JP2020162442A - Oil-in-water type emulsified fat composition for bread - Google Patents

Oil-in-water type emulsified fat composition for bread Download PDF

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JP2020162442A
JP2020162442A JP2019064411A JP2019064411A JP2020162442A JP 2020162442 A JP2020162442 A JP 2020162442A JP 2019064411 A JP2019064411 A JP 2019064411A JP 2019064411 A JP2019064411 A JP 2019064411A JP 2020162442 A JP2020162442 A JP 2020162442A
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oil
bread
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dough
fat composition
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啓太 千葉
Keita Chiba
啓太 千葉
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NOF Corp
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Abstract

To provide an oil-in-water type emulsified fat composition for bread capable of producing bread by a scratch dough baking method or a frozen dough baking method, the bread having no flavor typical of an emulsifier, feeling volume, and being easy to bite off and dissolve in the mouth, and bread dough including the same.SOLUTION: An oil-in-water type emulsified fat composition for bread of this invention is composed of 50-85 mass% of an aqueous phase part and 15-50 mass% of an oil phase part, where the aqueous phase part contains 5-50 mass% of water and the oil phase part contains the following components (A1), (A2), and (A3): (A1) being 10-30 mass% of liquid oil, (A2) being 2-6 mass% of succinic acid monoacylglycerol, and (A3) being 0.05-5 mass% of sorbitan fatty acid ester. Bread dough of this invention contains the oil-in-water type emulsified fat composition for bread.SELECTED DRAWING: None

Description

本発明は、製パン時に使用される製パン用水中油型乳化油脂組成物、及びこれを含有するパン生地、冷凍パン生地およびパンに関する。より詳細には、パン生地の発酵時や焼成後のボリュームが良好で、乳化剤特有の風味がなく、歯切れ、口溶けが良好なパンを得ることができる製パン用水中油型乳化油脂組成物に関する。 The present invention relates to an oil-in-water emulsified fat composition for bread making used at the time of bread making, and bread dough, frozen bread dough and bread containing the same. More specifically, the present invention relates to an oil-in-water emulsified oil / fat composition for bread making, which has a good volume during fermentation and baking of bread dough, does not have a flavor peculiar to an emulsifier, and can obtain bread having good crispness and melting in the mouth.

パンの製造方法にはパン生地を冷凍することなくパン生地の製造から焼成まで連続した工程をとるスクラッチ生地製法と、パン生地を一時的に冷凍する冷凍パン生地製法がある。スクラッチ製法は、工場でパンを大量生産するために向いている。一方、冷凍パン生地製法は、工場で製造した冷凍パン生地を、販売直前に店舗で解凍、焼成してパンを製造するため、簡単に焼き立てパンを提供できるという長所がある。
スクラッチ生地製法におけるパン生地の製造は、大規模ラインにおける機械耐性の観点から中種法と呼ばれる方法が主製法となっている。すなわち、使用小麦粉の50〜70%と水、イーストなどを捏ね上げてあらかじめ発酵させた生地(中種生地)を製造し、残りの小麦粉、砂糖、食塩や油脂などパン製造に必須な残りの原料とを捏合させる製法である。その際、油脂としては、バター又は、マーガリン、ショートニング等の製パン用練り込み油脂組成物が用いられている。これらの製パン用練り込み油脂組成物は乳化剤を含み、焼成品(焼成後のパンを指す)の外観、食感改良等の品質の改善に利用されている。しかしながら、焼成品の品質(外観、食感)を改善するためには乳化剤を多量に使用せねばならず、乳化剤独特の風味が焼成品に残り、風味を損なうとともに、乳化剤特有のくちゃつく食感が顕著化し、焼成品の食感に影響を与えるなどの問題がある。
冷凍パン生地製法におけるパン生地の製造は、配合−ミキシング−成型−冷凍−解凍−醗酵−焼成という一連の工程から構成されている。冷凍パン生地製法において特徴的なのは、冷凍という工程を経ることである。冷凍することによってパン生地中の水分が氷結晶となり、さらにそれが粗大化してパンの骨格をなすグルテンを損傷する。その結果、焼成品は内相の気泡膜が厚く、キメが粗い状態となる。そのような状態のパンは、経時的な硬化が進みやすく、歯切れ・口溶け等の食感が悪くなる。
Bread manufacturing methods include a scratch dough manufacturing method that takes a continuous process from bread dough manufacturing to baking without freezing the bread dough, and a frozen bread dough manufacturing method that temporarily freezes the bread dough. The scratch method is suitable for mass-producing bread in factories. On the other hand, the frozen bread dough manufacturing method has an advantage that freshly baked bread can be easily provided because the frozen bread dough produced at the factory is thawed and baked at the store immediately before sale to produce bread.
In the production of bread dough in the scratch dough manufacturing method, a method called the middle seed method is the main manufacturing method from the viewpoint of mechanical resistance in a large-scale line. That is, 50 to 70% of the flour used, water, yeast, etc. are kneaded to produce a pre-fermented dough (medium-sized dough), and the remaining wheat flour, sugar, salt, fat, etc. are the remaining ingredients essential for bread production. It is a manufacturing method that combines with. At that time, as the fat and oil, butter or a kneaded fat and oil composition for bread making such as margarine and shortening is used. These kneaded fat and oil compositions for bread making contain an emulsifier and are used for improving the appearance and texture of baked products (referring to bread after baking). However, in order to improve the quality (appearance, texture) of the baked product, a large amount of emulsifier must be used, and the flavor peculiar to the emulsifier remains in the baked product, impairing the flavor and fluttering food peculiar to the emulsifier. There is a problem that the texture becomes remarkable and affects the texture of the baked product.
The production of bread dough in the frozen bread dough manufacturing method consists of a series of steps of compounding-mixing-molding-freezing-thawing-fermentation-baking. A characteristic of the frozen bread dough manufacturing method is that it goes through a process called freezing. By freezing, the water in the bread dough becomes ice crystals, which further coarsen and damage the gluten that forms the skeleton of the bread. As a result, the fired product has a thick bubble film in the internal phase and a rough texture. Bread in such a state tends to harden over time, and the texture such as crispness and melting in the mouth deteriorates.

スクラッチ生地製法、冷凍パン生地製法いずれにおいても、製パン用生地改良剤として、有機酸モノアシルグリセロールが広く使用されている。例えば特許文献1には、有機酸モノアシルグリセロール、ジアシルグリセロール、リン脂質を主体とした組み合わせた油脂が開示されている。また特許文献2には、有機酸モノアシルグリセロール、タンパク質分解酵素を主体とした組み合わせの油脂組成物が開示されている。さらに、特許文献3にはモノアシルグリセロール、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、有機酸モノアシルグリセロールより選ばれる少なくとも1種を組み合わせた油脂組成物が開示されている。特許文献4にはモノアシルグリセロール、有機酸モノアシルグリセロール、ジアシルグリセロールを主体とした組み合わせの油脂組成物が、特許文献5にはモノアシルグリセロール、リン脂質を主体とした組み合わせの油脂組成物が開示されている。
しかしながら特許文献1に記載の油脂組成物はジアシルグリセロールを含んでいるが、この成分は発がん性物質との報告がなされている3−MCPDエステルの前駆体と考えられていることから、配合成分として使用しないことが好ましい。
特許文献2に記載の油脂組成物は、タンパク質分解酵素を配合しており、氷結晶の影響によってグルテンが損傷しやすい冷凍生地でこの酵素を使用した場合、焼成前のパン生地の冷凍期間が長くなると、グルテンの損傷が顕著化し、焼成品の歯切れ、口溶けなどの食感が悪くなりやすい。
特許文献3に記載の油脂組成物は、有機酸モノアシルグリセロールの使用量が少なく、有機酸モノアシルグリセロールによるグルテン改質効果が不十分であるため、冷凍期間が長くなるとグルテンが損傷し、焼成品の歯切れ、口溶けなどの食感が悪くなりやすい。
特許文献4に記載の油脂組成物は、油中水型油脂組成物であり、油脂組成物中の有機酸モノアシルグリセロールの割合が多く、乳化剤独特の風味により、焼成品の風味が悪くなる。
特許文献5に記載の油脂組成物は、油脂組成物中のモノアシルグリセロールの割合が多いため、モノアシルグリセロールと複合体を形成した澱粉粒同士の付着性が高まり、焼成品の口溶けが悪くなる。
In both the scratch dough manufacturing method and the frozen bread dough manufacturing method, monoacylglycerol organic acid is widely used as a dough improving agent for bread making. For example, Patent Document 1 discloses a combination of fats and oils mainly composed of monoacylglycerol organic acid, diacylglycerol, and phospholipid. Further, Patent Document 2 discloses a fat and oil composition in which a combination of monoacylglycerol organic acid and a proteolytic enzyme is mainly used. Further, Patent Document 3 discloses an oil / fat composition in which at least one selected from monoacylglycerol, sorbitan fatty acid ester, sucrose fatty acid ester, and organic acid monoacylglycerol is combined. Patent Document 4 discloses a fat and oil composition containing a combination of monoacylglycerol, monoacylglycerol organic acid, and diacylglycerol, and Patent Document 5 discloses a fat and oil composition containing a monoacylglycerol and a phospholipid. Has been done.
However, although the oil and fat composition described in Patent Document 1 contains diacylglycerol, this component is considered to be a precursor of 3-MCPD ester which has been reported to be a carcinogen, and therefore, as a compounding component. It is preferable not to use it.
The oil and fat composition described in Patent Document 2 contains a proteolytic enzyme, and when this enzyme is used in a frozen dough in which gluten is easily damaged by the influence of ice crystals, the freezing period of the bread dough before baking becomes long. , Gluten damage becomes noticeable, and the texture of baked products such as crispness and melting in the mouth tends to deteriorate.
In the fat and oil composition described in Patent Document 3, the amount of monoacylglycerol organic acid used is small and the gluten modifying effect of monoacylglycerol organic acid is insufficient. Therefore, if the freezing period is long, the gluten is damaged and fired. The texture of the product, such as crispness and melting in the mouth, tends to deteriorate.
The oil / fat composition described in Patent Document 4 is a water-in-oil type oil / fat composition, and the proportion of the organic acid monoacylglycerol in the oil / fat composition is large, and the flavor peculiar to the emulsifier makes the flavor of the baked product worse.
Since the fat and oil composition described in Patent Document 5 has a large proportion of monoacylglycerol in the fat and oil composition, the adhesion between the starch granules forming a complex with the monoacylglycerol is increased, and the baked product is poorly melted in the mouth. ..

特開2009−240240号公報JP-A-2009-240240 特開2010−200696号公報Japanese Unexamined Patent Publication No. 2010-200696 特開2017−85996号公報JP-A-2017-85996 特開2016−77240号公報Japanese Unexamined Patent Publication No. 2016-77240 特開2015−82981号公報Japanese Unexamined Patent Publication No. 2015-82981

本発明は、スクラッチ生地製法や冷凍生地製法で製造されるパンにおいて、乳化剤特有の風味がなく、ボリューム、歯切れ及び口溶けが良好なパンを製造することができる、製パン用水中油型乳化油脂組成物およびそれを含むパン生地を提供することを目的とする。 The present invention is an oil-in-water emulsified oil / fat composition for bread making capable of producing bread produced by a scratch dough manufacturing method or a frozen dough manufacturing method without the flavor peculiar to an emulsifier and having good volume, crispness and melting in the mouth. And the bread dough containing it is intended to be provided.

本発明者は鋭意検討を重ねた結果、融点が0℃以下の液状油、コハク酸モノアシルグリセロール、およびソルビタン脂肪酸エステルを組み合わせた水中油型乳化油脂組成物を含有することによって上記課題を解決することの知見を見出し、本発明を完成するに至った。
すなわち、本発明は以下の発明である。
As a result of diligent studies, the present inventor solves the above problems by containing an oil-in-water emulsified oil / fat composition in which a liquid oil having a melting point of 0 ° C. or less, monoacylglycerol succinate, and sorbitan fatty acid ester are combined. This finding has led to the completion of the present invention.
That is, the present invention is the following invention.

〔1〕
50〜85質量%の水相部、15〜50質量%の油相部からなる製パン用水中油型乳化油脂組成物であって、
前記水相部には、水を5〜50質量%含有し、前記油相部には、次の成分(A1)、(A2)、(A3)を含有する、製パン用水中油型乳化油脂組成物。
(A1):液状油10〜30質量%
(A2):コハク酸モノアシルグリセロール2〜6質量%
(A3):ソルビタン脂肪酸エステル0.05〜5質量%
〔2〕
〔1〕に記載の製パン用水中油型乳化油脂組成物を含有する、パン生地。
〔3〕
〔1〕に記載の製パン用水中油型乳化油脂組成物を含有する、冷凍パン生地。
〔4〕
〔2〕に記載のパン生地の焼成物、又は、〔3〕に記載の冷凍パン生地の焼成物、からなるパン。
[1]
An oil-in-water emulsified oil / fat composition for bread making, which comprises 50 to 85% by mass of an aqueous phase portion and 15 to 50% by mass of an oil phase portion.
The aqueous phase portion contains 5 to 50% by mass of water, and the oil phase portion contains the following components (A1), (A2), and (A3). object.
(A1): Liquid oil 10 to 30% by mass
(A2): Monoacylglycerol succinate 2 to 6% by mass
(A3): Sorbitan fatty acid ester 0.05 to 5% by mass
[2]
A bread dough containing the oil-in-water emulsified oil / fat composition for bread making according to [1].
[3]
A frozen bread dough containing the oil-in-water emulsified oil / fat composition for bread making according to [1].
[4]
A bread comprising the baked product of the bread dough according to [2] or the baked product of the frozen bread dough according to [3].

本発明により、スクラッチ生地製法や冷凍生地製法で製造されるパンにおいて、乳化剤特有の風味がなく、ボリューム、歯切れ及び口溶けが良好なパンとすることができる、製パン用水中油型乳化油脂組成物およびそれを含むパン生地を提供することができる。 According to the present invention, in a bread produced by a scratch dough manufacturing method or a frozen dough manufacturing method, an oil-in-water emulsified oil / fat composition for bread making can be obtained without a flavor peculiar to an emulsifier and has good volume, crispness and melting in the mouth. Bread dough containing it can be provided.

以下、本発明をさらに詳細に説明する。
本発明の製パン用水中油型乳化油脂組成物は、油相部と水相部からなり、油相部に(A1)液状油、(A2)コハク酸モノアシルグリセロール、(A3)ソルビタン脂肪酸エステルを含有する。なお、本発明において、「質量%」は、特別な断りがない場合には、製パン用水中油型乳化油脂組成物中における含有量を示す。
Hereinafter, the present invention will be described in more detail.
The oil-in-water emulsified oil / fat composition for bread making of the present invention comprises an oil phase portion and an aqueous phase portion, and (A1) liquid oil, (A2) monoacylglycerol succinate, and (A3) sorbitan fatty acid ester are contained in the oil phase portion. contains. In the present invention, "% by mass" indicates the content in the oil-in-water emulsified oil / fat composition for bread making unless otherwise specified.

(A1)液状油
本発明において使用する液状油は、一般的に用いられる精製した食用油脂であれば特に限定されないが、風味の観点より植物油が好ましく用いられる。例えば、菜種油、大豆油、コーン油、ヒマワリ油、紅花油、ゴマ油、綿実油、米油、落花生油、亜麻仁油等、および、これらの油脂を複数種類配合した混合油、分別油、エステル交換油などが挙げられる。液状油は、(A2)コハク酸モノアシルグリセロール、(A3)ソルビタン脂肪酸エステルを溶解し、パン生地中で細かく分散することにより、これら成分の効果を高めることができる。また、融点が0℃以下の植物油が好ましく用いられ、液状油の融点が0℃であると、本発明の水中油型乳化油脂組成物がパン生地に練りこむ際の分散性が良好になる。
(A1) Liquid oil The liquid oil used in the present invention is not particularly limited as long as it is a generally used refined edible oil and fat, but vegetable oil is preferably used from the viewpoint of flavor. For example, rapeseed oil, soybean oil, corn oil, sunflower oil, red flower oil, sesame oil, cottonseed oil, rice oil, peanut oil, linseed oil, etc., and mixed oils containing multiple types of these oils, fractionated oils, ester exchange oils, etc. Can be mentioned. The effect of these components can be enhanced by dissolving (A2) monoacylglycerol succinate and (A3) sorbitan fatty acid ester in the liquid oil and finely dispersing them in the bread dough. Further, when a vegetable oil having a melting point of 0 ° C. or lower is preferably used and the melting point of the liquid oil is 0 ° C., the dispersibility of the oil-in-water emulsified oil / fat composition of the present invention when kneaded into bread dough is improved.

製パン用水中油型乳化油脂組成物中の液状油の含有量は、10〜30質量%である。液状油の含有量が10質量%未満の場合には、(A2)コハク酸モノアシルグリセロール及び(A3)ソルビタン脂肪酸エステルをパン生地に分散させることができず、また、30質量%を超える場合には、乳化が不安定になって油滴が大きくなるため、パン生地への分散性が低下する。 The content of the liquid oil in the oil-in-water emulsified oil / fat composition for bread making is 10 to 30% by mass. When the content of the liquid oil is less than 10% by mass, (A2) monoacylglycerol succinate and (A3) sorbitan fatty acid ester cannot be dispersed in the bread dough, and when it exceeds 30% by mass, it cannot be dispersed. Since the emulsification becomes unstable and the oil droplets become large, the dispersibility in the bread dough decreases.

(A2)コハク酸モノアシルグリセロール
本発明で用いるコハク酸モノアシルグリセロールは、モノアシルグリセロール(グリセリン脂肪酸モノエステル、以下、「MAG」と記載する。)の水酸基の1つをコハク酸でエステル化した有機酸モノアシルグリセロールの1種である。有機酸モノアシルグリセロールを構成する有機酸としては、例えば、コハク酸、クエン酸、酒石酸、ジアセチル酒石酸などが挙げられるが、本願ではコハク酸が好ましい。パン生地を捏ね上げてグルテンのネットワークを形成する工程(ミキシング)において、コハク酸MAGは、グルテン同士の摩擦を低減し、細かく緻密なグルテンを形成するのに役立つ。また細かく緻密なグルテンはパン生地を冷凍するときに粗大な氷結晶ができるのを阻害し、冷凍によるグルテンの損傷を防止することができる。よって、スクラッチ製法、冷凍パン生地製法いずれにおいても、細かく緻密なグルテンの効果によりパン生地発酵時のガス保持力が高まりパンのボリュームが向上し、かつキメの細やかなパンとなるため歯切れ、口溶けが良好となる。
コハク酸MAG中のコハク酸以外のアシル基を構成する脂肪酸としては、風味の観点から炭素数14〜22の脂肪酸が好ましく、さらにグルテンとの結合性という観点から立体障害の少ない飽和脂肪酸が好ましい。炭素数14〜22の飽和脂肪酸としては、例えば、ミリスチン酸、パルミチン酸、ステアリン酸、アラキジン酸、ベヘン酸が挙げられる。一種の脂肪酸だけからなるコハク酸MAGであっても、異なる脂肪酸を結合したコハク酸MAG同士が混合されていても良い。製パン用水中油型乳化油脂組成物中のコハク酸MAGの含有量は2〜6質量%であり、好ましくは2.5〜5質量%、より好ましくは3〜4質量%である。コハク酸MAGが2質量%未満の場合には、パン生地の発酵時や焼成後のボリュームを向上させ、パンの歯切れ感及び口溶け感を向上させる効果が得られず、一方、6質量%を超える場合には、乳化剤特有の風味がパンの風味を悪くする。
コハク酸MAGとして、例えば理研ビタミン(株)製「ポエムB-10」(結合脂肪酸はスステアリン酸、パルミチン酸)、ケリー ・バイオサイエンス社(製)マイベロールSMG−K(結合脂肪酸はステアリン酸、パルミチン酸)等が例示できる。
(A2) Monoacylglycerol succinate The monoacylglycerol succinate used in the present invention is obtained by esterifying one of the hydroxyl groups of monoacylglycerol (glycerin fatty acid monoester, hereinafter referred to as "MAG") with succinic acid. It is a kind of organic acid monoacylglycerol. Examples of the organic acid constituting the organic acid monoacylglycerol include succinic acid, citric acid, tartaric acid, diacetyltartaric acid and the like, but succinic acid is preferable in the present application. In the process of kneading bread dough to form a network of gluten (mixing), MAG succinate reduces friction between gluten and helps to form fine and dense gluten. In addition, fine and dense gluten inhibits the formation of coarse ice crystals when freezing bread dough, and can prevent damage to gluten due to freezing. Therefore, in both the scratch manufacturing method and the frozen bread dough manufacturing method, the effect of fine and precise gluten enhances the gas retention during bread dough fermentation, improves the volume of bread, and makes the bread finely textured, resulting in good crispness and melting in the mouth. Become.
As the fatty acid constituting the acyl group other than succinic acid in succinic acid MAG, a fatty acid having 14 to 22 carbon atoms is preferable from the viewpoint of flavor, and a saturated fatty acid having less steric hindrance is preferable from the viewpoint of binding to gluten. Examples of saturated fatty acids having 14 to 22 carbon atoms include myristic acid, palmitic acid, stearic acid, arachidic acid, and behenic acid. The succinic acid MAG consisting of only one type of fatty acid may be used, or the succinic acid MAGs in which different fatty acids are bound may be mixed with each other. The content of succinic acid MAG in the oil-in-water emulsified oil / fat composition for bread making is 2 to 6% by mass, preferably 2.5 to 5% by mass, and more preferably 3 to 4% by mass. When the succinic acid MAG is less than 2% by mass, the effect of improving the volume of the bread dough during fermentation and baking and improving the crispness and melting feeling of the bread cannot be obtained, while it exceeds 6% by mass. In addition, the flavor peculiar to the emulsifier makes the bread flavor worse.
As succinic acid MAG, for example, "Poem B-10" manufactured by RIKEN Vitamin Co., Ltd. (binding fatty acids are stearic acid and palmitic acid), Kelly Bioscience Co., Ltd. Myberol SMG-K (binding fatty acids are stearic acid and palmitic acid). Acid) and the like can be exemplified.

(A3)ソルビタン脂肪酸エステル
本発明で用いるソルビタン脂肪酸エステルは、ソルビトール及び/又はその縮合物と脂肪酸との直接エステル化反応により製造されるものであって、主構成脂肪酸はステアリン酸、パルミチン酸が好ましく、エステルタイプはジエステルが好ましい。本発明で用いられるソルビタン脂肪酸エステルの原料として用いられるソルビトール及び/又はその縮合物としては、特に限定されないが、例えば、ソルビトールとしては、D−ソルビトールを50.0〜70.0質量%含有するD−ソルビトール液或いは白色粉末又は粒状のD−ソルビトールが挙げられる。また、ソルビトールの縮合物としては、ソルビトールが分子内脱水により、水1分子の脱水したソルビタン、水2分子の脱水したソルバイド等が挙げられる。
ソルビタン脂肪酸エステルは、コハク酸MAGと併用することによりその効果を増強することができる。すなわち、ソルビタン脂肪酸エステルはコハク酸MAGをパン生地中で微細に分散し、コハク酸MAGのパン生地での効果を高める働きがある。なお、製パン用水中油型乳化油脂組成物中におけるソルビタン脂肪酸エステルの含有量は0.05〜5質量%である。上限値として、好ましくは4質量%以下であり、より好ましくは2質量%以下であり、更に好ましくは1質量%以下であり、特に好ましくは0.5質量%以下である。ソルビタン脂肪酸エステルが0.05質量%未満の場合には、コハク酸MAGをパン生地中に微細に分散することができずないため、コハク酸MAGの添加効果が十分に得られず、パン生地の発酵時や焼成後のボリュームを向上させ、パンの歯切れ、口溶けを向上させることができない。5質量%を超える場合には、乳化剤特有の風味がパンの味を悪くする。
ソルビタン脂肪酸エステルとして、例えば理研ビタミン(株)製「ポエムS-320YN」(ジエステルタイプ、結合脂肪酸はステアリン酸、パルミチン酸が合計90質量%以上)、理研ビタミン(製)製「ポエムS-300V」(モノエステルタイプ、結合脂肪酸はステアリン酸、パルミチン酸が合計90質量%以上)等が例示できる。
(A3) Polysorbate Fatty Acid Ester The sorbitan fatty acid ester used in the present invention is produced by a direct esterification reaction of sorbitol and / or a condensate thereof with a fatty acid, and the main constituent fatty acids are preferably stearic acid and palmitic acid. , The ester type is preferably a diester. The sorbitol and / or a condensate thereof used as a raw material for the sorbitol fatty acid ester used in the present invention is not particularly limited, but for example, the sorbitol contains D-sorbitol in an amount of 50.0 to 70.0% by mass. -Sorbitol solution or white powder or granular D-sorbitol can be mentioned. Examples of the condensate of sorbitol include sorbitol in which one molecule of water is dehydrated by intramolecular dehydration of sorbitol, and sorbide in which two molecules of water are dehydrated.
The effect of sorbitan fatty acid ester can be enhanced by using it in combination with succinic acid MAG. That is, the sorbitan fatty acid ester has a function of finely dispersing succinic acid MAG in the bread dough and enhancing the effect of the succinic acid MAG in the bread dough. The content of the sorbitan fatty acid ester in the oil-in-water emulsified oil / fat composition for bread making is 0.05 to 5% by mass. The upper limit value is preferably 4% by mass or less, more preferably 2% by mass or less, still more preferably 1% by mass or less, and particularly preferably 0.5% by mass or less. When the sorbitan fatty acid ester is less than 0.05% by mass, the succinic acid MAG cannot be finely dispersed in the bread dough, so that the effect of adding the succinate MAG cannot be sufficiently obtained, and the bread dough is fermented. It is not possible to improve the volume after baking and to improve the crispness and melting of bread. If it exceeds 5% by mass, the flavor peculiar to the emulsifier deteriorates the taste of bread.
As sorbitan fatty acid esters, for example, "Poem S-320YN" manufactured by Riken Vitamin Co., Ltd. (diester type, combined fatty acids are stearic acid and palmitic acid totaling 90% by mass or more), "Poem S-300V" manufactured by Riken Vitamin Co., Ltd. (The monoester type, the bound fatty acid is stearic acid and palmitic acid in total of 90% by mass or more) and the like can be exemplified.

(A2)コハク酸モノアシルグリセロールを良好に分散するという観点から、(A2)コハク酸モノアシルグリセロールの含有量に対する(A3)ソルビタン脂肪酸エステルの含有量の比(A3/A2)は、好ましくは0.01〜1.5である。上限値として、より好ましくは1.0以下であり、更に好ましくは0.8以下であり、更により好ましくは0.3以下であり、特に好ましくは0.1以下である。 From the viewpoint of satisfactorily dispersing (A2) monoacylglycerol succinate, the ratio (A3 / A2) of the content of (A3) sorbitan fatty acid ester to the content of (A2) monoacylglycerol succinate is preferably 0. It is 0.01 to 1.5. The upper limit is more preferably 1.0 or less, still more preferably 0.8 or less, even more preferably 0.3 or less, and particularly preferably 0.1 or less.

[製パン用水中油型乳化油脂組成物]
本発明の製パン用水中油型乳化油脂組成物は、水中油型であるためパン生地への分散性が良好であり、少量の添加量でより効果的に作用させることができる。
[Water-based oil-type emulsified fat composition for bread making]
Since the oil-in-water emulsified oil / fat composition for bread making of the present invention is an oil-in-water type, it has good dispersibility in bread dough and can be made to act more effectively with a small amount of addition.

本発明の製パン用水中油型乳化油脂組成物は、50〜85質量%の水相部と、15〜50質量%の油相部からなる。油相部、水相部がこの範囲を超えると、本願の効果が得られないだけでなく、水中油型乳化油脂組成物としての状態を保つことができない。 The oil-in-water emulsified oil / fat composition for bread making of the present invention comprises 50 to 85% by mass of an aqueous phase portion and 15 to 50% by mass of an oil phase portion. If the oil phase portion and the aqueous phase portion exceed this range, not only the effect of the present application cannot be obtained, but also the state as an oil-in-water emulsified oil / fat composition cannot be maintained.

本願の製パン用油水中油型乳化油脂組成物は、油相部に(A1)液状油、(A2)コハク酸モノアシルグリセロール、(A3)ソルビタン脂肪酸エステルを所定の配合量で含有すれば、それ以外の成分として、固体脂、レシチン、HLB2〜6の油溶性の乳化剤、油溶性酸化防止剤、動植物蛋白、油溶性フレーバー等、一般的に製パン用に一般的に使用される油溶性成分を含有することができる。 The oil-in-water emulsified oil-and-fat composition for bread making of the present application contains (A1) liquid oil, (A2) monoacylglycerol succinate, and (A3) sorbitan fatty acid ester in a predetermined blending amount in the oil phase portion. Other ingredients include solid fats, lecithin, oil-soluble emulsifiers of HLB2-6, oil-soluble antioxidants, animal and plant proteins, oil-soluble flavors, and other oil-soluble components commonly used for bread making. Can be contained.

さらに、HLB2〜6の油溶性の乳化剤としてモノアシルグリセロール(モノグリセリド)を使用することができる。モノアシルグリセロールは、グリセリン1分子に対して、脂肪酸が1分子結合したグリセリン脂肪酸エステルである。モノアシルグリセロールを含有することにより、本発明の水中油型乳化油脂組成物の乳化状態を安定に保つことができ、水中油型乳化油脂組成物をパン生地へ均一に分散させて本発明の効果をより高めることができる。その構成脂肪酸としては、炭素数14〜22の脂肪酸が好ましく、さらに飽和脂肪酸が好ましい。炭素数14〜22の飽和脂肪酸としては、例えば、ミリスチン酸、パルミチン酸、ステアリン酸、アラキジン酸、ベヘン酸が挙げられる。モノアシルグリセロールの含有量は、製パン用水中油型乳化油脂組成物中に、好ましくは0.1〜5質量%である。 Furthermore, monoacylglycerol (monoglyceride) can be used as an oil-soluble emulsifier for HLB2-6. Monoacylglycerol is a glycerin fatty acid ester in which one molecule of fatty acid is bound to one molecule of glycerin. By containing monoacylglycerol, the emulsified state of the oil-in-water emulsified oil / fat composition of the present invention can be kept stable, and the oil-in-water emulsified oil / fat composition is uniformly dispersed in the bread dough to obtain the effect of the present invention. Can be enhanced. As the constituent fatty acids, fatty acids having 14 to 22 carbon atoms are preferable, and saturated fatty acids are more preferable. Examples of saturated fatty acids having 14 to 22 carbon atoms include myristic acid, palmitic acid, stearic acid, arachidic acid, and behenic acid. The content of monoacylglycerol is preferably 0.1 to 5% by mass in the oil-in-water emulsified oil / fat composition for bread making.

水相部には、水を5〜50質量%含有する。水の含有量がこの範囲外であると水中油型乳化油脂組成物の乳化状態を安定に保つことができず、水中油型乳化油脂組成物をパン生地へ均一に分散させることができないため、本発明の効果が得られない。 The aqueous phase portion contains 5 to 50% by mass of water. If the water content is out of this range, the emulsified state of the oil-in-water emulsified oil / fat composition cannot be kept stable, and the oil-in-water emulsified oil / fat composition cannot be uniformly dispersed in the bread dough. The effect of the invention cannot be obtained.

また、水相部には、水以外の水溶性成分として、乳、乳製品、澱粉、糖類、塩類、増粘多糖類、酸味料、酵素、pH調整剤等の安定剤、香辛料、呈味素材、HLB8〜15の水溶性の乳化剤、水溶性酸化防止剤、水溶性フレーバー等、製パン用に一般的に使用される水溶性成分を含有することができる。例えば、水相部には、水10〜50質量%、糖類10〜50質量%、HLB11以上の乳化剤0.2〜3質量%が好ましく用いることができる。例えば、水相部には、水5〜50質量%、糖類10〜50質量%、HLB8〜15の乳化剤0.01〜10質量%が好ましく用いることができる。なお、油溶性成分や水溶性成分の原料に水を含む場合には、原料由来の水分も本発明の製パン用水中油型乳化油脂組成物の水分として計算する。 In the aqueous phase, as water-soluble components other than water, stabilizers such as milk, dairy products, starch, sugars, salts, thickening polysaccharides, acidulants, enzymes, pH adjusters, spices, and taste materials , HLB8-15 water-soluble emulsifiers, water-soluble antioxidants, water-soluble flavors and the like, which can contain water-soluble components commonly used for bread making. For example, 10 to 50% by mass of water, 10 to 50% by mass of saccharides, and 0.2 to 3% by mass of an emulsifier of HLB 11 or higher can be preferably used in the aqueous phase portion. For example, 5 to 50% by mass of water, 10 to 50% by mass of saccharides, and 0.01 to 10% by mass of an emulsifier of HLB 8 to 15 can be preferably used in the aqueous phase portion. When water is contained in the raw material of the oil-soluble component or the water-soluble component, the water content derived from the raw material is also calculated as the water content of the oil-in-water emulsified oil / fat composition for bread making of the present invention.

さらに、HLB8〜15の水溶性の乳化剤としてショ糖脂肪酸エステルを使用することができる。ショ糖脂肪酸エステルは、親水基であるショ糖と、親油基である脂肪酸がエステル結合したものである。ショ糖脂肪酸エステルを含有することにより、水中油型乳化油脂組成物の状態が安定化し、パン生地に練りこむ際の分散性がより良好になる。その構成脂肪酸としては、風味の観点から炭素数14〜22の脂肪酸が好ましく、さらにグルテンとの結合性という観点から立体障害の少ない飽和脂肪酸が好ましい。炭素数14〜22の飽和脂肪酸としては、例えば、ミリスチン酸、パルミチン酸、ステアリン酸、アラキジン酸、ベヘン酸が挙げられる。ショ糖脂肪酸エステルの含有量は、製パン用水中油型乳化油脂組成物中に、好ましくは0.01〜10質量%である。下限値として、より好ましくは0.1質量%以上であり、更に好ましくは0.3質量%以上である。上限値として、より好ましくは7質量%以下であり、更に好ましくは5質量%以下である。 In addition, sucrose fatty acid esters can be used as water-soluble emulsifiers for HLBs 8-15. The sucrose fatty acid ester is an ester bond of sucrose, which is a hydrophilic group, and a fatty acid, which is a parent oil group. By containing the sucrose fatty acid ester, the state of the oil-in-water emulsified oil / fat composition is stabilized, and the dispersibility when kneaded into the bread dough is improved. As the constituent fatty acids, fatty acids having 14 to 22 carbon atoms are preferable from the viewpoint of flavor, and saturated fatty acids having less steric hindrance are preferable from the viewpoint of binding to gluten. Examples of saturated fatty acids having 14 to 22 carbon atoms include myristic acid, palmitic acid, stearic acid, arachidic acid, and behenic acid. The content of the sucrose fatty acid ester is preferably 0.01 to 10% by mass in the oil-in-water emulsified oil / fat composition for bread making. The lower limit is more preferably 0.1% by mass or more, still more preferably 0.3% by mass or more. The upper limit is more preferably 7% by mass or less, still more preferably 5% by mass or less.

製パン用水中油型乳化油脂組成物の製造方法としては、油相部として(A2)コハク酸モノアシルグリセロール、(A3)ソルビタン脂肪酸エステルを(A1)液状油に分散させ、乳化剤の融点以上の温度(70℃〜80℃)でプロペラ攪拌等にて10分間以上加熱攪拌し、均一に溶解する。さらに水相部として、糖類、高HLBの乳化剤を水に分散し、70℃でプロペラ攪拌等で加熱攪拌し、均一に溶解する。その後、油相部を水相部に投入し、乳化液を70℃〜80℃でプロペラ攪拌機にて10分間以上加熱攪拌した後、コンビネーター、リアクテーター、パーフェクター等の急冷練り合わせ機、あるいは冷却機能を有す均質機等を用いて40℃〜50℃まで降温し、水中油型乳化油脂組成物を得る。 As a method for producing an oil-in-water emulsified oil / fat composition for bread making, (A2) monoacylglycerol succinate and (A3) sorbitan fatty acid ester are dispersed in (A1) liquid oil as an oil phase portion, and the temperature is equal to or higher than the melting point of the emulsifier. Heat and stir at (70 ° C. to 80 ° C.) for 10 minutes or more with propeller stirring or the like to uniformly dissolve. Further, as the aqueous phase portion, saccharides and a high HLB emulsifier are dispersed in water, and the mixture is uniformly dissolved by heating and stirring at 70 ° C. with propeller stirring or the like. After that, the oil phase part is put into the aqueous phase part, and the emulsion is heated and stirred at 70 ° C. to 80 ° C. with a propeller stirrer for 10 minutes or more. The temperature is lowered to 40 ° C. to 50 ° C. using a homogenizing machine or the like to obtain an oil-in-water emulsified oil / fat composition.

[パン生地]
本発明の製パン用水中油型乳化油脂組成物用いてパン生地を製造する場合、穀粉100質量部に対して、製パン用水中油型乳化油脂組成物を1〜10質量部、混合する。製パン用水中油型乳化油脂組成物は、好ましくは1〜8質量部、さらに好ましくは1〜6質量部配合することができる。製パン用水中油型乳化油脂組成物の添加量が1質量部未満であると、パンの歯切れ、及び口溶けを向上させる十分な効果が得られず、10質量部を越えると、乳化剤特有の風味がパンの味を悪くする
[Dough]
When a bread dough is produced using the oil-in-water emulsified oil / fat composition for bread making of the present invention, 1 to 10 parts by mass of the oil-in-water emulsified oil / fat composition for bread making is mixed with 100 parts by mass of flour. The oil-in-water emulsified oil / fat composition for bread making can be preferably blended in an amount of 1 to 8 parts by mass, more preferably 1 to 6 parts by mass. If the amount of the oil-in-water emulsified oil / fat composition for bread making is less than 1 part by mass, a sufficient effect of improving the crispness and melting in the mouth of bread cannot be obtained, and if it exceeds 10 parts by mass, the flavor peculiar to the emulsifier is obtained. Make bread taste bad

本発明のパン用生地、冷凍パン用生地を焼成した焼成物からなるパン類には、フィリングなどの詰め物をしたパン類も含まれ、食パン、特殊パン、調理パン、菓子パンなどの冷凍パンが挙げられる。具体的には食パンとして白パン、黒パン、フランスパン、バラエティブレッド、ロール(テーブルロール、バンズ、バターロール)が挙げられる。特殊パンとしてはマフィンなど、調理パンとしてはホットドック、ハンバーガーなど、菓子パンとしてはジャムパン、あんパン、クリームパン、レーズンパン、メロンパンなどが挙げられる。 The breads made by baking the bread dough and the frozen bread dough of the present invention include breads filled with fillings and the like, and include frozen breads such as breads, special breads, cooked breads, and sweet breads. Be done. Specific examples of bread include white bread, black bread, French bread, variety red, and rolls (table rolls, buns, butter rolls). Special breads include muffins, cooking breads include hot docks and hamburgers, and sweet breads include jam bread, anpan, cream buns, raisin breads, and melon breads.

本発明のパン生地に用いる原料としては、主原料の穀粉として小麦粉の他にイースト、イーストフード、乳化剤、油脂類(ショートニング、ラード、マーガリン、バター、液状油糖)、水、加工澱粉、乳製品、食塩、糖類、調味料(グルタミン酸ソーダ類や核酸類)、保存料、ビタミン、カルシウム等の強化剤、蛋白質、アミノ酸、化学膨張剤、フレーバー等が挙げられる。さらに、一般に原料として用いると老化しやすくなる、レーズン等の乾燥果実、小麦粉ふすま、全粒粉等を使用できる。本発明の製パン用水中油型乳化油脂組成物は小麦粉を用いる種々の食品に添加し、パン類等のベーカリー製品に利用することができる。製パン工程としては、一般に行われているスクラッチ生地製法、冷凍生地製法の製造方法をそのまま適用することができる。 The raw materials used in the bread dough of the present invention include wheat flour as the main raw material, yeast, yeast food, emulsifiers, fats and oils (shortening, lard, margarine, butter, liquid oil sugar), water, processed starch, dairy products, etc. Examples thereof include salt, sugar, seasonings (sodium glutamate and nucleic acids), preservatives, fortifiers such as vitamins and calcium, proteins, amino acids, chemical expansion agents, flavors and the like. Furthermore, dried fruits such as raisins, wheat bran, whole grain flour and the like, which generally tend to age when used as raw materials, can be used. The oil-in-water emulsified oil / fat composition for bread making of the present invention can be added to various foods using wheat flour and used in bakery products such as breads. As the bread making process, the generally used scratch dough manufacturing method and frozen dough manufacturing method can be applied as they are.

以下に実施例を挙げて本発明をさらに具体的に説明する。実施例中の配合量と配合割合は質量基準である。 Hereinafter, the present invention will be described in more detail with reference to examples. The blending amount and blending ratio in the examples are based on mass.

(製パン用水中油型乳化油脂組成物の製造)
(実施例1及び、実施例2〜14、比較例1〜10の製造)
油相部として液状油(ナタネ油 日油製)15kgにコハク酸モノアシルグリセロール(ポエムB−10 理研ビタミン製)2kg、ソルビタン脂肪酸エステル(ポエムS−320YN 理研ビタミン製)0.1kg、その他成分としてモノグリセリド(エマルジーMS 理研ビタミン製)3kgを分散させ、70℃〜80℃まで加温しプロペラ攪拌機(スリーワンモーターBLh600 新東科学製)にて10分間以上加熱攪拌し、均一に溶解した。さらに水相部として、液糖(ソルビトールC 三菱商事フードテック製)40kg、高HLBの乳化剤(S−1570 三菱化学フーズ製)0.5kgを水39.4kgに分散し、70℃まで加温しプロペラ攪拌で加熱攪拌し、均一に溶解する。その後、油相部を水相部に投入し、乳化液を70℃〜80℃を維持しつつプロペラ攪拌機にて10分間以上加熱攪拌した後、マーガリン試作機(リアクテーター 本多交易製)を用いて40℃〜50℃まで急冷し、製パン用水中油型乳化油脂組成物を試作した。なお実施例2〜14、比較例1〜10については、表1、2の配合比率に従い、上述と同様の製造方法で試作した。
(Manufacturing of oil-in-water emulsified oil and fat composition for bread making)
(Manufacturing of Example 1, Examples 2 to 14, and Comparative Examples 1 to 10)
As the oil phase part, 15 kg of liquid oil (made by rapeseed oil Nichiyu), 2 kg of monoacylglycerol succinate (made by Poem B-10 Riken Vitamin), 0.1 kg of sorbitan fatty acid ester (made by Poem S-320YN made by Riken Vitamin), and other ingredients 3 kg of monoglyceride (manufactured by Emalgie MS Riken Vitamin) was dispersed, heated to 70 ° C to 80 ° C, heated and stirred with a propeller stirrer (Three One Motor BLh600 manufactured by Shinto Kagaku) for 10 minutes or more, and dissolved uniformly. Further, as the aqueous phase part, 40 kg of liquid sugar (sorbitol C manufactured by Mitsubishi Corporation Food Tech) and 0.5 kg of high HLB emulsifier (manufactured by S-1570 Mitsubishi Chemical Foods) are dispersed in 39.4 kg of water and heated to 70 ° C. Heat and stir with propeller stirring to dissolve uniformly. After that, the oil phase part was put into the aqueous phase part, and the emulsion was heated and stirred with a propeller stirrer for 10 minutes or more while maintaining 70 ° C. to 80 ° C., and then using a margarine prototype (reactator Honda Trading Co., Ltd.). The oil-in-water emulsified oil / fat composition for bread making was prototyped by quenching to 40 ° C. to 50 ° C. Examples 2 to 14 and Comparative Examples 1 to 10 were prototyped by the same manufacturing method as described above according to the blending ratios in Tables 1 and 2.

上記実施例1〜14および比較例1〜10の製パン用水中油型乳化油脂組成物を用いて、以下に示す方法により、冷凍生地製法及びスクラッチ生地製法でパンを製造した。
<冷凍生地製法パン>
強力粉(製品名:オーション 日清製粉製)1000g、上白糖(製品名:上白30 大東製糖製)200g、イースト(製品名:USオリエンタルイースト オリエンタル酵母製)60g、脱脂粉乳(製品名:脱脂粉乳 明治製)20g、食塩(製品名:食塩 日本食塩製造製)10g、全卵60g、水500g、実施例および比較例において得られた製パン用水中油型乳化油脂組成物20gを投入し製菓製パン用ミキサー AM−20(愛工社製)にて低速2分間中速5分間捏ね上げ、ここで練り込み用油脂を100g投入し、さらに低速3分、中速3分捏ね上げ、捏ね上げ温度20℃の生地を得た。すぐに55gに分割し、次いで棒状に成形した。成形された生地を天板に並べて、急速冷凍機(KOMAジャパン製)にて冷凍(−25℃ 30分間)し、冷凍パンを作製した。冷凍期間3ヶ月後の冷凍パンを解凍(室温、140分間)した後、温度38℃、湿度85%に設定したドウコンディショナーNS−XB923FA(パナソニック製)にて50分間最終発酵を行った。最終発酵後、焼成オーブン(PRINCE PJB2−222B(フジサワマルゼン製))にて上火210℃、下火200℃ 8分間焼成した。焼成後、室温にて放冷し袋に入れた。
Using the oil-in-water emulsified fat composition for bread making of Examples 1 to 14 and Comparative Examples 1 to 10, bread was produced by the frozen dough manufacturing method and the scratch dough manufacturing method by the methods shown below.
<Frozen dough manufacturing method bread>
Strong flour (product name: Auchon Nisshin Flour) 1000g, Johakuto (Product name: Johakuto 30 Daito Sugar) 200g, Yeast (Product name: US Oriental East Oriental Yeast) 60g, Non-fat dry milk (Product name: Non-fat powder) 20 g of Meiji), 10 g of salt (product name: salt manufactured by Nippon Shio), 60 g of whole eggs, 500 g of water, and 20 g of the oil-in-water emulsified fat composition for bread making obtained in Examples and Comparative Examples were added to make confectionery bread. Knead with a mixer AM-20 (manufactured by Aiko Co., Ltd.) for 2 minutes at low speed for 5 minutes at medium speed, add 100 g of fat and oil for kneading, knead for 3 minutes at low speed and 3 minutes at medium speed, and knead at a temperature of 20 ° C. I got the dough. It was immediately divided into 55 g and then molded into a rod shape. The molded dough was arranged on a top plate and frozen in a quick freezer (manufactured by KOMA Japan) (-25 ° C. for 30 minutes) to prepare a frozen bread. After thawing the frozen bread after the freezing period of 3 months (room temperature, 140 minutes), the final fermentation was carried out for 50 minutes with a dough conditioner NS-XB923FA (manufactured by Panasonic) set at a temperature of 38 ° C. and a humidity of 85%. After the final fermentation, it was fired in a baking oven (PRINCE PJB2-222B (manufactured by Fujisawa Maruzen)) at 210 ° C. on the top heat and 200 ° C. on the bottom heat for 8 minutes. After firing, it was allowed to cool at room temperature and placed in a bag.

<スクラッチ生地製法パン>
(中種生地製造)
強力粉700g、イーストフード(製品名:Cオリエンタルイースト オリエンタル酵母製)0.1g、イースト3g、実施例および比較例において得られた製パン用水中油型乳化油脂組成物20g、水420gを上述した製菓製パン用ミキサーにて低速2分間中速2分間捏ね上げ、できた生地を発酵装置KM−62DX(協同電熱製作所製)にて28℃、2時間発酵させた。
(本捏生地製造)
発酵させた中種生地と、さらに強力粉300g、上白糖140g、脱脂粉乳20g、食塩16g、水240gを投入し製菓製パン用ミキサーにて低速3分間中速5分間捏ね上げ、ここで練り込み用油脂(製品名:アンビションマーガリン 日油製)150g投入し、さらに低速3分間中速4分間捏ね上げ、捏ね上げ温度28℃の生地を得た。上述した発酵装置にて30分間静置させた後、35gに分割し、さらに同装置にて30分間静置させた後、棒状に成形した。成形された生地を天板に並べて、上述したドウコンディショナー(温度38℃、湿度85%)に50分間最終発酵を行った。最終発酵後、上述した焼成オーブン(上火205℃、下火200℃)にて8.5分間焼成した。焼成後、室温にて放冷し袋に入れた。
<Scratch dough manufacturing method bread>
(Manufacturing medium-sized fabrics)
700 g of strong flour, 0.1 g of yeast food (product name: C Oriental yeast oriental yeast), 3 g of yeast, 20 g of oil-in-water emulsified oil and fat composition for bread making obtained in Examples and Comparative Examples, and 420 g of water were added to the above-mentioned confectionery product. The dough was kneaded at a low speed of 2 minutes at a medium speed for 2 minutes with a bread mixer, and the resulting dough was fermented at 28 ° C. for 2 hours with a fermentation apparatus KM-62DX (manufactured by Kyodo Denki Seisakusho).
(Manufacturing of genuine kneading dough)
Add fermented medium-sized dough, 300 g of strong flour, 140 g of fine white sugar, 20 g of defatted milk powder, 16 g of salt, and 240 g of water, and knead with a confectionery bakery mixer for 3 minutes at low speed for 5 minutes at medium speed, and knead here. 150 g of fat (product name: Ambition Margarine NOF) was added and kneaded for 3 minutes at low speed for 4 minutes at medium speed to obtain a dough having a kneading temperature of 28 ° C. After allowing to stand for 30 minutes in the above-mentioned fermentation apparatus, the mixture was divided into 35 g, further allowed to stand for 30 minutes in the same apparatus, and then molded into a rod shape. The molded dough was arranged on a top plate and finally fermented in the above-mentioned dough conditioner (temperature 38 ° C., humidity 85%) for 50 minutes. After the final fermentation, it was fired in the above-mentioned baking oven (top heat 205 ° C., bottom heat 200 ° C.) for 8.5 minutes. After firing, it was allowed to cool at room temperature and placed in a bag.

(冷凍生地及びスクラッチ生地製法パンの評価)
実施例および比較例の製パン用水中油型乳化油脂組成物を用いた冷凍パンについて、「歯切れ」、「口溶け」、「ボリューム」、「風味」を評価した。これらの評価方法を以下に示す。なお、評価は、上記製造例において製パン用水中油型乳化油脂組成物を使用しない場合(無添加)をコントロールにし、これを100とした相対値で示す。
(Evaluation of frozen dough and scratch dough manufacturing method bread)
"Crisp", "melting in the mouth", "volume", and "flavor" were evaluated for the frozen bread using the oil-in-water emulsified oil / fat composition for bread making in Examples and Comparative Examples. These evaluation methods are shown below. In the evaluation, the case where the oil-in-water emulsified oil / fat composition for bread making is not used (no addition) in the above production example is controlled, and this is shown as a relative value of 100.

(歯切れ)
焼成後1日間、一定条件下で保管した焼成物の歯切れ感の測定には(株)山電製RHEONERIIを用いた。3cmの輪切りにした焼成物を測定台に置き、刃型プランジャーにて5mm/secで圧縮し刃が貫通するのに必要な破断荷重値(N)を測定した。得られた測定値を、コントロールとの相対値で示した。
(Crisp)
RHEONER II manufactured by Yamaden Co., Ltd. was used to measure the crispness of the fired product stored under certain conditions for one day after firing. A 3 cm sliced fired product was placed on a measuring table, compressed at 5 mm / sec with a blade-type plunger, and the breaking load value (N) required for the blade to penetrate was measured. The obtained measured values are shown as relative values to the control.

また、官能評価により効果を確認した。官能評価はパネラー10名によって行い、コントロールと比較して、咀嚼開始から5回までの咀嚼において、噛み切る際、歯への抵抗が少なく歯が通りやすいと感じる場合を「3点」、歯への抵抗への抵抗は感じられるがコントロールより歯が通りやすいと感じる場合を「2点」、コントロールと差異がないと感じる場合を「1点」として評価した。10名のパネラーの平均値が、2.5点以上の場合を「◎」、2点以上2.5点未満の場合を「〇」、1.5点以上2点未満の場合を「△」、1点以上1.5点未満の場合を「×」とした。
なお、評価結果は、各表の下部に「官能評価/破断荷重値の評価」として示した。
In addition, the effect was confirmed by sensory evaluation. Sensory evaluation was performed by 10 panelists, and compared to the control, when chewing up to 5 times from the start of chewing, when chewing off, there is less resistance to the teeth and it feels easy for the teeth to pass, "3 points", to the teeth The case where the resistance to the resistance was felt but the teeth were easier to pass than the control was evaluated as "2 points", and the case where the feeling was the same as the control was evaluated as "1 point". If the average value of the 10 panelists is 2.5 points or more, it is "◎", if it is 2 points or more and less than 2.5 points, it is "○", and if it is 1.5 points or more and less than 2 points, it is "△". The case of 1 point or more and less than 1.5 points was regarded as "x".
The evaluation results are shown at the bottom of each table as "sensory evaluation / evaluation of breaking load value".

(口溶け)
焼成後1日間、一定条件下で保管した焼成物のクラム部分を2cm四方の立法体に切り出し、その重量の1.2倍量の水分を含ませたサンプルを調整した。口溶け感の測定には(株)山電製RHEONERIIを用いた。サンプルを測定台に置き、円形プランジャーを用いて10mm/secで圧縮距離5mmから開始し、1mm/secずつ加算される動作を15回繰り返した。最終的に測定される崩壊荷重値(N)をパンの‘口溶け’とした。得られた測定値を、コントロールとの相対値で示した。
(Melting in the mouth)
For one day after firing, the crumb portion of the fired product stored under constant conditions was cut into a cube of 2 cm square, and a sample containing 1.2 times the weight of the cube was prepared. RHEONER II manufactured by Yamaden Co., Ltd. was used to measure the feeling of melting in the mouth. The sample was placed on a measuring table, and the operation of starting from a compression distance of 5 mm at 10 mm / sec using a circular plunger and adding 1 mm / sec at a time was repeated 15 times. The final measured collapse load value (N) was defined as the'melting in the mouth'of the bread. The obtained measured values are shown as relative values to the control.

また、官能評価により効果を確認した。官能評価はパネラー10名によって行い、コントロールと比較して、咀嚼するとすぐに口の中で固形物が溶けたと感じる場合を「3点」、コントロールと比較して少ない咀嚼回数で口の中で固形物が溶けたと感じた場合を「2点」、コントロールと差異がないと感じる場合を「1点」として評価した。10名のパネラーの平均値が、2.5点以上の場合を「◎」、2点以上2.5点未満の場合を「〇」、1.5点以上2点未満の場合を「△」、1点以上1.5点未満の場合を「×」とした。
なお、評価結果は、各表の下部に「官能評価/崩壊荷重値の評価」として示した。
In addition, the effect was confirmed by sensory evaluation. The sensory evaluation was performed by 10 panelists, and compared with the control, the case where the solid matter was felt to melt in the mouth immediately after chewing was "3 points", and the solid in the mouth was chewed less frequently than the control. The case where the object felt melted was evaluated as "2 points", and the case where it felt that there was no difference from the control was evaluated as "1 point". If the average value of the 10 panelists is 2.5 points or more, it is "◎", if it is 2 points or more and less than 2.5 points, it is "○", and if it is 1.5 points or more and less than 2 points, it is "△". The case of 1 point or more and less than 1.5 points was regarded as "x".
The evaluation results are shown at the bottom of each table as "sensory evaluation / evaluation of collapse load value".

(ボリューム)
焼成後1日間、一定条件下で保管した焼成物の比容積の測定には(株)アステックス製Selnac−WinVM2100Aレーザー体積計測機を用いた。パンの容積(cc)を測定し、容積をパンの重量で割ることで比容積(cc/g)とした。得られた測定値を、コントロールとの相対値で示した。
(volume)
A Sernac-WinVM2100A laser volume measuring device manufactured by Astex Co., Ltd. was used to measure the specific volume of the fired product stored under constant conditions for one day after firing. The volume (cc) of the bread was measured, and the volume was divided by the weight of the bread to obtain the specific volume (cc / g). The obtained measured values are shown as relative values to the control.

また、官能評価により効果を確認した。官能評価はパネラー10名によって行い、コントロールと比較して、明らかに外観に差異がある場合を「3点」、外観に差異がある場合を「2点」、やや外観に差異がある場合を「1点」、ほとんど差異がない場合を「0点」として評価した。10名のパネラーの平均値が、2.5点以上の場合を「◎」、2点以上の場合を「〇」、1.5点以上の場合を「△」、1.5点未満の場合を「×」とした。
なお、評価結果は、各表の下部に「官能評価/比容積の評価」として示した。
In addition, the effect was confirmed by sensory evaluation. The sensory evaluation was performed by 10 panelists, and when compared with the control, there was a clear difference in appearance as "3 points", a difference in appearance as "2 points", and a slight difference in appearance as "2 points". "1 point" and the case where there was almost no difference were evaluated as "0 point". When the average value of 10 panelists is 2.5 points or more, it is "◎", when it is 2 points or more, it is "○", when it is 1.5 points or more, it is "△", and when it is less than 1.5 points. Was set to "x".
The evaluation results are shown at the bottom of each table as "sensory evaluation / evaluation of specific volume".

(風味)
官能評価はパネラー10名によって行い、乳化剤特有の風味がなく、コントロールと比較して、同等であると感じる場合を「3点」、風味がやや異なると感じる場合を「2点」、やや乳化剤の特有の風味があると感じる場合を「1点」、乳化剤の特有の風味があると感じる場合を「0点」として評価した。10名のパネラーの平均値が、2.5点以上の場合を「◎」、2点以上の場合を「〇」、1.5点以上の場合を「△」、1.5点未満の場合を「×」とした。
なお、評価結果は、各表の下部に示した。
(Flavor)
The sensory evaluation was performed by 10 panelists, and "3 points" when the flavor was not peculiar to the emulsifier and felt to be equivalent to the control, "2 points" when the flavor was slightly different, and the emulsifier was slightly different. The case where the person felt that there was a peculiar flavor was evaluated as "1 point", and the case where the person felt that there was a peculiar flavor of the emulsifier was evaluated as "0 point". When the average value of 10 panelists is 2.5 points or more, it is "◎", when it is 2 points or more, it is "○", when it is 1.5 points or more, it is "△", and when it is less than 1.5 points. Was set to "x".
The evaluation results are shown at the bottom of each table.

表1を見ると、本発明で規定した製パン用水中油型乳化油脂組成物の実施例1〜14ではスクラッチ生地製法パンの比容積が向上していることが分かる。また、風味への影響は見られず、歯切れの破断荷重値、口溶けの崩壊荷重値が低下し、官能評価としては歯切れ、口溶けとも向上することが分かる。さらに、冷凍生地製法パンにおいても風味への影響は見られず、歯切れの破断荷重値、口溶けの崩壊荷重値が低下し、官能評価としては歯切れ、口溶けとも向上することが分かる。 Looking at Table 1, it can be seen that the specific volume of the scratch dough manufacturing method bread is improved in Examples 1 to 14 of the oil-in-water emulsified fat composition for bread making specified in the present invention. In addition, no effect on flavor was observed, and it was found that the breaking load value of crispness and the disintegration load value of melting in the mouth decreased, and the sensory evaluation improved both crispness and melting in the mouth. Further, it can be seen that the frozen dough manufacturing method bread does not have any effect on the flavor, the breaking load value of the crispness and the disintegration load value of the melting in the mouth decrease, and the sensory evaluation improves both the crispness and the melting in the mouth.

表2を見ると、液状油において本発明で規定する範囲外の場合、冷凍生地製法パン、スクラッチ生地製法パンでの口溶けが劣ることがわかる(比較例1、5、9)。コハク酸MAGにおいて本発明で規定する範囲を下回る場合、冷凍生地製法パンでの比容積が劣ることがわかり、配合量が規定範囲を上回る場合、風味が悪くなる(比較例3、7、8)。ソルビタン脂肪酸エステルにおいて本発明で規定する範囲を下回る場合、特に冷凍生地製法パンでの歯切れ、口溶けが劣ることが分かり、配合量が規定範囲を上回る場合、冷凍生地製法パンとスクラッチ生地製法パンのどちらにおいても、歯切れ、口溶けが劣るとともに、風味が悪くなる(比較例2、4、6、10)。

Looking at Table 2, it can be seen that when the liquid oil is out of the range specified in the present invention, the melt-in-the-mouth of the frozen dough-made bread and the scratch-dough-made bread is inferior (Comparative Examples 1, 5, and 9). When the succinic acid MAG is below the specified range in the present invention, it is found that the specific volume of the frozen dough manufacturing method bread is inferior, and when the blending amount exceeds the specified range, the flavor is deteriorated (Comparative Examples 3, 7, 8). .. If the sorbitan fatty acid ester is below the range specified in the present invention, especially if it is found that the frozen dough method bread is inferior in crispness and melting in the mouth, and the blending amount exceeds the specified range, either the frozen dough method bread or the scratch dough method bread In addition, the crispness and melting in the mouth are inferior, and the flavor is also deteriorated (Comparative Examples 2, 4, 6, and 10).

Claims (4)

50〜85質量%の水相部、15〜50質量%の油相部からなる製パン用水中油型乳化油脂組成物であって、
前記水相部には、水を5〜50質量%含有し、前記油相部には、次の成分(A1)、(A2)、(A3)を含有する、製パン用水中油型乳化油脂組成物。
(A1):液状油10〜30質量%
(A2):コハク酸モノアシルグリセロール2〜6質量%
(A3):ソルビタン脂肪酸エステル0.05〜5質量%
An oil-in-water emulsified oil / fat composition for bread making, which comprises 50 to 85% by mass of an aqueous phase portion and 15 to 50% by mass of an oil phase portion.
The aqueous phase portion contains 5 to 50% by mass of water, and the oil phase portion contains the following components (A1), (A2), and (A3). object.
(A1): Liquid oil 10 to 30% by mass
(A2): Monoacylglycerol succinate 2 to 6% by mass
(A3): Sorbitan fatty acid ester 0.05 to 5% by mass
請求項1に記載の製パン用水中油型乳化油脂組成物を含有する、パン生地。 A bread dough containing the oil-in-water emulsified oil / fat composition for bread making according to claim 1. 請求項1に記載の製パン用水中油型乳化油脂組成物を含有する、冷凍パン生地。 A frozen bread dough containing the oil-in-water emulsified oil / fat composition for bread making according to claim 1. 請求項2に記載のパン生地の焼成物、又は、請求項3に記載の冷凍パン生地の焼成物、からなるパン。


A bread comprising the baked product of the bread dough according to claim 2 or the baked product of the frozen bread dough according to claim 3.


JP2019064411A 2019-03-28 2019-03-28 Oil-in-water type emulsified fat composition for bread Pending JP2020162442A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023120382A1 (en) * 2021-12-23 2023-06-29 サントリーホールディングス株式会社 Oral composition and soft capsule agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023120382A1 (en) * 2021-12-23 2023-06-29 サントリーホールディングス株式会社 Oral composition and soft capsule agent

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