JP2020137502A - Pasty seasoning composition - Google Patents

Pasty seasoning composition Download PDF

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JP2020137502A
JP2020137502A JP2019037965A JP2019037965A JP2020137502A JP 2020137502 A JP2020137502 A JP 2020137502A JP 2019037965 A JP2019037965 A JP 2019037965A JP 2019037965 A JP2019037965 A JP 2019037965A JP 2020137502 A JP2020137502 A JP 2020137502A
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兼二 須藤
Kenji Sudo
兼二 須藤
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Abstract

To provide a pasty seasoning composition in which floating oil does not coagulate in a viscous gel form when dissolved in hot water.MEANS FOR SOLVING THE PROBLEM: The pasty seasoning composition includes an oil and fat composition containing the following components (a) and (b), and a powdered food material: (a) polyglycerol fatty acid ester comprising main constituting fatty acid of behenic acid and having an esterification degree of 50% or more and (b) polyglycerol fatty acid ester comprising main constituting fatty acid of oleic acid and/or diglycerol fatty acid ester comprising main constituting fatty acid of saturated fatty acid having 14 to 18 carbon atoms.SELECTED DRAWING: Figure 1

Description

本発明は、ペースト状調味組成物に関する。 The present invention relates to a paste-like seasoning composition.

従来、常温で半固体状の油脂と、食塩、砂糖等の粉末食材とを混合し、ペースト状に練り合わせた調味組成物が市販されている。このようなペースト状調味組成物は、他の調味料と併用しなくても、それ単体で食品に油脂由来の風味やコクと粉末食材由来の呈味とを同時に付与することができ、その手軽さから消費者に好まれている。 Conventionally, a seasoning composition in which semi-solid fats and oils at room temperature and powdered foodstuffs such as salt and sugar are mixed and kneaded into a paste is commercially available. Such a paste-like seasoning composition can easily impart a flavor derived from fats and oils and a richness and a taste derived from powdered foods to foods by itself without being used in combination with other seasonings. Therefore, it is preferred by consumers.

ペースト状調味組成物の製造においては、配合する成分の種類や配合量もさることながら、ベースとなる油脂の粘度調整が極めて重要となる。即ち、油脂の粘度が高すぎれば、組成物の物性が固くなりすぎて使用時に適量を取り分けづらくなり、油脂の粘度が低すぎれば、粉末食材を十分に保持することができず、輸送中や保存中に分離を生じるおそれがあるため、このような問題が生じない範囲に油脂の粘度を調整しなければならない。 In the production of the paste-like seasoning composition, it is extremely important to adjust the viscosity of the base fat and oil as well as the type and amount of the components to be blended. That is, if the viscosity of the fat is too high, the physical properties of the composition become too hard and it becomes difficult to separate an appropriate amount at the time of use, and if the viscosity of the fat is too low, the powdered foodstuff cannot be sufficiently retained, and during transportation or Since separation may occur during storage, the viscosity of fats and oils must be adjusted within a range that does not cause such problems.

ペースト状調味組成物の製造に使用する油脂の粘度を適切な範囲に調整する方法としては、例えば、該油脂に主構成脂肪酸がベヘン酸であり且つエステル化度が50%以上であるポリグリセリン脂肪酸エステルを有効成分とすることを特徴とする油脂の増粘剤を添加する方法(特許文献1)が知られている。この方法によれば油脂に適度な粘性を付与することができ、良好な物性のペースト状調味組成物を製造することができる。しかし、この方法により得られたペースト状調味組成物は、これを湯等に溶解した際、液面に浮いた油脂分(浮油)が粘稠なゲル状の凝集を形成し、これが食器、調理器具、歯等に付着して、喫食時や食器類の洗浄時に不快感を伴うことがあった。 As a method for adjusting the viscosity of the fat and oil used for producing the paste-like seasoning composition to an appropriate range, for example, a polyglycerin fatty acid in which the main constituent fatty acid of the fat and oil is behenic acid and the degree of esterification is 50% or more. A method of adding a thickener for fats and oils, which comprises an ester as an active ingredient, is known (Patent Document 1). According to this method, an appropriate viscosity can be imparted to the fat and oil, and a paste-like seasoning composition having good physical properties can be produced. However, in the paste-like seasoning composition obtained by this method, when it is dissolved in hot water or the like, the oil and fat (floating oil) floating on the liquid surface forms a viscous gel-like aggregate, which is the tableware. It may adhere to cooking utensils, teeth, etc. and cause discomfort when eating or washing dishes.

そこで、湯等に溶解した際に浮油が粘稠なゲル状に凝集しないペースト状調味組成物が求められていた。 Therefore, there has been a demand for a paste-like seasoning composition in which the floating oil does not aggregate into a viscous gel when dissolved in hot water or the like.

特開2001−69912号公報Japanese Unexamined Patent Publication No. 2001-69912

本発明は、湯等に溶解した際に浮油が粘稠なゲル状に凝集しないペースト状調味組成物を提供することを目的とする。 An object of the present invention is to provide a paste-like seasoning composition in which floating oil does not agglomerate into a viscous gel when dissolved in hot water or the like.

本発明者は、前記課題を解決するために鋭意研究を重ねた結果、主構成脂肪酸がベヘン酸であり且つエステル化度が50%以上であるポリグリセリン脂肪酸エステルを添加して増粘した油脂組成物に、さらに特定の食品用乳化剤を加えることにより、該油脂組成物を使用して製造したペースト状調味組成物を湯等に溶解した際に浮油がゲル化しにくくなることを見出し、この知見に基づきさらに研究を重ね、本発明を完成するに至った。 As a result of intensive research to solve the above problems, the present inventor has added a polyglycerin fatty acid ester in which the main constituent fatty acid is bechenic acid and the degree of esterification is 50% or more to thicken the oil and fat composition. It was found that by adding a specific food emulsifier to a product, the floating oil is less likely to gel when the paste-like seasoning composition produced using the oil / fat composition is dissolved in hot water or the like. Further research was carried out based on the above, and the present invention was completed.

即ち、本発明は、下記成分(a)及び(b)を含む油脂組成物と、粉末食材とを含有するペースト状調味組成物、からなっている。
(a)主構成脂肪酸がベヘン酸であり且つエステル化度が50%以上であるポリグリセリン脂肪酸エステル
(b)主構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステル及び/又は主構成脂肪酸が炭素数14〜18の飽和脂肪酸であるジグリセリン脂肪酸エステル
That is, the present invention comprises an oil / fat composition containing the following components (a) and (b), and a paste-like seasoning composition containing a powdered food material.
(A) Polyglycerin fatty acid ester in which the main constituent fatty acid is bechenic acid and the degree of esterification is 50% or more (b) Polyglycerin fatty acid ester in which the main constituent fatty acid is oleic acid and / or the main constituent fatty acid has 14 carbon atoms Diglycerin fatty acid ester, which is a saturated fatty acid of ~ 18.

本発明に係るペースト状調味組成物は、これを湯等に溶解した際、浮油が粘稠なゲル状に凝集しにくい。そのため、該浮油が食器等に付着しにくい。 In the paste-like seasoning composition according to the present invention, when it is dissolved in hot water or the like, the floating oil does not easily aggregate into a viscous gel. Therefore, the floating oil does not easily adhere to tableware and the like.

図1は、実施例の調味組成物1を熱湯に溶解した試験液1について、浮油の外観を撮影した写真である。FIG. 1 is a photograph of the appearance of the floating oil of the test solution 1 in which the seasoning composition 1 of the example was dissolved in boiling water. 図2は、比較例の調味組成物22を熱湯に溶解した試験液22について、浮油の外観を撮影した写真である。FIG. 2 is a photograph of the appearance of the floating oil of the test solution 22 in which the seasoning composition 22 of the comparative example was dissolved in boiling water. 図3は、実施例の調味組成物1を熱湯に溶解した試験液1について、浮油のべたつきを評価した際に使用したスプーンの外観を撮影した写真である。FIG. 3 is a photograph of the appearance of a spoon used when evaluating the stickiness of floating oil with respect to the test solution 1 in which the seasoning composition 1 of the example was dissolved in boiling water. 図4は、比較例の調味組成物22を熱湯に溶解した試験液22について、浮油のべたつきを評価した際に使用したスプーンの外観を撮影した写真である。FIG. 4 is a photograph of the appearance of a spoon used when evaluating the stickiness of the floating oil of the test solution 22 in which the seasoning composition 22 of the comparative example was dissolved in boiling water.

本発明に係るペースト状調味組成物(以下「本発明の調味組成物」ともいう)は、油相中に固体相が分散した構造をとるペースト状の組成物であって、該油相として以下に述べる成分(a)及び(b)を含む油脂組成物、該固体相として粉末食材を含有することを特徴とする。 The paste-like seasoning composition according to the present invention (hereinafter, also referred to as “the seasoning composition of the present invention”) is a paste-like composition having a structure in which a solid phase is dispersed in an oil phase, and the oil phase is described below. It is characterized by containing an oil / fat composition containing the components (a) and (b) described in the above, and a powdered food material as the solid phase.

本発明の調味組成物の油相を構成する油脂は、食用可能な油脂であれば特に制限はなく、例えば、大豆油、菜種油、綿実油、サフラワー油、ヒマワリ油、米糠油、コーン油、椰子油、パーム油、パーム核油、落花生油、オリーブ油、ゴマ油、ハイオレイック菜種油、ハイオレイックサフラワー油、ハイオレイックコーン油、ハイオレイックヒマワリ油等の植物油脂、牛脂、ラード、魚油、乳脂等の動物油脂、これら動植物油脂に分別、水素添加、エステル交換等の処理を施した加工油脂、あるいは中鎖脂肪酸トリグリセリド(MCT)等が挙げられる他、グリセリンジ脂肪酸エステル及びプロピレングリコールジ脂肪酸エステルもこれらに含まれる。また、これら油脂に香味を付与した香味油等を用いてもよい。これら油脂は、いずれか1種のみを単独で用いてもよいし、2種以上を任意に組み合わせて用いてもよいが、後述する成分(a)及び(b)を加えた後の粘度を良好な範囲に調整するため、常温(15〜25℃)で液状である油脂(例えば、大豆油、菜種油、綿実油、サフラワー油、ヒマワリ油、米糠油、コーン油、落花生油、オリーブ油、ゴマ油、ハイオレイック菜種油、ハイオレイックサフラワー油、ハイオレイックコーン油、ハイオレイックヒマワリ油等)と、常温(15〜25℃)で固体状である油脂(例えば、牛脂、ラード、パーム油、パーム核油等)を組み合わせて用いることが好ましい。 The fats and oils constituting the oil phase of the seasoning composition of the present invention are not particularly limited as long as they are edible fats and oils. For example, soybean oil, rapeseed oil, cottonseed oil, safflower oil, sunflower oil, rice bran oil, corn oil, and coconut oil. Vegetable oils such as oil, palm oil, palm kernel oil, peanut oil, olive oil, sesame oil, high oleic rapeseed oil, high oleic safflower oil, high oleic corn oil, high oleic sunflower oil, beef fat, lard, fish oil, milk fat, etc. Animal fats and oils, processed fats and oils obtained by subjecting these animal and vegetable fats and oils to treatments such as separation, hydrogenation, and ester exchange, medium-chain triglyceride (MCT), etc., as well as glycerindi fatty acid esters and propylene glycol difatty acid esters. include. Further, a flavor oil or the like obtained by imparting a flavor to these fats and oils may be used. As these fats and oils, only one of them may be used alone, or two or more of them may be used in any combination, but the viscosity after adding the components (a) and (b) described later is good. Oils and fats that are liquid at room temperature (15 to 25 ° C) (for example, soybean oil, rapeseed oil, cottonseed oil, safflower oil, sunflower oil, rice bran oil, corn oil, peanut oil, olive oil, sesame oil, high oleic) Rapeseed oil, high oleic safflower oil, high oleic corn oil, high oleic sunflower oil, etc.) and fats and oils that are solid at room temperature (15 to 25 ° C) (eg, beef fat, lard, palm oil, palm kernel oil) Etc.) are preferably used in combination.

本発明の成分(a)は、主構成脂肪酸がベヘン酸であり且つエステル化度が50%以上であるポリグリセリン脂肪酸エステル(以下「成分(a)のポリグリセリン脂肪酸エステル」ともいう)である。なお、ポリグリセリン脂肪酸エステルとは、グリセリン2分子以上が縮合してなる化合物であるポリグリセリンと脂肪酸とのエステルであり、ベヘン酸とは、炭素数22の飽和脂肪酸である。 The component (a) of the present invention is a polyglycerin fatty acid ester in which the main constituent fatty acid is behenic acid and the degree of esterification is 50% or more (hereinafter, also referred to as “polyglycerin fatty acid ester of component (a)”). The polyglycerin fatty acid ester is an ester of polyglycerin, which is a compound formed by condensing two or more molecules of glycerin, and a fatty acid, and behenic acid is a saturated fatty acid having 22 carbon atoms.

成分(a)のポリグリセリン脂肪酸エステルを構成するポリグリセリンの平均重合度に特に制限はないが、例えば、平均重合度2〜10のもの、具体的には、ジグリセリン(平均重合度2)、トリグリセリン(平均重合度3)、テトラグリセリン(平均重合度4)、ペンタグリセリン(平均重合度5)、ヘキサグリセリン(平均重合度6)、ヘプタグリセリン(平均重合度7)、オクタグリセリン(平均重合度8)、デカグリセリン(平均重合度10)等が挙げられる。 The average degree of polymerization of polyglycerin constituting the polyglycerin fatty acid ester of the component (a) is not particularly limited, but for example, those having an average degree of polymerization of 2 to 10, specifically diglycerin (average degree of polymerization 2). Triglycerin (average degree of polymerization 3), tetraglycerin (average degree of polymerization 4), pentaglycerin (average degree of polymerization 5), hexaglycerin (average degree of polymerization 6), heptaglycerin (average degree of polymerization 7), octaglycerin (average degree of polymerization 7) Degree 8), decaglycerin (average degree of polymerization 10) and the like.

成分(a)のポリグリセリン脂肪酸エステルの「主構成脂肪酸」とは、ポリグリセリン脂肪酸エステルを構成する脂肪酸100質量%中、通常50質量%以上、好ましくは60質量%以上、より好ましくは75質量%以上を占める脂肪酸をいう。即ち、成分(a)のポリグリセリン脂肪酸エステルは、該エステルを構成する脂肪酸100質量%中、50質量%以上をベヘン酸が占めていれば、残部にその他の脂肪酸を含んでいてもよい。なお、後述の成分(b)として用いられるポリグリセリン脂肪酸エステル及びジグリセリン脂肪酸エステルについての「主構成脂肪酸」の定義もこれと同様である。 The "main constituent fatty acid" of the polyglycerin fatty acid ester of the component (a) is usually 50% by mass or more, preferably 60% by mass or more, more preferably 75% by mass, based on 100% by mass of the fatty acids constituting the polyglycerin fatty acid ester. Fatty acids that occupy the above. That is, the polyglycerin fatty acid ester of the component (a) may contain other fatty acids in the balance as long as behenic acid accounts for 50% by mass or more of the 100% by mass of the fatty acids constituting the ester. The definition of "main constituent fatty acid" for the polyglycerin fatty acid ester and the diglycerin fatty acid ester used as the component (b) described later is the same as this.

成分(a)のポリグリセリン脂肪酸エステルは、エステル化度が50%以上、好ましくは50〜90%である。該エステル化度(%)は、下記式により算出される。なお、下記式中のエステル価及び水酸基価は、「基準油脂分析試験法(I)」(社団法人 日本油化学会編)の[2.3.3−1996 エステル価]及び[2.3.6−1996 ヒドロキシル価]に準じて測定される。 The polyglycerin fatty acid ester of the component (a) has an esterification degree of 50% or more, preferably 50 to 90%. The degree of esterification (%) is calculated by the following formula. The ester value and hydroxyl value in the following formula are [2.3-3-1996 ester value] and [2.3.3-1996 ester value] of "Standard Oil and Fat Analysis Test Method (I)" (edited by Japan Oil Chemists' Society). 6-1996 hydroxyl value] is measured.

Figure 2020137502
Figure 2020137502

成分(a)のポリグリセリン脂肪酸エステルの製造方法に特に制限はなく、エステル化反応等、自体公知の方法で製造することができる。 The method for producing the polyglycerin fatty acid ester of the component (a) is not particularly limited, and it can be produced by a method known per se, such as an esterification reaction.

成分(a)のポリグリセリン脂肪酸エステルとしては、例えば、リョートーポリグリエステルB−70D(商品名;デカグリセリンベヘン酸エステル;エステル化度:約58%;三菱ケミカルフーズ社製)、リョートーポリグリエステルB−100D(商品名;デカグリセリンベヘン酸エステル;エステル化度:約83%;三菱ケミカルフーズ社製)、ポエムJ−46B(商品名;テトラグリセリンベヘン酸エステル;エステル化度:約90%;理研ビタミン社製)、ポエムTR−FB(商品名;トリグリセリンベヘン酸エステル;エステル化度:約85%;理研ビタミン社製)等が商業的に販売されており、本発明ではこれを用いることができる。 Examples of the polyglycerin fatty acid ester of the component (a) include Ryoto polyglycerate B-70D (trade name; decaglycerin bechenic acid ester; degree of esterification: about 58%; manufactured by Mitsubishi Chemical Foods Co., Ltd.) and Ryoto polyglycerate. B-100D (trade name; decaglycerin behenic acid ester; degree of esterification: about 83%; manufactured by Mitsubishi Chemical Foods Co., Ltd.), Poem J-46B (trade name; tetraglycerin behenic acid ester; degree of esterification: about 90%; Riken Vitamin Co., Ltd.), Poem TR-FB (trade name; triglycerin behenic acid ester; esterification degree: about 85%; Riken Vitamin Co., Ltd.), etc. are commercially available, and this is used in the present invention. Can be done.

なお、本発明において成分(a)のポリグリセリン脂肪酸エステルは、本発明の調味組成物の油相に適度な粘性を付与するための増粘剤として作用するものである。 In the present invention, the polyglycerin fatty acid ester of the component (a) acts as a thickener for imparting an appropriate viscosity to the oil phase of the seasoning composition of the present invention.

本発明の成分(b)は、主構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステル(以下、「成分(b)のポリグリセリン脂肪酸エステル」ともいう)及び/又は主構成脂肪酸が炭素数14〜18の飽和脂肪酸であるジグリセリン脂肪酸エステル(以下「成分(b)のジグリセリン脂肪酸エステル」ともいう)である。なお、ジグリセリン脂肪酸エステルとは、ポリグリセリン脂肪酸エステルの一種であり、該エステルを構成するポリグリセリンが平均重合度2のジグリセリンであるものをいう。 The component (b) of the present invention contains a polyglycerin fatty acid ester in which the main constituent fatty acid is oleic acid (hereinafter, also referred to as “polyglycerin fatty acid ester of the component (b)”) and / or the main constituent fatty acid has 14 to 18 carbon atoms. Diglycerin fatty acid ester (hereinafter, also referred to as "diglycerin fatty acid ester of component (b)") which is a saturated fatty acid of. The diglycerin fatty acid ester is a kind of polyglycerin fatty acid ester, and the polyglycerin constituting the ester is a diglycerin having an average degree of polymerization of 2.

成分(b)のポリグリセリン脂肪酸エステルを構成するポリグリセリンの平均重合度に特に制限はないが、例えば、平均重合度2〜10のもの、具体的には、ジグリセリン(平均重合度2)、トリグリセリン(平均重合度3)、テトラグリセリン(平均重合度4)、ペンタグリセリン(平均重合度5)、ヘキサグリセリン(平均重合度6)、ヘプタグリセリン(平均重合度7)、オクタグリセリン(平均重合度8)、デカグリセリン(平均重合度10)等が挙げられる。これらの中でも、平均重合度2のジグリセリンが好ましい。 The average degree of polymerization of polyglycerin constituting the polyglycerin fatty acid ester of the component (b) is not particularly limited, but for example, those having an average degree of polymerization of 2 to 10, specifically diglycerin (average degree of polymerization 2). Triglycerin (average degree of polymerization 3), tetraglycerin (average degree of polymerization 4), pentaglycerin (average degree of polymerization 5), hexaglycerin (average degree of polymerization 6), heptaglycerin (average degree of polymerization 7), octaglycerin (average degree of polymerization 7) Degree 8), decaglycerin (average degree of polymerization 10) and the like. Among these, diglycerin having an average degree of polymerization of 2 is preferable.

成分(b)のポリグリセリン脂肪酸エステルの主構成脂肪酸であるオレイン酸とは、炭素数18の一価不飽和脂肪酸である。 Oleic acid, which is the main constituent fatty acid of the polyglycerin fatty acid ester of the component (b), is a monounsaturated fatty acid having 18 carbon atoms.

成分(b)のポリグリセリン脂肪酸エステルのエステル化度に特に制限はないが、例えば、50%以下であることが好ましく、30%以下であることがより好ましい。 The degree of esterification of the polyglycerin fatty acid ester of the component (b) is not particularly limited, but is preferably 50% or less, more preferably 30% or less, for example.

成分(b)のポリグリセリン脂肪酸エステルの製造方法に特に制限はなく、エステル化反応等、自体公知の方法で製造することができる。 The method for producing the polyglycerin fatty acid ester of the component (b) is not particularly limited, and it can be produced by a method known per se, such as an esterification reaction.

成分(b)のポリグリセリン脂肪酸エステルとしては、例えば、ポエムDO−100V(商品名;ジグリセリンオレイン酸エステル;理研ビタミン社製)、SYグリスターMO−3S(商品名;テトラグリセリンオレイン酸エステル;阪本薬品工業社製)、サンソフトA−171E(商品名;ペンタグリセリンオレイン酸エステル;太陽化学社製)、SYグリスターMO−5S(商品名;ヘキサグリセリンオレイン酸エステル;阪本薬品工業社製)、ポエムJ−0381V(商品名;デカグリセリンオレイン酸エステル;理研ビタミン社製)等が商業的に販売されており、本発明ではこれらを用いることができる。 Examples of the polyglycerin fatty acid ester of the component (b) include Poem DO-100V (trade name; diglycerin oleic acid ester; manufactured by RIKEN Vitamin Co., Ltd.) and SY Glycer MO-3S (trade name; tetraglycerin oleic acid ester; Sakamoto). Yakuhin Kogyo Co., Ltd.), Sunsoft A-171E (trade name; pentaglycerin oleic acid ester; Taiyo Kagaku Co., Ltd.), SY Glycer MO-5S (trade name; hexaglycerin oleic acid ester; Sakamoto Yakuhin Kogyo Co., Ltd.), Poem J-0381V (trade name; decaglycerin oleic acid ester; manufactured by RIKEN Vitamin Co., Ltd.) and the like are commercially available, and these can be used in the present invention.

成分(b)のジグリセリン脂肪酸エステルの主構成脂肪酸である炭素数14〜18の飽和脂肪酸としては、具体的には、例えば、ミリスチン酸(炭素数14)、パルミチン酸(炭素数16)、ステアリン酸(炭素数18)等が挙げられる。 Specific examples of the saturated fatty acid having 14 to 18 carbon atoms, which is the main constituent fatty acid of the diglycerin fatty acid ester of the component (b), include myristic acid (14 carbon atoms), palmitic acid (16 carbon atoms), and stearic acid. Acids (18 carbon atoms) and the like can be mentioned.

成分(b)のジグリセリン脂肪酸エステルのエステル化度に特に制限はないが、例えば、50%以下であることが好ましく、30%以下であることがより好ましい。言い換えれば、成分(b)のジグリセリン脂肪酸エステルとしてはモノエステル体の含有量の高いものが好ましく、例えば、モノエステル体の含有量が50質量%以上であるものが好ましく、70質量%以上であるものがより好ましい。 The degree of esterification of the diglycerin fatty acid ester of the component (b) is not particularly limited, but is preferably 50% or less, more preferably 30% or less, for example. In other words, the diglycerin fatty acid ester of the component (b) preferably has a high content of a monoester, for example, a monoester having a content of 50% by mass or more, preferably 70% by mass or more. Some are more preferred.

成分(b)のジグリセリン脂肪酸エステルの製造方法に特に制限はなく、エステル化反応等、自体公知の方法で製造することができる。 The method for producing the diglycerin fatty acid ester of the component (b) is not particularly limited, and it can be produced by a method known per se, such as an esterification reaction.

成分(b)のジグリセリン脂肪酸エステルとしては、例えば、ポエムDM−100(商品名;ジグリセリンミリスチン酸エステル;理研ビタミン社製)、ポエムDP−95RF(商品名;ジグリセリンパルミチン酸エステル;理研ビタミン社製)、ポエムDS−100A(商品名;ジグリセリンステアリン酸エステル;理研ビタミン社製)等が商業的に販売されており、本発明ではこれらを用いることができる。 Examples of the diglycerin fatty acid ester of the component (b) include Poem DM-100 (trade name; diglycerin myristic acid ester; manufactured by RIKEN Vitamin) and Poem DP-95RF (trade name; diglycerin luminic acid ester; RIKEN Vitamin). , Poem DS-100A (trade name; diglycerin stearic acid ester; manufactured by RIKEN Vitamin) and the like are commercially available, and these can be used in the present invention.

なお、本発明の成分(b)としては、前記成分(b)のポリグリセリン脂肪酸エステルと成分(b)のジグリセリン脂肪酸エステルのいずれか1種のみを単独で用いてもよいし、2種以上を任意に組み合わせて用いてもよいが、少なくともジグリセリンオレイン酸エステルを用いることが好ましい。本発明の成分(b)としてジグリセリンオレイン酸エステルを用いた場合には、本発明の調味組成物を湯等に溶解した際の浮油が極めて細かい粒状の油滴となって液面全体に均一に分散しやすくなり、且つ、該湯等が例えば30℃以下まで冷めた場合であっても、浮油のゲル化を抑制することができる。 As the component (b) of the present invention, only one of the polyglycerin fatty acid ester of the component (b) and the diglycerin fatty acid ester of the component (b) may be used alone, or two or more of them may be used. May be used in any combination, but at least diglycerin oleate is preferably used. When diglycerin oleic acid ester is used as the component (b) of the present invention, the floating oil when the seasoning composition of the present invention is dissolved in hot water or the like becomes extremely fine granular oil droplets on the entire liquid surface. It becomes easy to disperse uniformly, and gelation of floating oil can be suppressed even when the hot water or the like is cooled to, for example, 30 ° C. or lower.

本発明の調味組成物の油相中における前記油脂並びに成分(a)及び(b)の含有量に特に制限はないが、例えば、該油相100質量%中、油脂が80〜99.8質量%、好ましくは94〜99質量%、成分(a)が0.1〜10質量%、好ましくは0.5〜3.0質量%、成分(b)が0.1〜10質量%、好ましくは0.5〜3.0質量%である。 The content of the fats and oils and the components (a) and (b) in the oil phase of the seasoning composition of the present invention is not particularly limited. For example, 80 to 99.8% by mass of the fats and oils in 100% by mass of the oil phase. %, preferably 94 to 99% by mass, component (a) 0.1 to 10% by mass, preferably 0.5 to 3.0% by mass, component (b) 0.1 to 10% by mass, preferably 0.1 to 10% by mass. It is 0.5 to 3.0% by mass.

本発明の調味組成物の油相は、前記油脂並びに成分(a)及び(b)以外に、本発明の効果を阻害しない範囲で他の任意の成分を含有していてもよい。そのような成分としては、例えば、成分(a)及び(b)以外の食品用乳化剤、酸化防止剤(抽出トコフェロール、L−アスコルビン酸パルミチン酸エステル等)等が挙げられる。 The oil phase of the seasoning composition of the present invention may contain any other component other than the fat and oil and the components (a) and (b) as long as the effects of the present invention are not impaired. Examples of such a component include food emulsifiers other than the components (a) and (b), antioxidants (extracted tocopherol, L-ascorbic acid palmitic acid ester, etc.) and the like.

本発明の調味組成物の固体相を構成する粉末食材は、粉末状(顆粒状、粒状等を含む)の食品素材であれば特に制限はなく、例えば、元来粉末状の形態をとる食品素材をそのまま用いてもよく、元来粉末状ではない食品素材を粉末状に精製又は加工したものを用いてもよい。具体的には、例えば、基礎調味料(食塩、砂糖、粉末醤油、粉末魚醤、粉末酢、粉末ソース等)、うま味調味料(グルタミン酸ナトリウム、核酸系調味料等)、香辛料(コショウ、オールスパイス、オルガノ、カルダモン、クミン、唐辛子、コリアンダー等)、香味野菜(オニオンパウダー、ガーリックパウダー、ジンジャーパウダー等)、風味原料(鰹節粉末、鯖節粉末、鰯節粉末、鯵節粉末、煮干粉末、昆布粉末、椎茸粉末、貝柱粉末等)、畜肉エキス(ビーフエキスパウダー、ポークエキスパウダー、チキンエキスパウダー等)、甘味料(ステビア末等)、着色料(カラメル色素等)、酸味料(クエン酸、乳酸等)、賦形剤(デキストリン、澱粉等)等が挙げられる。 The powdered food material constituting the solid phase of the seasoning composition of the present invention is not particularly limited as long as it is a powdered (including granular, granular, etc.) food material. For example, a food material originally in the form of powder. May be used as it is, or a food material that is not originally in powder form may be purified or processed into powder. Specifically, for example, basic seasonings (salt, sugar, powdered soy sauce, powdered fish sauce, powdered vinegar, powdered sauce, etc.), umami seasonings (sodium glutamate, nucleic acid-based seasonings, etc.), spices (kosho, all spices, etc.) , Organo, cardamon, cumin, chili pepper, coriander, etc.), flavored vegetables (onion powder, garlic powder, ginger powder, etc.) , Shiitake powder, shellfish powder, etc.), livestock meat extract (beef extract powder, pork extract powder, chicken extract powder, etc.), sweetener (stevia powder, etc.), coloring agent (caramel pigment, etc.), acidulant (citrate, lactic acid, etc.) , Excipients (dextrin, starch, etc.) and the like.

本発明の調味組成物中における前記油相と固体相の含有量の比率に特に制限はないが、例えば、油相:固体相(質量比)が25:75〜75:25の範囲であることが好ましく、30:70〜50:50であることがより好ましい。油相と固体相の含有量の比率がこのような範囲であると、得られる調味組成物が扱いやすい物性になる。 The ratio of the content of the oil phase to the solid phase in the seasoning composition of the present invention is not particularly limited, and for example, the oil phase: solid phase (mass ratio) is in the range of 25:75 to 75:25. Is preferable, and 30:70 to 50:50 is more preferable. When the ratio of the contents of the oil phase and the solid phase is in such a range, the obtained seasoning composition has physical properties that are easy to handle.

本発明の調味組成物の製造方法に特に制限はないが、例えば、その好ましい一例は以下のとおりである。即ち、油脂に成分(a)及び(b)を加え、所望により加熱して溶融混合し、油相となる油脂組成物を調製する。その後、該油脂組成物に粉末食材を加え、所望により冷却しながら攪拌混合することにより、油相中に粉末食材が分散した状態のペースト状調味組成物を得ることができる。 The method for producing the seasoning composition of the present invention is not particularly limited, and for example, a preferred example thereof is as follows. That is, the components (a) and (b) are added to the oil and fat, and if desired, they are heated and melt-mixed to prepare an oil and fat composition to be an oil phase. Then, the powdered foodstuff is added to the oil / fat composition, and the powdered foodstuff is stirred and mixed while cooling if desired, whereby a paste-like seasoning composition in which the powdered foodstuff is dispersed in the oil phase can be obtained.

本発明の調味組成物の使用方法に特に制限はなく、従来のペースト状調味組成物と同様、これを湯等に溶解してそのままスープ等として喫食してもよく、各種食品の調理工程においてペースト状のまま、又は湯等に溶解してから添加して該食品の味付けに使用してもよい。特に、本発明の調味組成物は湯等に溶解した際に浮油が粘稠なゲル状に凝集しにくい点に特徴を有することから、湯等に溶解して使用することが好ましい。 The method of using the seasoning composition of the present invention is not particularly limited, and like the conventional paste-like seasoning composition, it may be dissolved in hot water or the like and eaten as it is as a soup or the like, and is pasted in the cooking process of various foods. It may be used as it is or after being dissolved in hot water or the like and added to season the food. In particular, since the seasoning composition of the present invention is characterized in that the floating oil does not easily aggregate into a viscous gel when dissolved in hot water or the like, it is preferably used by dissolving it in hot water or the like.

本発明の調味組成物の使用対象となる食品に特に制限はないが、例えば、中華スープ、ラーメンスープ(例えば、豚骨スープ等)、そばつゆ、うどんつゆ、鍋つゆ、味噌汁、野菜スープ、豆スープ、コンソメスープ、ポタージュスープ、チキンスープ、トムヤムクンスープ等のつゆ・スープ類、中華あんかけソース、和風あんかけソース、パスタソース、カレー、シチュー等のタレ・ソース類、餃子、中華まん、春巻等の包餡食品の中種、炒飯、野菜炒め、生姜焼き、ソテー、ハンバーグ、メンチカツ、コロッケ、から揚げ、麻婆豆腐等が挙げられる。 The food for which the seasoning composition of the present invention is used is not particularly limited, but for example, Chinese soup, ramen soup (for example, pork bone soup, etc.), soba soup, udon soup, pot soup, miso soup, vegetable soup, bean soup. , Consomme soup, potage soup, chicken soup, tom yam kun soup and other soups, Chinese sauce, Japanese style sauce, pasta sauce, curry, stew and other sauces, dumplings, Chinese buns, spring rolls and other wraps Examples of foods include medium-sized foods, fried rice, fried vegetables, grilled ginger, soup, hamburger, menchi cutlet, croquette, fried chicken, and mao tofu.

以下、実施例をもって本発明を具体的に説明するが、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be specifically described with reference to Examples, but the present invention is not limited thereto.

[ペースト状調味組成物の調製1]
(1)原材料
1)油脂
1−1)菜種油(商品名:ナタネサラダ油;ボーソー油脂社製)
1−2)ラード(商品名:純正ラード;ミヨシ油脂社製)
2)食品用乳化剤
<成分(a)の食品用乳化剤>
2−1)デカグリセリンベヘン酸エステル(商品名:リョートーポリグリエステルB−70D;エステル化度:約58%;三菱ケミカルフーズ社製)
2−2)テトラグリセリンベヘン酸エステル(商品名:ポエムJ−46B;エステル化度:約90%;理研ビタミン社製)
2−3)トリグリセリンベヘン酸エステル(商品名:ポエムTR−FB;エステル化度:約85%;理研ビタミン社製)
<成分(b)の食品用乳化剤>
2−4)ジグリセリンオレイン酸エステル(商品名:ポエムDO−100V;理研ビタミン社製)
2−5)テトラグリセリンオレイン酸エステル(商品名:SYグリスターMO−3S;阪本薬品工業社製)
2−6)ペンタグリセリンオレイン酸エステル(商品名:サンソフトA−171E;太陽化学社製)
2−7)ヘキサグリセリンオレイン酸エステル(商品名:SYグリスターMO−5S;阪本薬品工業社製)
2−8)デカグリセリンオレイン酸エステル(商品名:ポエムJ−0381V;理研ビタミン社製)
2−9)ジグリセリンミリスチン酸エステル(商品名:ポエムDM−100;理研ビタミン社製)
2−10)ジグリセリンパルミチン酸エステル(商品名:ポエムDP−95RF;理研ビタミン社製)
2−11)ジグリセリンステアリン酸エステル(商品名:ポエムDS−100A;理研ビタミン社製)
<成分(a)及び(b)以外の食品用乳化剤>
2−12)グリセリンオレイン酸エステル(商品名:エマルジーOL−100H;理研ビタミン社製)
2−13)ソルビタンオレイン酸エステル(商品名:ポエムO−80V;理研ビタミン社製)
2−14)プロピレングリコールオレイン酸エステル(商品名:リケマールPO−100V;理研ビタミン社製)
2−15)ジグリセリンラウリン酸エステル(商品名:ポエムDL−100;理研ビタミン社製)
2−16)ジグリセリンカプリル酸エステル(商品名:SYグリスターMCA150;阪本薬品工業社製)
2−17)グリセリンステアリン酸エステル(商品名:エマルジーMS;理研ビタミン社製)
2−18)デカグリセリンミリスチン酸エステル(商品名:SYグリスターMM−750;阪本薬品工業社製)
3)粉末食材
3−1)デキストリン(商品名:パインデックス♯2;松谷化学工業社製)
3−2)グルタミン酸ナトリウム(商品名:グルエース;MCフードスペシャリティーズ社製)
[Preparation of paste-like seasoning composition 1]
(1) Raw materials 1) Oils and fats 1-1) Rapeseed oil (trade name: rapeseed salad oil; manufactured by Bosoh Oil & Fat Co., Ltd.)
1-2) Lard (Product name: Genuine lard; manufactured by Miyoshi Oil & Fat Co., Ltd.)
2) Emulsifier for food <Emulsifier for food of component (a)>
2-1) Decaglycerin behenic acid ester (trade name: Ryoto polyglycerate B-70D; degree of esterification: about 58%; manufactured by Mitsubishi Chemical Foods Co., Ltd.)
2-2) Tetraglycerin behenic acid ester (trade name: Poem J-46B; degree of esterification: about 90%; manufactured by RIKEN Vitamin Co., Ltd.)
2-3) Triglycerin behenic acid ester (trade name: Poem TR-FB; degree of esterification: about 85%; manufactured by RIKEN Vitamin Co., Ltd.)
<Food emulsifier of ingredient (b)>
2-4) Diglycerin oleate (trade name: Poem DO-100V; manufactured by RIKEN Vitamin Co., Ltd.)
2-5) Tetraglycerin oleic acid ester (trade name: SY Glister MO-3S; manufactured by Sakamoto Pharmaceutical Co., Ltd.)
2-6) Pentaglycerin oleate (trade name: Sunsoft A-171E; manufactured by Taiyo Kagaku Co., Ltd.)
2-7) Hexaglycerin oleic acid ester (trade name: SY Glister MO-5S; manufactured by Sakamoto Pharmaceutical Co., Ltd.)
2-8) Decaglycerin oleate (trade name: Poem J-0381V; manufactured by RIKEN Vitamin Co., Ltd.)
2-9) Diglycerin myristic acid ester (trade name: Poem DM-100; manufactured by RIKEN Vitamin Co., Ltd.)
2-10) Diglycerin palmitic acid ester (trade name: Poem DP-95RF; manufactured by RIKEN Vitamin Co., Ltd.)
2-11) Diglycerin stearic acid ester (trade name: Poem DS-100A; manufactured by RIKEN Vitamin Co., Ltd.)
<Food emulsifiers other than ingredients (a) and (b)>
2-12) Glycerin oleic acid ester (trade name: Emulgie OL-100H; manufactured by RIKEN Vitamin Co., Ltd.)
2-13) Sorbitan oleic acid ester (trade name: Poem O-80V; manufactured by RIKEN Vitamin Co., Ltd.)
2-14) Propylene glycol oleic acid ester (trade name: Rikemar PO-100V; manufactured by RIKEN Vitamin Co., Ltd.)
2-15) Diglycerin laurate (trade name: Poem DL-100; manufactured by RIKEN Vitamin Co., Ltd.)
2-16) Diglycerin caprylic acid ester (trade name: SY Glister MCA150; manufactured by Sakamoto Pharmaceutical Co., Ltd.)
2-17) Glycerin stearic acid ester (trade name: Emarji MS; manufactured by RIKEN Vitamin Co., Ltd.)
2-18) Decaglycerin myristic acid ester (trade name: SY Glister MM-750; manufactured by Sakamoto Pharmaceutical Co., Ltd.)
3) Powdered foodstuffs 3-1) Dextrin (trade name: Paindex # 2; manufactured by Matsutani Chemical Industry Co., Ltd.)
3-2) Sodium glutamate (trade name: Gluace; manufactured by MC Food Specialties Inc.)

(2)原材料の配合
前記原材料を用いて調製した調味組成物1〜22の配合組成を表1及び2に示した。このうち、調味組成物1〜14は本発明の実施例であり、調味組成物15〜22はそれらに対する比較例である。なお、後述する目視評価を行いやすくするため、前記原材料の菜種油は、予め食品用着色料(商品名:リケカラーパプリカ240RG;トウガラシ色素製剤;理研ビタミン社製)を0.1%加えて橙色に着色したものを使用した。
(2) Formulation of Raw Materials Tables 1 and 2 show the compounding compositions of seasoning compositions 1 to 22 prepared using the raw materials. Of these, seasoning compositions 1 to 14 are examples of the present invention, and seasoning compositions 15 to 22 are comparative examples thereof. In order to facilitate visual evaluation, which will be described later, the raw material rapeseed oil is made orange by adding 0.1% of a food coloring agent (trade name: Rikecolor paprika 240RG; capsicum pigment preparation; manufactured by RIKEN Vitamin) in advance. A colored one was used.

Figure 2020137502
Figure 2020137502

Figure 2020137502
Figure 2020137502

(3)調味組成物の調製方法
前記原材料のうち、油脂及び食品用乳化剤を2L容量のステンレス製ジョッキに入れ、湯煎にて80℃に加温して溶融混合し、油相となる油脂組成物を得た。該油脂組成物を湯煎から外した後、ここに粉末食材を加え、50℃まで冷却しながら低速混合機(型式:ラボラトリーハイパワーミキサーSM−103;アズワン社製)を用いて60rpmで5分間混合し、ペースト状の調味組成物1〜22を各1000g得た。
(3) Method for preparing seasoning composition Of the above raw materials, fats and oils and food emulsifiers are placed in a 2 L capacity stainless steel jug, heated to 80 ° C. in a water bath and melt-mixed to form an oily phase. Got After removing the oil / fat composition from the water bath, powdered foodstuffs are added thereto, and the mixture is mixed at 60 rpm for 5 minutes using a low-speed mixer (model: Laboratory High Power Mixer SM-103; manufactured by AS ONE Corporation) while cooling to 50 ° C. Then, 1000 g of each of the paste-like seasoning compositions 1 to 22 was obtained.

[熱湯への溶解試験]
(1)浮油の外観の目視評価
前記調味組成物1〜22を100ml容量のビーカーに各1g入れ、ここに熱湯99gを加え、スプーンで攪拌して溶解し、これを試験液とした。該試験液について、液面に浮いた浮油の状態が安定するまで10分間静置した後、浮油の外観(油滴の形状・大きさ、液面への拡散状態)を目視により観察した。結果を表3に示す。
[Dissolution test in boiling water]
(1) Visual Evaluation of Appearance of Floating Oil 1 g of each of the seasoning compositions 1 to 22 was placed in a beaker having a capacity of 100 ml, 99 g of boiling water was added thereto, and the mixture was stirred and dissolved with a spoon to prepare a test solution. The test solution was allowed to stand for 10 minutes until the state of the floating oil floating on the liquid surface became stable, and then the appearance of the floating oil (shape and size of oil droplets, diffusion state on the liquid surface) was visually observed. .. The results are shown in Table 3.

(2)浮油のべたつきの目視評価
前記試験液1〜22をスプーンで浮油ごとすくった後、該スプーンをゆっくりと90°傾けて、すくった試験液を流し落とした。その後、スプーンの表面を目視により観察し、流れ落ちずスプーンに付着した浮油の有無を確認した。ここで、スプーンへの浮油の付着が多いほど、浮油がべたついていたことを示す。結果は下記の基準に従って記号化し、表3に示す。
〔記号化基準〕
○:良好 スプーンへの浮油の付着がほとんどない
△:やや悪い スプーンのつぼ部分への付着がやや目立つ
×:悪い スプーンのつぼから柄にかけて多量の付着が見られる
(2) Visual evaluation of stickiness of floating oil After scooping the test solutions 1 to 22 together with the floating oil with a spoon, the spoon was slowly tilted by 90 ° to wash off the scooped test solution. After that, the surface of the spoon was visually observed to confirm the presence or absence of floating oil adhering to the spoon without flowing down. Here, it is shown that the more the floating oil adheres to the spoon, the more sticky the floating oil is. The results are symbolized according to the criteria below and are shown in Table 3.
[Criteria for symbolization]
○: Good Almost no floating oil adheres to the spoon △: Slightly bad Adhesion to the spoon pot is slightly noticeable ×: Bad A large amount of adhesion is seen from the spoon pot to the handle

Figure 2020137502
Figure 2020137502

表3の結果から明らかなように、本発明の成分(a)及び(b)を含有する油脂組成物を油相として使用した調味組成物1〜14は、熱湯に溶解した際に浮油が細かい粒状の油滴となっており、これをスプーンですくっても該スプーンに付着するような不快なべたつきはなかった。即ち、いずれも浮油が粘稠なゲル状に凝集していなかった。とりわけ、調味組成物1、9〜13については浮油が極めて細かい粒状の油滴となって液面全体にほぼ均一に拡散しており、極めて良好であった。
一方、比較例の調味組成物15〜22は、熱湯に溶解した際に浮油が不均一に凝集していることが外観からも明らかであり、さらに、該浮油はスプーンですくうと該スプーンに付着するようなべたつきを呈していた。
As is clear from the results in Table 3, the seasoning compositions 1 to 14 using the oil and fat composition containing the components (a) and (b) of the present invention as the oil phase have floating oil when dissolved in boiling water. It was a fine granular oil droplet, and even if it was scooped with a spoon, there was no unpleasant stickiness that would adhere to the spoon. That is, in each case, the floating oil did not agglomerate into a viscous gel. In particular, the seasoning compositions 1, 9 to 13 were extremely good because the floating oil became extremely fine granular oil droplets and diffused almost uniformly over the entire liquid surface.
On the other hand, in the seasoning compositions 15 to 22 of the comparative example, it is clear from the appearance that the floating oil is unevenly aggregated when dissolved in boiling water, and further, when the floating oil is scooped with a spoon, the spoon is used. It was sticky as if it adhered to.

[放冷後の評価試験]
(1)浮油の外観の目視評価
前記熱湯への溶解試験において評価が極めて良好であった調味組成物のうち、調味組成物1、9又は10を溶解した試験液1、9及び10について、さらに室温にて60分間静置して放冷した。放冷後の液温は25℃であった。放冷後の試験液1について、浮油の外観(油滴の形状・大きさ、液面への拡散状態)を目視により観察した。結果を表4に示す。
[Evaluation test after cooling]
(1) Visual Evaluation of Appearance of Floating Oil Among the seasoning compositions that were extremely well evaluated in the dissolution test in boiling water, the test solutions 1, 9 and 10 in which the seasoning compositions 1, 9 or 10 were dissolved. Further, it was allowed to stand at room temperature for 60 minutes to cool. The liquid temperature after allowing to cool was 25 ° C. The appearance of the floating oil (shape / size of oil droplets, diffusion state on the liquid surface) of the test liquid 1 after allowing to cool was visually observed. The results are shown in Table 4.

(2)浮油のべたつきの評価
前記放冷後の試験液1、9又は10をスプーンで浮油ごとすくった後、該スプーンをゆっくりと90°傾けて、すくった試験液を流し落とした。その後、スプーンの表面を目視により観察し、流れ落ちずスプーンに付着した浮油の有無を確認した。ここで、スプーンへの浮油の付着が多いほど、浮油がべたついていたことを示す。結果は下記の基準に従って記号化し、表4に示す。
〔記号化基準〕
○:良好 スプーンへの浮油の付着がほとんどない
△:やや悪い スプーンのつぼ部分への付着がやや目立つ
×:悪い スプーンのつぼから柄にかけて多量の付着が見られる
(2) Evaluation of Stickiness of Floating Oil After scooping the test solution 1, 9 or 10 after cooling with a spoon together with the floating oil, the spoon was slowly tilted by 90 ° to drain off the scooped test solution. After that, the surface of the spoon was visually observed to confirm the presence or absence of floating oil adhering to the spoon without flowing down. Here, it is shown that the more the floating oil adheres to the spoon, the more sticky the floating oil is. The results are symbolized according to the following criteria and are shown in Table 4.
[Criteria for symbolization]
○: Good Almost no floating oil adheres to the spoon △: Slightly bad Adhesion to the spoon pot is slightly noticeable ×: Bad A large amount of adhesion is seen from the spoon pot to the handle

Figure 2020137502
Figure 2020137502

表4の結果から明らかなように、本発明の実施例である調味組成物1、9又は10を溶解した試験液1、9及び10はいずれも、液温が25℃まで低下しても浮油の外観が溶解した直後と同等であり、不快なべたつきも生じていなかった。 As is clear from the results in Table 4, all of the test solutions 1, 9 and 10 in which the seasoning compositions 1, 9 or 10 which are the examples of the present invention are dissolved float even when the liquid temperature drops to 25 ° C. The appearance of the oil was similar to that immediately after it was dissolved, and no unpleasant stickiness occurred.

[ペースト状調味組成物の調製2]
本発明の実用性を十分に確認するため、より実用的な中華風スープ用ペースト状調味組成物を想定した処方にて調味組成物を調製した。
[Preparation of paste-like seasoning composition 2]
In order to fully confirm the practicality of the present invention, a seasoning composition was prepared with a formulation assuming a more practical paste-like seasoning composition for Chinese-style soup.

(1)原材料
1)油脂
1−1)菜種油(商品名:ナタネサラダ油;ボーソー油脂社製)
1−2)ラード(商品名:純正ラード;ミヨシ油脂社製)
2)食品用乳化剤
<成分(a)の食品用乳化剤>
2−1)デカグリセリンベヘン酸エステル(商品名:リョートーポリグリエステルB−70D;エステル化度:約58%;三菱ケミカルフーズ社製)
<成分(b)の食品用乳化剤>
2−2)ジグリセリンオレイン酸エステル(商品名:ポエムDO−100V;理研ビタミン社製)
3)粉末食材
3−1)デキストリン(商品名:パインデックス♯2;松谷化学工業社製)
3−2)食塩(ナイカイ塩業社製)
3−3)グルタミン酸ナトリウム(商品名:グルエース;MCフードスペシャリティーズ社製)
3−4)核酸系調味料(商品名:リボタイド;MCフードスペシャリティーズ社製)
3−5)ポークエキスパウダー(商品名:ポークエキスパウダーG;理研ビタミン社製)
3−6)チキンエキスパウダー(商品名:チキンパウダーCPR;理研ビタミン社製)
3−7)オニオンパウダー(商品名:オニオンパウダーSK−3760;日研フード社製)
3−8)ガーリックパウダー(商品名:ガーリックパウダーSK−3237;日研フード社製)
3−9)コショウ末(ヱスビー食品社製)
(1) Raw materials 1) Oils and fats 1-1) Rapeseed oil (trade name: rapeseed salad oil; manufactured by Bosoh Oil & Fat Co., Ltd.)
1-2) Lard (Product name: Genuine lard; manufactured by Miyoshi Oil & Fat Co., Ltd.)
2) Emulsifier for food <Emulsifier for food of component (a)>
2-1) Decaglycerin behenic acid ester (trade name: Ryoto polyglycerate B-70D; degree of esterification: about 58%; manufactured by Mitsubishi Chemical Foods Co., Ltd.)
<Food emulsifier of ingredient (b)>
2-2) Diglycerin oleate (trade name: Poem DO-100V; manufactured by RIKEN Vitamin Co., Ltd.)
3) Powdered foodstuffs 3-1) Dextrin (trade name: Paindex # 2; manufactured by Matsutani Chemical Industry Co., Ltd.)
3-2) Salt (manufactured by Naikai Salt Industries)
3-3) Monosodium glutamate (trade name: Gluace; manufactured by MC Food Specialties Inc.)
3-4) Nucleic acid-based seasoning (trade name: Ribotide; manufactured by MC Food Specialties Inc.)
3-5) Pork extract powder (trade name: Pork extract powder G; manufactured by RIKEN Vitamin Co., Ltd.)
3-6) Chicken extract powder (trade name: chicken powder CPR; manufactured by RIKEN Vitamin Co., Ltd.)
3-7) Onion powder (trade name: onion powder SK-3760; manufactured by Nikken Foods Co., Ltd.)
3-8) Garlic powder (trade name: garlic powder SK-3237; manufactured by Nikken Foods Co., Ltd.)
3-9) Pepper powder (manufactured by S & B Foods)

(2)原材料の配合
前記原材料を用いて調製した調味組成物23の配合組成を表5に示した。
(2) Formulation of Raw Materials Table 5 shows the composition of the seasoning composition 23 prepared using the raw materials.

Figure 2020137502
Figure 2020137502

(3)調味組成物の調製方法
前記原材料のうち、油脂及び食品用乳化剤を2L容量のステンレス製ジョッキに入れ、湯煎にて80℃に加温して溶融混合し、油相となる油脂組成物を得た。該油脂組成物を湯煎から外した後、ここに粉末食材を加え、50℃まで冷却しながら低速混合機(型式:ラボラトリーハイパワーミキサーSM−103;アズワン社製)を用いて60rpmで5分間混合し、ペースト状の調味組成物23を1000g得た。
(3) Method for preparing seasoning composition Of the above raw materials, fats and oils and emulsifiers for foods are placed in a 2 L capacity stainless steel jug, heated to 80 ° C. in a water bath and melt-mixed to form an oily phase. Got After removing the oil / fat composition from the water bath, powdered foodstuffs are added thereto, and the mixture is mixed at 60 rpm for 5 minutes using a low-speed mixer (model: Laboratory High Power Mixer SM-103; manufactured by AS ONE Corporation) while cooling to 50 ° C. Then, 1000 g of the paste-like seasoning composition 23 was obtained.

[熱湯への溶解試験]
(1)浮油の外観の目視評価
前記調味組成物23を100ml容量のビーカーに1g入れ、ここに熱湯99gを加え、スプーンで攪拌して溶解し、試験液23を得た。該試験液23について、液面に浮いた浮油の状態が安定するまで10分間静置した後、浮油の外観(油滴の形状・大きさ、液面への拡散状態)を目視により観察した。結果を表6に示す。
[Dissolution test in boiling water]
(1) Visual Evaluation of Appearance of Floating Oil 1 g of the seasoning composition 23 was placed in a beaker having a capacity of 100 ml, 99 g of boiling water was added thereto, and the mixture was stirred and dissolved with a spoon to obtain a test solution 23. The test liquid 23 was allowed to stand for 10 minutes until the state of the floating oil floating on the liquid surface became stable, and then the appearance of the floating oil (shape and size of oil droplets, diffusion state on the liquid surface) was visually observed. did. The results are shown in Table 6.

(2)浮油のべたつきの目視評価
前記試験液23をスプーンで浮油ごとすくった後、該スプーンをゆっくりと90°傾けて、すくった試験液23を流し落とした。その後、スプーンの表面を目視により観察し、流れ落ちずスプーンに付着した浮油の有無を確認した。ここで、スプーンへの浮油の付着が多いほど、浮油の粘度が高く、べたついていたことを示す。結果は下記の基準に従って記号化し、表6に示す。
〔記号化基準〕
○:良好 スプーンへの浮油の付着がほとんどない
△:やや悪い スプーンのつぼ部分への付着がやや目立つ
×:悪い スプーンのつぼから柄にかけて多量の付着が見られる
(2) Visual Evaluation of Stickiness of Floating Oil After scooping the test solution 23 together with the floating oil with a spoon, the spoon was slowly tilted by 90 ° to wash off the scooped test solution 23. After that, the surface of the spoon was visually observed to confirm the presence or absence of floating oil adhering to the spoon without flowing down. Here, it is shown that the more the floating oil adheres to the spoon, the higher the viscosity of the floating oil and the more sticky it is. The results are symbolized according to the criteria below and are shown in Table 6.
[Criteria for symbolization]
○: Good Almost no floating oil adheres to the spoon △: Slightly bad Adhesion to the spoon pot is slightly noticeable ×: Bad A large amount of adhesion is seen from the spoon pot to the handle

Figure 2020137502
Figure 2020137502

表6の結果から明らかなように、油相及び固体相に各種呈味成分を配合したより実用的な処方の調味組成物23においても、本発明の成分(a)及び(b)を含有する油脂組成物を油相として使用したことにより、熱湯に溶解した際に浮油が粘稠なゲル状に凝集しなかった。 As is clear from the results in Table 6, the seasoning composition 23 having a more practical formulation in which various taste components are mixed in the oil phase and the solid phase also contains the components (a) and (b) of the present invention. By using the oil and fat composition as the oil phase, the floating oil did not aggregate into a viscous gel when dissolved in boiling water.

Claims (1)

下記成分(a)及び(b)を含む油脂組成物と、粉末食材とを含有するペースト状調味組成物。
(a)主構成脂肪酸がベヘン酸であり且つエステル化度が50%以上であるポリグリセリン脂肪酸エステル
(b)主構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステル及び/又は主構成脂肪酸が炭素数14〜18の飽和脂肪酸であるジグリセリン脂肪酸エステル
A paste-like seasoning composition containing an oil / fat composition containing the following components (a) and (b) and a powdered food material.
(A) Polyglycerin fatty acid ester in which the main constituent fatty acid is bechenic acid and the degree of esterification is 50% or more (b) Polyglycerin fatty acid ester in which the main constituent fatty acid is oleic acid and / or the main constituent fatty acid has 14 carbon atoms Diglycerin fatty acid ester, which is a saturated fatty acid of ~ 18.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7369480B1 (en) 2022-07-27 2023-10-26 株式会社カネカタカハシ Method for producing emulsifiers for frozen foods

Citations (4)

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Publication number Priority date Publication date Assignee Title
JPH08149950A (en) * 1994-09-28 1996-06-11 Riken Vitamin Co Ltd Edible emulsifying oil and fat composition
JP2001069912A (en) * 1999-08-31 2001-03-21 Mitsubishi-Kagaku Foods Corp Thickener for oil and fat, and thickened oil and fat composition
JP2007106935A (en) * 2005-10-14 2007-04-26 Sakamoto Yakuhin Kogyo Co Ltd Thickener for fats or oils
JP2011193756A (en) * 2010-03-18 2011-10-06 Ajinomoto Co Inc Granular or powdery instant soup or instant sauce

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08149950A (en) * 1994-09-28 1996-06-11 Riken Vitamin Co Ltd Edible emulsifying oil and fat composition
JP2001069912A (en) * 1999-08-31 2001-03-21 Mitsubishi-Kagaku Foods Corp Thickener for oil and fat, and thickened oil and fat composition
JP2007106935A (en) * 2005-10-14 2007-04-26 Sakamoto Yakuhin Kogyo Co Ltd Thickener for fats or oils
JP2011193756A (en) * 2010-03-18 2011-10-06 Ajinomoto Co Inc Granular or powdery instant soup or instant sauce

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Title
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Publication number Priority date Publication date Assignee Title
JP7369480B1 (en) 2022-07-27 2023-10-26 株式会社カネカタカハシ Method for producing emulsifiers for frozen foods

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