JP2020040994A - Cosmetic composition - Google Patents

Abstract

To provide a cosmetic composition having excellent dispersibility of a powder even in the presence of an ultraviolet absorber, good sense of use and spreadability and excellent preparation storage stability.SOLUTION: There is provided a cosmetic composition which comprises (a) 0.1 to 12 mass% of laurylpolyglyceryl-3 polydimethylsiloxyethyl dimethicone, (b) 0.1 to 45 mass% of a powder, (c) 6.5 to 20 mass% of an ultraviolet absorber, (d) 0.1 to 60 mass% of one or two or more oil agents having a viscosity at 25°C of 1 to 100 mm/s selected from a silicone oil and an ester oil, wherein the cosmetic composition comprises a dispersion in which the powder (b) is dispersed in an oil phase containing (I) the component (a) and the component (d) or (II) the component (a), the component (c) and the component (d) in advance.SELECTED DRAWING: None

Description

  The present invention relates to a cosmetic composition. In the present invention, a composition for cosmetics (cosmetic composition) may be simply referred to as a cosmetic.

  2. Description of the Related Art In cosmetics, when a powder is contained, a technique is known that uses a silicone activator or the like to improve wettability or dispersibility of the powder, thereby improving makeup durability and storage stability (Patent Documents) 1: JP-A-2014-043422). However, the dispersion performance of the polyether-modified silicone surfactant is sometimes insufficient.

  On the other hand, in sunscreen cosmetics, metal oxide powders such as titanium oxide and zinc oxide are so-called fine particle metal oxides having an average primary particle diameter of 100 nm or less in order to improve transparency and enhance an ultraviolet shielding effect. Object powder is widely used. However, the finely divided metal oxide powder has an increased surface area, thereby increasing the bonding force between the particles, and as a result, tends to aggregate. Therefore, when these fine metal oxide powders are used in sunscreen cosmetics, it is important that they can be stably contained without aggregation. In general, in cosmetics, techniques for improving formulation stability by blending a polyglycerin-modified silicone-based surfactant (Patent Document 2: JP-A-2013-035872), and a polyglycerin-modified silicone-based surfactant A technique for improving the stability of a preparation by using trimethylsiloxysilicic acid in combination is known (Patent Document 3: JP 2007-182402 A). However, the polyglycerin-modified silicone used here did not sufficiently improve formulation stability in the presence of an ultraviolet absorber.

JP-A-2014-043422 JP 2013-035872A JP 2007-182402 A

  The present invention has been made in view of the above circumstances, and provides a cosmetic composition having excellent powder dispersibility, good usability and spreadability even in the presence of an ultraviolet absorber, and excellent preparation storage stability. The purpose is to do.

The present inventors have conducted intensive studies to achieve the above object, and as a result, (a) silicone alkyl-branched polyglycerol-modified silicone, (b) powder, (c) ultraviolet absorber, (d) components other than (c) It has been found that the above problem can be solved by blending an oil agent having a viscosity of 1 to 100 mm ² / s at 25 ° C., and the present invention has been accomplished.

Accordingly, the present invention provides:
[1]. (A) Silicone / alkyl branched polyglycerol-modified silicone: 0.1 to 12% by mass, (b) Powder: 0.1 to 45% by mass, (c) UV absorber: 0.1 to A cosmetic composition containing 20% by mass, an oil agent having a viscosity of 1 to 100 mm ² / s at 25 ° C. other than the components (d) and (c): 0.1 to 60% by mass.
[2] The cosmetic composition according to [1], wherein the component (a) is lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone.
[3] The cosmetic composition according to [1] or [2], wherein the component (b) is a color pigment having an average primary particle diameter of 1.0 μm or less.
[4] The cosmetic composition according to [1] or [2], wherein the component (b) is an ultraviolet light scattering agent having an average primary particle diameter of 200 nm or less.
[5]. The powder (b) is previously contained in the oil phase containing the components (I) (a) and (d) or (II) (a), (c) and (d). The cosmetic composition according to any one of [1] to [4], comprising a dispersed material.
[6] The cosmetic composition according to any one of [1] to [5], which is an emulsion composition.
[7] The cosmetic composition according to any one of [1] to [5], which is a non-aqueous composition.

  The cosmetic composition of the present invention has excellent powder dispersibility even in the presence of an ultraviolet absorber, and is excellent in usability, spreadability, and preparation storage stability.

  Hereinafter, the present invention will be described in detail, but the present invention is not limited thereto.

（式中、Ｒ⁴は前記式（２）と同様の意味を示し、Ｑはエーテル結合及びエステル結合を含有してもよい炭素数２〜２０の二価炭化水素基を示す。ｓは２〜１０の整数、ｔは１〜１０の整数である。）
Ｒ³は下記一般式（５）で示されるケイ素含有基である。

（式中、Ｒ¹は上記式（１）と同様であり、ｇは１〜５の整数である。ｈは０〜５００である。）］ <(A) component>
<Silicone / alkyl branched polyglycerin-modified silicone>
The silicone / alkyl branched polyglycerin-modified silicone compound used in the present invention is a silicone / alkyl chain co-modified polyglycerin-modified silicone surfactant.
Among them, a silicone / alkyl branched polyglycerin-modified silicone represented by the following general formula (1) is preferable.
R ¹ _a R ² _b R ³ _c SiO _{(4-abc) / 2} (1)
Wherein a is 1.0 to 2.5, b is 0.001 to 1.5, and c is 0.001 to 1.5.
R ¹ is an unsubstituted or substituted monovalent hydrocarbon group such as an alkyl group having 1 to 30 carbon atoms, an aryl group, an aralkyl group, a fluorine-substituted alkyl group, an amino-substituted alkyl group, a carboxyl-substituted alkyl group, and the following general formula (2)
_{-C d H 2d -O- (C 2} H 4 O) e (C 3 H 6 O) f R 4 (2)
(Wherein, R ⁴ is a hydrogen atom, a monovalent hydrocarbon group having 1 to 30 carbon atoms, or R ⁵ — (CO) — (where R ⁵ is a monovalent hydrocarbon group having 1 to 30 carbon atoms). And d, e, and f are integers of 0 ≦ d ≦ 15, 0 ≦ e ≦ 50, and 0 ≦ f ≦ 50, respectively.)
Is an organic group selected from the organic groups represented by
R ² is a polyglycerin derivative represented by the following general formulas (3) and / or (4).

(Wherein, R ⁴ has the same meaning as in the above formula (2), and Q represents a divalent hydrocarbon group having 2 to 20 carbon atoms which may contain an ether bond and an ester bond. An integer of 10 and t is an integer of 1 to 10.)
R ³ is a silicon-containing group represented by the following general formula (5).

(In the formula, R ¹ is the same as in the above formula (1), g is an integer of 1 to 5, and h is 0 to 500.)]

  a is from 1.0 to 2.5, preferably from 1.2 to 2.3. If a is smaller than 1.0, the compatibility with the oil agent is inferior, and it may be difficult to obtain water resistance. On the other hand, if it is larger than 2.5, the hydrophilicity becomes poor, so that the adsorptivity to the powder becomes poor and stable dispersibility may not be easily obtained. b is 0.001 to 1.5, preferably 0.01 to 1.0. If b is smaller than 0.001, the hydrophilicity becomes poor, so that the adsorptivity to the powder becomes poor. If it is larger than 5, the hydrophilicity becomes too high, and it may be difficult to obtain stable dispersibility. c is from 0.001 to 1.5, preferably from 0.01 to 1.0. When c is smaller than 0.001, the compatibility with the silicone oil is poor, and it is difficult to obtain water resistance. If it is larger than 5, the hydrophilicity becomes poor, so that the adsorptivity to powder becomes poor, and it may be difficult to obtain stable dispersibility.

Among R ¹ , specific examples of an unsubstituted or substituted monovalent hydrocarbon group include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, Alkyl groups such as undecyl group, dodecyl group, tridecyl group and tetradecyl group; cycloalkyl groups such as cyclopentyl group and cyclohexyl group; aryl groups such as phenyl group and tolyl group; aralkyl groups such as benzyl group and phenethyl group; trifluoropropyl And a fluorine-substituted alkyl group such as a heptadecafluorodecyl group. Furthermore, amino-substituted alkyl groups such as 3-aminopropyl group and 3-[(2-aminoethyl) amino] propyl group, and carboxy-substituted alkyl groups such as 3-carboxypropyl group are exemplified. R ¹ has 1 to 30 carbon atoms, preferably 1 to 16 carbon atoms, more preferably a long-chain alkyl group having 8 or more carbon atoms, preferably 8 to 16 alkyl groups, more preferably 10 to 12 alkyl groups. Groups are more preferred.

Further, it may be an organic group represented by the following general formula (2).
_{-C d H 2d -O- (C 2} H 4 O) e (C 3 H 6 O) f R 4 (2)
R ⁴ is a hydrogen atom, 1 to 30 carbon atoms, or R ⁵ — (CO) — (however, R ⁵ is 1 to 30 carbon atoms, in particular, an alkyl group having 1 to 4 carbon atoms such as a methyl group, etc.) (Valent hydrocarbon group). The monovalent hydrocarbon group of R ⁴ is preferably an alkyl group having 1 to 4 carbon atoms such as a methyl group. In particular, it is preferable that 50 mol% or more of the entire R ⁴ is a methyl group, more preferably 70 mol% or more is a methyl group, and further preferably 100 mol% is a methyl group.

d, e, and f are integers of 0 ≦ d ≦ 15, 0 ≦ e ≦ 50, and 0 ≦ f ≦ 50, respectively. The general formula (2) is an alcohol residue and an alkenyl ether adduct residue. As a specific example, when d = 0: -O- if _{(C 2 H 4 O) e} (C 3 H 6 O) f R 4 and e = 0, f = 0, 1 to 30 carbon atoms Examples include an alkoxy group such as a lower alkoxy group such as a methoxy group and a butoxy group, to a higher alkoxy group such as a cetyl alcohol group such as cetyl alcohol, oleyl alcohol and stearyl alcohol, an oleoxy group and a stearyloxy group. In addition, fatty acid residues such as acetic acid, lactic acid, butyric acid, oleic acid, stearic acid, and behenyl acid are exemplified.

If e and f> 1, it is an alcohol residue of an alkylene oxide adduct of a higher alcohol (terminal is a hydroxyl group). d is 1 or more, in the case of e = 0, f = 0, in particular d is the 3, 5 or 11 Preferably, in this case propyl ether, pentenyl ether, an undecenyl ether residue, the substituents R ⁴ Examples thereof include an allyl stearyl ether residue, a pentenyl behenyl ether residue and an undecenyl oleyl ether residue. When e or f is not 0, an alkoxy group or an ester group exists through the polyoxyalkylene. Regardless of e and f, when d is 0, hydrolysis resistance may be poor, and when d is 15 or more, the oily odor is strong, so that it is preferably 3 to 5.

R ² is a polyglycerin derivative represented by the following general formulas (3) and / or (4).

R ⁴ has the same meaning as in the above formula (2), and Q represents a divalent hydrocarbon group having 2 to 20 carbon atoms which may contain an ether bond and an ester bond. For _{example, - (CH 2) 2 -} , - (CH 2) 3 -, - CH 2 CH (CH 3) CH 2 -, - (CH 2) 4 -, - (CH 2) 5 -, - (CH 2 _{) 6 -, - (CH 2} ) 7 -, - (CH 2) 8 -, - (CH 2) 2 -CH (CH 2 CH 2 CH 3) -, - CH 2 -CH (CH 2 CH 3) - _{, - (CH 2) 3 -O-} (CH 2) 2 -, - (CH 2) 3 -O- (CH 2) 2 -O- (CH 2) 2 -, - (CH 2) 3 -O- _{CH 2 CH (CH 3) -} , - CH 2 -CH (CH 3) -COO (CH 2) 2 - and the like can be exemplified. s is an integer of 2 to 10, especially 2 to 4, and t is an integer of 1 to 10, especially 1 to 4.

R ³ is a silicon-containing group represented by the following general formula (5).

In the general formula (5), R ¹ is the same as in the above formula (1), g is an integer of 1 to 5, and particularly when synthesized from the reaction of a vinylsiloxy group and a SiH group, g is 2 is there. h is 0 to 500, preferably 1 to 50. If h is greater than 500, problems such as poor reactivity with the main chain may occur.

  The silicone-alkyl-branched polyglycerin-modified silicone used in the present invention is not particularly limited as long as it satisfies the conditions, and is preferably lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone or the like (methyl group of dimethicone) defined by a cosmetic label. Is partially substituted with a lauryl group, a triglyceryl group and a polydimethylsiloxyethyl group). Examples of commercially available products include KF-6105 manufactured by Shin-Etsu Chemical Co., Ltd.

  The compounding amount of the component (a) is 0.1 to 12% by mass, preferably 0.5 to 5% by mass in the cosmetic composition.

<(B) component>
<Powder>
The powder used in the present invention is not particularly limited as long as it is a raw material that can be generally blended into cosmetics. However, fine particles having a small particle diameter tend to be difficult to disperse. Has remarkable dispersibility. Further, as another organic particle, a cross-linkable silicone powder (ie, a so-called silicone rubber powder composed of an organopolysiloxane having a structure in which repeating chains of diorganosiloxane units are cross-linked), silicone resin particles (polysiloxane having a three-dimensional network structure). Organosilsesquioxane resin particles) and the like, and specific examples thereof are known as (dimethicone / vinyl dimethicone) crosspolymer, polymethylsilsesquioxane, and the like. These are commercially available as powders or swelled products containing silicone oil and the like, and are commercially available, for example, under the trade names of KMP-598, 590, 591, KSG-016F and the like (all manufactured by Shin-Etsu Chemical Co., Ltd.). One or more of these powders can be used.

  (B) The compounding quantity of a component is 0.1-45 mass% in a cosmetics composition, Preferably it is 1-35 mass%.

  In particular, the silicone resin-coated silicone rubber powder is applied to sunscreens, make-ups, concealers, and the like because of its effect of improving feel such as prevention of stickiness and the effect of correcting morphology such as wrinkles and pores. Specific examples of the silicone resin-coated silicone rubber powder include (vinyl dimethicone / methicone silsesquioxane) crosspolymer, (diphenyldimethicone / vinyl diphenyldimethicone / silsesquioxane) crosspolymer, and poly (vinyl dimethicone / methicone silsesquioxane). It is known under the names of Silicone-22, Polysilicone-1 Crosspolymer and the like. These are commercially available under the trade names such as KSP-100, 101, 102, 105, 300, 411, 441 (all manufactured by Shin-Etsu Chemical Co., Ltd.). One or more of these powders can be used.

<Pigment>
The pigment (color pigment) is not particularly limited as long as it is generally used for makeup cosmetics. For example, talc, mica, kaolin, silica, calcium carbonate, zinc oxide, titanium oxide (titanium dioxide), red iron oxide, yellow iron oxide, black iron oxide, ultramarine, navy blue, carbon black, lower titanium oxide, cobalt violet, oxidation Inorganic pigments such as chromium, chromium hydroxide, cobalt titanate, bismuth oxychloride, and titanium-mica pearl pigments; red 201, red 202, red 204, red 205, red 220, red 220, red 226, red No. 228, Red No. 405, Orange No. 203, Yellow No. 205, Yellow No. 4, Yellow No. 5, Blue No. 1, Blue No. 404, Green No. 3, etc., organic pigments such as zirconium, barium or aluminum lake; chlorophyll, β -Natural pigments such as carotene; dyes and the like. Further, the average primary particle diameter of the color pigment is preferably 1.0 μm or less, and specifically, LL-100P (acicular, average primary particle diameter: 0.07 μm × 0.8 μm), R-516P (acicular, Average primary particle diameter: 0.08 μm × 0.7 μm), BL-100P (average primary particle diameter: 0.3 μm) (all manufactured by Titanium Industry), CR-50 (average primary particle diameter: 0.25 μm (Ishihara Sangyo) Which is surface-treated with silicone, etc. The lower limit is not particularly limited, but may be 0.02 μm. In the case of pigment, dispersion is difficult. According to the invention, good dispersibility is remarkable, and the average primary particle diameter can be measured by a transmission electron microscope photograph.

  When compounding the pigment (color pigment) used in the present invention, the compounding amount is not particularly limited, but is preferably 0.1 to 25% by mass in the cosmetic composition, and 1 to 20% by mass from the viewpoint of usability. % Is more preferred. If the amount is less than 0.1% by mass, a sufficient concealing effect or coloring effect cannot be obtained. If the amount is more than 25% by mass, spreading at the time of use becomes poor or powderyness appears on the decorative film. Or may be.

<Ultraviolet scattering agent>
The ultraviolet scattering agent used in the present invention is not particularly limited as long as it is a raw material that can be usually blended into cosmetics. Specifically, it is a metal oxide selected from one or more of titanium oxide, zinc oxide, and cerium oxide. This metal oxide may be a composite powder of two or more of titanium oxide, zinc oxide and cerium oxide, or may be a composite powder with another powder. The average primary particle size is preferably 200 nm or less, more preferably 120 nm or less. If the particle size is larger than this, the ultraviolet protection function is reduced, and white particles are left. The lower limit is not particularly limited, but may be 10 nm. The average primary particle diameter of the powder used as the ultraviolet scattering agent as defined in the present invention can be measured by a transmission electron microscope photograph. In general, these powders are not truly spherical, and in measurement, the average primary particle diameter is determined from the average of the major axes of the particles. In the case of an ultraviolet scattering agent, particularly titanium oxide, dispersion is difficult, but according to the present invention, good dispersibility is remarkable.

  The powder is not particularly limited, whether it is untreated or a known surface treatment generally used for cosmetics. For example, as the inorganic treatment, silica coating, alumina coating, aluminum hydroxide coating and the like can be mentioned, and as the organic treatment, silanes or silylating agents such as caprylylsilane (AES-3083 manufactured by Shin-Etsu Chemical Co., Ltd.), Dimethyl silicone (Shin-Etsu Chemical: KF-96A series), methyl hydrogen type polysiloxane (Shin-Etsu Chemical: KF-99P, KF-9901, etc.), silicone-branched silicone treatment agent (Shin-Etsu Chemical: KF- 9908, KF-9909, etc.), waxes, paraffins, organic fluorine compounds such as phosphates with perfluoroalkyl, surfactants, amino acids such as N-acylglutamic acid, aluminum stearate, magnesium myristate, etc. Metal soap and the like. In particular, KF-9909 (manufactured by Shin-Etsu Chemical Co., Ltd.) has high dispersibility in both oils such as silicone oil and ester oil, and is therefore applied to sunscreens and foundations. One or more of these surface treatments may be combined according to the purpose, and any combination of inorganic / inorganic, organic / organic, and inorganic / organic may be used.

  Commercially available UV scattering agents having been subjected to these surface treatments can also be used. For example, in the case of fine particle titanium oxide, MT-01, 05, 100Z, 100TV, 100AQ, 100WP, 150EX, 500B, 505SAS, 700B, 014Z, SMT-500SAS (manufactured by Teica), ST-455, 455WS, 457ECS, 495M (Titanium Industry) ), TTO-S1, S4, 51 (C), 55 (A), 55 (C), 80 (A) (manufactured by Ishihara Sangyo). For the fine particle zinc oxide, MZ-150, 200, 300, 306X, 500HP, 505T, 506X, MZY-203S, 303S, 210M3S, TMZ-HA1, MZX-3040TS (manufactured by Teica), FZO-50 (manufactured by Ishihara Sangyo), etc. It is commercially available under the trade name.

  When blending the fine metal oxide used in the present invention, the blending amount is not particularly limited, but is preferably 0.1 to 45% by mass in the cosmetic composition, and 1 to 40% by mass from the viewpoint of usability. Is more preferred. If the content is less than 0.1% by mass, a sufficient ultraviolet shielding effect cannot be obtained. If the content is more than 45% by mass, spreadability at the time of use becomes poor, and whiteness and powderiness appear in the decorative film. Or may be.

  The powder (b) is previously dispersed in an oil phase containing the components (I), (a) and (d), or (II), (a), (c) and (d). Or as a dispersion.

<(C) component>
<Ultraviolet absorber>
The ultraviolet absorber used in the present invention is not particularly limited as long as it is a raw material that can be generally blended into cosmetics. Specifically, homomenthyl salicylate, octocrylene, 4-tert-butyl-4′-methoxydibenzoylmethane, 4- (2-β-glucopyranosyloxy) propoxy-2-hydroxybenzophenone, octyl salicylate, 2- [4 -(Diethylamino) -2-hydroxybenzoyl] benzoyl hexyl ester, dihydroxydimethoxybenzophenone, sodium dihydroxydimethoxybenzophenone disulfonate, dihydroxybenzophenone, dimethicodiethylbenzalmalonate, 1- (3,4-dimethoxyphenyl) -4, 4-dimethyl-1,3-pentanedione, dimethoxybenzylidene dioxoimidazolidine 2-ethylhexyl propionate, tetrahydroxybenzophenone, terephthalidylenedicanfursulfo Acid, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine, methyl bis (trimethylsiloxy) silyl isopentyl trimethoxycinnamate, drometrizole trisiloxane, 2-ethylhexyl paradimethylaminobenzoate, isopropyl paramethoxycinnamate, 2-ethylhexyl paramethoxycinnamate, 2,4-bis-[{4- (2-ethylhexyloxy) -2-hydroxy} -phenyl]- 6- (4-methoxyphenyl) -1,3,5-triazine, 2-hydroxy-4-methoxybenzophenone, hydroxymethoxybenzophenonesulfonic acid and its trihydrate, sodium hydroxymethoxybenzophenonesulfonate, phenylbenzimidazolesulfonic acid, 2,2'- Chirenbisu [6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol], and the like. Further, a UVA absorber (for example, hexyl diethylaminohydroxybenzoylbenzoate) and a UVB absorber (for example, ethylhexyl methoxycinnamate) can be used in combination, and each can be arbitrarily combined.

  (C) The compounding quantity of a component is 0.1-20 mass% of the whole cosmetics of this invention, 3.5-18 mass% is more preferable, More preferably, it is 6.5-16 mass%.

<(D) component>
The oil agent having a viscosity of 1 to 100 mm ² / s at 25 ° C. other than the component (c) is not particularly limited as long as it is a raw material that can be usually blended in cosmetics. Specifically, silicone oil, ester oil, hydrocarbon oil, and fluorinated oil can be used.

-Silicone oil The silicone oil is not particularly limited as long as it is a raw material that can be usually blended in cosmetics. Specifically, dimethylpolysiloxane, cyclopentasiloxane (decamethylcyclopentasiloxane), cyclohexasiloxane, disiloxane, Methylphenylpolysiloxanes such as trisiloxane, methyltrimethicone, caprylylmethicone, diphenyldimethicone (cosmetic label), diphenylsiloxyphenyltrimethicone (cosmetic label), methylhexylpolysiloxane, methylhydrogenpolysiloxane, dimethylsiloxane. Methylphenylsiloxane copolymer and the like can be mentioned. Among them, volatile silicones that provide a refreshing feeling of use [commercially available from Shin-Etsu Chemical Co., Ltd .: TMF-1.5, KF-995, KF-96A-1cs, KF-96A-1.5cs, KF-96A] -2cs, etc.], low-viscosity silicone (commercially available from Shin-Etsu Chemical Co., Ltd .: KF-96A-6cs, etc.), and phenyl silicone [commercially available for the purpose of improving compatibility with other oil agents and polishing. Preferred are, for example, Shin-Etsu Chemical's KF-56A]. One or more of these silicone oils can be used.

  Other oils include cetyl ethylhexanoate, triethylhexanoin, glyceryl tri (caprylate / caprate), isononyl isononanoate, isotridecyl isononanoate, isopropyl palmitate, dicaprylyl ether, isopropyl myristate, ethylhexyl palmitate, carbonic acid Ester oils such as diethylhexyl, dicaprylyl carbonate, alkyl benzoate (C12-15), and neopentyl glycol diethylhexanoate; hydrocarbon oils such as isododecane and undecane; and fluorine-based oils such as perfluorohexane and perfluoropolyether. Can be

(D) The viscosity of component is 1 to 100 mm ² / s at 25 ° C., is preferably from 1 to 50 mm ² / s, more preferably from 1 to 30 mm ² / s. The compounding amount is 0.1 to 60% by mass in the cosmetic composition, and more preferably 5 to 55% by mass. In the present invention, the kinematic viscosity is a value measured at 25 ° C. by an Ostwald viscometer.

<Other optional ingredients>
The cosmetic of the present invention can be blended with various components used in ordinary cosmetics as long as the effects of the present invention are not impaired. As the components, for example, (1) an oil agent other than the components (c) and (d), (2) an aqueous component, (3) a coating agent, (4) a surfactant other than the (a) component, and (5) a crosslinking type It may contain organopolysiloxane, (6) wax, (7) other additives. These can be used alone or in combination of two or more.

(1) Oils other than the components (c) and (d) The oils other than the components (c) and (d) used in the present invention are raw materials that can be blended with ordinary cosmetics used for improving feel and emollient effects. Although not particularly limited, high-viscosity linear or branched organopolysiloxane, amino-modified organopolysiloxane, pyrrolidone-modified organopolysiloxane, pyrrolidonecarboxylic acid-modified organopolysiloxane, high polymerization degree gum-like dimethylpolysiloxane, gum Amino-modified organopolysiloxane and cyclic organopolysiloxane solution such as silicone gum, higher alkoxy-modified silicone such as stearoxysilicone, higher fatty acid-modified silicone, alkyl-modified silicone, long-chain alkyl-modified silicone, amino acid-modified silicone, fluorine-modified silicone Resin, silicone resin, and a melt of silicone resin. Among these, silicone wax (for commercial products, such as KP-561P, 562P, KF-7020S, etc., manufactured by Shin-Etsu Chemical Co., Ltd.) used for the purpose of polishing and adjusting the feeling of use is particularly preferably used. In addition to silicone, high-viscosity hydrocarbon oils such as petrolatum and hydrogenated polyisobutene are exemplified. The amount of the oil agent other than the components (c) and (d) is preferably 0.1 to 20% by mass in the cosmetic composition.

(2) Aqueous component The aqueous component is not particularly limited as long as it is a raw material that can be blended with a normal cosmetic used for a moisturizing effect or a cooling effect, but is not particularly limited, and is a lower alcohol such as ethanol and isopropanol; Polyhydric alcohols such as alcohol, butylene glycol, dibutylene glycol, propylene glycol, dibutylene glycol, pentylene glycol, decanediol, octanediol, hexanediol, erythritol, glycerin, diglycerin, and polyethylene glycol; glucose, glyceryl glucoside, and betaine , Hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside and the like. When blending the aqueous component, the blending amount is preferably 0.1 to 30% by mass in the cosmetic composition.

(3) Coating agent The coating agent is not particularly limited as long as it is a raw material that can be usually blended into cosmetics, and specific examples thereof include latexes such as polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl acetate, and polyalkyl acrylate, and dextrin. , Cellulose derivatives such as alkylcellulose and nitrocellulose, siliconized polysaccharide compounds such as tri (trimethylsiloxy) silylpropylcarbamate pullulan, acrylic-silicone graft copolymers such as (alkyl acrylate / dimethicone) copolymer, trimethylsiloxysilicone Silicone resin such as acid, silicone resin, silicone modified polynorbornene, fluorine modified silicone resin, etc., fluorine resin, aromatic hydrocarbon resin, polymer emulsion resin, terpene resin, polybutene, polyisoprene Alkyd resin, polyvinylpyrrolidone-modified polymer, rosin-modified resin, polyurethane and the like. When the filming agent is compounded, the amount is preferably 0.1 to 20% by mass in the cosmetic composition.

  Among these, a silicone-based film agent is particularly preferable, and among them, tri (trimethylsiloxy) silylpropylcarbamate pullulan [a commercially available product dissolved in a solvent, manufactured by Shin-Etsu Chemical Co., Ltd .: TSPL-30-D5, ID] Or (alkyl acrylate / dimethicone) copolymer [commercially available, as dissolved in a solvent, manufactured by Shin-Etsu Chemical Co., Ltd .: KP-543, 545, 549, 550, 545L], or trimethylsiloxysilicic acid [commercially available And K-7312J, X-21-5250 manufactured by Shin-Etsu Chemical Co., Ltd. and silicone-modified polynorbornene [commercially available as products dissolved in a solvent: NBN manufactured by Shin-Etsu Chemical: NBN -30-ID etc.] can be used, but the present invention is not limited thereto. One or two or more kinds of coating agents can be used.

(4) Surfactants other than component (a) Surfactants include nonionic, anionic, cationic and amphoteric surfactants, but are not particularly limited and are used in ordinary cosmetics. Any of the above can be used. Among these surfactants, partially crosslinked polyether-modified silicone, partially crosslinked polyglycerin-modified silicone, linear or branched polyoxyethylene-modified organopolysiloxane, linear or branched polyoxyethylene polyoxypropylene-modified organo Polysiloxane, linear or branched polyoxyethylene-alkyl co-modified organopolysiloxane, linear or branched polyoxyethylene polyoxypropylene-alkyl co-modified organopolysiloxane, linear or branched polyglycerin-modified organopolysiloxane, It is preferably a linear or branched polyglycerin / alkyl co-modified organopolysiloxane. In these surfactants, the content of the hydrophilic polyoxyethylene group, polyoxyethylene polyoxypropylene group or polyglycerin residue preferably accounts for 10 to 70% by mass of the molecule. Specific examples include KSG-210, 240, 310, 320, 330, 340, 320Z, 350Z, 710, 810, 820, 830, 840, 820Z, 850Z, and KF-6011, 6013, 6043, manufactured by Shin-Etsu Chemical Co., Ltd. 6028, 6038, 6048, 6100, 6104, and 6106. When the surfactant other than the component (a) is blended, the blending amount is preferably 0.1 to 10% by mass in the cosmetic composition.

(5) Cross-linked organopolysiloxane The cross-linked organopolysiloxane is not particularly limited as long as it is generally used in cosmetics, and can be used alone or in an appropriate combination of two or more. The component (5), unlike the component (4), is a compound having no polyether or polyglycerin structure in its molecular structure, and is an elastomer having a structural viscosity by swelling an oil agent. For example, (dimethicone / vinyl dimethicone) crosspolymer, (dimethicone / phenylvinyl dimethicone) crosspolymer, (vinyl dimethicone / lauryl dimethicone) crosspolymer, (lauryl polydimethylsiloxyethyl dimethicone / bisvinyl dimethicone) crosspolymer and the like can be mentioned. These are commercially available as swellings containing a liquid oil at room temperature, and specific examples are KSG-15, 1510, 16, 1610, 18A, 19, 41A, 42A, 43, 44, 042Z, 045Z manufactured by Shin-Etsu Chemical Co., Ltd. , 048Z and the like. In some cases, these products may contain a part (d) as a solvent.

(6) Wax The wax used in the present invention is not particularly limited as long as it is a raw material that can be usually blended into cosmetics. Specifically, hydrocarbon waxes such as ceresin, ozokerite, paraffin, synthetic wax, microcrystalline wax, polyethylene wax, carnauba wax, rice wax, rice bran wax, jojoba wax (including extremely hydrogenated jojoba oil), candelilla wax And wax derived from animals such as spermaceti, beeswax, snow wax and the like, and one or more of these waxes can be used. When the wax is compounded, the amount is preferably 0.1 to 10% by mass in the cosmetic composition.

(7) Other additives Other additives include oil-soluble gelling agents, antiperspirants, humectants, preservatives / bactericides, fragrances, salts, antioxidants, pH adjusters, chelating agents, and fresheners. , Anti-inflammatory agents, ingredients for beautiful skin (whitening agents, cell activators, skin roughness improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, water-soluble polymer compounds, plant extracts, etc. Is mentioned.

Oil-soluble gelling agents As oil-soluble gelling agents, metal soaps such as aluminum stearate, magnesium stearate and zinc myristate; amino acids such as N-lauroyl-L-glutamic acid, α, γ-di-n-butylamine Derivatives; dextrin fatty acid esters such as dextrin palmitate, dextrin stearate, and dextrin 2-ethylhexanoate palmitate; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide stearates , Fructooligosaccharides, 2-ethylhexanoic acid esters, etc .; fructooligosaccharide fatty acid esters; benzylidene derivatives of sorbitol, such as monobenzylidene sorbitol, dibenzylidene sorbitol; Hectorite, stearalkonium benzalkonium transfected write, and organic-modified clay minerals such as hectorite.

・ Preservatives ・ Bactericides As preservatives ・ bactericides, alkyl paraoxybenzoate, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, imidazolidinyl urea, benzoic acid, salicylic acid, isopropyl methyl phenol, Examples include phthalic acid, alkyl paraoxybenzoate, parachloromethcresol, hexachlorophen, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, propynyl iodide butylcarbamate, polylysine, photosensitizer, silver, and plant extract.

  The cosmetic composition of the present invention may be either an emulsion composition or a non-aqueous composition. When it is desired to impart a fresh feeling of use, an emulsion composition is selected. The emulsified form may be any of an O / W emulsion, a W / O emulsion and a W / O / W emulsion. When an oily feeling or water resistance is desired, a non-aqueous composition can be selected. In this case, a good cosmetic can be obtained. In the present invention, the “non-aqueous composition” refers to an oily composition containing substantially no water. In addition, it is also possible to use a non-aqueous composition as a dispersion and adjust it in cosmetics, and when blending an ultraviolet scattering agent, improve the dispersibility of the dispersion and improve the transparency and formulation. The degree of freedom increases.

  In the present invention, the cosmetic is not particularly limited as long as it is a cosmetic containing essential components, but, for example, a serum, an emulsion, a cream, a hair care, a foundation, a makeup base, a concealer, a teak color, It can be applied to various products such as lipstick, eye shadow, eye liner, body makeup, deodorant and the like. As the properties of the cosmetic of the present invention, various properties such as liquid, cream, solid, paste, gel, mousse, souffle, clay, and powder can be selected.

  Hereinafter, the present invention will be described specifically with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples. In the following examples, unless otherwise specified, “%” of the composition is% by mass.

[Example 1, Comparative Examples 1-4]
A slurry was prepared according to the formulation shown in Table 1 using a paint shaker (media diameter: 1.5 mm). The viscosity was measured at a temperature of 25 ° C./B-type viscometer, spindle LV-3, after 30 seconds at 30 rotations. The unit is mPa · s.

※ＳＴ−４５５（チタン工業製）
平均一次粒子径１２０ｎｍ
（注１）シリコーン・アルキル分岐型ポリグリセリン変性シリコーン（ＫＦ−６１０５：信越化学工業社製）
（注２）シリコーン分岐型ポリグリセリン変性シリコーン（ＫＦ−６１０６：信越化学工業社製）
（注３）シリコーン・アルキル分岐型ポリエーテル変性シリコーン（ＫＦ−６０３８：信越化学工業社製）
（注４）シリコーン分岐型ポリエーテル変性シリコーン（ＫＦ−６０２８：信越化学工業社製）
（注５）アルキル分岐型ポリエーテル変性シリコーン（ＫＦ−６０４８：信越化学工業社製）
（注６）ジフェニルシロキシフェニルトリメチコン：粘度１５ｍｍ²／ｓ（２５℃）（ＫＦ−５６Ａ：信越化学工業社製）
（注７）デカメチルシクロペンタシロキサン：粘度４．０ｍｍ²／ｓ（２５℃）（ＫＦ−９９５：信越化学工業社製）
表中の配合量は、記載の配合製品の配合量(以下同様)。

* ST-455 (manufactured by Titanium Industry)
Average primary particle size 120nm
(Note 1) Silicone / alkyl branched polyglycerin-modified silicone (KF-6105: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Silicone branched polyglycerin-modified silicone (KF-6106: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Silicone / alkyl branched polyether-modified silicone (KF-6038: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 4) Silicone branched polyether-modified silicone (KF-6028: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 5) Alkyl branched polyether-modified silicone (KF-6048: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 6) diphenyl phenyl trimethicone: viscosity ^{15mm 2 / s (25 ℃)} (KF-56A: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 7) Decamethylcyclopentasiloxane: viscosity 4.0 mm ² / s (25 ° C.) (KF-995: manufactured by Shin-Etsu Chemical Co., Ltd.)
The blending amount in the table is the blending amount of the described blended product (the same applies hereinafter).

  From the results shown in Table 1, it was found that in the present invention, the dispersibility of the powder was excellent in the presence of the ultraviolet absorber, and a cosmetic having a lower viscosity could be prepared.

[Production Examples 1 to 5, Example 2, Comparative Examples 5 to 8]
After preparing a paste using three rolls according to the formulation shown in Table 2, cosmetics having the formulation shown in Table 3 were produced. The viscosity was measured under conditions of a 25 ° C. B-type viscometer, a spindle TE, 30 rotations, and a viscosity after 30 seconds. The unit is mPa · s.

※ＢＡＥ−チタンＣＲ−５０（三好化成製）
平均一次粒子径０．２５μｍ
＊注は上記と同じ、以下同様

* BAE-Titanium CR-50 (manufactured by Miyoshi Kasei)
Average primary particle size 0.25μm
* Note is the same as above, same as below

（注８）部分架橋型ジメチルポリシロキサン組成物（ＫＳＧ−１５〈架橋物：４〜１０％、デカメチルシクロペンタシロキサン：９０〜９６％〉：信越化学工業社製）
（注９）フェニル変性・部分架橋型ジメチルポリシロキサン組成物（ＫＳＧ−１８Ａ〈架橋物：１０〜２０％、ジフェニルシロキシフェニルトリメチコン：８０〜９０％〉：信越化学工業社製）

(Note 8) Partially crosslinked dimethylpolysiloxane composition (KSG-15 (crosslinked product: 4 to 10%, decamethylcyclopentasiloxane: 90 to 96%): manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 9) Phenyl-modified / partially crosslinked dimethylpolysiloxane composition (KSG-18A (crosslinked product: 10 to 20%, diphenylsiloxyphenyl trimethicone: 80 to 90%): manufactured by Shin-Etsu Chemical Co., Ltd.)

  From the results shown in Table 2 above, it was found that in the present invention, the powder was excellent in dispersibility and a paste with lower viscosity could be prepared. Further, from the results in Table 3, when the dispersibility of the paste is improved, the viscosity of the cosmetic containing the paste is also reduced, and the degree of freedom of the formulation is increased. In addition, it was found that the present invention had good dispersibility regardless of the type of powder and the dispersion step.

[Example 3, Comparative Examples 9 to 12]
After preparing a slurry using a paint shaker (media diameter: 1.5 mm) according to the formulation shown in Table 4, a cosmetic composition shown in Table 6 was produced by the following method. The viscosity was measured at a temperature of 25 [deg.] C./B-type viscometer, spindle LV-4, 6 rotations and 60 seconds later. The unit is mPa · s.

※１ ＳＴ−４５５（チタン工業製）
平均一次粒子径１２０ｎｍ
※２ ＭＺＹ−５０６Ｘ（テイカ製）
平均一次粒子径２５ｎｍ

* 1 ST-455 (manufactured by Titanium Industry)
Average primary particle size 120nm
* 2 MZY-506X (manufactured by Teica)
Average primary particle diameter 25nm

<Preparation of cosmetic composition>
A: Components (1) to (8) were uniformly mixed.
B: Components (9) to (12) were uniformly mixed.
C: B was added to A and emulsified to obtain a sunscreen.

(1) Characteristic evaluation The cosmetic compositions of Example 3 and Comparative Examples 9 to 12 were evaluated for the feeling of use (no stickiness) and elongation (extensibility) of the cosmetic according to the evaluation criteria shown in Table 5. did. The results were determined based on the average value of 10 persons according to the following criteria. In addition, the storage stability of the preparation was confirmed for one month under the conditions of 50 ° C. and −5 ° C., respectively, and compared with that before storage, and determined according to the following criteria. The results are also shown in the table.

（２）判定基準
◎：平均点が４．５点以上
○：平均点が３．５点以上４．５点未満
△：平均点が２．５点以上３．５点未満
×：平均点が１．５点以上２．５点未満
××：平均点が１．５点未満

(2) Judgment criteria ：: Average score of 4.5 or more ○: Average score of 3.5 or more and less than 4.5 Δ: Average score of 2.5 or more and less than 3.5 ×: Average score of 1.5 or more and less than 2.5 points XX: Average point is less than 1.5 points

  From the results in Table 6 above, it was found that the cosmetic of the present invention had good feeling in use (no stickiness), elongation (extensibility), and storage stability of the preparation.

[Example 4]
W / O sunscreen <Preparation of cosmetics>
A: Components (1) to (10) were uniformly mixed.
B: Components (11) to (16) were uniformly mixed.
C: B was added to A and emulsified to obtain a sunscreen.
(1) Silicone / alkyl branched polyether-modified silicone (Note 3)
4
(2) Phenyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 9)
3.5
(3) Decamethylcyclopentasiloxane (Note 7) 4.5
(4) Diphenylsiloxyphenyl trimethicone (Note 6) 4
(5) Organically modified clay mineral 0.7
(6) Ethylhexyl methoxycinnamate 7
(7) Octocrylene 2
(8) Hexyl diethylaminohydroxybenzoyl benzoate 1
(9) Titanium oxide dispersion 1 13
(10) Zinc oxide dispersion 120
(11) Butylene glycol 4
(12) Ethanol 6
(13) Methyl paraben 0.1
(14) Sodium citrate 0.2
(15) Sodium chloride 1
(16) Water remaining
100.0% in total
This W / O sunscreen was high in transparency, good in use feeling, elongation, and good in formulation stability.

[Example 5]
W / O sunscreen <Preparation of cosmetics>
A: Components (1) to (9) were uniformly mixed.
B: Components (10) to (15) were uniformly mixed.
C: B was added to A and emulsified to obtain a sunscreen.
(1) Partially crosslinked polyether-modified silicone composition (Note 10) 3.5
(2) Silicone / alkyl branched polyether-modified silicone (Note 3)
1.5
(3) Phenyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 9)
2
(4) Decamethylcyclopentasiloxane (Note 7) 2
(5) isononyl isononanoate 6
(6) Ethylhexyl methoxycinnamate 7
(7) bisethylhexyloxyphenol methoxyphenyl triazine
1
(8) Hexyl diethylaminohydroxybenzoyl benzoate 2.5
(9) Titanium oxide dispersion 125
(10) Dipropylene glycol 4
(11) Ethanol 8
(12) Methyl paraben 0.1
(13) Sodium citrate 0.2
(14) Sodium chloride 1
(15) Water remaining
100.0% in total
(Note 10) Partially crosslinked polyether-modified silicone composition (KSG-240 (crosslinked product: 15 to 25%, decamethylcyclopentasiloxane: 75 to 85%): manufactured by Shin-Etsu Chemical Co., Ltd.)
This W / O sunscreen was highly transparent, and had good feeling in use, elongation, and stability of the preparation.

W / O sunscreen <Preparation of cosmetics>
A: Components (9) to (11) were dispersed in a bead mill.
B: Components (1) to (8) were uniformly mixed.
C: Components (12) to (17) were uniformly mixed.
D: C was added to B and emulsified, and A was added to obtain a sunscreen.
(1) Alkyl-modified / partially cross-linked polyether-modified silicone composition (Note 11)
3.5
(2) Silicone / alkyl branched polyether-modified silicone (Note 3)
1
(3) Alkyl-branched polyether-modified silicone (Note 5) 0.8
(4) Alkyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 12)
3
(5) Methyl trimethicone 4
(6) Isododecane 6
(7) Ethylhexyl methoxycinnamate 7
(8) Ethylhexyl salicylate 2
(9) Dimethyl polysiloxane (2cs) 10.5
(10) Silicone-alkyl branched polyglycerin-modified silicone (Note 1)
1.5
(11) Silicone-treated fine particle zinc oxide (average primary particle diameter: 20 nm)
18
(12) Propylene glycol 4
(13) Ethanol 8
(14) Phenoxyethanol 0.3
(15) Sodium citrate 0.2
(16) Sodium chloride 0.5
(17) Water remaining
100.0% in total
(Note 11) Alkyl-modified / partially crosslinked polyether-modified silicone composition (KSG-330 (crosslinked product: 15 to 25%, triethylhexanoin: 75 to 85%): manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 12) Alkyl-modified / partially crosslinked dimethylpolysiloxane composition (KSG-43 (crosslinked product: 25 to 35%, triethylhexanoin: 65 to 75%): manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 13) Methyl trimethicone (TMF-1.5: manufactured by Shin-Etsu Chemical Co., Ltd.)
This W / O sunscreen was highly transparent, and had good feeling in use, elongation, and stability of the preparation.

[Example 7]
W / O sunscreen <Preparation of cosmetics>
A: Components (1) to (7) were uniformly mixed.
B: Components (8) to (13) were uniformly mixed.
C: B was added to A and emulsified to obtain a sunscreen.
(1) Alkyl-modified / partially cross-linked polyglycerin-modified silicone composition (Note 14)
4
(2) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
1
(3) Silicone / alkyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 15)
3
(4) Decamethylcyclopentasiloxane (Note 7) 10
(5) Ethylhexyl methoxycinnamate 6
(6) Titanium oxide dispersion 1 13
(7) Zinc oxide dispersion 120
(8) Glycerin 4
(9) Ethanol 9
(10) Phenoxyethanol 0.3
(11) Sodium citrate 0.2
(12) Magnesium sulfate 0.5
(13) Water remaining
100.0% in total
(Note 14) Alkyl-modified / partially crosslinked polyglycerin-modified silicone composition (KSG-830 (crosslinked product: 15 to 25%, triethylhexanoin: 75 to 85%): manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 15) Silicone / alkyl-modified / partially crosslinked dimethylpolysiloxane composition (KSG-045Z (crosslinked product: 15 to 25%, cyclopentasiloxane: 75 to 85%): manufactured by Shin-Etsu Chemical Co., Ltd.)
This W / O sunscreen was highly transparent, and had good feeling in use, elongation, and stability of the preparation.

Example 8
W / O sunscreen <Preparation of cosmetics>
A: Components (8) to (11) and (12) to (15) were each dispersed by a bead mill.
B: Components (1) to (7) were uniformly mixed.
C: Components (16) to (21) were uniformly mixed.
D: C was added to B and emulsified, and A was added to obtain a sunscreen.
(1) Partially crosslinked dimethylpolysiloxane composition (Note 8) 2
(2) Partially crosslinked dimethylpolysiloxane composition (Note 16) 4
(3) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
0.5
(4) Decamethylcyclopentasiloxane (Note 7) 5
(5) Isotridecyl isononanoate 4
(6) Ethylhexyl methoxycinnamate 4
(7) Acrylic-silicone graft copolymer (Note 18) 1
(8) Decamethylcyclopentasiloxane (Note 7) 13.5
(9) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
2
(10) Silicone branched polyglycerin-modified silicone (Note 17)
1
(11) Metal-soap-treated fine particle titanium oxide (average primary particle diameter: 60 nm)
13.5
(12) Decamethylcyclopentasiloxane (Note 7) 12.25
(13) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
1
(14) Silicone branched polyglycerin-modified silicone (Note 17)
0.75
(15) Silicone-treated fine particle zinc oxide (average primary particle diameter: 60 nm)
21
(16) Butylene glycol 2
(17) Ethanol 3
(18) Methyl paraben 0.1
(19) Sodium citrate 0.2
(20) Sodium chloride 0.5
(21) Water remaining
100.0% in total
(Note 16) Partially crosslinked dimethylpolysiloxane composition (KSG-16 (crosslinked product: 20 to 30%, dimethicone (6cs): 70 to 80%): manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 17) Silicone branched polyglycerin-modified silicone (KF-6106: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 18) Acrylic-silicone graft copolymer (KP-545: manufactured by Shin-Etsu Chemical Co., Ltd.)
This W / O sunscreen was high in transparency, good in use feeling, elongation, and good in formulation stability.

[Example 9]
W / O foundation <Preparation of cosmetics>
A: Components (9) to (15) were dispersed by a roll mill.
B: Components (1) to (8) were uniformly mixed.
C: Components (16) to (21) were uniformly mixed.
D: C was added to B and emulsified, and A was added to obtain a foundation.
(1) Partially crosslinked polyether-modified silicone composition (Note 10) 3.5
(2) Alkyl-branched polyether-modified silicone (Note 5) 3
(3) Phenyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 9)
5
(4) Organic modified clay mineral 1.5
(5) Diphenylsiloxyphenyl trimethicone (Note 6) 9
(6) Decamethylcyclopentasiloxane (Note 7) 15
(7) Ethylhexyl methoxycinnamate 7
(8) Hexyl diethylaminohydroxybenzoyl benzoate 2
(9) Isotridecyl isononanoate 7.5
(10) Silicone-alkyl branched polyglycerin-modified silicone (Note 1)
1
(11) Metal-soap-treated fine particle titanium oxide (average primary particle diameter: 60 nm)
5
(12) Siliconized titanium oxide (average primary particle diameter: 0.25 μm) (Note 19)
6.5
(13) Silicone-treated yellow iron oxide (average primary particle size: 0.07 μm × 0.8 μm) (Note 19) 0.75
(14) Silicone-treated red iron oxide average primary particle size: 0.08 μm × 0.7 μm) (Note 19) 0.14
(15) Siliconized black iron oxide (average primary particle size: 0.3 μm (Note 19)
0.01
(16) Glycerin 2
(17) Dibutylene glycol 3
(18) Phenoxyethanol 0.2
(19) Sodium citrate 0.2
(20) Sodium chloride 0.5
(21) Water remaining
100.0% in total
(Note 19) Silicone-treated powder (KF-9909: Silicone-treated powder that is manufactured by Shin-Etsu Chemical Co., Ltd. and is subjected to hydrophobic surface treatment with titanium oxide, yellow iron oxide, red iron oxide, and black iron oxide, respectively)
This W / O foundation had good feeling in use, elongation, long-lasting makeup, and stability of the preparation.

[Example 10]
W / O Stick Foundation <Preparation of cosmetics>
A: Components (8) to (13) were dispersed by a roll mill.
B: A, components (1) to (7) were heated to 95 ° C. and mixed uniformly.
C: Components (14) to (18) were uniformly mixed and heated to 85 ° C.
D: C was added to B and emulsified, filled in a stick container, and then gradually cooled to obtain a stick foundation.
(1) Partially crosslinked polyglycerin-modified silicone composition (Note 20) 4
(2) Silicone / alkyl branched polyether-modified silicone (Note 3)
1.5
(3) Inulin stearate (Note 21) 2
(4) Selesin 6
(5) Diphenylsiloxyphenyl trimethicone (Note 6) 11.5
(6) Ethylhexyl methoxycinnamate 5
(7) Polymethylsilsesquioxane (Note 22) 1.5
(8) Isotridecyl isononanoate 4
(9) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
1
(10) Siliconized titanium oxide (average primary particle size: 0.25 μm) (Note 19)
6.5
(11) Silicone-treated yellow iron oxide (average primary particle size: 0.07 μm × 0.8 μm) (Note 19) 0.75
(12) Siliconized red iron oxide (average primary particle size: 0.08 μm × 0.7 μm) (Note 19) 0.14
(13) Silicone-treated black iron oxide (average primary particle size: 0.3 μm (Note 19)
0.01
(14) Dipropylene glycol 6
(15) Methyl paraben 0.1
(16) Sodium citrate 0.2
(17) Sodium chloride 0.5
(18) Water remaining
100.0% in total
(Note 20) Partially crosslinked polyglycerin-modified silicone composition (KSG-710 (crosslinked product: 20 to 30%, dimethicone (6cs): 70 to 80%): manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 21) Inulin stearate (Leopearl ISK2: manufactured by Chiba Flour Milling Co., Ltd.)
(Note 22) Polymethylsilsesquioxane (KMP-590: manufactured by Shin-Etsu Chemical Co., Ltd.)
This W / O stick foundation had good feeling in use, elongation, long-lasting makeup, and stability of the preparation.

[Example 11]
W / O sunscreen <Preparation of cosmetics>
A: Components (1) to (6) were uniformly mixed.
B: Components (7) to (13) were uniformly mixed.
C: B was added to A and emulsified to obtain a sunscreen.
(1) Alkyl-modified / partially cross-linked polyglycerin-modified silicone composition (Note 23)
3
(2) Alkyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 12)
3
(3) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
1.5
(4) Diphenylsiloxyphenyl trimethicone (Note 6) 12
(5) Ethylhexyl methoxycinnamate 6
(6) Silicone composite powder (Note 24) 3
(7) Xanthan gum 0.3
(8) Dipropylene glycol 5
(9) Glycerin 3
(10) Methyl paraben 0.1
(11) Sodium citrate 0.2
(12) Sodium chloride 0.5
(13) Water remaining
100.0% in total
(Note 23) Alkyl-modified / partially cross-linked polyglycerin-modified silicone composition (KSG-840 (cross-linked product: 25 to 35%, squalane: 65 to 75%): manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 24) Silicone composite powder (KSP-100: manufactured by Shin-Etsu Chemical Co., Ltd.)
This sunscreen had good usability, elongation, and formulation stability.

O / W sunscreen <Preparation of cosmetics>
A: Components (7) to (9) were dispersed by a roll mill.
B: Components (1) to (6) were heated to 70 ° C. and uniformly mixed.
C: A, Components (10) to (12) were heated to 70 ° C. and uniformly mixed.
D: C was added to B, emulsified, and gradually cooled to obtain a sunscreen.
(1) Xanthan gum 0.3
(2) Ethanol 10
(3) Butylene glycol 6
(4) Methyl paraben 0.1
(5) Sodium acrylate / acryloyldimethyl sodium taurate copolymer composition (Note 25) 2
(6) Water remaining (7) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
0.5
(8) Alkyl benzoate (C12-C15) 7.5
(9) Siliconized fine particles of zinc oxide (average primary particle diameter: 20 nm)
10
(10) Cetanol 2
(11) Ethylhexyl methoxycinnamate 5
(12) Polyoxyethylene (60) hydrogenated castor oil 1.5
100.0% in total
(Note 25) Sodium acrylate / sodium acryloyldimethyltaurate copolymer composition (SIMULGEL EG (polymer: 35 to 40%): manufactured by SEPPIC)
This O / W sunscreen had good usability, elongation, and formulation stability, high transparency, and water resistance.

Example 13
O / W sunscreen <Preparation of cosmetics>
A: Components (7) to (9) were dispersed by a roll mill.
B: Components (1) to (6) were heated to 70 ° C. and uniformly mixed.
C: A, Components (10) to (13) were heated to 70 ° C. and uniformly mixed.
D: C was added to B, emulsified, and gradually cooled to obtain a sunscreen.
(1) Hydroxyethyl cellulose 0.2
(2) Ethanol 10
(3) Butylene glycol 6
(4) Phenoxyethanol 0.3
(5) Acrylic amide composition (Note 26) 2.5
(6) Water remaining (7) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
1
(8) Tri (caprylic / capric acid) glyceryl 7.5
(9) Fine particles of titanium oxide treated with metal soap (average primary particle diameter: 80 nm)
7
(10) myristyl alcohol 2
(11) Ethylhexyl methoxycinnamate 5
(12) Hexyl diethylaminohydroxybenzoyl benzoate 1
(13) POE monostearate (20) sorbitan 1.5
100.0% in total
(Note 26) Acrylic amide composition (Sepigel 305 <Polymer: 40%>: manufactured by SEPPIC)
This O / W sunscreen had good usability, elongation, and formulation stability, high transparency, and water resistance.

[Example 14]
O / W sunscreen <Preparation of cosmetics>
A: Components (1) to (6) were heated to 70 ° C. and mixed uniformly.
B: Components (7) to (10) were heated to 70 ° C. and uniformly mixed.
C: B, (11) and (12) were added to A, emulsified, and gradually cooled to obtain a sunscreen.
(1) Xanthan gum 0.3
(2) Pentylene glycol 2
(3) Butylene glycol 10
(4) Ethylhexyl glycerin 0.1
(5) Sodium acrylate / acryloyldimethyl sodium taurate copolymer composition (Note 25) 2
(6) Water remaining (7) Cetanol 2
(8) Ethylhexyl methoxycinnamate 3
(9) Polyoxyethylene (60) hydrogenated castor oil 0.5
(10) Polyether-modified silicone (Note 27) 1
(11) Titanium oxide dispersion 15
(12) Dispersion of zinc oxide 110
100.0% in total
(Note 27) Polyether-modified silicone (KF-6043: manufactured by Shin-Etsu Chemical Co., Ltd.)
This O / W sunscreen had good usability, elongation, and formulation stability, high transparency, and water resistance.

[Example 15]
Moose Foundation <Preparation of cosmetics>
A: Components (8) to (15) were dispersed by a roll mill.
B: A, components (1) to (5) were uniformly mixed.
C: B, Components (6) and (7) were uniformly mixed to obtain a mousse foundation.
(1) Silicone / alkyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 15) 33
(2) Trimethylsiloxysilicate composition (Note 28) 10
(3) Diphenylsiloxyphenyl trimethicone (Note 6) 5
(4) Squalane 0.5
(5) Ethylhexyl methoxycinnamate 5
(6) Silicone composite powder (Note 24) 15.5
(7) Polymethyl methacrylate 2
(8) Dimethylpolysiloxane (Note 29) 8.5
(9) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
0.5
(10) Siliconized titanium oxide (average primary particle size: 0.25 μm) (Note 19)
6
(11) Silicone-treated yellow iron oxide (average primary particle size: 0.07 μm × 0.8 μm) (Note 19) 0.75
(12) Siliconized red iron oxide (average primary particle size: 0.08 μm × 0.7 μm) (Note 19) 0.14
(13) Silicone-treated black iron oxide (average primary particle size: 0.3 μm (Note 19)
0.01
(14) Metal-soap-treated fine particle titanium oxide (average primary particle diameter: 60 nm)
9
(15) Silicone treated talc (Note 30)
100.0% in total
(Note 28) Trimethylsiloxysilicic acid composition (KF-7312L: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 29) Dimethyl polysiloxane (KF-96A-6cs: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 30) Silicone-treated talc (KF-9909: Silicone-treated powder with talc hydrophobized using Shin-Etsu Chemical Co., Ltd.)
This mousse foundation had good feeling in use, elongation, long-lasting makeup, and stability of the preparation.

[Example 16]
Moose Foundation <Preparation of cosmetics>
A: Components (7) to (16) were dispersed by a roll mill.
B: A, components (1) to (6) were uniformly mixed to obtain a mousse foundation.
(1) Trimethylsiloxysilicate composition (Note 28) 10
(2) Decamethylcyclopentasiloxane (Note 7) 11
(3) Ethylhexyl methoxycinnamate 2
(4) Silicone composite powder (Note 24) 2
(5) Polymethyl methacrylate 8
(6) Silicone treated talc (Note 30) Remaining amount (7) Dimethyl polysiloxane (Note 29) 9
(8) Partially crosslinked dimethylpolysiloxane composition (Note 16) 30
(9) Neopentyl glycol diethylhexanoate 5
(10) Silicone-alkyl branched polyglycerin-modified silicone (Note 1)
1
(11) Siliconized titanium oxide (average particle size: 0.25 μm) (Note 19)
5
(12) Silicone-treated yellow iron oxide (average primary particle size: 0.07 μm × 0.8 μm) (Note 19) 0.75
(13) Siliconized red iron oxide (average primary particle size: 0.08 μm × 0.7 μm) (Note 19) 0.14
(14) Siliconized black iron oxide (average primary particle size: 0.3 μm (Note 19)
0.01
(15) Metal-soap-treated fine particle titanium oxide (average primary particle diameter: 120 nm)
8
(16) Dimethyl silylated silicic anhydride (average primary particle size: 16 nm) (Note 31)
0.5
100.0% in total
(Note 31) Dimethyl silylated silicic anhydride (Aerosil R972: manufactured by Nippon Aerosil Co., Ltd.)
This mousse foundation had good feeling in use, elongation, long-lasting makeup, and stability of the preparation.

[Example 17]
Lipstick <Preparation of cosmetics>
A: Components (10) to (18) were dispersed by a roll mill.
B: Components (1) to (9) were uniformly mixed at 90 ° C.
D: A, (19) and (20) were added to B, mixed uniformly at 80 ° C., filled in a mold, and then gradually cooled to obtain a lipstick.
(1) Candelilla Row 3
(2) Polyethylene 2
(3) Microcrystalline wax 2.5
(4) Selesin 6
(5) Silicone wax (Note 32) 13
(6) Macadamia nut oil 23
(7) diisostearyl malate 7
(8) Hydrogenated polyisobutene 8.5
(9) Isotridecyl isononanoate 15
(10) Ethylhexyl methoxycinnamate 1.5
(11) Polyglyceryl-2 triisostearate 4.5
(12) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
2.5
(13) Red No. 201 0.4
(14) Red No. 202 0.4
(15) Yellow No. 4 1.6
(16) Siliconized titanium oxide (average primary particle size: 0.25 μm) (Note 19)
3
(17) Siliconized red iron oxide (average primary particle size: 0.08 μm × 0.7 μm) (Note 19) 0.7
(18) Siliconized black iron oxide (average primary particle size: 0.3 μm) (Note 19)
0.2
(19) Silicone treated talc (Note 29) 0.7
(20) Mica 4.5
100.0% in total
(Note 32) Silicone wax (KP-561: manufactured by Shin-Etsu Chemical Co., Ltd.)
This lipstick had good usability, elongation, color development, and formulation stability.

[Example 18]
W / O sunscreen <Preparation of cosmetics>
A: Components (1) to (9) were uniformly mixed, and then (10) was uniformly mixed with a disper.
B: Components (11) to (16) were uniformly mixed.
C: B was added to A and emulsified to obtain a sunscreen.
(1) Partially crosslinked polyether-modified silicone composition (Note 10) 3.5
(2) Silicone / alkyl branched polyether-modified silicone (Note 3)
1.5
(3) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
2.5
(4) Phenyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 9)
2
(5) Decamethylcyclopentasiloxane (Note 7) 14.5
(6) Ethylhexyl palmitate 6
(7) Ethylhexyl methoxycinnamate 7
(8) bisethylhexyloxyphenol methoxyphenyl triazine
1
(9) Diethylaminohydroxybenzoyl hexyl benzoate 2.5
(10) Fine particles of titanium oxide treated with metal soap (average primary particle diameter: 120 nm)
10
(11) Dipropylene glycol 4
(12) Ethanol 8
(13) Methyl paraben 0.1
(14) Sodium citrate 0.2
(15) Sodium chloride 1
(16) Water remaining
100.0% in total
This W / O sunscreen had good feeling in use, elongation, and stability of the preparation.

[Example 19]
W / O sunscreen <Preparation of cosmetics>
A: Components (1) to (9) were uniformly mixed, and then (10) was uniformly mixed with a disper.
B: Components (11) to (16) were uniformly mixed.
C: B was added to A and emulsified to obtain a sunscreen.
(1) Alkyl-modified / partially cross-linked polyether-modified silicone composition (Note 11)
3.5
(2) Silicone / alkyl branched polyglycerin-modified silicone (Note 1)
1.5
(3) Alkyl-branched polyether-modified silicone (Note 5) 1.5
(4) Alkyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 12)
3
(5) Decamethylcyclopentasiloxane (Note 7) 4
(6) Cetyl ethylhexanoate 6
(7) Octocrylene 6
(8) Polysilicone-153
(9) Dimethyl polysiloxane (2cs) 10.5
(10) Silicone-treated fine particle zinc oxide (average primary particle diameter: 30 nm)
18
(11) Dipropylene glycol 4
(12) Ethanol 8
(13) Ethylhexyl glycerin 0.1
(14) Sodium citrate 0.2
(15) Sodium chloride 0.5
(16) Water remaining
100.0% in total
The W / O sunscreen had good usability, elongation, and formulation stability.

Claims (3)

(A) lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone: 0.1 to 12% by mass, (b) powder: 0.1 to 45% by mass, (c) ultraviolet absorber: 6.5 to 20% by mass, (D) one or two or more oils selected from silicone oils and ester oils having a viscosity of 1 to 100 mm ² / s at 25 ° C .: 0.1 to 60% by mass; (I) A cosmetic composition comprising a dispersion preliminarily dispersed in an oil phase containing the (a) component and the (d) component or the (II) component (a), the (c) component and the (d) component. .   The cosmetic composition according to claim 1, which is an emulsion composition.   The cosmetic composition according to claim 1, which is a non-aqueous composition.