JP2020078494A - Soap bubble type aromatic material - Google Patents
Soap bubble type aromatic material Download PDFInfo
- Publication number
- JP2020078494A JP2020078494A JP2018213734A JP2018213734A JP2020078494A JP 2020078494 A JP2020078494 A JP 2020078494A JP 2018213734 A JP2018213734 A JP 2018213734A JP 2018213734 A JP2018213734 A JP 2018213734A JP 2020078494 A JP2020078494 A JP 2020078494A
- Authority
- JP
- Japan
- Prior art keywords
- mass
- group
- content
- soap bubble
- fragrance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000344 soap Substances 0.000 title claims abstract description 108
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 48
- 239000000463 material Substances 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 claims abstract description 100
- 239000002304 perfume Substances 0.000 claims abstract description 33
- 230000001953 sensory effect Effects 0.000 claims abstract description 28
- 239000003205 fragrance Substances 0.000 claims description 94
- 239000000126 substance Substances 0.000 claims description 48
- 239000007789 gas Substances 0.000 claims description 18
- 239000003945 anionic surfactant Substances 0.000 claims description 11
- 239000002280 amphoteric surfactant Substances 0.000 claims description 9
- 239000000796 flavoring agent Substances 0.000 claims description 7
- 235000019634 flavors Nutrition 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 239000001307 helium Substances 0.000 claims description 3
- 229910052734 helium Inorganic materials 0.000 claims description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- -1 α-damascon Chemical compound 0.000 description 35
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 239000007788 liquid Substances 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 150000002596 lactones Chemical class 0.000 description 6
- 229940117986 sulfobetaine Drugs 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 4
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- ULDHMXUKGWMISQ-SECBINFHSA-N (-)-carvone Chemical compound CC(=C)[C@@H]1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-SECBINFHSA-N 0.000 description 2
- NFLGAXVYCFJBMK-BDAKNGLRSA-N (-)-menthone Chemical compound CC(C)[C@@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-BDAKNGLRSA-N 0.000 description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- MBDOYVRWFFCFHM-SNAWJCMRSA-N (2E)-hexenal Chemical compound CCC\C=C\C=O MBDOYVRWFFCFHM-SNAWJCMRSA-N 0.000 description 2
- GKGOLPMYJJXRGD-UHFFFAOYSA-N 2-methyl-4-propyl-1,3-oxathiane Chemical compound CCCC1CCOC(C)S1 GKGOLPMYJJXRGD-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- INAXVXBDKKUCGI-UHFFFAOYSA-N 4-hydroxy-2,5-dimethylfuran-3-one Chemical compound CC1OC(C)=C(O)C1=O INAXVXBDKKUCGI-UHFFFAOYSA-N 0.000 description 2
- WRYLYDPHFGVWKC-UHFFFAOYSA-N 4-terpineol Chemical compound CC(C)C1(O)CCC(C)=CC1 WRYLYDPHFGVWKC-UHFFFAOYSA-N 0.000 description 2
- ROWKJAVDOGWPAT-UHFFFAOYSA-N Acetoin Chemical compound CC(O)C(C)=O ROWKJAVDOGWPAT-UHFFFAOYSA-N 0.000 description 2
- SCCDQYPEOIRVGX-UHFFFAOYSA-N Acetyleugenol Chemical compound COC1=CC(CC=C)=CC=C1OC(C)=O SCCDQYPEOIRVGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- DZNVIZQPWLDQHI-UHFFFAOYSA-N Citronellyl formate Chemical compound O=COCCC(C)CCC=C(C)C DZNVIZQPWLDQHI-UHFFFAOYSA-N 0.000 description 2
- PXIKRTCSSLJURC-UHFFFAOYSA-N Dihydroeugenol Chemical compound CCCC1=CC=C(O)C(OC)=C1 PXIKRTCSSLJURC-UHFFFAOYSA-N 0.000 description 2
- ZFMSMUAANRJZFM-UHFFFAOYSA-N Estragole Chemical compound COC1=CC=C(CC=C)C=C1 ZFMSMUAANRJZFM-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- XINCECQTMHSORG-UHFFFAOYSA-N Isoamyl isovalerate Chemical compound CC(C)CCOC(=O)CC(C)C XINCECQTMHSORG-UHFFFAOYSA-N 0.000 description 2
- BJIOGJUNALELMI-ONEGZZNKSA-N Isoeugenol Natural products COC1=CC(\C=C\C)=CC=C1O BJIOGJUNALELMI-ONEGZZNKSA-N 0.000 description 2
- XXIKYCPRDXIMQM-UHFFFAOYSA-N Isopentenyl acetate Chemical compound CC(C)=CCOC(C)=O XXIKYCPRDXIMQM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- 229960002903 benzyl benzoate Drugs 0.000 description 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- BJIOGJUNALELMI-ARJAWSKDSA-N cis-isoeugenol Chemical compound COC1=CC(\C=C/C)=CC=C1O BJIOGJUNALELMI-ARJAWSKDSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- WTWBUQJHJGUZCY-UHFFFAOYSA-N cuminaldehyde Chemical compound CC(C)C1=CC=C(C=O)C=C1 WTWBUQJHJGUZCY-UHFFFAOYSA-N 0.000 description 2
- 238000009795 derivation Methods 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- HCRBXQFHJMCTLF-ZCFIWIBFSA-N ethyl (2r)-2-methylbutanoate Chemical compound CCOC(=O)[C@H](C)CC HCRBXQFHJMCTLF-ZCFIWIBFSA-N 0.000 description 2
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 2
- WDAXFOBOLVPGLV-UHFFFAOYSA-N ethyl isobutyrate Chemical compound CCOC(=O)C(C)C WDAXFOBOLVPGLV-UHFFFAOYSA-N 0.000 description 2
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 2
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 description 2
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 2
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- PQLMXFQTAMDXIZ-UHFFFAOYSA-N isoamyl butyrate Chemical compound CCCC(=O)OCCC(C)C PQLMXFQTAMDXIZ-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- QJJDNZGPQDGNDX-UHFFFAOYSA-N oxidized Latia luciferin Chemical compound CC(=O)CCC1=C(C)CCCC1(C)C QJJDNZGPQDGNDX-UHFFFAOYSA-N 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 description 2
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 2
- IAEGWXHKWJGQAZ-UHFFFAOYSA-N trimethylpyrazine Chemical compound CC1=CN=C(C)C(C)=N1 IAEGWXHKWJGQAZ-UHFFFAOYSA-N 0.000 description 2
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristin Chemical compound CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 2
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 description 2
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 2
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 description 2
- YKFLAYDHMOASIY-UHFFFAOYSA-N γ-terpinene Chemical compound CC(C)C1=CCC(C)=CC1 YKFLAYDHMOASIY-UHFFFAOYSA-N 0.000 description 2
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- SFEOKXHPFMOVRM-UHFFFAOYSA-N (+)-(S)-gamma-ionone Natural products CC(=O)C=CC1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-UHFFFAOYSA-N 0.000 description 1
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- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- QWOZZTWBWQMEPD-UHFFFAOYSA-N 1-(2-ethoxypropoxy)propan-2-ol Chemical compound CCOC(C)COCC(C)O QWOZZTWBWQMEPD-UHFFFAOYSA-N 0.000 description 1
- CHLICZRVGGXEOD-UHFFFAOYSA-N 1-Methoxy-4-methylbenzene Chemical compound COC1=CC=C(C)C=C1 CHLICZRVGGXEOD-UHFFFAOYSA-N 0.000 description 1
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- 239000001278 2-(5-ethenyl-5-methyloxolan-2-yl)propan-2-ol Substances 0.000 description 1
- ZPENOSKWEKGDCX-UHFFFAOYSA-N 2-Benzyl-5-hydroxymethyl-1,3-dioxolane Chemical compound O1C(CO)COC1CC1=CC=CC=C1 ZPENOSKWEKGDCX-UHFFFAOYSA-N 0.000 description 1
- FLUWAIIVLCVEKF-UHFFFAOYSA-N 2-Methyl-1-phenyl-2-propanyl acetate Chemical compound CC(=O)OC(C)(C)CC1=CC=CC=C1 FLUWAIIVLCVEKF-UHFFFAOYSA-N 0.000 description 1
- MJTPMXWJHPOWGH-UHFFFAOYSA-N 2-Phenoxyethyl isobutyrate Chemical compound CC(C)C(=O)OCCOC1=CC=CC=C1 MJTPMXWJHPOWGH-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本発明は、シャボン玉型の芳香物に関する。 The present invention relates to a soap bubble type fragrance.
従来、シャボン玉液に香料を添加することはごく一般的に行われている（例えば、特許文献１、２）。さらには、シャボン玉を積極的に楽しむことを目的としてシャボン玉液に芳香剤を溶解してシャボン玉に臭いを付けること（特許文献３）も提案されている。 Conventionally, it has been very common to add a fragrance to a soap bubble liquid (for example, Patent Documents 1 and 2). Furthermore, it has also been proposed that an aromatic agent be dissolved in a soap bubble liquid to give a smell to the soap bubble for the purpose of positively enjoying the soap bubble (Patent Document 3).
しかしながら、特許文献１〜３を始めとする従来の技術においてシャボン玉液に添加する具体的な香料化合物に関する検討がされたものはなく、シャボン玉液に単に賦香しただけではシャボン玉自体からの香り立ちは弱いか、又は香りがしない場合もあった。 However, there have been no studies on specific fragrance compounds to be added to the soap bubble liquid in the conventional techniques including Patent Documents 1 to 3, and if the soap bubble liquid is simply perfume, it will be In some cases, the fragrance was weak or no scent.
したがって本発明は、シャボン玉表面からの香り立ちが高く、このシャボン玉が空中を移動することで効果的に香りを拡散させることができるシャボン玉型芳香物に関する。 Therefore, the present invention relates to a soap bubble type aromatic substance which has a high scent rising from the surface of the soap bubble and can diffuse the scent effectively by moving the soap bubble in the air.
そこで発明者らは、シャボン玉からの香料化合物の揮発挙動解析データと、ヒトのニオイ感覚強度データを用いて、シャボン玉からの香り立ちに寄与する香料化合物を選定するための基準を構築すべく鋭意検討を行った。その結果、シャボン玉に使用する香料として特定の条件を満たす香料化合物を特定量用いることによって、シャボン玉の表面からの香り立ちが高く、シャボン玉が空中を移動することで効果的に香りを拡散させることができることを見出した。 Therefore, the inventors of the present invention should establish a standard for selecting a fragrance compound that contributes to the scent formation from soap bubbles by using the volatilization behavior analysis data of the fragrance compounds from soap bubbles and the human odor sensation intensity data. Diligently studied. As a result, by using a specific amount of a fragrance compound that satisfies specific conditions as a fragrance used for soap bubbles, the scent from the surface of the soap bubble is high and the scent diffuses effectively as the soap bubbles move in the air. I found that I can do it.
本発明は、式(3)で計算されるLabeled Magnitude Scaleによる香料化合物の感覚強度に基づいて分類される下記(A)〜(C)群； The present invention includes the following groups (A) to (C) classified based on the sensory intensity of the perfume compound according to the Labeled Magnitude Scale calculated by the formula (3):
〔式中、ｐ、ｑ及びｒは香料化合物ごとに決定された変数、Kovatsは香料化合物のKovats Index、Doseはシャボン玉型芳香物中における香料化合物の含有量（質量％）を示す。〕
(A)群：シャボン玉型芳香物中0.001質量％の含有量において式(3)の感覚強度が1.0以上となる香料化合物
(B)群：シャボン玉型芳香物中0.01質量％の含有量において式(3)の感覚強度が1.0以上となる(A)群以外の香料化合物
(C)群：シャボン玉型芳香物中0.03質量％の含有量において式(3)の感覚強度が1.0以上となる(A)群及び(B)群以外の香料化合物
から選択される１種又は２種以上の香料化合物を合計量で0.001質量％以上0.2質量％以下含有し、かつ、下記の条件(ｉ)〜(iii)；
条件(ｉ) ：(A)群の香料化合物の含有量が0.001質量％以上
条件(ii) ：(B)群の香料化合物の含有量が0.01質量％以上
条件(iii)：(C)群の香料化合物の含有量が0.03質量％以上
のうち１以上を満たすシャボン玉型芳香物を提供するものである。
[In the formula, p, q, and r are variables determined for each fragrance compound, Kovats indicates the Kovats Index of the fragrance compound, and Dose indicates the content (% by mass) of the fragrance compound in the soap bubble-shaped aromatic substance. ]
Group (A): A fragrance compound having a sensory strength of formula (3) of 1.0 or more at a content of 0.001% by mass in a soap bubble type aromatic substance.
Group (B): A perfume compound other than group (A), which has a sensory intensity of formula (3) of 1.0 or more at a content of 0.01% by mass in a soap bubble type aromatic substance.
Group (C): One selected from a fragrance compound other than the groups (A) and (B) in which the sensory strength of the formula (3) is 1.0 or more at a content of 0.03% by mass in a soap bubble type aromatic substance, or It contains 0.001% by mass or more and 0.2% by mass or less of a total amount of two or more flavor compounds, and the following conditions (i) to (iii);
Condition (i): the content of the fragrance compound of the (A) group is 0.001% by mass or more Condition (ii): the content of the fragrance compound of the (B) group is 0.01% by mass or more Condition (iii): of the (C) group It is intended to provide a soap bubble type aromatic substance in which the content of the fragrance compound satisfies one or more of 0.03 mass% or more.
また本発明は、上記のシャボン玉型芳香物を気流に乗せて空中を移動させることによる香りの拡散方法を提供するものである。 The present invention also provides a method for diffusing a scent by placing the above-mentioned soap bubble type aromatic substance in the air and moving it in the air.
本発明のシャボン玉型芳香物は、シャボン玉表面からの香り立ちが高く、このシャボン玉が空中を移動することで効果的に香りを拡散させることができる。 The soap bubble type aromatic substance of the present invention has a high scent from the surface of the soap bubble, and the scent can be effectively diffused by moving the soap bubble in the air.
本発明においては、以下の式(3)で計算されるLabeled Magnitude Scale（LMS）による香料化合物の感覚強度に基づいて、香料化合物をシャボン玉表面からの香り立ちの高さの順に、以下の(A)群〜(D)群に分類する。 In the present invention, based on the sensory intensity of the fragrance compound by Labeled Magnitude Scale (LMS) calculated by the following formula (3), the fragrance compound in the order of height of fragrance from the soap bubble surface, the following ( Classify into groups A) to (D).
〔式中、ｐ、ｑ及びｒは香料化合物ごとに決定された変数、Kovatsは香料化合物のKovats Index、Doseはシャボン玉型芳香物中における香料化合物の含有量（質量％）を示す。〕 [In the formula, p, q, and r are variables determined for each fragrance compound, Kovats indicates the Kovats Index of the fragrance compound, and Dose indicates the content (% by mass) of the fragrance compound in the soap bubble-shaped aromatic substance. ]
(A)群：シャボン玉型芳香物中0.001質量％の含有量において式(3)の感覚強度が1.0以上となる香料化合物
(B)群：シャボン玉型芳香物中0.01質量％の含有量において式(3)の感覚強度が1.0以上となる(A)群以外の香料化合物
(C)群：シャボン玉型芳香物中0.03質量％の含有量において式(3)の感覚強度が1.0以上となる(A)群及び(B)群以外の香料化合物
(D)群：(A)〜(C)群以外の香料化合物
Group (A): A fragrance compound having a sensory strength of formula (3) of 1.0 or more at a content of 0.001% by mass in a soap bubble type aromatic substance.
Group (B): A perfume compound other than group (A), which has a sensory intensity of formula (3) of 1.0 or more at a content of 0.01% by mass in a soap bubble type aromatic substance.
(C) group: a perfume compound other than the (A) group and the (B) group in which the sensory strength of the formula (3) becomes 1.0 or more at a content of 0.03 mass% in a soap bubble type aromatic substance
Group (D): fragrance compounds other than groups (A) to (C)
〔Labeled Magnitude Scale（LMS）について〕
Labeled Magnitude Scale（LMS）とは、B. G. Green（Chem. Senses., 1993, 18(6), 683-702）によって言語標識と対数尺度を組み合わせて開発された感覚強度尺度である。LMSは、測定対象による感覚強度の違いを直接的に、かつ、詳細に測ることが可能であり、味覚、嗅覚、触覚等の感覚強度の定量化・比較に利用されている。LMSは、図１に示すように０＝「Barely detectable」、100＝「Strongest Imaginable」で標識(ラベル)された０〜100の評価尺度内に示す感覚強度（「Barely Detectable」、「Weak」、「Moderate」、「Strong」、「Very Strong」）が標識されている。
[About Labeled Magnitude Scale (LMS)]
The Labeled Magnitude Scale (LMS) is a sensory strength scale developed by BG Green (Chem. Senses., 1993, 18(6), 683-702) by combining a language marker and a logarithmic scale. The LMS can directly and in detail measure the difference in sensory intensity depending on the measurement target, and is used for quantifying and comparing sensory intensities such as taste, smell and touch. As shown in FIG. 1, LMS is a sensory intensity (“Barely Detectable”, “Weak”, “Weak”, 0=“Barely detectable”, 100=“Strongest Imaginable”) labeled within a rating scale of 0 to 100. "Moderate", "Strong", "Very Strong") are labeled.
LMSによる数値が意味する強度を以下に示す。
０〜1.4：ほとんど匂いがしない、1.5〜6.1：弱い匂い、6.2〜17.2：楽に感じる匂い、17.3〜35.4：強い匂い、35.5〜53.3：とても強い匂い、53.4〜100：非常に強い匂い
The strengths indicated by the LMS values are shown below.
0-1.4: Almost no odor, 1.5-6.1: Weak odor, 6.2-17.2: Comfortable odor, 17.3-35.4: Strong odor, 35.5-53.3: Very strong odor, 53.4-100: Very strong odor
ただし、体性感覚差から、1.0の検知閾値であってもヒトによってはニオイを認知できる場合があること、さらに、単成分では検知閾値の香料化合物であっても、多成分系においてはニオイ間の相互作用によってニオイ強度の向上に寄与し得るという報告（Wise, M. P.; Miyazawa, T.; Gallagher, M.; Preti, G. Human Odor Detection of Homologous Carboxylic Acids and Their Binary Mixtures, Chem. Senses 2007, 32, 475-482）もあることから、本発明においては、香料化合物を選定する際、LMSによる各香料化合物の感覚強度の下限を1.0と設定した。 However, due to the somatosensory difference, some humans may be able to perceive odor even at a detection threshold of 1.0. Furthermore, even if a fragrance compound with a detection threshold is used as a single component, it may be detected as an odor between multi-component systems. (Wise, MP; Miyazawa, T.; Gallagher, M.; Preti, G. Human Odor Detection of Homologous Carboxylic Acids and Their Binary Mixtures, Chem. Senses 2007, 32, 475-482), the lower limit of the sensory intensity of each fragrance compound by LMS was set to 1.0 in the present invention when selecting the fragrance compound.
〔Kovats Indexについて〕
Kovats Indexは、アルカンの保持時間を基準にして算出されるガスクロマトグラフィーにおける保持指標を示し、香料の揮発しやすさを示す指標でもある。本発明においてKovats Indexの値は、Kovats, E., Helv. Chim. Acta, 41, 1915(1958)に記載の方法で計算される。一般的な非極性相カラムは、例えばHP-1（Hewlett-Packard）、CP Sil 5 CB（Chrompack）、OV-1（Ohio Valley）及びRtx-1（Restek）のような各種商標で供給される100％ジメチルポリシロキサン、極性カラムとしては、DB-WAX（Agilent）のような100％ポリエチレングリコールが好ましい。
[About Kovats Index]
The Kovats Index is a retention index in gas chromatography calculated based on the retention time of alkane, and is also an index indicating the volatility of a fragrance. In the present invention, the value of Kovats Index is calculated by the method described in Kovats, E., Helv. Chim. Acta, 41, 1915 (1958). Common non-polar phase columns are supplied under various trademarks such as HP-1 (Hewlett-Packard), CP Sil 5 CB (Chrompack), OV-1 (Ohio Valley) and Rtx-1 (Restek). 100% dimethylpolysiloxane, and as the polar column, 100% polyethylene glycol such as DB-WAX (Agilent) is preferable.
〔(A)群：0.001質量％の含有量で式(3)の感覚強度が1.0以上となる香料化合物〕
(A)群に属する香料化合物としては、アセトイン、アルデヒドC-10、アルデヒドC-8、アルデヒドC-6、ヘキサン酸アリル、ヘプタン酸アリル、アリルアミルグリコレート、カロン（登録商標）、酢酸シンナミル、cis-3-ヘキセノール、酢酸cis-3-ヘキセニル、チグリン酸cis-3-ヘキセニル、d-シトロネラール、ギ酸シトロネリル、ダマセノン、α-ダイナスコン、2-メチル酪酸エチル、酪酸エチル、イソ酪酸エチル、イソ吉草酸エチル、エチルリナロール、エチルマルトール、1,8-シネオール、オイゲノール、フラネオール（登録商標）、β-ヨノン、酢酸イソアミル、ジャスモラクトン、リナロール、マルトール、マンザネート、メチル β-ナフチルケトン、γ-メチルヨノン、メチルイソオイゲノール、オクチンカルボン酸メチル、p-クレゾール、フェニルアセトアルデヒドグリセリルアセタ-ル、8-メルカプトメントン、2,3,5-トリメチルピラジン、ズルフロール（登録商標）、トリプラール等が挙げられる。
[(A) Group: Perfume compound having a sensory strength of formula (3) of 1.0 or more at a content of 0.001 mass%]
As the perfume compound belonging to the group (A), acetoin, aldehyde C-10, aldehyde C-8, aldehyde C-6, allyl hexanoate, allyl heptanoate, allyl amyl glycolate, Karon (registered trademark), cinnamyl acetate, cis-3-hexenol, cis-3-hexenyl acetate, cis-3-hexenyl tiglate, d-citronellal, citronellyl formate, damacenone, α-dynascon, ethyl 2-methylbutyrate, ethyl butyrate, ethyl isobutyrate, isovaleric acid Ethyl, ethyl linalool, ethyl maltol, 1,8-cineole, eugenol, furaneol (registered trademark), β-ionone, isoamyl acetate, jasmolactone, linalool, maltol, manzanate, methyl β-naphthyl ketone, γ-methylionone, methyl Examples thereof include isoeugenol, methyl octynecarboxylate, p-cresol, phenylacetaldehyde glyceryl acetal, 8-mercaptomenthone, 2,3,5-trimethylpyrazine, Zulflor (registered trademark), and tripral.
〔(B)群：0.01質量％の含有量で式(3)の感覚強度が1.0以上となる(A)群以外の香料化合物〕
(B)群に属する香料化合物としては、2-メチル酪酸、アセチルオイゲノール、α-ダマスコン、アルデヒドC-18、アルデヒドC-9、アンブレットリド、アネトール、ベンズアルデヒド、酢酸ベンジル、ボアサンブレンフォルテ、ボルネオール、酢酸セドリル、シトラール、シトロネロール、酢酸シトロネリル、シトロネリルニトリル、クマリン、シクラメンアルデヒド、サリチル酸シクロヘキシル、シクロテン、シクロベルタール（登録商標）、ジヒドロ β-ヨノン、ヘキサン酸エチル、フロロパール、フロローザ、フルテート（登録商標）、ヘリオナール、酢酸ヘキシル、ヘキシルシンナミックアルデヒド、サリチル酸ヘキシル、ヒドロキシシトロネラール、インドール、酪酸イソアミル、イソシクロシトラール、イソオイゲノール、イソメントン、ラクトンC-12 デルタ、リファローム、リリアール、リモネン、酢酸リナリル、l-メントール、l-メントン、ケイ皮酸メチル、ネロリドール、ヌートカトン、p-クレジルメチルエーテル、ペンタリッド（登録商標）、フェニルエチルアルコール、ポワレネート（登録商標）、ポレナール II、酢酸プレニル、ローズオキサイド、テルピネオール、テトラヒドロリナロール、trans-2-ヘキセナール、プロピオン酸トリシクロデセニル、2-イソプロピル-4-メチルチアゾール等が挙げられる。
[(B) group: perfume compounds other than the (A) group having a sensory strength of the formula (3) of 1.0 or more at a content of 0.01 mass%]
As the fragrance compound belonging to the group (B), 2-methylbutyric acid, acetyleugenol, α-damascon, aldehyde C-18, aldehyde C-9, ambretlide, anethole, benzaldehyde, benzyl acetate, boasan brenforte, borneol , Cedolyl acetate, citral, citronellol, citronellyl acetate, citronellyl nitrile, coumarin, cyclamenaldehyde, cyclohexyl salicylate, cycloten, cyclovertal (registered trademark), dihydro β-ionone, ethyl hexanoate, fluoropearl, fluorosa, frutate (registered) Trademark), helional, hexyl acetate, hexyl cinnamic aldehyde, hexyl salicylate, hydroxycitronellal, indole, isoamyl butyrate, isocyclocitral, isoeugenol, isomentone, lactone C-12 delta, rifalolom, lilial, limonene, linalyl acetate, l-menthol, l-menthone, methyl cinnamate, nerolidol, nootkatone, p-cresyl methyl ether, pentalide (registered trademark), phenylethyl alcohol, poilenate (registered trademark), pollenal II, prenyl acetate, rose oxide, Examples include terpineol, tetrahydrolinalool, trans-2-hexenal, tricyclodecenyl propionate, 2-isopropyl-4-methylthiazole and the like.
〔(C)群：0.03質量％の含有量で式(3)の感覚強度が1.0以上となる(A)群及び(B)群以外の香料化合物〕
(C)群に属する香料化合物としては、2-メチル-4-プロピル-1,3-オキサチアン、アルデヒドC-16、アンブロキサン（登録商標）、α-ピネン、β-ダマスコン、カンファー、サリチル酸cis-3-ヘキセニル、クミンアルデヒド、エストラゴール、ゲラニオール、γ-テルピネン、ヘリオトロピン、酪酸ヘキシル、酢酸イソボルニル、ラクトンC-10 デルタ、ラクトンC-11 デルタ、ラクトンC-12 ガンマ、l-カルボン、リナロールオキサイド、ジヒドロジャスモン酸メチル、安息香酸メチル、ネロール、酪酸n-プロピル、酢酸o-tert-ブチルシクロヘキシル、酢酸フェニルエチル、ロミラット（登録商標）、サンダルマイソルコア、テルピローザ（登録商標）、バニリン等が挙げられる。
[(C) Group: A perfume compound other than the (A) group and the (B) group having a content of 0.03% by mass and a sensory intensity of the formula (3) of 1.0 or more]
Examples of the fragrance compound belonging to the group (C) include 2-methyl-4-propyl-1,3-oxathiane, aldehyde C-16, ambroxane (registered trademark), α-pinene, β-damascon, camphor, and cis-salicylic acid. 3-hexenyl, cuminaldehyde, estragole, geraniol, γ-terpinene, heliotropin, hexyl butyrate, isobornyl acetate, lactone C-10 delta, lactone C-11 delta, lactone C-12 gamma, l-carvone, linalool oxide, Methyl dihydrojasmonate, methyl benzoate, nerol, n-propyl butyrate, o-tert-butylcyclohexyl acetate, phenylethyl acetate, Romirat (registered trademark), sandalmysol core, terpyrosa (registered trademark), vanillin and the like can be mentioned. ..
なお、以上例示した香料化合物以外にも、Steffen Arctander編著“Perfume and Flavor Chemicals” Montclair, N.J.(U.S.A.) (1969年)、合成香料編集委員会編集「合成香料−化学と商品知識」（化学工業日報社、2016年12月20日、増補新版）、中島基貴編著「香料と調香の基礎知識」産業図書（1995年初版）等に記載されている公知の香料化合物であって、(A)〜(C)群に該当するものを用いることができる。 In addition to the perfume compounds exemplified above, "Perfume and Flavor Chemicals" edited by Steffen Arctander, Montclair, NJ (USA) (1969), edited by the Synthetic Perfume Editing Committee, "Synthetic Perfume-Chemistry and Product Knowledge" (Chemical Industry Daily Report) Co., December 20, 2016, supplemented new edition), "Fundamental knowledge of perfumes and perfumes" edited by Motoki Nakajima, industrial book (first edition in 1995), etc. Those corresponding to the group (C) can be used.
本発明のシャボン玉型芳香物中における(A)〜(C)群から選択される１種又は２種以上の香料化合物の合計量は、シャボン玉の表面からの香り立ちに優れ、香りの拡散性を効果的に向上する観点から、0.001質量％以上であって、好ましくは0.01質量％以上、より好ましくは0.02質量％以上、更に好ましくは0.03質量％以上であり、また、香りが強くなりすぎず、適切な強度で香りを拡散する観点から、0.2質量％以下であって、好ましくは0.15質量％以下、より好ましくは0.1質量％以下、更に好ましくは0.05質量％以下である。 The total amount of one or two or more fragrance compounds selected from the groups (A) to (C) in the soap bubble type aromatic substance of the present invention is excellent in scenting from the surface of the soap bubble, and spreads the scent. From the viewpoint of effectively improving the property, it is 0.001 mass% or more, preferably 0.01 mass% or more, more preferably 0.02 mass% or more, still more preferably 0.03 mass% or more, and the scent becomes too strong. However, from the viewpoint of diffusing the scent with appropriate strength, it is 0.2% by mass or less, preferably 0.15% by mass or less, more preferably 0.1% by mass or less, still more preferably 0.05% by mass or less.
本発明のシャボン玉型芳香物は、前記(A)〜(C)群から選択される１種又は２種以上の香料化合物を、下記の条件(ｉ)〜(iii)のいずれか１以上を満たすように含有する。
条件(ｉ) ：(A)群の香料化合物の含有量が0.001質量％以上
条件(ii) ：(B)群の香料化合物の含有量が0.01質量％以上
条件(iii)：(C)群の香料化合物の含有量が0.03質量％以上
The soap bubble type aromatic compound of the present invention comprises one or more kinds of fragrance compounds selected from the groups (A) to (C) described above and any one or more of the following conditions (i) to (iii). Contains to meet.
Condition (i): the content of the fragrance compound of the (A) group is 0.001% by mass or more Condition (ii): the content of the fragrance compound of the (B) group is 0.01% by mass or more Condition (iii): of the (C) group Content of fragrance compound is 0.03 mass% or more
(A)〜(C)群の香料化合物の含有量に関し、本発明のシャボン玉型芳香物の好適な態様としては、以下の条件を満たすシャボン玉型芳香物を挙げることができる。 With respect to the content of the fragrance compound of the groups (A) to (C), as a preferred embodiment of the soap bubble type aromatic substance of the present invention, a soap bubble type aromatic substance satisfying the following conditions can be mentioned.
・前記条件(ｉ)を満たすシャボン玉型芳香物の好適な態様例
下記の条件(iv)〜(vi)を満たすシャボン玉型芳香物。
条件(iv)：(A)群の香料化合物の含有量が0.002質量％以上
条件(ｖ)：(B)群の香料化合物の含有量が０質量％以上0.1質量％以下
条件(vi)：(C)群の香料化合物の含有量が０質量％以上0.035質量％以下
-Example of a suitable embodiment of a soap bubble type aromatic substance satisfying the above condition (i) A soap bubble type aromatic substance satisfying the following conditions (iv) to (vi).
Condition (iv): The content of the fragrance compound of the (A) group is 0.002% by mass or more Condition (v): The content of the fragrance compound of the (B) group is 0% by mass or more and 0.1% by mass or less Condition (vi): ( Content of fragrance compound of group C) is 0% by mass or more and 0.035% by mass or less
・前記条件(ii)を満たすシャボン玉型芳香物の好適な態様例
下記の条件(ii)、(vi)及び(vii)を満たすシャボン玉型芳香物。
条件(ii)：(B)群の香料化合物の含有量が0.01質量％以上
条件(vi)：(C)群の香料化合物の含有量が０質量％以上0.035質量％以下
条件(vii)：(A)群の香料化合物の含有量が０質量％以上0.08質量％以下
-Preferable embodiment of soap bubble type aromatic substance satisfying the above condition (ii) A soap bubble type aromatic substance satisfying the following conditions (ii), (vi) and (vii).
Condition (ii): The content of the fragrance compound of the (B) group is 0.01% by mass or more Condition (vi): The content of the fragrance compound of the (C) group is 0% by mass or more and 0.035% by mass or less Condition (vii): ( The content of the fragrance compound of the group A) is 0 mass% or more and 0.08 mass% or less.
〔(D)群：(A)〜(C)群以外の香料化合物〕
本発明のシャボン玉型芳香物は、更に(D)群として、(A)〜(C)群のいずれにも該当しない香料化合物、すなわちシャボン玉表面からの香り立ちに対する寄与の低い香料化合物を含有することができる。(D)群の香料化合物としては、酪酸2-メチルブチル、ドデシルアルデヒド、γ-ウンデカラクトン、アンバーコア（登録商標）、アンブロテック（登録商標）、アニスアルデヒド、アフェルメート、ベンジルアルコール、プロピオン酸ベンジル、β-ピネン、カンフェン、カリオフィレン、セドロール、シンナミックアルデヒド、シスジャスモン、酢酸ジメチルベンジルカルビニル、ジヒドロオイゲノール、アセト酢酸エチル、エチルバニリン、エチレンブラシレート、ガラクソリド、酢酸ゲラニル、ハーバベール（登録商標）、インドフロール、α-ヨノン、イソ吉草酸イソアミル、酢酸イソブチル、イソダマスコン、ラクトンC-10 ガンマ、ラクトンC-5 ガンマ、メルサット（登録商標）、アニス酸メチル、メチルアンスラニレート、ムセノン（登録商標）、マイラックアルデヒド、オシメン、パンプルフルール、p-シメン、ペラナット（登録商標）、イソ酪酸2-フェノキシエチル、フェニルヘキサノール、プリカトン、ラズベリーケトン、ルボフィックス、テルピネオール-4、ツヨン、トロエナン（登録商標）、バレンセン、ベルートン（登録商標）、インドレン、ヘキサン酸、エチルジグリコール等が挙げられる。
[(D) Group: Perfume Compounds Other than (A) to (C) Groups]
The soap bubble type aromatic substance of the present invention further contains, as the (D) group, a fragrance compound which does not correspond to any of the (A) to (C) groups, that is, a fragrance compound having a low contribution to the scent formation from the soap bubble surface. can do. Examples of the fragrance compound of group (D) include 2-methylbutyl butyrate, dodecylaldehyde, γ-undecalactone, Ambercore (registered trademark), Ambrotech (registered trademark), anisaldehyde, afermate, benzyl alcohol, and benzyl propionate. β-pinene, camphene, caryophyllene, cedrol, cinnamic aldehyde, cis jasmon, dimethylbenzylcarbinyl acetate, dihydroeugenol, ethyl acetoacetate, ethyl vanillin, ethylene brushlate, galaxolide, geranyl acetate, herbabert (registered trademark), indoflor , Α-ionone, isoamyl isovalerate, isobutyl acetate, isodamascon, lactone C-10 gamma, lactone C-5 gamma, Mersat (registered trademark), methyl anisate, methyl anthranilate, musenone (registered trademark), mirac Aldehyde, ocimene, pample fleur, p-cymene, peranat (registered trademark), 2-phenoxyethyl isobutyrate, phenylhexanol, plicaton, raspberry ketone, lubofix, terpineol-4, tsuyon, troenan (registered trademark), valensen, beruton ( (Registered trademark), indole, hexanoic acid, ethyl diglycol and the like.
また、以上例示した香料化合物以外にも、Steffen Arctander編著“Perfume and Flavor Chemicals” Montclair, N.J.(U.S.A.) (1969年)、合成香料編集委員会編集「合成香料−化学と商品知識」（化学工業日報社、2016年12月20日、増補新版）、中島基貴編著「香料と調香の基礎知識」産業図書（1995年初版）等に記載されている公知の香料化合物であって、(A)〜(C)群に該当しないものを用いることができる。 In addition to the perfume compounds exemplified above, "Perfume and Flavor Chemicals" edited by Steffen Arctander, Montclair, NJ (USA) (1969), edited by the Synthetic Perfume Editing Committee, "Synthetic Perfume-Chemistry and Product Knowledge" (Chemical Industry Daily Report) Inc., December 20, 2016, supplemented new edition), "Fundamental knowledge of perfumes and perfumes", edited by Motoki Nakajima, industrial book (first edition in 1995), etc. Those which do not correspond to the group (C) can be used.
本発明のシャボン玉型芳香物中における(D)群の香料化合物の合計量は、シャボン玉の表面からの香り立ちを優れたものとし、香りの拡散性を効果的に向上する観点から、好ましくは0.095質量％以下、より好ましくは0.06質量％以下、更に好ましくは0.02質量％以下である。 The total amount of the fragrance compounds of the (D) group in the soap bubble type aromatic substance of the present invention makes the scenting from the surface of the soap bubble excellent, and from the viewpoint of effectively improving the diffusibility of the scent, it is preferable. Is 0.095 mass% or less, more preferably 0.06 mass% or less, still more preferably 0.02 mass% or less.
また、本発明のシャボン玉型芳香物が(D)群の香料化合物を含有する場合であっても、本発明のシャボン玉型芳香物中における(A)〜(D)群から選択される１種又は２種以上の香料化合物の合計量は、前記同様の観点から、好ましくは0.001質量％以上、より好ましくは0.01質量％以上、更に好ましくは0.02質量％以上、更に好ましくは0.03質量％以上であり、また、好ましくは0.2質量％以下、より好ましくは0.15質量％以下、更に好ましくは0.12質量％以下、更に好ましくは0.1質量％以下である。 Further, even when the soap bubble type aromatic substance of the present invention contains a fragrance compound of the (D) group, it is selected from the groups (A) to (D) in the soap bubble type aromatic substance of the present invention. From the same viewpoint as above, the total amount of one or two or more flavor compounds is preferably 0.001% by mass or more, more preferably 0.01% by mass or more, still more preferably 0.02% by mass or more, still more preferably 0.03% by mass or more. It is preferably 0.2% by mass or less, more preferably 0.15% by mass or less, still more preferably 0.12% by mass or less, and further preferably 0.1% by mass or less.
〔溶媒（希釈剤）〕
本発明のシャボン玉型芳香物には、前記(A)〜(D)群の香料化合物を含有する香料組成物のための溶媒（希釈剤）を含有してもよい。溶媒としては、シャボン玉表面からの香り立ち向上の観点から、3-メトキシ-3-メチルブタノール、ジエチレングリコールモノエチルエーテル、フタル酸ジエチル、ジプロピレングリコール、ジプロピレングリコールモノエチルエーテル、ミリスチン酸イソプロピル、ミリスチン酸ベンジル、プロピレングリコール、エチレングリコール、アジピン酸ジイソブチル、エタノール、水添アビエチン酸メチル、クエン酸トリエチル、安息香酸ベンジル、ベンジルアルコール、フェノキシエタノール、グリセリン等が挙げられ、なかでもジプロピレングリコール、プロピレングリコール、エチレングリコール、安息香酸ベンジル、及びミリスチン酸イソプロピルから選択される１種又は２種以上が好ましい。
[Solvent (diluent)]
The soap bubble type aromatic substance of the present invention may contain a solvent (diluent) for the perfume composition containing the perfume compound of the above groups (A) to (D). As a solvent, 3-methoxy-3-methylbutanol, diethylene glycol monoethyl ether, diethyl phthalate, dipropylene glycol, dipropylene glycol monoethyl ether, isopropyl myristate, myristin, from the viewpoint of improving the aroma from the soap bubble surface. Benzyl acid, propylene glycol, ethylene glycol, diisobutyl adipate, ethanol, hydrogenated methyl abietic acid, triethyl citrate, benzyl benzoate, benzyl alcohol, phenoxyethanol, glycerin and the like, among which dipropylene glycol, propylene glycol, ethylene One or more selected from glycol, benzyl benzoate, and isopropyl myristate are preferable.
〔シャボン玉液用配合成分〕
本発明のシャボン玉型芳香物には、前記香料化合物及び溶媒のほか、通常シャボン玉液に用いられる各種成分を含有させることができる。このようなシャボン玉液用成分としては特に限定されず、シャボン玉液に一般的に配合されるものであれば適宜用いることができ、例えば、水、界面活性剤、多価アルコール、水溶性高分子、糖類、着色剤等が挙げられる。なお、本発明のシャボン玉型芳香物は、前記香料化合物及び溶媒をシャボン玉液に直接配合させた態様のみならず、香りを含む気体をシャボン膜に向けて噴出して香りが封入されたシャボン玉を生成させる態様であってもよい。
[Ingredients for soap bubble liquid]
The soap bubble type aromatic substance of the present invention may contain various components commonly used in soap bubble liquids in addition to the above-mentioned fragrance compound and solvent. There is no particular limitation on the component for such a soap bubble liquid, and any component that is commonly blended with a soap bubble liquid can be appropriately used, and examples thereof include water, a surfactant, a polyhydric alcohol, and a high water solubility. Examples include molecules, sugars, colorants and the like. The soap bubble type aromatic substance of the present invention is not only a mode in which the flavor compound and the solvent are directly blended in the soap bubble liquid, but also a bubble in which a scent-containing gas is ejected toward the soap bubble to encapsulate the scent. A mode in which balls are generated may be used.
界面活性剤としては、非イオン界面活性剤、両性界面活性剤、アニオン界面活性剤、カチオン界面活性剤のいずれを使用することもできるが、非イオン界面活性剤、両性界面活性剤、アニオン界面活性剤が、シャボン玉表面からの香り立ち向上の観点から好ましい。 As the surfactant, any of nonionic surfactant, amphoteric surfactant, anionic surfactant and cationic surfactant can be used, but nonionic surfactant, amphoteric surfactant, anionic surfactant The agent is preferable from the viewpoint of improving the scent formation from the surface of the soap bubble.
非イオン界面活性剤としては、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレンアルケニルエーテル、高級脂肪酸ショ糖エステル、ポリグリセリン脂肪酸エステル、高級脂肪酸モノ又はジエタノールアミド、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンソルビット脂肪酸エステル、アルキルサッカライド、アルキルグリセリルエーテル等が挙げられる。 As the nonionic surfactant, polyoxyalkylene alkyl ether, polyoxyalkylene alkenyl ether, higher fatty acid sucrose ester, polyglycerin fatty acid ester, higher fatty acid mono- or diethanolamide, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan fatty acid Examples thereof include esters, polyoxyethylene sorbite fatty acid esters, alkyl saccharides, alkyl glyceryl ethers and the like.
両性界面活性剤としてはイミダゾリン、カルボベタイン、アミドベタイン、スルホベタイン、ヒドロキシスルホベタイン、アミドスルホベタイン、アルキルアミンオキサイド、アルキルアミドアミンオキサイド等が挙げられる。 Examples of the amphoteric surfactant include imidazoline, carbobetaine, amidobetaine, sulfobetaine, hydroxysulfobetaine, amidosulfobetaine, alkylamine oxide and alkylamidoamine oxide.
なかでも、シャボン玉表面からの香り立ち向上の観点から、両性界面活性剤としてはスルホベタイン型界面活性剤が好ましく、アルキル基の炭素数が10〜18のN-アルキル-N,N-ジメチル-N-スルホプロピルアンモニウムスルホベタイン、N-アルキル-N,N-ジメチル-N-(2-ヒドロキシスルホプロピル)アンモニウムスルホベタイン；アルカノイル基の炭素数が10〜18のN-アルカノイルアミノプロピル-N,N-ジメチル-N-スルホプロピルアンモニウムスルホベタイン、N-アルカノイルアミノプロピル-N,N-ジメチル-N-(2-ヒドロキシスルホプロピル)アンモニウムスルホベタイン、N-アルキル-N,N-ジメチルアミンオキシドから選ばれる１種以上がより好ましい。 Among them, from the viewpoint of improving the fragrance from the soap bubble surface, sulfobetaine type surfactants are preferable as the amphoteric surfactant, and the carbon number of the alkyl group is 10 to 18 N-alkyl-N,N-dimethyl- N-sulfopropylammonium sulfobetaine, N-alkyl-N,N-dimethyl-N-(2-hydroxysulfopropyl)ammonium sulfobetaine; N-alkanoylaminopropyl-N,N having 10 to 18 carbon atoms in the alkanoyl group -Dimethyl-N-sulfopropylammonium sulfobetaine, N-alkanoylaminopropyl-N,N-dimethyl-N-(2-hydroxysulfopropyl)ammonium sulfobetaine, N-alkyl-N,N-dimethylamine oxide One or more is more preferable.
アニオン界面活性剤としては、アルキルベンゼンスルホン酸塩、アルキル又はアルケニルエーテル硫酸塩、アルキル又はアルケニル硫酸塩、オレフィンスルホン酸塩、アルカンスルホン酸塩、飽和又は不飽和脂肪酸塩、アルキル又はアルケニルエーテルカルボン酸塩、α-スルホ脂肪酸塩、N-アシルアミノ酸、リン酸モノ又はジエステル、スルホコハク酸エステル等が挙げられる。アルキルエーテル硫酸塩としては、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシプロピレンアルキルエーテル硫酸塩、ポリオキシ（エチレン/プロピレン）アルキルエーテル硫酸塩が挙げられる。 As the anionic surfactant, alkylbenzene sulfonate, alkyl or alkenyl ether sulfate, alkyl or alkenyl sulfate, olefin sulfonate, alkane sulfonate, saturated or unsaturated fatty acid salt, alkyl or alkenyl ether carboxylate, Examples thereof include α-sulfo fatty acid salt, N-acyl amino acid, phosphoric acid mono- or diester, and sulfosuccinic acid ester. Examples of the alkyl ether sulfate include polyoxyethylene alkyl ether sulfate, polyoxypropylene alkyl ether sulfate, and polyoxy(ethylene/propylene) alkyl ether sulfate.
なかでも、シャボン玉表面からの香り立ち向上の観点から、アニオン界面活性剤としては、下記一般式(I)又は(II)で表される化合物から選ばれる１種以上が好ましい。
Ｒ1−Ｏ−(ＰＯ)n−ＳＯ3Ｍ1 (I)
〔式中、Ｒ1は炭素数８〜18のアルキル基を示し、ＰＯはプロピレンオキシ基を示し、ｎは０〜６の数であってＰＯの平均付加モル数を示し、Ｍ1は陽イオンを示す。〕
Ｒ2−Ｏ−(ＰＯ)m−(ＥＯ)l−ＳＯ3Ｍ2 (II)
〔式中、Ｒ2は炭素数８〜18のアルキル基を示し、ＰＯはプロピレンオキシ基を示し、ＥＯはエチレンオキシ基を示し、ｍは０超１未満の数であってＰＯの平均付加モル数を示し、ｌは０超３以下の数であってＥＯの平均付加モル数を示し、Ｍ2は陽イオンを示す。〕
Among them, from the viewpoint of improving the scent formation from the surface of soap bubbles, the anionic surfactant is preferably one or more selected from the compounds represented by the following general formula (I) or (II).
R 1 -O- (PO) n -SO 3 M 1 (I)
[In the formula, R 1 represents an alkyl group having 8 to 18 carbon atoms, PO represents a propyleneoxy group, n is a number from 0 to 6 and represents the average number of moles of PO added, and M 1 is a cation. Indicates. ]
R 2 -O- (PO) m - (EO) l -SO 3 M 2 (II)
[In the formula, R 2 represents an alkyl group having 8 to 18 carbon atoms, PO represents a propyleneoxy group, EO represents an ethyleneoxy group, m is a number greater than 0 and less than 1, and the average addition mole of PO is Is a number greater than 0 and 3 or less, indicating the average number of moles of EO added, and M 2 is a cation. ]
これら界面活性剤は、単独で又は２種以上を組み合わせて使用することができ、なかでも、アニオン界面活性剤と両性界面活性剤とを併用することが、シャボン玉表面からの香り立ち向上の観点から好ましい。本発明のシャボン玉型芳香物中における界面活性剤の総含有量は、持続性の良好なシャボン玉を形成する観点から、好ましくは0.024質量％以上、より好ましくは0.24質量％以上、更に好ましくは0.5質量％以上であり、また、好ましくは３質量％以下、より好ましくは２質量％以下、更に好ましくは１質量％以下である。 These surfactants can be used alone or in combination of two or more, and in particular, it is preferable to use an anionic surfactant and an amphoteric surfactant in combination, from the viewpoint of improving the fragrance from the soap bubble surface. Is preferred. The total content of the surfactant in the soap bubble type aromatic compound of the present invention is preferably 0.024% by mass or more, more preferably 0.24% by mass or more, and further preferably from the viewpoint of forming a soap bubble having good sustainability. It is 0.5% by mass or more, preferably 3% by mass or less, more preferably 2% by mass or less, still more preferably 1% by mass or less.
シャボン玉表面からの香り立ち向上の観点から、シャボン玉芳香物中におけるアニオン界面活性剤の含有量は、好ましくは0.01質量％以上、より好ましくは0.05質量％以上、、更に好ましくは0.1質量％以上であり、また、好ましくは0.6質量％以下、より好ましくは0.4質量％以下である。 From the viewpoint of improving the fragrance from the soap bubble surface, the content of the anionic surfactant in the soap aromatic substance is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and further preferably 0.1% by mass or more. And preferably 0.6% by mass or less, more preferably 0.4% by mass or less.
シャボン玉表面からの香り立ち向上の観点から、シャボン玉型芳香物中における両性界面活性剤の含有量は、好ましくは0.005質量％以上、より好ましくは0.0075質量％以上、更に好ましくは0.01質量％以上であり、また、好ましくは0.15質量％以下、より好ましくは0.14質量％以下、更に好ましくは0.13質量％以下である。 From the viewpoint of improving the fragrance from the soap bubble surface, the content of the amphoteric surfactant in the soap bubble type aromatic is preferably 0.005 mass% or more, more preferably 0.0075 mass% or more, and further preferably 0.01 mass% or more. It is preferably 0.15% by mass or less, more preferably 0.14% by mass or less, still more preferably 0.13% by mass or less.
また、シャボン玉表面からの香り立ち向上の観点から、シャボン玉型芳香物中におけるアニオン界面活性剤及び両性界面活性剤の合計含有量に対する、アニオン界面活性剤の含有量の割合、すなわちアニオン界面活性剤の含有量／〔アニオン界面活性剤の含有量＋両性界面活性剤の含有量〕は、好ましくは0.5以上、より好ましくは0.6以上、更に好ましくは0.7以上であり、また、好ましくは１以下、より好ましくは0.9以下、更に好ましくは0.85以下である。 Further, from the viewpoint of improving the fragrance from the soap bubble surface, the ratio of the content of the anionic surfactant to the total content of the anionic surfactant and the amphoteric surfactant in the soap bubble type aroma, that is, the anionic surfactant The content of the agent/[content of the anionic surfactant+content of the amphoteric surfactant] is preferably 0.5 or more, more preferably 0.6 or more, still more preferably 0.7 or more, and preferably 1 or less, It is more preferably 0.9 or less, still more preferably 0.85 or less.
多価アルコールとしては、エチレングリコール、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、イソプレングリコール、1,3-ブチレングリコール、ポリビニルアルコール等のグリコール類；グリセリン、ジグリセリン、ポリグリセリン；ソルビトール、マルチトール等の糖類が挙げられる。 As the polyhydric alcohol, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, 1,3-butylene glycol, glycols such as polyvinyl alcohol; glycerin, diglycerin, Polyglycerin; saccharides such as sorbitol and maltitol.
これら多価アルコールは、単独で又は２種以上を組み合わせて使用することができる。本発明のシャボン玉型芳香物中における多価アルコールの含有量は、持続性の良好なシャボン玉を形成する観点から、好ましくは0.1質量％以上、より好ましくは１質量％以上、更に好ましくは５質量％以上であり、また、好ましくは45質量％以下、より好ましくは40質量％以下、更に好ましくは35質量％以下である。 These polyhydric alcohols can be used alone or in combination of two or more. The content of the polyhydric alcohol in the soap bubble type aromatic substance of the present invention is preferably 0.1% by mass or more, more preferably 1% by mass or more, and further preferably 5 from the viewpoint of forming a soap bubble having good durability. It is at least mass%, preferably at most 45 mass%, more preferably at most 40 mass%, further preferably at most 35 mass%.
〔香りの拡散方法〕
本発明のシャボン玉型芳香物は、シャボン玉表面からの香り立ちに優れるため、これを気流に乗せて空中を移動させることによって香りを拡散させることができる。
[Method of spreading scent]
Since the soap bubble type aromatic substance of the present invention is excellent in the scent rising from the surface of the soap bubble, the scent can be diffused by placing it in the air stream and moving it in the air.
〔内包させる気体〕
本発明のシャボン玉型芳香物に内包させる気体としては、シャボン玉を形成後、できるだけ長時間空中を浮遊させて周囲に香りを拡散する観点から、空気より軽い気体が好ましい。空気より軽い気体としては、ヘリウム、窒素等、又はこれらの気体と空気との混合気体が挙げられる。
[Gas to be included]
As the gas to be included in the soap bubble type aromatic substance of the present invention, a gas lighter than air is preferable from the viewpoint of floating the air in the air as long as possible after forming the soap bubble and diffusing the scent to the surroundings. Examples of the gas lighter than air include helium, nitrogen, and the like, or a mixed gas of these gases and air.
また、前記空気より軽い気体と共に白色気体を内包させることによって、形成したシャボン玉を白くすることができる。白色気体としては、プロピレングリコール、グリセリン等の親水性有機溶媒と水の混合物を加熱して水と共に蒸発させることで生ずる白い煙様気体、ドライアイスに水を接触させることで生ずる白い煙様気体が挙げられる。 In addition, by including a white gas together with a gas lighter than the air, the formed soap bubble can be whitened. As the white gas, white smoke-like gas produced by heating a mixture of water with a hydrophilic organic solvent such as propylene glycol or glycerin and evaporating with water, and white smoke-like gas produced by contacting dry ice with water. Can be mentioned.
前記のようにして形成させた白いシャボン玉型芳香物を気流に乗せて空中を移動させ、そのシャボン玉表面から拡散する香りのイメージに即した色の光又は映像を投射することによって、香りの拡散を可視化することができる。 By moving the white soap bubble type aromatic substance formed as described above in the air by moving it in the air, and projecting light or an image of a color according to the image of the scent diffused from the soap bubble surface, The diffusion can be visualized.
試験例１（香料放出量の予測式の導出）
香料組成物１（表１）又は香料組成物２（表２）を0.01質量％、0.05質量％又は0.10質量％含むシャボン玉芳香物（表３）をそれぞれ準備した。
シャボン玉は、先端にテフロン（登録商標）チューブを用いてシャボン玉ストロー（いち屋社製）を接続した100mL白硬注射筒（翼工業社製）を使用し、空気60mLを封入して作製した。作製したシャボン玉は500mLビーカーで捕集し、アルミホイルで蓋をした。
Tenax-TA（GLサイエンス社製）とダイヤフラムポンプ（GLサイエンス社製、SP 208 Dual）を用いてビーカーに揮散した香料を捕集した。シャボン玉から放出された香料について、GC/MSでビーカー内のヘッドスペースを定量分析した。
Test example 1 (derivation of a prediction formula for the amount of released fragrance)
A soap bubble aroma (Table 3) containing 0.01% by mass, 0.05% by mass or 0.10% by mass of the fragrance composition 1 (Table 1) or the fragrance composition 2 (Table 2) was prepared.
Soap bubbles were produced by using a 100 mL white hard syringe (made by Tsubasa Kogyo Co., Ltd.) with a soap bubble straw (made by Ichiya Co., Ltd.) connected to the tip using a Teflon (registered trademark) tube, and enclosing 60 mL of air. .. The produced soap bubbles were collected with a 500 mL beaker and covered with aluminum foil.
Using a Tenax-TA (GL Science Co., Ltd.) and a diaphragm pump (GL Science Co., SP 208 Dual), the fragrances collected in the beaker were collected. The headspace in the beaker was quantitatively analyzed by GC/MS for the fragrance released from the soap bubble.
ガスクロマトグラフィー分析条件
吸着管：Tenax TA（GLサイエンス社製）
GC：6890N（アジレントテクノロジー社製）
カラム：DB-WAX 60.0m × 250μm × 0.25μm
キャリアガス：ヘリウム（116.5kPa、1.1mL/min）
カラム温度：40℃で３分保持後、70℃まで６℃/分、240℃まで４℃/分で昇温し、20分保持
MS：5975B（アジレントテクノロジー社製）
Gas chromatography analysis conditions Adsorption tube: Tenax TA (GL Science)
GC: 6890N (manufactured by Agilent Technologies)
Column: DB-WAX 60.0m × 250 μm × 0.25 μm
Carrier gas: Helium (116.5kPa, 1.1mL/min)
Column temperature: After holding at 40°C for 3 minutes, raise the temperature to 70°C at 6°C/minute and to 240°C at 4°C/minute and hold for 20 minutes
MS: 5975B (manufactured by Agilent Technologies)
この定量分析の結果から、シャボン玉芳香物に配合された香料化合物の含有量と放出量（気相濃度；μg/L air）の関係は、次式(1)で表されることが分かった。 From the result of this quantitative analysis, it was found that the relationship between the content and the release amount (gas phase concentration; μg/L air) of the fragrance compound blended in the soap bubble aromatic substance is expressed by the following formula (1). .
〔式中、Kovatsは香料化合物のKovats Index、Doseはシャボン玉型芳香物中の香料化合物の含有量を示す。〕 [In the formula, Kovats represents the Kovats Index of the fragrance compound, and Dose represents the content of the fragrance compound in the soap bubble-shaped aromatic substance. ]
試験例２（気相濃度に対応した各香料化合物の強度曲線の導出）
３Ｌポリエチレン製におい袋（アズワン社から購入）にそれぞれの香料化合物0.5mLを導入し、無臭の空気を導入した。一晩静置したにおい袋からヘッドスペースを回収し、別のフッ素樹脂バッグを用いて様々な濃度のにおい袋を準備した。
Tenax-TAとサンプリングポンプを用いてフッ素樹脂バッグ内に揮散した香料を捕集し、GC/MSでバッグ内のヘッドスペースを定量分析した。
濃度既知のフッ素樹脂バッグをにおい識別用希釈混合装置（島津社製）に接続し、装置から出される濃度ごとのニオイ強度を専門パネル14名がLMSを用いて評価した。
評価結果から、次式(2)で表される、香料化合物の気相濃度に対応する感覚強度が得られた。
Test Example 2 (derivation of strength curve of each fragrance compound corresponding to gas phase concentration)
0.5 mL of each fragrance compound was introduced into a 3 L polyethylene scent bag (purchased from AS ONE), and odorless air was introduced. The headspace was collected from the odor bag left to stand overnight, and odor bags having various concentrations were prepared using another fluororesin bag.
The fragrance volatilized in the fluororesin bag was collected using Tenax-TA and a sampling pump, and the headspace in the bag was quantitatively analyzed by GC/MS.
A fluororesin bag having a known concentration was connected to an odor identifying dilution mixing device (manufactured by Shimadzu Corporation), and the odor intensity for each concentration emitted from the device was evaluated by 14 specialized panels using LMS.
From the evaluation results, the sensory strength represented by the following formula (2) corresponding to the gas phase concentration of the fragrance compound was obtained.
〔式中、ｐ、ｑ及びｒは香料化合物ごとに決定された変数を示す。〕 [In formula, p, q, and r show the variable determined for every perfume compound. ]
なお、係数ｐ、ｑ及びｒは、それぞれの香料化合物ごとに得られた気相濃度を式(2)に代入して算出された感覚強度の値が専門パネル14名の官能評価の平均値に近似するように、予測値と実測値間の残差の二乗和を最小とする（最小二乗法）ことで決定した。
決定には、表計算ソフトプログラムであるMicrosoft社のExcel 2010(ver14.0)のアドインプログラムであるソルバーを用いた。
In addition, as for the coefficients p, q and r, the value of the sensory intensity calculated by substituting the gas phase concentration obtained for each fragrance compound into the formula (2) is the average value of the sensory evaluation of 14 professional panels. As approximated, it was determined by minimizing the sum of squares of the residuals between the predicted value and the measured value (least square method).
For the determination, a solver which is an add-in program of Excel 2010 (ver14.0) of Microsoft Corporation which is a spreadsheet software program was used.
式(2)に式(1)を代入した式(3)により、シャボン玉芳香組成物に対する香料化合物の配合量から、香料化合物のニオイ強度が算出される。本式を用いて、シャボン玉からの香り立ちへの寄与の程度によって香料化合物を(A)群〜(D)群に分類する。 The odor intensity of the fragrance compound is calculated from the blending amount of the fragrance compound with respect to the soap bubble aroma composition according to the formula (3) in which the formula (1) is substituted into the formula (2). Using this formula, the fragrance compounds are classified into groups (A) to (D) according to the degree of contribution of soap bubbles to the scenting.
〔式中、ｐ、ｑ及びｒは香料化合物ごとに決定された変数、Kovatsは香料化合物のKovats Index、Doseはシャボン玉型芳香物中における香料化合物の含有量（質量％）を示す。〕 [In the formula, p, q, and r are variables determined for each fragrance compound, Kovats indicates the Kovats Index of the fragrance compound, and Dose indicates the content (% by mass) of the fragrance compound in the soap bubble-shaped aromatic substance. ]
表４〜７に、式(3)から計算されたLMSによる各香料化合物の感覚強度を各群別に示す。 Tables 4 to 7 show the sensory strength of each fragrance compound by LMS calculated from the formula (3) for each group.
実施例１〜19、比較例１
表９〜28に示すシャボン玉型芳香物用香料組成物を0.10質量％含むシャボン玉芳香組成物を準備した。シャボン玉芳香物の処方は表８に示すとおりである。シャボン玉型芳香物は、先端にテフロンチューブを用いてシャボン玉ストロー（いち屋社製）を接続した100mL白硬注射筒（翼工業社製）を使用し、空気60mLを封入して作製した。
Examples 1 to 19 and Comparative Example 1
A soap bubble aroma composition containing 0.10% by mass of the flavor composition for soap bubble type aromatics shown in Tables 9 to 28 was prepared. The formula of the soap bubble fragrance is as shown in Table 8. The soap bubble type fragrance was produced by using a 100 mL white hard injection cylinder (manufactured by Tsubasa Kogyo Co., Ltd.) to which a soap bubble straw (manufactured by Ichiya Co., Ltd.) was connected using a Teflon tube at the tip and enclosing 60 mL of air.
これらのシャボン玉型芳香物について、0.3〜1.0ｍの距離から、その香り立ちについて以下の基準に従い、下記の６段階評価尺度にて評価した。評価は0.5刻みとした。
０：無臭
１：やっと感知できるにおい
２：何のにおいであるかわかる弱いにおい
３：楽に感知できるにおい
４：強いにおい
５：強烈なにおい
These soap bubble type aroma substances were evaluated from the distance of 0.3 to 1.0 m according to the following criteria for the scent appearance according to the following criteria. The evaluation was in 0.5 increments.
0: Odorless 1: Smell that can be perceived finally 2: Weak odor that can tell what the odor is 3: Odor that can be easily perceived 4: Strong odor 5: Intense odor
Claims (8)
(A)群：シャボン玉型芳香物中0.001質量％の含有量において式(3)の感覚強度が1.0以上となる香料化合物
(B)群：シャボン玉型芳香物中0.01質量％の含有量において式(3)の感覚強度が1.0以上となる(A)群以外の香料化合物
(C)群：シャボン玉型芳香物中0.03質量％の含有量において式(3)の感覚強度が1.0以上となる(A)群及び(B)群以外の香料化合物
から選択される１種又は２種以上の香料化合物を合計量で0.001質量％以上0.2質量％以下含有し、かつ、下記の条件(ｉ)〜(iii)；
条件(ｉ) ：(A)群の香料化合物の含有量が0.001質量％以上
条件(ii) ：(B)群の香料化合物の含有量が0.01質量％以上
条件(iii)：(C)群の香料化合物の含有量が0.03質量％以上
のうち１以上を満たすシャボン玉型芳香物。 The following (A) to (C) groups classified based on the sensory intensity of the perfume compound according to the Labeled Magnitude Scale calculated by the formula (3);
Group (A): A fragrance compound having a sensory strength of formula (3) of 1.0 or more at a content of 0.001% by mass in a soap bubble type aromatic substance.
Group (B): A perfume compound other than group (A), which has a sensory intensity of formula (3) of 1.0 or more at a content of 0.01% by mass in a soap bubble type aromatic substance.
Group (C): One selected from a fragrance compound other than the groups (A) and (B) in which the sensory strength of the formula (3) is 1.0 or more at a content of 0.03% by mass in a soap bubble type aromatic substance, or It contains 0.001% by mass or more and 0.2% by mass or less of a total amount of two or more flavor compounds, and the following conditions (i) to (iii);
Condition (i): the content of the fragrance compound of the (A) group is 0.001% by mass or more Condition (ii): the content of the fragrance compound of the (B) group is 0.01% by mass or more Condition (iii): of the (C) group A soap bubble type aromatic substance in which the content of the fragrance compound satisfies one or more of 0.03 mass% or more.
(D)群：(A)〜(C)群以外の香料化合物 The content of the fragrance compound of the following (D) group is 0.095 mass% or less, and the total amount of the fragrance compounds of (A) to (D) groups is 0.001 mass% or more and 0.2 mass% or less. Soap bubbles for fragrance.
Group (D): fragrance compounds other than groups (A) to (C)
条件(iv)：(A)群の香料化合物の含有量が0.002質量％以上
条件(ｖ)：(B)群の香料化合物の含有量が０質量％以上0.1質量％以下
条件(vi)：(C)群の香料化合物の含有量が０質量％以上0.035質量％以下 The soap bubble type aromatic substance according to claim 1 or 2, which satisfies the following conditions (iv) to (vi).
Condition (iv): the content of the fragrance compound of the (A) group is 0.002% by mass or more Condition (v): the content of the fragrance compound of the (B) group is 0% by mass or more and 0.1% by mass or less Condition (vi): ( Content of fragrance compound of group C) is 0% by mass or more and 0.035% by mass or less
条件(ii)：(B)群の香料化合物の含有量が0.01質量％以上
条件(vi)：(C)群の香料化合物の含有量が０質量％以上0.035質量％以下
条件(vii)：(A)群の香料化合物の含有量が０質量％以上0.08質量％以下 The soap bubble type aromatic substance according to claim 1, which satisfies the following conditions (ii), (vi) and (vii).
Condition (ii): The content of the fragrance compound of the (B) group is 0.01% by mass or more Condition (vi): The content of the fragrance compound of the (C) group is 0% by mass or more and 0.035% by mass or less Condition (vii): ( The content of the fragrance compound of the group A) is 0% by mass or more and 0.08% by mass or less.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5839300U (en) * | 1981-09-04 | 1983-03-15 | 杉山 弘之 | soap bubble generator |
| JP2002256300A (en) * | 2001-03-02 | 2002-09-11 | Lion Corp | Liquid detergent composition |
| JP2007314693A (en) * | 2006-05-26 | 2007-12-06 | Kao Corp | Liquid detergent composition |
| US20120035311A1 (en) * | 2010-08-05 | 2012-02-09 | Crayola, Llc | Colored bubbles |
| JP2012197359A (en) * | 2011-03-22 | 2012-10-18 | Daizo:Kk | Aerosol composition |
| JP2016205819A (en) * | 2015-04-15 | 2016-12-08 | 小川香料株式会社 | Method of predicting, or evaluating, durability of preference |
-
2018
- 2018-11-14 JP JP2018213734A patent/JP6891156B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5839300U (en) * | 1981-09-04 | 1983-03-15 | 杉山 弘之 | soap bubble generator |
| JP2002256300A (en) * | 2001-03-02 | 2002-09-11 | Lion Corp | Liquid detergent composition |
| JP2007314693A (en) * | 2006-05-26 | 2007-12-06 | Kao Corp | Liquid detergent composition |
| US20120035311A1 (en) * | 2010-08-05 | 2012-02-09 | Crayola, Llc | Colored bubbles |
| JP2012197359A (en) * | 2011-03-22 | 2012-10-18 | Daizo:Kk | Aerosol composition |
| JP2016205819A (en) * | 2015-04-15 | 2016-12-08 | 小川香料株式会社 | Method of predicting, or evaluating, durability of preference |
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