JP2020103123A - Agent for suppressing reduction of crab miso flavor after freezing/thawing - Google Patents

Agent for suppressing reduction of crab miso flavor after freezing/thawing Download PDF

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JP2020103123A
JP2020103123A JP2018244878A JP2018244878A JP2020103123A JP 2020103123 A JP2020103123 A JP 2020103123A JP 2018244878 A JP2018244878 A JP 2018244878A JP 2018244878 A JP2018244878 A JP 2018244878A JP 2020103123 A JP2020103123 A JP 2020103123A
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crab
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aqueous solution
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cooked
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JP7194014B2 (en
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敏弘 藤本
Toshihiro Fujimoto
敏弘 藤本
綾子 藤原
Ayako Fujiwara
綾子 藤原
秀行 玉井
Hideyuki Tamai
秀行 玉井
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Kaneka Corp
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Abstract

To provide an agent for suppressing reduction of crab miso flavor after freezing/thawing, that is used in order to provide a crab miso having, after heating/cooking and freezing/thawing, the original rich flavor, by using an active ingredient that does not require food additive labeling, and without changing the crab miso original rich flavor with food additive or seasoning, and to provide an aqueous solution for immersion-treatment of live crab and a method for producing crab miso or frozen crab miso using said aqueous solution.SOLUTION: Provided are an agent for suppressing reduction of flavor, after freezing/thawing, of heated/cooked crab miso, containing at least one extract selected from the group consisting of enokitake mushroom (Flammulina velutipes) extract, yeast extract and barley extract, and an aqueous solution for immersion-treatment of live crab for suppressing the reduction of flavor, after freezing/thawing, of heated/cooked crab miso, containing the extract by 0.1 to 500 ppm (dry weight) and having a sodium chloride concentration of 2 to 3.5 wt.%.SELECTED DRAWING: None

Description

本発明は、加熱調理されたカニミソの冷解凍後の風味低下抑制剤、活カニの浸漬処理用水溶液、及び、該水溶液を用いたカニミソ又は冷凍カニミソの製造方法に関する。 The present invention relates to a flavor reduction inhibitor after cold thawing of cooked crab meat, an aqueous solution for dipping treatment of active crab, and a method for producing crab or frozen crab meat using the aqueous solution.

カニミソは、カニの甲羅の内側から採取される膵肝臓であり、その濃厚な風味から非常に人気の高い食材である。国内では主に、毛ガニ、ズワイガニ、ワタリガニなどのカニミソが消費されている。通常、カニミソは、カニの水揚げ後即座にボイルして甲羅ごと冷凍されるか、又は、甲羅からカニミソを取り出し加熱調理した後に冷凍される。 Crab meat is a pancreas liver collected from the inside of the shell of a crab, and it is a very popular food because of its rich flavor. In Japan, crabs such as hair crab, snow crab and blue crab are mainly consumed. Usually, the crab is boiled immediately after landing the crab and frozen with the shell, or the crab is taken out from the shell and cooked and then frozen.

しかし、添加剤を用いずに甲羅ごと冷凍した場合は、たとえ短期間の冷凍保管でも、風味が変質して、カニミソ本来の濃厚な風味が損なわれてしまう。また、甲羅から取り出し加熱調理してから冷凍した場合は、加熱調理工程で調味料や酸化防止剤を添加する方法が一般的であり、これらの添加剤によってカニミソ本来の濃厚な風味が失われてしまう。しかも、何れの場合であっても、冷凍保管中には水分昇華や解凍時のドリップなどによる冷凍障害が進行しやすく、これによって、解凍後にはカニミソの濃厚な風味が失われ、商品価値が著しく低下してしまう。現状では、水槽に海水を入れて酸素を供給しながら活カニを生きたまま定温輸送する方法などの対処がなされているが、温度管理や酸素管理に大型装置を必要とし、経済効率の上で満足いくものではなかった。 However, when the whole shell is frozen without using any additive, the flavor is altered even if it is stored in a frozen state for a short period of time, and the rich flavor inherent in Kanimiso is impaired. In addition, when the product is taken out of the shell and cooked and then frozen, it is common to add seasonings and antioxidants in the cooking process, and these additives will lose the rich flavor of the original Kaniso. I will end up. Moreover, in any case, during freezing storage, sublimation of water or freezing damage due to drip at the time of thawing is likely to progress, which results in loss of the rich flavor of crab meat after thawing, resulting in remarkable commercial value. Will fall. At present, measures such as putting seawater in a water tank and supplying oxygen while transporting live crabs at a constant temperature while keeping them alive are being taken, but a large-scale device is required for temperature control and oxygen control, which is economically efficient. I was not satisfied.

特許文献1では、アスコルビン酸化合物の第一成分と、有機多塩基酸化合物又はアミノ酸化合物の第二成分からなる甲殻類用保存剤を水溶液とした保存処理液に、活状態、仮死状態、又は生活反応を回復し得る状態を維持している甲殻類を所要の時間接触させた後に冷蔵又は冷凍して保存することで、甲殻類の外観色目や旨味の劣化を防止し、異味や異臭の発生も抑制できる旨が記載されている。しかし、当該文献には、カニミソそのものについても、また、カニミソが有する濃厚な風味についても言及されていない。また、前記保存剤は有効成分が食品添加物であるため、これを使用するとカニミソの商品価値が下がることになる。更に、当該文献に記載の保存剤では、加熱調理及び冷解凍後のカニミソの風味低下を抑制する効果は不十分である。 In Patent Document 1, a preservative for crustaceans consisting of a first component of an ascorbic acid compound and a second component of an organic polybasic acid compound or an amino acid compound is used as an aqueous solution, and a preservative is added to an active state, an asphyxia state, or a living state. By keeping the crustaceans that maintain a state capable of recovering the reaction for a required period of time and then refrigerating or freezing them, it is possible to prevent the appearance color and umami of the crustaceans from deteriorating and also to cause off-flavors and off-flavors. It states that it can be suppressed. However, the document does not mention the crab meat itself or the rich flavor of the crab meat. In addition, since the active ingredient of the preservative is a food additive, the use of this preservative reduces the commercial value of crab. Further, the preservative described in the document is insufficient in the effect of suppressing the flavor deterioration of the crab meat after cooking by heating and cooling and thawing.

特開2007−20566号公報JP, 2007-20566, A

本発明の目的は、食品添加物表示を必要としない有効成分を用いて、食品添加物又は調味料でカニミソ本来の濃厚な風味を変えることなく、加熱調理及び冷解凍後において本来の濃厚な風味を有するカニミソを提供するために使用される、カニミソの冷解凍後の風味低下抑制剤、活カニの浸漬処理用水溶液、及び、該水溶液を用いたカニミソ又は冷凍カニミソの製造方法を提供することである。 The object of the present invention is to use an active ingredient that does not require food additive labeling, without changing the rich flavor of the original Kanimiso with food additives or seasonings, and after cooking and cooling and thawing the original rich flavor. Used to provide a crab meat having, a flavor reduction inhibitor after cold thawing of crab meat, an aqueous solution for immersion treatment of active crab, and a method for producing a crab or a frozen crab using the aqueous solution. is there.

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、特定の抽出物を特定量含有した特定の塩化ナトリウム濃度の水溶液に、活カニを特定時間浸漬することで、その後の加熱調理及び冷解凍後に生じ得るカニミソの濃厚な風味の低下を抑制できることを見出し、本発明を完成するに至った。 As a result of repeated studies to solve the above-mentioned problems, the present inventors immerse the active crab for a specific time in an aqueous solution of a specific sodium chloride concentration containing a specific amount of the specific extract, and then heat it. The present inventors have found that it is possible to suppress the rich flavor deterioration of crab meat that may occur after cooking and thawing, and have completed the present invention.

即ち、本発明の第一は、エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物を含む、加熱調理されたカニミソの冷解凍後の風味低下抑制剤に関する。当該カニミソの冷解凍後の風味低下抑制剤は、前記抽出物を、前記風味低下抑制剤の乾燥重量全体中、乾燥重量で50〜100重量%含むことが好ましい。
本発明の第二は、エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物を0.1〜500ppm(乾燥重量)含有し、塩化ナトリウム濃度が2〜3.5重量%である、加熱調理されたカニミソの冷解凍後の風味低下を抑制するための、活カニの浸漬処理用水溶液に関する。当該水溶液は、前記カニミソの冷解凍後の風味低下抑制剤を用いたものであってよい。
本発明の第三は、温度が1〜35℃の範囲にある前記水溶液中に、酸素が供給された状態で50〜20000分間浸漬された活カニから取り出されたカニミソに関し、また、当該カニミソが加熱調理された後、冷凍された冷凍カニミソにも関する。さらに、温度が1〜35℃の範囲にある前記水溶液中に、酸素が供給された状態で50〜20000分間浸漬された活カニを加熱調理してから取り出されたカニミソにも関し、また、当該カニミソが冷凍された冷凍カニミソにも関する。当該冷凍カニミソは、加熱調理したカニから取り出された後、再加熱され、その後冷凍されたものであってもよい。更にまた、以上の冷凍カニミソが解凍された冷解凍カニミソにも関する。
本発明の第四は、エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物を0.1〜500ppm(乾燥重量)含有し、塩化ナトリウム濃度が2〜3.5重量%、温度が1〜35℃の範囲にある水溶液中に、酸素が供給された状態で活カニを50〜20000分間浸漬し、その後該カニからカニミソを取り出して加熱調理してから冷凍することを特徴とする、冷凍カニミソの製造方法に関する。また、エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物を0.1〜500ppm(乾燥重量)含有し、塩化ナトリウム濃度が2〜3.5重量%、温度が1〜35℃の範囲にある水溶液中に、酸素が供給された状態で活カニを50〜20000分間浸漬し、その後該カニを加熱調理してからカニミソを取り出し冷凍することを特徴とする、冷凍カニミソの製造方法にも関する。後者の製造方法においては、加熱調理したカニから取り出したカニミソを再加熱した後、冷凍してもよい。
That is, the first of the present invention relates to a flavor reduction inhibitor after cold thawing of heat-cooked kaniso, which contains at least one extract selected from the group consisting of enokitake mushroom extract, yeast extract and barley extract. .. It is preferable that the flavor reduction inhibitor after cold thawing of the crab meat contains the extract in a dry weight of 50 to 100% by weight in the total dry weight of the flavor reduction inhibitor.
The second of the present invention comprises 0.1 to 500 ppm (dry weight) of at least one extract selected from the group consisting of enokitake mushroom extract, yeast extract and barley extract, and has a sodium chloride concentration of 2 to 3 The present invention relates to an aqueous solution for dipping treatment of active crab, which is 0.5% by weight, for suppressing the deterioration of the flavor of heat-cooked crab meat after cooling and thawing. The aqueous solution may use the flavor reduction inhibitor after cold thawing of the crab meat.
The third of the present invention relates to a crab lime taken out from an active crab that has been immersed in the aqueous solution whose temperature is in the range of 1 to 35° C. for 50 to 20,000 minutes while oxygen is being supplied, and the crab mine is It also relates to frozen frozen crab meat that has been cooked and then frozen. Furthermore, the present invention also relates to a crab mine taken out after heating and cooking an active crab that has been immersed in the aqueous solution whose temperature is in the range of 1 to 35° C. for 50 to 20000 minutes while being supplied with oxygen. It also relates to frozen crabs, which are frozen crabs. The frozen crab miso may be one that is taken out from the cooked crab, reheated, and then frozen. Furthermore, the present invention also relates to a cold-thawed cypress that is thawed from the frozen cypress.
A fourth aspect of the present invention comprises 0.1 to 500 ppm (dry weight) of at least one extract selected from the group consisting of enokitake mushroom extract, yeast extract and barley extract, and has a sodium chloride concentration of 2 to 3 An active crab is immersed for 50 to 20,000 minutes in a state of being supplied with oxygen in an aqueous solution having a weight ratio of 0.5% by weight and a temperature of 1 to 35° C., and then the crab is taken out from the crab and cooked, and then frozen. The present invention relates to a method for producing frozen crab miso. Further, it contains 0.1 to 500 ppm (dry weight) of at least one extract selected from the group consisting of enokitake mushroom extract, yeast extract and barley extract, and the sodium chloride concentration is 2 to 3.5% by weight, It is characterized in that the active crab is immersed in an aqueous solution whose temperature is in the range of 1 to 35° C. for 50 to 20000 minutes in a state where oxygen is supplied, and then the crab is cooked, and then the crab miso is taken out and frozen. , Also relates to a method for producing frozen crab miso. In the latter manufacturing method, the crab miso taken out from the cooked crab may be reheated and then frozen.

本発明に従えば、食品添加物表示を必要としない有効成分を用いて、食品添加物又は調味料でカニミソ本来の濃厚な風味を変えることなく、加熱調理及び冷解凍後において本来の濃厚な風味を有するカニミソを提供するために使用される、カニミソの冷解凍後の風味低下抑制剤、活カニの浸漬処理用水溶液、及び、該水溶液を用いたカニミソ又は冷凍カニミソの製造方法を提供することができる。本発明によると、加熱調理後の冷解凍によるカニミソの濃厚な風味の低下が抑制され、いわゆる冷凍障害を抑制することができる。また、本発明の冷解凍後の風味低下抑制剤及び浸漬処理用水溶液は、食品添加物又は調味料を含む必要がないので、これらに由来する異味がカニミソに付着することも回避できる。更には、本発明の冷解凍後の風味低下抑制剤及び浸漬処理用水溶液は、食品添加物の表示が要請される材料を必須とするものではないので、食品添加物表示を避けることが可能である。本発明によると、加熱調理されたカニミソ、又はそれを含むカニを長期間冷凍保存した後解凍しても、本来の濃厚な風味を有するカニミソを提供することができるので、濃厚な風味を維持したカニミソ、又はそれを含むカニを輸送可能なエリアを拡大することができる。 According to the present invention, using an active ingredient that does not require food additive labeling, without changing the rich flavor of the original Kanimiso with food additives or seasonings, the original rich flavor after cooking and cooling and thawing. It is used to provide a crab meat having, a flavor reduction inhibitor after cold thawing of crab meat, an aqueous solution for dipping treatment of active crab, and a method for producing crab meat or frozen crab meat using the aqueous solution. it can. ADVANTAGE OF THE INVENTION According to this invention, the rich flavor fall of the crab meat by the thawing after heating and cooking is suppressed, and so-called freezing damage can be suppressed. In addition, since the flavor reduction inhibitor after cold thawing and the aqueous solution for immersion treatment of the present invention do not need to contain a food additive or a seasoning, it is possible to avoid that the off-taste derived from these is attached to the crab. Furthermore, since the flavor reduction inhibitor after cold thawing and the aqueous solution for immersion treatment of the present invention do not necessarily require materials for which labeling of food additives is required, it is possible to avoid labeling of food additives. is there. According to the present invention, even if the cooked crab meat or the crab containing it is frozen and stored for a long period of time and then thawed, the crab meat having the original rich flavor can be provided, so that the rich flavor was maintained. It is possible to expand the area where crabs or crabs containing them can be transported.

以下、本発明につき、さらに詳細に説明する。本発明のカニミソの冷解凍後の風味低下抑制剤は、加熱調理後の冷解凍によって生じ得るカニミソの濃厚な風味の低下を抑制するためのもので、特定の抽出物を含有する。本発明のカニミソの冷解凍後の風味低下抑制剤は、塩水に配合して使用されるもので、カニミソ、又はそれを含むカニを加熱調理する前に、本発明のカニミソの冷解凍後の風味低下抑制剤を含む塩水に活カニを浸漬することで本発明の目的を達成することができる。 Hereinafter, the present invention will be described in more detail. The flavor reduction inhibitor after cold thawing of crab meat of the present invention is for suppressing the rich reduction in flavor of crab meat that may be caused by cold thawing after cooking, and contains a specific extract. The flavor reduction inhibitor after cold thawing of the crab meat of the present invention is used by being mixed with salt water, and before the crab meat or the crab containing it is heated and cooked, the flavor of the crab meat of the present invention after the cold thawing. The object of the present invention can be achieved by immersing the active crab in salt water containing a reduction inhibitor.

本発明のカニミソの冷解凍後の風味低下抑制剤で使用する抽出物は、エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物である。 The extract used as the flavor reduction inhibitor after cold thawing of crab meat of the present invention is at least one extract selected from the group consisting of enokitake mushroom extract, yeast extract and barley extract.

前記エノキタケ抽出物としては特に限定されないが、例えば、エノキタケの子実体を熱水及び/又はアルコール等の抽出溶媒で抽出した抽出物、酵素やアルカリ性の溶媒でエノキタケの子実体を分解してから熱水やアルコール等の抽出溶媒で抽出した抽出物、更にはこれら抽出物を濃縮した濃縮液、前記抽出物または前記濃縮液を乾燥して得られた粉末等が挙げられる。これら抽出物は、消費者の安心安全志向から、水や天然由来エタノール以外の溶媒を用いない抽出物が好ましい。但し、コスト面を考えると、水がより好ましい。 The enokitake mushroom extract is not particularly limited, for example, an extract obtained by extracting fruit bodies of enokitake mushrooms with an extraction solvent such as hot water and/or alcohol, heat after decomposing the fruit bodies of enokitake mushrooms with an enzyme or an alkaline solvent. Examples of the extract include extracts extracted with an extraction solvent such as water or alcohol, concentrated solutions obtained by concentrating these extracts, and powders obtained by drying the extracts or the concentrated solutions. From the perspective of consumers' safety and security, these extracts are preferably extracts using no solvent other than water or naturally occurring ethanol. However, considering cost, water is more preferable.

抽出時の抽出溶媒の温度は、抽出溶媒の種類によって好適な温度幅が変動し得るが、一般に、抽出溶媒の大気圧下での沸点(℃)−20℃〜抽出溶媒の大気圧下での沸点(℃)が好ましい。抽出時の抽出溶媒の温度が、該抽出溶媒の大気圧下での沸点(℃)−20℃より低いと、冷解凍後のカニミソの濃厚な風味の低下を抑制する効果が弱くなる場合があり、大気圧下での沸点(℃)より高くなると、特殊な加圧設備が必要となるため、抽出方法が複雑になる場合がある。 Regarding the temperature of the extraction solvent during extraction, a suitable temperature range may vary depending on the type of the extraction solvent, but in general, the boiling point (° C.) of the extraction solvent under atmospheric pressure −20° C. to the extraction solvent under the atmospheric pressure. Boiling point (° C.) is preferred. When the temperature of the extraction solvent at the time of extraction is lower than the boiling point (° C.)-20° C. of the extraction solvent under atmospheric pressure, the effect of suppressing the rich flavor deterioration of kaniso after thawing may be weakened. When the temperature is higher than the boiling point (°C) under atmospheric pressure, special pressurizing equipment is required, which may complicate the extraction method.

前記エノキタケは、タマバリタケ科のキノコの一種であるFlammulina属velutipes種のことをいう。特に限定されないが、人工的に栽培した白色かつもやし状の市販エノキタケを使用することができる。かかる市販エノキタケは、一般に食用とされており、容易に入手可能である。 The above-mentioned Enokitake refers to a species of Flammulina velutipes, which is a kind of mushrooms belonging to the family Tamabaritake. Although not particularly limited, it is possible to use artificially cultivated white and bean sprouts-like commercial enoki mushrooms. Such commercially available Enoki mushrooms are generally edible and easily available.

前記酵母抽出物としては特に限定されないが、例えば、酵母を熱水やアルコール等の抽出溶媒で抽出した抽出物、酵素やアルカリ性の溶媒で酵母を分解してから熱水やアルコール等の抽出溶媒で抽出した抽出物、更にはこれら抽出物を濃縮した濃縮液、前記抽出物または前記濃縮液を乾燥して得られた粉末等が挙げられる。これら抽出物は、消費者の安心安全志向から、水や天然由来エタノール以外の溶媒を用いない抽出物が好ましい。但し、コスト面を考えると、水がより好ましい。 The yeast extract is not particularly limited, for example, an extract obtained by extracting yeast with an extraction solvent such as hot water or alcohol, with an extraction solvent such as hot water or alcohol after decomposing the yeast with an enzyme or an alkaline solvent. Examples include extracted extracts, concentrated liquids obtained by concentrating these extracts, powders obtained by drying the extract or the concentrated liquid, and the like. From the perspective of consumers' safety and security, these extracts are preferably extracts using no solvent other than water or naturally occurring ethanol. However, considering cost, water is more preferable.

抽出時の抽出溶媒の温度は、抽出溶媒の種類によって好適な温度幅が変動し得るが、一般に、抽出溶媒の大気圧下での沸点(℃)−20℃〜抽出溶媒の大気圧下での沸点(℃)が好ましい。抽出時の抽出溶媒の温度が、該抽出溶媒の大気圧下での沸点(℃)−20℃より低いと、冷解凍後のカニミソの濃厚な風味の低下を抑制する効果が弱くなる場合があり、大気圧下での沸点(℃)より高くなると、特殊な加圧設備が必要となるため、抽出方法が複雑になる場合がある。 Regarding the temperature of the extraction solvent during extraction, a suitable temperature range may vary depending on the type of the extraction solvent, but in general, the boiling point (° C.) of the extraction solvent under atmospheric pressure −20° C. to the extraction solvent under the atmospheric pressure. Boiling point (° C.) is preferred. When the temperature of the extraction solvent at the time of extraction is lower than the boiling point (° C.)-20° C. of the extraction solvent under atmospheric pressure, the effect of suppressing the rich flavor deterioration of kaniso after thawing may be weakened. When the temperature is higher than the boiling point (°C) under atmospheric pressure, special pressurizing equipment is required, which may complicate the extraction method.

前記酵母は、嫌気環境下で発酵する際に、糖を資化してアルコールを生成する微生物のことをいう。具体例として、サッカロミセス(Saccharomyces)属に属する酵母や、キャンディダ(Candida)属に属する酵母等が挙げられるが、特に限定されない。食経験が豊富である観点から、前記酵母は、サッカロミセス・セレビジエ(Saccharomyces cerevisiae)であってもよく、研究等で知見が多い観点から、前記酵母は、キャンディダ・ユーティリス(Candida utilis)であってもよい。 The yeast refers to a microorganism that assimilates sugar to produce alcohol during fermentation in an anaerobic environment. Specific examples include yeasts belonging to the genus Saccharomyces and yeasts belonging to the genus Candida, but are not particularly limited. From the viewpoint of rich food experience, the yeast may be Saccharomyces cerevisiae, and from the viewpoint of many findings in research, the yeast is Candida utilis. May be.

前記大麦抽出物としては特に限定されないが、例えば、大麦を熱水やアルコール等の抽出溶媒で抽出した抽出物、酵素やアルカリ性の溶媒で大麦を分解してから熱水やアルコール等の抽出溶媒で抽出した抽出物、更にはこれら抽出物を濃縮した濃縮液、前記抽出物または前記濃縮液を乾燥して得られた粉末等が挙げられる。これら抽出物は、消費者の安心安全志向から、水や天然由来エタノール以外の溶媒を用いない抽出物が好ましい。但し、コスト面を考えると、水がより好ましい。 The barley extract is not particularly limited, for example, an extract obtained by extracting barley with an extraction solvent such as hot water or alcohol, with an extraction solvent such as hot water or alcohol after decomposing barley with an enzyme or an alkaline solvent. Examples include extracted extracts, concentrated liquids obtained by concentrating these extracts, powders obtained by drying the extract or the concentrated liquid, and the like. From the perspective of consumers' safety and security, these extracts are preferably extracts using no solvent other than water or naturally occurring ethanol. However, considering cost, water is more preferable.

抽出時の抽出溶媒の温度は、抽出溶媒の種類によって好適な温度幅が変動し得るが、一般に、抽出溶媒の大気圧下での沸点(℃)−20℃〜抽出溶媒の大気圧下での沸点(℃)が好ましい。抽出時の抽出溶媒の温度が、該抽出溶媒の大気圧下での沸点(℃)−20℃より低いと、冷解凍後のカニミソの濃厚な風味の低下を抑制する効果が弱くなる場合があり、大気圧下での沸点(℃)より高くなると、特殊な加圧設備が必要となるため、抽出方法が複雑になる場合がある。 Regarding the temperature of the extraction solvent during extraction, a suitable temperature range may vary depending on the type of the extraction solvent, but in general, the boiling point (° C.) of the extraction solvent under atmospheric pressure −20° C. to the extraction solvent under the atmospheric pressure. Boiling point (° C.) is preferred. When the temperature of the extraction solvent at the time of extraction is lower than the boiling point (° C.)-20° C. of the extraction solvent under atmospheric pressure, the effect of suppressing the rich flavor deterioration of kaniso after thawing may be weakened. When the temperature is higher than the boiling point (°C) under atmospheric pressure, special pressurizing equipment is required, which may complicate the extraction method.

前記大麦は、中央アジア原産のイネ科の植物で、学名をHordeum vulgareといい、二条大麦と六条大麦、皮麦とはだか麦、うるち種ともち種に分類されるものをいう。 The barley is a plant belonging to the family Gramineae native to Central Asia, and has a scientific name of Hordeum vulgare, and is classified into two-row barley and six-row barley, barley and bare barley, and glutinous and glutinous species.

本発明のカニミソの冷解凍後の風味低下抑制剤は、エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物を、該風味低下抑制剤の乾燥重量全体に対し乾燥重量で50〜100重量%含有することが好ましい。より好ましくは70〜100重量%であり、さらに好ましくは90〜100重量%である。50重量%よりも少ないと、冷解凍後のカニミソの濃厚な風味の低下を抑制する効果を発揮できない場合がある。当該風味低下抑制剤に含まれ得る前記抽出物以外の固形分としては特に限定されず、天然由来の固形分であれば何を含有しても良い。 The flavor reduction inhibitor after cold thawing of crab meat of the present invention is at least one extract selected from the group consisting of enokitake extract, yeast extract and barley extract, in the entire dry weight of the flavor reduction inhibitor. On the other hand, it is preferable to contain 50 to 100% by dry weight. It is more preferably 70 to 100% by weight, and even more preferably 90 to 100% by weight. If the amount is less than 50% by weight, the effect of suppressing the rich flavor deterioration of kaniso after cooling and thawing may not be exhibited. The solid content other than the extract that can be contained in the flavor reduction inhibitor is not particularly limited, and any solid content derived from nature may be contained.

本発明のカニミソの冷解凍後の風味低下抑制剤の形状は特に限定されず、水溶液等の液体の形状であってもよいし、粉末状、顆粒状、ブロック状等の固形の形状であってもよい。 The shape of the flavor reduction inhibitor after cold thawing of crab meat of the present invention is not particularly limited, and may be a liquid shape such as an aqueous solution, or a solid shape such as powder, granule, or block. Good.

本発明のカニミソの冷解凍後の風味低下抑制剤は、これを真水、海水、または塩水に添加することで、次に説明する本発明の活カニの浸漬処理用水溶液を調製するために使用することができる。また、収穫した活カニを一時的に飼育している生け簀に、当該風味低下抑制剤を投入することで、冷解凍後のカニミソの濃厚な風味の低下を抑制する効果を得ることもできる。 The flavor reduction inhibitor after cold thawing of crab meat of the present invention is used by adding it to fresh water, sea water, or salt water to prepare an aqueous solution for immersion treatment of the active crab of the present invention described below. be able to. In addition, by adding the flavor reduction inhibitor to the cages in which live harvested live crabs are temporarily bred, it is possible to obtain the effect of suppressing the rich flavor reduction of the crabmeat after cooling and thawing.

本発明の活カニの浸漬処理用水溶液は、前記抽出物を含有するものである。該水溶液に活カニを浸漬することで使用される。この使用後に、活カニを前記水溶液から取り出して甲羅ごと加熱調理し、冷凍保存、更に解凍してからカニミソを甲羅から分離した際に、カニミソの濃厚な風味の低下を抑制することができる。また、前記使用後に、活カニを前記水溶液から取り出し、カニミソを甲羅から分離した後、カニミソを加熱調理し、冷凍保存、更に解凍した際にも、カニミソの濃厚な風味の低下を抑制することができる。更に、前記使用後に、活カニを前記水溶液から取り出して甲羅ごと加熱調理してから、カニミソを甲羅から分離し、必要に応じて殺菌等を目的にカニミソを再加熱した後、得たカニミソを冷凍保存、更に解凍した際にも、カニミソの濃厚な風味の低下を抑制することができる。 The aqueous solution for dipping treatment of live crab of the present invention contains the above extract. It is used by immersing live crab in the aqueous solution. After this use, when the live crab is taken out of the aqueous solution, cooked together with the shell, frozen and stored, and then thawed and then the crab meat is separated from the shell, it is possible to suppress the rich flavor deterioration of the crab meat. Further, after the use, after removing the active crab from the aqueous solution, separating the crab from the shell, heat cooking the crab, frozen storage, even when thawed, it is possible to suppress the reduction of the rich flavor of the crab. it can. Furthermore, after the use, after removing the live crab from the aqueous solution and cooking it with the shell, the crab miso is separated from the shell and, if necessary, the crab miso is reheated for the purpose of sterilization, etc., and the obtained crab miso is frozen. Even when it is stored and then thawed, it is possible to suppress the decrease in the rich flavor of crab miso.

本発明の活カニの浸漬処理用水溶液は、前記抽出物を乾燥重量で0.1〜500ppm含有することが好ましい。当該含有量は、1〜500ppmがより好ましく、10〜450ppmが更に好ましく、50〜400ppmが特に好ましく、100〜400ppmが最も好ましい。0.1ppmより少ないと、冷解凍後のカニミソの濃厚な風味の低下を抑制する効果を発揮できない場合がある。500ppmを越えると前記抽出物に由来する色素成分がカニミソに付着したり、カニミソの濃厚な風味が損なわれる場合がある。 The aqueous solution for immersion treatment of live crab of the present invention preferably contains the extract in a dry weight of 0.1 to 500 ppm. The content is more preferably 1 to 500 ppm, further preferably 10 to 450 ppm, particularly preferably 50 to 400 ppm, and most preferably 100 to 400 ppm. If it is less than 0.1 ppm, it may not be possible to exert the effect of suppressing the rich flavor deterioration of crab meat after cooling and thawing. If it exceeds 500 ppm, the pigment component derived from the extract may adhere to the kaniso or the rich flavor of the kaniso may be impaired.

本発明の活カニの浸漬処理用水溶液の塩化ナトリウム濃度は、2〜3.5重量%が好ましく、2.3〜3.5重量%がより好ましく、2.3〜3.2重量%がさらに好ましく、2.5〜3重量%が特に好ましい。塩化ナトリウム濃度が2重量%未満、又は3.5重量%を超えると、該水溶液中でカニが生育できず、却ってカニミソの濃厚な風味が損なわれる場合がある。 The sodium chloride concentration of the aqueous solution for immersion treatment of live crab of the present invention is preferably 2 to 3.5% by weight, more preferably 2.3 to 3.5% by weight, and further preferably 2.3 to 3.2% by weight. 2.5 to 3% by weight is particularly preferable. When the sodium chloride concentration is less than 2% by weight or more than 3.5% by weight, the crab cannot grow in the aqueous solution, which may rather impair the rich flavor of crab miso.

本発明の活カニの浸漬処理用水溶液は、上記塩化ナトリウム濃度を満足する限り、塩化ナトリウム以外の塩類を含有していてもよい。しかし、塩化ナトリウム以外の塩類の含有量は、塩化ナトリウム重量に対して1/3の重量までに制限することが好ましい。塩化ナトリウム以外の塩類の種類としては食品添加物として使用し得る塩類であれば特に限定されない。 The aqueous solution for immersion treatment of active crab of the present invention may contain salts other than sodium chloride as long as the above sodium chloride concentration is satisfied. However, it is preferable that the content of salts other than sodium chloride is limited to 1/3 of the weight of sodium chloride. The type of salt other than sodium chloride is not particularly limited as long as it can be used as a food additive.

前記浸漬処理用水溶液は、上記塩化ナトリウム濃度を満足する限り、真水に食塩を添加して製造されたものであってもよいし、海水を利用して、又は、海水の塩化ナトリウム濃度を調整したものを利用して製造されたものであってもよい。 The aqueous solution for immersion treatment may be one prepared by adding salt to fresh water as long as the above sodium chloride concentration is satisfied, seawater is used, or the sodium chloride concentration of seawater is adjusted. It may be manufactured by using a material.

カニミソ、又はそれを含むカニを加熱調理及び冷凍する前に、本発明の活カニの浸漬処理用水溶液に活カニを浸漬し一定時間保持することで、本来の濃厚な風味の低下が抑制されたカニミソを製造することができる。当該製造の具体的態様の一例は以下のとおりである。必要に応じ前記水溶液を殺菌した後、該水溶液の温度を、好適には1〜35℃の範囲とし、該水溶液に酸素を供給しつつ活カニを浸漬して、好適には50〜20000分間保持する。その後、該水溶液から活カニを取り出し、甲羅ごとカニミソの加熱調理及び冷解凍を行った後、甲羅からカニミソを分離することで、本来の濃厚な風味の低下が抑制されたカニミソを得ることができる。また、上述のように、前記水溶液から活カニを取り出し、カニミソを甲羅から分離した後、カニミソの加熱調理及び冷解凍を行うことでも、本来の濃厚な風味の低下が抑制されたカニミソを得ることができる。更には、上述のように、甲羅ごとカニミソの加熱調理を行った後、カニミソを甲羅から分離し、必要に応じて殺菌等を目的にカニミソを再加熱した後、得たカニミソの冷解凍を行うことでも、本来の濃厚な風味の低下が抑制されたカニミソを得ることができる。前記水溶液から活カニを取り出し、水溶液の殺菌方法としては特に限定されず、例えば、紫外線照射による殺菌、オゾン殺菌、塩素殺菌などを行なえばよい。また、カニミソを再加熱する際の条件も特に限定されず、熱水に浸漬したり、蒸したりする方法などが挙げられる。 Before cooking and freezing the crab meat or the crab containing it, by dipping the active crab in the aqueous solution for dipping treatment of the active crab of the present invention and holding it for a certain period of time, the original reduction in rich flavor was suppressed. Can produce crab. An example of the specific embodiment of the production is as follows. After sterilizing the aqueous solution as needed, the temperature of the aqueous solution is preferably set in the range of 1 to 35° C., the active crab is immersed while supplying oxygen to the aqueous solution, and preferably kept for 50 to 20000 minutes. To do. After that, the live crab is taken out of the aqueous solution, and the shellfish and the shellfish are cooked and cold-thawed, and then the shellfish is separated from the shell to obtain the original rich flavor-controlled crabmeat. .. In addition, as described above, by removing the active crab from the aqueous solution, separating the crab from the shell, and then cooking and cooling and thawing the crab, it is possible to obtain a crab which has suppressed the original rich flavor reduction. You can Furthermore, as described above, after cooking the shellfish with the shell, the shellfish is separated from the shell, and if necessary, the shellfish is reheated for the purpose of sterilization, etc., and then the obtained shellfish is cooled and thawed. Even in this case, it is possible to obtain the crab miso in which the original rich flavor reduction is suppressed. The method for sterilizing the aqueous solution by taking out the active crab from the aqueous solution is not particularly limited, and for example, sterilization by ultraviolet irradiation, ozone sterilization, chlorine sterilization and the like may be performed. Further, the conditions for reheating the crab meat are also not particularly limited, and examples thereof include a method of dipping in steamed water or steaming.

前記水溶液の温度はカニが生育できる温度域にあればよく、具体的には、1〜35℃の範囲でコントロールすることが好ましい。該温度が1℃より低い又は35℃より高いと、前記水溶液中で活カニの活動が低下して、冷解凍後のカニミソの濃厚な風味の低下を抑制する効果を発揮できない場合がある。より好ましい温度範囲は、本発明を適用するカニの種類によって異なる。例えば、毛ガニの場合、前記水溶液の温度は1〜15℃が好ましく、ズワイガニの場合、前記水溶液の温度は1〜10℃が好ましく、ワタリガニの場合、前記水溶液の温度は7〜35℃が好ましい。 The temperature of the aqueous solution may be in the temperature range where the crab can grow, and specifically, it is preferable to control the temperature in the range of 1 to 35°C. If the temperature is lower than 1° C. or higher than 35° C., the activity of active crab in the aqueous solution may decrease, and the effect of suppressing the rich flavor deterioration of crab miso after cooling and thawing may not be exhibited. A more preferable temperature range depends on the type of crab to which the present invention is applied. For example, in the case of hair crab, the temperature of the aqueous solution is preferably 1 to 15°C, in the case of snow crab, the temperature of the aqueous solution is preferably 1 to 10°C, and in the case of blue crab, the temperature of the aqueous solution is preferably 7 to 35°C.

前記水溶液への酸素の供給方法としては、カニの生育に必要な溶存酸素濃度を確保できれば、どのような方法であってもよい。 As a method of supplying oxygen to the aqueous solution, any method may be used as long as the dissolved oxygen concentration necessary for growing a crab can be secured.

活カニを前記水溶液中に浸漬する時間は、50〜20000分間が好ましく、50〜9000分間がより好ましく、50〜7200分間が更に好ましく、100〜6000分間が特に好ましく、150〜6000分間が極めて好ましい。浸漬時間が50分間より短いと浸漬処理時間が不足し、冷解凍後のカニミソの濃厚な風味の低下を抑制する効果を発揮できない場合がある。また20000分間より長いとカニミソの濃厚な風味が損なわれる場合がある。 The time for immersing the live crab in the aqueous solution is preferably 50 to 20000 minutes, more preferably 50 to 9000 minutes, further preferably 50 to 7200 minutes, particularly preferably 100 to 6000 minutes, and particularly preferably 150 to 6000 minutes. .. If the dipping time is shorter than 50 minutes, the dipping treatment time will be insufficient, and the effect of suppressing the rich flavor deterioration of the cypress after thawing may not be exhibited. If it is longer than 20,000 minutes, the rich flavor of the crab meat may be impaired.

以上で説明した本発明の活カニの浸漬処理用水溶液への活カニの浸漬処理は、静置した水槽で行なってもよいし、水槽ごと輸送しつつ行なってもよい。輸送しながら該浸漬処理を行う場合であっても、本発明の方法によると、水溶液の温度が前述した範囲内にあれば厳格な温度管理を行なう必要がないので、従来の魚介類を生きたまま輸送する方法と比較して輸送コストを抑制することができる。 The immersion treatment of the active crab in the aqueous solution for immersion treatment of the active crab of the present invention described above may be performed in a static water tank or may be performed while transporting the whole water tank. Even when the dipping treatment is carried out during transportation, according to the method of the present invention, it is not necessary to perform strict temperature control as long as the temperature of the aqueous solution is within the above-mentioned range. The transportation cost can be suppressed as compared with the method of transporting as it is.

浸漬処理後の活カニは、殻をむかずに殻付きで、常法により加熱調理に付すことができる。加熱調理は公知の方法であってよく、特に限定されないが、熱水に投入してボイルしたり、蒸したりする方法が挙げられる。このように加熱調理されたカニを冷凍して甲羅付きの冷凍カニとした後、解凍して、カニミソを甲羅から分離して食することができる。また、浸漬処理後の活カニを加熱調理に付すことなく、直ちにカニミソを取り出し、そのカニミソを常法により加熱処理に付してもよい。このように加熱調理されたカニミソを冷凍することで、冷凍カニミソを製造することができ、これを解凍することで食することができる。更には、浸漬処理及び加熱調理後のカニからカニミソを取り出した後、必要に応じて殺菌等を目的にカニミソを再加熱した後、得たカニミソを冷凍して冷凍カニミソを製造した後、これを解凍することで食することもできる。前記甲羅付きの冷凍カニ又は冷凍カニミソは、冷凍で1週間〜24カ月間程度保存後に解凍しても、カニミソ本来の濃厚な風味を賞味することができる。 The live crab after the dipping treatment has a shell without peeling, and can be cooked by a conventional method. The heating and cooking may be a known method and is not particularly limited, but examples thereof include a method of boiling in hot water and steaming. After the crab cooked in this way is frozen into a frozen crab with a shell, it can be thawed and crab meat can be separated from the shell and eaten. Alternatively, the crab meat may be immediately taken out without subjecting the live crab after the dipping treatment to the heat cooking, and the crab meat may be subjected to the heat treatment by a conventional method. Frozen crab meat can be produced by freezing the crab meat cooked in this way, and can be eaten by thawing it. Furthermore, after removing the crab from the crab after the immersion treatment and cooking, after reheating the crab for the purpose of sterilization, etc., if necessary, after freezing the crab so obtained to produce a frozen crab, this It can also be eaten by thawing. The frozen crab or frozen crab meat with the shell can enjoy the original rich flavor of the crab meat even if it is thawed after being stored in the frozen state for about 1 week to 24 months.

本発明を適用可能なカニの種類は、カニミソを食することができるカニであれば、特に限定されない。具体例としては、毛ガニ、ズワイガニ、紅ズワイガニ、ワタリガニ等のカニ下目のカニが挙げられる。 The type of crab to which the present invention can be applied is not particularly limited as long as the crab can eat crab miso. Specific examples thereof include lower crabs such as hairy crab, snow crab, red snow crab, and blue crab.

以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。 Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited to these examples. In the examples, "parts" and "%" are based on weight.

(製造例1) エノキタケ抽出物の作製
市販のエノキタケ(子実体)100gに100℃に加熱した熱水200mlを加え、2時間保持した。その後固形分を濾別して、固形分量が0.6重量%のエノキタケ抽出物を得た。得られたエノキタケ抽出物の0.5重量%(W/W)固形分濃度の水溶液の粘度は17mPa・sであった。
(Production Example 1) Preparation of Enokitake mushroom extract To 100 g of commercially available Enokitake mushroom (fruit body), 200 ml of hot water heated to 100°C was added and held for 2 hours. Then, the solid content was separated by filtration to obtain an enokitake extract having a solid content of 0.6% by weight. The viscosity of an aqueous solution of the obtained Enokitake mushroom extract having a solid content concentration of 0.5% by weight (W/W) was 17 mPa·s.

(製造例2) 酵母抽出物の作製
パン酵母(株式会社カネカ製「カネカイーストGA」)100gに100℃に加熱した熱水200mlを加え、2時間保持した。その後固形分を濾別して、固形分量が1.0重量%の酵母抽出物を得た。得られた酵母抽出物の0.5重量%(W/W)固形分濃度の水溶液の粘度は8mPa・sであった。
(Production Example 2) Preparation of yeast extract To 100 g of baker's yeast ("Kaneka Yeast GA" manufactured by Kaneka Corporation), 200 ml of hot water heated to 100°C was added and held for 2 hours. Thereafter, the solid content was filtered off to obtain a yeast extract having a solid content of 1.0% by weight. The viscosity of an aqueous solution of the obtained yeast extract having a solid content concentration of 0.5% by weight (W/W) was 8 mPa·s.

(製造例3) 大麦抽出物の作製
大麦粉(石橋工業株式会社製「大麦粉」)100gに100℃に加熱した熱水200mlを加え、2時間保持した。その後固形分を濾別して、固形分量が0.5重量%の大麦抽出物を得た。得られた大麦抽出物の0.5重量%(W/W)固形分濃度の水溶液の粘度は5mPa・sであった。
(Production Example 3) Preparation of barley extract To 100 g of barley flour ("Barley flour" manufactured by Ishibashi Industry Co., Ltd.), 200 ml of hot water heated to 100°C was added and held for 2 hours. Then, the solid content was filtered off to obtain a barley extract having a solid content of 0.5% by weight. The viscosity of an aqueous solution of the obtained barley extract having a solid content concentration of 0.5% by weight (W/W) was 5 mPa·s.

(製造例4) 昆布抽出物の作製
真昆布(株式会社くらこん製「真昆布」)100gに100℃に加熱した熱水200mlを加え、2時間保持した。その後固形分を濾別して、固形分量が2.0重量%のコンブ抽出物を得た。得られたコンブ抽出物の0.5重量%(W/W)固形分濃度の水溶液の粘度は120mPa・sであった。
(Production Example 4) Preparation of kelp extract To 100 g of true kelp (“true kelp” manufactured by Kurako Co., Ltd.) was added 200 ml of hot water heated to 100° C., and the mixture was kept for 2 hours. Then, the solid content was separated by filtration to obtain a kelp extract having a solid content of 2.0% by weight. The viscosity of an aqueous solution of the obtained kelp extract having a solid content concentration of 0.5% by weight (W/W) was 120 mPa·s.

<カニミソの濃厚な風味の評価>
実施例および比較例において得たカニミソの風味は、訓練された10名(男性5人、女性5人)のパネラーにカニミソを食してもらい、以下の基準により評価した。10人の各評価点の平均値を評価値とした。但し、以下に示した評価基準は毛ガニを用いた実施例に関するものである。ズワイガニを用いた実施例においては、下記評価基準中の「実施例9」を「実施例14」に読み替えた評価基準を使用し、ワタリガニを用いた実施例においては、下記評価基準中の「実施例9」を「実施例16」に読み替えた評価基準を使用した。
5点:実施例9のカニミソよりも非常に良く、濃厚な風味を非常に強く感じる。
4点:実施例9のカニミソよりも良く、濃厚な風味を強く感じる。
3点:実施例9のカニミソと同等で、濃厚な風味が感じられる。
2点:実施例9のカニミソよりも悪く、濃厚な風味が感じられにくい。
1点:実施例9のカニミソよりも非常に悪く、異味が強く濃厚な風味が感じられない。
<Evaluation of the rich flavor of crab miso>
The flavor of kaniso obtained in the examples and comparative examples was evaluated by the following criteria by having 10 trained panelists (5 men and 5 women) eat kaniso. The average value of the evaluation points of 10 persons was used as the evaluation value. However, the evaluation criteria shown below relate to Examples using hair crab. In the examples using snow crab, the evaluation criteria obtained by replacing “Example 9” in the following evaluation criteria with “Example 14” were used, and in the examples using blue crab, “implementation” in the following evaluation criteria was used. The evaluation standard which replaced "Example 9" with "Example 16" was used.
5 points: It is much better than the crab meat of Example 9, and the rich flavor is felt very strongly.
4 points: Better than the crab meat of Example 9 and strongly felt a rich flavor.
3 points: Similar to the crab meat of Example 9, a rich flavor is felt.
2 points: It is worse than the crab meat of Example 9, and it is difficult to feel a rich flavor.
1 point: It is much worse than the crab meat of Example 9, and it has a strong off-taste and no rich flavor is felt.

(実施例1)
表1の配合に従い、製造例1で得られたエノキタケ抽出物1重量%と、食塩3重量%を配合した水溶液200リットルを水槽に調製し、水温を5℃にコントロールした。該水槽に、活毛ガニ10体を浸漬し、酸素を供給しながら、360分間保持した後、水揚げした。水揚げ後速やかに脚を縛り、沸騰した3%の食塩水中で20分間ボイルした。その後、冷水中で荒熱を取り、水気を切った後に包装し、−20℃で冷凍した。その温度で1週間冷凍保存した後、カニを冷凍庫から取り出し、5℃の恒温槽に1日静置して、自然解凍させた。その後、甲羅をむいてカニミソを採取し、カニミソの濃厚な風味について評価した。その結果を表1に示した。
(Example 1)
According to the formulation in Table 1, 200 liters of an aqueous solution containing 1% by weight of the Enokitake mushroom extract obtained in Production Example 1 and 3% by weight of salt was prepared in a water tank, and the water temperature was controlled at 5°C. Ten living crabs were dipped in the water tank, kept for 360 minutes while supplying oxygen, and then landed. Immediately after landing, the legs were bound and boiled in boiling 3% saline for 20 minutes. Then, it was taken out of cold heat in cold water to remove water, then packaged and frozen at -20°C. After freezing and storing at that temperature for 1 week, the crab was taken out from the freezer and allowed to stand in a constant temperature bath at 5°C for 1 day to be naturally thawed. After that, the shells were peeled off to collect the crab, and the rich flavor of the crab was evaluated. The results are shown in Table 1.

Figure 2020103123
Figure 2020103123

(実施例2)
表1の配合に従い、前記エノキタケ抽出物の代わりに、製造例2で得られた酵母抽出物を配合した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表1に示した。
(Example 2)
According to the formulation of Table 1, a kaniso was obtained in the same manner as in Example 1 except that the yeast extract obtained in Production Example 2 was blended in place of the Enoki mushroom extract. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 1.

(実施例3)
表1の配合に従い、前記エノキタケ抽出物の代わりに、製造例3で得られた大麦抽出物を配合した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表1に示した。
(Example 3)
According to the formulation of Table 1, a kaniso was obtained in the same manner as in Example 1 except that the barley extract obtained in Production Example 3 was blended in place of the Enoki mushroom extract. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 1.

(比較例1)
表1の配合に従い、前記エノキタケ抽出物の代わりに、製造例4で得られた昆布抽出物を配合した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表1に示した。
(Comparative Example 1)
According to the formulation of Table 1, a kaniso was obtained in the same manner as in Example 1 except that the kelp extract obtained in Production Example 4 was blended instead of the Enoki mushroom extract. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 1.

表1から明らかなように、抽出物の0.5%(W/W)固形分濃度の水溶液の粘度が3〜50mPa・sの範囲にあるエノキタケ抽出物(製造例1)、酵母抽出物(製造例2)、又は、大麦抽出物(製造例3)を含む食塩水に浸漬し、加熱調理及び冷解凍したカニから得られたカニミソ(実施例1〜3)は、いずれも、本来の濃厚な風味が感じられた。一方、抽出物の0.5%(W/W)固形分濃度の水溶液の粘度が120mPa・sの昆布抽出物(製造例4)を含む食塩水に浸漬し、加熱調理及び冷解凍したカニから得られたカニミソ(比較例1)は、本来の濃厚な風味が感じられにくかった。 As is apparent from Table 1, the enokitake mushroom extract (Production Example 1) and the yeast extract (in which the viscosity of the aqueous solution having a solid content concentration of 0.5% (W/W) of the extract is in the range of 3 to 50 mPa·s (Production Example 1) Production Example 2) or crab meat (Examples 1 to 3) obtained from crabs that were immersed in a saline solution containing a barley extract (Production Example 3), cooked and cooled and thawed had the original rich concentration. I could feel the unique flavor. On the other hand, from a crab which was immersed in a saline solution containing a kelp extract (Production Example 4) having a viscosity of an aqueous solution having a solid content concentration of 0.5% (W/W) of 120 mPa·s (Production Example 4), cooked, and thawed. The resulting crab meat (Comparative Example 1) was hard to feel the original rich flavor.

(実施例4及び5、比較例2)
表2の配合に従い、エノキタケ抽出物の配合量を1.0重量%から、0.1重量%(実施例4)、5.0重量%(実施例5)、又は、10.0重量%(比較例2)に変更した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表2に示した。
(Examples 4 and 5, Comparative Example 2)
According to the formulation in Table 2, the amount of the enokitake extract compounded is from 1.0 wt% to 0.1 wt% (Example 4), 5.0 wt% (Example 5), or 10.0 wt% ( Crabs were obtained in the same manner as in Example 1 except that Comparative Example 2) was changed. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 2.

Figure 2020103123
Figure 2020103123

(比較例3)
表2の配合に従い、エノキタケ抽出物を配合せずに調製した水溶液を使用した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表2に示した。
(Comparative example 3)
A kaniso was obtained in the same manner as in Example 1 except that an aqueous solution prepared according to the formulation of Table 2 and not containing the enokitake extract was used. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 2.

表2から明らかなように、水溶液中のエノキタケ抽出物の固形分量が0.1〜500ppmの範囲にある食塩水に浸漬し、加熱調理及び冷解凍したカニから得られたカニミソ(実施例1、4、及び5)は、いずれも、本来の濃厚な風味が感じられた。特に前記固形分量が300ppmの食塩水に浸漬したカニのカニミソ(実施例5)の風味は極めて良好な評価であった。一方、エノキタケ抽出物の固形分量が600ppmの食塩水に浸漬し、加熱調理及び冷解凍したカニから得られたカニミソ(比較例2)は、本来の濃厚な風味が感じられにくかった。また、エノキタケ抽出物を含有しない食塩水に浸漬し、加熱調理及び冷解凍したカニから得られたカニミソ(比較例3)は、異味が強く本来の濃厚な風味が感じられなかった。 As is clear from Table 2, the kanimizo obtained from the crabs which were soaked in a saline solution in which the solid content of the enokitake mushroom extract in the aqueous solution was in the range of 0.1 to 500 ppm, cooked and cooled and thawed (Example 1, In 4 and 5), the original rich flavor was felt. In particular, the flavor of the crab crab meat (Example 5) dipped in a saline solution having a solid content of 300 ppm was evaluated as very good. On the other hand, the crab meat (Comparative Example 2) obtained from the crabs that had been cooked and cooled and thawed by immersing the enokitake mushroom extract in a saline solution having a solid content of 600 ppm (Comparative Example 2) was hard to sense the original rich flavor. In addition, the crab meat (Comparative Example 3) obtained from the crabs that had been soaked in a saline solution containing no Enokitake extract, cooked and thawed by cooling (Comparative Example 3) had a strong off-taste and the original rich flavor was not felt.

(実施例6)
表3の条件に従い、塩を含む水溶液の種類を食塩水から海水へ変更した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表3に示した。
(Example 6)
According to the conditions in Table 3, a crab lime was obtained in the same manner as in Example 1 except that the type of aqueous solution containing salt was changed from saline to seawater. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 3.

Figure 2020103123
Figure 2020103123

(比較例4)
この比較例は、特許文献1(特開2007−20566号公報)で最も良好な評価が示されている表5の試験番号215の保存処理液の組成に準拠したものである。表3の配合に従い、エノキタケ抽出物を配合せず、食塩の配合量を1重量%に変更し、更に、L−アスコルビン酸2重量%とグリシン0.5重量%を配合して水の量を調整した以外は、実施例1と同様にして活カニを浸漬した後、水揚げした。
(Comparative Example 4)
This comparative example is based on the composition of the preservation treatment liquid of test number 215 in Table 5 which shows the best evaluation in Patent Document 1 (JP 2007-20566 A). According to the formulation of Table 3, the enokitake mushroom extract was not blended, the blending amount of salt was changed to 1% by weight, and further 2% by weight of L-ascorbic acid and 0.5% by weight of glycine were blended to adjust the amount of water. Except for the adjustment, the active crab was immersed in the same manner as in Example 1 and then landed.

表3から明らかなように、エノキタケ抽出物を含み塩化ナトリウムの含有量が2〜3.5重量%の範囲にある水溶液に浸漬し、加熱調理及び冷解凍したカニから得られたカニミソ(実施例1、及び6)は、いずれも、本来の濃厚な風味が強く感じられた。一方、塩化ナトリウムを含有するが、エノキタケ抽出物を含有せず、特許文献1に記載のようにL−アスコルビン酸とグリシンを含有する水溶液に活カニを浸漬すると、360分間の浸漬によってカニが活力を失い、その後加熱調理及び冷解凍したカニから得られたカニミソ(比較例4)は、異味が強く本来の濃厚な風味が全く感じられなかった。 As is clear from Table 3, a kaniso obtained from a crab which was soaked in an aqueous solution containing an enokitake mushroom extract and having a sodium chloride content in the range of 2 to 3.5% by weight, cooked and thawed (Example) In 1 and 6), the original rich flavor was strongly felt. On the other hand, if the active crab contains sodium chloride but does not contain the enokitake mushroom extract and is immersed in an aqueous solution containing L-ascorbic acid and glycine as described in Patent Document 1, the crab becomes active by the immersion for 360 minutes. The crab miso (Comparative Example 4) obtained from the crab that had been cooked and then cooled and thawed had a strong off taste and the original rich flavor was not felt at all.

(実施例7及び8)
表4の条件に従い、水溶液の水温を5℃から、2℃(実施例7)、又は、15℃(実施例8)にそれぞれ変更した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表4に示した。
(Examples 7 and 8)
According to the conditions in Table 4, the water temperature of the aqueous solution was changed from 5° C. to 2° C. (Example 7) or 15° C. (Example 8), respectively, to obtain crab meat in the same manner as in Example 1. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 4.

Figure 2020103123
Figure 2020103123

表4から明らかなように、エノキタケ抽出物を含み水温が1〜35℃の食塩水に浸漬し、加熱調理及び冷解凍したカニから得られたカニミソ(実施例1、7、及び8)は、いずれも、本来の濃厚な風味が強く感じられた。 As is clear from Table 4, the kanimizo (Examples 1, 7, and 8) obtained from the crabs containing the enokitake mushroom extract and immersed in a saline solution having a water temperature of 1 to 35° C., cooked, and cooled and thawed (Examples 1, 7, and 8) were: In each case, the original rich flavor was strongly felt.

(実施例9及び10、比較例5及び6)
表5の条件に従い、水溶液へのカニの浸漬時間を360分間から、90分間(実施例9)、17280分間(実施例10)、30分間(比較例5)、又は、23040分間(比較例6)に変更した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表5に示した。
(Examples 9 and 10, Comparative Examples 5 and 6)
According to the conditions shown in Table 5, the immersion time of the crab in the aqueous solution was changed from 360 minutes to 90 minutes (Example 9), 17280 minutes (Example 10), 30 minutes (Comparative Example 5), or 23040 minutes (Comparative Example 6). ) Was obtained in the same manner as in Example 1 except that the content was changed to ). The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 5.

Figure 2020103123
Figure 2020103123

表5から明らかなように、エノキタケ抽出物を含む食塩水に50〜20000分間浸漬し、加熱調理及び冷解凍したカニから得られたカニミソ(実施例1、9、及び10)は、いずれも、本来の濃厚な風味が感じられた。一方、浸漬時間を30分間としたカニのカニミソ(比較例5)、及び、浸漬時間を23040分間としたカニのカニミソ(比較例6)は、いずれも、本来の濃厚な風味が感じられにくかった。 As is clear from Table 5, all the crabs (Examples 1, 9, and 10) obtained from the crabs that were soaked in a saline solution containing the enokitake mushroom extract for 50 to 20000 minutes, cooked and thawed were The original rich flavor was felt. On the other hand, both the crab crab miso (Comparative Example 5) having an immersion time of 30 minutes and the crab crab miso (Comparative Example 6) having an immersion time of 23040 minutes were difficult to feel the original rich flavor. ..

(実施例11及び12)
表6の条件に従い、冷凍保存期間を1週間から、3カ月間(実施例11)、又は、1日(実施例12)に変更した以外は実施例1と同様にして、カニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表6に示した。
(Examples 11 and 12)
According to the conditions of Table 6, the crab lime was obtained in the same manner as in Example 1 except that the frozen storage period was changed from 1 week to 3 months (Example 11) or 1 day (Example 12). The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 6.

Figure 2020103123
Figure 2020103123

(実施例13)
表6の条件に従い、実施例1と同様にエノキタケ抽出物を含む水溶液に浸漬した後、水揚げし、実施例1と同様にボイルしてから荒熱を取った後、カニの甲羅をむいてカニミソを採取した。採取したカニミソを包装し、−20℃で冷凍した。その温度で1週間冷凍保存した後、カニミソを冷凍庫から取り出し、5℃の恒温槽に1日静置して、自然解凍させた。得られたカニミソの濃厚な風味を評価した。その結果を表6に示した。
(Example 13)
According to the conditions of Table 6, after immersing in an aqueous solution containing the enokitake mushroom extract in the same manner as in Example 1, landing, boiling as in Example 1 and removing heat, the shell of the crab is peeled off and crab meat is removed. Was collected. The collected crabs were packaged and frozen at -20°C. After cryopreservation at that temperature for 1 week, the cypress was taken out of the freezer and allowed to stand in a constant temperature bath at 5° C. for 1 day to be naturally thawed. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 6.

(比較例7)
表6の条件に従い、−20℃で1週間の冷凍による保存条件を、4℃で1週間の冷蔵による保存条件に変更した以外は実施例1と同様にして、カニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表6に示した。
(Comparative Example 7)
According to the conditions shown in Table 6, the crab lime was obtained in the same manner as in Example 1 except that the storage condition for freezing at -20°C for 1 week was changed to the storage condition for cold storage at 4°C for 1 week. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 6.

(参考例)
実施例1の浸漬処理を行わず、活毛ガニの脚を縛り、沸騰した3%の食塩水中で20分間ボイルした。その後、冷水中で荒熱を取り、水気を切った後、包装や冷凍保存をせず直ちに、甲羅をむいてカニミソを採取し、カニミソの濃厚な風味について評価した。その結果を表6に示した。
(Reference example)
The dipping treatment of Example 1 was not performed, and the legs of the live hair crab were tied and boiled in boiling 3% saline for 20 minutes. Then, after removing the heat in cold water and draining the water, the shellfish was immediately peeled off without packaging or frozen storage, and the scallops were collected to evaluate the rich flavor of the scallops. The results are shown in Table 6.

表6から明らかなように、エノキタケ抽出物を含む食塩水に浸漬し、加熱調理した後、1日〜3カ月間冷凍保存したカニから得られたカニミソ(実施例1、11及び12)は、いずれも、本来の濃厚な風味が感じられた。特に、冷凍保存期間を1日としたカニのカニミソ(実施例12)の風味は極めて良好な評価であり、浸漬処理も冷解凍も行っていないカニのカニミソ(参考例)に迫る評価であった。また、浸漬処理後のカニからカニミソを取り出した後に加熱調理し、1週間冷凍保存して得られたカニミソも、本来の濃厚な風味が強く感じられた。一方、エノキタケ抽出物を含有しない食塩水に浸漬し、加熱調理した後、1週間冷凍保存したカニから得られたカニミソ(比較例3)は、異味が強く本来の濃厚な風味が感じられなかった。また、エノキタケ抽出物を含む食塩水に浸漬し、加熱調理した後、1週間冷蔵保存したカニから得られたカニミソ(比較例8)も、異味が強く本来の濃厚な風味が感じられなかった。 As is clear from Table 6, the kanimizo (Examples 1, 11 and 12) obtained from the crabs that had been soaked in a saline solution containing the enokitake mushroom extract and cooked under heating for 1 day to 3 months were: In each case, the original rich flavor was felt. In particular, the flavor of the crab crab meat (Example 12) having a frozen storage period of 1 day was a very good evaluation, and the evaluation was close to that of a crab crab meat (reference example) that was not subjected to the immersion treatment or the cooling and thawing. .. Moreover, the original rich flavor was strongly felt also in the crab meat obtained by taking out the crab meat from the crab after the immersion treatment, followed by heating and cooking, and refrigerating and storing for one week. On the other hand, the crab meat (Comparative Example 3) obtained from a crab that had been soaked in a saline solution containing no Enokitake extract, cooked and then frozen and stored for 1 week (Comparative Example 3) had a strong off taste and the original rich flavor was not felt. .. In addition, the crab meat (Comparative Example 8) obtained from a crab that had been soaked in a saline solution containing an enokitake extract, cooked, and then refrigerated for one week (Comparative Example 8) also had a strong off taste and the original rich flavor was not felt.

(実施例14)
表7の条件に従い、毛ガニの代わりにズワイガニを使用し、水溶液へのカニの浸漬時間を360分間から90分間に変更した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表7に示した。
(Example 14)
According to the conditions in Table 7, snow crab was used instead of the hair crab, and the crab immerse was obtained in the same manner as in Example 1 except that the immersion time of the crab in the aqueous solution was changed from 360 minutes to 90 minutes. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 7.

Figure 2020103123
Figure 2020103123

(実施例15)
表7の条件に従い、水溶液へのカニの浸漬時間を90分間から360分間に変更した以外は、実施例14と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表7に示した。
(Example 15)
According to the conditions in Table 7, a crab miso was obtained in the same manner as in Example 14 except that the immersion time of the crab in the aqueous solution was changed from 90 minutes to 360 minutes. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 7.

(実施例16)
表7の条件に従い、毛ガニの代わりにワタリガニを使用し、水溶液の水温を5℃から20℃に変更し、水溶液へのカニの浸漬時間を360分間から90分間に変更した以外は、実施例1と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表7に示した。
(Example 16)
According to the conditions in Table 7, Example 1 was repeated except that blue crab was used instead of the hair crab, the water temperature of the aqueous solution was changed from 5°C to 20°C, and the immersion time of the crab in the aqueous solution was changed from 360 minutes to 90 minutes. I obtained crab miso in the same way. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 7.

(実施例17)
表7の条件に従い、水溶液へのカニの浸漬時間を90分間から360分間に変更した以外は、実施例16と同様にしてカニミソを得た。得られたカニミソの濃厚な風味を評価した。その結果を表7に示した。
(Example 17)
According to the conditions in Table 7, a crab miso was obtained in the same manner as in Example 16 except that the immersion time of the crab in the aqueous solution was changed from 90 minutes to 360 minutes. The rich flavor of the resulting crab meat was evaluated. The results are shown in Table 7.

表7から明らかなように、エノキタケ抽出物を含む食塩水に浸漬し、加熱調理及び冷解凍したカニから得られたカニミソ(実施例1、及び14〜17)は、カニの種類に関わらず、本来の濃厚な風味が感じられた。
As is clear from Table 7, the crab meat (Examples 1 and 14 to 17) obtained from the crabs soaked in the saline solution containing the enokitake mushroom extract, cooked and cooled and thawed (Examples 1 and 14 to 17) were The original rich flavor was felt.

Claims (13)

エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物を含む、加熱調理されたカニミソの冷解凍後の風味低下抑制剤。 A flavor reduction inhibitor after cold thawing of heat-cooked kaniso, which comprises at least one extract selected from the group consisting of enokitake extract, yeast extract and barley extract. 前記抽出物を、前記風味低下抑制剤の乾燥重量全体中、乾燥重量で50〜100重量%含む、請求項1に記載の加熱調理されたカニミソの冷解凍後の風味低下抑制剤。 The flavor reduction inhibitor after cold thawing of heat-cooked kaniso according to claim 1, wherein the extract comprises 50 to 100% by dry weight of the total dry weight of the flavor reduction inhibitor. エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物を0.1〜500ppm(乾燥重量)含有し、塩化ナトリウム濃度が2〜3.5重量%である、加熱調理されたカニミソの冷解凍後の風味低下を抑制するための、活カニの浸漬処理用水溶液。 Enokitake mushroom extract, yeast extract and at least one extract selected from the group consisting of barley extract containing 0.1-500 ppm (dry weight), sodium chloride concentration is 2-3.5 wt%, An aqueous solution for dipping a live crab for suppressing the deterioration of the flavor of the cooked crab miso after cooling and thawing. 請求項1又は2に記載の加熱調理されたカニミソの冷解凍後の風味低下抑制剤を用いた請求項3に記載の水溶液。 The aqueous solution according to claim 3, wherein the flavor reduction inhibitor after cold thawing of the cooked crab meat according to claim 1 or 2 is used. 温度が1〜35℃の範囲にある請求項3又は4に記載の水溶液中に、酸素が供給された状態で50〜20000分間浸漬された活カニから取り出されたカニミソ。 Crabs taken from active crabs, which are immersed in the aqueous solution according to claim 3 or 4 having a temperature in the range of 1 to 35°C for 50 to 20000 minutes in a state where oxygen is supplied. 請求項5に記載のカニミソが加熱調理された後、冷凍された冷凍カニミソ。 Frozen crab mine which was frozen after the crab mine according to claim 5 was cooked. 温度が1〜35℃の範囲にある請求項3又は4に記載の水溶液中に、酸素が供給された状態で50〜20000分間浸漬された活カニを加熱調理してから取り出されたカニミソ。 A crab mine taken out after heat-cooking a live crab that has been immersed in the aqueous solution according to claim 3 or 4 for 50 to 20000 minutes in a temperature range of 1 to 35°C while oxygen is supplied. 請求項7に記載のカニミソが冷凍された冷凍カニミソ。 Frozen crab meat in which the crab meat according to claim 7 is frozen. 加熱調理したカニから取り出された後、再加熱され、その後冷凍された請求項8に記載の冷凍カニミソ。 The frozen crab mine according to claim 8, which is taken out from the cooked crab, reheated, and then frozen. 請求項6、8又は9に記載の冷凍カニミソが解凍された冷解凍カニミソ。 A cold-thawed crab imizo obtained by thawing the frozen crab lime according to claim 6, 8 or 9. エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物を0.1〜500ppm(乾燥重量)含有し、塩化ナトリウム濃度が2〜3.5重量%、温度が1〜35℃の範囲にある水溶液中に、酸素が供給された状態で活カニを50〜20000分間浸漬し、その後該カニからカニミソを取り出して加熱調理してから冷凍することを特徴とする、冷凍カニミソの製造方法。 Contains 0.1 to 500 ppm (dry weight) of at least one extract selected from the group consisting of enokitake mushroom extract, yeast extract and barley extract, and has a sodium chloride concentration of 2 to 3.5 wt% and a temperature of In an aqueous solution in the range of 1 to 35° C., the active crab is immersed for 50 to 20000 minutes in a state of being supplied with oxygen, and then the crab is taken out from the crab, cooked, and then frozen. Frozen crab miso production method. エノキタケ抽出物、酵母抽出物及び大麦抽出物からなる群より選ばれる少なくとも1種の抽出物を0.1〜500ppm(乾燥重量)含有し、塩化ナトリウム濃度が2〜3.5重量%、温度が1〜35℃の範囲にある水溶液中に、酸素が供給された状態で活カニを50〜20000分間浸漬し、その後該カニを加熱調理してからカニミソを取り出し冷凍することを特徴とする、冷凍カニミソの製造方法。 Contains 0.1 to 500 ppm (dry weight) of at least one extract selected from the group consisting of enokitake mushroom extract, yeast extract and barley extract, and has a sodium chloride concentration of 2 to 3.5 wt% and a temperature of Freezing, characterized in that an active crab is immersed in an aqueous solution in a range of 1 to 35° C. for 50 to 20000 minutes in a state where oxygen is supplied, and then the crab is cooked, and then the crab miso is taken out and frozen. Crab miso production method. 加熱調理したカニから取り出したカニミソを再加熱した後、冷凍する、請求項12に記載の製造方法。 The manufacturing method according to claim 12, wherein the crab miso taken out from the cooked crab is reheated and then frozen.
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