JP2020147656A - Sterilizing detergent composition - Google Patents

Abstract

To provide a sterilizing detergent composition comprising both an anionic surfactant and a cationic surfactant which has sufficiently high detergency and bactericidal power and produces no insoluble matter.SOLUTION: There is provided a sterilizing detergent composition which comprises an anionic surfactant and a cationic surfactant, wherein the anionic surfactant is at least one selected from the group consisting of a carboxylic acid type anionic surfactant, a sulfonic acid type anionic surfactant and a sulfuric acid ester-type anion surfactant, the cationic surfactant is at least one selected from the group consisting of an alkyl dimethyl hydroxyethyl ammonium salt, a dialkyl dimethylammonium salt (the alkyl chain length having 8 or less of carbon atoms) and a trialkyl type quaternary ammonium salt and the sterilizing detergent composition is used for cleaning applications of a tableware, kitchen, shop, glass, bathroom or toilet.SELECTED DRAWING: None

Description

The present invention relates to a disinfectant cleaning agent composition.

Conventionally, liquid cleaning agent compositions containing cationic surfactants have been known.

Patent Document 1 describes (A) nonionic surfactant 20 to 40% by mass, (B) cationic surfactant 2 to 10% by mass, (C) alkaline agent 1 to 5% by mass, and (D) water-soluble solvent 5. ~ 20% by mass, (E) 0.1 to 5% by mass of surfactant, and (F) water, and the pH in the undiluted solution (JIS-Z-8802: 1984 "pH measurement method") is 25 ° C. Described is a composition of a disinfectant cleaning agent for hard surfaces, which is characterized by being set to 12 or more.
Further, Patent Document 1 describes that the sterilizing action is improved by the cationic surfactant.

JP-A-2007-126581

Anionic surfactants have a surface-active effect, and anionic surfactants are known as one of the components used in a cleaning agent composition for improving detergency.

Usually, the hydrophilic groups of anionic surfactants are negatively charged and the hydrophilic groups of cationic surfactants are positively charged. Therefore, when the anionic surfactant is mixed with the cleaning agent composition containing the cationic surfactant, the hydrophilic group of the anionic surfactant and the hydrophilic group of the cationic surfactant are electrically attracted to each other, and the surface active effect is exhibited. descend.
As a result, there is a problem that the sterilizing power of the cleaning agent composition is lowered and an insoluble matter such as a precipitate is generated.

The present invention has been made to solve the above problems, and an object of the present invention is to provide an anionic surfactant and a cationic surfactant, which have sufficiently high sterilizing power and do not generate insoluble matter such as precipitate. It is to provide a disinfectant cleaning agent composition containing both.

As a result of diligent research, the present inventors have improved the sterilizing power of the sterilizing cleaning agent composition by combining a specific type of anionic surfactant and cation surfactant, and insoluble matter such as precipitate. The present invention was completed by finding that

That is, the sterilizing cleaning agent composition of the present invention is a sterilizing cleaning agent composition containing an anionic surfactant and a cationic surfactant, and the anionic surfactant is a carboxylic acid type anionic surfactant. , At least one selected from the group consisting of sulfonic acid type anionic surfactant and sulfate ester type anionic surfactant, and the above-mentioned cationic surfactant is an alkyldimethylhydroxyethylammonium salt or a dialkyldimethylammonium salt (alkyl chain). The length is at least one selected from the group consisting of a trialkyl-type quaternary ammonium salt (with 8 or less carbon atoms), and the disinfectant detergent composition is for tableware, kitchen, store cleaning, glass, etc. It is characterized in that it is used for cleaning purposes for bathrooms or toilets.

When an anionic surfactant is added to a disinfectant cleaning agent composition containing a cationic surfactant, the disinfecting power and cleaning power are lowered, and insoluble matter such as a precipitate may be generated. However, when the above-mentioned type of anionic surfactant and cationic surfactant are combined, the sterilizing power of the sterilizing cleaning agent composition is improved. In addition, insoluble matter such as precipitate does not occur in the disinfectant cleaning agent composition.

The anionic surfactants include linear alkylbenzene sulfonate, polyoxyethylene alkyl ether sulfate, α-olefin sulfonate, alkane sulfonate, polyoxyethylene alkyl ether acetate, fatty acid salt, and α-sulfo fatty acid methyl. It is desirable that it is at least one selected from the group consisting of ester salts, dialkyl sulfosuccinates and alkyl sulfates.
Combining these anionic surfactants with the above-mentioned cationic surfactants further improves the sterilizing power of the sterilizing cleaning agent composition. In addition, insoluble substances such as precipitates are less likely to occur in the disinfectant cleaning agent composition.

The disinfectant cleaning agent composition of the present invention further comprises at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin, and nonionic surfactants, semi-semi. It contains at least one type of surfactant selected from the group consisting of polar surfactants and amphoteric surfactants, and is preferably for tableware.
When the above solvent is contained, the compounding stability of the liquid cleaning agent composition is improved.
Further, when the above-mentioned surfactant is contained, the detergency against oil stains is improved.
From the above, when the above components are included, the composition is suitable as a disinfectant cleaning agent composition for tableware.

The disinfectant cleaning agent composition of the present invention further comprises at least one alkaline agent selected from the group consisting of alkali metal hydroxides, silicates, amine compounds and carbonates, and glycol-based solvents and alcohol-based solvents. It contains at least one solvent selected from the group consisting of ether solvents, ester solvents and glycerin, and is preferably for kitchen use.
When the above alkaline agent is contained, the detergency against oil stains is improved.
Further, when the above solvent is contained, the wettability to the cleaning surface is improved.
From the above, when the above components are included, the composition is suitable as a disinfectant cleaning agent composition for kitchens.

The disinfectant cleaning agent composition of the present invention further comprises at least one alkaline agent selected from the group consisting of amine compounds and carbonates, and glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin. It is desirable that it contains at least one solvent selected from the above group and is used for cleaning stores.
When the above alkaline agent is contained, the detergency against oil stains and hand stains is improved.
Further, when the above solvent is contained, the wettability to the cleaning surface is improved.
From the above, when the above components are included, the composition is suitable as a disinfectant cleaning agent composition for store cleaning.

The disinfectant cleaning agent composition of the present invention further comprises an amine compound or the like as an alkaline agent, and at least one solvent selected from the group consisting of a glycol solvent, an alcohol solvent, an ether solvent, an ester solvent and glycerin. Including, preferably for glass.
When the above amine compound is contained, wiping marks are less likely to remain on the glass surface.
From the above, when the above components are included, the composition is suitable as a disinfectant cleaning agent composition for glass.

The disinfectant cleaning agent composition of the present invention further comprises at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin, and aminocarboxylic acid-based chelating agents. At least one chelating agent selected from the group consisting of phosphonic acid-based chelating agents, hydroxycarboxylic acid-based chelating agents, phosphoric acid-based chelating agents and ether carboxylate-based chelating agents, and alkali metal hydroxides, carbonates and It contains at least one alkaline agent selected from the group consisting of amine compounds and is preferably for bathroom use.
When the above solvent is contained, the detergency against sebum and protein stains is improved.
When the above chelating agent is contained, the detergency against soap scum is improved.
When the above alkaline agent is contained, the detergency is improved.
From the above, when the above components are included, the composition is suitable as a disinfectant cleaning agent composition for bathrooms.

The disinfectant cleaning agent composition of the present invention is further selected from the group consisting of an aminocarboxylic acid chelating agent, a phosphonic acid chelating agent, a hydroxycarboxylic acid chelating agent, a phosphoric acid chelating agent and an ether carboxylate chelating agent. It is desirable that it contains at least one chelating agent to be used for toilets.
When the above chelating agent is contained, the detergency against urinary stone stains is improved.
From the above, when the above components are included, the composition is suitable as a disinfectant cleaning agent composition for toilets.

The disinfectant cleaning composition of the present invention contains a specific type of anionic surfactant and cationic surfactant. Therefore, the sterilizing power of the sterilizing cleaning agent composition is improved, and insoluble substances such as precipitates are not generated.

Hereinafter, the disinfectant cleaning agent composition of the present invention will be described while showing specific embodiments. However, the present invention is not limited to the following embodiments, and can be appropriately modified and applied without changing the gist of the present invention.

(First Embodiment)
The disinfectant cleaning agent composition according to the first embodiment of the present invention is a disinfectant cleaning agent composition for tableware.
The disinfectant cleaning agent composition according to the first embodiment of the present invention contains an anionic surfactant and a cationic surfactant.

The anionic surfactant is at least one selected from the group consisting of a carboxylic acid type anionic surfactant, a sulfonic acid type anionic surfactant and a sulfate ester type anionic surfactant.
Examples of the carboxylic acid type anionic surfactant include polyoxyethylene alkyl ether acetate and fatty acid salts.
Examples of the sulfonic acid type anionic surfactant include linear alkylbenzene sulfonate, α-olefin sulfonate, alkane sulfonate, α-sulfo fatty acid methyl ester salt, dialkyl sulfosuccinate and the like.
Examples of the sulfate ester type anionic surfactant include polyoxyethylene alkyl ether sulfate and alkyl sulfate.

The linear alkylbenzene sulfonate may be a sodium salt, a potassium salt, an ammonium salt, or an ethanolamine salt.
In particular, triethanolamine dodecylbenzene sulfonate is desirable.

The polyoxyethylene alkyl ether sulfate may be a sodium salt, a potassium salt, an ammonium salt, or an ethanolamine salt.
In particular, sodium polyoxyethylene lauryl sulfate or sodium polyoxyethylene tridecyl sulfate is desirable.

The α-olefin sulfonate may be a sodium salt, a potassium salt, an ammonium salt, or an ethanolamine salt.
In particular, sodium α-olefin sulfonate is desirable.

The alkane sulfonate may be a sodium salt, a potassium salt, an ammonium salt, or an ethanolamine salt.
In particular, it is desirable to use secondary sodium alkane sulfonate.

The polyoxyethylene alkyl ether acetate salt may be a sodium salt, a potassium salt, an ammonium salt, or an ethanolamine salt.
In particular, polyoxyethylene lauryl ether sodium acetate is desirable.

The fatty acid salt may be a sodium salt, a potassium salt, an ammonium salt, or an ethanolamine salt.
In particular, it is desirable that it is an ethanolamine salt.

The α-sulfo fatty acid methyl ester salt may be a sodium salt, a potassium salt, an ammonium salt, or an ethanolamine salt.
In particular, it is desirable to use α-sulfo beef tallow fatty acid ester sodium.

The alkyl sulfate may be a sodium salt, a potassium salt, an ammonium salt, or an ethanolamine salt.
In particular, sodium dodecyl sulfate is desirable.

The cationic surfactant is at least one selected from the group consisting of an alkyldimethylhydroxyethylammonium salt, a dialkyldimethylammonium salt (alkyl chain length is 8 or less carbon atoms) and a trialkyl quaternary ammonium salt.

The alkyldimethylhydroxyethylammonium salt is preferably alkyldimethyldihydroxyethylammonium chloride.

The dialkyldimethylammonium salt is preferably dioctyldimethylammonium chloride.

The trialkyl-type quaternary ammonium salt is preferably myristyltrimethylammonium chloride, lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, or tripolyoxyethylene stearylammonium chloride.

In the disinfectant cleaning agent composition according to the first embodiment of the present invention, the molar ratio of the anionic surfactant to the cationic surfactant is anionic surfactant / cationic surfactant = 0.01 to 99.0. It is preferably 0.10 to 50.0, and more preferably 0.10 to 50.0.

In the disinfectant cleaning agent composition according to the first embodiment of the present invention, the ratio of the total weight of the anionic surfactant and the cationic surfactant to the weight of the disinfectant cleaning agent composition is 3.0 to 80.0 weight. It is preferably%, and more preferably 5.0 to 50% by weight.

In the disinfectant cleaning agent composition according to the first embodiment of the present invention, the pH is preferably 4.0 to 10.0, and more preferably 6.0 to 8.0.

The disinfectant cleaning agent composition according to the first embodiment of the present invention further contains at least one surfactant selected from the group consisting of nonionic surfactants, semi-polar surfactants, and amphoteric surfactants. Is desirable.
Examples of these surfactants include alkyl betaine, alkyl amine oxide, polyoxyethylene alkyl ether, alkyl glucoside and the like.
The content of these surfactants is preferably 1.0 to 20.0% by weight, more preferably 3.0 to 10.0% by weight.
When these surfactants are included, foaming is improved.

The disinfectant cleaning agent composition according to the first embodiment of the present invention further contains at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin. Is desirable.
Examples of glycol-based solvents include ethylene glycol, propylene glycol, dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, polyethylene glycol, polypropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, and ethylene glycol mono. Propyl ether, ethylene glycol monobutyl ether, ethylene glycol t-butyl ether, ethylene glycol monohexyl ether, ethylene glycol monophenyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene Glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, triethylene glycol monoethyl ether, tri Examples thereof include ethylene glycol monobutyl ether.
As alcohol solvents, methyl alcohol, ethyl alcohol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methoxyethanol, 2-ethoxyethanol, benzyl alcohol, 3-methoxy-3-methyl-1 -Butanol, polyoxyethylene benzyl alcohol and the like can be mentioned.
Examples of the ether solvent include diethyl ether, diisopropyl ether, dibutyl ether and the like.
As the ester solvent, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, 3-methoxy-3-methyl Examples thereof include -1-butyl acetate.
The content of these solvents is preferably 1.0 to 20.0% by weight, more preferably 2.0 to 15.0% by weight.
When these solvents are contained, the compounding stability of the liquid cleaning agent composition is improved.

The disinfectant cleaning agent composition according to the first embodiment of the present invention may further contain a solubilizing agent and a chelating agent.

(Example 1-1) to (Example 1-40) and (Comparative Example 1-1) to (Comparative Example 1-5)
Disinfectant cleaning agent compositions according to Examples 1-1 to 1-40 and disinfectant cleaning agent compositions according to Comparative Examples 1-1 to 1-5 with the formulations shown in Tables 1 to 4. Was produced.
The numerical values in Tables 1 to 4 indicate "% by weight".

<Turbidity evaluation>
The turbidity of the disinfectant cleaning agent composition according to each Example and each Comparative Example was evaluated by the following procedure. The results are shown in Tables 1-4.
The turbidity of the liquid cleaning agent composition described in Examples was measured using an ultraviolet-visible near-infrared spectrophotometer (model number: V-670DS, manufactured by JASCO Corporation) and a spectrophotometer cell 10 mm.
The evaluation criteria are as follows.
〇: The turbidity is less than 150 degrees (formazine).
X: The turbidity is 150 degrees (formazine) or more.

<Detergency evaluation>
The detergency of the disinfectant cleaning agent composition according to each example and each comparative example was evaluated by the following procedure. The results are shown in Tables 1-4.
A melamine plate (6 cm x 6 cm) was coated with 0.2 g of a complex stain (soybean white squeezed oil: beef tallow: cake flour = 85: 5:10) and left for 10 minutes to prepare a model stain.
The disinfectant cleaning agent composition according to each Example and each Comparative Example was diluted 30-fold with water.
Next, the dirty melamine plate was immersed in the cleaning liquid, and the degree of removal of the stain after immersion for 3 minutes was visually evaluated.
The evaluation criteria are as follows.
◯: Dirt is removed by 50% or more.
X: Dirt is removed by less than 50%.

<Test of sterilization effect on E. coli>
(1) were inoculated with E. coli (Escherichia coli NBRC3972) in nutrient broth medium, was Kin'eki cultured for 24 hours at 35 ℃.
(2) The disinfectant cleaning agent composition of each Example and each Comparative Example and the bacterial solution were mixed at a ratio (volume) of 99: 1, and after 1 minute at room temperature, 1 platinum loop was transplanted to SCDLP medium. After culturing at 35 ° C. for 48 hours, the survival of the bacterium was determined.
(3) When turbidity was observed in the SCDLP medium, it was judged that the bacteria did not die, and when no turbidity was observed, it was judged that the bacteria had died. The results are shown in Tables 1-4.
The evaluation criteria are as follows.
〇: Escherichia coli has died.
X: Escherichia coli was not killed.

<Staphylococcus aureus eradication effect test>
Except for using Staphylococcus aureus NBRC12732 instead of Escherichia coli, the above <Sterilization test 1: Escherichia coli eradication effect test>
Similarly, the bactericidal effect on Staphylococcus aureus was tested. The results are shown in Tables 1-4.
The evaluation criteria are as follows.
〇: Staphylococcus aureus has died.
X: Staphylococcus aureus did not die.

<Test of sterilization effect on Campylobacter>
(1) Campylobacter jejuni subsp. Jejuni ATCC 33560 with 5% horse defibrotic blood added Blood Agar Base No. After microaerobic culture at 35 ° C. ± 1 ° C. for 2 to 3 days, the cells were suspended in physiological saline.
(2) The disinfectant cleaning agent composition of each Example and each Comparative Example and the bacterial solution were mixed at a ratio (volume) of 100: 1, and after 1 minute at room temperature, diluted 10-fold with SCDLP medium. The action of the composition on the fungus was stopped.
(3) Add 5% horse defibered blood to the stop solution Blood Agar Base No. After smearing to No. 2 and microaerobic culturing at 35 ° C. ± 1 ° C. for 5 days, the killing of the bacterium was judged based on the presence or absence of colonies. The results are shown in Tables 1-4.
The evaluation criteria are as follows.
〇: No colony was detected.
X: Colonies were detected.

As shown in Tables 1 to 3, the disinfectant cleaning agent composition according to each example was found to have sufficient detergency.
Further, it was found that the disinfectant cleaning agent composition according to each example had a good turbidity evaluation and did not generate insoluble matter such as precipitate.
In addition, it was found that the disinfectant cleaning agent composition according to each example exhibits sufficient disinfecting power against Escherichia coli, Staphylococcus aureus and Campylobacter, which cause food poisoning.

(Second Embodiment)
The disinfectant cleaning agent composition according to the second embodiment of the present invention is a disinfectant cleaning agent composition for kitchens.
The disinfectant cleaning agent composition according to the second embodiment of the present invention contains an anionic surfactant and a cationic surfactant.

The desirable anionic surfactant and cationic surfactant contained in the disinfectant cleaning agent composition according to the second embodiment of the present invention are preferably contained in the disinfectant cleaning agent composition according to the first embodiment of the present invention. Same as anionic and cationic surfactants.

In the disinfectant cleaning agent composition according to the second embodiment of the present invention, the molar ratio of the anionic surfactant to the cationic surfactant is anionic surfactant / cationic surfactant = 0.01 to 99.0. It is preferably 0.10 to 50.0, and more preferably 0.10 to 50.0.

In the disinfectant cleaning agent composition according to the second embodiment of the present invention, the ratio of the total weight of the anionic surfactant and the cationic surfactant to the weight of the disinfectant cleaning agent composition is 0.5 to 80.0 weight by weight. It is preferably%, and more preferably 5.0 to 50% by weight.

In the disinfectant cleaning agent composition according to the second embodiment of the present invention, the pH is preferably 7 to 14, and more preferably 11 to 14.

The disinfectant cleaning agent composition according to the second embodiment of the present invention preferably contains at least one alkaline agent selected from the group consisting of alkali metal hydroxides, silicates, amine compounds and carbonates. ..
Examples of the alkali metal hydroxide include potassium hydroxide and sodium hydroxide.
Examples of the silicate include sodium metasilicate, sodium orthosilicate, potassium silicate and the like.
Examples of the amine compound include monoethanolamine, propanolamine, monoisopropanolamine and the like.
Examples of the carbonate include potassium carbonate, sodium carbonate and the like.
The content of these alkaline agents is preferably 1 to 30% by weight, more preferably 5 to 20% by weight.
When the above alkaline agent is contained, the detergency against accumulated oil stains is improved.

The disinfectant cleaning agent composition according to the second embodiment of the present invention may contain at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin. desirable.
Examples of glycol-based solvents include ethylene glycol, propylene glycol, dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, polyethylene glycol, polypropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, and ethylene glycol mono. Propyl ether, ethylene glycol monobutyl ether, ethylene glycol t-butyl ether, ethylene glycol monohexyl ether, ethylene glycol monophenyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene Glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, triethylene glycol monoethyl ether, tri Examples thereof include ethylene glycol monobutyl ether.
Examples of the alcohol solvent include methyl alcohol, ethyl alcohol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methoxyethanol, 2-ethoxyethanol, benzyl alcohol, 3-methoxy-3-methyl-1. -Butanol, polyoxyethylene benzyl alcohol and the like can be mentioned.
The content of these solvents is preferably 1 to 30% by weight, more preferably 5 to 20% by weight.
When the above solvent is contained, the wettability to the cleaning surface is improved.

The disinfectant cleaning agent composition according to the second embodiment of the present invention may contain a solubilizing agent and a chelating agent.

(Example 2-1) to (Example 2-40) and (Comparative Example 2-1) to (Comparative Example 2-5)
Disinfectant cleaning agent compositions according to Examples 2-1 to Example 2-40 and disinfectant cleaning agent compositions according to Comparative Examples 2-1 to 2-5 with the formulations shown in Tables 5-8. Was produced.
The numerical values in Tables 5 to 8 indicate "% by weight".

<Turbidity evaluation>
The turbidity evaluation of the disinfectant cleaning agent composition according to each Example and each comparative example is as follows in the same manner as the <turbidity evaluation> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. I did it in the procedure. The results are shown in Tables 5-8.

<Detergency evaluation>
The detergency of the disinfectant cleaning agent composition according to each example and each comparative example was evaluated by the following procedure. The results are shown in Tables 5-8.
0.2 g of composite stain (soybean white squeezed oil: beef tallow: cake flour = 85: 5:10) was applied to a stainless steel plate (6 cm × 6 cm) and left for 10 minutes to prepare a model stain.
The disinfectant cleaning agent composition according to each Example and each Comparative Example was diluted 20-fold with water.
Next, the dirty stainless steel plate was immersed in the cleaning liquid, and the degree of removal of the stain after immersion for 3 minutes was visually evaluated.
The evaluation criteria are as follows.
◯: Dirt is removed by 50% or more.
X: Dirt is removed by less than 50%.

<Test of sterilization effect on E. coli>
The sterilization cleaning agent composition according to the first embodiment of the present invention is sterilized against Escherichia coli by the same method as the <sterilization effect test against Escherichia coli>. The effect was tested. The results are shown in Tables 5-8.

<Staphylococcus aureus eradication effect test>
The yellow grapes of the disinfectant cleaning agent composition according to each Example and each comparative example in the same manner as the <sterilization effect test against Staphylococcus aureus> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. The sterilizing effect on staphylococci was tested. The results are shown in Tables 5-8.

<Test of sterilization effect on Campylobacter>
Disinfection of the disinfectant cleaning agent composition according to the first embodiment of the present invention against Campylobacter in the same manner as in <Test of disinfectant effect on Campylobacter>. The effect was tested. The results are shown in Tables 5-8.

As shown in Tables 5 to 7, it was found that the disinfectant cleaning agent composition according to each example had sufficient detergency.
Further, it was found that the disinfectant cleaning agent composition according to each example had a good turbidity evaluation and did not generate insoluble matter such as precipitate.
In addition, it was found that the disinfectant cleaning agent composition according to each example exhibits sufficient disinfecting power against Escherichia coli, Staphylococcus aureus and Campylobacter, which cause food poisoning.

(Third Embodiment)
The disinfectant cleaning agent composition according to the third embodiment of the present invention is a disinfectant cleaning agent composition for store cleaning.
The disinfectant cleaning agent composition according to the third embodiment of the present invention contains an anionic surfactant and a cationic surfactant.
In addition, in this specification, for store cleaning means the use for cleaning floors, walls, etc. of restaurants, supermarkets, kitchens of hotels, etc., bakeries, etc.

The desirable anionic surfactant and cationic surfactant contained in the disinfectant cleaning agent composition according to the third embodiment of the present invention are preferably contained in the disinfectant cleaning agent composition according to the first embodiment of the present invention. Same as anionic and cationic surfactants.

In the disinfectant cleaning agent composition according to the third embodiment of the present invention, the molar ratio of the anionic surfactant to the cationic surfactant is anionic surfactant / cationic surfactant = 0.01 to 99.0. It is preferably 0.10 to 50.0, and more preferably 0.10 to 50.0.

In the disinfectant cleaning agent composition according to the third embodiment of the present invention, the ratio of the total weight of the anionic surfactant and the cationic surfactant to the weight of the disinfectant cleaning agent composition is 0.1 to 10% by weight. It is preferably present, and more preferably 0.5 to 5.0% by weight.

In the disinfectant cleaning agent composition according to the third embodiment of the present invention, the pH is preferably 6 to 12, more preferably 9 to 11.

The disinfectant cleaning agent composition according to the third embodiment of the present invention preferably contains at least one alkaline agent selected from the group consisting of amine compounds and carbonates.
Examples of the amine compound include monoethanolamine, propanolamine, monoisopropanolamine, diethanolamine and the like.
Examples of the carbonate include potassium carbonate, sodium carbonate, potassium hydrogen carbonate, sodium hydrogen carbonate and the like.
The content of these alkaline agents is preferably 0.1 to 10.0% by weight, more preferably 0.5 to 5.0% by weight.
When the above alkaline agent is contained, the detergency against accumulated oil stains is improved.

The disinfectant cleaning agent composition according to the third embodiment of the present invention preferably contains at least one solvent selected from the group consisting of a glycol solvent, an alcohol solvent, an ether solvent, an ester solvent, and glycerin. ..
Examples of glycol-based solvents include ethylene glycol, propylene glycol, dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, polyethylene glycol, polypropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, and ethylene glycol mono. Propyl ether, ethylene glycol monobutyl ether, ethylene glycol t-butyl ether, ethylene glycol monohexyl ether, ethylene glycol monophenyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene Glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, triethylene glycol monoethyl ether, tri Examples thereof include ethylene glycol monobutyl ether.
Examples of the alcohol solvent include methyl alcohol, ethyl alcohol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methoxyethanol, 2-ethoxyethanol, benzyl alcohol, 3-methoxy-3-methyl-1. -Butanol, polyoxyethylene benzyl alcohol and the like can be mentioned.
Examples of the ether solvent include diethyl ether, diisopropyl ether, dibutyl ether and the like.
As the ester solvent, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, 3-methoxy-3-methyl Examples thereof include -1-butyl acetate.
The content of these solvents is preferably 0.5 to 10.0% by weight, more preferably 1.0 to 5.0% by weight.
When the above solvent is contained, the wettability to the cleaning surface is improved.

The disinfectant cleaning agent composition according to the third embodiment of the present invention may further contain a chelating agent.

(Example 3-1) to (Example 3-42) and (Comparative Example 3-1) to (Comparative Example 3-5)
The disinfectant cleaning agent compositions according to Examples 3-1 to 3-42 and Comparative Examples 3-1 to 3-5 were prepared with the formulations shown in Tables 9 to 12.
The numerical values in Tables 9 to 12 indicate "% by weight".

<Turbidity evaluation>
The turbidity evaluation of the disinfectant cleaning agent composition according to each Example and each comparative example is as follows in the same manner as the <turbidity evaluation> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. I did it in the procedure. The results are shown in Tables 9-12.

<Detergency evaluation>
The detergency of the disinfectant cleaning agent composition according to each example and each comparative example was evaluated by the following procedure. The results are shown in Tables 9-12.
A polypropylene plate (86 mm × 26 mm) was coated with 0.1 g of a composite stain (triolein: oleic acid: squalene = 60:30: 10) and left for 60 minutes to prepare a model stain.
Next, the soiled polypropylene plate was immersed in the undiluted solution of the cleaning solution, and the degree of removal of the stain after immersion for 1 minute was visually evaluated.
The evaluation criteria are as follows.
◯: Dirt is removed by 50% or more.
X: Dirt is removed by less than 50%.

<Test of sterilization effect on E. coli>
The sterilization cleaning agent composition according to the first embodiment of the present invention is sterilized against Escherichia coli by the same method as the <sterilization effect test against Escherichia coli>. The effect was tested. The results are shown in Tables 9-12.

<Staphylococcus aureus eradication effect test>
The yellow grapes of the disinfectant cleaning agent composition according to each Example and each comparative example in the same manner as the <sterilization effect test against Staphylococcus aureus> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. The sterilizing effect on staphylococci was tested. The results are shown in Tables 9-12.

<Sterilization effect test against Salmonella>
Similar to the <sterilization effect test on Escherichia coli> of the sterilization cleaning agent composition according to the first embodiment of the present invention, except that Salmonella enteridis NBRC3313 was used instead of Escherichia coli, the sterilization effect on Salmonella. Was tested. The results are shown in Tables 9-12.
The evaluation criteria are as follows.
〇: Salmonella has died.
X: Salmonella did not die.

As shown in Tables 9 to 11, it was found that the disinfectant cleaning agent compositions according to each example had sufficient detergency.
Further, it was found that the disinfectant cleaning agent composition according to each example had a good turbidity evaluation and did not generate insoluble matter such as precipitate.
In addition, it was found that the disinfectant cleaning agent composition according to each example exhibits sufficient disinfectant power against Escherichia coli, Staphylococcus aureus and Salmonella, which cause food poisoning.

(Fourth Embodiment)
The disinfectant cleaning agent composition according to the fourth embodiment of the present invention is a disinfectant cleaning agent composition for glass.
The disinfectant cleaning agent composition according to the fourth embodiment of the present invention contains an anionic surfactant and a cationic surfactant.

The desirable anionic surfactant and cationic surfactant contained in the disinfectant cleaning agent composition according to the fourth embodiment of the present invention are preferably contained in the disinfectant cleaning agent composition according to the first embodiment of the present invention. Same as anionic and cationic surfactants.

In the disinfectant cleaning agent composition according to the fourth embodiment of the present invention, the molar ratio of the anionic surfactant to the cationic surfactant is anionic surfactant / cationic surfactant = 0.01 to 99.0. It is preferably 0.10 to 50.0, and more preferably 0.10 to 50.0.

In the disinfectant cleaning agent composition according to the fourth embodiment of the present invention, the ratio of the total weight of the anionic surfactant and the cationic surfactant to the weight of the disinfectant cleaning agent composition is 0.1 to 10.0 weight. It is preferably%, and more preferably 0.5 to 5.0% by weight.

In the disinfectant cleaning agent composition according to the fourth embodiment of the present invention, the pH is preferably 6 to 12, more preferably 9 to 11.

It is desirable that the disinfectant cleaning agent composition according to the fourth embodiment of the present invention contains an amine compound as an alkaline agent.
Examples of the amine compound include monoethanolamine, morpholine, monoisopropanolamine and the like.
The content of these amine compounds is preferably 0.1 to 10.0% by weight, more preferably 0.5 to 5.0% by weight.
When the above amine compound is contained, wiping marks are less likely to remain on the glass surface.

The disinfectant cleaning agent composition according to the fourth embodiment of the present invention may contain at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin. desirable.
Examples of glycol-based solvents include ethylene glycol, propylene glycol, dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, polyethylene glycol, polypropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, and ethylene glycol mono. Propyl ether, ethylene glycol monobutyl ether, ethylene glycol t-butyl ether, ethylene glycol monohexyl ether, ethylene glycol monophenyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene Glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, triethylene glycol monoethyl ether, tri Examples thereof include ethylene glycol monobutyl ether.
Examples of the alcohol solvent include methyl alcohol, ethyl alcohol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methoxyethanol, 2-ethoxyethanol, benzyl alcohol, 3-methoxy-3-methyl-1. -Butanol, polyoxyethylene benzyl alcohol and the like can be mentioned.
Examples of the ether solvent include diethyl ether, diisopropyl ether, dibutyl ether and the like.
As the ester solvent, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, 3-methoxy-3-methyl Examples thereof include -1-butyl acetate.
The content of these solvents is preferably 0.5 to 10.0% by weight, more preferably 1.0 to 5.0% by weight.
When the above solvent is contained, quick-drying property is improved.

The disinfectant cleaning agent composition according to the fourth embodiment of the present invention may further contain a chelating agent.

(Example 4-1) to (Example 4-42) and (Comparative Example 4-1) to (Comparative Example 4-5)
The disinfectant cleaning agent compositions according to Examples 4-1 to 4-42 and Comparative Examples 4-1 to 4-5 were prepared with the formulations shown in Tables 13 to 16.
The numerical values in Tables 13 to 16 indicate "% by weight".

<Turbidity evaluation>
The turbidity evaluation of the disinfectant cleaning agent composition according to each Example and each comparative example is as follows in the same manner as the <turbidity evaluation> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. I did it in the procedure. The results are shown in Tables 13-16.

<Detergency evaluation>
The detergency of the disinfectant cleaning agent composition according to each example and each comparative example was evaluated by the following procedure. The results are shown in Tables 13-16.
0.15 g of a composite stain (triolein: oleic acid: squalene = 60:30: 10) was applied to a slide glass (72 mm × 52 mm) and left for 60 minutes to prepare a model stain.
Next, the stained slide glass was immersed in the undiluted solution of the cleaning solution, and the degree of removal of the stain after immersion for 1 minute was visually evaluated.
The evaluation criteria are as follows.
◯: Dirt is removed by 50% or more.
X: Dirt is removed by less than 50%.

<Test of sterilization effect on E. coli>
The sterilization cleaning agent composition according to the first embodiment of the present invention is sterilized against Escherichia coli by the same method as the <sterilization effect test against Escherichia coli>. The effect was tested. The results are shown in Tables 13-16.

<Staphylococcus aureus eradication effect test>
The yellow grapes of the disinfectant cleaning agent composition according to each Example and each comparative example in the same manner as the <sterilization effect test against Staphylococcus aureus> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. The sterilizing effect on staphylococci was tested. The results are shown in Tables 13-16.

<Sterilization effect test against Salmonella>
Disinfection of the disinfectant cleaning agent composition according to the third embodiment of the present invention against Salmonella in the same manner as in <Test of disinfectant effect against Salmonella>. The effect was tested. The results are shown in Tables 13-16.

As shown in Tables 13 to 15, it was found that the disinfectant cleaning agent compositions according to each example had good turbidity evaluation and did not generate insoluble matter such as precipitate.
Further, it was found that the disinfectant cleaning agent composition according to each example has sufficient detergency.
In addition, it was found that the disinfectant cleaning agent composition according to each example showed sufficient disinfecting power against Escherichia coli, Staphylococcus aureus and Salmonella.

(Fifth Embodiment)
The disinfectant cleaning agent composition according to the fifth embodiment of the present invention is a disinfectant cleaning agent composition for a bathroom.
The disinfectant cleaning agent composition according to the fifth embodiment of the present invention contains an anionic surfactant and a cationic surfactant.

The desirable anionic surfactant and cationic surfactant contained in the disinfectant cleaning agent composition according to the fifth embodiment of the present invention are preferably contained in the disinfectant cleaning agent composition according to the first embodiment of the present invention. Same as anionic and cationic surfactants.

In the disinfectant cleaning agent composition according to the fifth embodiment of the present invention, the molar ratio of the anionic surfactant to the cationic surfactant is anionic surfactant / cationic surfactant = 0.01 to 99.0. It is preferably 0.10 to 50.0, and more preferably 0.10 to 50.0.

In the disinfectant cleaning agent composition according to the fifth embodiment of the present invention, the ratio of the total weight of the anionic surfactant and the cationic surfactant to the weight of the disinfectant cleaning agent composition is 0.5 to 20.0 weight by weight. It is preferably%, and more preferably 3.0 to 10.0% by weight.

In the disinfectant cleaning agent composition according to the fifth embodiment of the present invention, the pH is preferably 6 to 12, more preferably 7 to 9.

The disinfectant cleaning agent composition according to the fifth embodiment of the present invention may contain at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin. desirable.
Examples of glycol-based solvents include ethylene glycol, propylene glycol, dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, polyethylene glycol, polypropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, and ethylene glycol mono. Propyl ether, ethylene glycol monobutyl ether, ethylene glycol t-butyl ether, ethylene glycol monohexyl ether, ethylene glycol monophenyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene Glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, triethylene glycol monoethyl ether, tri Examples thereof include ethylene glycol monobutyl ether.
As alcohol solvents, methyl alcohol, ethyl alcohol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methoxyethanol, 2-ethoxyethanol, benzyl alcohol, 3-methoxy-3-methyl-1 -Butanol, polyoxyethylene benzyl alcohol and the like can be mentioned.
Examples of the ether solvent include diethyl ether, diisopropyl ether, dibutyl ether and the like.
As the ester solvent, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, 3-methoxy-3-methyl Examples thereof include -1-butyl acetate.
The content of these solvents is preferably 1.0 to 20.0% by weight, more preferably 3.0 to 10.0% by weight.
When the above solvent is contained, the wettability to the cleaning surface is improved.

The disinfectant cleaning agent composition according to the fifth embodiment of the present invention includes an aminocarboxylic acid chelating agent, a phosphonic acid chelating agent, a hydroxycarboxylic acid chelating agent, a phosphoric acid chelating agent, and an ether carboxylate chelating agent. It is desirable to include at least one chelating agent selected from the group consisting of.
Examples of aminocarboxylic acid-based chelating agents include ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), methylglycine diacetic acid (MGDA), diethylenetriaminetetraacetic acid (DTPA), hydroxyethylethylenediaminetriacetic acid (HEDTA), and triethylenetetramine. Hexacetic acid (TTHA), glutamate diacetic acid (GLDA), hydroxyethyliminodiacetic acid (HIDA), dihydroxyethylglycine (DHEG), 1,3-propanediaminetetraacetic acid (PDTA), 1,3-diamino-2-hydroxy Examples thereof include propanehexacetic acid (DPTA-OH), diacetic acid aspartate (ASDA), ethylenediaminesuccinic acid (EDDS) and salts thereof.
Examples of the phosphonic acid-based chelating agent include hydroxyetidronic acid phosphonic acid (HEDP), nitrilotrimethylenephosphonic acid (NTMP), phosphonobutanetricarboxylic acid (PBTC), and ethylenediaminetetramethylenephosphonic acid (EDTPP).
Examples thereof include hydroxycarboxylic acid chelating agents, malic acid, citric acid, lactic acid, tartaric acid, gluconic acid or salts thereof.
Examples of the phosphoric acid-based chelating agent include tripolyphosphoric acid and hexametaphosphate.
The content of these chelating agents is preferably 1.0 to 10.0% by weight, more preferably 2.0 to 6.0% by weight.
When the above chelating agent is contained, the detergency against soap scum is improved.

The disinfectant cleaning agent composition according to the fifth embodiment of the present invention preferably contains at least one alkaline agent selected from the group consisting of alkali metal hydroxides, carbonates and amine compounds.
Examples of the alkali metal hydroxide include potassium hydroxide and sodium hydroxide.
Examples of the carbonate include potassium carbonate, sodium carbonate, potassium hydrogen carbonate, sodium hydrogen carbonate and the like.
Examples of the amine compound include monoethanolamine and isopropanolamine.

(Example 5-1) to (Example 5-42) and (Comparative Example 5-1) to (Comparative Example 5-5)
The disinfectant cleaning agent compositions according to Examples 5-1 to 5-42 and Comparative Examples 5-1 to 5-5 were prepared with the formulations shown in Tables 17 to 20.
The numerical values in Tables 17 to 20 indicate "% by weight".

<Turbidity evaluation>
The turbidity evaluation of the disinfectant cleaning agent composition according to each Example and each comparative example is as follows in the same manner as the <turbidity evaluation> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. I did it in the procedure. The results are shown in Tables 17-20.

<Detergency evaluation>
The detergency of the disinfectant cleaning agent composition according to each example and each comparative example was evaluated by the following procedure. The results are shown in Tables 17-20.
0.2 g of composite stain (triolein: oleic acid: squalene = 60:30: 10) was applied to an FRP plate (75 mm × 70 mm) and left for 60 minutes to prepare a model stain.
Next, the dirty FRP plate was immersed in the undiluted solution of the cleaning solution, and the degree of removal of the stain after immersion for 1 minute was visually evaluated.
The evaluation criteria are as follows.
◯: Dirt is removed by 50% or more.
X: Dirt is removed by less than 50%.

<Test of sterilization effect on E. coli>
The sterilization cleaning agent composition according to the first embodiment of the present invention is sterilized against Escherichia coli by the same method as the <sterilization effect test against Escherichia coli>. The effect was tested. The results are shown in Tables 17-20.

<Staphylococcus aureus eradication effect test>
The yellow grapes of the disinfectant cleaning agent composition according to each Example and each comparative example in the same manner as the <sterilization effect test against Staphylococcus aureus> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. The sterilizing effect on staphylococci was tested. The results are shown in Tables 17-20.

<Sterilization effect test against Pseudomonas aeruginosa>
The disinfectant cleaning agent composition according to the third embodiment of the present invention is subjected to the same method as the <sterilization effect test against Salmonella> against Pseudomonas aeruginosa of the disinfectant cleaning agent composition according to each Example and each comparative example. The sterilization effect was tested. The results are shown in Tables 17-20.

As shown in Tables 17 to 19, it was found that the disinfectant cleaning agent compositions according to each example had good turbidity evaluation and did not generate insoluble matter such as precipitate.
Further, it was found that the disinfectant cleaning agent composition according to each example has sufficient detergency.
In addition, it was found that the disinfectant cleaning agent composition according to each example showed sufficient disinfecting power against Escherichia coli, Staphylococcus aureus and Pseudomonas aeruginosa.

(Sixth Embodiment)
The disinfectant cleaning agent composition according to the sixth embodiment of the present invention is a disinfectant cleaning agent composition for toilets.
The disinfectant cleaning agent composition according to the sixth embodiment of the present invention contains an anionic surfactant and a cationic surfactant.

The desirable anionic surfactant and cationic surfactant contained in the disinfectant cleaning agent composition according to the sixth embodiment of the present invention are preferably contained in the disinfectant cleaning agent composition according to the first embodiment of the present invention. Same as anionic and cationic surfactants.

In the disinfectant cleaning agent composition according to the sixth embodiment of the present invention, the molar ratio of the anionic surfactant to the cationic surfactant is anionic surfactant / cationic surfactant = 0.01 to 99.0. It is preferably 0.10 to 50.0, and more preferably 0.10 to 50.0.

In the disinfectant cleaning agent composition according to the sixth embodiment of the present invention, the ratio of the total weight of the anionic surfactant and the cationic surfactant to the weight of the disinfectant cleaning agent composition is 0.5 to 20.0 weight by weight. It is preferably%, and more preferably 3.0 to 10.0% by weight.

In the disinfectant cleaning agent composition according to the sixth embodiment of the present invention, the pH is preferably 6 to 12, more preferably 7 to 9.

The disinfectant cleaning agent composition according to the sixth embodiment of the present invention includes an aminocarboxylic acid chelating agent, a phosphonic acid chelating agent, a hydroxycarboxylic acid chelating agent, a phosphoric acid chelating agent, and an ether carboxylate chelating agent. It is desirable to include at least one chelating agent selected from the group consisting of.
Examples of aminocarboxylic acid-based chelating agents include ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), methylglycine diacetic acid (MGDA), diethylenetriaminetetraacetic acid (DTPA), hydroxyethylethylenediaminetriacetic acid (HEDTA), and triethylenetetramine. Hexacetic acid (TTHA), glutamate diacetic acid (GLDA), hydroxyethyliminodiacetic acid (HIDA), dihydroxyethylglycine (DHEG), 1,3-propanediaminetetraacetic acid (PDTA), 1,3-diamino-2-hydroxy Examples thereof include propanehexacetic acid (DPTA-OH), diacetic acid aspartate (ASDA), ethylenediaminesuccinic acid (EDDS) and salts thereof.
Examples of the phosphonic acid-based chelating agent include hydroxyetidronic phosphonic acid (HEDP), nitrilotrimethylenephosphonic acid (NTMP), phosphonobutanetricarboxylic acid (PBTC), and ethylenediaminetetramethylenephosphonic acid (EDTPP).
Examples thereof include hydroxycarboxylic acid chelating agents, malic acid, citric acid, lactic acid, tartaric acid, gluconic acid or salts thereof.
Examples of the phosphoric acid-based chelating agent include tripolyphosphoric acid and hexametaphosphate.
The content of these chelating agents is preferably 0.5 to 10.0% by weight, more preferably 1.0 to 5.0% by weight.
When the above chelating agent is contained, the detergency against urinary stone stains is improved.

(Example 6-1) to (Example 6-42) and (Comparative Example 6-1) to (6-5)
The disinfectant cleaning agent compositions according to Examples 6-1 to 6-42 and Comparative Examples 6-1 to 6-5 were prepared with the formulations shown in Tables 21 to 24.
The numerical values in Tables 21 to 24 indicate "% by weight".

<Turbidity evaluation>
The turbidity evaluation of the disinfectant cleaning agent composition according to each Example and each comparative example is as follows in the same manner as the <turbidity evaluation> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. I did it in the procedure. The results are shown in Tables 21-24.

<Detergency evaluation>
The detergency evaluation was performed on the disinfectant cleaning agent compositions according to each Example and each comparative example by the same method as the <detergency evaluation> of the disinfectant cleaning agent composition according to the third embodiment of the present invention. ..

<Test of sterilization effect on E. coli>
The sterilization cleaning agent composition according to the first embodiment of the present invention is sterilized against Escherichia coli by the same method as the <sterilization effect test against Escherichia coli>. The effect was tested. The results are shown in Tables 21-24.

<Staphylococcus aureus eradication effect test>
The yellow grapes of the disinfectant cleaning agent composition according to each Example and each comparative example in the same manner as the <sterilization effect test against Staphylococcus aureus> of the disinfectant cleaning agent composition according to the first embodiment of the present invention. The sterilizing effect on staphylococci was tested. The results are shown in Tables 21-24.

<Sterilization effect test against Pseudomonas aeruginosa>
Pseudomonas aeruginosa NBRC13275 is used instead of Escherichia coli. The sterilizing effect on Pseudomonas aeruginosa was tested. The results are shown in Tables 21-24.
The evaluation criteria are as follows.
〇: Pseudomonas aeruginosa has died.
X: Pseudomonas aeruginosa did not die.

As shown in Tables 21 to 23, it was found that the disinfectant cleaning agent compositions according to each example had good turbidity evaluation and did not generate insoluble matter such as precipitate.
Further, it was found that the disinfectant cleaning agent composition according to each example has sufficient detergency.
In addition, it was found that the disinfectant cleaning agent composition according to each example showed sufficient disinfecting power against Escherichia coli, Staphylococcus aureus and Pseudomonas aeruginosa.

Claims (8)

A disinfectant cleaning agent composition containing an anionic surfactant and a cationic surfactant.
The anionic surfactant is at least one selected from the group consisting of a carboxylic acid type anionic surfactant, a sulfonic acid type anionic surfactant and a sulfate ester type anionic surfactant.
The cationic surfactant is at least one selected from the group consisting of an alkyldimethylhydroxyethylammonium salt, a dialkyldimethylammonium salt (alkyl chain length is 8 or less carbon atoms) and a trialkyl quaternary ammonium salt.
The disinfectant cleaning agent composition is characterized in that it is used for cleaning of tableware, kitchen, store cleaning, glass, bathroom, or toilet. The anionic surfactant includes linear alkylbenzene sulfonate, polyoxyethylene alkyl ether sulfate, α-olefin sulfonate, alkane sulfonate, polyoxyethylene alkyl ether acetate, fatty acid salt, α-sulfo fatty acid methyl. The disinfectant cleaning agent composition according to claim 1, which is at least one selected from the group consisting of ester salts, dialkyl sulfosuccinates and alkyl sulfates. Further, at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin, and
Includes at least one surfactant selected from the group consisting of nonionic surfactants, semi-polar surfactants, and amphoteric surfactants.
The disinfectant cleaning agent composition according to claim 1 or 2, which is for tableware. Further, at least one alkaline agent selected from the group consisting of alkali metal hydroxides, silicates, amine compounds and carbonates, and
It contains at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin.
The disinfectant cleaning agent composition according to claim 1 or 2, which is for kitchen use. Further, at least one alkaline agent selected from the group consisting of amine compounds and carbonates, and
It contains at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin.
The disinfectant cleaning agent composition according to claim 1 or 2, which is used for cleaning stores. Furthermore, as an alkaline agent, an amine compound and
It contains at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin.
The disinfectant cleaning agent composition according to claim 1 or 2, which is for glass. Further, at least one solvent selected from the group consisting of glycol-based solvents, alcohol-based solvents, ether-based solvents, ester-based solvents and glycerin, and
At least one chelating agent selected from the group consisting of an aminocarboxylic acid chelating agent, a phosphonic acid chelating agent, a hydroxycarboxylic acid chelating agent, a phosphoric acid chelating agent, and an ether carboxylate chelating agent.
It contains at least one alkaline agent selected from the group consisting of alkali metal hydroxides, carbonates and amine compounds.
The disinfectant cleaning agent composition according to claim 1 or 2, which is for a bathroom. Further, it contains at least one chelating agent selected from the group consisting of an aminocarboxylic acid chelating agent, a phosphonic acid chelating agent, a hydroxycarboxylic acid chelating agent, a phosphoric acid chelating agent and an ether carboxylate chelating agent.
The disinfectant cleaning agent composition according to claim 1 or 2, which is for toilets.