JP2020138933A - Cleanser composition filled in non-gas type foam discharge container - Google Patents

Abstract

To provide a cleanser composition filled in a non-gas type foam discharge container, which is excellent in foam performance and low-temperature stability, provides refreshing washing without sliminess during rinsing, gives moist feeling after drying with a towel, and has an excellent foam discharge property.SOLUTION: There is provided a cleanser composition filled in a non-gas type foam discharge container, which comprises (A) a lauric acid salt, (B) a myristic acid salt and (C) a palmitic acid salt and further comprises (D) at least one cationized polymer having a structure represented by the following general formula and (E) at least one amphoteric surfactant selected from the group consisting of alkylbetaine types, amidopropyl betaine types and sulfobetaine-types, wherein a mixed mass ratio of the components (A) to (C) is 41:58:1 to 45:50:5, the content of components (A) to (C) is 8 to 14 mass% in the cleanser composition and the content of the components (D) is 0.05 to 1 mass%.SELECTED DRAWING: None

Description

The present invention relates to a non-gas type cleaning agent composition containing a foam discharge container (hereinafter, also simply referred to as "cleaning agent composition"). Specifically, the present invention is excellent in foam performance and low temperature stability, and is refreshing without sliminess during rinsing. The present invention relates to a non-gas type cleaning agent composition containing a foam discharge container, which is washed and has a moist feeling after towel drying and is excellent in foam discharge property.

The cleaning agent is required to have foam performance such as foaming, foam durability, foam elasticity, and ease of rinsing. Therefore, foam performance and ease of rinsing occupy a very important position in determining the quality of the cleaning agent. For this reason, various proposals have been made in order to improve foam performance, ease of rinsing, and the like.

For example, Patent Document 1 proposes a liquid cleaning agent composition that is excellent in foam performance, mesh clogging property, and also excellent in low temperature stability, and can be suitably used for a non-gas foam discharge container. Further, Patent Document 2 proposes a cleaning agent composition containing a foam discharge container, which has a creamy foam quality, has elasticity, is excellent in low temperature stability, and gives a moist skin feel after cleaning. Furthermore, in Patent Document 3, the amount of foam and the creaminess of the foam are good, the smoothness of the skin during rinsing, the smooth feeling of the skin after towel drying, and the moistness of the skin after towel drying. A liquid skin cleansing composition having an excellent feeling has been proposed.

Japanese Unexamined Patent Publication No. 2005-154651 Japanese Unexamined Patent Publication No. 2006-183039 JP-A-2018-052830

However, in the liquid cleaning agent composition proposed in Patent Document 1, the finishability has not been studied. That is, the liquid cleaning agent composition proposed in Patent Document 1 has a problem that it becomes taut due to the washing after washing, which is peculiar to fatty acid salts, because the amount of lauric acid salt, myristic acid salt and palmitic acid salt is large. ing.

Further, in the cleaning agent composition proposed in Patent Document 2, a large amount of synthetic surfactant is blended, and the washing finish becomes slimy. Therefore, it is not preferable for consumers who prefer a refreshing wash.

Further, the liquid skin cleaning agent composition proposed in Patent Document 3 includes lauric acid salt, myristate, palmitic acid salt, a dimethyldiallylammonium chloride polymer as a cationic polymer, and dimethyldialylammonium chloride-acrylic acid. It contains at least one selected from the polymers, and at the same time it is refreshing after washing, and at the same time, a moist feeling is obtained after towel drying. However, the liquid skin cleansing composition proposed in Patent Document 3 is not always suitable for a foam discharge container, and does not have the convenience of a foamy cleansing agent.

Therefore, an object of the present invention is a non-gas type foam discharge container which is excellent in foam performance and low temperature stability, has no slimy during rinsing, is washed cleanly, and has a moist feeling after towel drying, and is excellent in foam discharge property. To provide a cleaning agent composition containing a mixture.

As a result of diligent studies to solve the above problems, the present inventors have found laurate, myristate, and palmitate, at least one or more cationic polymers having a predetermined structure, and a predetermined structure. The present invention has been completed by finding that a cleaning agent composition containing the having amphoteric activator in a predetermined ratio can highly balance the above characteristics.

で表される構造を有するカチオン化ポリマーの少なくとも１種と、（Ｅ）アルキルベタイン系、アミドプロピルベタイン系、およびスルホベタイン系からなる群から選択される少なくとも１種の両性界面活性剤と、を含有し、
（Ａ）ラウリン酸塩と、（Ｂ）ミリスチン酸塩と、（Ｃ）パルミチン酸塩との混合質量比が、４１：５８：１〜４５：５０：５であり、（Ａ）ラウリン酸塩と、（Ｂ）ミリスチン酸塩と、（Ｃ）パルミチン酸塩との合計量が、前記ノンガス型の泡吐出容器入り洗浄剤組成物中に８〜１４質量％であり、
（Ｄ）前記一般式で表される構造を有するカチオン化ポリマーが、前記泡吐出容器入り洗浄剤組成物中に０．０５〜１質量％であることを特徴とするものである。 That is, the cleaning agent composition in a non-gas type foam discharge container of the present invention contains (A) laurate salt, (B) myristic acid salt, and (C) palmitic acid salt. In the containerized cleaning composition,
Furthermore, (D) the following general formula,

At least one of the cationized polymers having the structure represented by (E) and at least one amphoteric surfactant selected from the group consisting of (E) alkyl betaine, amide propyl betaine, and sulfobetaine. Contains,
The mixed mass ratio of (A) laurate, (B) myristate, and (C) palmitate is 41: 58: 1 to 45: 50: 5, and (A) laurate. , (B) myristate and (C) palmitate are 8 to 14% by mass in the non-gas type foam discharge container-containing cleaning agent composition.
(D) The cationized polymer having the structure represented by the general formula is characterized in that it is 0.05 to 1% by mass in the cleaning agent composition containing a foam discharge container.

In the cleaning agent composition of the present invention, (F) nonionic surfactant is preferably contained in the cleaning agent composition containing a foam discharge container in an amount of 0.5 to 4% by mass, and (F) nonionic surfactant. The alkylalkanol-type nonionic surfactant is preferable, and the coconut oil fatty acid N-methylethanolamide is more preferable. Further, the cleaning composition of the present invention preferably further contains (G) polyhydric alcohol, and dipropylene glycol is preferable as the (G) polyhydric alcohol. Furthermore, the cleaning composition of the present invention preferably contains at least one of (H) amino acid-based anionic surfactants.

According to the present invention, it is excellent in foam performance and low temperature stability, it can be washed cleanly without slimy during rinsing, and a moist feeling can be obtained after towel drying, and it is a non-gas type foam discharge container cleaning with excellent foam discharge property. The agent composition can be provided. The cleaning agent composition of the present invention is excellent in foaming performance such as foaming, foam sustainability, foam elasticity, rinsing ease, etc., and is also excellent in pump discharge property. It can be suitably used as a body soap, etc.).

で表される構造を有するカチオン化ポリマー（以下、「（Ｄ）成分とも称する」）の少なくとも１種と、（Ｅ）アルキルベタイン系、アミドプロピルベタイン系、およびスルホベタイン系からなる群から選択される両性界面活性剤（以下、「（Ｅ）成分とも称する」）と、少なくとも１種を含有している。 Hereinafter, the non-gas type cleaning agent composition containing a foam discharge container of the present invention will be described in detail.
The cleaning composition of the present invention contains (A) laurate, (B) myristate, and (C) palmitate as fatty acid salts. In the cleaning agent composition of the present invention, (D) the following general formula,

Selected from the group consisting of at least one cationized polymer having the structure represented by (hereinafter, also referred to as “component (D)”) and (E) alkyl betaine, amide propyl betaine, and sulfobetaine. It contains at least one amphoteric surfactant (hereinafter, also referred to as “component (E)”).

In the cleaning composition of the present invention, the mixed mass ratio of (A) laurate, (B) myristate, and (C) palmitate is 41: 58: 1 to 45:50: It is 5. By setting the mixed mass ratio of (A) laurate salt, (B) myristate salt, and (C) palmitate salt in such a range, sufficient detergency can be obtained, and foaming and foam persistence. , Foam performance such as foam elasticity can be highly balanced.

Further, in the cleaning agent composition of the present invention, the total amount of (A) laurate, (B) myristate, and (C) palmitate is 8 in the cleaning agent composition of the present invention. ~ 14% by mass. Preferably, it is contained in an amount of more than 50% by mass in the total surfactant. That is, the cleaning agent composition of the present invention is mainly composed of a soap component. Therefore, it has a creamy foam quality, does not have a slimy finish, is excellent in rinsing, and gives a refreshing feeling. In order to obtain such an effect satisfactorily, the total amount of (A) laurate salt, (B) myristate salt, and (C) palmitate salt should be 10 to 10 in the cleaning composition of the present invention. 14% by mass is preferable.

In the cleaning agent composition of the present invention, the counterions in (A) laurate, (B) myristate and (C) palmitate are not particularly limited and may be appropriately selected depending on the intended purpose. It can be made, and examples thereof include alkali metals, amines, and amino acids.

The alkali metal is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include sodium and potassium.

The amine is also not particularly limited and may be appropriately selected depending on the intended purpose. For example, ammonium, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methylpropanol, 2-amino-2- Examples thereof include alkanolamines such as methylpropanediol.

The amino acid is also not particularly limited, and examples thereof include lysine and arginine.

In the cleaning composition of the present invention, the (A) laurate, (B) myristate, and (C) palmitate are preferably potassium laurate, potassium myristate, and potassium palmitate, respectively. .. The cleaning composition of the present invention may contain other fatty acid salts other than (A) lauric acid salt, (B) myristic acid salt, and (C) palmitic acid salt, for example, oleic acid. Higher fatty acid salts such as salts, linoleic acid, linolenic acid and stearic acid can be used. However, a fatty acid salt having about 10 to 18 carbon atoms is preferable because the raw material odor, foaming, and low temperature stability may be deteriorated. The content of other higher fatty acid salts in the cleaning agent composition is preferably 2.0% by mass or less, preferably 1.0% by mass or less, and more preferably 0% by mass.

で表される構造を有するカチオン化ポリマーの少なくとも１種が、０．０５〜１質量％含まれている。このような構造を有するカチオン性ポリマーを用いることで、タオルドライ後においても、しっとり感を維持することができる。このようなカチオン化ポリマーとしては、例えば、塩化ジメチルジアリルアンモニウム重合体、塩化ジメチルジアリルアンモニウム−アクリル酸共重合体、塩化ジメチルジアリルアンモニウム−アクリルアミド共重合体、およびアクリルアミド−アクリル酸−塩化ジメチルジアリルアンモニウム共重合体を挙げることができる。これらの中でも、タオルドライ後のしっとり感に優れることから、塩化ジメチルジアリルアンモニウム重合体がより好ましい。（Ｄ）成分の含有量は、洗浄剤組成物中、０．１〜０．８質量％が好ましく、より好ましくは、０．２〜０．６質量％である。なお、（Ｄ）成分は、１種単独で使用してもよく、２種以上を併用してもよい。 Further, the cleaning agent composition of the present invention has the following general formula as the component (D).

At least one kind of cationized polymer having a structure represented by is contained in an amount of 0.05 to 1% by mass. By using a cationic polymer having such a structure, a moist feeling can be maintained even after towel drying. Examples of such cationized polymers include dimethyldiallylammonium chloride polymer, dimethyldialylammonium chloride-acrylic acid copolymer, dimethyldialylammonium chloride-acrylamide copolymer, and acrylamide-acrylic acid-dimethyldialylammonium chloride. Polymers can be mentioned. Among these, the dimethyldiallylammonium chloride polymer is more preferable because it has an excellent moist feeling after towel drying. The content of the component (D) is preferably 0.1 to 0.8% by mass, more preferably 0.2 to 0.6% by mass in the cleaning agent composition. The component (D) may be used alone or in combination of two or more.

Further, in the cleaning agent composition of the present invention, as the component (E), at least one amphoteric surfactant selected from the group consisting of alkyl betaine-based, amide propyl betaine-based, and sulfobetaine-based is contained. There is. This alleviates the skin irritation caused by the anionic surfactant and makes the cleansing composition transparent. As a result, clogging of the mesh portion of the foam discharge container can be prevented, and the cleaning agent composition used for the foam discharge container is suitable. Among these, alkyl betaine type and amide propyl betaine type are more preferable because they are excellent in low temperature pump discharge property. In the cleaning agent composition of the present invention, the component (E) is preferably 3 to 8% by mass, more preferably 4 to 6% by mass. As for the component (E), one type may be used alone, or two or more types may be used in combination.

Examples of the alkylbetaine-based amphoteric surfactant include alkyldimethylaminoacetic acid betaine and the like. Examples of the alkyldimethylaminoacetic acid betaine include coconut oil fatty acid dimethylaminoacetic acid betaine, lauryldimethylaminoacetic acid betaine, myristyldimethylaminoacetic acid betaine, stearyldimethylaminoacetic acid betaine and the like. These may be used alone or in combination of two or more. Among these, lauryl dimethylaminoacetic acid betaine and coconut oil fatty acid dimethylamino acetate betaine are preferable.

Examples of the amidopropyl betaine-based amphoteric surfactant include alkylamide propyl betaine and the like. Examples of the alkylamide propyl betaine include coconut oil fatty acid amide propyl betaine, lauric acid amide propyl betaine, and isostearamide propyl betaine. These may be used alone or in combination of two or more. Among these, amide propyl betaine laurate and amide propyl betaine coconut oil fatty acid are preferable.

Examples of the sulfobetaine-based amphoteric surfactant include hydroxysulfobetaine-based amphoteric surfactants and amide sulfobetaine-based amphoteric surfactants.

Examples of the hydroxysulfobetaine-based amphoteric surfactant include coconut oil fatty acid dimethylaminohydroxysulfobetaine, lauryldimethylaminohydroxysulfobetaine, and laurylhydroxysulfobetaine. These may be used alone or in combination of two or more.

Examples of the amide sulfobetaine-based amphoteric surfactant include dodecylaminomethyldimethylsulfopropyl betaine and octadecylaminomethyldimethylsulfopropyl betaine. These may be used alone or in combination of two or more.

The cleaning composition of the present invention preferably contains (F) nonionic surfactant in an amount of 0.5 to 4% by mass. Foaming performance can be further improved by adding an amount of (F) nonionic surfactant in such a range. More preferably, it is 1 to 3% by mass.

Examples of the nonionic surfactant include polyoxyethylene cetyl ether, sorbitan monostearate, polyoxyethylene sorbitan triisostearate, polyoxyethylene hydrogenated castor oil, polyoxyethylene monoisostearate, and glyceryl polyoxyethylene dioleate. , Polyoxyethylene polyoxypropylene glycol, polyethylene glycol monolaurate and the like. These may be used alone or in combination of two or more.

In the cleaning agent composition of the present invention, among nonionic surfactants, an alkyl alkanol type containing coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, coconut oil fatty acid N-methylethanolamide, and lauric acid monoisopropanolamide. A nonionic surfactant is preferable, and a coconut oil fatty acid N-methylethanolamide is more preferable from the viewpoint of low temperature stability.

In addition to these, in the cleaning composition of the present invention, an alkyl polyglucoside can also be used as the nonionic surfactant. Examples of the alkyl polyglycoside include decyl glucoside, lauryl glucoside, myristyl glucoside, cocoyl glucoside and the like. Commercially available products may be used for these alkyl polyglucosides, and examples of the commercially available products include the PLANTACARE series (all of which are manufactured by Kao Corporation), PLANTACARE2000UP, PLANTACARE1200UP, PLANTACARE818UP, PLANTACARE800UP and the like. Made by BASF).

In addition to these, in the cleaning composition of the present invention, alkylmethylglucamide can also be used as the nonionic surfactant. Examples thereof include cocoyl methyl glucamide, (capriloyl / caproyl) methyl glucamide, lauroyl methyl glucamide, (lauroyl / myristoylation) methyl glucamido cocobetaine, and (capriloyl / caproyl) methyl glucamide (lauroyl / myristoylation) methyl glucamide. .. Commercially available products may be used as these alkylmethyl glucamides, and examples thereof include the GlucoTine series (all manufactured by Clariant AG) such as GlucoTine Care, GlucoTine Clear, GlucoTine Flex, GlucoTine liquiFlex, and GlucoTine Plus.

The cleaning composition of the present invention preferably contains at least one of anionic surfactants. Examples of the anionic surfactant include (H) amino acid-based anionic surfactant, sulfonate type anionic surfactant, sulfate ester salt type anionic surfactant, alkyl phosphate ester salt type anionic surfactant, and hydroxyalkyl. Examples thereof include ether carboxylate. These may be used alone or in combination of two or more. In particular, the (H) amino acid-based anionic surfactant is preferable because it gives an excellent moist feeling after towel drying.

Examples of amino acid-based anionic surfactants include triethanolamine lauroyl glutamate (TEA), sodium lauroyl glutamate, sodium cocoyl alanine, cocoyl alanine TEA, sodium lauroyl methyl alanine, TEA cocoyl glutamate, sodium myristyl glutamate, potassium myritoyl glutamate, and sodium cocoyl glutamate. , Potassium cocoyl glutamate, TEA lauroyl aspartate, sodium lauroyl aspartate, TEA cocoyl aspartate, sodium cocoyl aspartate, sodium cocoyl glycine, potassium cocoyl glycine, sodium lauroyl sarcosin TEA, sodium lauroyl sarcosin, sodium cocoyl sarcosin, etc. Can be mentioned.

Examples of the sulfonate-type anionic surfactant include N-acylaminosulfonate, polyoxyethylene sulfosuccinate and the like, and specifically, for example, N-cocoyl methyl taurine sodium and polyoxy. Examples thereof include sodium ethylenealkylsulfosuccinate.

Examples of the sulfate ester salt type anionic surfactant include higher alkyl sulfates and polyoxyethylene alkyl ether sulfates.

Examples of the alkyl phosphate ester salt-type anionic surfactant include triethanolamine monolauryl phosphate and dipotassium monolauryl phosphate.

Examples of the hydroxyalkyl ether carboxylate include sodium lauryl glycol carboxylate and potassium tridecyl glycol carboxylate.

In the cleaning composition of the present invention, when an anionic surfactant is contained, the anionic surfactant is preferably 1 to 3% by mass. By setting the amount in such a range, the foam performance can be further improved.

Further, it is also preferable that the cleaning agent composition of the present invention further contains (G) a polyhydric alcohol. By containing the polyhydric alcohol, the low temperature stability is improved, the viscosity of the cleaning agent composition is lowered, and the clogging of the mesh portion of the foam discharge container can be satisfactorily prevented. It is also preferable from the viewpoint of moisturizing after washing.

Examples of the polyhydric alcohol include ethylene glycol, diethylene glycol, hexylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, glycerin, diglycerin, triglycerin, tetraglycerin, hexaglycerin, and the like. Ethylhexyl glycerin, decaglycerin, 1,3-butylene glycol, trimethylpropanol, erythritol, pentaerythritol, dipentaerythritol, glucose, mannose, galactose, sucrose, fructose, maltose, martitol, xylitol, inositol, sorbitan, sorbitol, these Examples of the ethylene oxide (EO) adduct of the polyhydric alcohol of the above. Among these, propylene glycol, dipropylene glycol, glycerin, 1,3-butylene glycol, and ethylhexyl glycerin are particularly preferable, and dipropylene glycol is particularly preferable, from the viewpoint of moisturizing feeling and moisturizing after rinsing. These may be used alone or in combination of two or more.

In the cleaning composition of the present invention, the content of the polyhydric alcohol is preferably 5 to 20% by mass, more preferably 5 to 10% by mass. When it is set to 5% by mass, the effect of improving stability at low temperature can be sufficiently exhibited, but when it exceeds 20% by mass, nulling may occur during rinsing and the usability may deteriorate. is there.

The cleaning composition of the present invention may contain other components in addition to the above components. Other ingredients include, for example, oils, alcohols, moisturizers, thickeners, preservatives, antioxidants, chelating agents, pH regulators, UV absorbers / scattering agents, vitamins, amino acids, fragrances, extracts, Pigments, water, etc. can be mentioned. These may be used alone or in combination of two or more.

The oil content includes, for example, vegetable oils and fats such as castor oil, olive oil, cacao oil, hardened palm oil, camellia oil, palm oil, wax, jojoba oil, grape seed oil, and avocado oil, or ester compounds thereof; mink oil, Animal oils and fats such as egg yolk oil; waxes such as beeswax, whale wax, lanolin, hydrogenated lanolin, carnauba wax, candelilla wax; hydrocarbons such as liquid paraffin, squalane, microcrystallin wax, ceresin wax, paraffin wax, and vaseline. Natural and synthetic fatty acids such as laurate, myristic acid, stearic acid, oleic acid, isostearic acid, behenic acid; glycerol tri-2-ethylhexanoic acid ester, 2-ethylhexyl stearate, butyl stearate, isopropyl myristate, Esters such as isopropyl palmitate, octyldodecyl myristate, octyldodecyl oleate, and cholesterol oleate; dimethylpolysiloxane and the like can be mentioned.

Examples of alcohols include natural and synthetic lower alcohols such as ethyl alcohol, propyl alcohol, butyl alcohol and pentyl alcohol and their structural isomers, cetyl alcohol, oleyl alcohol, stearyl alcohol, hexyldecanol, octyldodecanol, lauryl alcohol and the like. Natural and synthetic higher alcohols and the like.

Examples of the moisturizing agent include 1,3-butanediol, isoprene glycol, 1,2-pentanediol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, diethylene glycol monoalkyl ether, and polyethylene glycol (average molecular weight: 190 to 1). , 650), polypropylene glycol, polyethylene glycol / polypropylene glycol, hardened castor oil (30EO), glycerin, diglycerin, triglycerin, polyglycerin, sorbitol and the like.

Examples of the thickener include natural polymers such as sodium alginate, xanthan gum, aluminum silicate, malmero seed extract, tragant gum and starch; and semi-synthetic polymers such as methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and soluble starch. ; Synthetic polymer compounds such as carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, and methacryloyl ethylbetaine / methacrylate copolymer can be mentioned.

Examples of preservatives include benzoate, sorbate, dehydroacetate, paraoxybenzoic acid ester, 2,4,4'-trichloro-2'-hydroxydiphenyl ether, 3,4,4'-trichlorocarbanilide. , Benzolic acid chloride, hinokithiol, resorcin, methylchloroisothiazolinone / methylisothiazolinone solution (trade name: Kason CG, manufactured by Roam & Haas Japan), salicylic acid, pentandiol, phenoxyethanol, ethanol, etc. be able to.

Examples of the antioxidant include dibutylhydroxytoluene, butylhydroxyanisole, ascorbic acid and the like.

Examples of the chelating agent include ethylenediaminetetraacetic acid salt, hexametaphosphate, and gluconic acid.

Examples of the pH adjuster include sodium hydroxide, potassium hydroxide, citric acid, sodium citrate, succinic acid, triethanolamine, aqueous ammonia, triisopropanolamine, phosphoric acid, glycolic acid and the like.

Examples of the ultraviolet absorbing and scattering agent include 2-hydroxy-4-methoxybenzophenone, octyldimethylparaaminobenzoate, ethylhexylparamethoxycinnamate, titanium oxide, kaolin, talc and the like.

Examples of vitamins include vitamin A, vitamin B group, vitamin C, vitamin D, vitamin E, vitamin F, vitamin K, vitamin P, vitamin U, carnitine, ferulic acid, γ-orizanol, α-lipoic acid, and ollot. Acids, derivatives thereof and the like can be mentioned.

Examples of amino acids include glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, glutamic acid, arginine, histidine, lysine or derivatives thereof. Can be done.

Examples of the fragrance and the fragrance composition include the fragrance components described in paragraphs [0021] to [0035] of JP-A-2003-300811 and the fragrances described in paragraph [0050] of JP-A-2003-300811. A solvent or the like can be mentioned. The content of the fragrance composition is preferably 0.005 to 3% by mass, more preferably 0.01 to 1% by mass, based on the total amount of the cleaning agent composition.

Examples of the extract include plant-based extracts sold by Ichimaru Falcos Co., Ltd. For example, aloe, aloe vera, ginkgo, fennel, seaweed, cucumber, chamomile, kiwi, cucumber, loofah, cutinashi, rice bran, peach, yuzu, pearl barley and the like can be mentioned. When the extract is contained, not only the moisturizing effect but also the effect peculiar to the extract is imparted. The content of the extract is preferably 0.001 to 3% by mass, more preferably 0.005 to 1% by mass in the cleaning composition of the present invention from the viewpoint of compounding stability and moisturizing effect.

The method for producing the cleaning agent composition of the present invention is not particularly limited, and it can be produced by a known method. For example, (A) laurate, (B) myristate, (C) palmitate, (D) component, (E) component, other components if necessary, and water are prepared by stirring and mixing. can do. The pH of the cleaning agent composition is preferably 9.5 to 11.0. Within this range, the amount of foam is large, there is no irritation to the skin, and low temperature stability is good.

As an apparatus for preparing the cleaning agent composition of the present invention, for example, an apparatus provided with a plurality of stirring blades (for example, a propeller, a turbine, a dispar, etc.) capable of mixing with a shearing force can be preferably used. A homomixer, a backflow mixer, a hive rod mixer and the like are more preferable.

The viscosity of the cleaning agent composition of the present invention is not particularly limited and may be appropriately selected depending on the intended purpose. However, from the viewpoint of foam forming property, appearance of discharged bubbles, etc., for example, at 25 ° C. It is preferably 40 mPa · s or less, and more preferably 20 mPa · s or less.

Next, the foam discharge container of the cleaning agent composition of the present invention will be described.
The foam discharge container according to the cleaning agent composition of the present invention is a non-gas type foam discharge container capable of discharging creamy foam. By using a non-gas type foam discharge container, the characteristics of the cleaning agent composition according to the present invention can be fully exhibited. Such a discharge container can be obtained from, for example, Daiwa Seikan Co., Ltd., Yoshino Kogyosho Co., Ltd., and the like.

The non-gas type foam discharge container usually has a porous body for forming bubbles, and bubbles are formed by passing the cleaning agent composition through the porous body. In the cleaning agent composition of the present invention, the mesh of the porous body is not particularly limited and can be appropriately designed according to the intended purpose. If it is coarse, the foam performance will deteriorate, and if it is too fine, the mesh may be clogged. Therefore, for example, 100 to 400 mesh is preferable, and 100 to 300 mesh is more preferable. The number of porous bodies is not particularly limited and may be appropriately selected depending on the intended purpose, and is preferably two or more from the viewpoint of improving foam performance.

The cleaning agent composition of the present invention has excellent foaming performance and low-temperature stability, has no sliminess during rinsing and can be washed cleanly, and has a moist feeling after towel drying and is excellent in foam ejection property. Since it has, it can be suitably used as a body cleanser. The cleansing composition of the present invention can be used as a body cleansing agent in a usual dose and washing method.

Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples.
<Examples and Comparative Examples>
Each cleaning agent composition was prepared by a conventional method with the formulations shown in Tables 1 to 8 below. Each of the obtained cleaning agent compositions was evaluated for foaming, foam persistence, ease of rinsing, evaluation after towel drying, elasticity of discharged foam, low temperature pump discharge property and low temperature stability. The evaluation procedure and evaluation criteria are as follows. The units in the table are parts by mass, and the total amount was adjusted to 100 parts by mass with purified water.

As the foam discharge container, a discharge volume of 1 ml, a nozzle diameter (inner diameter) of 3.5 mm, and a product manufactured by Yoshino Kogyosho Co., Ltd. were used. The mesh of the foam discharge container was two 200 meshes.

<Bubbling>
Eight expert evaluation panelists wet the left forearm and the right palm with water, and 1.0 g (1.0 push) of the cleaning agent composition was applied to the water-wet right palm from the foam discharge container under the condition of 25 ° C. Foam of the cleaning agent composition was discharged. After rubbing the left forearm 10 times with the right palm with the discharged foam, the average evaluation score was obtained according to the following evaluation criteria, and the foaming of the foam was evaluated according to the following criteria.

-Evaluation criteria-
5 points: Good foaming, very much foam 4 points: Good foaming, more foam 3 points: Good foaming, slightly more foam 2 points: Poor foaming, no foaming 1 point: Poor foaming , Foam is reduced-Criteria-
⊚: 4.0 points or more and 5.0 points or less ○: 3.0 points or more and less than 4.0 points Δ: 2.0 points or more and less than 3.0 points ×: less than 2.0 points

<Foam persistence>
Eight expert evaluation panelists wet the left forearm and the palm of the right hand with water, and 1.0 g (1.0 push) of the liquid cleaning agent composition was applied to the wet palm of the right hand from the foam discharge container under the condition of 25 ° C. Foam of each cleaning agent composition was discharged. After rubbing the left forearm 10 times with the right palm with the discharged foam, the amount of foam was visually compared immediately after and after the discharge. The persistence of the foam was determined by the amount of residual foam. In this case, it was evaluated that the case where the residual amount of bubbles was large was not sustained, and the case where the residual amount of bubbles was small was evaluated as not persistent. The average evaluation score was obtained according to the following evaluation criteria, and the durability of the foam was evaluated according to the following criteria.

-Evaluation criteria-
5 points: All left 4 points: Almost left 3 points: About half left 2 points: A little left 1 point: Almost no left-Judgment criteria-
⊚: 4.0 points or more and 5.0 points or less ○: 3.0 points or more and less than 4.0 points Δ: 2.0 points or more and less than 3.0 points ×: less than 2.0 points

<Easy to rinse>
Eight expert evaluation panelists wet the left forearm and the palm of the right hand with water, and 1.0 g (1.0 push) of the liquid cleaning agent composition was applied to the wet palm of the right hand from the foam discharge container under the condition of 25 ° C. Foam of each cleaning agent composition was discharged. The left forearm was rubbed 10 times back and forth with the right palm with the discharged foam. Then, after rinsing in running water for about 10 seconds, the average evaluation score was obtained according to the following evaluation criteria, and the ease of rinsing was evaluated according to the following criteria.

-Evaluation criteria-
5 points: Very clean and quick 4 points: Quick and clean 3 points: Slightly quick and smooth 2 points: Slightly slow rinse left with a little null 1 point: Slow rinse left with null -Criteria-
⊚: 4.0 points or more and 5.0 points or less ○: 3.0 points or more and less than 4.0 points Δ: 2.0 points or more and less than 3.0 points ×: less than 2.0 points

<Evaluation after towel drying>
Eight expert evaluation panelists wet the left forearm and the palm of the right hand with water, and 1.0 g (1.0 push) of the liquid cleaning agent composition was applied to the wet palm of the right hand from the foam discharge container under the condition of 25 ° C. Foam of each cleaning agent composition was discharged. The left forearm was rubbed 10 times back and forth with the right palm with the discharged foam. Then, after rinsing in running water for about 10 seconds and wiping off the water with a towel, the average evaluation score was obtained according to the following evaluation criteria, and the skin condition (moist feeling) after rinsing was evaluated according to the following criteria.

-Evaluation criteria-
5 points: There is considerable moisture on the skin 4 points: There is moisture on the skin 3 points: There is no dryness on the skin 2 points: There is a slight dryness on the skin 1 point: There is dryness on the skin-Judgment criteria-
⊚: 4.0 points or more and 5.0 points or less ○: 3.0 points or more and less than 4.0 points Δ: 2.0 points or more and less than 3.0 points ×: less than 2.0 points

<Evaluation of elasticity of discharged bubbles>
A hole was made under a 250 ml plastic graduated cylinder, and after pushing the foam from the bottom hole of the graduated cylinder using a foam discharge container to fill the foam to the top, a 23 mm diameter bouncy ball was gently placed and placed. The time from time to fall was measured. When the fall time was long, the elasticity of the foam was evaluated as good, and when the fall time was short, the elasticity of the foam was evaluated as poor.
⊚: 150 seconds or more ○: 100 seconds or more and less than 150 seconds Δ: 50 seconds or more and less than 100 seconds ×: less than 50 seconds

<Low temperature pump discharge property>
Each cleaning agent composition was filled in a pump foam discharge container and stored at 5 ° C. for 7 days. Then, the average evaluation point was obtained according to the following evaluation criteria, and the foam after pump discharge was evaluated according to the following criteria. If the mesh in the foam discharge container is clogged due to an increase in the liquid viscosity or precipitation of the liquid contents, it may be difficult to push the pump of the foam discharge container and the foam may be damaged.

5 points: Easy to push the pump to produce uniform bubbles 4 points: Press the pump to generate bubbles 3 points: Press the pump to produce slightly crushed bubbles 2 points: It is a little difficult to push the pump and crushed One point where bubbles are generated: It is difficult to push the pump and it does not form bubbles-Judgment criteria-
⊚: 4.0 points or more and 5.0 points or less ○: 3.0 points or more and less than 4.0 points Δ: 2.0 points or more and less than 3.0 points ×: less than 2.0 points

<Low temperature stability>
Each cleaning agent composition was filled in a screw vial and allowed to stand at 0 ° C. for 3, 5, 10 and 20 days. Then, the vial was tilted and the state of the cleaning agent composition was visually confirmed.
⊚: Maintains transparent liquid for 20 days or more ○: Maintains transparent liquid for 10 days or more and less than 20 days △: Maintains transparent liquid for 5 days or more and less than 10 days ×: Thickening, cloudiness and precipitates in less than 5 days Can be seen

A: Potassium laurate B: Potassium myristate C: Potassium palmitate H1: Alanone ALE (Lauroylmethylalanine Na)
H2: Aminoformer FLDS-L (Na lauroyl aspartate)
H3: Amisoft CT-12S (TEA cocoyl glutamate)
H4: Soipon SCE (cocoyl sarcosine Na)
H5: Amisoft CK-22 (cocoyl glutamic acid K)
H6: Amylite GCK-12K (cocoyl glycine K)
F1: Aminone C11-S (coconut oil fatty acid N-methylethanolamide)
F2: Plantarea 818 UP (C8-16 alkyl polyglycoside)
F3: Plantare 2000 UP (C10-16 alkyl polyglycoside)
F4: Plantare 1200 UP (C12-16 alkyl polyglycoside)
F5: GLUCOTAIN CLEAR (caproyl methyl glucamido)
E1: Lebon HC30W (palm oil fatty acid amide propyl betaine solution)
E2: GENAGEN DAB-J (amide propyl betaine laurate)
E3: Obazoline LB-SF (betaine lauryldimethylaminoacetate)
E'1: Levon 105 (2-alkyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine)
E'2: Softazoline LHL (N-lauroyl-N'-carboxymethyl-N'-hydroxyethylethylenediamine Na)
E4: Amphorex LSB (lauryl hydroxysulfobetaine solution)
D1: Adeka Catio Ace PD50 (Polyquaternium-6)
D2: FLOCARE C 107 PF (Polyquaternium-7)
D3: FLOCARE DP / C 139 (Polyquaternium-39)
G1: DPG-RF (dipropylene glycol)
G2: Cosmetic propylene glycol (propylene glycol)
G3: RG Ko (glycerin)
G4: Adecanol GE-RF (ethylhexyl glycerin)
I1: Ethylenediaminetetraacetic acid tetrasodium tetrahydrate I2: White flakes Potassium hydroxide (potassium hydroxide)
I3: Citric acid (citric acid)
I4: Extract I5: Fragrance

From Tables 1 to 8, the cleaning agent composition of the present invention has excellent foaming performance, excellent low temperature stability, no sliminess during rinsing, a refreshing feeling after washing, and moistness after towel drying. It can be seen that the feeling is excellent and the foam ejection property is excellent, and that it is suitable as a cleaning agent composition for a foam discharging container, particularly as a body cleaning agent.

Claims (8)

In a non-gas type cleaning agent composition containing a foam discharge container containing (A) laurate salt, (B) myristic acid salt, and (C) palmitic acid salt,
Furthermore, (D) the following general formula,

At least one of the cationized polymers having the structure represented by (E) and at least one amphoteric surfactant selected from the group consisting of (E) alkyl betaine, amide propyl betaine, and sulfobetaine. Contains,
The mixed mass ratio of (A) laurate, (B) myristate, and (C) palmitate is 41: 58: 1 to 45: 50: 5, and the non-gas type foam. 8 to 14% by mass in the cleaning agent composition in the discharge container.
(D) A non-gas type foam discharge container containing 0.05 to 1% by mass of the cationized polymer having the structure represented by the general formula in the cleaning agent composition containing the foam discharge container. Cleaning agent composition. The non-gas type foam discharge container according to claim 1, wherein the mixed mass of (A) laurate, (B) myristic acid, and (C) palmitate is more than 50% by mass in the total surfactant. Detergent composition. The non-gas type cleaning agent composition containing a foam discharge container according to claim 1 or 2, wherein the nonionic surfactant is contained in the cleaning agent composition containing a foam discharge container in an amount of 0.5 to 4% by mass. (F) The cleaning agent composition in a non-gas type foam discharge container according to claim 3, wherein the nonionic surfactant is an alkylalkanol-type nonionic surfactant. The cleaning composition containing a non-gas type foam discharge container according to claim 4, wherein the alkylalkanol-type nonionic surfactant is coconut oil fatty acid N-methylethanolamide. (G) The non-gas type cleaning agent composition containing a foam discharge container according to any one of claims 1 to 5, which contains a polyhydric alcohol. (G) The cleaning agent composition containing a non-gas type foam discharge container according to claim 6, wherein the polyhydric alcohol is dipropylene glycol. (H) The non-gas type cleaning agent composition in a foam discharge container according to any one of claims 1 to 7, which contains at least one amino acid-based anionic surfactant.