JP2021028349A - Two-agent simultaneous discharge type hair dye - Google Patents
Two-agent simultaneous discharge type hair dye Download PDFInfo
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- JP2021028349A JP2021028349A JP2020199252A JP2020199252A JP2021028349A JP 2021028349 A JP2021028349 A JP 2021028349A JP 2020199252 A JP2020199252 A JP 2020199252A JP 2020199252 A JP2020199252 A JP 2020199252A JP 2021028349 A JP2021028349 A JP 2021028349A
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- agent
- hair dye
- filled
- ratio
- discharge
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 247
- 239000000118 hair dye Substances 0.000 title claims abstract description 37
- 238000007599 discharging Methods 0.000 claims abstract description 14
- 239000000443 aerosol Substances 0.000 claims abstract description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 20
- -1 polyoxyethylene Polymers 0.000 description 17
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 14
- 239000004615 ingredient Substances 0.000 description 13
- 238000001816 cooling Methods 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 229910001873 dinitrogen Inorganic materials 0.000 description 9
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- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 8
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- 239000000975 dye Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
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- 230000003020 moisturizing effect Effects 0.000 description 2
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- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 2
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- 239000005720 sucrose Substances 0.000 description 2
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- JPPRXACMNPYJNK-UHFFFAOYSA-N 1-docosoxydocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC JPPRXACMNPYJNK-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
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- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
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- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
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- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本発明は、二剤同時吐出型染毛剤に関するものである。 The present invention relates to a two-agent simultaneous ejection type hair dye.
従来のクリームタイプの染毛剤は、アルカリ剤を含む第一剤と酸化剤を含む第二剤とを別々に使用する際には特に問題は生じないが、第一剤と第二剤とを所定の吐出量の比率にて同時に吐出させて使用する場合、第一剤と第二剤との吐出量を調整する必要があり、消費者が使用することを考えると、第一剤と第二剤との吐出量は使い始めから使い終わるまで安定である必要があった。 The conventional cream-type hair dye does not cause any problem when the first agent containing an alkaline agent and the second agent containing an oxidizing agent are used separately, but the first agent and the second agent are used. When using by simultaneously discharging at a predetermined discharge amount ratio, it is necessary to adjust the discharge amount of the first agent and the second agent, and considering that the consumer uses it, the first agent and the second agent are used. The discharge rate with the agent had to be stable from the beginning to the end of use.
しかしながら、単純にクリーム状の染毛剤を、内袋を有する耐圧容器の内袋中に充填し、更に、内袋と耐圧容器間に圧縮ガスを充填したエアゾール容器において、使い始めから使い終わるまでの吐出量を評価したとき、充填する染毛剤によって吐出量が変化するため、第一剤と第二剤とを所定の吐出量の比率にて同時に吐出させて使用する場合、使い始めから使い終わるまで第一剤と第二剤とが所定の吐出量の比率にて同時に吐出出来ないことがあった。 However, in an aerosol container in which a creamy hair dye is simply filled in the inner bag of a pressure-resistant container having an inner bag, and a compressed gas is filled between the inner bag and the pressure-resistant container, from the beginning to the end of use. When the discharge amount of is evaluated, the discharge amount changes depending on the hair dye to be filled. Therefore, when the first agent and the second agent are simultaneously discharged at a predetermined discharge amount ratio, use from the beginning of use. Until the end, the first agent and the second agent could not be discharged at the same time at a predetermined discharge amount ratio.
又、従来のクリームタイプの染毛剤は、第一剤と第二剤とが所定の混合比率になるようトレイ等に出し、コームやブラシできちんと混ぜた後に頭髪に塗布するが、第一剤と第二剤とを所定の吐出量の比率にて同時に吐出させて使用する二剤同時吐出型染毛剤を頭髪に塗布する際、吐出後に直接頭髪に塗布するか、もしくはブラシに出してから頭髪に塗布し、第一剤と第二剤とを頭髪上で混ぜる行為を行うため、第一剤と第二剤とが所定の吐出量の比率にて同時に吐出されていないとムラ染めを引き起こすことがあった。 In the conventional cream-type hair dye, the first agent and the second agent are put out on a tray or the like so as to have a predetermined mixing ratio, mixed properly with a comb or a brush, and then applied to the hair. When applying a two-agent simultaneous discharge type hair dye that is used by simultaneously discharging and the second agent at a predetermined discharge rate ratio, apply it directly to the hair after discharge, or after applying it to a brush. Since it is applied to the hair and the first agent and the second agent are mixed on the hair, uneven dyeing is caused if the first agent and the second agent are not discharged at the same time at a predetermined discharge rate ratio. There was something.
そこで、第一剤及び／又は第二剤にシリコーン類を配合することで、吐出量が変化することなく、経時的吐出量の安定な原液を調製する提案がされている（特許文献１）。 Therefore, it has been proposed to prepare a stock solution having a stable discharge amount over time without changing the discharge amount by blending silicones with the first agent and / or the second agent (Patent Document 1).
本発明は、第一剤と第二剤とを同時に吐出する機構を有するエアゾール容器に充填した二剤同時吐出型染毛剤において、使い始めから使い終わるまで第一剤と第二剤とを所定の吐出量の比率にて同時に吐出することで、毛髪に対し簡便かつムラなく均一に染め上げることが出来る染毛剤を提供することを目的とする。 According to the present invention, in a two-agent simultaneous discharge type hair dye filled in an aerosol container having a mechanism for simultaneously discharging the first agent and the second agent, the first agent and the second agent are predetermined from the beginning to the end of use. It is an object of the present invention to provide a hair dye capable of easily and evenly dyeing hair by simultaneously discharging at the ratio of the discharge amount of.
本発明者は、上記課題を解決するために鋭意検討した結果、第一剤と第二剤とを同時に吐出する機構を有するエアゾール容器に充填した二剤同時吐出型染毛剤において、第一剤と第二剤との粘度が共に５０，０００ｍＰａ・ｓ以下であり、第一剤と第二剤との粘度の比率を、第一剤／第二剤＝０．８〜１．２にすることにより、使い始めから使い終わるまで第一剤と第二剤との吐出量の比率の変化が少なく、安定に所定の吐出量の比率にて同時に吐出することが出来ることを見い出し、本発明を完成させるに至った。 As a result of diligent studies to solve the above problems, the present inventor has found that the first agent is a two-agent simultaneous discharge type hair dye filled in an aerosol container having a mechanism for simultaneously discharging the first agent and the second agent. The viscosities of both the first agent and the second agent are 50,000 mPa · s or less, and the viscosity ratio of the first agent and the second agent is set to 0.8 to 1.2 for the first agent / second agent. As a result, it was found that the ratio of the discharge amount of the first agent and the second agent does not change much from the beginning to the end of use, and stable discharge can be performed at the same time at a predetermined discharge amount ratio, and the present invention is completed. I came to let you.
本発明によれば、第一剤と第二剤とを同時に吐出する機構を有するエアゾール容器に充填した二剤同時吐出型染毛剤において、使い始めから使い終わるまで第一剤と第二剤との吐出量の比率の変化が少なく、安定に所定の吐出量の比率にて同時に吐出することが出来るため、毛髪に対し簡便かつムラなく均一に染め上げることが出来る。 According to the present invention, in a two-agent simultaneous discharge type hair dye filled in an aerosol container having a mechanism for simultaneously discharging the first agent and the second agent, the first agent and the second agent are used from the beginning to the end of use. Since the change in the discharge amount ratio of the hair is small and the hair can be stably discharged at the same time at a predetermined discharge amount ratio, the hair can be dyed easily and evenly.
本発明にある吐出量とは重量であり、比率とは、特に記載がない限り重量比であり、第一剤と第二剤との所定の吐出量の比率は任意に設定可能である。 The discharge amount in the present invention is a weight, and the ratio is a weight ratio unless otherwise specified, and a predetermined discharge amount ratio between the first agent and the second agent can be arbitrarily set.
本発明の二剤同時吐出型染毛剤は、アルカリ剤を含有する第一剤と酸化剤を含有する第二剤とからなり、第一剤と第二剤との粘度が共に５０，０００ｍＰａ・ｓ以下であることを特徴とする。毛髪への塗布後の伸び、タレ落ちを考慮すると、好ましくは５，０００〜２５，０００ｍＰａ・ｓである。５０，０００ｍＰａ・ｓを超えると圧縮ガス等による容器からの吐出が困難になるため、吐出量にムラが生じ、所定の吐出量の比率にて同時に吐出することが困難になる。 The two-agent simultaneous discharge type hair dye of the present invention comprises a first agent containing an alkaline agent and a second agent containing an oxidizing agent, and the viscosities of both the first agent and the second agent are 50,000 mPa. It is characterized in that it is s or less. Considering the elongation after application to the hair and the sagging drop, it is preferably 5,000 to 25,000 mPa · s. If it exceeds 50,000 mPa · s, it becomes difficult to discharge the compressed gas from the container, so that the discharge amount becomes uneven and it becomes difficult to simultaneously discharge at a predetermined discharge amount ratio.
尚、粘度とは、二剤同時吐出型染毛剤の第一剤と第二剤とを別々の容器に吐出した各剤を２０度に調温し、ＴＶＢ−１０型粘度計（東機産業株式会社）でＳＰＩＮＤＬＥ ＮＯ．Ｍ４（ＣＯＤＥ ＮＯ．２３）を使用し、１２ｒｐｍで回転させてから１分後に測定したものとする。 In addition, the viscosity is a TVB-10 type viscometer (Toki Sangyo), in which the first agent and the second agent of the two-agent simultaneous discharge type hair dye are discharged to separate containers and the temperature is adjusted to 20 degrees. Co., Ltd.) SPINDLE NO. It is assumed that the measurement was performed 1 minute after the rotation at 12 rpm using M4 (CODE NO.23).
本発明の二剤同時吐出型染毛剤は、アルカリ剤を含有する第一剤と酸化剤を含有する第二剤とからなり、第一剤と第二剤との粘度の比率が、第一剤／第二剤＝０．８〜１．２であることを特徴とする。好ましくは０．９〜１．１である。粘度の比率が０．８未満であると、第二剤に比べ第一剤の粘度が低いため、第一剤が吐出し易くなり、第一剤の吐出量が多くなる。粘度の比率が１．２を超えると、第一剤に比べ第二剤の粘度が低いため、第二剤が吐出し易くなり、第二剤の吐出量が多くなる。このように、第一剤と第二剤との粘度に差が生じると第一剤と第二剤との吐出量に差が生じ、第一剤と第二剤とを所定の吐出量の比率にて同時に吐出することが困難になる。 The two-agent simultaneous discharge type hair dye of the present invention comprises a first agent containing an alkaline agent and a second agent containing an oxidizing agent, and the viscosity ratio of the first agent and the second agent is first. The agent / second agent = 0.8 to 1.2. It is preferably 0.9 to 1.1. When the viscosity ratio is less than 0.8, the viscosity of the first agent is lower than that of the second agent, so that the first agent can be easily discharged and the discharge amount of the first agent increases. When the viscosity ratio exceeds 1.2, the viscosity of the second agent is lower than that of the first agent, so that the second agent is easily discharged and the discharge amount of the second agent is increased. In this way, when there is a difference in viscosity between the first agent and the second agent, there is a difference in the discharge amount between the first agent and the second agent, and the ratio of the discharge amount between the first agent and the second agent is predetermined. It becomes difficult to discharge at the same time.
本発明の二剤同時吐出型染毛剤は、第一剤と第二剤とが共に高級アルコールを０．１〜１０．０重量％含有することを特徴とする。 The two-agent simultaneous discharge type hair dye of the present invention is characterized in that both the first agent and the second agent contain 0.1 to 10.0% by weight of higher alcohol.
本発明の二剤同時吐出型染毛剤に含有される高級アルコールとしては、例えば、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、セトステアリルアルコール、アラキルアルコール、ベヘニルアルコール、イソステアリルアルコール、オレイルアルコール、２−ヘキシルデカノール、２−オクチルドデカノール等が挙げられる。これらの中でも特に安定性の点から、直鎖飽和高級アルコールであるラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、セトステアリルアルコール、アラキルアルコール、ベヘニルアルコールが好ましい。その含有量は０．１〜１０．０重量％、好ましくは０．５〜５．０重量％である。０．１重量％未満であると分離等、剤の経時的安定性に影響があり、１０．０重量％を超えると剤の粘度が高くなり、圧縮ガス等による容器からの吐出が困難になるため、吐出量にムラが生じ、第一剤と第二剤とを所定の吐出量の比率にて同時に吐出することが困難になる。 Examples of the higher alcohol contained in the two-agent simultaneous discharge type hair dye of the present invention include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, araquil alcohol, behenyl alcohol, isostearyl alcohol, and oleyl alcohol. , 2-Hexyldecanol, 2-octyldodecanol and the like. Among these, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, araquil alcohol, and behenyl alcohol, which are linear saturated higher alcohols, are particularly preferable from the viewpoint of stability. Its content is 0.1 to 10.0% by weight, preferably 0.5 to 5.0% by weight. If it is less than 0.1% by weight, the stability of the agent over time such as separation will be affected, and if it exceeds 10.0% by weight, the viscosity of the agent will increase and it will be difficult to discharge the agent from the container with compressed gas or the like. Therefore, the discharge amount becomes uneven, and it becomes difficult to simultaneously discharge the first agent and the second agent at a predetermined discharge amount ratio.
本発明の二剤同時吐出型染毛剤には非イオン性界面活性剤を適宜配合することが可能である。非イオン性界面活性剤としては、例えば、ポリオキシエチレン（以下、ＰＯＥという）アルキルエーテル類、ＰＯＥアルキルフェニルエーテル類、ＰＯＥ・ポリオキシプロピレン（以下、ＰＯＰという）アルキルエーテル類、ＰＯＥ脂肪酸類、ＰＯＥソルビタン脂肪酸エステル類、ＰＯＥヒマシ油、ＰＯＥ硬化ヒマシ油、ＰＯＥソルビトールテトラ脂肪酸エステル、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、アルキルポリグルコシド、Ｎ−アルキルジメチルアミンオキシド、ＰＯＥプロピレングリコール脂肪酸エステル等が挙げられる。 A nonionic surfactant can be appropriately blended in the two-agent simultaneous ejection type hair dye of the present invention. Examples of the nonionic surfactant include polyoxyethylene (hereinafter referred to as POE) alkyl ethers, POE alkylphenyl ethers, POE / polyoxypropylene (hereinafter referred to as POP) alkyl ethers, POE fatty acids, and POE. Polysorbate fatty acid esters, POE castor oil, POE hardened castor oil, POE sorbitol tetra fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, alkyl polyglucoside, N-alkyldimethylamine oxide, POE Examples thereof include propylene glycol fatty acid ester.
これらの中でも酸やアルカリ剤に強いことから、ＰＯＥアルキルエーテル類、ＰＯＥアルキルフェニルエーテル類、ＰＯＥ・ＰＯＰアルキルエーテル類、ＰＯＥソルビタン脂肪酸エステル類が好ましく、更にこれらの中ではＰＯＥアルキルエーテル類が特に好ましい。ＰＯＥアルキルエーテル類の具体例としては、ＰＯＥラウリルエーテル、ＰＯＥセチルエーテル、ＰＯＥステアリルエーテル、ＰＯＥベヘニルエーテル、ＰＯＥオレイルエーテル等が挙げられる。その含有量は０．１〜１０．０重量％、好ましくは２．０〜６．０重量％である。０．１重量％未満であると分離等、剤の経時的安定性に影響があり、１０．０重量％を超えると剤の粘度が高くなり、圧縮ガス等による容器からの吐出が困難になるため、吐出量にムラが生じ、第一剤と第二剤とを所定の吐出量の比率にて同時に吐出することが困難になる。又、非イオン性界面活性剤は異なる２種以上を含有することが好ましく、１種はＨＬＢ値９．０未満、他の１種はＨＬＢ値１３．０以上であることが好ましい。 Among these, POE alkyl ethers, POE alkylphenyl ethers, POE / POP alkyl ethers, and POE sorbitan fatty acid esters are preferable because they are resistant to acids and alkaline agents, and among these, POE alkyl ethers are particularly preferable. .. Specific examples of POE alkyl ethers include POE lauryl ether, POE cetyl ether, POE stearyl ether, POE behenyl ether, POE oleyl ether and the like. Its content is 0.1 to 10.0% by weight, preferably 2.0 to 6.0% by weight. If it is less than 0.1% by weight, the stability of the agent over time such as separation will be affected, and if it exceeds 10.0% by weight, the viscosity of the agent will increase and it will be difficult to discharge the agent from the container with compressed gas or the like. Therefore, the discharge amount becomes uneven, and it becomes difficult to simultaneously discharge the first agent and the second agent at a predetermined discharge amount ratio. Further, the nonionic surfactant preferably contains two or more different types, one having an HLB value of less than 9.0, and the other having an HLB value of 13.0 or more.
尚、ＨＬＢとは、親水性−親油性のバランス（Ｈｙｄｒｏｐｈｉｌｅ−Ｌｉｐｏｐｈｉｌｅ Ｂａｌａｎｃｅ）を示す指標であり、本発明においては、小田・寺村らによる次式を用いて算出した値を用いた。
ＨＬＢ＝｛（Σ無機性値）／（Σ有機性値）｝×１０
The HLB is an index showing a hydrophilic-lipophilic balance (Hydrophile-lipophilic Balance), and in the present invention, a value calculated by using the following formula by Oda and Teramura et al. Was used.
HLB = {(Σ inorganic value) / (Σ organic value)} × 10
本発明の二剤同時吐出型染毛剤には炭化水素を適宜配合することが可能である。炭化水素としては、例えば、α−オレフィンオリゴマー、流動パラフィン、軽質イソパラフィン、軽質流動イソパラフィン、流動イソパラフィン、ワセリン、ポリエチレン末、オゾケライト、ポリブテン、セレシン等が挙げられる。これらの中でも特に安定性の点から、流動パラフィン、軽質イソパラフィン、軽質流動イソパラフィン、流動イソパラフィンが好ましい。その含有量は０．１〜２０．０重量％、好ましくは２．０〜１５．０重量％である。０．１重量％未満であると分離等、剤の経時的安定性に影響があり、２０．０重量％を超えると剤の粘度が高くなり、圧縮ガス等による容器からの吐出が困難になるため、吐出量にムラが生じ、第一剤と第二剤とを所定の吐出量の比率にて同時に吐出することが困難になる。 Hydrocarbons can be appropriately added to the two-agent simultaneous discharge type hair dye of the present invention. Examples of hydrocarbons include α-olefin oligomers, liquid paraffins, light isoparaffins, light liquid isoparaffins, liquid isoparaffins, petrolatum, polyethylene powder, ozokelite, polybutene, selecin and the like. Of these, liquid paraffin, light isoparaffin, light liquid isoparaffin and liquid isoparaffin are preferred from the standpoint of stability. Its content is 0.1 to 20.0% by weight, preferably 2.0 to 15.0% by weight. If it is less than 0.1% by weight, the stability of the agent over time such as separation will be affected, and if it exceeds 20.0% by weight, the viscosity of the agent will increase and it will be difficult to discharge the agent from the container with compressed gas or the like. Therefore, the discharge amount becomes uneven, and it becomes difficult to simultaneously discharge the first agent and the second agent at a predetermined discharge amount ratio.
本発明の二剤同時吐出型染毛剤にはその他に、酸化染料、アルカリ剤、酸化剤、シリコーン類、ロウ類、動植物油脂、高級脂肪酸類、有機溶剤又は浸透促進剤、多価アルコール類、エステル類、エーテル類、カチオン性界面活性剤、両性界面活性剤、アニオン性界面活性剤、カチオン性ポリマー、アニオン性ポリマー、両性ポリマー、蛋白誘導体及びアミノ酸類、防腐剤、キレート剤、安定化剤、酸化防止剤、ｐＨ調整剤、各種植物抽出物、生薬抽出物、ビタミン類、色素、香料、紫外線吸収剤等を適宜配合することが可能である。 In addition to the two-agent simultaneous discharge type hair dye of the present invention, oxidative dyes, alkaline agents, oxidants, silicones, waxes, animal and vegetable fats and oils, higher fatty acids, organic solvents or penetration promoters, polyhydric alcohols, etc. Esters, Ethers, Cationic Surfactants, Amphoteric Surfactants, Anionic Surfactants, Cationic Polymers, Anionic Polymers, Amphoteric Polymers, Protein Derivatives and Amino Acids, Preservatives, Chelating Agents, Stabilizers, Antioxidants, pH adjusters, various plant extracts, crude drug extracts, vitamins, pigments, fragrances, ultraviolet absorbers and the like can be appropriately blended.
尚、本発明の二剤同時吐出型染毛剤は、酸化染料が配合されない時には脱色剤として用いることが出来る。その他にも、ヘアケアやスキンケア等の二剤同時吐出型一般化粧料として用いることも出来る。 The two-agent simultaneous ejection type hair dye of the present invention can be used as a decolorizing agent when an oxidation dye is not blended. In addition, it can also be used as a two-agent simultaneous discharge type general cosmetic for hair care and skin care.
本発明の二剤同時吐出型染毛剤は、特開２００４−９１３５６号公報（特許文献１）に記載された二連エアゾール容器や、特開２００５−２３１６４４号公報に記載された二重構造エアゾール容器等を用いることが出来る。 The two-agent simultaneous discharge type hair dye of the present invention includes a double aerosol container described in JP-A-2004-91356 (Patent Document 1) and a double-structured aerosol described in JP-A-2005-231644. A container or the like can be used.
本発明の二剤同時吐出型染毛剤に用いられる圧縮ガスとしては、例えば、ジメチルエーテル、液化石油ガス、窒素ガス、代替フロン等、一般にエアゾール製品に用いられるものや、圧縮空気等を用いることが出来る。これらの中でも特に変質防止の面から、窒素ガスが好ましい。 As the compressed gas used in the two-agent simultaneous discharge type hair dye of the present invention, for example, dimethyl ether, liquefied petroleum gas, nitrogen gas, alternative freon, etc., which are generally used for aerosol products, compressed air, etc. may be used. You can. Among these, nitrogen gas is particularly preferable from the viewpoint of preventing deterioration.
本発明の二剤同時吐出型染毛剤において、第一剤と第二剤とにかかる初期内圧は、使用性の面から、２５℃において０．３〜０．８ＭＰａが好ましく、０．４〜０．７ＭＰａであることがより好ましい。又、第一剤と第二剤とにかかる初期内圧の比率を、第一剤／第二剤＝０．９５〜１．０５とすることで、より本発明の効果が得られる。 In the two-agent simultaneous discharge type hair dye of the present invention, the initial internal pressure applied to the first agent and the second agent is preferably 0.3 to 0.8 MPa at 25 ° C. from the viewpoint of usability, and is 0.4 to 0.4 MPa. It is more preferably 0.7 MPa. Further, the effect of the present invention can be further obtained by setting the ratio of the initial internal pressure applied to the first agent and the second agent to 0.95 to 1.05 for the first agent / second agent.
以下に実施例を挙げて本発明をより詳細に説明するが、本発明はこれらの実施例のみに限定されるものではない。配合量はすべて重量％である。 Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. All blending amounts are% by weight.
実施例に先立って各実施例で採用した試験法及び評価法を説明する。 Prior to the examples, the test method and the evaluation method adopted in each example will be described.
同時吐出性
実施例、比較例記載の処方により染毛剤を調製し、第一剤と第二剤との所定の吐出量の比率を、第一剤／第二剤＝１．０とした。調製した原液の第一剤５０ｇを充填した第一内装パウチ及び第二剤５０ｇを充填した第二内装パウチを１つの耐圧容器に収納し、内装パウチと耐圧容器間に窒素ガスを充填した、第一剤と第二剤とを同時に吐出する機構を有する二剤同時吐出型染毛剤の、使い始めから使い終わるまでの第一剤と第二剤との吐出量（ｇ／１０秒）を測定し、第一剤と第二剤との吐出量の比率を得た。評価の基準は以下の通りである。
＜評価基準＞
◎：とても良好 第一剤と第二剤との所定の吐出量の比率に対し、使い始めから使い終わるまでの第一剤と第二剤との吐出量（ｇ／１０秒）の比率が±５％以内
○：良好 第一剤と第二剤との所定の吐出量の比率に対し、使い始めから使い終わるまでの第一剤と第二剤との吐出量（ｇ／１０秒）の比率が±６〜１０％
△：普通 第一剤と第二剤との所定の吐出量の比率に対し、使い始めから使い終わるまでの第一剤と第二剤との吐出量（ｇ／１０秒）の比率が±１１〜２０％
×：悪い 第一剤と第二剤との所定の吐出量の比率に対し、使い始めから使い終わるまでの第一剤と第二剤との吐出量（ｇ／１０秒）の比率が±２１％を超える
Simultaneous ejection properties Hair dyes were prepared according to the formulations described in Examples and Comparative Examples, and the ratio of the predetermined ejection amount of the first agent and the second agent was set to 1.0 for the first agent / second agent. The first interior pouch filled with 50 g of the first agent and the second interior pouch filled with 50 g of the second agent of the prepared undiluted solution were housed in one pressure-resistant container, and nitrogen gas was filled between the interior pouch and the pressure-resistant container. Measure the discharge amount (g / 10 seconds) of the first agent and the second agent from the beginning to the end of use of the two-agent simultaneous discharge type hair dye that has a mechanism to discharge the first agent and the second agent at the same time. Then, the ratio of the discharge amount of the first agent and the second agent was obtained. The evaluation criteria are as follows.
<Evaluation criteria>
⊚: Very good The ratio of the discharge amount (g / 10 seconds) of the first agent and the second agent from the beginning to the end of use is ± with respect to the predetermined discharge amount ratio of the first agent and the second agent. Within 5% ○: Good The ratio of the discharge amount (g / 10 seconds) of the first agent and the second agent from the beginning to the end of use with respect to the predetermined discharge amount ratio of the first agent and the second agent. Is ± 6 to 10%
Δ: Normally, the ratio of the discharge amount (g / 10 seconds) of the first agent and the second agent from the start to the end of use is ± 11 with respect to the predetermined discharge amount ratio of the first agent and the second agent. ~ 20%
×: Bad The ratio of the discharge amount (g / 10 seconds) of the first agent and the second agent from the beginning to the end of use is ± 21 with respect to the predetermined discharge amount ratio of the first agent and the second agent. Over%
実施例１〜１３、比較例１〜５
実施例１〜１３、比較例１〜５に示した染毛剤を調製した。それぞれの同時吐出性について評価し、その結果を表１〜３に示した。
Examples 1 to 13, Comparative Examples 1 to 5
The hair dyes shown in Examples 1 to 13 and Comparative Examples 1 to 5 were prepared. The simultaneous ejection properties of each were evaluated, and the results are shown in Tables 1 to 3.
表１，２から明らかなように、本発明の二剤同時吐出型染毛剤は、同時吐出性において優れていた。一方、表３より、第一剤と第二剤との粘度差が大きい比較例１〜３、第一剤の粘度が高く、粘度差が大きい比較例４、及び第一剤と第二剤共に粘度が高く、粘度差が大きい比較例５は同時吐出性が劣っていた。 As is clear from Tables 1 and 2, the two-agent simultaneous ejection type hair dye of the present invention was excellent in simultaneous ejection property. On the other hand, from Table 3, Comparative Examples 1 to 3 in which the viscosity difference between the first agent and the second agent is large, Comparative Example 4 in which the viscosity of the first agent is high and the viscosity difference is large, and both the first agent and the second agent Comparative Example 5 having a high viscosity and a large viscosity difference was inferior in simultaneous ejection property.
実施例１４（脱色剤）
下記組成の脱色剤を調製し、第一剤と第二剤との所定の吐出量の比率を、第一剤／第二剤＝１．０とした。原液の第一剤５０ｇを充填した第一内装パウチ及び第二剤５０ｇを充填した第二内装パウチを１つの耐圧容器に収納し、内装パウチと耐圧容器間に窒素ガスを充填した、第一剤と第二剤とを同時に吐出する機構を有する二剤同時吐出型脱色剤の評価を行った。
（第一剤）
成分 配合量（重量％）
１） セチルアルコール ５．００
２） 流動イソパラフィン １０．００
３） 流動パラフィン ５．００
４） ジメチルポリシロキサン ５．００
５） ポリオキシエチレンステアリルエーテル ５．００
６） 塩化ステアリルトリメチルアンモニウム（７０％） １．５０
７） ステアリン酸 ０．５０
８） 香料 ０．５０
９） ポリ塩化ジメチルメチレンピペリジニウム液 １．００
１０） 大豆たん白加水分解物 ０．５０
１１） 加水分解シルク液 ０．５０
１２） アンモニア水（２５％） ６．００
１３） 精製水 残量
合 計 １００．００
製法
成分１〜８を８０℃にて加温溶融したものに、成分９，１３を８５℃にて加温溶融したものを加えて混合する。次いで撹拌しながら冷却を行い、４５℃にて成分１０〜１２を加え、室温まで撹拌しながら冷却を行い、第一剤を得た。
初期内圧 ０．５０ＭＰａ （充填：窒素ガス）
粘度 ２４，０００ｍＰａ・ｓ
Example 14 (decolorizing agent)
A decolorizing agent having the following composition was prepared, and the ratio of the predetermined discharge amount of the first agent and the second agent was set to 1.0 for the first agent / second agent. The first agent pouch filled with 50 g of the first agent of the undiluted solution and the second interior pouch filled with 50 g of the second agent were stored in one pressure-resistant container, and nitrogen gas was filled between the interior pouch and the pressure-resistant container. We evaluated a two-agent simultaneous discharge type decolorizing agent that has a mechanism for simultaneously discharging the second agent and the second agent.
(First agent)
Ingredient content (% by weight)
1) Cetyl alcohol 5.00
2) Liquid isoparaffin 10.00
3) Liquid paraffin 5.00
4) Didimethylpolysiloxane 5.00
5) Polyoxyethylene stearyl ether 5.00
6) Stearyltrimethylammonium chloride (70%) 1.50
7) Stearic acid 0.50
8) Fragrance 0.50
9) Polydimethylmethylene piperidinium solution 1.00
10) Soy protein hydrolyzate 0.50
11) Hydrolyzed silk liquid 0.50
12) Ammonia water (25%) 6.00
13) Remaining amount of purified water
Total 100.00
Manufacturing method Ingredients 1 to 8 are heated and melted at 80 ° C., and components 9 and 13 are heated and melted at 85 ° C. and mixed. Next, cooling was performed with stirring, components 10 to 12 were added at 45 ° C., and cooling was performed with stirring to room temperature to obtain a first agent.
Initial internal pressure 0.50 MPa (filling: nitrogen gas)
Viscosity 24,000 mPa · s
（第二剤）
成分 配合量（重量％）
１） セチルアルコール ５．００
２） ステアリルアルコール ４．００
３） 流動パラフィン ５．００
４） ポリオキシエチレンセチルエーテル ５．００
５） ヒドロキシエタンジホスホン酸（６０％） ０．２０
６） リン酸 ０．０２
７） リン酸水素二ナトリウム ０．１０
８） 過酸化水素水（３５％） １６．６０
９） 精製水 残量
合 計 １００．００
製法
成分１〜５を８０℃にて加温溶融したものに、成分６，７，９を８５℃にて加温溶融したものを加えて混合する。次いで撹拌しながら冷却を行い、４０℃にて成分８を加え、室温まで撹拌しながら冷却を行い、第二剤を得た。
初期内圧 ０．５０ＭＰａ （充填：窒素ガス）
粘度 ２５，０００ｍＰａ・ｓ
粘度比率（第一剤／第二剤） ０．９６
(Second agent)
Ingredient content (% by weight)
1) Cetyl alcohol 5.00
2) Stearyl alcohol 4.00
3) Liquid paraffin 5.00
4) Polyoxyethylene cetyl ether 5.00
5) Hydroxyethanediphosphonic acid (60%) 0.20
6) Phosphoric acid 0.02
7) Disodium hydrogen phosphate 0.10
8) Hydrogen peroxide solution (35%) 16.60
9) Remaining amount of purified water
Total 100.00
Manufacturing method Ingredients 1 to 5 are heated and melted at 80 ° C., and components 6, 7 and 9 are heated and melted at 85 ° C. and mixed. Next, cooling was performed with stirring, component 8 was added at 40 ° C., and cooling was performed with stirring to room temperature to obtain a second agent.
Initial internal pressure 0.50 MPa (filling: nitrogen gas)
Viscosity 25,000 mPa · s
Viscosity ratio (first agent / second agent) 0.96
実施例１５（シャンプー＆リンス）
下記組成のシャンプー＆リンスを調製し、第一剤と第二剤との所定の吐出量の比率を、第一剤／第二剤＝１．０とした。原液の第一剤５０ｇを充填した第一内装パウチ及び第二剤５０ｇを充填した第二内装パウチを１つの耐圧容器に収納し、内装パウチと耐圧容器間に圧縮空気を充填した、第一剤と第二剤とを同時に吐出する機構を有する二剤同時吐出型化粧料の評価を行った。
（第一剤）
成分 配合量（重量％）
１） ステアリルアルコール ０．１０
２） ラウリル硫酸ＴＥＡ（４０％） １５．００
３） （Ｃ１２，１３）パレス−３硫酸Ｎａ（２９％） ８．００
４） ラウレス−２５ ５．００
５） ジステアリン酸グリコール １．５０
６） ラウラミドプロピルベタイン（３０％） ２０．００
７） ラウロイルメチルアラニンＮａ ７．００
８） オリーブ油 ０．５０
９） 香料 ０．５０
１０） ポリクオタニウム−７ ０．５０
１１） ポリクオタニウム−１０ ０．５０
１２） クエン酸 ０．８０
１３） ＥＤＴＡ−２Ｎａ ０．３０
１４） 安息香酸Ｎａ ０．３０
１５） ローヤルゼリーエキス ０．５０
１６） 加水分解ダイズタンパク ０．５０
１７） 加水分解シルク ０．５０
１８） 水 残量
合 計 １００．００
製法
成分１〜９を８０℃にて加温溶融したものに、成分１０〜１４，１８を８５℃にて加温溶融したものを加えて混合する。次いで撹拌しながら冷却を行い、４０℃にて成分１５〜１７を加え、室温まで撹拌しながら冷却を行い、第一剤を得た。
初期内圧 ０．４０ＭＰａ （充填：圧縮空気）
粘度 １，６００ｍＰａ・ｓ
Example 15 (shampoo & conditioner)
A shampoo and rinse having the following composition was prepared, and the ratio of the predetermined discharge amount of the first agent and the second agent was set to 1.0 for the first agent / second agent. The first agent pouch filled with 50 g of the first agent of the undiluted solution and the second interior pouch filled with 50 g of the second agent are stored in one pressure-resistant container, and compressed air is filled between the interior pouch and the pressure-resistant container. We evaluated a two-agent simultaneous discharge type cosmetic that has a mechanism for simultaneously discharging the second agent and the second agent.
(First agent)
Ingredient content (% by weight)
1) Stearyl alcohol 0.10
2) TEA lauryl sulfate (40%) 15.00
3) (C12, 13) Palace-3 Na Sulfate (29%) 8.00
4) Laureth-25 5.00
5) Glycol distearate 1.50
6) Lauramide propyl betaine (30%) 20.00
7) Lauroylmethylalanine Na 7.00
8) Olive oil 0.50
9) Fragrance 0.50
10) Polyquaternium-7 0.50
11) Polyquaternium-10 0.50
12) Citric acid 0.80
13) EDTA-2Na 0.30
14) Na benzoate 0.30
15) Royal jelly extract 0.50
16) Hydrolyzed soy protein 0.50
17) Hydrolyzed silk 0.50
18) Remaining amount of water
Total 100.00
Manufacturing method Ingredients 1 to 9 are heated and melted at 80 ° C., and components 10 to 14 and 18 are heated and melted at 85 ° C. and mixed. Next, cooling was performed with stirring, components 15 to 17 were added at 40 ° C., and cooling was performed with stirring to room temperature to obtain a first agent.
Initial internal pressure 0.40 MPa (filling: compressed air)
Viscosity 1,600 mPa · s
（第二剤）
成分 配合量（重量％）
１） ステアリルアルコール ３．５０
２） ベヘントリモニウムクロリド １．００
３） ジメチコン ２．００
４） アミノプロピルジメチコン １．５０
５） （ヒドロキシステアリン酸／ステアリン酸
／ロジン酸）ジペンタエリスリチル １．００
６） ヘキサエルカ酸スクロース １．００
７） グリセリン ３．００
８） 香料 ０．５０
９） クエン酸 ０．０２
１０） クエン酸Ｎａ ０．１０
１１） ＢＧ ２．００
１２） メチルパラベン ０．２０
１３） グアーヒドロキシプロピルトリモニウムクロリド ０．５０
１４） ローヤルゼリーエキス ０．５０
１５） 加水分解ダイズタンパク ０．５０
１６） 加水分解シルク ０．５０
１７） 黄４ ０．０００２
１８） 水 残量
合 計 １００．００
製法
成分１〜８を９０℃にて加温溶融したものに、成分９〜１３，１８を９０℃にて加温溶融したものを加えて混合する。次いで撹拌しながら冷却を行い、４０℃にて成分１４〜１７を加え、室温まで撹拌しながら冷却を行い、第二剤を得た。
初期内圧 ０．４０ＭＰａ （充填：圧縮空気）
粘度 １，６００ｍＰａ・ｓ
粘度比率（第一剤／第二剤） １．００
(Second agent)
Ingredient content (% by weight)
1) Stearyl alcohol 3.50
2) Behentrimonium chloride 1.00
3) Dimethicone 2.00
4) Aminopropyl dimethicone 1.50
5) (Hydroxystearic acid / stearic acid
/ Rosinic acid) Dipentaerythrityl 1.00
6) Sucrose hexaerucate 1.00
7) Glycerin 3.00
8) Fragrance 0.50
9) Citric acid 0.02
10) Na citrate 0.10
11) BG 2.00
12) Methylparaben 0.20
13) Guar hydroxypropyltrimonium chloride 0.50
14) Royal jelly extract 0.50
15) Hydrolyzed soy protein 0.50
16) Hydrolyzed silk 0.50
17) Yellow 4 0.0002
18) Remaining amount of water
Total 100.00
Manufacturing method Ingredients 1 to 8 are heated and melted at 90 ° C., and components 9 to 13 and 18 are heated and melted at 90 ° C. and mixed. Next, cooling was performed with stirring, components 14 to 17 were added at 40 ° C., and cooling was performed with stirring to room temperature to obtain a second agent.
Initial internal pressure 0.40 MPa (filling: compressed air)
Viscosity 1,600 mPa · s
Viscosity ratio (first agent / second agent) 1.00
実施例１６（保湿用ハンドクリーム）
下記組成の保湿用ハンドクリームを調製し、第一剤と第二剤との所定の吐出量の比率を、第一剤／第二剤＝１．０とした。原液の第一剤と第二剤とをそれぞれ内袋を有する耐圧容器の内袋中に４０ｇ充填し、内袋と耐圧容器間に窒素ガスを充填した、第一剤と第二剤とを同時に吐出する機構を有する二剤同時吐出型化粧料の評価を行った。
（第一剤）
成分 配合量（重量％）
１） ステアリルアルコール ０．３０
２） ベヘニルアルコール ０．３０
３） マイクロクリスタリンワックス ２．５０
４） パラフィン ６．００
５） スクワラン ３．００
６） ワセリン １．００
７） ミリスチン酸オクチルドデシル ２．００
８） ジメチコン １．００
９） ステアリン酸グリセリル ０．５０
１０） ＢＧ ６．００
１１） メチルパラベン ０．３０
１２） グリセリン ３．００
１３） ＥＤＴＡ−２Ｎａ ０．０５
１４） （アクリレーツ／アクリル酸アルキル
（Ｃ１０−３０））クロスポリマー ０．２０
１５） キサンタンガム ０．０５
１６） 水酸化Ｋ ０．０８
１７） モモ葉エキス ０．５０
１８） 水 残量
合 計 １００．００
製法
成分１〜９を８５℃にて加温溶融したものに、成分１０〜１５，１８を８５℃にて加温溶融したものを加えて混合する。次いで成分１６を加えて混合し、撹拌しながら冷却を行い、４５℃にて成分１７を加え、室温まで撹拌しながら冷却を行い、第一剤を得た。
初期内圧 ０．５０ＭＰａ （充填：窒素ガス）
粘度 １６，０００ｍＰａ・ｓ
Example 16 (moisturizing hand cream)
A moisturizing hand cream having the following composition was prepared, and the ratio of the predetermined discharge amount of the first agent and the second agent was set to 1.0 for the first agent / second agent. 40 g of the first agent and the second agent of the undiluted solution were filled in the inner bag of a pressure-resistant container having an inner bag, and nitrogen gas was filled between the inner bag and the pressure-resistant container. We evaluated a two-agent simultaneous discharge type cosmetic that has a discharge mechanism.
(First agent)
Ingredient content (% by weight)
1) Stearyl alcohol 0.30
2) Behenyl alcohol 0.30
3) Microcrystalline wax 2.50
4) Paraffin 6.00
5) Squalene 3.00
6) Vaseline 1.00
7) Octyldodecyl myristate 2.00
8) Dimethicone 1.00
9) Glyceryl stearate 0.50
10) BG 6.00
11) Methylparaben 0.30
12) Glycerin 3.00
13) EDTA-2Na 0.05
14) (Acrylate / Alkyl acrylate
(C10-30)) Cross Polymer 0.20
15) Xanthan gum 0.05
16) K hydroxide 0.08
17) Peach leaf extract 0.50
18) Remaining amount of water
Total 100.00
Manufacturing method Ingredients 1 to 9 are heated and melted at 85 ° C., and components 10 to 15 and 18 are heated and melted at 85 ° C. and mixed. Next, component 16 was added and mixed, and cooling was performed with stirring. Component 17 was added at 45 ° C. and cooling was performed with stirring to room temperature to obtain a first agent.
Initial internal pressure 0.50 MPa (filling: nitrogen gas)
Viscosity 16,000 mPa · s
（第二剤）
成分 配合量（重量％）
１） ベヘニルアルコール ２．００
２） ステアリン酸 １．００
３） ステアリン酸ステアリル ２．００
４） スクワラン ５．００
５） ミリスチン酸オクチルドデシル ３．００
６） ジメチコン １．５０
７） ステアリン酸ソルビタン １．５０
８） ステアリン酸グリセリル（ＳＥ） １．００
９） ステアリン酸ＰＥＧ−４０ ２．００
１０） ビタミンＡ油 ０．５０
１１） ＢＧ ６．００
１２） メチルパラベン ０．３０
１３） グリセリン ３．００
１４） （アクリレーツ／アクリル酸アルキル
（Ｃ１０−３０））クロスポリマー ０．１０
１５） 水酸化Ｋ ０．０５
１６） グリチルリチン酸２Ｋ ０．５０
１７） 赤５０４ ０．０００２
１８） 水 残量
合 計 １００．００
製法
成分１〜１０を８０℃にて加温溶融したものに、成分１１〜１４，１８を８５℃にて加温溶融したものを加えて混合する。次いで成分１５を加えて混合し、撹拌しながら冷却を行い、４５℃にて成分１６〜１７を加え、室温まで撹拌しながら冷却を行い、第二剤を得た。
初期内圧 ０．５０ＭＰａ （充填：窒素ガス）
粘度 １９，０００ｍＰａ・ｓ
粘度比率（第一剤／第二剤） ０．８４
(Second agent)
Ingredient content (% by weight)
1) Behenyl alcohol 2.00
2) Stearic acid 1.00
3) Stearyl stearate 2.00
4) Squalene 5.00
5) Octyldodecyl myristate 3.00
6) Dimethicone 1.50
7) Sorbitan stearate 1.50
8) Glyceryl stearate (SE) 1.00
9) PEG-40 2.00 stearate
10) Vitamin A oil 0.50
11) BG 6.00
12) Methylparaben 0.30
13) Glycerin 3.00
14) (Acrylate / Alkyl acrylate
(C10-30)) Cross polymer 0.10
15) Hydroxide K 0.05
16) Glycyrrhizinate 2K 0.50
17) Red 504 0.0002
18) Remaining amount of water
Total 100.00
Manufacturing method Ingredients 1 to 10 are heated and melted at 80 ° C., and components 11 to 14 and 18 are heated and melted at 85 ° C. and mixed. Next, component 15 was added and mixed, and cooling was performed while stirring. Ingredients 16 to 17 were added at 45 ° C., and cooling was performed while stirring to room temperature to obtain a second agent.
Initial internal pressure 0.50 MPa (filling: nitrogen gas)
Viscosity 19,000 mPa · s
Viscosity ratio (first agent / second agent) 0.84
実施例１４〜１６は、同時吐出性において優れていた。 Examples 14 to 16 were excellent in simultaneous ejection property.
実施例１４は、同時吐出性において優れていた。 Examples 14 were excellent in simultaneous ejection property.
Claims (4)
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003095901A (en) * | 2001-09-27 | 2003-04-03 | Hoyu Co Ltd | Hair-decoloring agent composition and hair-dyeing agent composition |
| JP2003201225A (en) * | 2001-10-30 | 2003-07-18 | Kanebo Ltd | Aerosol type creamy hair dye |
| JP2004091356A (en) * | 2002-08-30 | 2004-03-25 | Kanebo Ltd | Simultaneously spraying type creamy hair dye composition |
| JP2005097310A (en) * | 2004-10-06 | 2005-04-14 | Hoyu Co Ltd | Hair make-up agent, hair cosmetic and method for using hair make-up agent |
| JP2005194207A (en) * | 2003-12-26 | 2005-07-21 | Kao Corp | Two-pack type hair cosmetic |
| JP2012229318A (en) * | 2011-04-26 | 2012-11-22 | Toyo Aerosol Ind Co Ltd | Foam forming aerosol product |
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2020
- 2020-12-01 JP JP2020199252A patent/JP7097097B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003095901A (en) * | 2001-09-27 | 2003-04-03 | Hoyu Co Ltd | Hair-decoloring agent composition and hair-dyeing agent composition |
| JP2003201225A (en) * | 2001-10-30 | 2003-07-18 | Kanebo Ltd | Aerosol type creamy hair dye |
| JP2004091356A (en) * | 2002-08-30 | 2004-03-25 | Kanebo Ltd | Simultaneously spraying type creamy hair dye composition |
| JP2005194207A (en) * | 2003-12-26 | 2005-07-21 | Kao Corp | Two-pack type hair cosmetic |
| JP2005097310A (en) * | 2004-10-06 | 2005-04-14 | Hoyu Co Ltd | Hair make-up agent, hair cosmetic and method for using hair make-up agent |
| JP2012229318A (en) * | 2011-04-26 | 2012-11-22 | Toyo Aerosol Ind Co Ltd | Foam forming aerosol product |
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