JP2021052608A - Plastic oil/fat composition - Google Patents
Plastic oil/fat composition Download PDFInfo
- Publication number
- JP2021052608A JP2021052608A JP2019176882A JP2019176882A JP2021052608A JP 2021052608 A JP2021052608 A JP 2021052608A JP 2019176882 A JP2019176882 A JP 2019176882A JP 2019176882 A JP2019176882 A JP 2019176882A JP 2021052608 A JP2021052608 A JP 2021052608A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- fatty acid
- fat
- plastic
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 92
- 239000004033 plastic Substances 0.000 title claims abstract description 83
- 239000003921 oil Substances 0.000 claims abstract description 118
- 235000019198 oils Nutrition 0.000 claims abstract description 117
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 46
- 239000000194 fatty acid Substances 0.000 claims abstract description 46
- 229930195729 fatty acid Natural products 0.000 claims abstract description 46
- -1 fatty acid ester Chemical class 0.000 claims abstract description 46
- 239000007788 liquid Substances 0.000 claims abstract description 16
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- 239000002540 palm oil Substances 0.000 claims abstract description 15
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
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- 150000004671 saturated fatty acids Chemical class 0.000 claims description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 3
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 3
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- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 2
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 2
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- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000012773 waffles Nutrition 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
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- Edible Oils And Fats (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Abstract
Description
本発明は、可塑性油脂組成物に関する。 The present invention relates to a plastic fat composition.
製菓用マーガリンおよびファットスプレッドでは、広い温度範囲における良好な可塑性、また、これに由来する好ましい硬さやクリーミング性を得るために、固体脂と液状油を適度にバランスよく調合した油脂が使用される。従来、固体脂には天然の動植物油脂に水素添加した硬化油が使用され、一般に、完全水素添加を行った硬化油を極度硬化油、部分的に水素添加を行った硬化油を部分硬化油と呼ぶ。これらは、融点を調整するために水素添加の度合いを制御して製造されるが、部分硬化油を製造する際、トランス脂肪酸が生成する。これらは、血液中のLDLコレステロールや中性脂肪の増加を促し、心筋梗塞や動脈硬化などの生活習慣病を引き起こすことが示唆されている。そのため、トランス脂肪酸を含まない、または低減したマーガリンおよびファットスプレッドが求められている。 In confectionery margarines and fat spreads, fats and oils in which solid fats and liquid oils are appropriately well-balanced are used in order to obtain good plasticity in a wide temperature range and favorable hardness and creaming property derived from the good plasticity. Conventionally, hydrogenated oils obtained by hydrogenating natural animal and vegetable fats and oils have been used as solid fats. Generally, hydrogenated oils that have been completely hydrogenated are referred to as extremely hydrogenated oils, and hydrogenated oils that have been partially hydrogenated are referred to as partially hydrogenated oils. Call. These are produced by controlling the degree of hydrogenation in order to adjust the melting point, but trans fatty acids are produced when the partially hydrogenated oil is produced. It has been suggested that these promote an increase in LDL cholesterol and triglyceride in the blood and cause lifestyle-related diseases such as myocardial infarction and arteriosclerosis. Therefore, there is a need for margarines and fat spreads that do not contain or reduce trans fatty acids.
このことから、トランス脂肪酸を含有する部分硬化油の代替として、天然由来固体脂であるパーム油の利用が提案されている(特許文献1)。しかし、パーム油を可塑性油脂の原料油脂として使用した場合、パーム油は結晶化が遅く、保管中に結晶化が進んでしまうことから伸展性が悪く作業性が大きく損なわれるという問題があった。その問題に対してパーム油やパームステアリンと、ラウリン酸を含む油脂を特定量の脂肪酸比率に混合し、エステル交換することで、経時的な品質変化を抑制できる油脂組成物が開示されている(特許文献2)。しかし、この方法はパーム油中のトリグリセリドPOPを他成分に変えるものであり、経日変化の抑制について一定の効果はあるが十分ではなく、口溶けの悪化などの欠点もあった。また、近年、健康への配慮からマーガリンやファットスプレッドに用いる油脂として、液状油をより多く利用できることが望まれている。しかし、液状油はマーガリンやファットスプレッドとして良好な可塑性を付与する効果が低いため、マーガリンやファットスプレッドに必要な好ましい硬さやクリーミング性が失われる。油脂固化剤を添加することで、好ましい可塑性を付与した液状油を多く含有するマーガリンおよびショートニングが提案されている(特許文献3、4)。しかし、この方法では、液状油を多く含有する油脂に対して可塑性を付与するために、油脂固化剤の添加量が多くなり、実用性に欠ける問題がある。 For this reason, the use of palm oil, which is a naturally derived solid fat, has been proposed as an alternative to partially hydrogenated oil containing trans fatty acids (Patent Document 1). However, when palm oil is used as a raw material fat for plastic fats and oils, palm oil has a problem that crystallization is slow and crystallization progresses during storage, resulting in poor extensibility and greatly impaired workability. To solve this problem, a fat and oil composition that can suppress quality changes over time by mixing palm oil or palm stearin with fats and oils containing lauric acid in a specific amount of fatty acid ratio and transesterifying them (disclosed). Patent Document 2). However, this method changes the triglyceride POP in palm oil into other components, and although it has a certain effect on suppressing diurnal changes, it is not sufficient and has drawbacks such as deterioration of melting in the mouth. Further, in recent years, it has been desired that more liquid oil can be used as fats and oils used for margarine and fat spreads in consideration of health. However, since the liquid oil has a low effect of imparting good plasticity as a margarine or fat spread, the preferable hardness and creaming property required for the margarine or fat spread are lost. Margarine and shortening containing a large amount of liquid oil to which preferable plasticity is imparted by adding an oil solidifying agent have been proposed (Patent Documents 3 and 4). However, this method has a problem that it is not practical because the amount of the fat and oil solidifying agent added is large in order to impart plasticity to the fat and oil containing a large amount of liquid oil.
本発明は、上記事情に鑑み、パーム油高配合でありながら、適度な可塑性を有しクリーミング性に優れる可塑性油脂組成物を提供することである。 In view of the above circumstances, the present invention provides a plastic oil / fat composition having an appropriate plasticity and excellent creaming property while having a high palm oil content.
本発明者が鋭意研究を重ねた結果、精製パーム油60〜90重量%、20℃で液状である油10〜40重量%を含有する油脂、乳化剤、水からなり、20℃での最大応力および溶融状態から5℃まで毎分2℃で冷却した際の5℃における粘度が特定の範囲である可塑性油脂組成物を用いることで、上記課題が達成されることを見出し、本発明を完成するに至った。 As a result of diligent research by the present inventor, it is composed of fats and oils, emulsifiers and water containing 60 to 90% by weight of refined palm oil and 10 to 40% by weight of oil that is liquid at 20 ° C. We have found that the above problems can be achieved by using a plastic oil / fat composition having a viscosity at 5 ° C. in a specific range when cooled from a molten state to 5 ° C. at 2 ° C. per minute, and complete the present invention. I arrived.
本発明の可塑性油脂組成物はクリーミング性に優れ、長期保存した場合でも物性変化なく安定なクリーミング性、気泡安定性を示すものを提供することができる。さらに、本発明の可塑性油脂組成物を用いることで、ボリューム感があるケーキを製造することができる。 The plastic oil / fat composition of the present invention is excellent in creaming property, and can provide a composition exhibiting stable creaming property and bubble stability without change in physical properties even when stored for a long period of time. Furthermore, by using the plastic oil / fat composition of the present invention, a cake with a voluminous feel can be produced.
以下に本発明を実施するために最適な形態について詳細に説明する。なお、本発明の範囲はこの実施形態に限定されるものではなく、本発明の趣旨を損なわない範囲で変更等が加えられた形態も本発明に属する。なお、範囲を表す「〜」は上限と下限を含むものである。 The optimum mode for carrying out the present invention will be described in detail below. The scope of the present invention is not limited to this embodiment, and modifications and the like are also included in the present invention as long as the gist of the present invention is not impaired. In addition, "~" representing a range includes an upper limit and a lower limit.
本発明は、以下の通りである。
下記成分(A)、成分(B)、および、成分(C)からなる可塑性油脂組成物において、20℃での最大応力が600〜1,200gであり、溶融状態から5℃まで毎分2℃で冷却した際の5℃における粘度が2,000〜40,000mPa・sであり、成分(B)として可塑性油脂組成物全量に対し、ポリグリセリン脂肪酸エステルを0.01〜5重量%含有することを特徴とする可塑性油脂組成物。
(A)精製パーム油60〜90重量%、20℃で液状である油10〜40重量%を含有する油脂
(B)乳化剤
(C)水
The present invention is as follows.
In the plastic oil / fat composition composed of the following components (A), component (B), and component (C), the maximum stress at 20 ° C. is 600 to 1,200 g, and the temperature is 2 ° C. per minute from the molten state to 5 ° C. The viscosity at 5 ° C. when cooled with is 2,000 to 40,000 mPa · s, and 0.01 to 5% by weight of polyglycerin fatty acid ester is contained as the component (B) with respect to the total amount of the plastic fat and oil composition. A plastic oil / fat composition characterized by.
(A) Oil containing 60 to 90% by weight of refined palm oil and 10 to 40% by weight of oil liquid at 20 ° C. (B) Emulsifier (C) Water
本発明に係る成分(A)は、精製パーム油60〜90重量%、20℃で液状である油10〜40重量%を含有する油脂である。 The component (A) according to the present invention is an oil or fat containing 60 to 90% by weight of refined palm oil and 10 to 40% by weight of oil that is liquid at 20 ° C.
20℃で液状の油は、特に限定されるものではないが、例えば大豆油、ナタネ油、コーン油、ゴマ油、シソ油、亜麻仁油、落花生油、紅花油、高オレイン酸紅花油、綿実油、ぶどう種子油、マカデミアナッツ油、ヘーゼルナッツ油、かぼちゃ種子油、クルミ油、椿油、茶実油、エゴマ油、オリーブ油、カラシ油、パームオレイン、米油、米糠油、小麦麦芽油、サフラワー油、ひまわり油およびこれらの分別油脂が例示される。更に、ジグリセライドおよび/またはモノグリセライドが含有または調合されているものであっても良い。 The oil liquid at 20 ° C. is not particularly limited, but for example, soybean oil, rapeseed oil, corn oil, sesame oil, perilla oil, flaxseed oil, peanut oil, safflower oil, high oleic safflower oil, cottonseed oil, grapes. Seed oil, macadamia nut oil, hazelnut oil, pumpkin seed oil, walnut oil, camellia oil, tea seed oil, egoma oil, olive oil, mustard oil, palm olein, rice oil, rice bran oil, wheat germ oil, safflower oil, sunflower oil and Examples of these separated oils and fats. Further, it may contain or be formulated with diglyceride and / or monoglyceride.
本発明に係る成分(A)は、精製パーム油や20℃で液状の油以外の油脂も使用することができるが、トランス脂肪酸を含んだ部分硬化油を実質的に含有しない油脂で構成されることが好ましい。例えば、パーム核油、ヤシ油、カカオ脂等の植物油脂や、牛脂、ラード、鶏脂、乳脂、魚油、アザラシ油等の動物油脂、およびこれらの分別油脂や混合油が例示される。また、対象となる油脂が、エステル交換した油脂や完全水素添加した極度硬化油であっても良い。更に、ジグリセライドおよび/またはモノグリセライドが含有または調合されているものであっても良い。 The component (A) according to the present invention may contain oils and fats other than refined palm oil and oils liquid at 20 ° C., but is composed of oils and fats that do not substantially contain partially hydrogenated oil containing trans fatty acids. Is preferable. Examples thereof include vegetable oils and fats such as palm kernel oil, coconut oil and coconut oil, animal oils and fats such as beef tallow, lard, chicken fat, milk fat, fish oil and coconut oil, and fractionated oils and fats and mixed oils thereof. Further, the target oil or fat may be a transesterified oil or an extremely hydrogenated oil or a completely hydrogenated oil. Further, it may contain or be formulated with diglyceride and / or monoglyceride.
本発明に係る成分(B)は乳化剤であり、乳化剤のうちポリグリセリン脂肪酸エステルを可塑性油脂組成物全量に対して0.01〜5重量%含有するものであり、0.1重量%以上含有することが好ましい。 The component (B) according to the present invention is an emulsifier, and among the emulsifiers, the polyglycerin fatty acid ester is contained in an amount of 0.01 to 5% by weight based on the total amount of the plastic fat / oil composition, and is contained in an amount of 0.1% by weight or more. Is preferable.
本発明に係るポリグリセリン脂肪酸エステルは、グリセリン同士を脱水縮合したポリグリセリンと脂肪酸のエステル化反応によって得られ、ポリグリセリンの種類(重合度)、脂肪酸の種類(炭素数、二重結合の数)、エステル組成などにより、多数存在する。そして、その種類毎に異なる性質を示すことが知られている。 The polyglycerin fatty acid ester according to the present invention is obtained by an esterification reaction of a fatty acid with polyglycerin obtained by dehydration condensation of glycerins, and the type of polyglycerin (degree of polymerization) and the type of fatty acid (number of carbon atoms, number of double bonds). , There are many depending on the ester composition and the like. And it is known that each type exhibits different properties.
ポリグリセリン脂肪酸エステルはその平均重合度が限定されるものではないが、2〜10であることが好ましく、4〜10であることが更に好ましい。ここで、平均重合度は、末端基分析法による水酸基価から算出されるポリグリセリンの平均重合度(n)である。詳しくは、下記式(1)及び下記式(2)から算出される。
分子量=74n+18 ・・・(1)
水酸基価=56110(n+2)/分子量 ・・・(2)
The average degree of polymerization of the polyglycerin fatty acid ester is not limited, but is preferably 2 to 10 and more preferably 4 to 10. Here, the average degree of polymerization is the average degree of polymerization (n) of polyglycerin calculated from the hydroxyl value by the end group analysis method. Specifically, it is calculated from the following formula (1) and the following formula (2).
Molecular weight = 74n + 18 ... (1)
Hydroxy group value = 56110 (n + 2) / molecular weight ... (2)
上記式(2)中の水酸基価とは、ポリグリセリンに含まれる水酸基数の大小の指標となる数値であり、1gのポリグリセリンに含まれる遊離ヒドロキシル基をアセチル化するために必要な酢酸を中和するのに要する水酸化カリウムのミリグラム数をいう。水酸化カリウムのミリグラム数は、社団法人日本油化学会編纂「日本油化学会制定、基準油脂分析試験法、2003年度版」に準じて算出される。 The hydroxyl value in the above formula (2) is a numerical value that is an index of the number of hydroxyl groups contained in polyglycerin, and contains acetic acid required for acetylating the free hydroxyl group contained in 1 g of polyglycerin. The number of milligrams of potassium hydroxide required for summing. The number of milligrams of potassium hydroxide is calculated according to "Established by the Japan Oil Chemists'Association, Standard Oil and Fat Analysis Test Method, 2003 Edition" compiled by the Japan Oil Chemists' Society.
ポリグリセリン脂肪酸エステルを構成する脂肪酸としては、特に限定されないが、通常炭素数8〜24の飽和または不飽和の脂肪酸が用いられる。前記脂肪酸は混合物であってもよく、前記脂肪酸の具体例としては、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、リシノール酸、リノール酸、リノレン酸、エルカ酸、ベヘン酸、及びその縮合物等が挙げられる。 The fatty acid constituting the polyglycerin fatty acid ester is not particularly limited, but a saturated or unsaturated fatty acid having 8 to 24 carbon atoms is usually used. The fatty acid may be a mixture, and specific examples of the fatty acid include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, ricinolic acid, linoleic acid, linolenic acid, and erucic acid. , Behenic acid, and condensates thereof.
ポリグリセリン脂肪酸エステルは、従来公知のエステル化反応により製造することができる。例えば、脂肪酸とポリグリセリンとを水酸化ナトリウム等のアルカリ触媒の存在下でエステル化反応させることにより製造することができる。エステル化は、ポリグリセリン脂肪酸エステルのエステル化率が所望の値になるまで行われる。 The polyglycerin fatty acid ester can be produced by a conventionally known esterification reaction. For example, it can be produced by subjecting a fatty acid and polyglycerin to an esterification reaction in the presence of an alkaline catalyst such as sodium hydroxide. Esterification is carried out until the esterification rate of the polyglycerin fatty acid ester reaches a desired value.
ここで、エステル化率とは、水酸基価から算出されるポリグリセリンの平均重合度(n)、このポリグリセリンが有する水酸基数(n+2)、ポリグリセリンに付加する脂肪酸のモル数(M)としたとき、下記式(3)で算出される値である。水酸基価とは、上記式(2)により算出される値である。
エステル化率(%)=(M/(n+2))×100 ・・・(3)
Here, the esterification rate is defined as the average degree of polymerization (n) of polyglycerin calculated from the hydroxyl value, the number of hydroxyl groups of this polyglycerin (n + 2), and the number of moles of fatty acid added to polyglycerin (M). Then, it is a value calculated by the following formula (3). The hydroxyl value is a value calculated by the above formula (2).
Esterification rate (%) = (M / (n + 2)) × 100 ... (3)
本発明に係るポリグリセリン脂肪酸エステルは、良好なクリーミング性と適度な可塑性を両立する点から、構成脂肪酸が炭素数16〜22の飽和脂肪酸であるポリグリセリン脂肪酸エステル(1)から選ばれる1種以上と、構成脂肪酸が炭素数18〜22の不飽和脂肪酸であるポリグリセリン脂肪酸エステル(2)から選ばれる1種以上であることが特に好ましい。これらの中でも特にクリーミング性を向上できる点からポリグリセリン脂肪酸エステル(1)はパルミチン酸、ステアリン酸、ベヘン酸で構成されることが最も好ましく、ポリグリセリン脂肪酸エステル(2)は製菓用可塑性油脂組成物の硬さを調節する点からオレイン酸で構成されることが最も好ましい。 The polyglycerin fatty acid ester according to the present invention is one or more selected from the polyglycerin fatty acid ester (1) whose constituent fatty acid is a saturated fatty acid having 16 to 22 carbon atoms from the viewpoint of achieving both good creaming property and appropriate plasticity. It is particularly preferable that the constituent fatty acid is at least one selected from the polyglycerin fatty acid ester (2), which is an unsaturated fatty acid having 18 to 22 carbon atoms. Among these, the polyglycerin fatty acid ester (1) is most preferably composed of palmitic acid, stearic acid, and behenic acid from the viewpoint of improving creaming property, and the polyglycerin fatty acid ester (2) is a plastic fat and oil composition for confectionery. It is most preferably composed of oleic acid from the viewpoint of adjusting the hardness of the ester.
ポリグリセリン脂肪酸エステルを2種以上併用する場合、ポリグリセリン脂肪酸エステル(1)のエステル化率は60〜100%が好ましく、75〜100%がより好ましい。また、ポリグリセリン脂肪酸エステル(2)のエステル化率は5〜30%が好ましく10〜25%がより好ましい。 When two or more kinds of polyglycerin fatty acid esters are used in combination, the esterification rate of the polyglycerin fatty acid ester (1) is preferably 60 to 100%, more preferably 75 to 100%. The esterification rate of the polyglycerin fatty acid ester (2) is preferably 5 to 30%, more preferably 10 to 25%.
本発明に係るポリグリセリン脂肪酸エステルのHLBは1〜18であることが好ましく、より好ましくは2〜13である。HLBはアトラス法を用い、エステルのけん化価および脂肪酸の中和価から算出したものであり、以下の式(4)により算出する。また、式(4)中のけん化価および中和価は社団法人日本油化学会編纂「日本油化学会制定、基準油脂分析試験法、2003年度版」に準じて測定する。
HLB=20×(1−けん化価/中和価) ・・・(4)
The HLB of the polyglycerin fatty acid ester according to the present invention is preferably 1 to 18, and more preferably 2 to 13. The HLB is calculated from the saponification value of the ester and the neutralization value of the fatty acid using the Atlas method, and is calculated by the following formula (4). The saponification value and the neutralization value in the formula (4) are measured according to "Established by the Japan Oil Chemists'Association, Standard Oil and Fat Analysis Test Method, 2003 Edition" compiled by the Japan Oil Chemists' Society.
HLB = 20 × (1-saponification value / neutralization value) ・ ・ ・ (4)
また、ポリグリセリン脂肪酸エステルを2種以上併用する場合は、ポリグリセリン脂肪酸エステル(1)のHLBは2〜5が好ましく、ポリグリセリン脂肪酸エステル(2)のHLBは8〜13が好ましい。 When two or more kinds of polyglycerin fatty acid esters are used in combination, the HLB of the polyglycerin fatty acid ester (1) is preferably 2 to 5, and the HLB of the polyglycerin fatty acid ester (2) is preferably 8 to 13.
本発明に係る成分(B)には、ポリグリセリン脂肪酸エステル以外を併用しても良く、例えば、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ショ糖脂肪酸エステル、リン脂質等を1種以上併用することができる。可塑性油脂組成物全量に対して乳化剤含量は0.01〜5重量%が好ましく、より好ましくは0.1〜3重量%である。 A component (B) according to the present invention may be used in combination with other than polyglycerin fatty acid ester, for example, one or more glycerin fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, sucrose fatty acid ester, phospholipid and the like. Can be used together. The emulsifier content is preferably 0.01 to 5% by weight, more preferably 0.1 to 3% by weight, based on the total amount of the plastic fat / oil composition.
本実施形態における可塑性油脂組成物を用いてなる食品には必要に応じ、一般的にマーガリン、ファットスプレッドに使用されている他の原料、例えば、トコフェロール、L−アスコルビン酸パルミチン酸エステル、茶抽出物等の酸化防止剤、カロチン等の着色料、脱脂粉乳、クリーム等の乳成分、蔗糖、液糖、はちみつ、ブドウ糖、果糖、黒糖、麦芽糖、乳糖、水飴、ソルビトール、エリスリトール、異性化液糖、ショ糖結合飴、オリゴ糖、トレハロース、ヘミセルロース等の糖類、食塩、酸味料、調味料、香料、重合リン酸塩等の乳化安定剤、ローカストビーンガム、カラギーナン、アルギン酸類、ペクチン、キサンタンガム、寒天、グルコマンナン、ゼラチン、化工澱粉、澱粉等の増粘安定剤等を、適宜使用することができる。 For foods using the plastic fat composition in the present embodiment, if necessary, margarine, other raw materials generally used for fat spread, for example, tocopherol, L-ascorbic acid palmitate, tea extract, etc. Antioxidants such as antioxidants, colorants such as carrageenan, defatted milk powder, milk components such as cream, sucrose, liquid sugar, honey, glucose, fructose, brown sugar, malt sugar, lactose, starch syrup, sorbitol, erythritol, isomerized liquid sugar, sho Sugar-bonded starch syrup, oligosaccharides, trehalose, sugars such as hemicellulose, salt, acidulants, seasonings, fragrances, emulsion stabilizers such as polymerized phosphates, locust bean gum, carrageenan, alginic acids, pectin, xanthan gum, agar, gluco Thickening stabilizers such as mannan, gelatin, sucrose starch, and starch can be appropriately used.
本実施形態の可塑性油脂組成物は、経日的な油脂の粗大結晶化や固液分離が抑えられるため、可塑性、展延性、ショートニング性、クリーミング性等の物理的性質が好適に付与されてなり、食品に使用することが可能である。 Since the plastic fat and oil composition of the present embodiment suppresses coarse crystallization and solid-liquid separation of fats and oils over time, physical properties such as plasticity, malleability, shortening property, and creaming property are preferably imparted. , Can be used in food.
本発明に係る可塑性油脂組成物は、20℃での最大応力が600〜1,200gである。20℃での最大応力が600〜1,200gである可塑性油脂組成物は、柔らかすぎたり、硬すぎたりすることなくハンドリング性が良好であり、クリーミング性に優れるものである。 The plastic oil / fat composition according to the present invention has a maximum stress of 600 to 1,200 g at 20 ° C. The plastic oil / fat composition having a maximum stress of 600 to 1,200 g at 20 ° C. is not too soft or too hard, has good handleability, and is excellent in creaming property.
20℃での最大応力とは、レオメーターおよび圧縮弾性用アダプター(φ10mm平丸)を用い、20℃にて1時間静置した可塑性油脂組成物の最大応力を測定した値であり、テーブルスピードを6cm/minとして、アダプターが試料を10mm圧縮した時の最大応力を測定した。 The maximum stress at 20 ° C is a value obtained by measuring the maximum stress of a plastic oil / fat composition that has been allowed to stand at 20 ° C for 1 hour using a rheometer and an adapter for compressive elasticity (φ10 mm flat circle), and has a table speed of 6 cm. As / min, the maximum stress when the adapter compressed the sample by 10 mm was measured.
本発明に係る可塑性油脂組成物は、溶融状態から5℃まで毎分2℃で冷却した際の5℃における粘度が2,000〜40,000mPa・sであり、3,000〜20,000mPa・sが好ましい。溶融状態から5℃まで毎分2℃で冷却した際の5℃における粘度が2,000〜40,000mPa・sである可塑性油脂組成物は温度変化による液油の染み出しが抑制され、口どけが良いものである。また、クリーミング性が良く、ケーキ高さが向上するといった点で最大応力と粘度の両性能を満たすことが特に好ましい。 The plastic oil / fat composition according to the present invention has a viscosity at 5 ° C. of 2,000 to 40,000 mPa · s and 3,000 to 20,000 mPa · s when cooled from a molten state to 5 ° C. at 2 ° C. per minute. s is preferable. The plastic oil and fat composition having a viscosity at 5 ° C. of 2,000 to 40,000 mPa · s when cooled from the molten state to 5 ° C. at 2 ° C. per minute suppresses the exudation of liquid oil due to temperature changes and melts in the mouth. Is a good one. Further, it is particularly preferable to satisfy both the maximum stress and viscosity performances in terms of good creaming property and improvement in cake height.
溶融状態から5℃まで毎分2℃で冷却した際の5℃における粘度とは、70℃に加熱し均一に溶解させた可塑性油脂組成物を、70℃に調温した動的粘弾性装置(TAインスツルメント社製)の加熱、冷却ステージと、測定治具(40mm平板プレート)の間に約1mL注入し、周波数1Hz、歪0.001〜100%の条件でせん断を付与しながら2℃/minで5℃まで冷却し、5℃に到達するまでの粘度を測定した値である。 The viscosity at 5 ° C. when cooled from the molten state to 5 ° C. at 2 ° C. per minute is a dynamic viscoelastic device in which a plastic fat / oil composition heated to 70 ° C. and uniformly dissolved is adjusted to 70 ° C. Approximately 1 mL is injected between the heating / cooling stage of TA Instruments (manufactured by TA Instruments) and the measuring jig (40 mm flat plate), and at 2 ° C. while applying shear under the conditions of frequency 1 Hz and strain 0.001 to 100%. It is a value obtained by cooling to 5 ° C. at / min and measuring the viscosity until reaching 5 ° C.
本実施形態の可塑性油脂組成物は、ポリグリセリン脂肪酸エステルの含有量が少量であるので、食品の風味の悪化が抑えられる。本発明の可塑性油脂組成物を用いてなる食品としては、通常のマーガリン、ファットスプレッドを用いる食品であれば、特に限定はないが、具体的には、食パン、菓子パン、デニッシュ・ペストリー、パイ等のベーカリー製品、シュー、ドーナツ、パウンドケーキ、スポンジケーキ、クッキー、ワッフル、マフィン、ハードビスケット、スコーン等の菓子製品に使用することができる。また、これらの用途における本発明の可塑性油脂組成物の使用量は、使用用途により異なるものであり、特に限定されるものではない。 Since the plastic fat / oil composition of the present embodiment contains a small amount of polyglycerin fatty acid ester, deterioration of food flavor can be suppressed. The food product using the plastic oil / fat composition of the present invention is not particularly limited as long as it is a food product using ordinary margarine or fat spread, but specifically, bread, confectionery bread, Danish pastry, pie, etc. It can be used in bakery products, shoes, donuts, pound cakes, sponge cakes, cookies, waffles, muffins, hard biscuits, scones and other confectionery products. Further, the amount of the plastic oil / fat composition of the present invention used in these uses varies depending on the intended use and is not particularly limited.
以下に実施例に基づいて本発明を具体的に説明するが、本発明は、実施例に限定されるものではない。なお、以下の説明において特に記述がない限り、配合割合等は質量基準とする。 Hereinafter, the present invention will be specifically described based on examples, but the present invention is not limited to the examples. Unless otherwise specified in the following description, the blending ratio and the like are based on mass.
<可塑性油脂組成物Aの調製>
精製パーム油と大豆白絞油を重量比で83/17の割合で混合した油脂を83.2重量%と表1に示すポリグリセリン脂肪酸エステル(PGFE)1、4およびグリセリン脂肪酸エステル(MG)、ソルビタン脂肪酸エステル(SoE)0.8重量%を70℃で混合した。この混合物に、0.6%食塩水を16重量%添加し、手撹拌にて10回振とうさせたものを5℃で10分間固化させた後、20℃で1時間静置した。
<Preparation of plastic fat composition A>
83.2% by weight of fats and oils obtained by mixing refined palm oil and white squeezed soybean oil in a weight ratio of 83/17, polyglycerin fatty acid esters (PGFE) 1, 4 and glycerin fatty acid esters (MG), shown in Table 1. 0.8% by weight of sorbitan fatty acid ester (SoE) was mixed at 70 ° C. To this mixture, 16% by weight of 0.6% saline solution was added, and the mixture was shaken 10 times by hand stirring and solidified at 5 ° C. for 10 minutes, and then allowed to stand at 20 ° C. for 1 hour.
<可塑性油脂組成物Bの調製>
PGFEとして、表1に示すPGFE1、5を用いたこと以外は、可塑性油脂組成物Aと同様にして可塑性油脂組成物Bを調製した。
<Preparation of plastic fat composition B>
A plastic fat / oil composition B was prepared in the same manner as the plastic fat / oil composition A except that PGFEs 1 and 5 shown in Table 1 were used as the PGFE.
<可塑性油脂組成物Cの調製>
PGFEとして、表1に示すPGFE1、6を用いたこと以外は、可塑性油脂組成物Aと同様にして可塑性油脂組成物Cを調製した。
<Preparation of plastic fat composition C>
A plastic fat / oil composition C was prepared in the same manner as the plastic fat / oil composition A except that PGFEs 1 and 6 shown in Table 1 were used as the PGFE.
<可塑性油脂組成物Dの調製>
PGFEとして、表1に示すPGFE2、6を用いたこと以外は、可塑性油脂組成物Aと同様にして可塑性油脂組成物Dを調製した。
<Preparation of plastic fat composition D>
A plastic fat / oil composition D was prepared in the same manner as the plastic fat / oil composition A except that PGFEs 2 and 6 shown in Table 1 were used as the PGFE.
<可塑性油脂組成物Eの調製>
PGFEとして、表1に示すPGFE3、5を用いたこと以外は、可塑性油脂組成物Aと同様にして可塑性油脂組成物Eを調製した。
<Preparation of plastic fat composition E>
A plastic fat / oil composition E was prepared in the same manner as the plastic fat / oil composition A except that PGFEs 3 and 5 shown in Table 1 were used as the PGFE.
<可塑性油脂組成物Fの調製>
PGFEとして、表1に示すPGFE1、4を用いたこと以外は、可塑性油脂組成物Aと同様にして可塑性油脂組成物Fを調製した。
<Preparation of plastic fat composition F>
A plastic fat / oil composition F was prepared in the same manner as the plastic fat / oil composition A except that PGFEs 1 and 4 shown in Table 1 were used as the PGFE.
<可塑性油脂組成物Gの調製>
PGFEとして、表1に示すPGFE1、7を用いたこと以外は、可塑性油脂組成物Aと同様にして可塑性油脂組成物Gを調製した。
<Preparation of plastic fat composition G>
The plastic fat / oil composition G was prepared in the same manner as the plastic fat / oil composition A except that PGFEs 1 and 7 shown in Table 1 were used as the PGFE.
<可塑性油脂組成物Hの調製>
PGFEとして、表1に示すPGFE1を用いたこと以外は、可塑性油脂組成物Aと同様にして可塑性油脂組成物Hを調製した。
<Preparation of plastic fat composition H>
The plastic fat / oil composition H was prepared in the same manner as the plastic fat / oil composition A except that PGFE1 shown in Table 1 was used as the PGFE.
<可塑性油脂組成物Iの調製>
PGFEとして、表1に示すPGFE4を用いたこと以外は、可塑性油脂組成物Aと同様にして可塑性油脂組成物Iを調製した。
<Preparation of plastic fat composition I>
The plastic fat / oil composition I was prepared in the same manner as the plastic fat / oil composition A except that PGFE4 shown in Table 1 was used as the PGFE.
<可塑性油脂組成物Jの調製>
PGFEとして、表1に示すPGFE8を用いたこと以外は、可塑性油脂組成物Aと同様にして可塑性油脂組成物Jを調製した。
<Preparation of plastic fat composition J>
A plastic fat / oil composition J was prepared in the same manner as the plastic fat / oil composition A except that PGFE8 shown in Table 1 was used as the PGFE.
<硬さの測定方法>
レオメーターおよび圧縮弾性用アダプター(φ10mm平丸)を用い、可塑性油脂組成物A〜Jを10gスクリュー管に分注し20℃にて1時間静置した後の硬さを測定した。テーブルスピードを6cm/minとして、アダプターが試料を10mm圧縮した時の最大応力を硬さとした。
<Hardness measurement method>
Using a rheometer and an adapter for compression elasticity (φ10 mm flat circle), the plastic oil and fat compositions A to J were dispensed into a 10 g screw tube and allowed to stand at 20 ° C. for 1 hour, and then the hardness was measured. The table speed was set to 6 cm / min, and the maximum stress when the adapter compressed the sample by 10 mm was defined as the hardness.
<粘度の測定方法>
70℃に加熱し均一に溶解させた可塑性油脂組成物A〜Jを、70℃に調温した動的粘弾性装置(TAインスツルメント社製)の加熱、冷却ステージと、測定治具の間に約1mL注入し、周波数1Hz、歪0.001〜100%の条件でせん断を付与しながら2℃/minで5℃まで冷却し、5℃に到達するまでの粘度を測定した。治具には40mm平板プレートを使用した。
<Viscosity measurement method>
Between the heating and cooling stages of the dynamic viscoelastic device (manufactured by TA Instruments) whose temperature was adjusted to 70 ° C, and the measuring jig, the plastic fat and oil compositions A to J heated to 70 ° C and uniformly dissolved. About 1 mL was injected into the mixture, and the mixture was cooled to 5 ° C. at 2 ° C./min while applying shear under the conditions of a frequency of 1 Hz and a strain of 0.001 to 100%, and the viscosity until reaching 5 ° C. was measured. A 40 mm flat plate was used as the jig.
表1に示す乳化剤の詳細は以下の通りである。 The details of the emulsifiers shown in Table 1 are as follows.
PGFE1:デカグリセリンステアリン酸エステル(エステル化率:78%、HLB:3.8)
PGFE2:ペンタグリセリンステアリン酸エステル(エステル化率:64%、HLB:4.5)
PGFE3:デカグリセリンベヘン酸エステル(エステル化率:96%、HLB:2.5)
PGFE4:テトラグリセリンオレイン酸エステル(エステル化率:23%、HLB:8.8)
PGFE5:ペンタグリセリンオレイン酸エステル(エステル化率:16%、HLB:11.6)
PGFE6:デカグリセリンオレイン酸エステル(エステル化率:12%、HLB:12.9)
PGFE7:デカグリセリンオレイン酸エステル(エステル化率:84%、HLB:3.3)
PGFE8:デカグリセリンカプリル酸エステル(エステル化率:12%、HLB:16.1)
MG:グリセリンステアリン酸モノエステル(商品名:ポエムS−100、理研ビタミン株式会社製)
SoE:ソルビタンステアリン酸エステル(商品名:ポエムS−60V、理研ビタミン株式会社製)
PGFE1: Decaglycerin stearic acid ester (esterification rate: 78%, HLB: 3.8)
PGFE2: Pentaglycerin stearic acid ester (esterification rate: 64%, HLB: 4.5)
PGFE3: Decaglycerin behenic acid ester (esterification rate: 96%, HLB: 2.5)
PGFE4: Tetraglycerin oleate (esterification rate: 23%, HLB: 8.8)
PGFE5: Pentaglycerin oleate (esterification rate: 16%, HLB: 11.6)
PGFE6: Decaglycerin oleate (esterification rate: 12%, HLB: 12.9)
PGFE7: Decaglycerin oleate (esterification rate: 84%, HLB: 3.3)
PGFE8: Decaglycerin caprylic acid ester (esterification rate: 12%, HLB: 16.1)
MG: Glycerin stearic acid monoester (trade name: Poem S-100, manufactured by RIKEN Vitamin Co., Ltd.)
SoE: Sorbitan stearic acid ester (trade name: Poem S-60V, manufactured by RIKEN Vitamin Co., Ltd.)
上記により得られた可塑性油脂組成物について、硬さと粘度を測定した結果を表1に示した。 Table 1 shows the results of measuring the hardness and viscosity of the plastic fat and oil composition obtained as described above.
<実施例1>
可塑性油脂組成物Aと同様の重量比で調製した可塑性油脂組成物3,000gを70℃で溶解し、T.K.ホモミキサー(プライミクス社製)を用いて温度を70℃に保持しつつ、回転数8,000rpmで10分間乳化した。その後、マーガリンプロセッサー(パワーポイントインターナショナル社製)により急冷、混錬した。これを、20℃で1日保存することによりマーガリンを得た。
<Example 1>
3,000 g of the plastic fat composition prepared at the same weight ratio as that of the plastic fat composition A was dissolved at 70 ° C., and T.I. K. Emulsification was carried out at a rotation speed of 8,000 rpm for 10 minutes while maintaining the temperature at 70 ° C. using a homomixer (manufactured by Primix Corporation). After that, it was rapidly cooled and kneaded with a margarine processor (manufactured by Powerpoint International). This was stored at 20 ° C. for 1 day to obtain margarine.
<実施例2>
可塑性油脂組成物として、可塑性油脂組成物Bと同様の重量比で調製したこと以外は、実施例1と同様にしてマーガリンを調製した。
<Example 2>
As the plastic fat and oil composition, margarine was prepared in the same manner as in Example 1 except that it was prepared in the same weight ratio as that of the plastic fat and oil composition B.
<実施例3>
可塑性油脂組成物として、可塑性油脂組成物Cと同様の重量比で調製したこと以外は、実施例1と同様にしてマーガリンを調製した。
<Example 3>
As the plastic fat and oil composition, margarine was prepared in the same manner as in Example 1 except that it was prepared in the same weight ratio as that of the plastic fat and oil composition C.
<実施例4>
可塑性油脂組成物として、可塑性油脂組成物Dと同様の重量比で調製したこと以外は、実施例1と同様にしてマーガリンを調製した。
<Example 4>
As the plastic fat and oil composition, margarine was prepared in the same manner as in Example 1 except that it was prepared in the same weight ratio as that of the plastic fat and oil composition D.
<実施例5>
可塑性油脂組成物として、可塑性油脂組成物Eと同様の重量比で調製したこと以外は、実施例1と同様にしてマーガリンを調製した。
<Example 5>
As the plastic fat and oil composition, margarine was prepared in the same manner as in Example 1 except that it was prepared in the same weight ratio as that of the plastic fat and oil composition E.
<実施例6>
可塑性油脂組成物として、可塑性油脂組成物Fと同様の重量比で調製したこと以外は、実施例1と同様にしてマーガリンを調製した。
<Example 6>
As the plastic fat and oil composition, margarine was prepared in the same manner as in Example 1 except that it was prepared in the same weight ratio as that of the plastic fat and oil composition F.
<比較例1>
可塑性油脂組成物として、可塑性油脂組成物Gと同様の重量比で調製したこと以外は、実施例1と同様にしてマーガリンを調製した。
<Comparative example 1>
As the plastic fat and oil composition, margarine was prepared in the same manner as in Example 1 except that it was prepared in the same weight ratio as that of the plastic fat and oil composition G.
<比較例2>
可塑性油脂組成物として、可塑性油脂組成物Hと同様の重量比で調製したこと以外は、実施例1と同様にしてマーガリンを調製した。
<Comparative example 2>
As the plastic fat and oil composition, margarine was prepared in the same manner as in Example 1 except that it was prepared in the same weight ratio as that of the plastic fat and oil composition H.
<比較例3>
可塑性油脂組成物として、可塑性油脂組成物Iと同様の重量比で調製したこと以外は、実施例1と同様にしてマーガリンを調製した。
<Comparative example 3>
As the plastic fat and oil composition, margarine was prepared in the same manner as in Example 1 except that it was prepared in the same weight ratio as that of the plastic fat and oil composition I.
<比較例4>
可塑性油脂組成物として、可塑性油脂組成物Jと同様の重量比で調製したこと以外は、実施例1と同様にしてマーガリンを調製した。
<Comparative example 4>
As the plastic fat and oil composition, margarine was prepared in the same manner as in Example 1 except that it was prepared in the same weight ratio as that of the plastic fat and oil composition J.
<クリーミング性試験>
実施例1〜6及び比較例1〜4のそれぞれのマーガリン200gと、上白糖200gを卓上スタンドミキサー(商品名:KSM5: キッチンエイド社製)のボウルに秤量し、低速(70rpm)で30秒間混合した。その後、中速(130rpm)で比重が0.85になるまでミキシングをおこない、バタークリームを調製した。アタッチメントには平面ビーターを使用した。バタークリームの比重は容積100mlのカップを用いて以下の式(5)により算出した。ミキシング時間が短いほど作業性が良好であるとした。
比重=バタークリームをすり切り充填したカップの重量(g)−カップの空重量(g)/カップの容積(ml) ・・・(5)
[クリーミング性の評価基準]
◎:ミキシング時間が0.75分未満。
〇:ミキシング時間が0.75分以上、1分未満。
△:ミキシング時間が1分以上、1.5分未満。
×:ミキシング時間が1.5分以上。
※ミキシング時間は中速でミキシングした時間を計測した。
<Creaming property test>
200 g of each of Examples 1 to 6 and Comparative Examples 1 to 4 and 200 g of white sugar are weighed in a bowl of a tabletop stand mixer (trade name: KSM5: manufactured by KitchenAid) and mixed at a low speed (70 rpm) for 30 seconds. did. Then, mixing was performed at medium speed (130 rpm) until the specific gravity became 0.85 to prepare butter cream. A flat beater was used for the attachment. The specific gravity of butter cream was calculated by the following formula (5) using a cup having a volume of 100 ml. The shorter the mixing time, the better the workability.
Specific gravity = weight of cup filled with butter cream (g) -empty weight of cup (g) / volume of cup (ml) ... (5)
[Evaluation criteria for creaming]
⊚: Mixing time is less than 0.75 minutes.
〇: Mixing time is 0.75 minutes or more and less than 1 minute.
Δ: Mixing time is 1 minute or more and less than 1.5 minutes.
X: Mixing time is 1.5 minutes or more.
* The mixing time was measured at medium speed.
<パウンドケーキの調製>
バタークリームを調製後、全卵を50gずつ計200gをバタークリームに加え、それぞれ中速(130rpm)で30秒間撹拌した。次いで予め篩っておいた薄力粉200gとベーキングパウダー4gを3回に分けて生地に加え、それぞれ低速(70rpm)で30秒間ずつ撹拌しケーキ生地を調製した。オーブン(商品名:ミックベーカーWGT−11T:ワールド精機製)の上火を170℃、下火を160℃に設定し、庫内を180℃にした後、ステンレス製パウンド型(幅85mm×長さ180mm×高さ60mm)に生地を300g流しこんだ。型の中心部がへこむように充填し、オーブンで45分間焼成した。その後、室温にて2時間静置冷却しパウンドケーキを得た。
<Preparation of pound cake>
After preparing the butter cream, 50 g of whole eggs, a total of 200 g, were added to the butter cream, and each was stirred at medium speed (130 rpm) for 30 seconds. Next, 200 g of the soft flour and 4 g of the baking powder that had been sieved in advance were added to the dough in three portions, and each was stirred at a low speed (70 rpm) for 30 seconds to prepare a cake dough. Set the top heat of the oven (trade name: Mick Baker WGT-11T: manufactured by World Seiki) to 170 ° C and the bottom heat to 160 ° C, set the inside of the oven to 180 ° C, and then make a stainless steel pound type (width 85 mm x length). 300 g of the dough was poured into (180 mm × 60 mm in height). The mold was filled with a dent in the center and baked in an oven for 45 minutes. Then, it was allowed to cool at room temperature for 2 hours to obtain a pound cake.
<気泡安定性試験>
パウンドケーキの高さをノギスにて測定した。底面からケーキ頂点までの最大値をケーキ高さとして評価した。ケーキ高さが高いほど気泡安定性が良好であるとした。
[気泡安定性の評価基準]
◎:7.0cm以上。
〇:6.6cm以上、7.0cm未満。
×:6.6cm未満。
<Bubble stability test>
The height of the pound cake was measured with a caliper. The maximum value from the bottom to the top of the cake was evaluated as the cake height. The higher the cake height, the better the bubble stability.
[Evaluation criteria for bubble stability]
⊚: 7.0 cm or more.
〇: 6.6 cm or more and less than 7.0 cm.
X: Less than 6.6 cm.
<経時安定性試験>
20℃で3か月間保管したマーガリンを用いて上記の評価と同様に試験した。
[経時安定性の評価基準]
〇:1日目に比べてクリーミング性、ケーキ高さともに変化なし。
△:1日目に比べてクリーミング性、ケーキ高さのいずれかが低下。
×:1日目に比べてクリーミング性、ケーキ高さともに低下。
<Stability test over time>
The test was carried out in the same manner as in the above evaluation using margarine stored at 20 ° C. for 3 months.
[Evaluation criteria for stability over time]
〇: No change in creaming property and cake height compared to the first day.
Δ: Either creaming property or cake height is reduced compared to the first day.
×: Both creaming property and cake height are reduced compared to the first day.
上記により得られたマーガリンについて、クリーミング性と気泡安定性、経時安定性を評価した結果を表2に示した。 Table 2 shows the results of evaluating the creaming property, bubble stability, and aging stability of the margarine obtained as described above.
本発明の可塑性油脂組成物を用いた実施例1〜6のマーガリンは、最大応力もしくは粘度の条件を満たさない可塑性油脂組成物を用いた比較例1〜4に比べて、クリーミング性に優れ、ケーキを焼成した際のケーキ高さが高く、経時安定性も良好であった。 The margarines of Examples 1 to 6 using the plastic fat and oil composition of the present invention are superior in creaming property and cake as compared with Comparative Examples 1 to 4 using the plastic fat and oil composition which does not satisfy the condition of maximum stress or viscosity. The cake height was high when the cake was baked, and the stability over time was also good.
Claims (3)
(A)精製パーム油60〜90重量%、20℃で液状である油10〜40重量%を含有する油脂
(B)乳化剤
(C)水 It is a plastic fat / oil composition composed of the following component (A), component (B), and component (C), and as component (B), 0.01 to 5 weight of polyglycerin fatty acid ester is added to the total amount of the plastic fat / oil composition. %, The maximum stress at 20 ° C. is 600 to 1,200 g, and the viscosity at 5 ° C. when cooled from the molten state to 5 ° C. at 2 ° C. per minute is 2,000 to 40,000 mPa · s. A plastic oil / fat composition characterized by the above.
(A) Oil containing 60 to 90% by weight of refined palm oil and 10 to 40% by weight of oil liquid at 20 ° C. (B) Emulsifier (C) Water
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