JP2021025699A - Collection method of fluid medium in fluid bed furnace - Google Patents

Collection method of fluid medium in fluid bed furnace Download PDF

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JP2021025699A
JP2021025699A JP2019143788A JP2019143788A JP2021025699A JP 2021025699 A JP2021025699 A JP 2021025699A JP 2019143788 A JP2019143788 A JP 2019143788A JP 2019143788 A JP2019143788 A JP 2019143788A JP 2021025699 A JP2021025699 A JP 2021025699A
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furnace
medium
fluidized
furnace body
flow
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JP7065058B2 (en
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大 藤原
Masaru Fujiwara
大 藤原
克義 谷田
Katsuyoshi Tanida
克義 谷田
勇 青木
Isamu Aoki
勇 青木
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Shinko Pantec Co Ltd
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Kobelco Eco Solutions Co Ltd
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Abstract

To provide a method which can efficiently collect a valuable metal contained in a refuse in a fluid bed furnace.SOLUTION: In a collection method of a fluid medium in a fluid bed furnace, the fluid bed furnace comprises: a furnace main body; the fluid medium filled into the furnace main body; and a furnace bottom plate in which a withdrawal port for withdrawing the fluid medium to the outside of the furnace main body is formed, and which is inclined downward at an angle smaller than a repose angle of the fluid medium toward the withdrawal port. In the fluid bed furnace for burning or gasifying a refuse containing a valuable metal in a state that the fluid medium circulates, the method for collecting the fluid medium from the furnace main body when the fluid bed furnace is stopped comprises: a withdrawal process for withdrawing the fluid medium which is filled in the furnace main body to the outside of the furnace main body through the withdrawal port; and a collection process for collecting the fluid medium remaining on the furnace bottom plate after the withdrawal process in a state that the remaining fluid medium is separated from the fluid medium which is withdrawn from the inside of the furnace main body in the withdrawal process.SELECTED DRAWING: Figure 2

Description

本発明は、流動床炉における流動媒体の回収方法に関する。 The present invention relates to a method for recovering a fluidized medium in a fluidized bed furnace.

従来、特許文献1,2に記載されているように、砂等の流動媒体が流動した状態で各種廃棄物を焼却処理する流動床式焼却炉或いは当該廃棄物をガス化する流動床式ガス化炉が知られている。これらの流動床炉には、流動媒体を炉から取り出すと共に当該流動媒体を不燃物と分離した後、流動媒体を炉に戻す循環機構が設けられている。 Conventionally, as described in Patent Documents 1 and 2, a fluidized bed incinerator that incinerates various wastes in a state where a fluidized medium such as sand is flowing, or a fluidized bed gasification that gasifies the waste. The furnace is known. These fluidized bed furnaces are provided with a circulation mechanism for taking out the fluidized medium from the furnace, separating the fluidized medium from the incombustible material, and then returning the fluidized medium to the furnace.

特許文献1には、流動床式ガス化炉の炉底残渣の処理方法が記載されており、この方法では、流動床式ガス化炉より排出された炉底残渣から金属分及び非金属分が回収されて残った流動媒体が炉に戻されると共に、回収された非金属分が溶融炉でスラグ化される。特許文献2には、流動床式ガス化炉の底部より排出された流動砂と不燃物の混合物から不燃物を分離して流動砂のみを炉に戻す循環機構として、砂分級装置と、砂循環エレベータと、を備えたものが記載されている。 Patent Document 1 describes a method for treating the bottom residue of a fluidized bed gasifier. In this method, metal and non-metal components are removed from the bottom residue discharged from the fluidized bed gasifier. The recovered fluidized bed is returned to the furnace, and the recovered non-metal content is slagged in the melting furnace. Patent Document 2 describes a sand classification device and sand circulation as a circulation mechanism for separating incombustibles from a mixture of fluidized sand and incombustibles discharged from the bottom of a fluidized bed gasifier and returning only the fluidized sands to the furnace. Elevators and those equipped with are listed.

特許第3909514号公報Japanese Patent No. 3909514 特許第4321823号公報Japanese Patent No. 4321823

流動床式焼却炉により焼却処理される或いは流動床式ガス化炉によりガス化される廃棄物には、金や銀等の貴金属或いは鉛や亜鉛等の重金属等、有価金属が微量に含まれている。特許文献1,2では、このような廃棄物に含まれる有価金属を効率的に回収することが困難であり、本発明者等はこの課題に着目した。 Waste that is incinerated by a fluidized bed incinerator or gasified by a fluidized bed gasifier contains a small amount of precious metals such as gold and silver or heavy metals such as lead and zinc. There is. In Patent Documents 1 and 2, it is difficult to efficiently recover valuable metals contained in such waste, and the present inventors have focused on this problem.

本発明は、上記課題に鑑みてなされたものであり、その目的は、流動床炉において廃棄物に含まれる有価金属を効率的に回収することが可能な方法を提供することである。 The present invention has been made in view of the above problems, and an object of the present invention is to provide a method capable of efficiently recovering valuable metals contained in waste in a fluidized bed furnace.

本発明の一局面に係る流動床炉における流動媒体の回収方法は、炉本体と、前記炉本体内に充填された流動媒体と、前記流動媒体を前記炉本体の外へ抜き出すための抜出口が形成されると共に前記抜出口に向かって前記流動媒体の安息角よりも小さい角度で下向きに傾斜する炉底板と、を備え、前記流動媒体が流動した状態で有価金属を含む廃棄物を焼却処理或いはガス化する流動床炉において、前記流動床炉を停止した時に前記炉本体内から前記流動媒体を回収する方法である。この回収方法は、前記炉本体内に充填された前記流動媒体を、前記抜出口を通じて重力により前記炉本体の外へ抜き出す抜出工程と、前記抜出工程の後に前記炉底板上に残存した前記流動媒体を、前記抜出工程で前記炉本体内から抜き出した前記流動媒体と分離した状態で回収する回収工程と、を備えている。 In the method for recovering a flow medium in a flow bed furnace according to one aspect of the present invention, a furnace body, a flow medium filled in the furnace body, and an outlet for extracting the flow medium to the outside of the furnace body are provided. A furnace bottom plate that is formed and inclines downward at an angle smaller than the rest angle of the flow medium toward the outlet is provided, and waste containing valuable metals is incinerated while the flow medium is flowing. In a gasifying flow bed furnace, this is a method of recovering the flow medium from the inside of the furnace body when the flow bed furnace is stopped. In this recovery method, the flow medium filled in the furnace body is extracted to the outside of the furnace body by gravity through the extraction port, and the extraction step remains on the bottom plate after the extraction step. It is provided with a recovery step of recovering the flow medium in a state of being separated from the flow medium extracted from the furnace body in the extraction step.

上記回収方法では、流動床炉を停止した後、まず、炉本体内に充填された流動媒体を、抜出口を通じて炉本体の外へ抜き出す(抜出工程)。この時、炉底板の傾斜角が流動媒体の安息角よりも小さいため、上記抜出工程では炉本体内に充填された流動媒体が全て炉外へ抜き出されることはなく、一部の流動媒体が炉底板上に残存する。 In the above recovery method, after stopping the fluidized bed furnace, first, the fluidized medium filled in the furnace main body is taken out of the furnace main body through an extraction port (extraction step). At this time, since the inclination angle of the furnace bottom plate is smaller than the angle of repose of the flow medium, not all the flow medium filled in the furnace body is taken out of the furnace in the above extraction step, and a part of the flow medium is not extracted. Remains on the bottom plate.

本発明者等は、鋭意研究の結果、上述のように抜出工程の後に炉底板上に残存した流動媒体に、廃棄物由来の有価金属が高濃度に含まれていることを新たに発見した。このため、本発明の流動床炉における流動媒体の回収方法では、上記知見に基づき、抜出工程の後に炉底板上に残存した流動媒体を、上記抜出工程で炉外へ抜き出された流動媒体と混合することなく、これと分離した状態で別途回収する(回収工程)。これにより、高濃度の有価金属を含む流動媒体のみを回収することが可能になり、その後、回収された流動媒体から有価金属を分離することにより、廃棄物由来の有価金属を効率的に回収することができる。 As a result of diligent research, the present inventors have newly discovered that the fluid medium remaining on the bottom plate after the extraction process contains a high concentration of valuable metals derived from waste as described above. .. Therefore, in the method for recovering the fluidized bed in the fluidized bed furnace of the present invention, based on the above findings, the fluidized medium remaining on the bottom plate after the extraction step is extracted to the outside of the furnace in the extraction step. It is separately collected in a state separated from the medium without being mixed with the medium (recovery step). This makes it possible to recover only the fluid medium containing a high concentration of valuable metal, and then efficiently recover the valuable metal derived from waste by separating the valuable metal from the recovered fluid medium. be able to.

上記流動床炉における流動媒体の回収方法は、前記回収工程で回収した前記流動媒体から有価金属を分離する分離工程をさらに備えていてもよい。 The method for recovering the fluidized medium in the fluidized bed furnace may further include a separation step for separating the valuable metal from the fluidized medium recovered in the recovery step.

この方法によれば、流動媒体から分離した有価金属を種々の用途に利用することができる。 According to this method, the valuable metal separated from the flow medium can be used for various purposes.

上記流動床炉における流動媒体の回収方法において、前記流動床炉は、前記炉本体の外へ抜き出された前記流動媒体を前記炉本体へ戻す循環機構であって、前記流動媒体を搬送する搬送部と、前記搬送部により搬送された前記流動媒体を貯留する貯留槽と、を有する前記循環機構をさらに備えていてもよい。前記抜出工程では、前記炉本体の外へ抜き出された前記流動媒体を、前記搬送部により搬送すると共に前記貯留槽に供給してもよい。前記回収工程では、前記炉底板上に残存した前記流動媒体を前記炉本体の外へ排出した後、前記貯留槽と異なる場所で回収してもよい。 In the method for recovering a fluidized medium in the fluidized bed furnace, the fluidized bed furnace is a circulation mechanism for returning the fluidized medium extracted to the outside of the furnace body to the furnace body, and transports the fluidized medium. The circulation mechanism may further include a unit and a storage tank for storing the fluidized medium transported by the transport unit. In the extraction step, the flow medium extracted to the outside of the furnace body may be conveyed by the conveying unit and supplied to the storage tank. In the recovery step, the flow medium remaining on the bottom plate of the furnace may be discharged to the outside of the furnace body and then recovered at a place different from the storage tank.

この方法によれば、抜出工程の後に炉底板上に残存した流動媒体を、抜出工程において炉外へ抜き出された流動媒体と確実に分離した状態で回収することが可能になる。 According to this method, the flow medium remaining on the furnace bottom plate after the extraction step can be recovered in a state of being surely separated from the flow medium extracted to the outside of the furnace in the extraction step.

以上の説明から明らかなように、本発明によれば、流動床炉において廃棄物に含まれる有価金属を効率的に回収することが可能な方法を提供することができる。 As is clear from the above description, according to the present invention, it is possible to provide a method capable of efficiently recovering valuable metals contained in waste in a fluidized bed furnace.

本発明の実施形態1における流動床炉の構成を模式的に示す図である。It is a figure which shows typically the structure of the fluidized bed furnace in Embodiment 1 of this invention. 上記流動床炉における散気管の構成を示す断面図である。It is sectional drawing which shows the structure of the air diffuser pipe in the said fluidized bed furnace. 上記流動床炉における散気管の構成を示す平面図である。It is a top view which shows the structure of the air diffuser pipe in the said fluidized bed furnace. 本発明の実施形態1に係る流動床炉における流動媒体の回収方法の手順を示すフローチャートである。It is a flowchart which shows the procedure of the recovery method of the fluidized medium in the fluidized bed furnace which concerns on Embodiment 1 of this invention. 上記流動床炉における流動媒体の回収方法の抜出工程後に炉底板上に残存した流動媒体を示す模式図である。It is a schematic diagram which shows the fluidized medium which remained on the furnace bottom plate after the extraction process of the method of recovering a fluidized bed in the said fluidized bed furnace. 本発明の実施形態2における流動床炉の構成を模式的に示す図である。It is a figure which shows typically the structure of the fluidized bed furnace in Embodiment 2 of this invention.

以下、図面に基づいて、本発明の実施形態に係る流動床炉における流動媒体の回収方法を詳細に説明する。 Hereinafter, a method for recovering a fluidized medium in a fluidized bed furnace according to an embodiment of the present invention will be described in detail with reference to the drawings.

(実施形態1)
<流動床式ガス化溶融炉の構成>
まず、本発明の実施形態1に係る流動床炉における流動媒体の回収方法を、図1〜図5を参照して説明する。はじめに、本回収方法が実施される流動床式ガス化溶融炉1の構成を、図1〜図3を参照して説明する。
(Embodiment 1)
<Composition of fluidized bed gasification and melting furnace>
First, a method for recovering a fluidized medium in a fluidized bed furnace according to a first embodiment of the present invention will be described with reference to FIGS. 1 to 5. First, the configuration of the fluidized bed type gasification melting furnace 1 in which the present recovery method is carried out will be described with reference to FIGS. 1 to 3.

図1に示すように、本実施形態における流動床式ガス化溶融炉1は、流動床式ガス化炉10と、旋回流溶融炉20と、ダクト30と、を主に備えている。以下、これらの構成要素についてそれぞれ説明する。 As shown in FIG. 1, the fluidized bed type gasification and melting furnace 1 in the present embodiment mainly includes a fluidized bed type gasification furnace 10, a swirling flow melting furnace 20, and a duct 30. Hereinafter, each of these components will be described.

流動床式ガス化炉10は、例えば都市ごみ、下水汚泥又は自動車破砕残渣(ASR:Automobile Shredder Residue)等の各種廃棄物を、可燃性ガス(一酸化炭素、水素、炭化水素等)、未燃物(チャー)及び灰に熱分解するための設備である。図1に示すように、流動床式ガス化炉10は、炉本体12と、炉本体12内に充填された流動媒体13と、流動媒体13を炉本体12の外へ抜き出すための抜出口16bが形成された炉底板16と、抜出口16bに接続された抜出管15と、を主に有している。 The fluidized bed gasifier 10 uses, for example, municipal waste, sewage sludge, and various wastes such as automobile crushing residue (ASR: Automobile Shredder Resolution) as combustible gas (carbon monoxide, hydrogen, hydrocarbon, etc.) and unburned. Equipment for thermally decomposing into objects (char) and ash. As shown in FIG. 1, in the fluidized bed gasification furnace 10, the furnace main body 12, the fluidized medium 13 filled in the furnace main body 12, and the outlet 16b for extracting the fluidized medium 13 to the outside of the furnace main body 12b. It mainly has a furnace bottom plate 16 in which the above is formed, and an extraction pipe 15 connected to the extraction outlet 16b.

炉本体12は、上下方向に延びる円筒形状を有している。炉本体12には、廃棄物を炉本体12内に供給するための供給口14と、炉本体12内で発生した可燃性ガスを炉外へ流出させるための流出口11と、流動媒体13を流動させるための流動化ガス(例えば、空気)を風箱18(炉本体12内における炉底板16よりも下側の空間)に導入するための導入口17と、がそれぞれ設けられている。図1に示すように、供給口14は、炉本体12の側部のうち炉底板16よりも上側の部位に設けられている。流出口11は、炉本体12の頂部に設けられている。導入口17は、炉本体12の側部のうち炉底板16よりも下側の部位に設けられている。 The furnace body 12 has a cylindrical shape extending in the vertical direction. The furnace body 12 is provided with a supply port 14 for supplying waste into the furnace body 12, an outflow port 11 for allowing flammable gas generated in the furnace body 12 to flow out of the furnace, and a flow medium 13. An introduction port 17 for introducing the fluidized gas (for example, air) for flowing into the air box 18 (the space below the bottom plate 16 in the furnace body 12) is provided, respectively. As shown in FIG. 1, the supply port 14 is provided in a portion of the side portion of the furnace main body 12 above the furnace bottom plate 16. The outlet 11 is provided at the top of the furnace body 12. The introduction port 17 is provided in a portion of the side portion of the furnace main body 12 below the furnace bottom plate 16.

炉底板16は、炉本体12内の底部側に配置されており、その中央部に流動媒体13の抜出口16bが形成されている。炉底板16における抜出口16bの周囲部分には、多数の散気管16aが貫通している。また図1に示すように、炉底板16は、中央の抜出口16bに向かって下向きに傾斜しており、その傾斜角は、流動媒体13の安息角よりも小さい角度となっている。具体的には、流動媒体13の安息角が35〜40°であるのに対し、炉底板16の傾斜角は10〜30°となっている。なお、図1では、炉底板16の傾斜角が、水平方向(図1中の破線)と炉底板16の下面との間の角として示されているが、水平方向と炉底板16の上面との間の角もこれと同じである。 The furnace bottom plate 16 is arranged on the bottom side in the furnace body 12, and the outlet 16b of the flow medium 13 is formed in the central portion thereof. A large number of air diffusers 16a penetrate the peripheral portion of the outlet 16b in the bottom plate 16. Further, as shown in FIG. 1, the furnace bottom plate 16 is inclined downward toward the central outlet 16b, and the inclination angle thereof is smaller than the angle of repose of the flow medium 13. Specifically, the angle of repose of the flow medium 13 is 35 to 40 °, while the inclination angle of the furnace bottom plate 16 is 10 to 30 °. In FIG. 1, the inclination angle of the furnace bottom plate 16 is shown as an angle between the horizontal direction (broken line in FIG. 1) and the lower surface of the furnace bottom plate 16, but the horizontal direction and the upper surface of the furnace bottom plate 16 The angle between them is the same.

図2及び図3は、散気管16aの構成を詳細に示している。図2に示すように、各散気管16aは、炉底板16を厚さ方向に貫通する直管部16a1と、直管部16a1の上端に接続されたU字管部16a2と、を有している。導入口17(図1)から風箱18に導入された流動化ガスは、直管部16a1内を上昇した後、U字管部16a2の開口から流動媒体13に向けて送り出される(図3中矢印)。 2 and 3 show in detail the configuration of the air diffuser 16a. As shown in FIG. 2, each air diffuser pipe 16a has a straight pipe portion 16a1 penetrating the furnace bottom plate 16 in the thickness direction and a U-shaped pipe portion 16a2 connected to the upper end of the straight pipe portion 16a1. There is. The fluidized gas introduced into the air box 18 from the introduction port 17 (FIG. 1) rises in the straight pipe portion 16a1 and then is sent out toward the flow medium 13 from the opening of the U-shaped pipe portion 16a2 (in FIG. 3). Arrow).

流動媒体13は、例えば珪砂やオリビン砂等の流動砂であり、炉底板16上に充填されている。これにより、図1に示すように、所定の厚さを有する流動層(砂層)が、炉底板16上に形成されている。流動床式ガス化炉10は、流動媒体13が流動した状態で有価金属(例えば、金、銀、銅、鉛又は亜鉛)を含む廃棄物を処理する。 The fluidizing medium 13 is fluid sand such as silica sand or olivine sand, and is filled on the bottom plate 16. As a result, as shown in FIG. 1, a fluidized bed (sand layer) having a predetermined thickness is formed on the furnace bottom plate 16. The fluidized bed gasifier 10 treats waste containing valuable metals (for example, gold, silver, copper, lead or zinc) in a fluidized state of the fluidized medium 13.

抜出管15は、流動媒体13を不燃物と共に炉本体12の外へ抜き出すためのものである。図1に示すように、抜出管15は、炉底板16の抜出口16bに接続された上端部と、炉本体12の外側に位置する下端部と、を有し、炉本体12の底壁部を貫通して上端部から下端部まで上下に延びている。 The extraction pipe 15 is for extracting the flow medium 13 together with the incombustible material to the outside of the furnace body 12. As shown in FIG. 1, the extraction pipe 15 has an upper end portion connected to the extraction port 16b of the furnace bottom plate 16 and a lower end portion located outside the furnace body 12, and has a bottom wall of the furnace body 12. It penetrates the portion and extends vertically from the upper end to the lower end.

旋回流溶融炉20は、流動床式ガス化炉10で発生した可燃性ガスの旋回流100を形成しつつ当該可燃性ガス及び未燃物を完全燃焼させると共に、可燃性ガスに同伴された灰を溶融させる炉である。図1に示すように、旋回流溶融炉20は、可燃性ガスの流入口21及び灰が溶融することにより形成される溶融スラグを炉外へ排出するための出滓口22がそれぞれ設けられた炉本体23を有している。 The swirl flow melting furnace 20 completely burns the combustible gas and the unburned material while forming the swirl flow 100 of the combustible gas generated in the fluidized bed gasification furnace 10, and the ash accompanied by the combustible gas. It is a furnace that melts. As shown in FIG. 1, the swirling flow melting furnace 20 is provided with an inflow port 21 for flammable gas and a slag port 22 for discharging molten slag formed by melting ash to the outside of the furnace. It has a furnace body 23.

流入口21は、炉本体23の側部のうち頂部近傍の部位に設けられており、ダクト30により流動床式ガス化炉10の流出口11に接続されている。また出滓口22は、炉本体23の底部に設けられている。旋回流溶融炉20において可燃性ガスが燃焼することにより発生した排ガスは、旋回流溶融炉20の後段に配置された各種設備(ボイラ、減温塔、バグフィルタ、触媒反応塔等)を通過した後、煙突(図示しない)から大気中に放出される。 The inflow port 21 is provided at a portion near the top of the side portion of the furnace main body 23, and is connected to the outflow port 11 of the fluidized bed gasification furnace 10 by a duct 30. Further, the slag opening 22 is provided at the bottom of the furnace main body 23. The exhaust gas generated by the combustion of the flammable gas in the swirl flow melting furnace 20 has passed through various facilities (boiler, temperature reducing tower, bag filter, catalytic reaction tower, etc.) arranged after the swirl flow melting furnace 20. Later, it is released into the atmosphere from a chimney (not shown).

流動床式ガス化炉10は、循環機構40を有している。循環機構40は、炉本体12の外へ抜き出された流動媒体13を、不燃物から分離した後に炉本体12へ戻すものである。図1に示すように、循環機構40は、抜出スクリュ41と、分級装置42と、循環エレベータ43(搬送部)と、貯留槽44と、第1〜第3搬送経路45,46,47と、を主に有している。 The fluidized bed gasifier 10 has a circulation mechanism 40. The circulation mechanism 40 separates the flow medium 13 extracted from the furnace body 12 from the incombustible material and then returns it to the furnace body 12. As shown in FIG. 1, the circulation mechanism 40 includes a extraction screw 41, a classification device 42, a circulation elevator 43 (transport section), a storage tank 44, and first to third transport paths 45, 46, 47. Mainly has.

抜出スクリュ41は、回転駆動によって炉本体12の底部から流動媒体13を不燃物と共に抜き出すためのものであり、抜出管15の下端部に設けられている。分級装置42は、抜出スクリュ41の下流端に設けられており、篩によって流動媒体13と不燃物とを分離する。なお、流動媒体13から分離された不燃物は、粉砕された後に旋回流溶融炉20においてスラグ化され、又は系外へ搬出される。 The extraction screw 41 is for extracting the flow medium 13 together with the incombustible material from the bottom portion of the furnace main body 12 by rotational driving, and is provided at the lower end portion of the extraction pipe 15. The classification device 42 is provided at the downstream end of the extraction screw 41, and separates the flow medium 13 and the incombustible material by a sieve. The incombustible material separated from the flow medium 13 is crushed and then slagged in the swirling flow melting furnace 20 or carried out of the system.

循環エレベータ43は、分級装置42により不燃物が除去された流動媒体13を、所定の高さまで搬送するものである。図1に示すように、循環エレベータ43の下部には流動媒体13の入口43Aが設けられており、当該入口43Aは第1搬送経路45により分級装置42の出口42A(流動媒体13の出口)と接続されている。また循環エレベータ43の上部には、流動媒体13の出口43Bが設けられている。 The circulation elevator 43 conveys the flow medium 13 from which incombustibles have been removed by the classification device 42 to a predetermined height. As shown in FIG. 1, an inlet 43A of the flow medium 13 is provided in the lower part of the circulation elevator 43, and the inlet 43A and the outlet 42A of the classification device 42 (the outlet of the flow medium 13) are provided by the first transport path 45. It is connected. An outlet 43B of the flow medium 13 is provided above the circulation elevator 43.

貯留槽44は、循環エレベータ43により上方に搬送された流動媒体13を貯留するための槽である。図1に示すように、循環エレベータ43の出口43Bには第2搬送経路46の上端が接続されており、当該第2搬送経路46の途中に貯留槽44が配置されている。これにより、循環エレベータ43によって上方に搬送された流動媒体13を、第2搬送経路46を通じて貯留槽44へ落下させ、当該貯留槽44において貯留することができる。 The storage tank 44 is a tank for storing the flow medium 13 carried upward by the circulation elevator 43. As shown in FIG. 1, the upper end of the second transport path 46 is connected to the outlet 43B of the circulation elevator 43, and the storage tank 44 is arranged in the middle of the second transport path 46. As a result, the flow medium 13 transported upward by the circulation elevator 43 can be dropped into the storage tank 44 through the second transport path 46 and stored in the storage tank 44.

また図1に示すように、第3搬送経路47は、一端が第2搬送経路46における貯留槽44よりも上側の部位に接続されると共に、他端が炉本体12の側部に接続されている。これにより、循環エレベータ43の出口43Bから出た流動媒体13を、第3搬送経路47を通じて炉本体12に戻すことができる。なお、図示は省略するが、循環機構40は、循環エレベータ43の出口43Bから出た流動媒体13を、貯留槽44へ導くか又は炉本体12へ導くかを切り替える切替部(バルブ等)をさらに有していてもよい。 Further, as shown in FIG. 1, one end of the third transport path 47 is connected to a portion of the second transport path 46 above the storage tank 44, and the other end is connected to a side portion of the furnace body 12. There is. As a result, the flow medium 13 exiting the outlet 43B of the circulation elevator 43 can be returned to the furnace body 12 through the third transport path 47. Although not shown, the circulation mechanism 40 further has a switching unit (valve or the like) for switching whether the flow medium 13 exiting the outlet 43B of the circulation elevator 43 is guided to the storage tank 44 or the furnace body 12. You may have.

<流動床炉における流動媒体の回収方法>
次に、本実施形態に係る流動床炉における流動媒体の回収方法を、図4に示すフローチャートに従って説明する。本回収方法は、以下に説明する通り、例えば流動床式ガス化炉10のメンテナンス時等、流動床式ガス化炉10を停止した時に炉本体12内から流動媒体13を回収する方法である。
<Recovery method of fluidized bed in fluidized bed furnace>
Next, a method of recovering the fluidized medium in the fluidized bed furnace according to the present embodiment will be described with reference to the flowchart shown in FIG. As described below, this recovery method is a method of recovering the fluidized medium 13 from the inside of the furnace main body 12 when the fluidized bed gasifier 10 is stopped, for example, during maintenance of the fluidized bed gasifier 10.

まず、流動床式ガス化炉10のメンテナンス前、すなわち流動床式ガス化炉10の定常運転(工程S10)においては、散気管16aにより送り込まれる流動化ガス(例えば、空気)により流動媒体13が流動した状態で、廃棄物が供給口14から炉本体12内に供給される。そして、当該廃棄物は、炉本体12内で加熱されることにより可燃性ガス、未燃物及び灰に熱分解される。ここで、廃棄物中には、貴金属(金、銀、銅等)や重金属(鉛、亜鉛等)等の有価金属が相当量含まれている。 First, before the maintenance of the fluidized bed gasifier 10, that is, in the steady operation of the fluidized bed gasifier 10 (step S10), the fluidized gas (for example, air) sent by the diffuser pipe 16a causes the fluidized medium 13 to move. The waste is supplied into the furnace body 12 from the supply port 14 in a fluidized state. Then, the waste is thermally decomposed into flammable gas, unburned matter and ash by being heated in the furnace body 12. Here, the waste contains a considerable amount of valuable metals such as precious metals (gold, silver, copper, etc.) and heavy metals (lead, zinc, etc.).

流動床式ガス化炉10で発生した可燃性ガスは、未燃物及び灰と共にダクト30を通じて旋回流溶融炉20内に流入する。そして、当該旋回流溶融炉20において、可燃性ガス及び未燃物が完全燃焼すると共に灰が溶融する。この定常運転の間、循環機構40を作動させることにより、炉本体12内に充填された流動媒体13を不燃物と共に炉外へ抜き出すと共に、不燃物が除去された流動媒体13を炉本体12に戻す。 The flammable gas generated in the fluidized bed gasifier 10 flows into the swirling flow melting furnace 20 through the duct 30 together with the unburned material and ash. Then, in the swirling flow melting furnace 20, the combustible gas and the unburned material are completely burned and the ash is melted. During this steady operation, by operating the circulation mechanism 40, the flow medium 13 filled in the furnace body 12 is taken out of the furnace together with the incombustibles, and the flow medium 13 from which the incombustibles have been removed is brought into the furnace body 12. return.

次に、流動床式ガス化炉10のメンテナンス時期が到来すると(工程S20のYES)、まず、炉本体12への廃棄物の供給を停止し(工程S30)、続いて風箱18への流動化ガスの供給も停止する(工程S40)。その後、炉本体12内に充填された流動媒体13を、当該炉本体12の外へ抜き出す工程(抜出工程S50)が行われる。 Next, when the maintenance time for the fluidized bed gasifier 10 arrives (YES in step S20), first, the supply of waste to the furnace body 12 is stopped (step S30), and then the flow to the air box 18 is reached. The supply of gasification is also stopped (step S40). After that, a step of extracting the flow medium 13 filled in the furnace body 12 to the outside of the furnace body 12 (extraction step S50) is performed.

抜出工程S50では、炉本体12内に充填された流動媒体13を、抜出口16bを通じて重力により炉本体12の外へ抜き出す。具体的には、抜出スクリュ41を回転駆動させることにより、炉本体12内に充填された流動媒体13を抜出管15を通じて炉本体12の外へ抜き出す。 In the extraction step S50, the flow medium 13 filled in the furnace body 12 is extracted to the outside of the furnace body 12 by gravity through the extraction port 16b. Specifically, by rotationally driving the extraction screw 41, the flow medium 13 filled in the furnace body 12 is extracted out of the furnace body 12 through the extraction pipe 15.

そして、炉外へ抜き出された流動媒体13は、分級装置42で不燃物と分離され、循環エレベータ43により上方に搬送された後、貯留槽44に貯留される。つまり、抜出工程S50では、炉本体12から抜き出された流動媒体13が、炉本体12に戻されず、全て貯留槽44に貯留される。 Then, the flow medium 13 extracted to the outside of the furnace is separated from the incombustible material by the classification device 42, transported upward by the circulation elevator 43, and then stored in the storage tank 44. That is, in the extraction step S50, the flow medium 13 extracted from the furnace body 12 is not returned to the furnace body 12, but is all stored in the storage tank 44.

図5は、上記抜出工程S50の後における炉本体12内の様子(炉底板16の近傍の様子)を模式的に示している。上述の通り、炉底板16は、流動媒体13の安息角よりも小さい角度θで抜出口16bに向かって下向きに傾斜している。このため、図5に示すように、上記抜出工程S50で炉本体12内の流動媒体13が全て炉外へ抜き出されることはなく、上記抜出工程S50の後に炉底板16上において一部の流動媒体13が残存する。より詳細には、炉底板16の上面と散気管16aのU字管部16a2との間には、流動化ガスの影響を受けにくい領域(不動層)が存在し、当該不動層において一定量の流動媒体13が残存する。以下、上述のように抜出工程S50の後に炉底板16上に残存した流動媒体13を、「炉底媒体(炉底砂)」とも称する。 FIG. 5 schematically shows the inside of the furnace body 12 (the state near the bottom plate 16) after the extraction step S50. As described above, the furnace bottom plate 16 is inclined downward toward the outlet 16b at an angle θ smaller than the angle of repose of the flow medium 13. Therefore, as shown in FIG. 5, the flow medium 13 in the furnace body 12 is not completely extracted to the outside of the furnace in the extraction step S50, and a part of the flow medium 13 in the furnace body 12 is partially extracted on the furnace bottom plate 16 after the extraction step S50. The flow medium 13 of the above remains. More specifically, between the upper surface of the furnace bottom plate 16 and the U-shaped pipe portion 16a2 of the air diffuser pipe 16a, there is a region (immobile layer) that is not easily affected by the fluidized gas, and a certain amount of the immovable layer exists. The flow medium 13 remains. Hereinafter, the flow medium 13 remaining on the furnace bottom plate 16 after the extraction step S50 as described above is also referred to as “fire bottom medium (fire bottom sand)”.

本発明者等は、この炉底媒体中に廃棄物由来の有価金属(金、銀、銅、鉛、亜鉛等)が高濃度に含まれていることを新たに発見した。すなわち、炉底媒体は、流動媒体13と有価金属の混合物である。本発明者等の知見によると、炉底媒体は、上記抜出工程S50で貯留槽44に貯留された流動媒体13と比較して有価金属の濃度が大幅に高く、その結果かさ密度(g/cm)も大きくなっている。なお、上記抜出工程S50の前に炉本体12内に充填された流動媒体13のうち、大半(例えば99%)が上記抜出工程S50で貯留槽44に送られ、残りが炉底板16上に炉底媒体として残存する。 The present inventors have newly discovered that valuable metals derived from waste (gold, silver, copper, lead, zinc, etc.) are contained in a high concentration in the bottom medium. That is, the bottom medium is a mixture of the flow medium 13 and the valuable metal. According to the findings of the present inventors, the furnace bottom medium has a significantly higher concentration of valuable metals than the flow medium 13 stored in the storage tank 44 in the extraction step S50, resulting in a bulk density (g / g /). cm 3 ) is also larger. Of the fluid medium 13 filled in the furnace body 12 before the extraction step S50, most (for example, 99%) is sent to the storage tank 44 in the extraction step S50, and the rest is on the furnace bottom plate 16. Remains as a bottom medium.

このため、本実施形態に係る回収方法では、上記抜出工程S50に続く回収工程S60において、上記抜出工程S50で炉本体12内から抜き出した流動媒体13(貯留槽44に貯留された流動媒体13)と分離した状態で、炉底媒体を別途回収する。具体的には、上記抜出工程S50が完了した後に作業者が炉本体12内に立ち入り、炉底媒体を採取することによって当該炉底媒体を炉本体12内から直接回収する。 Therefore, in the recovery method according to the present embodiment, in the recovery step S60 following the extraction step S50, the flow medium 13 (flow medium stored in the storage tank 44) extracted from the furnace body 12 in the extraction step S50. Separately collect the bottom medium in a state separated from 13). Specifically, after the extraction step S50 is completed, an operator enters the furnace body 12 and collects the bottom medium to directly recover the bottom medium from the inside of the furnace body 12.

その後、作業者は、炉本体12内の清掃や点検等のメンテナンス作業を行う(工程S70)。なお、炉底媒体の回収前に炉内の清掃、点検等が行われてもよいし、炉底媒体の回収と炉内のメンテナンス作業とが併行して行われてもよい。 After that, the worker performs maintenance work such as cleaning and inspection of the inside of the furnace main body 12 (step S70). The inside of the furnace may be cleaned and inspected before the bottom medium is recovered, or the recovery of the bottom medium and the maintenance work inside the furnace may be performed in parallel.

このように、本実施形態に係る回収方法では、流動床式ガス化炉10のメンテナンスのタイミングを利用して、廃棄物由来の有価金属を高濃度に含んだ流動媒体13を回収する。下記の表1は、本実施形態における流動床式ガス化炉10(図1)と同様の構成を備えた複数の廃棄物処理施設(施設A〜E)において、抜出工程S50で貯留槽44に回収した流動媒体13の有価金属濃度(mg/kg)と、抜出工程S50の後に炉底板16上に残存した炉底媒体の有価金属濃度(mg/kg)と、を調査した結果を示している。表1から明らかなように、炉底媒体は、貯留槽44に回収した流動媒体13に比較して、有価金属(Au、Ag、Cu)の濃度が顕著に高くなっている。なお、施設Aについては時期を分けて2回調査を行い、各調査結果を表1においてそれぞれ(1),(2)で示している。 As described above, in the recovery method according to the present embodiment, the fluidized medium 13 containing a high concentration of valuable metal derived from waste is recovered by utilizing the timing of maintenance of the fluidized bed gasifier 10. Table 1 below shows the storage tank 44 in the extraction step S50 in a plurality of waste treatment facilities (facilities A to E) having the same configuration as the fluidized bed gasifier 10 (FIG. 1) in the present embodiment. The results of investigating the valuable metal concentration (mg / kg) of the fluidized bed 13 recovered in the above and the valuable metal concentration (mg / kg) of the furnace bottom medium remaining on the furnace bottom plate 16 after the extraction step S50 are shown. ing. As is clear from Table 1, the concentration of valuable metals (Au, Ag, Cu) in the bottom medium is significantly higher than that in the flow medium 13 recovered in the storage tank 44. For facility A, two surveys were conducted at different times, and the results of each survey are shown in Table 1 in (1) and (2), respectively.

Figure 2021025699
Figure 2021025699

また下記の表2は、施設A,Bについて、抜出工程S50で貯留槽44に回収した流動媒体13のかさ密度(g/cm)と、炉底媒体のかさ密度(g/cm)と、を調査した結果を示している。表2から明らかなように、貯留槽44に回収した流動媒体13に比べて炉底媒体の方がかさ密度が大きくなり、これは有価金属濃度の差に起因するものと考えられる。 Table 2 below also facilities A, for B, the bulk density of the flowing medium 13 recovered in the storage tank 44 by an extraction step S50 (g / cm 3), bulk density (g / cm 3) of the furnace bottom medium The result of the investigation is shown. As is clear from Table 2, the bulk density of the bottom medium is higher than that of the flow medium 13 recovered in the storage tank 44, which is considered to be due to the difference in the concentration of valuable metals.

Figure 2021025699
Figure 2021025699

最後に、上記回収工程S60で回収した流動媒体13(炉底媒体)から有価金属を分離する(分離工程S80)。具体的には、熱処理、化学処理又は物理選別等の方法により、炉底媒体に含まれる有価金属を流動媒体13から分離する。熱処理としては、例えば、溶融処理(製錬)、焼成処理又は塩化揮発等が挙げられる。化学処理としては、例えば、酸等の溶媒抽出がある。また物理選別としては、例えば、磁力選別、渦電流選別、静電選別又は比重選別等が挙げられる。 Finally, the valuable metal is separated from the flow medium 13 (furnace bottom medium) recovered in the recovery step S60 (separation step S80). Specifically, the valuable metal contained in the furnace bottom medium is separated from the flow medium 13 by a method such as heat treatment, chemical treatment, or physical sorting. Examples of the heat treatment include melting treatment (smelting), firing treatment, chloride volatilization, and the like. Examples of the chemical treatment include solvent extraction of an acid or the like. Examples of the physical sorting include magnetic force sorting, eddy current sorting, electrostatic sorting, specific gravity sorting, and the like.

(実施形態2)
次に、本発明の実施形態2に係る流動床炉における流動媒体の回収方法を、図6を主に参照して説明する。実施形態2に係る流動床炉における流動媒体の回収方法は、基本的に上記実施形態1に係る流動床炉における流動媒体の回収方法と同様であるが、回収工程S60の具体的方法において上記実施形態1と異なっている。以下、上記実施形態1と異なる点についてのみ説明する。
(Embodiment 2)
Next, a method for recovering the fluidized medium in the fluidized bed furnace according to the second embodiment of the present invention will be described mainly with reference to FIG. The method for recovering the fluidized medium in the fluidized bed furnace according to the second embodiment is basically the same as the method for recovering the fluidized medium in the fluidized bed furnace according to the first embodiment, but the specific method in the recovery step S60 is described above. It is different from Form 1. Hereinafter, only the differences from the first embodiment will be described.

図6は、実施形態2における流動床式ガス化溶融炉1Aの構成を模式的に示している。実施形態2における流動床式ガス化炉10Aは、上記実施形態1における流動床式ガス化炉10(図1)の構成に加えて、流動媒体13を循環機構40の外へ抜き出して回収する回収機構50をさらに備えている。 FIG. 6 schematically shows the configuration of the fluidized bed type gasification melting furnace 1A in the second embodiment. In the fluidized bed gasification furnace 10A of the second embodiment, in addition to the configuration of the fluidized bed gasification furnace 10 (FIG. 1) of the first embodiment, the fluidized bed 13 is taken out of the circulation mechanism 40 and recovered. It further includes a mechanism 50.

図6に示すように、回収機構50は、第1搬送経路45に接続された回収経路51と、回収経路51上に設けられた第1バルブ52と、第1搬送経路45上において回収経路51の接続部P1よりも下流側に設けられた第2バルブ53と、を有している。第1バルブ52及び第2バルブ53は、制御部(図示しない)により自動制御されるものであってもよいし、手動制御されるものであってもよい。 As shown in FIG. 6, the recovery mechanism 50 includes a recovery path 51 connected to the first transport path 45, a first valve 52 provided on the recovery path 51, and a recovery path 51 on the first transport path 45. It has a second valve 53 provided on the downstream side of the connecting portion P1 of the above. The first valve 52 and the second valve 53 may be automatically controlled by a control unit (not shown) or may be manually controlled.

実施形態2における抜出工程S50では、第1バルブ52を閉じ且つ第2バルブ53を開いた状態で、抜出スクリュ41を回転駆動させる。これにより、炉本体12から炉外へ抜き出された流動媒体13は、回収経路51内に入らず、循環エレベータ43により上方に搬送された後、上記実施形態1と同様に貯留槽44に供給される。 In the extraction step S50 in the second embodiment, the extraction screw 41 is rotationally driven with the first valve 52 closed and the second valve 53 open. As a result, the flow medium 13 extracted from the furnace body 12 to the outside of the furnace does not enter the recovery path 51, is transported upward by the circulation elevator 43, and then is supplied to the storage tank 44 in the same manner as in the first embodiment. Will be done.

続いて、実施形態2における回収工程S60では、第1バルブ52を開状態に切り替えると共に、第2バルブ53を閉状態に切り替える。そして、作業者が炉本体12内に立ち入り、炉底板16上に残存した流動媒体13を抜出口16bから抜出管15内に落下させる。その後、抜出スクリュ41を回転駆動させる。 Subsequently, in the recovery step S60 in the second embodiment, the first valve 52 is switched to the open state and the second valve 53 is switched to the closed state. Then, an operator enters the furnace main body 12 and drops the flow medium 13 remaining on the furnace bottom plate 16 from the outlet 16b into the extraction pipe 15. After that, the extraction screw 41 is rotationally driven.

これにより、上記抜出工程S50の後に炉底板16上に残存した流動媒体13は、炉本体12の外へ排出された後、貯留槽44側へ搬送されず、貯留槽44と異なる場所(回収経路51)で回収される。その結果、上記実施形態1と同様に、上記抜出工程S50で貯留槽44に貯留した流動媒体13と分離した状態で、炉底媒体を別途回収することができる。 As a result, the flow medium 13 remaining on the furnace bottom plate 16 after the extraction step S50 is discharged to the outside of the furnace body 12 and then is not transported to the storage tank 44 side, and is not transported to the storage tank 44 side (recovery). It is collected by route 51). As a result, similarly to the first embodiment, the bottom medium can be separately recovered in a state of being separated from the flow medium 13 stored in the storage tank 44 in the extraction step S50.

上記の通り開示された実施形態は、全ての点で例示であって、制限的なものではないと解されるべきである。本発明の範囲は、上記した説明ではなくて特許請求の範囲により示され、特許請求の範囲と均等の意味及び範囲内での全ての変更が含まれることが意図される。 It should be understood that the embodiments disclosed as described above are exemplary in all respects and are not restrictive. The scope of the present invention is shown by the scope of claims rather than the above description, and it is intended to include all modifications within the meaning and scope equivalent to the scope of claims.

すなわち、以下のような変形例も、本発明の範囲に含まれる。 That is, the following modifications are also included in the scope of the present invention.

上記実施形態2では、第1搬送経路45の途中で炉底媒体を回収する場合を説明したが、循環機構40における別の場所(例えば、循環エレベータ43等)において炉底媒体の回収口が設けられてもよい。 In the second embodiment, the case where the bottom medium is collected in the middle of the first transport path 45 has been described, but the collection port for the bottom medium is provided at another place (for example, the circulation elevator 43) in the circulation mechanism 40. May be done.

上記実施形態2では、作業者が炉底媒体を抜出管15内に落下させる場合を説明したが、散気管16aから流動化ガスを供給することにより炉底媒体を抜出管15内に落下させてもよい。 In the second embodiment, the case where the operator drops the bottom medium into the extraction pipe 15 has been described, but the bottom medium is dropped into the extraction pipe 15 by supplying the fluidized gas from the air diffuser pipe 16a. You may let me.

上記実施形態1,2では、廃棄物をガス化する流動床式ガス化炉10,10Aを流動床炉の一例として説明したが、廃棄物を焼却処理する流動床式焼却炉においても本発明の流動媒体の回収方法を適用することができる。 In the first and second embodiments, the fluidized bed gasifiers 10 and 10A for gasifying waste have been described as an example of the fluidized bed incinerator, but the fluidized bed incinerator for incinerating waste is also the present invention. A method for recovering a fluidized bed can be applied.

1,1A 流動床式ガス化溶融炉
10,10A 流動床式ガス化炉(流動床炉)
12 炉本体
13 流動媒体
16 炉底板
16b 抜出口
40 循環機構
43 循環エレベータ(搬送部)
44 貯留槽
θ 角度
1,1A fluidized bed gasification and melting furnace 10,10A fluidized bed gasification furnace (fluidized bed furnace)
12 Furnace body 13 Flow medium 16 Furnace bottom plate 16b Extraction outlet 40 Circulation mechanism 43 Circulation elevator (conveyor)
44 Storage tank θ angle

Claims (3)

炉本体と、前記炉本体内に充填された流動媒体と、前記流動媒体を前記炉本体の外へ抜き出すための抜出口が形成されると共に前記抜出口に向かって前記流動媒体の安息角よりも小さい角度で下向きに傾斜する炉底板と、を備え、前記流動媒体が流動した状態で有価金属を含む廃棄物を焼却処理或いはガス化する流動床炉において、前記流動床炉を停止した時に前記炉本体内から前記流動媒体を回収する方法であって、
前記炉本体内に充填された前記流動媒体を、前記抜出口を通じて重力により前記炉本体の外へ抜き出す抜出工程と、
前記抜出工程の後に前記炉底板上に残存した前記流動媒体を、前記抜出工程で前記炉本体内から抜き出した前記流動媒体と分離した状態で回収する回収工程と、を備えた、流動床炉における流動媒体の回収方法。
A furnace body, a flow medium filled in the furnace body, and an outlet for extracting the flow medium to the outside of the furnace body are formed, and at the same time, from the rest angle of the flow medium toward the outlet. In a flow bed furnace provided with a furnace bottom plate that inclines downward at a small angle and incinerates or gasifies waste containing valuable metals while the flow medium is flowing, the furnace is said to be stopped when the flow bed furnace is stopped. A method of recovering the fluid medium from the main body,
The extraction step of extracting the flow medium filled in the furnace body to the outside of the furnace body by gravity through the extraction port, and
A fluidized bed including a recovery step of recovering the fluidized medium remaining on the furnace bottom plate after the extraction step in a state of being separated from the flow medium extracted from the inside of the furnace body in the extraction step. A method for recovering a fluidized medium in a furnace.
前記回収工程で回収した前記流動媒体から有価金属を分離する分離工程をさらに備えた、請求項1に記載の流動床炉における流動媒体の回収方法。 The method for recovering a fluidized medium in a fluidized bed furnace according to claim 1, further comprising a separation step of separating valuable metals from the fluidized medium recovered in the recovery step. 前記流動床炉は、前記炉本体の外へ抜き出された前記流動媒体を前記炉本体へ戻す循環機構であって、前記流動媒体を搬送する搬送部と、前記搬送部により搬送された前記流動媒体を貯留する貯留槽と、を有する前記循環機構をさらに備え、
前記抜出工程では、前記炉本体の外へ抜き出された前記流動媒体を、前記搬送部により搬送すると共に前記貯留槽に供給し、
前記回収工程では、前記炉底板上に残存した前記流動媒体を前記炉本体の外へ排出した後、前記貯留槽と異なる場所で回収する、請求項1又は2に記載の流動床炉における流動媒体の回収方法。
The fluidized bed furnace is a circulation mechanism for returning the fluidized medium extracted to the outside of the furnace body to the furnace body, and is a transport unit for transporting the fluidized medium and the flow transported by the transport unit. Further comprising the circulation mechanism having a storage tank for storing a medium,
In the extraction step, the flow medium extracted to the outside of the furnace body is conveyed by the transport unit and supplied to the storage tank.
The fluidized bed in the fluidized bed furnace according to claim 1 or 2, wherein in the recovery step, the fluidized medium remaining on the bottom plate is discharged to the outside of the furnace body and then recovered at a place different from the storage tank. How to collect.
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