by mass. To do.
本発明の実施の形態の含浸加熱用チョコレートは、好ましくは糖質を含有する。なお、本発明で糖質は、炭水化物から食物繊維を除いたもののことである。糖質の具体例は、糖類、糖アルコール（マルチトール、キシリトール、エリスリトール、ソルビトール、ラクチトール、マンニトール、還元水飴等）、でんぷん、オリゴ糖、デキストリン等である。また、本発明で糖類は、単糖類、二糖類（ブドウ糖、果糖、ガラクトース、砂糖（ショ糖）、乳糖、麦芽糖等）のことである。
本発明の実施の形態の含浸加熱用チョコレートの製造に使用される糖質は、好ましくは糖類であり、より好ましくは砂糖、乳糖である。
The impregnated heating chocolate of the embodiment of the present invention preferably contains a sugar. In the present invention, the sugar is a carbohydrate obtained by removing dietary fiber. Specific examples of sugars include sugars, sugar alcohols (maltitol, xylitol, erythritol, sorbitol, lactitol, mannitol, reduced water candy, etc.), starch, oligosaccharides, dextrins, and the like. Further, in the present invention, the saccharides are monosaccharides and disaccharides (glucose, fructose, galactose, sugar (sucrose), lactose, maltose, etc.).
The sugar used in the production of the impregnated heating chocolate according to the embodiment of the present invention is preferably sugar, more preferably sugar or lactose.
本発明の実施の形態の含浸加熱用チョコレートは、糖質を好ましくは２０〜６０質量％含有し、より好ましくは２３〜５５質量％含有し、さらに好ましくは２５〜５０質量％含有する。 The impregnated heating chocolate of the embodiment of the present invention preferably contains 20 to 60% by mass, more preferably 23 to 55% by mass, and further preferably 25 to 50% by mass of sugar.
本発明の実施の形態の含浸加熱用チョコレートは、乳化剤、油脂、糖質以外にも、チョコレートに一般的に配合される原料を使用することができる。具体的には、例えば、全脂粉乳、脱脂粉乳等の乳製品、カカオマス、ココアパウダー等のカカオ成分、大豆粉、大豆蛋白、果実加工品、野菜加工品、抹茶粉末、コーヒー粉末等の各種粉末、ガム類、澱粉類、酸化防止剤、着色料、香料等を使用することができる。 In the impregnated heating chocolate according to the embodiment of the present invention, in addition to emulsifiers, fats and oils, and sugars, raw materials generally blended in chocolate can be used. Specifically, for example, dairy products such as full-fat milk powder and defatted milk powder, cocoa components such as cocoa mass and cocoa powder, various powders such as soybean flour, soybean protein, fruit processed products, processed vegetable products, matcha powder, and coffee powder. , Gum, starch, antioxidant, colorant, fragrance and the like can be used.
本発明の実施の形態の含浸加熱用チョコレートは、従来公知の方法により製造することができる。本発明の実施の形態の含浸加熱用チョコレートは、例えば、油脂、カカオ成分、糖類、乳製品、乳化剤（前記乳化剤Ａ、乳化剤Ｂ等）等を原料として、混合工程、微粒化工程（リファイニング）、精練工程（コンチング）、冷却工程等を経て製造することができる。本発明の実施の形態の含浸加熱用チョコレートは、好ましくは微粒化工程を経て製造される。 The impregnated heating chocolate according to the embodiment of the present invention can be produced by a conventionally known method. The impregnated heating chocolate according to the embodiment of the present invention uses, for example, fats and oils, cacao components, sugars, dairy products, emulsifiers (emulsifier A, emulsifier B, etc.) as raw materials, and is used in a mixing step and atomization step (refining). , Can be manufactured through a refining process (continging), a cooling process, and the like. The impregnated heating chocolate according to the embodiment of the present invention is preferably produced through a atomization step.
本発明の実施の形態の含浸加熱用チョコレートは、粘度が好ましくは１００〜３０００ｃＰ（センチポアズ）であり、より好ましくは３００〜２０００ｃＰであり、更に好ましくは４００〜１３００ｃＰである。本発明で粘度とは、ＢＭ型粘度計（例えば、東機産業社製等）を用いて、５０℃の粘度を測定した値である。 The impregnated heating chocolate according to the embodiment of the present invention has a viscosity of preferably 100 to 3000 cP (centipores), more preferably 300 to 2000 cP, and even more preferably 400 to 1300 cP. In the present invention, the viscosity is a value obtained by measuring the viscosity at 50 ° C. using a BM type viscometer (for example, manufactured by Toki Sangyo Co., Ltd.).
本発明の実施の形態の含浸加熱用チョコレートは、好ましくはノンテンパリング型チョコレートである。 The impregnated heating chocolate according to the embodiment of the present invention is preferably a non-tempering type chocolate.
本発明の実施の形態の含浸加熱用チョコレートは、食材に含浸させた後、加熱して使用される。
チョコレートを食材に含浸させる手段は、例えば、常圧法、遠心法、減圧法、加圧法等が挙げられる。本発明の実施の形態の含浸加熱用チョコレートを食材に含浸させる手段は、好ましくは常圧法である。
また、食材に含浸したチョコレートを加熱する手段は、例えば、焼成、蒸す、揚げる（フライ）、マイクロ波（電子レンジ）等が挙げられる。食材に含浸した本発明の実施の形態の含浸加熱用チョコレートを加熱する手段は、好ましくは焼成である。従って、本発明の実施の形態の含浸加熱用チョコレートは、好ましくは含浸焼成用チョコレートである。
The impregnated heating chocolate according to the embodiment of the present invention is used by impregnating a food material and then heating it.
Examples of the means for impregnating the food material with chocolate include a normal pressure method, a centrifugal method, a reduced pressure method, and a pressurized method. The means for impregnating the foodstuff with the impregnated heating chocolate according to the embodiment of the present invention is preferably the normal pressure method.
Further, as a means for heating the chocolate impregnated in the food material, for example, baking, steaming, frying (fried), microwave (microwave oven) and the like can be mentioned. The means for heating the impregnated heating chocolate according to the embodiment of the present invention impregnated in the food material is preferably baking. Therefore, the impregnated heating chocolate according to the embodiment of the present invention is preferably an impregnated baking chocolate.
本発明の実施の形態の含浸加熱用チョコレートは、食材に含浸しやすく、加熱後のべたつきが少ない。 The impregnated heating chocolate according to the embodiment of the present invention is easily impregnated into foodstuffs and has less stickiness after heating.
本発明の実施の形態の複合食品は、本発明の実施の形態の含浸加熱用チョコレートを食材に含浸させた後、加熱して得られる。 The complex food according to the embodiment of the present invention is obtained by impregnating a food material with the impregnated heating chocolate according to the embodiment of the present invention and then heating the food.
本発明の実施の形態の複合食品の製造に使用される食材の具体例は、例えば、ビスケット、クッキー、クラッカー、パイ、ウエハース、スポンジケーキ、シュー、ラスク、ワッフル等の焼き菓子、あられ、煎餅、おかき等の米菓、食パン、コッペパン、フランスパン等のパン、ドーナツ、クルトン、パフスナック、果実の乾燥物、野菜の乾燥物等である。本発明の実施の形態の複合食品に使用する食材は、好ましくは、菓子又はパンであり、より好ましくはラスクである。
また、本発明の実施の形態の複合食品に使用する食材は、好ましくは多孔質の食材である。なお、本発明で多孔質の食材とは、食材内部の空隙率が大きい食材のことである。
Specific examples of the ingredients used in the production of the complex food according to the embodiment of the present invention include, for example, baked goods such as biscuits, cookies, crackers, pies, wafers, sponge cakes, shoes, rusks, waffles, hail, rice crackers, and the like. Rice crackers such as rice crackers, bread, coppe bread, bread such as French bread, donuts, rusks, puff snacks, dried fruits, dried vegetables, etc. The foodstuff used in the complex food of the embodiment of the present invention is preferably confectionery or bread, and more preferably rusks.
In addition, the foodstuff used in the complex food according to the embodiment of the present invention is preferably a porous foodstuff. In the present invention, the porous food material is a food material having a large porosity inside the food material.
本発明の実施の形態の複合食品は、従来公知の方法によって、食材に本発明の実施の形態の含浸加熱用チョコレートを含浸させた後、加熱することで製造することができる。
食材にチョコレートを含浸させる手段は、前記したとおりである。また、食材に含浸したチョコレートを加熱する手段を加熱する手段も、前記したとおりである。食材に含浸した本発明の実施の形態の含浸加熱用チョコレートを加熱する時の加熱温度は、好ましくは１００〜１６０℃であり、より好ましくは１１０〜１５０℃であり、さらに好ましくは１２０〜１４０℃である。食材に含浸した本発明の実施の形態の含浸加熱用チョコレートを加熱する時の加熱時間は、好ましくは１〜３０分間であり、より好ましくは３〜２５分間であり、さらに好ましくは５〜２０分間である。
The complex food of the embodiment of the present invention can be produced by impregnating a food material with the impregnated heating chocolate of the embodiment of the present invention by a conventionally known method and then heating the food.
The means for impregnating the food material with chocolate is as described above. Further, the means for heating the means for heating the chocolate impregnated in the food material is also as described above. The heating temperature at the time of heating the impregnated heating chocolate according to the embodiment of the present invention impregnated in the food material is preferably 100 to 160 ° C, more preferably 110 to 150 ° C, and further preferably 120 to 140 ° C. Is. The heating time for heating the impregnated heating chocolate according to the embodiment of the present invention impregnated in the food material is preferably 1 to 30 minutes, more preferably 3 to 25 minutes, and further preferably 5 to 20 minutes. Is.
本発明の実施の形態の複合食品は、加熱後のチョコレート部分のべたつきが少ない。 The complex food according to the embodiment of the present invention has less stickiness of the chocolate portion after heating.
次に実施例により本発明を説明するが、本発明はこれらの実施例により限定されるものではない。 Next, the present invention will be described with reference to Examples, but the present invention is not limited to these Examples.
乳化剤、油脂は以下のものを使用した。なお、下記油脂ａ、油脂ｂは、ラウリン系油脂である。
乳化剤Ａ１：ショ糖混合脂肪酸エステル（パルミチン酸含有量３０質量％、ステアリン酸含有量３０質量％、オレイン酸含有量４０質量％、ＨＬＢ１）
乳化剤Ｂ１：ポリグリセリン飽和脂肪酸エステル（デカグリセリンベヘン酸エステル、ＨＬＢ２．３）
乳化剤ｂ１：ソルビタンベヘン酸エステル（ＨＬＢ２．５）
乳化剤ｃ：ポリグリセリン縮合リシノール酸エステル
油脂ａ（パーム核硬化油（融点３４℃））
油脂ｂ（ヤシ油）
The following emulsifiers and fats and oils were used. The following fats and oils a and b are lauric-based fats and oils.
Emulsifier A1: Sucrose mixed fatty acid ester (palmitic acid content 30% by mass, stearic acid content 30% by mass, oleic acid content 40% by mass, HLB1)
Emulsifier B1: Polyglycerin saturated fatty acid ester (decaglycerin behenic acid ester, HLB2.3)
Emulsifier b1: Sorbitan behenic acid ester (HLB2.5)
Emulsifier c: Polyglycerin condensed ricinoleic acid ester fat a (palm kernel hydrogenated oil (melting point 34 ° C))
Oil b (coconut oil)
〔チョコレートの製造〕
表１の配合で常法（混合、微粒化、精練、冷却）によりチョコレート（ノンテンパリング型チョコレート）を製造した。製造した全てのチョコレートは、水分が３質量％以下だった。また、チョコレートの粘度は、ＢＭ型粘度計（東機産業社製）を用いて、５０℃の粘度を測定した。
[Chocolate production]
Chocolate (non-tempering type chocolate) was produced by a conventional method (mixing, atomization, scouring, cooling) according to the formulation shown in Table 1. All the chocolates produced had a moisture content of 3% by mass or less. The viscosity of chocolate was measured at 50 ° C. using a BM type viscometer (manufactured by Toki Sangyo Co., Ltd.).
〔複合食品の製造及び評価〕
４０〜４５℃の融解している各チョコレートに、ラスク（多孔質食材）を浸漬し、チョコレートをラスクに含浸させた。ラスクを取り出し、過剰なチョコレートを落した後、２０℃で冷却固化することで、チョコレートが含浸したラスクを得た。チョコレートの含浸のしやすさ（含浸性）を以下の基準に従い評価した。各評価は○である場合を良好と判断した。評価結果を表１に示す。
チョコレートが含浸したラスクを、デッキオーブンで、１２０℃５分間、１２０℃１５分間、１４０℃５分間、１４０℃１５分間又は１６０℃１０分間の条件で焼成することで、チョコレートが含浸した焼成ラスクを得た。チョコレートが含浸した焼成ラスクを２０℃で一晩エージングした後、３０℃、２時間保存した後のラスクの表面を以下の基準に従い評価した。各評価は○である場合を良好と判断した。評価結果を表１に示す。
[Manufacturing and evaluation of complex foods]
Rusks (porous foodstuffs) were dipped in each of the melted chocolates at 40 to 45 ° C., and the chocolates were impregnated into the rusks. Rusks were taken out, excess chocolate was removed, and then cooled and solidified at 20 ° C. to obtain chocolate-impregnated rusks. The ease of impregnation of chocolate (impregnation property) was evaluated according to the following criteria. Each evaluation was judged to be good when it was ○. The evaluation results are shown in Table 1.
The chocolate-impregnated rusks are baked in a deck oven at 120 ° C. for 5 minutes, 120 ° C. for 15 minutes, 140 ° C. for 5 minutes, 140 ° C. for 15 minutes, or 160 ° C. for 10 minutes to obtain chocolate-impregnated rusks. Obtained. The baked rusks impregnated with chocolate were aged at 20 ° C. overnight and then stored at 30 ° C. for 2 hours, and the surface of the rusks was evaluated according to the following criteria. Each evaluation was judged to be good when it was ○. The evaluation results are shown in Table 1.
＜含浸性の評価基準＞
○：良好 （含浸している）
△：不良 （やや含浸している）
×：不可 （含浸していない）
＜べたつきの評価基準＞
○：良好 （べたつきがない）
△：不良 （ややべたつきがある）
×：不可 （べたつきがある）
<Evaluation criteria for impregnation>
◯: Good (impregnated)
Δ: Defective (slightly impregnated)
×: Not possible (not impregnated)
<Evaluation criteria for stickiness>
○: Good (no stickiness)
△: Defective (slightly sticky)
×: Not possible (sticky)
表１から分かるように、実施例のチョコレートは、含浸しやすく、焼成後のべたつきもなかった。
一方、表１から分かるように、比較例のチョコレートは、１４０℃１５分間の焼成でべたつきが認められた。
As can be seen from Table 1, the chocolates of the examples were easily impregnated and were not sticky after baking.
On the other hand, as can be seen from Table 1, the chocolate of the comparative example was found to be sticky after baking at 140 ° C. for 15 minutes.
Claims (3)
乳化剤Ａ：ＨＬＢが５以下であり、構成脂肪酸がパルミチン酸、ステアリン酸、オレイン酸からなるショ糖混合脂肪酸エステル。
乳化剤Ｂ：ＨＬＢが５以下であるポリグリセリン飽和脂肪酸エステル。 The following emulsifier A is contained in an amount of 0.01 to 3% by mass, the following emulsifier B is contained in an amount of 0.01 to 3% by mass, and the solid fat content of the fat and oil contained in chocolate is 60 to 85% at 10 ° C. and 35 at 20 ° C. Chocolate for impregnation heating that is ~ 65% and 20% or less at 30 ° C.
Emulsifier A: A sucrose mixed fatty acid ester in which HLB is 5 or less and the constituent fatty acids are palmitic acid, stearic acid, and oleic acid.
Emulsifier B: Polyglycerin-saturated fatty acid ester having an HLB of 5 or less.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012152113A (en) * | 2011-01-24 | 2012-08-16 | Adeka Corp | Oil and fat composition for coating |
| JP2016165235A (en) * | 2015-03-09 | 2016-09-15 | 不二製油株式会社 | Chocolate for simultaneously baking with baked confectionery dough |
| JP2017175929A (en) * | 2016-03-28 | 2017-10-05 | 日清オイリオグループ株式会社 | Chocolate snack |
| JP2017175928A (en) * | 2016-03-28 | 2017-10-05 | 日清オイリオグループ株式会社 | Chocolate used by being impregnated into food material, and composite food impregnated with the chocolate |
| JP2018171019A (en) * | 2017-03-31 | 2018-11-08 | 不二製油株式会社 | Chocolate for impregnation baking and composite food product using the same |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012152113A (en) * | 2011-01-24 | 2012-08-16 | Adeka Corp | Oil and fat composition for coating |
| JP2016165235A (en) * | 2015-03-09 | 2016-09-15 | 不二製油株式会社 | Chocolate for simultaneously baking with baked confectionery dough |
| JP2017175929A (en) * | 2016-03-28 | 2017-10-05 | 日清オイリオグループ株式会社 | Chocolate snack |
| JP2017175928A (en) * | 2016-03-28 | 2017-10-05 | 日清オイリオグループ株式会社 | Chocolate used by being impregnated into food material, and composite food impregnated with the chocolate |
| JP2018171019A (en) * | 2017-03-31 | 2018-11-08 | 不二製油株式会社 | Chocolate for impregnation baking and composite food product using the same |
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