JP2021066832A - Polyfunctional phenolic resin, polyfunctional epoxy resin, curable resin composition including the same and cured product thereof - Google Patents

Abstract

To provide a polyfunctional phenolic resin that has low viscosity and results in a cured product having excellent mechanical characteristics and heat resistance, and a polyfunctional epoxy resin, a curable resin composition including the same, and a cured product thereof.SOLUTION: The present invention relates to a polyfunctional phenolic resin in which a naphthol structure optionally having a substituent on an aromatic ring and a catechol structure having a C4 to 8 alkyl group as a substituent on an aromatic ring are coupled through an optionally substituted methylene group. There are also provided a polyfunctional epoxy resin obtained by epoxidizing the polyfunctional phenolic resin, a curable resin composition including any of these, and a cured product thereof.SELECTED DRAWING: Figure 1

Description

The present invention has an excellent balance between heat resistance and mechanical strength of the obtained cured product, and is a polyfunctional phenol resin, a polyfunctional epoxy resin, and a curable resin composition containing them, which can be suitably used for composite materials and electrical materials. Regarding a product and its cured product.

Phenol formaldehyde and epoxy resins are used as materials for adhesives, molding materials, paints, etc., and composites such as fiber-reinforced composite materials because the obtained cured product is excellent in heat resistance, mechanical strength, moisture resistance, etc. It is widely used in the electrical and electronic fields such as material applications, semiconductor encapsulants, and insulating materials for printed wiring boards.

In recent years, fiber-reinforced resin molded products reinforced with reinforced fibers have attracted attention for their light weight and excellent mechanical strength, and are used in various structural applications such as housings for automobiles, aircraft, ships, and various members. The use is expanding. The fiber-reinforced resin molded product can be manufactured by molding a fiber-reinforced composite material by a molding method such as a filament winding method, a press molding method, a hand lay-up method, a pull-fusion method, or an RTM method.

The fiber-reinforced composite material is made by impregnating reinforcing fibers with a resin. Since the resin used for the fiber-reinforced composite material is required to have stability at room temperature, durability and strength of the cured product, etc., generally, unsaturated polyester resin, vinyl ester resin, epoxy resin and the like are used. Thermosetting resin is used. Among these, epoxy resins have high strength, elastic modulus, and excellent heat resistance, and are therefore being put to practical use in various applications as resins for fiber-reinforced composite materials.

As the epoxy resin for the fiber-reinforced composite material, as described above, the reinforcing fibers are impregnated with the resin and used, so that the epoxy resin is required to have a low viscosity. In addition, when used as a fiber-reinforced resin molded product for structural parts around engines in automobiles and the like, and as an electric wire core material, the heat-resistant product is heat-resistant so that the fiber-reinforced resin molded product can withstand harsh usage environments for a long period of time. Resins with excellent properties and mechanical strength are required.

From the viewpoint of the balance between low viscosity and mechanical strength of the cured product as described above, for example, an epoxy resin composition containing an epoxy resin obtained by epoxidizing 1,2,4-trihydroxybenzene is provided. (See, for example, Patent Document 1). Further, an epoxy resin composition in which a divalent phenol glycidyl ether and a trifunctional or higher functional glycidyl amine type epoxy resin are used in combination and combined with a curing agent is also known (see, for example, Patent Document 2). However, although the epoxy resin compositions provided in Patent Documents 1 and 2 have high impregnation properties for reinforcing fibers and exhibit certain performances in heat resistance and mechanical strength of cured products, these days It did not satisfy the increasing required characteristics.

International Publication No. 2019/013081 International Publication No. 2016/148175

Therefore, the problem to be solved by the present invention is a polyfunctional phenol resin, a polyfunctional epoxy resin, and a curable resin composition containing the same, which have a low viscosity and an excellent balance between mechanical properties and heat resistance in the obtained cured product. , And its cured product.

As a result of diligent studies in order to solve the above problems, the present inventors have used a polyfunctional compound having a naphthol structure and a substituent-containing catechol structure in one molecule, and the heat resistance and mechanical properties of the cured product are used. In particular, they have found that the balance with the elastic modulus is good, and have completed the present invention.

That is, in the present invention, the naphthol structure which may have a substituent on the aromatic ring and the catechol structure which has an alkyl group having 4 to 8 carbon atoms as the substituent on the aromatic ring have a substituent. Provided are a polyfunctional phenol resin characterized by being bonded via a methylene group which may be used, a curable resin composition containing the same, and a cured product thereof.

Further, in the present invention, the naphthol structure which may have a substituent on the aromatic ring and the catechol structure which has an alkyl group having 4 to 8 carbon atoms as the substituent on the aromatic ring have a substituent. Provided are a polyfunctional epoxy resin characterized by being bonded via a methylene group which may be present, a curable resin composition containing the polyfunctional epoxy resin, and a cured product thereof.

According to the present invention, a polyfunctional phenol resin having a low viscosity, a good balance of heat resistance and mechanical properties of a cured product, and which can be suitably used as a fiber-reinforced composite material, a semiconductor encapsulating material, or the like. It is possible to provide a polyfunctional epoxy resin, a curable resin composition containing these, and a cured product thereof.

FIG. 1 is a GPC chart of the polyfunctional phenol resin synthesized in Example 1. FIG. 2 is a GPC chart of the polyfunctional epoxy resin obtained in Example 1. ^{FIG. 3 is a 13} C-NMR spectrum of the polyfunctional epoxy resin obtained in Example 1. FIG. 4 is an MS spectrum of the polyfunctional epoxy resin obtained in Example 1.

Hereinafter, the present invention will be described in detail.
<Polyfunctional phenol resin>
In the polyfunctional phenol resin of the present invention, a naphthol structure which may have a substituent on the aromatic ring and a catechol structure having an alkyl group having 4 to 8 carbon atoms as the substituent on the aromatic ring are substituted. It is characterized in that it is bonded via a methylene group which may have a group.

The polyfunctional phenol resin has three or more phenolic hydroxyl groups in one molecule, and also has a benzene ring and a naphthalene ring, so that the crosslink density in the cured product is improved and the crosslink density on the benzene ring is improved. Adjacent hydroxyl groups make it easier for hydrogen bonds to work, and it is thought that the elastic coefficient is also improved.

The naphthalene ring may have a substituent other than the hydroxyl group, but it is preferable that the naphthalene ring does not have a substituent from the viewpoint of improving the crosslink density in the cured product and further improving the heat resistance. Further, from the viewpoint of easy availability of raw materials and reactivity, it is more preferable that the connecting portion between the benzene ring and the naphthalene ring is a methylene group having no substituent.

Examples of the polyfunctional phenol resin include those represented by the following structural formula (1).

〔構造式（１）中、Ｒは水素原子、アルキル基又はアリール基であり、Ｒ^１は水素原子または炭素原子数４〜８のアルキル基であり、少なくとも一つは炭素原子数４〜８のアルキル基である。Ｒ^２は水素原子またはアルキル基であり、ｎは０〜３の整数であり、ｍは０〜６の整数であり、ｌは１〜３の整数であり、ｎ＋ｌは４である。複数あるＲ^１、Ｒ^２は同一でも異なっていてもよい。〕
なお、前記式（１）において、ナフタレン環と置換基を有していてもよいメチレン基との結合位置は任意であり、水酸基を有する環上であっても、水酸基を有さない環上で結合していてもよいことを示すものであり、ｌが２以上の場合、同一構造であっても異なる構造であってもよい。

[In the structural formula (1), R is a hydrogen atom, an alkyl group or an aryl group, R ¹ is a hydrogen atom or an alkyl group having 4 to 8 carbon atoms, and at least one has 4 to 8 carbon atoms. It is an alkyl group. R ² is a hydrogen atom or an alkyl group, n is an integer of 0 to 3, m is an integer of 0 to 6, l is an integer of 1 to 3, and n + l is 4. A plurality of R ¹ and R ² may be the same or different. ]
In the above formula (1), the bonding position between the naphthalene ring and the methylene group which may have a substituent is arbitrary, and even on a ring having a hydroxyl group, on a ring having no hydroxyl group. It indicates that they may be combined, and when l is 2 or more, they may have the same structure or different structures.

R in the structural formula (1) is a hydrogen atom, an alkyl group, or an aryl group, and examples of the alkyl group include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, and a cyclo. Examples thereof include a xyl group, and examples of the aryl group include a phenyl group, an alkoxyphenyl group, a tolyl group, a xsilyl group, and a naphthyl group. In the production method described later, R is preferably a hydrogen atom, a methyl group, or an ethyl group, and is a hydrogen atom, from the viewpoint of easy availability of raw materials, reactivity, and heat resistance of the obtained cured product. Is particularly preferable.

^{Further, R 1} in the structural formula (1) is a hydrogen atom or an alkyl group having 4 to 8 carbon atoms, and at least one is an alkyl group having 4 to 8 carbon atoms. From the viewpoint of the balance between properties and elasticity, it is preferable to have one alkyl group having 4 to 8 carbon atoms as a substituent on the benzene ring, and the alkyl group is preferably a butyl group, particularly t-. Most preferably it is a butyl group. Further, from the viewpoint of reactivity, it is preferable that the hydroxyl group is bonded to any of the para positions.

^{Further, R 2} in the structural formula (1) is a hydrogen atom or an alkyl group, and the alkyl group is preferably an alkyl group having 1 to 6 carbon atoms, for example, a methyl group, an ethyl group, or a propyl group. Examples include a group, a butyl group, a pentyl group, and a hexyl group. In the production method described later, from the viewpoint of easy availability of raw materials and reactivity, and from the viewpoint of the balance between heat resistance and elastic modulus of the obtained cured product, it is preferable that there is no substituent on the naphthalene ring, and therefore a hydrogen atom. It is particularly preferable that m is 6.

Further, l in the structural formula (1) indicates the number of naphthalene rings bonded to the benzene ring, which is an integer of 1 to 3, but when used as a precursor of a polyfunctional epoxy resin described later. Is preferably one having a high content of the compound in which l is 1.

<Multifunctional epoxy resin>
In the polyfunctional epoxy resin of the present invention, a naphthol structure which may have a substituent on the aromatic ring and a catechol structure having an alkyl group having 4 to 8 carbon atoms as the substituent on the aromatic ring are substituted. It is characterized by being a reaction product of epihalohydrin and a polyfunctional phenol resin bonded via a methylene group which may have a group.

The polyfunctional epoxy resin has two or more glycidyl ether groups in one molecule, and also has a benzene ring and a naphthalene ring, so that the crosslink density in the cured product is improved and the adjacent glycidyl ethers are present. The hydroxyl groups generated during the curing reaction between the group and the curing agent are also close to each other. As a result, it is considered that hydrogen bonds act more strongly and the elastic modulus of the cured product is also improved.

The naphthalene ring may have a substituent other than the glycidyl ether group, but from the viewpoint of improving the crosslink density in the cured product and having more excellent heat resistance, the naphthalene ring may not have a substituent. preferable. Further, from the viewpoint of easy availability of raw materials and reactivity, it is more preferable that the connecting portion between the benzene ring and the naphthalene ring is a methylene group having no substituent.

Examples of the polyfunctional epoxy resin include those represented by the following structural formula (2).

〔構造式（２）中、Ｇはグリシジル基であり、Ｒは水素原子、アルキル基又はアリール基であり、Ｒ^１は水素原子または炭素原子数４〜８のアルキル基であり、少なくとも一つは炭素原子数４〜８のアルキル基である。Ｒ^２は水素原子またはアルキル基であり、ｎは０〜３の整数であり、ｍは０〜６の整数であり、ｌは１〜３の整数であり、ｎ＋ｌは４である。複数あるＲ^１、Ｒ^２は同一でも異なっていてもよい。〕
なお、前記式（２）において、ナフタレン環と置換基を有していてもよいメチレン基との結合位置は任意であり、水酸基を有する環上であっても、水酸基を有さない環上で結合していてもよいことを示すものであり、ｌが２以上の場合、同一構造であっても異なる構造であってもよい。

[In structural formula (2), G is a glycidyl group, R is a hydrogen atom, an alkyl group or an aryl group, R ¹ is a hydrogen atom or an alkyl group having 4 to 8 carbon atoms, and at least one is It is an alkyl group having 4 to 8 carbon atoms. R ² is a hydrogen atom or an alkyl group, n is an integer of 0 to 3, m is an integer of 0 to 6, l is an integer of 1 to 3, and n + l is 4. A plurality of R ¹ and R ² may be the same or different. ]
In the above formula (2), the bonding position between the naphthalene ring and the methylene group which may have a substituent is arbitrary, and even on a ring having a hydroxyl group, on a ring having no hydroxyl group. It indicates that they may be combined, and when l is 2 or more, they may have the same structure or different structures.

R in the structural formula (2) is a hydrogen atom, an alkyl group, or an aryl group, and examples of the alkyl group include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, and a cyclo. Examples thereof include a xyl group, and examples of the aryl group include a phenyl group, an alkoxyphenyl group, a tolyl group, a xsilyl group, and a naphthyl group. In the production method described later, R is preferably a hydrogen atom, a methyl group, or an ethyl group, and is a hydrogen atom, from the viewpoint of easy availability of raw materials, reactivity, and heat resistance of the obtained cured product. Is particularly preferable.

^{Further, R 1} in the structural formula (1) is a hydrogen atom or an alkyl group having 4 to 8 carbon atoms, and at least one is an alkyl group having 4 to 8 carbon atoms. From the viewpoint of the balance between properties and elasticity, it is preferable to have one alkyl group having 4 to 8 carbon atoms as a substituent on the benzene ring, and the alkyl group is preferably a butyl group, particularly t-. Most preferably it is a butyl group. Further, from the viewpoint of reactivity, it is preferable that the glycidyl ether group is bonded to any of the para positions.

^{Further, R 2} in the structural formula (2) is a hydrogen atom or an alkyl group, and the alkyl group is preferably an alkyl group having 1 to 6 carbon atoms, for example, a methyl group, an ethyl group, or a propyl group. Examples include a group, a butyl group, a pentyl group, and a hexyl group. In the production method described later, from the viewpoint of easy availability of raw materials and reactivity, and from the viewpoint of the balance between heat resistance and elastic modulus of the obtained cured product, it is preferable that there is no substituent on the naphthalene ring, and therefore a hydrogen atom. It is particularly preferable that m is 6.

Further, l in the structural formula (2) indicates the number of naphthalene rings bonded to the benzene ring, which is an integer of 1 to 3, but a polyfunctional epoxy resin described later is used as a curable resin composition. From the viewpoint of handleability and curability when used, it is preferable that the content of the compound having l of 1 is high.

The epoxy equivalent of the polyfunctional epoxy resin is preferably in the range of 165 to 300 g / eq, particularly preferably in the range of 165 to 250 g / eq, from the viewpoint of being superior in heat resistance of the obtained cured product.

The melt viscosity of the polyfunctional epoxy resin at 150 ° C. is preferably in the range of 0.1 to 2 dPa · s, particularly in the range of 0.1 to 1 dPa · s, from the viewpoint of ease of handling. It is preferable to have.

The polyfunctional epoxy resin in the present invention reacts an intermediate polyfunctional phenol resin with epihalohydrin to convert hydroxyl groups into glycidyl ether, but during this reaction, a side reaction occurs and adjacent hydroxyl groups in the catechol structure occur. The hydroxyl groups on the benzene ring and the hydroxyl groups on the naphthalene ring may cyclize with each other or on the naphthalene ring. By including such a by-product, the epoxy resin after the glycidyl etherification reaction may have a lower viscosity, and also contributes to the improvement of the elastic modulus in the obtained cured product, so that the by-product is contained. It is also preferable to use the resin composition as it is.

Examples of the compound obtained by the cyclization include those represented by the following structural formulas.

<Manufacturing method of polyfunctional phenol resin>
The method for producing the polyfunctional phenol resin of the present invention is not particularly limited, and examples thereof include a method of reacting a naphthol compound, an alkylcatechol compound, and an aldehyde compound.

Examples of the naphthol compound include α-naphthol, β-naphthol, and various dihydroxynaphthalene which may have a substituent, but from the viewpoint of reactivity, it is preferable to use unsubstituted β-naphthol.

Examples of the alkylcatechol compound include n-butylcatechol, sec-butylcatechol, t-butylcatechol, 4-octylcatechol, 3,5-di-t-butylcatechol and the like, and the compound comprises only one kind. However, two or more kinds may be mixed and used. Among these, from the viewpoint of the elastic modulus of the obtained cured product, it is preferable to have an alkyl group having a bulkier structure, and t-butylcatechol and 3,5-di-t-butylcatechol may be used. Preferably, t-butylcatechol is most preferred.

Further, examples of the aldehyde compound include formaldehyde, trioxane, acetaldehyde, propionaldehyde, tetraoxymethylene, polyoxymethylene, chloral, hexamethylenetetramine and the like. Each of these may be used alone, or two or more types may be used in combination. Of these, formaldehyde is preferably used because of its excellent reactivity. Formaldehyde may be used as formalin in an aqueous solution state or as paraformaldehyde in a solid state.

From the viewpoint of controlling the molecular weight distribution, it is preferable to use the aldehyde compound in the range of 0.99 to 1.20 mol times the total molar amount of the naphthol compound and the alkylcatechol compound, and particularly 1 It is preferable to use it in the range of 0.001 to 1.10 mol times.

The ratio of the naphthol compound and the alkyl catechol compound should be in the range of naphthol compound / catechol compound = 7/3 to 3/7 in terms of molar ratio from the viewpoint of high heat resistance and high elastic modulus. preferable.

The reaction can be carried out under the same conditions as a normal novolacization reaction. From the viewpoint of more efficiently obtaining the desired compound, as the solvent, toluene, xylene, methyl isobutyl ketone, isopropyl alcohol, n-butanol, propylene glycol monomethyl ether, ethylene glycol, propylene glycol, diethylene glycol and the like can be used. .. The solvent is preferably used in the range of 0.1 to 10 times by mass with respect to the total mass of the raw material naphthol compound and alkyl catechol compound.

Further, examples of the reaction catalyst include inorganic alkalis such as sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate. The amount of the catalyst used is preferably in the range of 0.02 to 0.50 times the total mole of the naphthol compound and the catechol compound.

The reaction temperature is preferably in the range of 60 to 120 ° C., and the water produced by the reaction is preferably distilled off. The reaction time is usually 1 to 16 hours, more preferably 2 to 12 hours.

By the reaction, a polyfunctional phenol resin represented by the structural formula (1) is obtained, but other by-products may be contained. This by-product may be removed and only the compound represented by the structural formula (1) may be taken out and used, but the by-product may be removed and used as a curable resin composition described later, or may be described later. It can also be used as a precursor of a polyfunctional epoxy resin. Further, the content of l in 1 in the structural formula (1) can be usually obtained in an amount of 60% by mass or more by the above-mentioned method, and in particular, a content having a high content of 70% by mass or more can be obtained. it can.

<Manufacturing method of polyfunctional epoxy resin>
The polyfunctional epoxy resin of the present invention can be obtained by a method of epoxidizing the polyfunctional phenol resin obtained by the above-mentioned method.

In addition, other phenols may be used in combination as long as the effects of the present invention are not impaired.

The method for producing a polyfunctional epoxy resin of the present invention is a method for producing an epoxy resin in which the polyfunctional phenol resin of the present invention is reacted with epihalohydrin to epoxidize as described above, and a known technique is appropriately applied to the epoxidation method. can do.

For example, for epihalohydrin, 1 to 10 mol is added to 1 mol of the hydroxyl group contained in the polyfunctional phenol resin, and 0.9 to 2.0 mol of the basic catalyst is added all at once to 1 mol of the raw material hydroxyl group. Alternatively, a method of reacting at a temperature of 20 to 120 ° C. for 0.5 to 10 hours with gradual addition can be mentioned. This basic catalyst may be solid or an aqueous solution thereof may be used. When an aqueous solution is used, water and epihalohydrins are continuously added from the reaction mixture under reduced pressure or under normal pressure. It may be dispensed, further separated to remove water, and epihalohydrins may be continuously returned to the reaction mixture.

During industrial production, all of the epihalohydrins used for preparation are new in the first batch of epoxy resin production, but after the next batch, they are consumed in the reaction with the epihalohydrins recovered from the crude reaction product. It is preferable to use in combination with new epihalohydrins corresponding to the amount that disappears in a certain amount. At this time, impurities such as glycidol, which are induced by the reaction of epichlorohydrin with water, an organic solvent, etc., may be contained. At this time, the epichlorohydrin used is not particularly limited, and examples thereof include epichlorohydrin, epibromohydrin, and β-methylepichlorohydrin. Among these, epichlorohydrin is preferable because it is industrially easily available.

Specific examples of the basic catalyst include alkaline earth metal hydroxides, alkali metal carbonates and alkali metal hydroxides. In particular, alkali metal hydroxides are preferable from the viewpoint of excellent catalytic activity in the epoxy resin synthesis reaction, and examples thereof include sodium hydroxide and potassium hydroxide. In use, these basic catalysts may be used in the form of an aqueous solution of about 10% by mass to 55% by mass, or may be used in the form of a solid. Further, by using an organic solvent in combination, the reaction rate in the synthesis of the epoxy resin can be increased. Such an organic solvent is not particularly limited, and for example, ketones such as acetone and methyl ethyl ketone, alcohols such as methanol, ethanol, 1-propyl alcohol, isopropyl alcohol, 1-butanol, secondary butanol and tertiary butanol, and methyl. Examples thereof include cellosolves such as cellosolve and ethyl cellosolve, ethers such as tetrahydrofuran, 1,4-dioxane, 1,3-dioxane and diethoxyethane, and aprotic polar solvents such as acetonitrile, dimethylsulfoxide and dimethylformamide. Each of these organic solvents may be used alone, or two or more kinds may be used in combination as appropriate to adjust the polarity.

Subsequently, the reaction product of the above-mentioned epoxidation reaction is washed with water, and then the unreacted epihalohydrin and the organic solvent used in combination are distilled off by distillation under heating and reduced pressure. Further, in order to obtain an epoxy resin having less hydrolyzable halogen, the obtained epoxy resin is dissolved again in an organic solvent such as toluene, methyl isobutyl ketone and methyl ethyl ketone, and alkali metal hydroxide such as sodium hydroxide and potassium hydroxide is used. Further reaction can be carried out by adding an aqueous solution of the substance. At this time, a phase transfer catalyst such as a quaternary ammonium salt or a crown ether may be present for the purpose of improving the reaction rate. When the phase transfer catalyst is used, the amount used is preferably in the range of 0.1% by mass to 3.0% by mass with respect to the epoxy resin used. After completion of the reaction, the produced salt is removed by filtration, washing with water, or the like, and further, a solvent such as toluene or methyl isobutyl ketone is distilled off under heating and reduced pressure to obtain a high-purity epoxy resin. By such a method, the content of l of 1 in the structural formula (2) can be usually obtained in an amount of 50% by mass or more by the above-mentioned method, and particularly in a high content of 60% by mass or more. Can be obtained.

<Curable resin composition containing polyfunctional phenol resin>
The polyfunctional phenol resin of the present invention can be made into a curable resin composition by using another compound having a functional group that reacts with a hydroxyl group, that is, a curing agent (X) in combination. The curable resin composition can be suitably used for various electric / electronic member applications such as adhesives, paints, photoresists, printed wiring boards, and semiconductor encapsulation materials.

Examples of the curing agent (X) include a melamine compound, a guanamine compound, a glycoluril compound, a urea compound, a resole resin, and an epoxy substituted with at least one group selected from a methylol group, an alkoxymethyl group, and an acyloxymethyl group. Examples thereof include resins, isocyanate compounds, azide compounds, compounds containing double bonds such as alkenyl ether groups, acid anhydrides, and oxazoline compounds.

The melamine compound is, for example, a compound in which 1 to 6 methylol groups of hexamethylol melamine, hexamethoxymethyl melamine, and hexamethylol melamine are methoxymethylated, hexamethoxyethyl melamine, hexaacyloxymethyl melamine, and methylol of hexamethylol melamine. Examples thereof include compounds in which 1 to 6 groups are asyloxymethylated.

The guanamine compound is, for example, a compound in which 1 to 4 methylol groups of tetramethylol guanamine, tetramethoxymethyl guanamine, tetramethoxymethylbenzoguanamine, and tetramethylol guanamine are methoxymethylated, tetramethoxyethyl guanamine, tetraacyloxyguanamine, and tetra. Examples thereof include compounds in which 1 to 4 methylol groups of methoxyl guanamine are asyloxymethylated.

The glycoluril compound is, for example, 1,3,4,6-tetrakis (methoxymethyl) glycoluril, 1,3,4,6-tetrakis (butoxymethyl) glycoluril, 1,3,4,6-tetrakis (1,3,4,6-tetrakis). Hydroxymethyl) glycol uryl and the like can be mentioned.

Examples of the urea compound include 1,3-bis (hydroxymethyl) urea, 1,1,3,3-tetrakis (butoxymethyl) urea and 1,1,3,3-tetrakis (methoxymethyl) urea. Be done.

The resole resin is, for example, phenol, an alkylphenol such as cresol or xylenol, phenylphenol, resorcinol, biphenyl, bisphenol such as bisphenol A or bisphenol F, a phenolic hydroxyl group-containing compound such as naphthol or dihydroxynaphthalene, and an aldehyde compound that is alkaline. Examples thereof include a polymer obtained by reacting under catalytic conditions.

Examples of the epoxy resin include bisphenol A type epoxy resin, bisphenol F type epoxy resin, biphenyl type epoxy resin, tetramethylbiphenyl type epoxy resin, polyhydroxynaphthalene type epoxy resin, phenol novolac type epoxy resin, and cresol novolac type epoxy resin. Triphenylmethane type epoxy resin, tetraphenylethane type epoxy resin, dicyclopentadiene-phenol addition reaction type epoxy resin, phenol aralkyl type epoxy resin, naphthol novolac type epoxy resin, diglycidyloxynaphthalene, naphthol aralkyl type epoxy resin, naphthol- Phenolic co-condensed novolac type epoxy resin, naphthol-cresol co-condensed novolak type epoxy resin, aromatic hydrocarbon formaldehyde resin modified phenol resin type epoxy resin, biphenyl modified novolac type epoxy resin, 1,1-bis (2,7-diglycidyl) Oxy-1-naphthyl) alkane, naphthylene ether type epoxy resin, triphenylmethane type epoxy resin, phosphorus atom-containing epoxy resin, polyglycidyl ether of cocondensate of phenolic hydroxyl group-containing compound and alkoxy group-containing aromatic compound, etc. Alternatively, the polyfunctional epoxy resin of the present invention can be mentioned. Among these epoxy resins, tetramethylbiphenol type epoxy resin, biphenylaralkyl type epoxy resin, polyhydroxynaphthalene type epoxy resin, and novolac type epoxy resin can be used in terms of obtaining a cured product having particularly excellent flame retardancy. A dicyclopentadiene-phenol addition reaction type epoxy resin is preferable in that a cured product having excellent dielectric properties can be obtained.

Examples of the isocyanate compound include tolylene diisocyanate, diphenylmethane diisocyanate, hexamethylene diisocyanate, cyclohexane diisocyanate and the like.

Examples of the azide compound include 1,1'-biphenyl-4,4'-bis azide, 4,4'-methylidene azide, 4,4'-oxybis azide and the like.

Examples of the compound containing a double bond such as an alkenyl ether group include ethylene glycol divinyl ether, triethylene glycol divinyl ether, 1,2-propanediol divinyl ether, 1,4-butanediol divinyl ether, and tetramethylene glycol divinyl ether. , Neopentyl glycol divinyl ether, trimethylolpropantrivinyl ether, hexanediol divinyl ether, 1,4-cyclohexanediol divinyl ether, pentaerythritol trivinyl ether, pentaerythritol tetravinyl ether, sorbitol tetravinyl ether, sorbitol pentavinyl ether, trimethylol propanetrivinyl ether And so on.

The acid anhydrides include, for example, phthalic anhydride, trimellitic anhydride, pyromellitic anhydride, 3,3', 4,4'-benzophenone tetracarboxylic acid dianhydride, biphenyltetracarboxylic acid dianhydride, 4,4. Aromatic acid anhydrides such as'-(isopropyridene) diphthalic anhydride, 4,4'-(hexafluoroisopropylidene) diphthalic anhydride; tetrahydrophthalic anhydride, methyltetrahydrophthalic anhydride, hexahydrophthalic anhydride , Alicyclic carboxylic acid anhydrides such as methylhexahydrophthalic anhydride, endomethylenetetrahydrophthalic anhydride dodecenylsuccinic anhydride, and trialkyltetrahydrophthalic anhydride.

Among these, an epoxy resin is particularly preferable because it is a curable resin composition having excellent curability and heat resistance in the cured product.

Further, when the epoxy resin is used, a curing agent for epoxy resin may be blended.

Examples of the epoxy resin curing agent that can be used here include various known curing agents for epoxy resins such as amine compounds, amide compounds, acid anhydride compounds, and phenol compounds.

Specifically, diaminodiphenylmethane as amine compound, diethylenetriamine, triethylenetetramine, diaminodiphenyl sulfone, isophoronediamine, imidazo - Le, BF 3 _- amine complex, guanidine derivatives and the like, Examples of the amide compounds include dicyandiamide , Polyamide resin synthesized by a dimer of linolenic acid and ethylenediamine, and the like. Examples of acid anhydride compounds include phthalic anhydride, trimellitic anhydride, pyromellitic anhydride, maleic anhydride, tetrahydrophthalic anhydride, methyltetrahydrophthalic anhydride, methylnadic anhydride, hexahydrophthalic anhydride, and methylhexahydro. Examples include phthalic anhydride. Examples of phenolic compounds include phenol novolac resin, cresol novolac resin, aromatic hydrocarbon formaldehyde resin-modified phenol resin, dicyclopentadienephenol-added resin, phenol aralkyl resin (Zyroc resin), naphthol aralkyl resin, and triphenylol methane resin. Tetraphenylol ethane resin, naphthol novolac resin, naphthol-phenol co-condensed novolak resin, naphthol-cresol co-condensed novolak resin, biphenyl-modified phenol resin (polyphenolic hydroxyl group-containing compound in which phenol nuclei are linked by bismethylene groups), biphenyl Modified naphthol resin (polyvalent naphthol compound in which phenol nuclei are linked by bismethylene group), aminotriazine-modified phenol resin (polyvalent phenolic hydroxyl group-containing compound in which phenol nuclei are linked by melamine, benzoguanamine, etc.) and alkoxy group-containing aromatic ring Examples thereof include polyhydric phenolic hydroxyl group-containing compounds such as modified novolak resin (polyhydric phenolic hydroxyl group-containing compound in which a phenol nucleus and an alkoxy group-containing aromatic ring are linked with formaldehyde).

<Curable resin composition containing a polyfunctional epoxy resin>
The polyfunctional epoxy resin of the present invention can be made into a curable resin composition by using various curing agents (Y) having a group having reactivity with an epoxy group in combination. The curable resin composition can be suitably used for various applications such as adhesives, paints, composite materials, photoresists, printed wiring boards, and semiconductor encapsulation materials.

Examples of the curing agent (Y) that can be used here include various known curing agents for epoxy resins such as amine compounds, amide compounds, acid anhydride compounds, and phenol compounds.

Specifically, diaminodiphenylmethane as amine compound, diethylenetriamine, triethylenetetramine, diaminodiphenyl sulfone, isophoronediamine, imidazo - Le, BF 3 _- amine complex, guanidine derivatives and the like, Examples of the amide compounds include dicyandiamide , Polyamide resin synthesized by a dimer of linolenic acid and ethylenediamine, and the like. Examples of acid anhydride compounds include phthalic anhydride, trimellitic anhydride, pyromellitic anhydride, maleic anhydride, tetrahydrophthalic anhydride, methyltetrahydrophthalic anhydride, methylnadic anhydride, hexahydrophthalic anhydride, and methylhexahydro. Examples include phthalic anhydride. Examples of phenolic compounds include phenol novolac resin, cresol novolac resin, aromatic hydrocarbon formaldehyde resin-modified phenol resin, dicyclopentadienephenol-added resin, phenol aralkyl resin (Zyroc resin), naphthol aralkyl resin, and triphenylol methane resin. Tetraphenylol ethane resin, naphthol novolac resin, naphthol-phenol co-condensed novolak resin, naphthol-cresol co-condensed novolak resin, biphenyl-modified phenol resin (polyphenolic hydroxyl group-containing compound in which phenol nuclei are linked by bismethylene groups), biphenyl Modified naphthol resin (polyvalent naphthol compound in which phenol nuclei are linked by bismethylene group), aminotriazine-modified phenol resin (polyvalent phenolic hydroxyl group-containing compound in which phenol nuclei are linked by melamine, benzoguanamine, etc.) and alkoxy group-containing aromatic ring Examples thereof include polyhydric phenolic hydroxyl group-containing compounds such as modified novolak resin (polyhydric phenolic hydroxyl group-containing compound in which a phenol nucleus and an alkoxy group-containing aromatic ring are linked with formaldehyde). Further, the polyfunctional phenol resin of the present invention may be used.

Further, the curable resin composition of the present invention may be used in combination with other epoxy resins other than the epoxy resin specified above as long as the effects of the present invention are not impaired.

Examples of the other epoxy resin include bisphenol A type epoxy resin, bisphenol F type epoxy resin, biphenyl type epoxy resin, tetramethylbiphenyl type epoxy resin, polyhydroxynaphthalene type epoxy resin, phenol novolac type epoxy resin, and cresol novolac type. Epoxy resin, triphenylmethane type epoxy resin, tetraphenylethane type epoxy resin, dicyclopentadiene-phenol addition reaction type epoxy resin, phenol aralkyl type epoxy resin, naphthol novolac type epoxy resin, naphthol aralkyl type epoxy resin, naphthol-phenol Examples thereof include a reduced novolac type epoxy resin, a naphthol-cresol co-reduced novolak type epoxy resin, an aromatic hydrocarbon formaldehyde resin modified phenol resin type epoxy resin, and a biphenyl modified novolak type epoxy resin. Among these epoxy resins, tetramethylbiphenol type epoxy resin, biphenylaralkyl type epoxy resin, polyhydroxynaphthalene type epoxy resin, and novolac type epoxy resin can be used in terms of obtaining a cured product having particularly excellent flame retardancy. A dicyclopentadiene-phenol addition reaction type epoxy resin is preferable in that a cured product having excellent dielectric properties can be obtained. When other epoxy resins are used in combination, the effect of the present invention is that the epoxy resin of the present invention is contained in an amount of 30 to 90 parts by mass with respect to a total of 100 parts by mass of the epoxy resin of the present invention and the other epoxy resin. Is preferable from the viewpoint that can be easily expressed.

In the curable resin composition of the present invention, the blending amount of the epoxy resin and the curing agent (Y) is the epoxy group in the epoxy resin and other epoxy resins used in combination with the epoxy resin, if necessary, from the viewpoint of excellent curability. It is preferable that the total amount of the active groups in the curing agent (Y) is 0.8 to 1.2 equivalents with respect to the total 1 equivalent.

<Other ingredients>
In the present invention, any of the above-mentioned curable resin composition containing a phenol resin and the curable resin composition containing an epoxy resin may be used in combination with other thermosetting resins.

Examples of other thermosetting resins include cyanate ester resins, resins having a benzoxazine structure, maleimide compounds, active ester resins, vinylbenzyl compounds, acrylic compounds, copolymers of styrene and maleic acid anhydride, and the like. .. When the other thermosetting resin described above is used in combination, the amount used is not particularly limited as long as the effect of the present invention is not impaired, but is in the range of 1 to 50 parts by mass out of 100 parts by mass of the curable resin composition. It is preferable to have.

Examples of the cyanate ester resin include bisphenol A type cyanate ester resin, bisphenol F type cyanate ester resin, bisphenol E type cyanate ester resin, bisphenol S type cyanate ester resin, bisphenol sulfide type cyanate ester resin, and phenylene ether type cyanate ester resin. , Naftyrene ether type cyanate ester resin, biphenyl type cyanate ester resin, tetramethylbiphenyl type cyanate ester resin, polyhydroxynaphthalene type cyanate ester resin, phenol novolac type cyanate ester resin, cresol novolac type cyanate ester resin, triphenylmethane type cyanate. Ester resin, tetraphenylethane type cyanate ester resin, dicyclopentadiene-phenol addition reaction type cyanate ester resin, phenol aralkyl type cyanate ester resin, naphthol novolac type cyanate ester resin, naphthol aralkyl type cyanate ester resin, naphthol-phenol co-condensed novolak Examples thereof include type cyanate ester resin, naphthol-cresol co-condensed novolak type cyanate ester resin, aromatic hydrocarbon formaldehyde resin modified phenol resin type cyanate ester resin, biphenyl modified novolak type cyanate ester resin, and anthracene type cyanate ester resin. Each of these may be used alone, or two or more types may be used in combination.

Among these cyanate ester resins, bisphenol A type cyanate ester resin, bisphenol F type cyanate ester resin, bisphenol E type cyanate ester resin, and polyhydroxynaphthalene type cyanate ester resin are particularly excellent in heat resistance. , Naftylene ether type cyanate ester resin and novolak type cyanate ester resin are preferably used, and dicyclopentadiene-phenol addition reaction type cyanate ester resin is preferable in that a cured product having excellent dielectric properties can be obtained.

The resin having a benzoxazine structure is not particularly limited, but for example, a reaction product of bisphenol F, formalin and aniline (Fa type benzoxazine resin) or a reaction product of diaminodiphenylmethane, formalin and phenol (P-). D-type benzoxazine resin), reaction product of bisphenol A, formalin and aniline, reaction product of dihydroxydiphenyl ether, formalin and aniline, reaction product of diaminodiphenyl ether, formalin and phenol, dicyclopentadiene-phenol addition type resin and formalin And aniline reaction products, phenolphthalein, formalin and aniline reaction products, diphenylsulfide, formalin and aniline reaction products, and the like. Each of these may be used alone, or two or more types may be used in combination.

Examples of the maleimide compound include various compounds represented by any of the following structural formulas (i) to (iii).

（式中Ｒはｍ価の有機基であり、α及びβはそれぞれ水素原子、ハロゲン原子、アルキル基、アリール基の何れかであり、ｓは１以上の整数である。）

(In the formula, R is an m-valent organic group, α and β are any of a hydrogen atom, a halogen atom, an alkyl group, and an aryl group, respectively, and s is an integer of 1 or more.)

（式中Ｒは水素原子、アルキル基、アリール基、アラルキル基、ハロゲン原子、水酸基、アルコキシ基の何れかであり、ｓは１〜３の整数、ｔは繰り返し単位の平均で０〜１０である。）

(In the formula, R is any of a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, a halogen atom, a hydroxyl group, and an alkoxy group, s is an integer of 1 to 3, and t is an average of 0 to 10 in repeating units. .)

（式中Ｒは水素原子、アルキル基、アリール基、アラルキル基、ハロゲン原子、水酸基、アルコキシ基の何れかであり、ｓは１〜３の整数、ｔは繰り返し単位の平均で０〜１０である。）これらはそれぞれ単独で用いても良いし、２種類以上を併用しても良い。

(In the formula, R is any of a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, a halogen atom, a hydroxyl group, and an alkoxy group, s is an integer of 1 to 3, and t is an average of 0 to 10 in repeating units. .) Each of these may be used alone, or two or more types may be used in combination.

The active ester resin is not particularly limited, but generally contains an ester group having high reactive activity such as phenol esters, thiophenol esters, N-hydroxyamine esters, and esters of heterocyclic hydroxy compounds in one molecule. A compound having two or more is preferably used. The active ester resin is preferably obtained by a condensation reaction between a carboxylic acid compound and / or a thiocarboxylic acid compound and a hydroxy compound and / or a thiol compound. In particular, from the viewpoint of improving heat resistance, an active ester resin obtained from a carboxylic acid compound or a halide thereof and a hydroxy compound is preferable, and an active ester resin obtained from a carboxylic acid compound or a halide thereof and a phenol compound and / or a naphthol compound is preferable. More preferred. Examples of the carboxylic acid compound include benzoic acid, acetic acid, succinic acid, maleic acid, itaconic acid, phthalic acid, isophthalic acid, terephthalic acid, pyromellitic acid and the like, or halides thereof. Examples of the phenol compound or naphthol compound include hydroquinone, resorcin, bisphenol A, bisphenol F, bisphenol S, dihydroxydiphenyl ether, phenol phthalein, methylated bisphenol A, methylated bisphenol F, methylated bisphenol S, phenol, o-cresol, m. -Cresol, p-cresol, catechol, α-naphthol, β-naphthol, 1,5-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 2,6-dihydroxynaphthalene, dihydroxybenzophenol, trihydroxybenzophenone, tetrahydroxybenzophenone, fluoroglusin , Benzintriol, dicyclopentadiene-phenol-added resin and the like.

Specific examples of the active ester resin include an active ester resin containing a dicyclopentadiene-phenol addition structure, an active ester resin containing a naphthalene structure, an active ester resin which is an acetylated product of phenol novolac, and an activity which is a benzoyl product of phenol novolac. Ester resins and the like are preferable, and among them, an active ester resin containing a dicyclopentadiene-phenol addition structure and an active ester resin containing a naphthalene structure are more preferable in that they are excellent in improving peel strength. Specific examples of the active ester resin containing a dicyclopentadiene-phenol addition structure include compounds represented by the following general formula (iv).

However, in the formula (iv), R is a phenyl group or a naphthyl group, u represents 0 or 1, and n is an average of 0.05 to 2.5 in repeating units. From the viewpoint of reducing the dielectric loss tangent of the cured product of the resin composition and improving the heat resistance, R is preferably a naphthyl group, u is preferably 0, and n is preferably 0.25 to 1.5. ..

Further, various novolak resins, addition polymerization resins of alicyclic diene compounds such as dicyclopentadiene and phenol compounds, modified novolak resins of phenolic hydroxyl group-containing compounds and alkoxy group-containing aromatic compounds, and phenol aralkyl resins (Zyrocyl resins). ), Naftor aralkyl resin, trimethylolmethane resin, tetraphenylol ethane resin, biphenyl-modified phenol resin, biphenyl-modified naphthol resin, aminotriazine-modified phenol resin, and various vinyl polymers may be used in combination.

More specifically, the various novolak resins are acid catalysts of phenol, phenylphenol, resorcinol, biphenyl, bisphenol such as bisphenol A and bisphenol F, phenolic hydroxyl group-containing compounds such as naphthol and dihydroxynaphthalene, and aldehyde compounds. Examples thereof include a polymer obtained by reacting under conditions.

The various vinyl polymers include polyhydroxystyrene, polystyrene, polyvinylnaphthalene, polyvinylanthracene, polyvinylcarbazole, polyinden, polyacenaftylene, polynorbornene, polycyclodecene, polytetracyclododecene, polynortricyclene, and poly (polynortricyclene, poly). Examples thereof include homopolymers of vinyl compounds such as meth) acrylates and copolymers thereof.

When these other resins are used, the blending ratio can be arbitrarily set according to the intended use, but the effect of balancing the fluidity of the composition and the molding shrinkage during heat curing is more remarkable. From the viewpoint of expression, it is preferable that the proportion of the other resin is 0.5 to 100 parts by mass with respect to 100 parts by mass of the phenol resin or epoxy resin of the present invention.

A curing accelerator may be used in combination with the curable resin composition of the present invention. As the curing accelerator, tertiary amine compounds such as imidazole and dimethylaminopyridine; phosphorus compounds such as triphenylphosphine; boron trifluoride amine complex such as boron trifluoride and boron trifluoride monoethylamine complex; thiodipropion. Organic acid compounds such as acids; benzoxazine compounds such as thiodiphenol benzoxazine and sulfonylbenzoxazine; sulfonyl compounds and the like can be mentioned. Each of these may be used alone, or two or more types may be used in combination. The amount of these catalysts added is preferably in the range of 0.001 to 15 parts by mass in 100 parts by mass of the curable resin composition.

Further, when the curable resin composition of the present invention is used for applications where high flame retardancy is required, a non-halogen flame retardant which does not substantially contain a halogen atom may be blended.

Examples of the non-halogen flame retardant include phosphorus flame retardants, nitrogen flame retardants, silicone flame retardants, inorganic flame retardants, organic metal salt flame retardants, and the like, and their use is also restricted. It may be used alone, a plurality of flame retardants of the same system may be used, and flame retardants of different systems may be used in combination.

As the phosphorus-based flame retardant, either an inorganic type or an organic type can be used. Examples of the inorganic compound include ammonium phosphates such as red phosphorus, monoammonium phosphate, diammonium phosphate, triammonium phosphate and ammonium polyphosphate, and inorganic nitrogen-containing phosphorus compounds such as phosphate amide. ..

Further, the red phosphorus is preferably surface-treated for the purpose of preventing hydrolysis and the like, and examples of the surface treatment method include (i) magnesium hydroxide, aluminum hydroxide, zinc hydroxide and water. A method of coating with an inorganic compound such as titanium oxide, bismuth oxide, bismuth hydroxide, bismuth nitrate or a mixture thereof, (ii) inorganic compounds such as magnesium hydroxide, aluminum hydroxide, zinc hydroxide and titanium hydroxide, and Method of coating with a mixture of thermosetting resins such as phenol resin, (iii) Thermocurability of phenol resin or the like on a film of an inorganic compound such as magnesium hydroxide, aluminum hydroxide, zinc hydroxide, titanium hydroxide Examples thereof include a method of double coating with a resin.

The organic phosphorus compounds include, for example, general-purpose organic phosphorus compounds such as phosphoric acid ester compounds, phosphonic acid compounds, phosphinic acid compounds, phosphine oxide compounds, phosphoran compounds, and organic nitrogen-containing phosphorus compounds, as well as 9,10-dihydro. -9-Oxa-10-phosphaphenanthrene-10-oxide, 10- (2,5-dihydrooxyphenyl) -10H-9-oxa-10-phosphaphenanthrene-10-oxide, 10- (2,7-) Examples thereof include cyclic organophosphorus compounds such as dihydrooxynaphthyl) -10H-9-oxa-10-phosphaphenanthrene-10-oxide and derivatives obtained by reacting the cyclic organophosphorus compounds with compounds such as epoxy resins and phenol resins.

The blending amount of these phosphorus-based flame retardants is appropriately selected depending on the type of the phosphorus-based flame retardant, other components of the resin composition, and the desired degree of flame retardancy. For example, a non-halogen flame retardant. When red phosphorus is used as a non-halogen flame retardant, it is blended in the range of 0.1 parts by mass to 2.0 parts by mass in 100 parts by mass of the resin composition containing all of the fillers and other additives. In the same way, when an organic phosphorus compound is used, it is preferably blended in the range of 0.1 parts by mass to 10.0 parts by mass, and blended in the range of 0.5 parts by mass to 6.0 parts by mass. It is more preferable to do so.

When the phosphorus-based flame retardant is used, hydrotalcite, magnesium hydroxide, boron compound, zirconium oxide, black dye, calcium carbonate, zeolite, zinc molybdate, activated charcoal, etc. may be used in combination with the phosphorus-based flame retardant. Good.

Examples of the nitrogen-based flame retardant include triazine compounds, cyanuric acid compounds, isocyanuric acid compounds, and phenothiazine, and triazine compounds, cyanuric acid compounds, and isocyanuric acid compounds are preferable.

The triazine compound includes, for example, melamine, acetoguanamine, benzoguanamine, melon, melam, succinoguanamine, ethylenedimelamine, polyphosphate melamine, triguanamine and the like, and for example, (1) guanyl melamine sulfate, melem sulfate, melam sulfate. Aminotriazine sulfate compounds such as (2) Phenols such as phenol, cresol, xylenol, butylphenol and nonylphenol, and melamines such as melamine, benzoguanamine, acetguanamine and formguanamine, and a cocondensate of formaldehyde, (3) above. Examples thereof include a mixture of the cocondensate of (2) and a phenol resin such as a phenol formaldehyde condensate, and (4) the above (2) and (3) further modified with tung oil, isomerized melamine oil and the like.

Examples of the cyanuric acid compound include cyanuric acid and melamine cyanuric acid.

The blending amount of the nitrogen-based flame retardant is appropriately selected depending on the type of the nitrogen-based flame retardant, other components of the resin composition, and the desired degree of flame retardancy. For example, a non-halogen flame retardant. And other fillers, additives, etc. are all blended in the range of 0.05 to 10 parts by mass, preferably in the range of 0.1 parts by mass to 5 parts by mass, out of 100 parts by mass of the resin composition. It is more preferable to do so.

When using the nitrogen-based flame retardant, a metal hydroxide, a molybdenum compound, or the like may be used in combination.

The silicone-based flame retardant can be used without particular limitation as long as it is an organic compound containing a silicon atom, and examples thereof include silicone oil, silicone rubber, and silicone resin. The blending amount of the silicone flame retardant is appropriately selected depending on the type of the silicone flame retardant, other components of the resin composition, and the desired degree of flame retardancy. For example, a non-halogen flame retardant. It is preferable to blend in the range of 0.05 to 20 parts by mass in 100 parts by mass of the resin composition containing all of the other fillers and additives. Further, when using the silicone flame retardant, a molybdenum compound, alumina or the like may be used in combination.

Examples of the inorganic flame retardant include metal hydroxides, metal oxides, metal carbonate compounds, metal powders, boron compounds, and low melting point glass.

Examples of the metal hydroxide include aluminum hydroxide, magnesium hydroxide, dolomite, hydrotalcite, calcium hydroxide, barium hydroxide, zirconium hydride and the like.

The metal oxide includes, for example, zinc molybdenum, molybdenum trioxide, zinc tinate, tin oxide, aluminum oxide, iron oxide, titanium oxide, manganese oxide, zirconium oxide, zinc oxide, molybdenum oxide, cobalt oxide, and bismuth oxide. Examples thereof include chromium oxide, nickel oxide, copper oxide, and tungsten oxide.

Examples of the metal carbonate compound include zinc carbonate, magnesium carbonate, calcium carbonate, barium carbonate, basic magnesium carbonate, aluminum carbonate, iron carbonate, cobalt carbonate, titanium carbonate and the like.

Examples of the metal powder include aluminum, iron, titanium, manganese, zinc, molybdenum, cobalt, bismuth, chromium, nickel, copper, tungsten, tin and the like.

Examples of the boron compound include zinc borate, zinc metaborate, barium metaborate, boric acid, and borax.

The low melting point glass includes, for example, Shipley (Boxy Brown Co., Ltd.), hydrated glass SiO ₂ -MgO-H ₂ O, PbO-B ₂ O ₃ system, ZnO-P ₂ O _5- MgO system, P ₂ O ₅ -B ₂ O _3- PbO-MgO system, P-Sn-OF system, PbO-V ₂ O _5- TeO ₂ system, Al ₂ O _3- H ₂ O system, lead borosilicate glassy compounds, etc. Can be mentioned.

The blending amount of the inorganic flame retardant is appropriately selected depending on the type of the inorganic flame retardant, other components of the resin composition, and the desired degree of flame retardancy. For example, a non-halogen flame retardant. It is preferable to blend in the range of 0.05 parts by mass to 20 parts by mass, and in the range of 0.5 parts by mass to 15 parts by mass, out of 100 parts by mass of the resin composition containing all of the other fillers and additives. It is more preferable to mix with.

The organometallic salt-based flame retardant includes, for example, ferrocene, an acetylacetonate metal complex, an organometallic carbonyl compound, an organocobalt salt compound, an organosulfonic acid metal salt, a metal atom and an aromatic compound or a heterocyclic compound in an ionic bond or arrangement. Examples thereof include position-bonded compounds.

The blending amount of the organic metal salt-based flame retardant is appropriately selected depending on the type of the organic metal salt-based flame retardant, other components of the resin composition, and the desired degree of flame retardancy. It is preferable to blend in the range of 0.005 parts by mass to 10 parts by mass in 100 parts by mass of the resin composition containing all of the halogen-based flame retardant and other fillers and additives.

The curable resin composition of the present invention can be blended with an inorganic filler, if necessary. Examples of the inorganic filler include fused silica, crystalline silica, alumina, silicon nitride, aluminum hydroxide and the like. When the blending amount of the inorganic filler is particularly large, it is preferable to use fused silica. The molten silica can be used in either a crushed form or a spherical shape, but in order to increase the blending amount of the molten silica and suppress an increase in the melt viscosity of the molding material, it is preferable to mainly use a spherical one. Further, in order to increase the blending amount of spherical silica, it is preferable to appropriately adjust the particle size distribution of spherical silica. The filling rate is preferably high in consideration of flame retardancy, and is particularly preferably 20% by mass or more with respect to the total mass of the curable resin composition. When used for applications such as conductive paste, a conductive filler such as silver powder or copper powder can be used.

In addition to this, various compounding agents such as a silane coupling agent, a mold release agent, a pigment, and an emulsifier can be added to the curable resin composition of the present invention, if necessary.

<Use of curable resin composition>
The curable resin composition of the present invention shall be applied to semiconductor encapsulant materials, semiconductor devices, prepregs, printed circuit boards, build-up substrates, build-up films, fiber-reinforced composite materials, fiber-reinforced resin molded products, conductive pastes, and the like. Can be done.

1. 1. Semiconductor encapsulation material As a method for obtaining a semiconductor encapsulation material from the curable resin composition of the present invention, the curable resin composition and a compounding agent such as an inorganic filler are used in an extruder or a feeder as necessary. , A method of sufficiently melting and mixing until uniform using a roll or the like can be mentioned. At that time, fused silica is usually used as the inorganic filler, but when used as a high thermal conductivity semiconductor encapsulant for power transistors and power ICs, crystalline silica, alumina, and silicon nitride having higher thermal conductivity than fused silica are used. It is preferable to use high-filling silicon or the like, or use molten silica, crystalline silica, alumina, silicon nitride, or the like. It is preferable to use an inorganic filler in the range of 30 parts by mass to 95 parts by mass per 100 parts by mass of the curable resin composition, and among them, improvement of flame retardancy, moisture resistance and solder crack resistance, wire In order to reduce the coefficient of expansion, 70 parts by mass or more is more preferable, and 80 parts by mass or more is further preferable.

2. Semiconductor device As a method for obtaining a semiconductor device from the curable resin composition of the present invention, the semiconductor encapsulant material is cast or molded using a transfer molding machine, an injection molding machine, or the like, and further at 50 to 200 ° C. 2 A method of heating for 10 hours can be mentioned.

3. 3. Prepreg As a method for obtaining a prepreg from the curable resin composition of the present invention, a curable resin composition obtained by blending an organic solvent to form a varnish is used as a reinforcing base material (paper, glass cloth, glass non-woven fabric, aramid paper, aramid cloth). , Glass mat, glass roving cloth, etc.) and then heated at a heating temperature, preferably 50 to 170 ° C., depending on the type of solvent used. The mass ratio of the resin composition and the reinforcing base material used at this time is not particularly limited, but it is usually preferable to prepare the resin content in the prepreg to be 20% by mass to 60% by mass.

Examples of the organic solvent used here include methyl ethyl ketone, acetone, dimethylformamide, methyl isobutyl ketone, methoxypropanol, cyclohexanone, methyl cellosolve, ethyl diglycol acetate, propylene glycol monomethyl ether acetate and the like. It can be appropriately selected depending on the application, but for example, when further producing a printed circuit board from prepylene as described below, it is preferable to use a polar solvent having a boiling point of 160 ° C. or lower, such as methyl ethyl ketone, acetone, or dimethylformamide. , It is preferable to use the non-volatile content at a ratio of 40% by mass to 80% by mass.

4. Printed circuit board As a method for obtaining a printed circuit board from the curable resin composition of the present invention, the prepregs are laminated by a conventional method, copper foils are appropriately laminated, and the temperature is 170 to 300 ° C. under a pressure of 1 to 10 MPa. Examples thereof include a method of heat-bonding for 10 minutes to 3 hours.

5. Build-up substrate As a method for obtaining a build-up substrate from the curable resin composition of the present invention, a method via steps 1 to 3 can be mentioned. In step 1, first, the curable resin composition in which rubber, a filler and the like are appropriately mixed is applied to a circuit board on which a circuit is formed by a spray coating method, a curtain coating method, or the like, and then cured. In step 2, if necessary, a circuit board coated with the curable resin composition is drilled with a predetermined through-hole portion or the like, treated with a roughening agent, and the surface thereof is washed with hot water. Concavities and convexities are formed on the substrate, and a metal such as copper is plated. In step 3, the operations of steps 1 and 2 are sequentially repeated as desired, and the resin insulating layer and the conductor layer having a predetermined circuit pattern are alternately built up to form a build-up substrate. In the above step, the through-hole portion may be drilled after the outermost resin insulating layer is formed. Further, the build-up substrate of the present invention is roughened by heat-pressing a resin-containing copper foil obtained by semi-curing the resin composition on a copper foil onto a wiring board on which a circuit is formed at 170 to 300 ° C. It is also possible to produce a build-up substrate by omitting the steps of forming a chemical surface and plating.

6. Build-up film As a method of obtaining a build-up film from the curable resin composition of the present invention, for example, a curable resin composition is applied on a support film, dried, and a resin composition layer is placed on the support film. There is a method of forming. When the curable resin composition of the present invention is used as a build-up film, the film is softened under the temperature conditions of lamination (usually 70 ° C. to 140 ° C.) in the vacuum laminating method, and is applied to the circuit board at the same time as laminating the circuit board. It is important to show fluidity (resin flow) capable of filling the existing via hole or through hole with resin, and it is preferable to blend each of the above components so as to exhibit such characteristics.

Here, the diameter of the through hole of the circuit board is usually 0.1 to 0.5 mm, and the depth is usually 0.1 to 1.2 mm, and it is usually preferable to enable resin filling in this range. When laminating both sides of a circuit board, it is desirable to fill about 1/2 of the through holes.

As a specific method for producing the above-mentioned build-up film, after preparing a varnished resin composition by blending an organic solvent, the composition is applied to the surface of a support film, and further heated or hot air is used. Examples thereof include a method of drying the organic solvent by spraying or the like to form a layer of the resin composition.

Examples of the organic solvent used here include ketones such as acetone, methyl ethyl ketone and cyclohexanone, acetates such as ethyl acetate, butyl acetate, cellosolve acetate, propylene glycol monomethyl ether acetate and carbitol acetate, cellosolve and butyl carbitol. Carbitols, aromatic hydrocarbons such as toluene and xylene, dimethylformamide, dimethylacetamide, N-methylpyrrolidone and the like are preferably used, and the non-volatile content is 30% by mass to 60% by mass. Is preferable.

The thickness of the layer of the resin composition to be formed usually needs to be equal to or larger than the thickness of the conductor layer. Since the thickness of the conductor layer of the circuit board is usually in the range of 5 to 70 μm, the thickness of the resin composition layer is preferably 10 to 100 μm. The layer of the resin composition in the present invention may be protected by a protective film described later. By protecting with a protective film, it is possible to prevent dust and the like from adhering to the surface of the resin composition layer and scratches.

The support film and protective film described above include polyolefins such as polyethylene, polypropylene and polyvinyl chloride, polyethylene terephthalate (hereinafter, may be abbreviated as "PET"), polyesters such as polyethylene naphthalate, polycarbonate, polyimide, and further release. Examples include metal foils such as patterns, copper foils, and aluminum foils. The support film and the protective film may be subjected to a mold release treatment in addition to the mud treatment and the corona treatment. The thickness of the support film is not particularly limited, but is usually 10 to 150 μm, and is preferably used in the range of 25 to 50 μm. The thickness of the protective film is preferably 1 to 40 μm.

The support film described above is peeled off after being laminated on a circuit board or after forming an insulating layer by heat curing. If the support film is peeled off after the resin composition layer constituting the build-up film is heat-cured, it is possible to prevent the adhesion of dust and the like in the curing step. When peeling after curing, the support film is usually subjected to a mold release treatment in advance.

A multilayer printed circuit board can be manufactured from the build-up film obtained as described above. For example, when the layers of the resin composition are protected by a protective film, they are peeled off, and then the layer of the resin composition is directly contacted with the circuit board on one or both sides of the circuit board, for example, a vacuum lamination method. Laminate with. The laminating method may be a batch method or a continuous method using a roll. If necessary, the build-up film and the circuit board may be preheated if necessary before laminating. As for the laminating conditions, the crimping temperature (lamination temperature) is preferably 70 to 140 ° C., and the crimping pressure is 1 to 11 kgf / cm ² (9.8 × 10 ^{4 to} 107.9 × 10 ⁴ N / m ² ). It is preferable to laminate under a reduced air pressure of 20 mmHg (26.7 hPa) or less.

7. Fiber-reinforced composite material As a method of obtaining a fiber-reinforced composite material (a sheet-like intermediate material in which a resin is impregnated in a reinforcing fiber) from the resin composition of the present invention, each component constituting the resin composition is uniformly mixed and varnished. Then, after impregnating the reinforcing base material made of reinforcing fibers with the reinforcing base material, a polymerization reaction may be carried out to produce the material.

Specifically, the curing temperature at the time of carrying out such a polymerization reaction is preferably in the temperature range of 50 to 250 ° C., in particular, after curing at 50 to 100 ° C. to obtain a tack-free cured product, further , 120-200 ° C. is preferable.

Here, the reinforcing fiber may be any of twisted yarn, untwisted yarn, untwisted yarn and the like, but the untwisted yarn and the untwisted yarn are preferable because they have both moldability and mechanical strength of the fiber reinforced plastic member. Further, as the form of the reinforcing fiber, one in which the fiber directions are aligned in one direction or a woven fabric can be used. For woven fabrics, plain weaves, satin weaves, and the like can be freely selected according to the part to be used and the intended use. Specific examples thereof include carbon fiber, glass fiber, aramid fiber, boron fiber, alumina fiber, and silicon carbide fiber because of their excellent mechanical strength and durability, and two or more of these can be used in combination. Among these, carbon fibers are particularly preferable from the viewpoint of improving the strength of the molded product, and various carbon fibers such as polyacrylonitrile-based, pitch-based, and rayon-based can be used. Of these, polyacrylonitrile-based ones, which can easily obtain high-strength carbon fibers, are preferable. Here, the amount of the reinforcing fiber used when impregnating the reinforcing base material made of the reinforcing fiber with the varnish to obtain the fiber-reinforced composite material is such that the volume content of the reinforcing fiber in the fiber-reinforced composite material is 40% to 85%. The amount is preferably in the range of.

8. Fiber-reinforced resin molded product As a method of obtaining a fiber-reinforced molded product (molded product in which a sheet-like member impregnated with resin impregnated in reinforcing fibers is cured) from the resin composition of the present invention, a fiber aggregate is laid on a mold and the varnish is applied. Using either the hand lay-up method, spray-up method, or male or female type, in which multiple layers are laminated, the base material made of reinforcing fibers is impregnated with varnish and stacked to form, and pressure is applied to the molded product. Vacuum bag method in which a flexible mold that can be used is covered and airtightly sealed is vacuum (decompressed) molded, SMC press method in which a sheet of varnish containing reinforcing fibers is previously compression-molded with a mold, and fibers are laid out. Examples thereof include a method of producing a prepreg in which reinforcing fibers are impregnated with the varnish by an RTM method in which the varnish is injected into a mating mold, and baking the prepreg with a large autoclave. The fiber-reinforced resin molded product obtained above is a molded product having a reinforcing fiber and a cured product of the resin composition. Specifically, the amount of the reinforcing fiber in the fiber-reinforced molded product is 40 mass. It is preferably in the range of% to 70% by mass, and particularly preferably in the range of 50% by mass to 70% by mass from the viewpoint of strength.

9. Conductive Paste As a method for obtaining a conductive paste from the resin composition of the present invention, for example, a method of dispersing fine conductive particles in the curable resin composition can be mentioned. The conductive paste can be a paste resin composition for circuit connection or an anisotropic conductive adhesive depending on the type of fine conductive particles used.

Next, the present invention will be specifically described with reference to Examples and Comparative Examples. In the following, "parts" and "%" are based on mass unless otherwise specified. GPC, ¹³ C-NMR, and MS were measured under the following conditions.

<GPC measurement conditions>
Measuring device: "HLC-8320 GPC" manufactured by Tosoh Corporation,
Column: Guard column "HXL-L" manufactured by Tosoh Corporation
+ "TSK-GEL G2000HXL" manufactured by Tosoh Corporation
+ "TSK-GEL G2000HXL" manufactured by Tosoh Corporation
+ "TSK-GEL G3000HXL" manufactured by Tosoh Corporation
+ "TSK-GEL G4000HXL" manufactured by Tosoh Corporation
Detector: RI (Differential Refractometer)
Data processing: "GPC Workstation EcoSEC-WorkStation" manufactured by Tosoh Corporation
Measurement conditions: Column temperature 40 ° C
Developing solvent tetrahydrofuran
Flow velocity 1.0 ml / min Standard: The following monodisperse polystyrene with a known molecular weight was used in accordance with the measurement manual of the above-mentioned "GPC workstation EcoSEC-WorkStation".
(Polystyrene used)
"A-500" manufactured by Tosoh Corporation
"A-1000" manufactured by Tosoh Corporation
"A-2500" manufactured by Tosoh Corporation
"A-5000" manufactured by Tosoh Corporation
"F-1" manufactured by Tosoh Corporation
"F-2" manufactured by Tosoh Corporation
"F-4" manufactured by Tosoh Corporation
"F-10" manufactured by Tosoh Corporation
"F-20" manufactured by Tosoh Corporation
"F-40" manufactured by Tosoh Corporation
"F-80" manufactured by Tosoh Corporation
"F-128" manufactured by Tosoh Corporation
Sample: A solution of 1.0% by mass in terms of resin solid content in tetrahydrofuran filtered with a microfilter (50 μl).

< ¹³ C-NMR measurement conditions>
Equipment: ECA500 manufactured by JEOL Ltd.
Measurement mode: Decoupling with reverse gate Solvent: Deuterated dimethyl sulfoxide Pulse angle: 30 ° pulse Sample concentration: 30 wt%
Accumulation number: 2000 times

<Measurement conditions for MALDI-MS spectrum>
The measurement was performed using a matrix-assisted laser desorption / ionization time-of-flight mass spectrometer AXIMA TOF2 manufactured by Shimadzu Corporation.

<Softening point>
Measured based on JIS K7234.

<Melting viscosity>
It was measured with an ICI viscometer according to ASTM D4287.
<Epoxy equivalent>
Measured based on JIS K7236.

Example 1: Synthesis of polyfunctional epoxy resin A-1 122.5 g (0.85 mol) of β-naphthol, t-butylcatechol (trade name DIC manufactured by DIC Corporation) in a 2 L flask equipped with a thermometer, a cooling tube, and a stirrer. -TBC) 141.2 g (0.85 mol) and 20% aqueous sodium hydroxide solution 38.3 g (0.19 mol) were charged, and the temperature was raised to 100 ° C. while dissolving. While maintaining the temperature, 71.0 g (0.88 mol) of 37% formalin was added dropwise over 2 hours. The reaction was then carried out at 100 ° C. for 6 hours and cooled to room temperature. After neutralization with 26.4 g of sodium dihydrogen phosphate, 380 g of methyl isobutyl ketone was added and dissolved, washed with water, and the methyl isobutyl ketone was distilled off under reduced pressure to obtain a product containing a polyfunctional phenol resin. The GPC chart is shown in FIG. As a result of GPC measurement, in the structural formula (1), ^{R 1} is t- butyl, n = 1, m = 0 , a peak assumed to correspond to the l = 1 was 76 area%.

Next, 1174.8 g (12.7 mol) of epichlorohydrin was charged, and the temperature was raised to 50 ° C. while stirring and dissolving. Then, 9.47 g of benzyltrimethylammonium chloride was charged and reacted at a temperature of 50 ° C. for 24 hours. Further, 238.2 g of a 49% aqueous sodium hydroxide solution was added dropwise over 3 hours, and the mixture was further reacted at 50 ° C. for 1 hour. After completion of the reaction, n-butanol 117.4 was added, stirring was stopped, the aqueous layer accumulated in the lower layer was removed, stirring was restarted, and unreacted epichlorohydrin was distilled off under reduced pressure at 150 ° C. 708.9 g of methyl isobutyl ketone and 105.0 g of n-butanol were added to the obtained crude epoxy resin and dissolved. Further, 33.8 g of a 10% aqueous sodium hydroxide solution was added to this solution and reacted at 80 ° C. for 2 hours, and then washing with 209.0 g of water was repeated until the pH of the washing solution became neutral. Next, the inside of the system was dehydrated by azeotrope, and after undergoing microfiltration, the solvent was distilled off under reduced pressure to obtain the desired polyfunctional epoxy resin (A-1). The epoxy equivalent of the obtained polyfunctional epoxy resin (A-1) was 237 g / eq, the melt viscosity at 150 ° C. was 0.2 dPa · s, and the softening point was 54 ° C. The GPC chart of the epoxy resin (A-1) is shown in FIG. 2, the ¹³ C-NMR spectrum is shown in FIG. 3, and the MALDI-MS spectrum is shown in FIG. As a result of GPC measurement, in the structural formula (2), ^{R 1} is t- butyl, n = 1, m = 0 , a peak assumed to correspond to the l = 1 was 65 area%.

Comparative epoxy resin (B-1): t-butylcatechol type epoxy resin EPICLON HP-820 manufactured by DIC Corporation (epoxy equivalent 208 g / eq viscosity 1500 mPa · s at 25 ° C.) was used as it was.

Comparative epoxy resin (B-2): Naphthalene-type epoxy resin EPICLON HP-4770 manufactured by DIC Corporation (epoxy equivalent 204 g / eq, melt viscosity at 150 ° C. 0.7 dPa · s) was used as it was.

Example 3, Comparative Examples 1-2
The epoxy resin (A-1) obtained in Example 1, the comparative epoxy resin (B-1), and (B-2) the epoxy resin of Comparative Examples 1 and 2 and 4,4'-diaminodiphenylsulfone as a curing agent. Was blended so that epoxy equivalent / active hydrogen equivalent = 1/1, and melt-mixed at 120 ° C. to obtain a curable resin composition. Further, the curable resin composition was poured between glass plates sandwiching 2 mm and 4 mm spacers, respectively, and a curing reaction was carried out at 150 ° C. for 1 hour and then at 180 ° C. for 3 hours to prepare a cured product, which was evaluated as follows. .. The results are summarized in Table 1.

<Glass transition temperature>
A cured product having a thickness of 2 mm was cut into a size having a width of 5 mm and a length of 20 mm, and this was used as a test piece. This test piece is used as a viscoelasticity measuring device (DMA: solid viscoelasticity measuring device "DMS6100" manufactured by Hitachi High-Tech Science Co., Ltd., deformation mode: double-sided bending, measurement mode: sinusoidal vibration, frequency 1 Hz, heating rate 3 ° C./min) The temperature at which the change in viscoelasticity was maximized (the rate of change in tan δ was the largest) was evaluated as the glass transition temperature.

<Bending strength, flexural modulus, bending strain>
The bending strength, flexural modulus, and bending strain of a cured product having a thickness of 4 mm were measured according to JIS K7171.

Claims (18)

The naphthol structure which may have a substituent on the aromatic ring and the catechol structure which has an alkyl group having 4 to 8 carbon atoms as the substituent on the aromatic ring may have a substituent. A polyfunctional phenol resin characterized by being bonded via a group. The polyfunctional phenol resin according to claim 1, which is represented by the following structural formula (1).

[In the structural formula (1), R is a hydrogen atom, an alkyl group or an aryl group, R ¹ is a hydrogen atom or an alkyl group having 4 to 8 carbon atoms, and at least one has 4 to 8 carbon atoms. It is an alkyl group. R ² is a hydrogen atom or an alkyl group, n is an integer of 0 to 3, m is an integer of 0 to 6, l is an integer of 1 to 3, and n + l is 4. A plurality of R ¹ and R ² may be the same or different. ] The polyfunctional phenol resin according to claim 2, wherein ^{R and R 2} in the structural formula (1) are hydrogen atoms and m is 6. Claim 1 in the structural formula (1), wherein ^one of R1 is a butyl group, the other is a hydrogen atom, and the butyl group is bonded to any of the para positions with respect to the hydroxyl group. 3. The polyfunctional phenol resin according to any one of Items 3. A curable resin composition containing the polyfunctional phenol resin according to any one of claims 1 to 4 and a curing agent (X). The naphthol structure which may have a substituent on the aromatic ring and the catechol structure which has an alkyl group having 4 to 8 carbon atoms as the substituent on the aromatic ring may have a substituent. A polyfunctional epoxy resin characterized by being a reaction product of a polyfunctional phenol resin bonded via a group and epihalohydrin. The polyfunctional epoxy resin according to claim 6, which is represented by the following structural formula (2).

[In structural formula (2), G is a glycidyl group, R is a hydrogen atom, an alkyl group or an aryl group, R ¹ is a hydrogen atom or an alkyl group having 4 to 8 carbon atoms, and at least one is It is an alkyl group having 4 to 8 carbon atoms. R ² is a hydrogen atom or an alkyl group, n is an integer of 0 to 3, m is an integer of 0 to 6, l is an integer of 1 to 3, and n + l is 4. A plurality of R ¹ and R ² may be the same or different. ] The polyfunctional epoxy resin according to claim 6, wherein ^{R and R 2} in the structural formula (1) are hydrogen atoms and m is 6. ^{The claim that one} of R1 in the structural formula (1) is a butyl group, the other is a hydrogen atom, and the butyl group is bonded to any of the para positions with respect to the glycidyl ether group. Item 6. The polyfunctional epoxy resin according to any one of Items 6 to 8. A curable resin composition containing the polyfunctional epoxy resin according to any one of claims 6 to 9 and a curing agent (Y). A cured product of the curable resin composition according to claim 5 or 10. A fiber-reinforced composite material containing the curable resin composition according to claim 5 or 10 and reinforcing fibers. A fiber-reinforced molded product which is a cured product of the fiber-reinforced composite material according to claim 10. A semiconductor encapsulating material containing the curable resin composition according to claim 5 or 10 and an inorganic filler. A semiconductor device which is a cured product of the semiconductor encapsulating material according to claim 14. A prepreg that is a semi-cured product of an impregnated base material having the curable resin composition according to claim 5 or 10 and a reinforcing base material. A circuit board comprising a plate-shaped excipient of the epoxy resin composition according to claim 5 or 10 and a copper foil. A build-up film comprising a cured product of the epoxy resin composition according to claim 5 or 10 and a base film.

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