JP2021036828A - Fat composition for instant precooked food and instant precooked food including the same - Google Patents
Fat composition for instant precooked food and instant precooked food including the same Download PDFInfo
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- JP2021036828A JP2021036828A JP2019160608A JP2019160608A JP2021036828A JP 2021036828 A JP2021036828 A JP 2021036828A JP 2019160608 A JP2019160608 A JP 2019160608A JP 2019160608 A JP2019160608 A JP 2019160608A JP 2021036828 A JP2021036828 A JP 2021036828A
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- oil
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- fat
- instant cooked
- oils
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Abstract
Description
本発明は、即席調理食品用油脂組成物およびこれを含む即席調理食品に関する。 The present invention relates to an oil / fat composition for instant cooked foods and an instant cooked food containing the same.
従来、簡便さと美味しさから、即席調理食品として、カレールウ、ハヤシルウ、ホワイトルウ等の固形ルウが家庭、食堂、給食等に広く使用されている。このような固形ルウは、小麦粉、食用油脂、調味料等を配合して混合加熱した後、包材となる成形容器の型に流し込み、冷却固化させることによって製造されている。また、この固形ルウは、一般に常温で流通・販売され、調理時には熱水に溶解しカレーやシチュー等として喫食に供されている。 Conventionally, solid roux such as curry roux, haya shiru, and white roux has been widely used as instant cooked foods in homes, dining rooms, school lunches, and the like because of its simplicity and deliciousness. Such solid roux is produced by blending wheat flour, edible oils and fats, seasonings and the like, mixing and heating, pouring into a mold of a molding container to be a packaging material, and cooling and solidifying. In addition, this solid roux is generally distributed and sold at room temperature, is dissolved in hot water during cooking, and is used for eating as curry or stew.
固形ルウなどの即席調理食品は、流通時に高温に晒されると、油脂成分のうち融点の低い部分が融解して表面に浮出して再結晶化し、粗大結晶を形成して表面が白色化したり、表面のザラツキや触感の悪さが発生することで、製品価値を低下させてしまう場合がある。 When instant cooked foods such as solid roux are exposed to high temperatures during distribution, the part of the fat and oil component with a low melting point melts and emerges on the surface and recrystallizes, forming coarse crystals and whitening the surface. , The surface may be rough or the texture may be poor, which may reduce the product value.
このような即席調理食品の表面の白色化などを抑制するための技術として、例えば、特許文献1、2が知られている。 For example, Patent Documents 1 and 2 are known as techniques for suppressing whitening of the surface of such instantly cooked foods.
しかしながら、近年、原料供給事情などにより、牛脂やラードなどの動物系油脂の一部を植物系油脂に置き換える試みがなされており、植物系油脂の割合が増えると、さらに即席調理食品の白色化が起こりやすくなる。このような状況にあって、特許文献1、2の即席調理食品用油脂組成物の場合、即席調理食品の白色化を抑制することが難しい場合がある。 However, in recent years, due to the supply of raw materials, attempts have been made to replace some animal-based fats and oils such as beef tallow and lard with plant-based fats and oils. It is easy to happen. Under such circumstances, in the case of the oil and fat compositions for instant cooked foods of Patent Documents 1 and 2, it may be difficult to suppress the whitening of the instant cooked foods.
さらに、固形ルウなどの即席調理食品には、ロウ臭と呼ばれる、食べた時の口溶けの悪さによる蝋のような風味が生じる場合があり、ロウ臭を抑制することも検討すべき点であると考えられている。特許文献1、2の即席調理食品用油脂組成物の場合、食べた時の口溶けが必ずしも良好でなく、ロウ臭を十分に抑制することは難しいという問題もある。 Furthermore, instant cooked foods such as solid roux may have a waxy flavor called waxy odor due to poor melting in the mouth when eaten, and it should be considered to suppress the waxy odor. It is considered. In the case of the oil and fat compositions for instant cooked foods of Patent Documents 1 and 2, there is also a problem that the melting in the mouth when eaten is not always good and it is difficult to sufficiently suppress the waxy odor.
本発明は、以上の事情に鑑みてなされたものであり、即席調理食品の表面の白色化および喫食時のロウ臭を確実に抑制することができる即席調理食品用油脂組成物、および、これを含む即席調理食品を提供することを課題としている。 The present invention has been made in view of the above circumstances, and is an oil / fat composition for instant cooked foods capable of reliably suppressing whitening of the surface of instant cooked foods and waxy odor during eating, and an oil / fat composition for instant cooked foods. The challenge is to provide instant cooked foods, including.
上記の課題を解決するために、本発明の即席調理食品用油脂組成物は、トリグリセリドを構成する脂肪酸のうち、最大鎖長差が4以上であるトリグリセリドを40%以上含有することを特徴としている。 In order to solve the above problems, the fat and oil composition for instant cooked foods of the present invention is characterized by containing 40% or more of triglycerides having a maximum chain length difference of 4 or more among the fatty acids constituting the triglycerides. ..
本発明の即席調理食品は、前記の即席調理食品用油脂組成物を含有することを特徴としている。 The instant cooked food of the present invention is characterized by containing the above-mentioned fat and oil composition for instant cooked food.
本発明の即席調理食品用油脂組成物は、即席調理食品の表面の白色化および喫食時のロウ臭を確実に抑制することができる。 The oil and fat composition for instant cooked foods of the present invention can surely suppress the whitening of the surface of instant cooked foods and the waxy odor at the time of eating.
以下、本発明の即席調理食品用油脂組成物の一実施形態について説明する。 Hereinafter, an embodiment of the oil / fat composition for instant cooked foods of the present invention will be described.
本発明の即席調理食品用油脂組成物は、例えば、原料となる1種又は2種以上の油脂を加温下で溶解し、必要に応じて食品添加物等のその他の成分とを添加し、公知の方法で均一に分散し溶解することによって製造することができる。 In the fat and oil composition for instant cooked foods of the present invention, for example, one or more kinds of fats and oils as raw materials are dissolved under heating, and if necessary, other components such as food additives are added. It can be produced by uniformly dispersing and dissolving by a known method.
本発明の即席調理食品用油脂組成物は、油脂中のトリグリセリドを構成する脂肪酸のうち、最大鎖長差が4以上であるトリグリセリドを40%以上含有する。 The fat and oil composition for instant cooked foods of the present invention contains 40% or more of triglycerides having a maximum chain length difference of 4 or more among the fatty acids constituting the triglycerides in the fats and oils.
油脂中のトリグリセリドとは、1分子のグリセロールに3分子の脂肪酸がエステル結合した構造を有するものである。トリグリセリドの1位、2位、3位とは、脂肪酸が結合した位置を表す。トリグリセリドを構成する脂肪酸は、飽和脂肪酸または不飽和脂肪酸である。 The triglyceride in fats and oils has a structure in which three molecules of fatty acids are ester-bonded to one molecule of glycerol. The 1st, 2nd, and 3rd positions of triglyceride represent the positions to which fatty acids are bound. The fatty acids that make up triglycerides are saturated fatty acids or unsaturated fatty acids.
各トリグリセリド分子に結合している2つまたは3つの飽和脂肪酸は、同一の飽和脂肪酸であってもよいし、異なる飽和脂肪酸であってもよい。 The two or three saturated fatty acids attached to each triglyceride molecule may be the same saturated fatty acid or different saturated fatty acids.
飽和脂肪酸としては、酪酸(4)、カプロン酸(6)、カプリル酸(8)、カプリン酸(10)、ラウリン酸(12)、ミリスチン酸(14)、パルミチン酸(16)、ステアリン酸(18)、アラキジン酸(20)、ベヘン酸(22)、リグノセリン酸(24)等が挙げられる。なお、上記の数値表記は、脂肪酸の炭素数である。 Examples of saturated fatty acids include butyric acid (4), caproic acid (6), caprylic acid (8), capric acid (10), lauric acid (12), myristic acid (14), palmitic acid (16), and stearic acid (18). ), Arachidic acid (20), behenic acid (22), lignoseric acid (24) and the like. The above numerical notation is the number of carbon atoms of the fatty acid.
各トリグリセリド分子に結合している2つまたは3つの不飽和脂肪酸は、同一の不飽和脂肪酸であってもよいし、異なる不飽和脂肪酸であってもよい。不飽和脂肪酸としては、ミリストレイン酸(14:1)、パルミトレイン酸(16:1)、オレイン酸(18:1)、リノール酸(18:2)、リノレン酸(18:3)およびエルシン酸(22:1)等が挙げられる。なお、上記の数値表記は、脂肪酸の炭素数と二重結合数の組み合わせである。 The two or three unsaturated fatty acids attached to each triglyceride molecule may be the same unsaturated fatty acid or different unsaturated fatty acids. Unsaturated fatty acids include myristoleic acid (14: 1), palmitoleic acid (16: 1), oleic acid (18: 1), linoleic acid (18: 2), linolenic acid (18: 3) and erucic acid ( 22: 1) and the like. The above numerical notation is a combination of the number of carbon atoms of the fatty acid and the number of double bonds.
油脂は、1分子のグリセロールに2分子の飽和脂肪酸Sと1分子の不飽和脂肪酸Uが結合した2飽和トリグリセリドとして、1位および3位に飽和脂肪酸Sが結合し、かつ2位に不飽和脂肪酸Uが結合した対称型トリグリセリド(SUS)と、1位および2位に飽和脂肪酸Sが結合し、かつ3位に不飽和脂肪酸Uが結合した非対称型トリグリセリド(SSU)とを含むことができる。また、油脂は、1位、2位、および3位の全てに飽和脂肪酸Sが結合した3飽和トリグリセリドを含むことができる。さらに、油脂は、その他に1分子のグリセロールに2分子の不飽和脂肪酸Uと1分子の飽和脂肪酸Sが結合した2不飽和トリグリセリド、1位、2位、および3位の全てに不飽和脂肪酸Uが結合した3不飽和トリグリセリドを含むことができる。 Fats and oils are di-saturated triglycerides in which two molecules of saturated fatty acid S and one molecule of unsaturated fatty acid U are bound to one molecule of glycerol, and saturated fatty acid S is bound to the 1st and 3rd positions, and unsaturated fatty acid is 2nd. It can contain a symmetric triglyceride (SUS) to which U is bound and an asymmetric triglyceride (SSU) to which saturated fatty acid S is bound at the 1st and 2nd positions and unsaturated fatty acid U is bound at the 3rd position. Further, the fat and oil can contain a trisaturated triglyceride in which the saturated fatty acid S is bound to all of the 1, 2, and 3 positions. Further, the fat and oil is a diunsaturated triglyceride in which two molecules of unsaturated fatty acid U and one molecule of saturated fatty acid S are bound to one molecule of glycerol, and all of the 1, 2, and 3 positions are unsaturated fatty acids U. Can include triunsaturated triglycerides bound to.
そして、本発明において、「トリグリセリドを構成する脂肪酸の最大鎖長差」とは、1分子のグリセロールに結合している3分子の脂肪酸の内、最も炭素数が小さい脂肪酸と最も炭素数が大きい脂肪酸との炭素数の差を言う。この最大鎖長差が4以上であるトリグリセリドを40%以上含有する即席調理食品用油脂組成物を含むことで、即席調理食品に含まれる動物油脂の一部を即席調理食品用油脂組成物に置き換えても、即席調理食品の表面の白色化および喫食時のロウ臭を確実に抑制することができる。最大鎖長差が4以上であるトリグリセリドの割合の上限値としては、70%以下であることが好ましく、60%以下であることがより好ましく、50%以下であることがさらに好ましい。最大鎖長差が4以上であるトリグリセリドを40%以上含有する即席調理食品用油脂組成物は、例えばラウリン系油脂、パーム起源油脂、エルシン酸系油脂の内2種以上をエステル交換反応することで得ることができる。 In the present invention, the "maximum chain length difference of fatty acids constituting triglyceride" is defined as the fatty acid having the smallest carbon number and the fatty acid having the largest carbon number among the three molecules of fatty acid bound to one molecule of glycerol. The difference in carbon number with. By including the fat / oil composition for instant cooked foods containing 40% or more of triglyceride having a maximum chain length difference of 4 or more, a part of the animal fats / oils contained in the instant cooked foods is replaced with the fats / oils composition for instant cooked foods. However, the whitening of the surface of the instantly cooked food and the waxy odor at the time of eating can be surely suppressed. The upper limit of the proportion of triglyceride having a maximum chain length difference of 4 or more is preferably 70% or less, more preferably 60% or less, and further preferably 50% or less. An instant cooked food fat composition containing 40% or more of triglyceride having a maximum chain length difference of 4 or more is obtained by transesterifying two or more of lauric-based fats and oils, palm-derived fats and oils, and erucic acid-based fats and oils, for example. Obtainable.
本発明の即席調理食品用油脂組成物は、即席調理食品の製造時の固化性を向上させること等を考慮すると、35℃における30分後の等温結晶化SFCの下限値が1%以上であることが好ましく、4%以上であることがより好ましい。等温結晶化SFCは、油脂を加熱し完全に溶解した後、所定の温度および時間で保持した時のSFCを表している。
即席調理食品のロウ臭をさらに抑制する観点から、35℃における30分後の等温結晶化SFCの上限値が50%以下であることが好ましく、30%以下であることがより好ましく、9%以下であることがさらに好ましく、5.5%以下であることが特に好ましい。最大鎖長差が4以上であるトリグリセリドを40%以上含有し、さらに35℃における30分後の等温結晶化SFCが所定の範囲内であると、即席調理食品に含まれる動物油脂の一部を即席調理食品用油脂組成物に置き換えても、即席調理食品の表面の白色化を抑制しつつも、ロウ臭が少なく口溶けが良好な即席調理食品用油脂組成物を得ることができる。
The oil and fat composition for instant cooked foods of the present invention has a lower limit of 1% or more of isothermal crystallization SFC after 30 minutes at 35 ° C. in consideration of improving the solidification property during the production of instant cooked foods. It is preferably 4% or more, and more preferably 4% or more. The isothermal crystallized SFC represents an SFC when the fat and oil are heated and completely melted and then held at a predetermined temperature and time.
From the viewpoint of further suppressing the waxy odor of instant cooked foods, the upper limit of the isothermal crystallized SFC after 30 minutes at 35 ° C. is preferably 50% or less, more preferably 30% or less, and 9% or less. Is more preferable, and 5.5% or less is particularly preferable. When 40% or more of triglyceride having a maximum chain length difference of 4 or more is contained and the isothermal crystallized SFC after 30 minutes at 35 ° C. is within a predetermined range, a part of animal fats and oils contained in instant cooked foods is removed. Even if it is replaced with the oil / fat composition for instant cooked food, it is possible to obtain the oil / fat composition for instant cooked food which has less waxy odor and good melting in the mouth while suppressing whitening of the surface of the instant cooked food.
本発明の即席調理食品用油脂組成物に含まれるトリグリセリドは、構成脂肪酸中にベヘン酸を0.03〜1.5%含有することが好ましい。これによって、トリグリセリド間でメチル基末端の積層にひずみが生じ、加熱溶解した即席調理食品の口中での固化速度を遅延させることで、即席調理食品喫食時のロウ臭をより確実に抑制することができる。 The triglyceride contained in the fat composition for instant cooked foods of the present invention preferably contains 0.03 to 1.5% of behenic acid in the constituent fatty acids. As a result, the lamination of the methyl group terminals is distorted between the triglycerides, and the solidification rate in the mouth of the heat-dissolved instant cooked food is delayed, so that the waxy odor at the time of eating the instant cooked food can be more reliably suppressed. it can.
油脂は、全トリグリセリドに対する軟質トリグリセリドの割合の上限値が50%以下であることが好ましく、45%以下であることがより好ましく、40%以下であることがさらに好ましい。ここで、「軟質トリグリセリド」とは、1)3つの不飽和脂肪酸を有するトリグリセリド、2)2つの不飽和脂肪酸と1つの飽和脂肪酸を有するトリグリセリド、3)1つの不飽和脂肪酸と、炭素数17以下の2つの飽和脂肪酸を有するトリグリセリドを言う。軟質トリグリセリドの割合がこの範囲であると、即席調理食品に含まれる低融点部分が少なくなり、即席調理食品に含まれる動物油脂の一部を即席調理食品用油脂組成物に置き換えても、即席調理食品の表面における白色化の発生を抑制することができる。 For fats and oils, the upper limit of the ratio of soft triglyceride to total triglyceride is preferably 50% or less, more preferably 45% or less, and further preferably 40% or less. Here, the "soft triglyceride" refers to 1) a triglyceride having three unsaturated fatty acids, 2) a triglyceride having two unsaturated fatty acids and one saturated fatty acid, and 3) one unsaturated fatty acid and 17 or less carbon atoms. Refers to a triglyceride having two saturated fatty acids. When the ratio of soft triglyceride is in this range, the low melting point portion contained in the instant cooked food is reduced, and even if a part of the animal fat and oil contained in the instant cooked food is replaced with the fat composition for instant cooked food, instant cooking is performed. It is possible to suppress the occurrence of whitening on the surface of food.
油脂は、トリグリセリドを構成する脂肪酸に含まれる炭素数12の脂肪酸(C12)の割合の上限値が30%以下であることが好ましく、25%以下であることがより好ましく、20%以下であることがさらに好ましく、15%以下であることが特に好ましい。炭素数12の脂肪酸がこの範囲内であると、分子運動を起こしやすい炭素数12以下の脂肪酸量を抑えることができ、即席調理食品に含まれる動物油脂の一部を即席調理食品用油脂組成物に置き換えても、即席調理食品の表面における白色化の発生を抑制することができる。 For fats and oils, the upper limit of the ratio of the fatty acid (C12) having 12 carbon atoms contained in the fatty acids constituting the triglyceride is preferably 30% or less, more preferably 25% or less, and more preferably 20% or less. Is more preferable, and 15% or less is particularly preferable. When the fatty acid having 12 carbon atoms is within this range, the amount of fatty acid having 12 or less carbon atoms that easily causes molecular motion can be suppressed, and a part of the animal fat and oil contained in the instant cooked food can be used as an oil and fat composition for instant cooked food. Even if it is replaced with, the occurrence of whitening on the surface of the instant cooked food can be suppressed.
また、トリグリセリドを構成する脂肪酸に含まれる炭素数16の脂肪酸(C16)の割合の下限値が20%以上であることが好ましく、25%以上であることがより好ましく、30%以上であることがさらに好ましい。トリグリセリドを構成する脂肪酸に含まれる炭素数16の脂肪酸(C16)の割合の上限値としては、50%以下であることが好ましく、45%以下であることがより好ましく、40%以下であることがさらに好ましい。 Further, the lower limit of the ratio of the fatty acid (C16) having 16 carbon atoms contained in the fatty acids constituting the triglyceride is preferably 20% or more, more preferably 25% or more, and more preferably 30% or more. More preferred. The upper limit of the ratio of the fatty acid (C16) having 16 carbon atoms contained in the fatty acids constituting the triglyceride is preferably 50% or less, more preferably 45% or less, and preferably 40% or less. More preferred.
さらに、トリグリセリドを構成する脂肪酸に含まれる炭素数18の脂肪酸(C18)の割合の下限値が30%以上であることが好ましく、35%以上であることがより好ましく、40%以上であることがさらに好ましい。トリグリセリドを構成する脂肪酸に含まれる炭素数18の脂肪酸(C18)の割合の上限値としては、60%以下であることが好ましく、55%以下であることがより好ましく、50%以下であることがさらに好ましい。 Further, the lower limit of the ratio of the fatty acid (C18) having 18 carbon atoms contained in the fatty acids constituting the triglyceride is preferably 30% or more, more preferably 35% or more, and more preferably 40% or more. More preferred. The upper limit of the ratio of the fatty acid (C18) having 18 carbon atoms contained in the fatty acids constituting the triglyceride is preferably 60% or less, more preferably 55% or less, and more preferably 50% or less. More preferred.
トリグリセリドを構成する脂肪酸に含まれるC12脂肪酸、C16脂肪酸およびC18脂肪酸の割合がこの範囲であると、即席調理食品に含まれる動物油脂の一部を即席調理食品用油脂組成物に置き換えても、即席調理食品の表面の白色化および喫食時のロウ臭を抑制することができる。 When the ratio of C12 fatty acid, C16 fatty acid and C18 fatty acid contained in the fatty acids constituting the triglyceride is within this range, even if a part of the animal fat and oil contained in the instant cooked food is replaced with the fat and oil composition for instant cooked food, it is instant. Whitening of the surface of cooked foods and waxy odor during eating can be suppressed.
また、C12脂肪酸とC16脂肪酸の比率(C16量(%)/C12量(%))は、1.5〜4.0であることが好ましく、2.0〜3.5であることがより好ましく、2.5〜3.0であることがさらに好ましく、C12脂肪酸とC18脂肪酸の比率(C18量(%)/C12量(%))は、2.5〜5.0であることが好ましく、3.0〜4.5であることがより好ましく、3.5〜4.0であることがさらに好ましい。C12脂肪酸とC16脂肪酸の比率(C16量(%)/C12量(%))とC12脂肪酸とC18脂肪酸の比率(C18量(%)/C12量(%))の比率がこの範囲であると、即席調理食品に含まれる動物油脂の一部を即席調理食品用油脂組成物に置き換えても、即席調理食品の表面の白色化および喫食時のロウ臭をより確実に抑制することができる。 The ratio of C12 fatty acid to C16 fatty acid (C16 amount (%) / C12 amount (%)) is preferably 1.5 to 4.0, more preferably 2.0 to 3.5. , 2.5 to 3.0, and the ratio of C12 fatty acid to C18 fatty acid (C18 amount (%) / C12 amount (%)) is preferably 2.5 to 5.0. It is more preferably 3.0 to 4.5, and even more preferably 3.5 to 4.0. When the ratio of C12 fatty acid to C16 fatty acid (C16 amount (%) / C12 amount (%)) and the ratio of C12 fatty acid to C18 fatty acid (C18 amount (%) / C12 amount (%)) is in this range, Even if a part of the animal fats and oils contained in the instantly cooked food is replaced with the fat and oil composition for the instantly cooked food, the whitening of the surface of the instantly cooked food and the waxy odor at the time of eating can be more reliably suppressed.
本発明の即席調理食品用油脂組成物における油脂のヨウ素価の下限値は、即席調理食品喫食時のロウ臭をさらに抑制する観点から、10以上が好ましく、15以上がより好ましく、20以上がさらに好ましい。即席調理食品の表面の白色化をさらに抑制する観点から、ヨウ素価の上限値は45以下が好ましく、40以下がより好ましく、35以下がさらに好ましい。 The lower limit of the iodine value of fats and oils in the fats and oils composition for instant cooked foods of the present invention is preferably 10 or more, more preferably 15 or more, and further 20 or more from the viewpoint of further suppressing the waxy odor when eating instant cooked foods. preferable. From the viewpoint of further suppressing the whitening of the surface of the instant cooked food, the upper limit of the iodine value is preferably 45 or less, more preferably 40 or less, still more preferably 35 or less.
本発明の即席調理食品用油脂組成物に使用される油脂の種類としては、植物油脂、動物油脂、乳脂、これらの分別油、硬化油(部分水素添加油又は極度硬化油)、エステル交換油脂などを例示することができる。これらは、油脂中の、最大鎖長差が4以上であるトリグリセリドの割合や、軟質トリグリセリドの含有量などを適宜調整するために、1種または2種以上を選択することができる。最大鎖長差が4以上であるトリグリセリドを40%以上含有する即席調理食品用油脂組成物を得るためには、1種以上の油脂をエステル交換反応したものが好適に用いられる。 The types of fats and oils used in the fats and oils composition for instant cooked foods of the present invention include vegetable fats and oils, animal fats and oils, milk fats, fractionated oils thereof, hydrogenated oils (partially hydrogenated oils or extremely hardened oils), ester-exchanged fats and oils, and the like. Can be exemplified. One or two or more of these can be selected in order to appropriately adjust the proportion of triglyceride having a maximum chain length difference of 4 or more in fats and oils, the content of soft triglyceride, and the like. In order to obtain an instant cooked food fat / oil composition containing 40% or more of triglyceride having a maximum chain length difference of 4 or more, one or more kinds of fats and oils subjected to transesterification reaction are preferably used.
植物油脂としては、パーム油、ヤシ油、パーム核油、菜種油、大豆油、コーン油、米油、綿実油、ヒマワリ油、ゴマ油、オリーブ油、サフラワー油、落花生油等が挙げられる。 Examples of vegetable oils and fats include palm oil, palm oil, palm kernel oil, rapeseed oil, soybean oil, corn oil, rice oil, cottonseed oil, sunflower oil, sesame oil, olive oil, saflower oil, and peanut oil.
植物油脂は、パーム油起源の油脂から選ばれる少なくとも1種であることが好ましい。パーム油起源の油脂としては、パーム油、パーム分別油、これらの硬化油やエステル交換油脂等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。パーム分別油としては、硬質部(パームステアリン、パームハードステアリン等)、軟質部(パームオレイン、パームダブルオレイン等)、中融点部等を用いることができる。 The vegetable oil is preferably at least one selected from oils and fats derived from palm oil. Examples of oils and fats derived from palm oil include palm oil, palm fractionated oil, hydrogenated oils thereof, transesterified oils and fats, and the like, and these may be used alone or in combination of two or more. As the palm fractionating oil, a hard portion (palm stearin, palm hard stearin, etc.), a soft portion (palm olein, palm double olein, etc.), a mid-melting point portion, and the like can be used.
動物油脂としては、動物の脂肉から溶出法により採取した脂肪を精製したものを用いることができる。具体的には、牛脂、ラードおよびこれらの硬化油(部分水素添加油又は極度硬化油)等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。動物油脂は、即席調理食品に対して、即席調理食品用油脂組成物とは別に使用してもよく、即席調理食品用油脂組成物中に配合してもよい。 As the animal fat and oil, purified fat collected from animal fat and meat by an elution method can be used. Specific examples thereof include beef tallow, lard, and hydrogenated oils thereof (partially hydrogenated oil or extremely hydrogenated oil), and these may be used alone or in combination of two or more. The animal fats and oils may be used separately from the fats and oils composition for instant cooked foods for instant cooked foods, or may be blended in the fats and oils compositions for instant cooked foods.
そして、本発明の即席調理食品用油脂組成物には、全構成脂肪酸中のラウリン酸含有量が40〜55質量%であるラウリン系油脂(A1)と、全構成脂肪酸中の炭素数16以上の脂肪酸含有量が35質量%以上であるパーム油起源の油脂(A2)とのエステル交換油脂(A)を使用することが好ましい。このようなエステル交換油脂を用いると、即席調理食品に含まれる動物油脂の一部を即席調理食品用油脂組成物に置き換えても、即席調理食品の表面の白色化および喫食時のロウ臭をより確実に抑制することができる。 The oil / fat composition for instant cooked foods of the present invention contains lauric acid-based oil / fat (A1) having a lauric acid content of 40 to 55% by mass in all constituent fatty acids and 16 or more carbon atoms in all constituent fatty acids. It is preferable to use a transesterified fat (A) with a fat (A2) derived from palm oil having a fatty acid content of 35% by mass or more. When such transesterified fats and oils are used, even if a part of the animal fats and oils contained in the instant cooked food is replaced with the fat and oil composition for instant cooked food, the surface of the instant cooked food is whitened and the waxy odor at the time of eating is further improved. It can be surely suppressed.
そして、エステル交換油脂(A)は、ラウリン系油脂(A1)が好ましくは10〜60質量%、より好ましくは15〜50質量%、さらに好ましくは20〜40質量%と、パーム油起源の油脂(A2)が好ましくは40〜90質量%、より好ましくは50〜85質量%、さらに好ましくは60〜80質量%とをエステル交換反応して得られたものであることが好ましい。ラウリン系油脂(A1)の量が多過ぎると、分子運動を起こしやすい炭素数12以下の脂肪酸量が増えるため、白色化を生じやすくなってしまう。 The transesterified fat (A) is preferably a laurin-based fat (A1) in an amount of 10 to 60% by mass, more preferably 15 to 50% by mass, still more preferably 20 to 40% by mass, and is derived from palm oil. A2) is preferably obtained by transesterification with 40 to 90% by mass, more preferably 50 to 85% by mass, and even more preferably 60 to 80% by mass. If the amount of lauric oil (A1) is too large, the amount of fatty acids having 12 or less carbon atoms, which are likely to cause molecular motion, increases, so that whitening is likely to occur.
エステル交換油脂(A)の原料であるラウリン系油脂(A1)は、全構成脂肪酸中のラウリン酸含有量が40〜55質量%であることが好ましく、45〜50質量%であることがより好ましい。このようなラウリン系油脂(A1)としては、パーム核油、ヤシ油、これらの分別油、硬化油等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。これらのうち、ヤシ油に比べて融点が高く、高融点のエステル交換油脂(A)を容易に得ることができる点を考慮すると、パーム核油およびその分別油や硬化油が好ましい。硬化油の場合、水素添加量によってトランス酸の含有量が増加する虞があるため、硬化油を用いる場合には完全水素添加した極度硬化油が好ましい。 The lauric acid content of the lauric acid-based fat (A1), which is the raw material of the transesterified fat (A), is preferably 40 to 55% by mass, more preferably 45 to 50% by mass in the total constituent fatty acids. .. Examples of such lauric oils and fats (A1) include palm kernel oil, coconut oil, fractionated oils thereof, hydrogenated oils, and the like, and these may be used alone or in combination of two or more. Good. Of these, palm kernel oil and its fractionated oil or hydrogenated oil are preferable in consideration of the fact that the transesterified oil (A) having a higher melting point than coconut oil and having a high melting point can be easily obtained. In the case of hydrogenated oil, the content of trans acid may increase depending on the amount of hydrogenation. Therefore, when hydrogenated oil is used, extremely hydrogenated extremely hydrogenated oil is preferable.
ラウリン系油脂(A1)は、ヨウ素価の上限値が2以下であることが好ましい。ヨウ素価が2以下のラウリン系油脂(A1)を用いると、他の油脂に対して核となりやすく、核発生を誘発するため固化が遅れるのを抑制できる。ヨウ素価が2以下のラウリン系油脂(A1)としては、極度硬化油を用いることができる。 The upper limit of the iodine value of the lauric oil (A1) is preferably 2 or less. When a lauric-based fat or oil (A1) having an iodine value of 2 or less is used, it tends to become a nucleus with respect to other fats and oils and induces nucleation, so that delay in solidification can be suppressed. As the lauric oil (A1) having an iodine value of 2 or less, an extremely hydrogenated oil can be used.
エステル交換油脂(A)の原料であるパーム油起源の油脂(A2)としては、パーム油、パーム分別油、これらの硬化油、エステル交換油脂等が挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。パーム分別油としては、硬質部、軟質部、中融点部等を用いることができる。パーム油起源の油脂(A2)として硬化油を使用する場合、部分硬化油、低温硬化油、極度硬化油等を用いることができるが、中でも極度硬化油が好ましい。 Examples of the oil (A2) derived from palm oil, which is the raw material of the transesterified oil (A), include palm oil, palm fractionated oil, hydrogenated oils thereof, transesterified oil and fat, etc., and these are used alone. Often, two or more types may be used in combination. As the palm fractionating oil, a hard portion, a soft portion, a medium melting point portion and the like can be used. When a hydrogenated oil is used as the oil (A2) derived from palm oil, a partially hydrogenated oil, a low-temperature hydrogenated oil, an extremely hydrogenated oil, or the like can be used, but the extremely hydrogenated oil is particularly preferable.
パーム油起源の油脂(A2)は、ヨウ素価が30〜55であることが好ましく、30〜40であることがより好ましい。パーム油起源の油脂(A2)のヨウ素価がこの範囲内であると、即席調理食品に含まれる動物油脂の一部を即席調理食品用油脂組成物に置き換えても、即席調理食品喫食時のロウ臭をより確実に抑制することができる。 The fat (A2) derived from palm oil preferably has an iodine value of 30 to 55, more preferably 30 to 40. If the iodine value of the fat (A2) derived from palm oil is within this range, even if a part of the animal fat contained in the instant cooked food is replaced with the fat composition for instant cooked food, the wax at the time of eating the instant cooked food The odor can be suppressed more reliably.
パーム油起源の油脂(A2)は、極度硬化油を5〜45質量%の範囲内で含有することが好ましく、20〜45質量%の範囲内で含有することがより好ましい。極度硬化油をこの範囲内で含有すると、即席調理食品に含まれる動物油脂の一部を即席調理食品用油脂組成物に置き換えても、即席調理食品の表面の白色化をより確実に抑制することができる。 The fat (A2) derived from palm oil preferably contains extremely hydrogenated oil in the range of 5 to 45% by mass, and more preferably in the range of 20 to 45% by mass. When extremely hydrogenated oil is contained within this range, even if a part of the animal fat and oil contained in the instant cooked food is replaced with the fat and oil composition for instant cooked food, the whitening of the surface of the instant cooked food is more surely suppressed. Can be done.
ラウリン系油脂(A1)と、パーム油起源の油脂(A2)とのエステル交換反応には、エステル交換触媒として化学触媒や酵素触媒が用いられる。化学触媒としてはナトリウムメチラートや水酸化ナトリウム等が用いられ、酵素触媒としてはリパーゼ等が用いられる。リパーゼとしてはアスペルギルス属、アルカリゲネス属等のリパーゼが挙げられ、イオン交換樹脂、ケイ藻土、セラミック等の担体上に固定化したものを用いても、粉末の形態として用いても良い。また位置選択性のあるリパーゼ、位置選択性のないリパーゼのいずれも用いることができるが、位置選択性のないリパーゼを用いることが好ましい。 A chemical catalyst or an enzyme catalyst is used as the transesterification catalyst in the transesterification reaction between the lauric-based fat (A1) and the fat (A2) derived from palm oil. Sodium methylate, sodium hydroxide and the like are used as the chemical catalyst, and lipase and the like are used as the enzyme catalyst. Examples of the lipase include lipases of the genus Aspergillus and the genus Alcaligenes, which may be immobilized on a carrier such as an ion exchange resin, diatomaceous earth, or ceramic, or may be used in the form of a powder. Further, both a lipase having regioselectivity and a lipase having no regioselectivity can be used, but it is preferable to use a lipase having no regioselectivity.
ラウリン系油脂(A1)における全構成脂肪酸中のラウリン酸の割合、パーム油起源の油脂(A2)における全構成脂肪酸中の炭素数16以上の脂肪酸含有量、エステル交換反応の終了は、ガスクロマトグラフ法により確認することができる。
構成脂肪酸中にベヘン酸を含有する油脂としては、ハイエルシン酸菜種極度硬化油、魚油極度硬化油等が例示され、ハイエルシン酸菜種極度硬化油が特に好ましい。構成脂肪酸中にベヘン酸を含有する油脂は、そのまま用いても、他の1種以上の油脂とエステル交換反応して用いても良いが、結晶核となりやすく、即席調理食品の表面の白色化を抑制しやすい観点から、そのまま用いることがより好ましい。
The ratio of lauric acid in the total constituent fatty acids in the lauric oil (A1), the fatty acid content of 16 or more carbon atoms in the total constituent fatty acids in the oil derived from palm oil (A2), and the completion of the transesterification reaction are determined by gas chromatography. Can be confirmed by.
Examples of fats and oils containing behenic acid in the constituent fatty acids include high-ercic acid rapeseed extremely hardened oil, fish oil extremely hardened oil, and the like, and high-ercic acid rapeseed extremely hardened oil is particularly preferable. The fats and oils containing behenic acid in the constituent fatty acids may be used as they are or may be used by transesterification reaction with one or more other kinds of fats and oils, but they tend to form crystal nuclei and whiten the surface of instant cooked foods. From the viewpoint of easy suppression, it is more preferable to use it as it is.
本発明の即席調理食品用油脂組成物における油脂の含有量は、70〜99.9質量%であることが好ましく、90〜99.8質量%であることがより好ましく、96〜99.8質量%であることが特に好ましい。 The content of fats and oils in the fats and oils composition for instant cooked foods of the present invention is preferably 70 to 99.9% by mass, more preferably 90 to 99.8% by mass, and 96 to 99.8% by mass. % Is particularly preferable.
本発明の即席調理食品用油脂組成物は、その他の配合成分として、各種の食品添加物や食品素材を配合することができる。具体的には、例えば、食品添加物としては、乳化剤、酸化防止剤、着色料、フレーバー、食品素材としては、調味料、食塩、香味油等が挙げられる。例えば、グリセリン脂肪酸エステル、有機酸グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタン脂肪酸エステル等が挙げられる。 The oil and fat composition for instant cooked foods of the present invention can contain various food additives and food materials as other compounding ingredients. Specifically, for example, food additives include emulsifiers, antioxidants, colorants, flavors, and food materials include seasonings, salts, flavor oils, and the like. For example, glycerin fatty acid ester, organic acid glycerin fatty acid ester, sucrose fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, stearoyl calcium lactate, sodium stearoyl lactate, polyoxyethylene sorbitan fatty acid ester and the like can be mentioned.
次に、本発明の即席調理食品の一実施形態について説明する。 Next, an embodiment of the instant cooked food of the present invention will be described.
本発明の即席調理食品用油脂組成物を用いた即席調理食品としては、ソース類、シチュー類等の加工食品に用いられる固形ルウなどを例示することができる。 Examples of instant cooked foods using the oil and fat composition for instant cooked foods of the present invention include solid roux used in processed foods such as sauces and stews.
本発明の即席調理食品は、常法に従って、即席調理食品用油脂組成物と小麦粉と必要に応じてその他の原料を配合して混合加熱した後、型に流し込み、冷却固化させることによって製造することができる。 The instant cooked food of the present invention is produced by mixing and heating an oil / fat composition for instant cooked food, wheat flour and other raw materials as necessary according to a conventional method, and then pouring it into a mold and cooling and solidifying it. Can be done.
例えば、カレールウの場合は、本発明の即席調理食品用油脂組成物および動物油脂を加熱溶解し、小麦粉を加えて混合物を作製し、この混合物を撹拌しながら加熱焙煎してルウを作製する。加熱焙焼は、例えば混合物を80〜120℃で撹拌しながら行うことができる。その後、ここにカレーパウダー等の香辛料や、その他に必要に応じて調味料等の副原料を添加して、混合する。例えば、蒸気釜にて100℃前後でじっくりと煮込んでもよい。その後、ペースト状になったルウをプラスチックトレー等の容器(型)に流し込み、風冷等の冷却方法により、例えば0〜25℃で冷却して固化させることによって製造することができる。プラスチックトレーに充填されたカレールウは、密封され、トレーごと包装される。 For example, in the case of curry roux, the fat composition for instant cooked foods and animal fats and oils of the present invention are heated and dissolved, flour is added to prepare a mixture, and the mixture is heated and roasted with stirring to prepare roux. Heat roasting can be performed, for example, by stirring the mixture at 80 to 120 ° C. After that, spices such as curry powder and other auxiliary raw materials such as seasonings are added and mixed if necessary. For example, it may be slowly simmered in a steam kettle at around 100 ° C. After that, the paste-like ruu is poured into a container (mold) such as a plastic tray, cooled by a cooling method such as air cooling at 0 to 25 ° C., and solidified. The curry roux filled in the plastic tray is sealed and packed together with the tray.
固形ルウ等の即席調理食品における即席調理食品用油脂組成物および動物油脂の合計配合量は、特に限定されないが、例えば25〜70質量%であり、小麦粉の配合量は、特に限定されないが、例えば25〜70質量%である。 The total amount of the fat composition for instant cooked food and the animal fat and oil in the instant cooked food such as solid roux is not particularly limited, but is, for example, 25 to 70% by mass, and the blended amount of wheat flour is not particularly limited, for example. It is 25 to 70% by mass.
固形ルウ等の即席調理食品における本発明の即席調理食品用油脂組成物の配合量は、特に限定されないが、例えば動物油脂(即席調理食品用油脂組成物中の動物油脂を除く)に対して、好ましくは20〜50質量%、より好ましくは25〜43質量%である。 The blending amount of the fat and oil composition for instant cooked food of the present invention in the instant cooked food such as solid roux is not particularly limited, but for example, with respect to animal fat and oil (excluding animal fat and oil in the fat and oil composition for instant cooked food). It is preferably 20 to 50% by mass, more preferably 25 to 43% by mass.
固形ルウ等の即席調理食品には、本発明の即席調理食品用油脂組成物および小麦粉以外の成分として、通常、即席調理食品に配合される成分を適宜に使用することができる。具体的には、カレーパウダー等の香辛料、澱粉、食塩、糖類、糖アルコール類、アスパルテーム、ステビア等の甘味料、乳化剤、アミノ酸、核酸等の調味料、増粘安定剤、牛乳、チーズ、粉乳、生クリーム等の乳製品、クエン酸、L-酒石酸、乳酸等の酸味料、β-カロチン、カラメル、紅麹色素等の着色料、トコフェロール、アスコルビン酸、茶抽出物等の酸化防止剤、蛋白、pH調整剤、食品保存料、酒類、果実、果汁、はちみつ、フレーバー、コーヒー、カカオマス、ココアパウダー、ナッツペースト、豆類、野菜類、肉類、魚介類、コンソメ、ブイヨン、水等が挙げられる。 For instant cooked foods such as solid roux, ingredients usually blended in instant cooked foods can be appropriately used as ingredients other than the fat and oil composition for instant cooked foods and wheat flour of the present invention. Specifically, spices such as curry powder, starches, salt, sugars, sugar alcohols, sweeteners such as aspartame and stevia, seasonings such as emulsifiers, amino acids and nucleic acids, thickening stabilizers, milk, cheese, milk powder, etc. Milk products such as fresh cream, acidity agents such as citric acid, L-tartrate acid, lactic acid, coloring agents such as β-carotene, caramel, red koji pigment, antioxidants such as tocopherol, ascorbic acid, tea extract, proteins, Examples include pH adjusters, food preservatives, alcoholic beverages, fruits, fruit juices, honey, flavors, coffee, cacao mass, cocoa powder, nut paste, beans, vegetables, meat, seafood, consomme, bouillon, water and the like.
本発明の即席調理食品用油脂組成物を用いた即席調理食品は、加熱等によって溶解させることで、即席で加工食品を製造することができ、その具体例としては、カレーソース、ホワイトソース、デミグラスソース、ハヤシソース等のソース類や、ビーフシチュー、クリームシチュー等のシチュー類が挙げられる。 The instant cooked food using the oil and fat composition for instant cooked food of the present invention can be instantly produced as a processed food by melting it by heating or the like. Specific examples thereof include curry sauce, white sauce and demiglas sauce. , Sauces such as Hayashi sauce, and stews such as beef stew and cream stew.
ソース類やシチュー類は、肉や野菜と調味料等を加えて煮込んだスープ類に、固形ルウ等の即席調理食品を包材から取り出し、手で割り入れて製造することができる。 Sauces and stews can be produced by taking out instant cooked foods such as solid roux from the packaging material and manually inserting them into soups that are stewed by adding meat, vegetables and seasonings.
本発明の即席調理食品は、表面の白色化が抑制されており、喫食時の口どけが良好であり、ロウ臭が抑制されている。 In the instant cooked food of the present invention, the whitening of the surface is suppressed, the mouthfeel at the time of eating is good, and the waxy odor is suppressed.
本発明の即席調理食品用油脂組成物および即席調理食品は、以上の実施形態に限定されるものではない。 The fat composition for instant cooked foods and the instant cooked foods of the present invention are not limited to the above embodiments.
以下に、実施例により本発明の乳化油脂組成物などについて詳しく説明するが、本発明はこれらの実施例に限定されるものではない。 Hereinafter, the emulsified oil / fat composition of the present invention and the like will be described in detail with reference to Examples, but the present invention is not limited to these Examples.
<1>油脂組成物の調製
(エステル交換油脂1、2)
エステル交換油脂1、2は次の方法で調製した。表1に示す割合で、パーム核極度硬化油、パーム油、パーム極度硬化油を混合して110℃に加熱し、十分に脱水させた後、化学触媒としてナトリウムメチラートを油脂量の0.08質量%添加し、減圧下、100℃で0.5時間攪拌しながらエステル交換反応を行った。エステル交換反応後、水洗して触媒を除去し、活性白土を用いて脱色し、更に脱臭を行ってエステル交換油脂1、2を得た。
<1> Preparation of oil and fat composition (transesterified oil and fat 1, 2)
Transesterified fats and oils 1 and 2 were prepared by the following methods. At the ratio shown in Table 1, palm kernel extremely hardened oil, palm oil, and palm extremely hardened oil are mixed, heated to 110 ° C., sufficiently dehydrated, and then sodium methylate is used as a chemical catalyst with an amount of oil and fat of 0.08. Mass% was added, and the transesterification reaction was carried out under reduced pressure while stirring at 100 ° C. for 0.5 hours. After the transesterification reaction, the mixture was washed with water to remove the catalyst, decolorized using activated clay, and further deodorized to obtain transesterified fats and oils 1 and 2.
このエステル交換油脂1、2に、必要に応じて他の油脂を加え、油脂組成物を調製した(実施例1〜8、比較例1、2)。 Other fats and oils were added to the transesterified fats and oils 1 and 2 as needed to prepare a fat and oil composition (Examples 1 to 8 and Comparative Examples 1 and 2).
<2>カレールウの作製
表2の配合でカレールウを作製した。
<2> Preparation of curry roux A curry roux was prepared according to the formulation shown in Table 2.
〈カレールウの製法〉
[1]牛脂、実施例および比較例の油脂組成物を、撹拌羽根を備えた加熱釜に量り入れ、80℃で加熱溶解した。
[2][1]の加熱釜に薄力粉を入れ、撹拌しながら80〜120℃で滑らかになるまで炒め、ルウを作製した。
[3]得られたルウにカレーパウダーを加え、滑らかになるまで炒め合わせカレールウを作製した。
[4]得られたカレールウは80℃に調温し、溶融状態で80gをプラスチック製のシャーレ(90φ×20mm)に移し、0℃の恒温器内で20分間冷却した。得られた固形のカレールウは25℃の恒温器に移し4週間保管した。
<Manufacturing method of curry roux>
[1] Beef tallow and the oil and fat compositions of Examples and Comparative Examples were weighed into a heating kettle equipped with stirring blades and dissolved by heating at 80 ° C.
[2] Put the cake flour in the heating pot of [1] and stir-fry at 80 to 120 ° C. until smooth to prepare roux.
[3] Curry powder was added to the obtained roux and fried until smooth to prepare curry roux.
[4] The temperature of the obtained curry roux was adjusted to 80 ° C., 80 g of the obtained curry roux was transferred to a plastic petri dish (90φ × 20 mm) in a molten state, and cooled in an incubator at 0 ° C. for 20 minutes. The obtained solid curry roux was transferred to an incubator at 25 ° C. and stored for 4 weeks.
上記カレールウ表面の白色化について、以下の基準で評価した。なお、評価は△以上を課題が解決できたものとした。
(白色化)
25℃で4週間保管した固形のカレールウについて、表面の油脂結晶粗大化による白色化を以下の基準で評価した。
評価基準
◎:良好な艶を有しており、白色化は見られなかった。
○:白色化は見られなかったが、やや艶が失われていた。
△:艶がなく、ややざらついている。
×:白色化し、ざらつきがある。
The whitening of the curry roux surface was evaluated according to the following criteria. In the evaluation, it was assumed that the problem could be solved if the above was △.
(Whitening)
For solid curry roux stored at 25 ° C. for 4 weeks, whitening due to coarsening of oil and fat crystals on the surface was evaluated according to the following criteria.
Evaluation Criteria ⊚: Good luster and no whitening was observed.
◯: No whitening was observed, but the luster was slightly lost.
Δ: Matte and slightly rough.
X: Whitened and rough.
<3>カレーソースの作製
作製したカレールウ100質量部に対して食塩10質量部、糖類10質量部、水800質量部を加え撹拌しながら10分間煮立たせ、カレーソースを作製した。
<3> Preparation of Curry Sauce To 100 parts by mass of the prepared curry roux, 10 parts by mass of salt, 10 parts by mass of sugar, and 800 parts by mass of water were added and boiled for 10 minutes with stirring to prepare a curry sauce.
その後、品温45℃におけるカレーソースのロウ臭を以下の基準に従い、パネル20名で評価した。評価を実施するにあたりパネル全体で討議し、各評価項目の特性に対してすり合わせを行って、各パネルが共通認識を持つようにした。また、官能評価におけるパネルの偏りを排除し、評価の精度を高めるために、サンプルの試験区番号や内容はパネルに知らせず、ランダムに提示した。
(ロウ臭)
評価基準
◎:ロウ臭が無く、口溶けが極めて良好である。
○:ロウ臭が少なく、口溶けが良好である。
△:ロウ臭が少しあり、口溶けがやや不良である。
×:ロウ臭が強く、不良である。
Then, the waxy odor of the curry sauce at a product temperature of 45 ° C. was evaluated by 20 panels according to the following criteria. In carrying out the evaluation, discussions were held by the entire panel, and the characteristics of each evaluation item were adjusted so that each panel had a common understanding. In addition, in order to eliminate the bias of the panel in the sensory evaluation and improve the accuracy of the evaluation, the test plot number and contents of the sample were presented at random without notifying the panel.
(Wax smell)
Evaluation Criteria ⊚: No waxy odor and extremely good melting in the mouth.
◯: There is little waxy odor and it melts well in the mouth.
Δ: There is a slight waxy odor, and the melting in the mouth is slightly poor.
X: The waxy odor is strong and defective.
<4>評価結果
結果を表3に示す。
<4> Evaluation results The results are shown in Table 3.
表3に示したように、最大鎖長差が4以上であるトリグリセリドを40%以上含有する実施例1〜8は、動物油脂に対して即席調理食品用油脂組成物を43質量%配合したところ、カレールウ表面の白色化および喫食時のロウ臭が抑制されていることが確認された。さらに、35℃における30分後の等温結晶化SFCが4%以上、トリグリセリドの構成脂肪酸中にベヘン酸を0.03〜1.5%含有する実施例4〜8は、白色化およびロウ臭の抑制効果が顕著であることが確認された。 As shown in Table 3, in Examples 1 to 8 containing 40% or more of triglyceride having a maximum chain length difference of 4 or more, 43% by mass of an instant cooked food fat or oil composition was blended with animal fat or oil. It was confirmed that the whitening of the curry roux surface and the waxy odor during eating were suppressed. Further, Examples 4 to 8 in which the isothermal crystallized SFC at 35 ° C. after 30 minutes contained 4% or more and 0.03 to 1.5% behenic acid in the constituent fatty acids of the triglyceride had whitening and a waxy odor. It was confirmed that the inhibitory effect was remarkable.
一方、最大鎖長差が4以上であるトリグリセリドの含有量が40%未満である比較例1、2は、白色化、ロウ臭を同時に抑制できないことが確認された。また、比較例2より、等温結晶化SFCおよびベヘン酸含有量が所定の範囲であっても、最大鎖長差が4以上であるトリグリセリドの含有量が40%未満であると、ロウ臭抑制できないことが確認された。 On the other hand, it was confirmed that in Comparative Examples 1 and 2 in which the content of triglyceride having a maximum chain length difference of 4 or more and less than 40%, whitening and waxy odor could not be suppressed at the same time. Further, from Comparative Example 2, even if the content of isothermal crystallized SFC and behenic acid is within a predetermined range, if the content of triglyceride having a maximum chain length difference of 4 or more is less than 40%, the waxy odor cannot be suppressed. It was confirmed that.
このようにトリグリセリドを構成する脂肪酸のうち、最大鎖長差が4以上であるトリグリセリドの含有量を40%以上含有する本発明の即席調理食品用油脂組成物は、動物油脂の一部と置き換えて使用した即席調理食品の表面の白色化および喫食時のロウ臭を確実に抑制できることが確認された。
Among the fatty acids constituting the triglyceride, the fat and oil composition for instant cooking food of the present invention containing 40% or more of the triglyceride having a maximum chain length difference of 4 or more is replaced with a part of the animal fat and oil. It was confirmed that the whitening of the surface of the instant cooked food used and the waxy odor during eating can be reliably suppressed.
Claims (4)
An instant cooked food containing the oil / fat composition for an instant cooked food according to any one of claims 1 to 3.
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