JP2020180402A - Manufacturing method of fiber molded product, and fiber molded product - Google Patents

Manufacturing method of fiber molded product, and fiber molded product Download PDF

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JP2020180402A
JP2020180402A JP2019084843A JP2019084843A JP2020180402A JP 2020180402 A JP2020180402 A JP 2020180402A JP 2019084843 A JP2019084843 A JP 2019084843A JP 2019084843 A JP2019084843 A JP 2019084843A JP 2020180402 A JP2020180402 A JP 2020180402A
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molded product
fiber
eggshell powder
molding
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裕也 櫻井
Hironari Sakurai
裕也 櫻井
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Oki Yuriko
Samurai Trading Inc
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Samurai Trading Inc
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Abstract

To provide a fiber molded product with greatly reduced use amount of fibrous materials.SOLUTION: The manufacturing method of a fiber molded product by molding a fibrous material for formation of a fiber molded product includes a mixing step of mixing a fibrous material and an egg shell powder for formation of a molding raw material and a molding process of molding the molding raw material to a desired shape.SELECTED DRAWING: Figure 1

Description

本発明は、繊維を糸状に撚らずに、そのまま成形して繊維成形品を生成する繊維成形品の製造方法等に関する。 The present invention relates to a method for producing a fiber-molded product, which produces a fiber-molded product by molding the fiber as it is without twisting it into a thread.

繊維成形品とは、バラバラになった微細繊維を糸として撚ることなく、そのまま膠着させることで、所望の形に成形したものである。繊維成形品には様々なものが存在するが、例えば、紙、パルプモールド等が代表的であり、様々な産業分野において利用されている。 The fiber-molded product is a product formed into a desired shape by sticking the disjointed fine fibers as threads without twisting them. There are various kinds of fiber molded products, for example, paper, pulp mold and the like are typical, and they are used in various industrial fields.

紙は、植物繊維やその他の繊維を膠着させてシート状に成形したものである。紙の種類には、薄くて軽い洋紙(これを紙と表現する場合もある)、厚くて堅い板紙、和紙、不織布等が存在する。洋紙は、柔軟性があるものが多く、新聞紙、印刷用紙、包装用紙、衛生用紙、雑種紙等が含まれる。板紙は、多層抄きによって剛性を高めたものが多く、段ボール原紙、紙器用板紙、建材原紙、紙管原紙、ワンプ等が含まれる。和紙は、洋紙の植物繊維の繊維長(1mm〜5mm)よりも長い、15mm〜25mmの植物繊維を絡めたものが多く、その分、洋紙よりも硬くなる。 Paper is formed into a sheet by sticking plant fibers and other fibers together. Types of paper include thin and light Western paper (sometimes referred to as paper), thick and hard paperboard, Japanese paper, and non-woven fabric. Many foreign papers are flexible, and include newspapers, printing papers, wrapping papers, sanitary papers, hybrid papers, and the like. Most of the paperboards have increased rigidity by multi-layer papermaking, and include corrugated cardboard base paper, paperboard for paper containers, building material base paper, paper tube base paper, wamps, and the like. Many Japanese papers are entwined with plant fibers of 15 mm to 25 mm, which is longer than the fiber length (1 mm to 5 mm) of the plant fibers of Western paper, and are harder than Western paper by that amount.

不織布は、紙と布の中間的な繊維成形品となり、5mm〜100mm程度の繊維を、熱・機械的または化学的な作用によって接着または絡み合わせる事でシート状(布状)にしたものである。不織布は、広義のフェルトを含み、紙の範疇に含まれる場合もある。 The non-woven fabric is an intermediate fiber molded product between paper and cloth, and is made into a sheet (cloth) by adhering or entwining fibers of about 5 mm to 100 mm by thermal, mechanical or chemical action. .. Nonwoven fabrics include felt in a broad sense and may be included in the category of paper.

パルプモールドは、新聞・雑誌・段ボール・牛乳パックなどの古紙を、再度、植物繊維に離解してから、これを水に溶かして金網(金型)で抄き上げて成形し、乾燥させたものである。パルプモールドは、容器や緩衝材などに多く使われている(例えば、特許文献1参照)。 Pulp mold is made by separating used paper such as newspapers, magazines, corrugated cardboard, and milk cartons into plant fibers again, dissolving it in water, making it with a wire net (mold), molding it, and drying it. is there. Pulp molds are often used in containers, cushioning materials, etc. (see, for example, Patent Document 1).

特開2011−208289号JP 2011-208289

繊維成形品の原材料となる繊維には、主として、植物繊維、動物繊維、化学繊維、金属繊維の四種類が存在するが、その中でも、用途や適用範囲の広さから、植物繊維と化学繊維が多量に利用される。 There are four main types of fibers that are used as raw materials for fiber molded products: plant fibers, animal fibers, chemical fibers, and metal fibers. Among them, plant fibers and chemical fibers are selected because of their wide range of applications and applications. Used in large quantities.

しかし、化学繊維は、廃棄時の焼却処理や埋立て処理における環境破壊等の観点から、その利用が規制されつつある。植物繊維の多くは、木材パルプや古紙パルプが用いられるが、木材パルプの場合、針葉樹や広葉樹を伐採する必要が在るため、環境破壊が問題となる。これらの結果として、古紙の重要性が高まってきているが、需要の増大に伴い、古紙の流通量が不足し、古紙の流通価格(出願時現在約20円/kg)が高騰するという問題も生じている。 However, the use of chemical fibers is being regulated from the viewpoint of environmental destruction in incineration treatment at the time of disposal and landfill treatment. Wood pulp and used paper pulp are used for most of the plant fibers, but in the case of wood pulp, it is necessary to cut down coniferous trees and broad-leaved trees, so environmental destruction becomes a problem. As a result of these, the importance of used paper is increasing, but with the increase in demand, the distribution volume of used paper is insufficient, and the distribution price of used paper (about 20 yen / kg at the time of filing) also rises. It is happening.

本発明は上記問題点に鑑みてなされたものであり、繊維の使用量を削減可能な繊維成形品の製造方法等を提供するものである。 The present invention has been made in view of the above problems, and provides a method for producing a fiber molded product capable of reducing the amount of fibers used.

上記目的を達成する本発明は、繊維状物質を成形して繊維成形品を生成する繊維成形品の製造方法であって、繊維状物質及び卵殻粉末を混合して成形原料を生成する混合工程と、前記成形原料を所望形状に成形する成形工程と、を備えることを特徴とする、繊維成形品の製造方法である。 The present invention that achieves the above object is a method for producing a fibrous molded product by molding a fibrous substance to produce a fibrous molded product, which comprises a mixing step of mixing the fibrous substance and eggshell powder to produce a molding raw material. , A method for producing a fiber-molded article, which comprises a molding step of molding the molding raw material into a desired shape.

また、上記目的を達成する本発明は、繊維状物質と卵殻粉末を含有することを特徴とする繊維成形品である。 Further, the present invention that achieves the above object is a fiber molded product containing a fibrous substance and eggshell powder.

本発明によれば、繊維状物質の使用量が大幅に削減された繊維成形品を得ることができるという優れた効果を奏し得る。 According to the present invention, it is possible to obtain an excellent effect that a fiber molded product in which the amount of the fibrous substance used is significantly reduced can be obtained.

本実施形態の繊維成形品に含有させる卵殻粉末の製造方法を示す工程図。The process chart which shows the manufacturing method of the eggshell powder contained in the fiber molded article of this embodiment. 本実施形態のパルプモールドの製造方法を示す工程図。The process drawing which shows the manufacturing method of the pulp mold of this embodiment. 本実施形態のパルプモールドの製造方法で用いる成形装置を示す正面図。The front view which shows the molding apparatus used in the manufacturing method of the pulp mold of this embodiment. 本実施形態のパルプモールドの製造方法で作成したサンプル成形品の写真。A photograph of a sample molded product produced by the method for manufacturing a pulp mold of the present embodiment. 本実施形態の製紙方法を示す工程図。The process chart which shows the papermaking method of this embodiment.

以下、本発明の実施の形態について添付図面を参照して説明する。なお、本実施形態では、繊維成形品の製造方法として、パルプモールドの製造方法と、製紙方法について例示するが、その前に、これらの製造方法で用いる卵殻粉末の製造方法について説明する。 Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. In the present embodiment, a pulp mold manufacturing method and a paper manufacturing method will be exemplified as a method for manufacturing the fiber molded product, but before that, the eggshell powder manufacturing method used in these manufacturing methods will be described.

<卵殻粉末の製造方法> <Manufacturing method of eggshell powder>

図1を参照して、卵殻粉末の製造方法について説明する。卵殻粉末の製造方法は、割卵工程、洗浄工程、卵殻膜分離工程、微粉砕工程を有する。割卵工程では、鶏卵を割卵機によって内容物(卵)と卵殻に分離する。内容物(卵黄と卵白等)は、食品工場等において様々な食品に利用される。洗浄工程では、卵殻を水等によって洗浄する。洗浄工程の後、数ミリ程度の粒径となるように卵殻を粗く粉砕しても良い。卵殻膜分離工程では、卵殻と卵殻膜を分離する。卵殻と卵殻膜の分離方法は様々あるが、例えば、卵殻及び卵殻膜を液漕中で撹拌して分離する方法や、卵殻を塩酸、硫酸、酢酸等の弱酸性水溶液に浸漬して卵殻膜を剥離する方法や、卵殻と卵殻膜との比重差を利用して卵殻膜を分離する方法等を採用できる。 A method for producing eggshell powder will be described with reference to FIG. The method for producing eggshell powder includes an egg breaking step, a washing step, an eggshell membrane separation step, and a fine pulverization step. In the egg breaking process, chicken eggs are separated into contents (eggs) and eggshells by an egg breaking machine. The contents (egg yolk and egg white, etc.) are used for various foods in food factories and the like. In the washing step, the eggshell is washed with water or the like. After the washing step, the eggshell may be roughly crushed so as to have a particle size of about several millimeters. In the eggshell membrane separation step, the eggshell and the eggshell membrane are separated. There are various methods for separating eggshell and eggshell membranes. For example, the eggshell and eggshell membranes are separated by stirring in a liquid tank, or the eggshell membranes are immersed in a weakly acidic aqueous solution such as hydrochloric acid, sulfuric acid, or acetic acid. A method of peeling, a method of separating the eggshell membrane by utilizing the difference in specific gravity between the eggshell and the eggshell membrane, and the like can be adopted.

微粉砕行程では、卵殻膜が分離された卵殻のみを、ミルを用いて微粉砕する。粉砕する粒径は、例えば、体積平均粒形として300μm以下となるようにするのが好ましく、更に100μm以下が好ましく、70μm以下が望ましい。一方、粉砕後の凝集作用を低減するためには、体積平均粒形として5μm以上にすることが好ましく、望ましくは10μm以上、更に望ましくは20μm以上とする。この結果、本実施形態におけるパウダー状の卵殻粉末が得られる。なお、ここでは鶏卵を利用した卵殻粉末を例示したが、鶏卵に限られず、他の動物の卵殻を用いても良い。 In the pulverization process, only the eggshell from which the eggshell membrane has been separated is pulverized using a mill. The particle size to be crushed is, for example, preferably 300 μm or less as a volume average grain shape, more preferably 100 μm or less, and preferably 70 μm or less. On the other hand, in order to reduce the agglutination action after pulverization, the volume average grain shape is preferably 5 μm or more, preferably 10 μm or more, and more preferably 20 μm or more. As a result, the powdery eggshell powder of the present embodiment is obtained. Although the eggshell powder using chicken eggs is illustrated here, the eggshell powder is not limited to chicken eggs, and eggshells of other animals may be used.

上記卵殻粉末は、焼成されていないため、炭酸カルシウムが主成分となる。一方、本実施形態の卵殻粉末は、焼成工程を経た卵殻粉末であってもよい。焼成工程としては、上記卵殻粉末(又は微粉砕工程の前の卵殻であっても良い)を例えば850℃以上、好ましくは900℃以上で焼成して一旦、酸化カルシウムとし、これに加水を施して水酸化カルシウムの粉末にする。水酸化カルシウムとなった卵殻粉末を、後述する製紙工程で繊維材料に混入させると、抄造工程の前の繊維原液が強アルカリ性水溶液となり、殺菌効果が得られる。なお、卵殻粉末を焼成して酸化カルシウムとした粉末を、そのまま、湿式の抄造工程で用いることは、可能な限り避けるべきである。酸化カルシウムは、水に溶ける時に強く発熱するからである。 Since the eggshell powder is not calcined, calcium carbonate is the main component. On the other hand, the eggshell powder of the present embodiment may be eggshell powder that has undergone a baking step. In the firing step, the eggshell powder (or the eggshell before the fine grinding step) is fired at, for example, 850 ° C. or higher, preferably 900 ° C. or higher to temporarily obtain calcium oxide, and water is added thereto. Make calcium hydroxide powder. When the eggshell powder that has become calcium hydroxide is mixed with the fiber material in the papermaking process described later, the fiber stock solution before the papermaking process becomes a strongly alkaline aqueous solution, and a bactericidal effect can be obtained. It should be noted that it should be avoided as much as possible to use the powder obtained by calcining the eggshell powder into calcium oxide as it is in the wet papermaking process. This is because calcium oxide strongly generates heat when it dissolves in water.

卵殻粉末を焼成して酸化カルシウム(水酸化カルシウム)に化学変化させると、粒径が小さくなると同時に、表面形状も平滑化して、繊維状物質に絡み難くなる。従って、後述する繊維成形品の製造方法においては、未焼成の卵殻粉末を利用するほうが好ましい。 When eggshell powder is calcined and chemically changed to calcium oxide (calcium hydroxide), the particle size becomes smaller and the surface shape becomes smoother, making it difficult to get entangled with fibrous substances. Therefore, in the method for producing a fiber molded product described later, it is preferable to use unbaked eggshell powder.

<パルプモールド成形品の製造方法> <Manufacturing method of pulp molded products>

次に、図2を参照して、上記卵殻粉末を用いたパルプモールド成形品の製造方法について説明する。この製造方法は、離解工程、混合工程、成形(造形)工程、乾燥工程を有する。 Next, a method for producing a pulp molded product using the eggshell powder will be described with reference to FIG. This manufacturing method includes a disintegration step, a mixing step, a molding (modeling) step, and a drying step.

(離解工程) 離解工程では、古紙を水に離解させて繊維状物質を得る。具体的には、パルパーという攪拌装置に、水と古紙を投入して両者を攪拌する。その結果、古紙は、平均繊維長が1mm〜5mm程度の微細な繊維状物質(古紙パルプ)となる。なお、目的に応じて、異物を除去する工程や、古紙に付着したインキを除去する工程等を経ても良い。 (Dissolution step) In the disassembly step, the used paper is dissociated into water to obtain a fibrous substance. Specifically, water and used paper are put into a stirring device called a pulper to stir both. As a result, the used paper becomes a fine fibrous substance (waste paper pulp) having an average fiber length of about 1 mm to 5 mm. Depending on the purpose, a step of removing foreign matter, a step of removing ink adhering to used paper, and the like may be performed.

(混合行程) 混合工程は、繊維状物質及び卵殻粉末を混合して成形原料を生成する。具体的には、離解工程におけるパルパーに、卵殻粉末を投入して、古紙パルプ・卵殻粉末・水を混合、攪拌して、水に繊維状物質及び卵殻粉末が分散した成形原料を生成する。この成形原料では、繊維状物質(古紙パルプ)と卵殻粉末の総重量に対する卵殻粉末の重量含有比率が10%以上となるようにし、好ましくは30%以上となるようにする。より望ましくは、卵殻粉末の重量含有比率を50%以上とし、更に好ましくは、60%以上とする。また、卵殻粉末の体積平均粒形は300μm以下が好ましく、更に100μm以下が好ましく、70μm以下が望ましい。一方、凝集作用を低減するためには、5μm以上であることが好ましく、望ましくは10μm以上とし、更に望ましくは20μm以上とする。更に、卵殻粉末は、高温焼成されておらず、主成分が炭酸カルシウムとなるものを混合することが好ましい。なお、この混合行程又はその前後において、成形原料に対して定着剤を混ぜ込むことが好ましい。定着剤は、例えば、水溶性の無機塩や高分子電解質等であり、これを添加することによって、卵殻粉末を、繊維状物質に吸着させたり、卵殻粉末のフロックを形成させたりすることが可能となる。結果、この定着剤によって、繊維状物質と卵殻粉末のイオン結合させることが可能となり、成形後の卵殻粉末の含有量を高めることが可能となる。 (Mixing process) In the mixing step, the fibrous substance and eggshell powder are mixed to produce a molding raw material. Specifically, eggshell powder is put into the pulper in the disintegration step, and waste paper pulp, eggshell powder, and water are mixed and stirred to produce a molding raw material in which fibrous substances and eggshell powder are dispersed in water. In this molding raw material, the weight content ratio of the eggshell powder to the total weight of the fibrous substance (waste paper pulp) and the eggshell powder is set to 10% or more, preferably 30% or more. More preferably, the weight content ratio of the eggshell powder is 50% or more, and even more preferably 60% or more. The volume average grain shape of the eggshell powder is preferably 300 μm or less, more preferably 100 μm or less, and preferably 70 μm or less. On the other hand, in order to reduce the agglutination effect, it is preferably 5 μm or more, preferably 10 μm or more, and more preferably 20 μm or more. Further, it is preferable to mix the eggshell powder that has not been calcined at a high temperature and whose main component is calcium carbonate. In addition, it is preferable to mix the fixing agent with the molding raw material in or before and after this mixing process. The fixing agent is, for example, a water-soluble inorganic salt, a polymer electrolyte, or the like, and by adding this, it is possible to adsorb the eggshell powder to a fibrous substance or to form flocs of the eggshell powder. It becomes. As a result, this fixing agent makes it possible to ionically bond the fibrous substance and the eggshell powder, and it is possible to increase the content of the eggshell powder after molding.

(成形工程) 成形工程は、成形原料を所望形状に成形する。成形工程は、ここでは造形工程となっており、図3に示すような、立体形状(三次元形状)となる網状キャビティー10に対して、成形原料を付着させることで三次元形状に成形する。なお、本実施形態では、繊維成形品として、卵を保管・運搬する為の卵ケース100を製造する場合を例示する。従って、網状キャビティー10は、卵ケースと同一形状となっており、卵を収容するための凹部10Aが複数形成される。水に分散している成形原料はスラリー50の状態で、原料液槽40に貯留される。網状キャビティー10を成形原料内に投入し、網状キャビティーの背面側の支持部20に負圧を加えることで、網状キャビティーを介して成形原料(スラリー50)を吸引する。結果、網状キャビティーの表面に、繊維状物質及び卵殻粉末が吸着して、三次元形状に成形される。網状キャビティーを回転させることで、原料液槽40から引き上げた後、吸引アーム60によって、網状キャビティーから成形体70を取り出して次工程に移載する。 (Molding step) In the molding step, the molding raw material is molded into a desired shape. The molding process is a molding process here, and is molded into a three-dimensional shape by adhering a molding raw material to the net-like cavity 10 having a three-dimensional shape (three-dimensional shape) as shown in FIG. .. In this embodiment, a case where an egg case 100 for storing and transporting eggs is manufactured as a fiber molded product is illustrated. Therefore, the reticulated cavity 10 has the same shape as the egg case, and a plurality of recesses 10A for accommodating the egg are formed. The molding raw material dispersed in water is stored in the raw material liquid tank 40 in the state of the slurry 50. The reticulated cavity 10 is put into the molding raw material, and a negative pressure is applied to the support portion 20 on the back surface side of the reticulated cavity to suck the molding raw material (slurry 50) through the reticulated cavity. As a result, the fibrous substance and eggshell powder are adsorbed on the surface of the reticulated cavity and formed into a three-dimensional shape. After pulling up from the raw material liquid tank 40 by rotating the reticulated cavity, the molded body 70 is taken out from the reticulated cavity by the suction arm 60 and transferred to the next step.

なお、この網状キャビティー10で用いられる金網は、目開き(開口寸法)が1000μm以下となることが好ましい。より好ましくは、600μm以下とし、更に好ましくは500μm以下とする。更に目開き(開口寸法)は200μm以下となるものが好ましく、より好ましくは150μm以下とする。メッシュ数としては、18以上が好ましく、より好ましくは30以上、更に好ましくは40以上とする。更にメッシュ数は、80以上、好ましくは100以上とする。目開きが1000μm以上になると、成形時に卵殻粉末が金網を通過しやすくなって、成形体に残存する卵殻粉末量が減少しやすい。なお、卵殻粉末の体積平均粒形を20μm〜100μmの範囲内、好ましくは20μm〜70μmの範囲内に設定すると、網状キャビティーの表面に繊維と共に定着しつつ、目詰まりを抑制し、適度に水分を透過させることが可能となる。結果、成形体に卵殻粉末を十分に残存させることが可能となる。なお、金網の目開き(開口寸法)を10μm未満とすると、目詰まりが生じやすく、量産効率が低下しやすい。 The wire mesh used in the mesh cavity 10 preferably has a mesh opening (opening size) of 1000 μm or less. It is more preferably 600 μm or less, and further preferably 500 μm or less. Further, the opening (opening size) is preferably 200 μm or less, more preferably 150 μm or less. The number of meshes is preferably 18 or more, more preferably 30 or more, and further preferably 40 or more. Further, the number of meshes is 80 or more, preferably 100 or more. When the opening is 1000 μm or more, the eggshell powder easily passes through the wire mesh during molding, and the amount of eggshell powder remaining in the molded product tends to decrease. When the volume average grain shape of the eggshell powder is set within the range of 20 μm to 100 μm, preferably within the range of 20 μm to 70 μm, clogging is suppressed while being fixed together with the fibers on the surface of the reticulated cavity, and the moisture content is appropriate. Can be made transparent. As a result, it becomes possible to sufficiently leave the eggshell powder in the molded product. If the mesh opening (opening size) of the wire mesh is less than 10 μm, clogging is likely to occur and mass production efficiency is likely to decrease.

また、成形体に含有する卵殻粉末量を増大させることを主眼とする場合、金網の目開きを、卵殻粉末の体積平均粒形よりも小さくすることも好ましい。例えば、体積平均粒形を300μm以上とする場合は、金網の目開きを300μm未満とし、体積平均粒形を100μm以上とする場合は、金網の目開きを100μm未満とし、体積平均粒形を50μm以上とする場合は、金網の目開きを50μm未満としても良い。 Further, when the main purpose is to increase the amount of eggshell powder contained in the molded product, it is also preferable to make the mesh size of the wire mesh smaller than the volume average grain shape of the eggshell powder. For example, when the volume average grain shape is 300 μm or more, the mesh size of the wire mesh is less than 300 μm, and when the volume average grain shape is 100 μm or more, the mesh size of the wire mesh is less than 100 μm and the volume average grain shape is 50 μm. In the above case, the mesh size of the wire mesh may be less than 50 μm.

(乾燥工程) 乾燥工程は、成形体をコンベア等によって乾燥装置に搬入して成形体を乾燥させる。この結果、パルプモールド(繊維成形品)となる卵ケースが完成する。 (Drying step) In the drying step, the molded product is carried into a drying device by a conveyor or the like to dry the molded product. As a result, an egg case that becomes a pulp mold (fiber molded product) is completed.

以上の通り、本実施形態のパルプモールドの製造方法によれば、繊維成形品となる卵ケースの総重量に対して、例えば50重量%以上の卵殻粉末を含有させることが可能となる。また本実施形態の造形工程によれば、繊維状物質(古紙パルプ)と卵殻粉末を複雑に積層させることが可能となるので、卵殻粉末の含有量を増大させつつ、十分な強度を確保できる。卵殻粉末は、造形工程において、互いに絡み合ったり積層されたりする繊維状物質の隙間に収まることで、繊維成型品の内部に保持される。 As described above, according to the method for producing a pulp mold of the present embodiment, it is possible to contain, for example, 50% by weight or more of eggshell powder with respect to the total weight of the egg case to be a fiber molded product. Further, according to the modeling process of the present embodiment, the fibrous substance (waste paper pulp) and the eggshell powder can be laminated in a complicated manner, so that sufficient strength can be secured while increasing the content of the eggshell powder. The eggshell powder is held inside the fibrous molded product by being contained in the gaps between the fibrous substances that are entangled or laminated with each other in the molding process.

なお、繊維成形品の積層厚みは、乾燥後の状態で例えば0.3mm以上、好ましくは0.5mm、より好ましくは1.0mm以上、さらに望ましくは2.0mm以上とする。また、卵殻粉末の体積平均粒形を20μm以上にすることで、繊維状物質の隙間に適度に挟まって落下しにくくなる。また、卵殻粉末の体積平均粒形を100μm以下にすることで、繊維成形品の表面を比較的なめらかにできる。結果、産業廃棄物となり得る卵殻をリサイクルできると同時に、古紙パルプの使用量を削減することも可能になる。更に、卵殻粉末は、天然の生物由来物質であることから、人体に対してアレルギーや副作用を生じさせるおそれが少ない。 The laminated thickness of the fiber molded product is, for example, 0.3 mm or more, preferably 0.5 mm, more preferably 1.0 mm or more, and further preferably 2.0 mm or more in the dried state. Further, by setting the volume average grain shape of the eggshell powder to 20 μm or more, it is appropriately sandwiched between the fibrous substances and is less likely to fall. Further, by setting the volume average grain shape of the eggshell powder to 100 μm or less, the surface of the fiber-molded product can be made comparatively smooth. As a result, eggshells that can be industrial waste can be recycled, and at the same time, the amount of used paper pulp used can be reduced. Furthermore, since eggshell powder is a naturally occurring biological substance, it is less likely to cause allergies or side effects on the human body.

とりわけ、本実施形態のように、卵ケースに、搬送対象となる卵の卵殻粉末を含有させるようにすると、利用者に対して、天然資源リサイクルの重要性や循環型社会の実現に関して、明快で強力なメッセージを伝達することが可能となる。 In particular, if the egg case contains egg shell powder to be transported as in the present embodiment, it is clear to the user regarding the importance of recycling natural resources and the realization of a recycling-oriented society. It is possible to convey a powerful message.

図4に、本実施形態のパルプモールドの製造方法によって、50重量%の卵殻粉末を含有させた板状サンプルを成形した写真を示す。卵殻粉末を含まない従来のパルプモールドと遜色ない成形品が得られた。 FIG. 4 shows a photograph of a plate-shaped sample containing 50% by weight of eggshell powder formed by the method for producing a pulp mold of the present embodiment. A molded product not inferior to the conventional pulp mold containing no eggshell powder was obtained.

なお、本パルプモールド製造方法では、離解工程におけるパルパーに卵殻粉末を直接投入して混合する場合を例示したが、本発明はこれに限定されない。例えば、離解工程によって得られる古紙パルプ原液を脱水・乾燥し、古紙パルプ一時的に貯留しておくことも好ましい。この場合、保管された古紙パルプと卵殻粉末を水に溶かして成形原料とする。また、成形工程では、網状キャビティーを成形原料に浸漬する場合を例示したが、本発明はこれに限定されない。例えば、網状キャビティーに対して成形原料(スラリー)を流し込むことで、網状キャビティー表面に繊維状物質及び卵殻粉末を固定することもできる。 In the present pulp mold manufacturing method, a case where eggshell powder is directly charged into the pulper in the disintegration step and mixed is illustrated, but the present invention is not limited to this. For example, it is also preferable to dehydrate and dry the used paper pulp stock solution obtained by the disintegration step and temporarily store the used paper pulp. In this case, the stored waste paper pulp and eggshell powder are dissolved in water to be used as a molding raw material. Further, in the molding step, the case where the net-like cavity is immersed in the molding raw material has been illustrated, but the present invention is not limited to this. For example, the fibrous substance and eggshell powder can be fixed on the surface of the reticulated cavity by pouring a molding raw material (slurry) into the reticulated cavity.

更に本パルプモールドの製造方法では、水を含む成形原料を利用した湿式成形を例示したが、本発明はこれに限定されない。例えば、乾燥した繊維状物質及び卵殻粉末を混合して、これらを空気搬送し、網状キャビティーに吹き付けて固定する乾式成形を採用しても良い。ただし、乾式成形の場合は、卵殻粉末が飛散しやすいので、好ましくは、湿式成形を採用する。 Further, in the method for producing the pulp mold, wet molding using a molding raw material containing water has been exemplified, but the present invention is not limited to this. For example, a dry molding method may be adopted in which a dry fibrous substance and eggshell powder are mixed, transported by air, and sprayed into a net-like cavity to fix the powder. However, in the case of dry molding, eggshell powder is likely to scatter, so wet molding is preferably adopted.

<製紙方法> <Papermaking method>

図5を参照して、上記卵殻粉末を用いた製紙方法について説明する。ここでは洋紙を製造する場合を例示する。本実施形態の製紙方法は、パルプ化工程、叩解工程、成形(抄紙)工程、脱水工程、乾燥工程を有する。 A papermaking method using the eggshell powder will be described with reference to FIG. Here, a case of manufacturing foreign paper will be illustrated. The papermaking method of the present embodiment includes a pulping step, a beating step, a molding (papermaking) step, a dehydration step, and a drying step.

(パルプ化工程) パルプ化工程では、木材パルプを蒸解釜で煮込むことでリグニンを分離し、微細な繊維状物質(木材パルプ)を生成する。なお、蒸解釜で生成された木材パルプは、洗浄工程、異物除去工程、漂白工程等を経て白色の木材パルプにしても良い。木材パルプの繊維長は、広葉樹と針葉樹で異なるが、例えば、0.5mm〜4.0mm程度となる。 (Pulping step) In the pulping step, lignin is separated by boiling wood pulp in a cooking pot to produce fine fibrous substance (wood pulp). The wood pulp produced in the cooking kettle may be made into white wood pulp through a washing step, a foreign matter removing step, a bleaching step, and the like. The fiber length of wood pulp differs between hardwood and softwood, but is, for example, about 0.5 mm to 4.0 mm.

(叩解工程) 水に溶かした木材パルプを、叩解装置を利用して毛羽立たせることで、繊維同士が絡みやすい状態にする。叩解装置は、相対回転する一対のディスクの隙間に、繊維状物質(木材パルプ)を通過させることで行う。 (Beating process) Wood pulp dissolved in water is fluffed using a beating device to make the fibers easily entangled with each other. The beating device is performed by passing a fibrous substance (wood pulp) through a gap between a pair of discs that rotate relative to each other.

(混合行程) 混合工程は、叩解した繊維状物質に対して卵殻粉末を混合して成形原料を生成する。具体的には、叩解工程を経た繊維状物質(スラリー)を攪拌装置に貯留し、更に卵殻粉末を投入して混合、攪拌して、水・繊維状物質・卵殻粉末を含む成形原料を生成する。この成形原料において、繊維状物質(木材パルプ)と卵殻粉末の総重量に対する卵殻粉末の重量含有比率が10%以上となるようにし、好ましくは30%以上とする。より望ましくは、卵殻粉末の重量含有比率を50%以上とし、更に好ましくは、60%以上とする。また、卵殻粉末の体積平均粒形は300μm以下が好ましく、更に100μm以下が好ましく、70μm以下が望ましい。一方、卵殻粉末の凝集作用を低減するためには、5μm以上であることが好ましく、望ましくは10μm以上とし、更に望ましくは20μm以上する。更に、卵殻粉末は、高温焼成されておらず、主成分が炭酸カルシウムとなるものを混合することが好ましい。なお、この混合行程又はその前後において、成形原料に対して定着剤を混ぜ込むことが好ましい。定着剤は、例えば、水溶性の無機塩や高分子電解質等であり、これを添加することによって、卵殻粉末を、繊維状物質に吸着させたり、卵殻粉末のフロックを形成させたりすることが可能となる。結果、この定着剤によって、繊維状物質と卵殻粉末のイオン結合させることが可能となり、成形後の卵殻粉末の含有量を高めることが可能となる。 (Mixing process) In the mixing step, eggshell powder is mixed with the beaten fibrous substance to produce a molding raw material. Specifically, the fibrous substance (slurry) that has undergone the beating step is stored in a stirrer, and eggshell powder is further added and mixed and stirred to generate a molding raw material containing water, fibrous substance, and eggshell powder. .. In this molding raw material, the weight content ratio of the eggshell powder to the total weight of the fibrous substance (wood pulp) and the eggshell powder is set to 10% or more, preferably 30% or more. More preferably, the weight content ratio of the eggshell powder is 50% or more, and even more preferably 60% or more. The volume average grain shape of the eggshell powder is preferably 300 μm or less, more preferably 100 μm or less, and preferably 70 μm or less. On the other hand, in order to reduce the agglutinating action of eggshell powder, it is preferably 5 μm or more, preferably 10 μm or more, and more preferably 20 μm or more. Further, it is preferable to mix the eggshell powder that has not been calcined at a high temperature and whose main component is calcium carbonate. In addition, it is preferable to mix the fixing agent with the molding raw material in or before and after this mixing process. The fixing agent is, for example, a water-soluble inorganic salt, a polymer electrolyte, or the like, and by adding this, it is possible to adsorb the eggshell powder to a fibrous substance or to form flocs of the eggshell powder. It becomes. As a result, this fixing agent makes it possible to ionically bond the fibrous substance and the eggshell powder, and it is possible to increase the content of the eggshell powder after molding.

(成形工程) 成形工程は、成形原料を所望形状に成形する。本実施形態の成形工程は、いわゆる抄紙工程となっており、面状の網体に対して、成形原料を付着させることでシート状に成形する。なお、抄紙装置は、長網抄紙式と円網抄紙式に大別される。長網抄紙式は、ベルトコンベアーのように環状回転する網体の表面に対して、成形原料を吐出することで、網体の表面に繊維状物質・卵殻粉末を吸着させる方式となる。円網抄紙式は、ドラム状(円筒状)の網体の一部を、成形原料(スラリー)の貯留槽内に浸漬させつつ網体を回転させることで、網体表面に繊維状物質・卵殻粉末を汲み取ってシート状に成形する。シート状に成形したものを積み重ねて、多層シート状に成形することも可能である。 (Molding step) In the molding step, the molding raw material is molded into a desired shape. The molding process of the present embodiment is a so-called papermaking process, in which a molding raw material is adhered to a planar net body to form a sheet. The papermaking apparatus is roughly classified into a long net paper making type and a circular net paper making type. The long net papermaking method is a method in which a fibrous substance / eggshell powder is adsorbed on the surface of a net body by discharging a molding raw material onto the surface of a net body that rotates in an annular shape like a belt conveyor. In the circular net papermaking type, a part of the drum-shaped (cylindrical) net body is immersed in the storage tank of the molding raw material (slurry) while the net body is rotated, so that the fibrous substance / eggshell is placed on the surface of the net body. The powder is pumped up and molded into a sheet. It is also possible to stack the sheets molded into a multi-layer sheet shape.

なお、この抄紙工程で用いられる網体の金網は、目開き(開口寸法)が1000μm以下となることが好ましい。より好ましくは、600μm以下とし、更に好ましくは500μm以下とする。更に目開き(開口寸法)は200μm以下となるものが好ましく、より好ましくは150μm以下とする。メッシュ数としては、18以上が好ましく、より好ましくは30以上、更に好ましくは40以上とする。更にメッシュ数は、80以上、好ましくは100以上とする。目開きが1000μm以上になると、卵殻粉末が通過しやすくなって、紙に含有する卵殻粉末量が減少しやすい。この際、卵殻粉末の体積平均粒形を20μm〜100μmの範囲内、好ましくは20μm〜70μmの範囲内に設定すると、網体の目詰まりを抑制しつつ、適度に水分を透過させることが可能となり、紙に卵殻粉末を十分に残存させることが可能となる。なお、金網の目開き(開口寸法)を10μm未満とすると、目詰まりが生じやすく、量産効率が低下しやすい。 The wire mesh of the net body used in this papermaking process preferably has a mesh opening (opening size) of 1000 μm or less. It is more preferably 600 μm or less, and further preferably 500 μm or less. Further, the opening (opening size) is preferably 200 μm or less, more preferably 150 μm or less. The number of meshes is preferably 18 or more, more preferably 30 or more, and further preferably 40 or more. Further, the number of meshes is 80 or more, preferably 100 or more. When the opening is 1000 μm or more, the eggshell powder easily passes through, and the amount of eggshell powder contained in the paper tends to decrease. At this time, if the volume average grain shape of the eggshell powder is set within the range of 20 μm to 100 μm, preferably within the range of 20 μm to 70 μm, it becomes possible to appropriately permeate water while suppressing clogging of the net body. , It becomes possible to sufficiently leave eggshell powder on paper. If the mesh opening (opening size) of the wire mesh is less than 10 μm, clogging is likely to occur and mass production efficiency is likely to decrease.

また、紙に含有する卵殻粉末量を増大させる観点では、金網の目開きを、卵殻粉末の体積平均粒形よりも小さくすることも好ましい。例えば、体積平均粒形を300μm以上とする場合は、金網の目開きを300μm未満とし、体積平均粒形を100μm以上とする場合は、金網の目開きを100μm未満とし、体積平均粒形を50μm以上とする場合は、金網の目開きを50μm未満としても良い。 From the viewpoint of increasing the amount of eggshell powder contained in the paper, it is also preferable to make the mesh size of the wire mesh smaller than the volume average grain shape of the eggshell powder. For example, when the volume average grain shape is 300 μm or more, the mesh size of the wire mesh is less than 300 μm, and when the volume average grain shape is 100 μm or more, the mesh size of the wire mesh is less than 100 μm and the volume average grain shape is 50 μm. In the above case, the mesh size of the wire mesh may be less than 50 μm.

(脱水工程) プレス工程では、抄紙工程を経たシート状の成形体をフェルト状のコンベアに移し替えて搬送して脱水し、更に、一対のプレスローラで挟み込むことで、余分な水分を除去する。 (Dehydration Step) In the press step, the sheet-shaped molded body that has undergone the papermaking process is transferred to a felt-shaped conveyor, transported and dehydrated, and further sandwiched between a pair of press rollers to remove excess water.

(乾燥工程) 乾燥工程は、シート状の成形体を乾燥装置に搬入して乾燥させる。乾燥装置では、加熱ローラに成形体を接触させて水分を蒸発させる。この結果、卵殻粉末を含有した紙が完成する。 (Drying step) In the drying step, the sheet-shaped molded product is carried into a drying device and dried. In the drying apparatus, the molded product is brought into contact with the heating roller to evaporate the water content. As a result, a paper containing eggshell powder is completed.

以上、本実施形態の製紙方法によれば、繊維成形品となる紙の総重量に対して、例えば50重量%以上の卵殻粉末を含有させることが可能となる。結果、産業廃棄物として処理されやすい卵殻を有効活用できると同時に、木材パルプの使用量を削減することが可能になる。更に、卵殻粉末は、天然の生物由来物質であることから、人体に対してアレルギーや副作用を生じさせるおそれが少ない。なお、紙の厚みは、例えば0.3mm以上、好ましくは0.5mm以上であることが好ましく、卵殻粉末の保持力を高めることが出来る。 As described above, according to the papermaking method of the present embodiment, it is possible to contain, for example, 50% by weight or more of eggshell powder with respect to the total weight of the paper to be a fiber molded product. As a result, eggshells, which are easily treated as industrial waste, can be effectively used, and at the same time, the amount of wood pulp used can be reduced. Furthermore, since eggshell powder is a naturally occurring biological substance, it is less likely to cause allergies or side effects on the human body. The thickness of the paper is, for example, 0.3 mm or more, preferably 0.5 mm or more, and the holding power of the eggshell powder can be enhanced.

なお、本製紙方法では、叩解工程の後の繊維状物質に対して卵殻粉末を混合する場合を例示したが、本発明はこれに限定されない。例えば、パルプ化工程で得られた繊維状物質に卵殻粉末を混合してから、叩解工程を行うことも好ましい。このようにすると、繊維状物質を毛羽立たせつつ、そこに卵殻粉末を同時に絡めることが可能となり、紙における卵殻粉末の定着率を高めることができる。 In the present papermaking method, the case where eggshell powder is mixed with the fibrous substance after the beating step is illustrated, but the present invention is not limited to this. For example, it is also preferable to mix eggshell powder with the fibrous substance obtained in the pulping step and then perform the beating step. In this way, it becomes possible to entangle the eggshell powder with the fibrous substance while fluffing it, and it is possible to increase the fixing rate of the eggshell powder on the paper.

また、本製紙方法では、水を含む成形原料(スラリー)を利用した湿式成形を例示したが、本発明はこれに限定されない。例えば、乾燥した繊維状物質及び卵殻粉末を混合して、これらを空気搬送し、シート状(筒状の場合を含む)の網体にこれらを吹き付けて固定する乾式成形を採用しても良い。ただし、乾式成形の場合は、卵殻粉末が飛散しやすいので、好ましくは、湿式成形を採用する。 Further, in the present papermaking method, wet molding using a molding raw material (slurry) containing water has been exemplified, but the present invention is not limited to this. For example, a dry molding method may be adopted in which a dried fibrous substance and eggshell powder are mixed, transported by air, and sprayed onto a sheet-shaped (including tubular) net body to fix them. However, in the case of dry molding, eggshell powder is likely to scatter, so wet molding is preferably adopted.

なお、本製紙方法では、木材チップから木材パルプを生成するパルプ化工程を例示したが、このパルプ化工程に代えて、古紙パルプを生成する離解工程を採用しても良い。離解工程は、古紙を水に離解させて繊維状物質(古紙パルプ)を得る。具体的には、パルパーという攪拌装置に、水と古紙を投入して両者を攪拌する。その結果、古紙は、微細な繊維状物質(古紙パルプ)となる。古紙パルプを用いて製紙を行う場合、例えば、段ボール原紙を製造することが好ましい。 In this papermaking method, a pulping step of producing wood pulp from wood chips has been illustrated, but instead of this pulping step, a disintegration step of producing used paper pulp may be adopted. In the disintegration step, the waste paper is dissociated into water to obtain a fibrous substance (waste paper pulp). Specifically, water and used paper are put into a stirring device called a pulper to stir both. As a result, the used paper becomes a fine fibrous substance (waste paper pulp). When papermaking is carried out using used paper pulp, for example, it is preferable to manufacture corrugated board base paper.

なお、上記製紙方法では、繊維状物質として、古紙や木材パルプを用いる場合を例示したが、本発明はこれに限定されず、合成繊維、金属繊維を用いることも可能である。 In the above papermaking method, a case where used paper or wood pulp is used as the fibrous substance has been exemplified, but the present invention is not limited to this, and synthetic fibers and metal fibers can also be used.

更に、本製紙工程を応用して、不織布を製造することもできる。不織布の製造方法の場合、湿式手法又は乾式手法にシート状に成形された繊維成形品に対して、さらに、繊維結合工程を適用する。繊維結合工程の種類には、例えば、浸漬法、スプレー法、サーマルボンド法、ニードルパンチ法、水流交絡法等がある。浸漬法は、繊維成形品をバインダーに浸漬、乾燥させて繊維同士を結合する。スプレー法は、繊維成形品に対してバインダーをスプレーし、乾燥させて繊維同士を結合する。サーマルボンド法は、繊維状物質に予め熱溶解性繊維を混ぜ込んでおき、繊維成形品を加熱カレンダ(加熱ローラ)で挟み込んで熱溶解性繊維を部分的に溶解させて、繊維同士を結合する。ニードルパンチ法は、繊維成形品に対してニードル(針)を突き刺すことで、繊維同士を機械的に絡める。水流交絡法は、繊維成形品に対してノズルから水流を噴射することで、繊維同士を機械的に絡める。 Further, the non-woven fabric can be produced by applying the present papermaking process. In the case of a method for producing a non-woven fabric, a fiber bonding step is further applied to a fiber-molded product molded into a sheet by a wet method or a dry method. Types of fiber bonding steps include, for example, a dipping method, a spray method, a thermal bond method, a needle punching method, a water flow entanglement method, and the like. In the dipping method, the fiber molded product is dipped in a binder and dried to bond the fibers to each other. In the spray method, a binder is sprayed on the fiber molded product and dried to bond the fibers to each other. In the thermal bond method, heat-soluble fibers are mixed in advance with a fibrous substance, and the fiber-molded product is sandwiched between heating calenders (heating rollers) to partially dissolve the heat-soluble fibers and bond the fibers to each other. .. In the needle punch method, the fibers are mechanically entwined with each other by piercing the fiber molded product with a needle. In the water flow entanglement method, fibers are mechanically entangled with each other by injecting a water flow from a nozzle onto a fiber molded product.

なお、卵殻粉末の定着率を高める観点では、浸漬法、スプレー法等のケミカルボンド法が好ましい。また、サーマルボンド法も、熱溶融した繊維に卵殻粉末が固定される点で好ましい。水流交絡法は、水流の噴射時に卵殻粉末が離脱しやすいので、他の手法と比較して好ましくない。 From the viewpoint of increasing the fixation rate of eggshell powder, a chemical bond method such as a dipping method or a spray method is preferable. The thermal bond method is also preferable in that the eggshell powder is fixed to the heat-melted fibers. The water flow confounding method is not preferable as compared with other methods because the eggshell powder is easily separated when the water flow is sprayed.

また、上記製紙方法では、さらに、紙表面にコーティング剤等を塗布することも好ましく、卵殻粉末の離脱を抑制できる。同様に、成形原料となるスラリーに固着剤・接着剤を含有させることも好ましい。 Further, in the above papermaking method, it is also preferable to apply a coating agent or the like to the paper surface, and it is possible to suppress the detachment of eggshell powder. Similarly, it is also preferable to include a fixing agent / adhesive in the slurry as a molding raw material.

以上の通り、本実施形態の繊維成形品の製造方法等によれば、繊維状物質と卵殻粉末を混合してから、シート形状や三次元形状となる所望形状に成形するので、卵殻粉末のリサイクルを実現すると同時に、繊維状物質の消費量を削減することが可能になる。更に、繊維成形品において、卵殻粉末の重量含有比率を全重量の30%以上にすることが可能となり、卵殻粉末のリサイクルを進展させることができる。とりわけ、鶏卵の卵殻は、日本国では年間16万トンが産業廃棄物として処理されているといわれており、これを再資源化することで、環境負荷を低減することができる。 As described above, according to the method for producing a fiber-molded product of the present embodiment, the fibrous substance and the eggshell powder are mixed and then molded into a desired shape having a sheet shape or a three-dimensional shape. Therefore, the eggshell powder is recycled. At the same time, it becomes possible to reduce the consumption of fibrous substances. Further, in the fiber molded product, the weight content ratio of the eggshell powder can be 30% or more of the total weight, and the recycling of the eggshell powder can be promoted. In particular, it is said that 160,000 tons of chicken egg shells are treated as industrial waste annually in Japan, and by recycling this, the environmental load can be reduced.

また、卵殻粉末として、未焼成の炭酸カルシウムを用いる場合は、繊維状物質に対する絡まりが強くなり、繊維成形品に対する含有量を増大させることが出来る。また、卵殻粉末として、焼成及び水和後の水酸化カルシウムを用いる場合は、繊維成形品に殺菌効果や消臭効果を付加することが可能となる。従って、未焼成の卵殻粉末と、焼成後の卵殻粉末の双方を含有させることも好ましい。なお、焼成後の卵殻粉末(酸化カルシウムや水酸化カルシウム)を再処理して、炭酸カルシウムに戻したものも、本発明の卵殻粉末の範疇に含まれる。 Further, when unbaked calcium carbonate is used as the eggshell powder, the entanglement with the fibrous substance becomes strong, and the content in the fibrous molded product can be increased. Further, when calcium hydroxide after firing and hydration is used as the eggshell powder, it is possible to add a bactericidal effect and a deodorizing effect to the fiber molded product. Therefore, it is also preferable to contain both unbaked eggshell powder and baked eggshell powder. The eggshell powder (calcium oxide or calcium hydroxide) after firing is retreated and returned to calcium carbonate, which is also included in the category of eggshell powder of the present invention.

更に、本実施形態の繊維成形品は、含有する卵殻粉末の体積平均粒形が300μm以下となり得るので、繊維成形品の表面を滑らかにできる。一方、卵殻粉末の体積平均粒形が20μm以上となり得るので、繊維状物質に絡みつきやすく、繊維成形品の表面からの卵殻粉末の離散を低減できる。特に本実施形態では、肉厚を0.3mm以上に設定し得るので、繊維状物質と卵殻粉末が内部で複雑に絡み合うようになり、卵殻粉末の保持力を高めることが出来る。なお、卵殻粉末の保持力を一層高めるためには、乾燥前に成形品をプレスして、圧力を付与することが好ましい。 Further, since the volume average grain shape of the eggshell powder contained in the fiber-molded product of the present embodiment can be 300 μm or less, the surface of the fiber-molded product can be smoothed. On the other hand, since the volume average grain shape of the eggshell powder can be 20 μm or more, it is easy to get entangled with the fibrous substance, and the dispersion of the eggshell powder from the surface of the fibrous molded product can be reduced. In particular, in the present embodiment, since the wall thickness can be set to 0.3 mm or more, the fibrous substance and the eggshell powder become intricately entangled inside, and the holding power of the eggshell powder can be enhanced. In order to further increase the holding power of the eggshell powder, it is preferable to press the molded product before drying to apply pressure.

10 網状キャビティー
20 支持部
40 原料液槽
50 スラリー(成形原料)
60 吸引アーム
70 成形体
100 卵ケース
10 Reticulated cavity 20 Support part 40 Raw material liquid tank 50 Slurry (molding raw material)
60 Suction arm 70 Mold 100 Egg case

Claims (17)

繊維状物質を成形して繊維成形品を生成する繊維成形品の製造方法であって、
繊維状物質及び卵殻粉末を混合して成形原料を生成する混合工程と、
前記成形原料を所望形状に成形する成形工程と、
を備えることを特徴とする、
繊維成形品の製造方法。
A method for producing a fibrous molded product by molding a fibrous substance to produce a fibrous molded product.
A mixing step of mixing a fibrous substance and eggshell powder to produce a molding raw material,
A molding step of molding the molding raw material into a desired shape, and
It is characterized by having
Manufacturing method of fiber molded products.
前記成形原料において、前記繊維状物質と前記卵殻粉末の総重量に対する該卵殻粉末の重量含有比率が、10%以上であることを特徴とする、
請求項1に記載の繊維成形品の製造方法。
The molding raw material is characterized in that the weight content ratio of the eggshell powder to the total weight of the fibrous substance and the eggshell powder is 10% or more.
The method for producing a fiber molded product according to claim 1.
前記繊維状物質は、植物繊維、合成繊維、金属繊維の少なくともいずれかを含むことを特徴とする、
請求項1または2に記載の繊維成形品の製造方法。
The fibrous substance is characterized by containing at least one of a plant fiber, a synthetic fiber, and a metal fiber.
The method for producing a fiber molded product according to claim 1 or 2.
前記卵殻粉末は、鶏卵の卵殻を粉砕したものであることを特徴とする、
請求項1ないし3のいずれか一項に記載の繊維成形品の製造方法。
The eggshell powder is a crushed egg shell of a chicken egg.
The method for producing a fiber molded product according to any one of claims 1 to 3.
前記卵殻粉末は、体積平均粒形が300μm以下となることを特徴とする、
請求項1ないし4のいずれか一項に記載の繊維成形品の製造方法。
The eggshell powder is characterized by having a volume average grain shape of 300 μm or less.
The method for producing a fiber molded product according to any one of claims 1 to 4.
前記卵殻粉末は、体積平均粒形が20μm以上となることを特徴とする、
請求項1ないし5のいずれか一項に記載の繊維成形品の製造方法。
The eggshell powder is characterized by having a volume average grain shape of 20 μm or more.
The method for producing a fiber molded product according to any one of claims 1 to 5.
前記卵殻粉末は、900℃以上の焼成が行われていない状態のものを含むことを特徴とする、
請求項1ないし6のいずれか一項に記載の繊維成形品の製造方法。
The eggshell powder is characterized by containing a powder that has not been calcined at 900 ° C. or higher.
The method for producing a fiber molded product according to any one of claims 1 to 6.
古紙を離解させて前記繊維状物質を得る離解工程を有することを特徴とする、
請求項1ないし7のいずれか一項に記載の繊維成形品の製造方法。
It is characterized by having a dissociation step of dissociating used paper to obtain the fibrous substance.
The method for producing a fiber molded product according to any one of claims 1 to 7.
前記成形工程は、面状の網体に対して前記成形原料を付着させることでシート状に成型する抄紙工程を含むことを特徴とする、
請求項1ないし8のいずれか一項に記載の繊維成形品の製造方法。
The molding step is characterized by including a papermaking step of molding into a sheet by adhering the molding raw material to a planar net body.
The method for producing a fiber molded product according to any one of claims 1 to 8.
前記繊維成形品が段ボール原紙であることを特徴とする、
請求項9に記載の繊維成形品の製造方法。
The fiber molded product is a corrugated cardboard base paper.
The method for producing a fiber molded product according to claim 9.
前記成形工程は、立体形状となる網状キャビティーに前記成形原料を付着させることで三次元形状に成形する造形工程を含むことを特徴とする、
請求項1ないし8のいずれか一項に記載の繊維成形品の製造方法。
The molding step is characterized by including a molding step of molding into a three-dimensional shape by adhering the molding raw material to a net-like cavity having a three-dimensional shape.
The method for producing a fiber molded product according to any one of claims 1 to 8.
前記繊維成形品の肉厚を0.3mm以上にすることを特徴とする、
請求項1ないし11のいずれか一項に記載の繊維成形品の製造方法。
The fiber molded product has a wall thickness of 0.3 mm or more.
The method for producing a fiber molded product according to any one of claims 1 to 11.
前記繊維成形品として、卵用のトレイを成形することを特徴とする、
請求項11に記載の繊維成形品の製造方法。
As the fiber molded product, a tray for eggs is molded.
The method for producing a fiber molded product according to claim 11.
前記網体又は前記網状キャビティーの目開き寸法が、1000μm以下であることを特徴とする、
請求項9又は請求項11に記載の繊維成形品の製造方法。
The mesh size of the net body or the net-like cavity is 1000 μm or less.
The method for producing a fiber molded product according to claim 9 or 11.
請求項1乃至14のいずれか一項に記載の繊維成形品の製造方法によって製造されることを特徴とする繊維成形品。 A fiber-molded product, which is produced by the method for producing a fiber-molded product according to any one of claims 1 to 14. 繊維状物質と卵殻粉末を含有することを特徴とする繊維成形品。 A fibrous molded product characterized by containing a fibrous substance and eggshell powder. 前記卵殻粉末を10重量%以上含有することを特徴とする請求項16に記載の繊維成形品。 The fiber-molded product according to claim 16, wherein the eggshell powder is contained in an amount of 10% by weight or more.
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