JP2020036690A - Diaper having enzyme battery mounted thereon - Google Patents
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- JP2020036690A JP2020036690A JP2018164350A JP2018164350A JP2020036690A JP 2020036690 A JP2020036690 A JP 2020036690A JP 2018164350 A JP2018164350 A JP 2018164350A JP 2018164350 A JP2018164350 A JP 2018164350A JP 2020036690 A JP2020036690 A JP 2020036690A
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Inert Electrodes (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Abstract
Description
本発明は、酵素電池が搭載されたおむつに関する。 The present invention relates to a diaper on which an enzyme battery is mounted.
近年、少子高齢社会化による医療費増大や労働力不足などが問題となっている。特に介護現場においては、慢性的な人手不足が問題となり労働環境の改善が急務となっている。さらに、介護作業の中でも、寝たきり患者や高齢者などに対する排泄ケアは介護者に体力的・精神的に過大な負担を負わせている。
通常、介護施設や病院などでは、排泄があった状態で患者を長時間放置することや、おむつ漏れによるシーツやベッドの汚染を防ぐため、定期的におむつの汚れ具合を確認し、おむつ交換がなされている。しかし、この確認作業には、排泄をしていない場合や、交換する必要がない場合も多分に含まれ、本来不必要なおむつ開閉作業や交換する必要のないおむつ交換作業が発生し、介護者への負担を大きくしている。
排尿の有無をセンサーなどによって検知できれば、不必要なおむつ開閉及び交換作業を軽減させることが可能となる。
In recent years, increasing medical expenses and labor shortages due to a declining birthrate and aging society have become problems. Particularly in the nursing care field, chronic labor shortage has become a problem, and there is an urgent need to improve the working environment. Furthermore, in nursing care work, excretion care for bedridden patients, the elderly and the like places an excessive burden on caregivers physically and mentally.
Normally, in nursing homes and hospitals, to prevent patients from leaving for a long time after excretion, and to prevent contamination of sheets and beds due to diaper leaks, regularly check the condition of dirt and change diapers. It has been done. However, this check often includes cases where the patient has not excreted or does not need to change the diaper. The burden on is increasing.
If the presence or absence of urination can be detected by a sensor or the like, unnecessary diaper opening / closing and replacement work can be reduced.
特許文献１および２では、おむつ内側表面に水分センサーを設置し排尿を検知する方法が開示されている。 Patent Documents 1 and 2 disclose a method of detecting a urination by installing a moisture sensor on the inner surface of a diaper.
しかしながら、特許文献１および２に記載の水分センサーは駆動に電源を別に必要とすることや、センサーに金属が使用されるため、電池交換の手間や廃棄時の分別の手間などが問題となる。さらに、排尿の回数をセンシング出来るが、排尿量（おむつ交換時期）を検知することは困難である。 However, the moisture sensors described in Patent Literatures 1 and 2 require a separate power supply for driving, and since metal is used for the sensor, there are problems such as trouble of battery replacement and separation of disposal. Furthermore, although the number of urinations can be sensed, it is difficult to detect the amount of urination (diaper replacement time).
また、シート電極を接合した酵素電池を股下に設置した場合、装着時や体位変更の際、足で酵素電池が押しつぶされて電池が変形し、通常に作動しない可能性がある。 In addition, when an enzyme battery to which a sheet electrode is bonded is installed in the crotch, the enzyme battery may be deformed by crushing the foot with a foot when the body is worn or the body position is changed, and the battery may not operate normally.
本発明者らは、前記課題を解決すべく検討を重ねた結果、本発明に至った。 The present inventors have repeatedly studied to solve the above-mentioned problems, and as a result, have reached the present invention.
すなわち本発明は、透液性のトップシートとバックシートとの間に吸水材と酵素電池とが存在するおむつであって、以下の条件（１）〜（３）のすべてを満たすおむつに関する。
（１）前記酵素電池が正極または負極の少なくとも一方に酵素を含有する。
（２）前記おむつを腹部、股下部、尻部と３分割した際、腹部または尻部に前記酵素電池が存在する。
（３）前記酵素電池が吸水層と接続され、吸水層が少なくとも股下部に配置されている。
That is, the present invention relates to a diaper in which a water-absorbing material and an enzyme battery exist between a liquid-permeable top sheet and a back sheet, and satisfy all of the following conditions (1) to (3).
(1) The enzyme battery contains an enzyme in at least one of a positive electrode and a negative electrode.
(2) When the diaper is divided into three parts, abdomen, crotch and buttocks, the enzyme battery is present in the abdomen and buttocks.
(3) The enzyme battery is connected to a water-absorbing layer, and the water-absorbing layer is arranged at least in a crotch portion.
また、本発明は、おむつの外部より供給された尿中の成分により発電しうる酵素を含有する上記おむつに関する。 In addition, the present invention relates to the diaper containing an enzyme capable of generating power by components in urine supplied from the outside of the diaper.
また、本発明は、さらに、酵素電池の内部または近傍に燃料を含有する上記おむつに関する。 In addition, the present invention further relates to the above-mentioned diaper containing a fuel inside or near the enzyme cell.
また、本発明は、前記酵素電池と酵素電池に接続された吸水層とが、以下のいずれかの位置にあることを特徴とする上記おむつに関する。
（１）トップシートと吸水材との間に位置する。
（２）バックシートと吸水材との間に位置する。
（３）吸水材内部に位置する。
Further, the present invention relates to the diaper, wherein the enzyme battery and the water absorbing layer connected to the enzyme battery are located at any one of the following positions.
(1) It is located between the top sheet and the water absorbing material.
(2) It is located between the back sheet and the water absorbing material.
(3) It is located inside the water absorbing material.
本発明の酵素電池を搭載したおむつを用いることで、電池交換の手間が無く、容易に廃棄が可能で、安定して排尿を検知できるおむつセンサーを提供することである。さらに、酵素電池と吸水層を調整することで、交換時期をセンシングできるおむつセンサーを提供する。 It is an object of the present invention to provide a diaper sensor that uses a diaper equipped with the enzyme battery of the present invention, can easily dispose of the battery without trouble of battery replacement, and can stably detect urination. Furthermore, a diaper sensor capable of sensing a replacement time by adjusting an enzyme battery and a water absorbing layer is provided.
以下、詳細に本発明について説明する。 Hereinafter, the present invention will be described in detail.
＜酵素電池を搭載したおむつ（トップシート、吸水材、バックシート）＞
本発明におけるおむつは、少なくとも透液性のトップシート、バックシート、吸収体を含むものである。トップシートは肌に直接接する部分で、不織布（ポリプロピレン、ポリエステル、レーヨンなど）や綿などからなり、排泄された尿を速やかに拡散、透過し、吸収体に送る役割を担う。吸水材は、綿状パルプ、高分子吸収剤、吸水紙などからなり、トップシートから流入した尿を吸水、保水する役割を担う。バックシートは、ポリエチレンフィルムなどからなり、防水機能を有し、尿などの漏れを防止する役割を担う。
<Diapers equipped with enzyme batteries (top sheet, water absorbing material, back sheet)>
The diaper according to the present invention includes at least a liquid-permeable top sheet, a back sheet, and an absorber. The top sheet is a part that is in direct contact with the skin and is made of non-woven fabric (polypropylene, polyester, rayon, etc.), cotton, or the like, and plays a role in promptly diffusing, transmitting, and transmitting excreted urine to the absorber. The water-absorbing material is made of cotton-like pulp, polymer absorbent, water-absorbing paper, etc., and plays a role of absorbing and retaining urine flowing from the top sheet. The back sheet is made of a polyethylene film or the like, has a waterproof function, and plays a role of preventing leakage of urine and the like.
酵素電池を搭載するおむつは、トップシートと吸水材とバックシートとを順に有し、酵素電池と酵素電池に接続された吸水層はトップシートとバックシートの間搭載されることが好ましい。つまり、トップシートと吸水材との間、吸水材とバックシートとの間、または吸水材の内部のいずれかの位置に酵素電池と酵素電池に接続された吸水層が搭載されることが好ましい。 The diaper on which the enzyme battery is mounted preferably has a top sheet, a water absorbing material, and a back sheet in this order, and the enzyme battery and the water absorbing layer connected to the enzyme battery are preferably mounted between the top sheet and the back sheet. That is, it is preferable that the enzyme battery and the water-absorbing layer connected to the enzyme battery be mounted at any position between the top sheet and the water absorbing material, between the water absorbing material and the back sheet, or inside the water absorbing material.
さらに、おむつを３分割し、人体に接触する名称からそれぞれの部位を、腹部、股下部、尻部とする。具体的には、図１のように、おむつの吸水材に注目し、吸水材の長手方向に対し垂直に３等分割して３つの部位とする。その際、腹部または尻部の部位に酵素電池が存在し、酵素電池に接続された吸水層が少なくとも股下部の位置に搭載される。このようにすることで、装着時や体位変更によって、酵素電池が押しつぶされて変形することを防ぐことができるほか、吸水層を搭載する位置や吸水層の形状や物性を制御することによって、おむつの交換時期（吸水材の限界値）に酵素電池に尿が到達し、発電することが可能となる。 Furthermore, the diaper is divided into three parts, and the respective parts are referred to as abdomen, crotch, and buttocks from the name that comes into contact with the human body. Specifically, as shown in FIG. 1, attention is paid to the water-absorbing material of the diaper, and it is divided into three equal parts perpendicularly to the longitudinal direction of the water-absorbing material to obtain three portions. At this time, an enzyme battery is present at the abdomen or butt, and a water-absorbing layer connected to the enzyme battery is mounted at least at the position of the crotch. In this way, it is possible to prevent the enzyme battery from being crushed and deformed by wearing or changing the body position, and by controlling the position where the water absorbing layer is mounted and the shape and physical properties of the water absorbing layer, the diaper The urine reaches the enzyme battery at the time of replacement (limit value of the water-absorbing material), and power can be generated.
＜酵素電池＞
酵素電池は、酵素が、糖やアルコール、有機酸等の多様な有機物を酸化し、アノード（負極）で電子及びイオンを発生させ、カソード（正極）側で酸素還元反応させることにより発電しうる発電デバイスである。
電源としての利用の外に、発電の有無や発電量を検知することにより、燃料となる有機物等を対象としたセンサーとして利用することも可能となる。
更に、酵素反応により発電した電力を用いて、同センサーを駆動させることにより、外部から電力供給不要な電源フリーのセンサーとして利用することが出来る。
尿中に含まれる有機物や水などの成分により起きる発電は、２通りがある。一つは、有機物が燃料として発電する場合であり、もう一つは、予め酵素電池の内部または近傍に燃料が位置され、尿中の水により、当該燃料が移動し、酵素と反応して発電する場合である。
すなわち、おむつに搭載して使用する場合は、尿中や尿糖、尿酸等の有機物を燃料及び／又はセンシング対象物として利用される。また、尿などの外部より供給される生体試料中に燃料として利用できる有機物を含まなくても、予め燃料となる有機物を酵素発電電池やおむつに内蔵することで、外部より供給された水分などの液体成分により、当該燃料が運ばれ、酵素と反応して発電することもできる。このように、本発明では酵素電池は電源としての利用と、センサーとしての利用、およびその両方としての利用が出来る。
酵素電池の構成としては、燃料を酸化するアノードと、酸素還元が起こるカソードと、アノードとカソードを分離するセパレータを含む。但し、アノードとカソードを電気的に分離することができればセパレータは必ずしもなくても構わない。また、アノードからカソード側にイオンを伝達するためのイオン伝導体を含んでいても良い。小型・軽量化や保存安定性等を考慮すると、燃料及び／又はセンシング対象物である尿中に含まれる電解質を使用する形態の酵素電池の方が好ましい場合がある。
アノードとカソードが完全に分離していない、非セパレータ系や紙等をセパレータに使用する形態の酵素電池においては、燃料等に含まれる不純物成分がカソード反応の酸素還元触媒を被毒する場合があり、活性低下、出力不安定化が生じやすいため注意が必要となる。特に白金等の貴金属触媒は被毒されやすいため同系においての使用は好ましくない場合がある。一方、貴金属を含まない酵素電池用炭素触媒はこれら貴金属触媒よりも被毒に強いため、不純物が存在する系においても好適に使用できる。
加えて、不織布やフェルト、紙など易廃棄なセパレータに直接アノード及びカソードを塗布し作製されるデバイスに対して、本発明に用いられる酵素電池用炭素触媒をカソードに使用すると、高価な貴金属や酸素還元酵素を使用せず低コストで、使い捨て可能（易廃棄、リサイクル不要など）なデバイスを実現することが可能となる。
<Enzyme battery>
Enzyme batteries generate electricity by oxidizing various organic substances such as sugars, alcohols, and organic acids, generating electrons and ions at the anode (negative electrode), and performing an oxygen reduction reaction at the cathode (positive electrode) side. Device.
In addition to the use as a power source, by detecting the presence or absence of power generation and the amount of power generation, it becomes possible to use the sensor as a sensor for organic substances or the like serving as fuel.
Further, by driving the sensor using the electric power generated by the enzymatic reaction, the sensor can be used as a power-free sensor that does not require external power supply.
There are two types of power generation caused by components such as organic substances and water contained in urine. One is the case where the organic matter generates power as fuel, and the other is where the fuel is previously located inside or near the enzyme cell, and the water moves in the urine to move the fuel and react with the enzyme to generate power. This is the case.
That is, when mounted on a diaper and used, organic substances such as urine, urine sugar, and uric acid are used as fuel and / or a sensing target. In addition, even if a biological sample supplied from the outside such as urine does not contain an organic substance that can be used as a fuel, the organic substance serving as a fuel can be incorporated in the enzymatic power generation battery or the diaper in advance so that the moisture supplied from the outside can be reduced. The liquid component carries the fuel and reacts with enzymes to generate electricity. Thus, in the present invention, the enzyme battery can be used as a power source, used as a sensor, and used as both.
The configuration of the enzyme cell includes an anode for oxidizing fuel, a cathode for oxygen reduction, and a separator for separating the anode and the cathode. However, a separator is not necessarily required as long as the anode and the cathode can be electrically separated. Further, an ion conductor for transmitting ions from the anode to the cathode side may be included. In consideration of reduction in size and weight, storage stability, and the like, an enzyme battery using an electrolyte contained in fuel and / or urine, which is a sensing target, may be preferable.
In an enzyme battery in which the anode and the cathode are not completely separated and non-separator type or paper is used for the separator, impurity components contained in the fuel and the like may poison the oxygen reduction catalyst of the cathode reaction. Attention must be paid to the fact that the activation is reduced and the output is unstable. In particular, noble metal catalysts such as platinum are easily poisoned, so that use in the same system may not be preferable. On the other hand, a noble metal-free carbon catalyst for an enzyme battery is more resistant to poisoning than these noble metal catalysts, and thus can be suitably used in a system containing impurities.
In addition, when a carbon catalyst for an enzyme battery used in the present invention is used for a cathode of a device manufactured by applying an anode and a cathode directly to an easily disposable separator such as nonwoven fabric, felt, and paper, expensive noble metals and oxygen It is possible to realize a low-cost, disposable (easy disposal, no need for recycling, etc.) device without using a reductase.
＜吸水層＞
吸水層は、水分を吸収、吸い上げることで、酵素電池（酵素電池用電極）に水分を伝達するものであれば特に限定されない。例えば、ポリエチレン繊維、ポリプロピレン繊維、ガラス繊維、樹脂不織布、ガラス不織布、フェルト、濾紙、和紙等を用いることができる。また、吸水層を延長して、後述するセパレータとして使用しても良く、吸水層とセパレータを接合して使用しても良い。
前記吸水材とは別に設置する。吸水材は、一旦、吸水した水を再放出しないのに対し、吸水層は、水を酵素電池へ伝達すべく水を再放出する点で機能が異なる。
吸水層と酵素電池との接続形態としては、セパレータを用いる場合は、吸水層とセパレータとが一体となる形態と、セパレータと吸収層と接合する形態が挙げられる。また、セパレータを用いない場合は電極と吸水層を接合する形態が挙げられる。接合方法は、後述する回路配線に記載する方法が挙げられる。
<Water absorption layer>
The water-absorbing layer is not particularly limited as long as it absorbs and absorbs moisture to transmit moisture to the enzyme battery (electrode for enzyme battery). For example, polyethylene fiber, polypropylene fiber, glass fiber, resin nonwoven fabric, glass nonwoven fabric, felt, filter paper, Japanese paper, and the like can be used. Further, the water-absorbing layer may be extended and used as a separator described later, or the water-absorbing layer and the separator may be joined and used.
Installed separately from the water absorbing material. The water absorbing material does not re-release the water once absorbed, whereas the water-absorbing layer functions differently in that it re-releases water to transfer the water to the enzyme battery.
When a separator is used, the form of connection between the water absorbing layer and the enzyme battery includes a form in which the water absorbing layer and the separator are integrated, and a form in which the separator and the absorbing layer are joined. In the case where the separator is not used, a mode in which the electrode and the water absorbing layer are joined is exemplified. Examples of the joining method include a method described in circuit wiring described below.
＜回路配線＞
回路配線は、酵素電池において正極および負極と外部デバイスを電気的に接続し、回路を形成するための導電性部材である。回路配線は、正極あるいは負極と別途用意された導電性部材を接続し更に外部デバイスに接続してもよく、正極あるいは負極の導電性支持体をそのまま延長して回路配線として外部デバイスと接続してもよい。回路配線と外部デバイスを接続する方法としては特に限定するものではなく、接着剤あるいは粘着剤による接続の他に、スナップボタン、マグネット、クリップ、ファスナー、マジックテープ（登録商標）等を用いた接続が例示できる。
回路配線の材料としては、導電性を有するものであれば特に限定するものではないが、易廃棄性などの観点から、非金属材料を用いることが好ましい。例えば、カーボンペーパーやカーボンクロス、カーボンフェルト等の導電性炭素材料の他、紙類、布類等の非導電性支持体に酵素電池回路配線用導電炭素組成物やポリアニリン、ポリアセチレン、ポリピロール、ポリチオフェン等の導電性高分子を塗布、乾燥したものやそれらを併用したものを用いてもよい。廃棄の容易さやコストの観点から非導電性支持体に酵素電池回路配線用導電炭素組成物を塗布、乾燥したものを用いた方が好ましい。特に非導電性支持体は折り曲げ可能な支持体であることが好ましい。更には、紙類の非導電性支持体に酵素電池回路配線用導電炭素組成物を塗布、乾燥したものを用いた方が好ましい。
<Circuit wiring>
The circuit wiring is a conductive member for electrically connecting a positive electrode and a negative electrode to an external device in an enzyme battery to form a circuit. The circuit wiring may be connected to an external device by connecting a separately prepared conductive member to the positive or negative electrode, and may be connected to an external device as a circuit wiring by extending the positive or negative conductive support as it is. Is also good. The method for connecting the circuit wiring and the external device is not particularly limited. In addition to the connection using an adhesive or an adhesive, a connection using a snap button, a magnet, a clip, a fastener, a magic tape (registered trademark), or the like is used. Can be illustrated.
The material of the circuit wiring is not particularly limited as long as it has conductivity, but it is preferable to use a nonmetallic material from the viewpoint of easy disposal. For example, in addition to conductive carbon materials such as carbon paper, carbon cloth, carbon felt, etc., conductive carbon compositions for enzyme battery circuit wiring, polyaniline, polyacetylene, polypyrrole, polythiophene, etc. A conductive polymer coated and dried or a combination thereof may be used. From the viewpoint of easy disposal and cost, it is preferable to use a non-conductive support on which a conductive carbon composition for circuit wiring of an enzyme battery is applied and dried. In particular, the non-conductive support is preferably a bendable support. Further, it is preferable to use a non-conductive support such as paper coated with a conductive carbon composition for enzyme battery circuit wiring and dried.
＜導電性支持体＞
酵素電池において、正極および負極に導電性支持体を用いても良い。酵素電池に用いる導電性支持体は、導電性を有する材料であれば特に限定は無い。カーボンペーパーやカーボンクロス等導電性の炭素材料からなる導電層や金属箔、金属メッシュ等が挙げられる。また、回路配線と同様に、紙類、布類等の非導電性支持体に酵素電池回路配線用導電炭素組成物やポリアニリン、ポリアセチレン、ポリピロール、ポリチオフェン等の導電性高分子を塗布、乾燥したものやそれらを併用したものを用いてもよい。前記組成物の塗布方法としては、特に限定されるものではなく、酵素電池用回路配線の作製の際に使用するような一般的な方法を適用できる。
廃棄の容易さやコストの観点から、非導電性支持体に酵素電池回路配線用導電炭素組成物を塗布、乾燥したものを用いた方が好ましい。特に非導電性支持体は折り曲げ可能な支持体であることが好ましい。更に、紙類の非導電性支持体に酵素電池回路配線用導電炭素組成物を塗布、乾燥したものを用いた方が好ましい。
<Conductive support>
In an enzyme battery, a conductive support may be used for the positive electrode and the negative electrode. The conductive support used in the enzyme battery is not particularly limited as long as it is a material having conductivity. Examples include a conductive layer made of a conductive carbon material such as carbon paper and carbon cloth, a metal foil, and a metal mesh. In addition, as in the case of the circuit wiring, a conductive polymer such as a conductive carbon composition for enzyme battery circuit wiring or a conductive polymer such as polyaniline, polyacetylene, polypyrrole, or polythiophene is applied to a non-conductive support such as paper or cloth and dried. Or a combination thereof may be used. The method for applying the composition is not particularly limited, and a general method used for producing a circuit wiring for an enzyme battery can be applied.
From the viewpoint of easy disposal and cost, it is preferable to use a non-conductive support obtained by applying and drying a conductive carbon composition for enzyme battery circuit wiring. In particular, the non-conductive support is preferably a bendable support. Further, it is preferable to use a non-conductive support such as paper which has been coated with a conductive carbon composition for enzyme battery circuit wiring and dried.
＜酵素電池回路配線用導電炭素組成物＞
酵素電池回路配線用導電炭素組成物は、少なくとも黒鉛やカーボンブラック、グラフェン系材料などの導電性炭素と、溶剤とバインダーを含む。また、酵素電池回路配線用導電炭素組成物は、必要に応じて分散剤、増粘剤、成膜助剤、消泡剤、レベリング剤、防腐剤、ｐＨ調整剤等を配合できる。導電性炭素及び溶剤とバインダー、分散剤の割合は、特に限定されるものではなく、広い範囲内で適宜選択され得る。ＶＯＣ排出の観点から、水あるいは水性溶剤を用いることが好ましく、それに伴いバインダーおよび分散剤等も水性であることが好ましい。
<Conductive carbon composition for enzyme battery circuit wiring>
The conductive carbon composition for enzyme battery circuit wiring contains at least conductive carbon such as graphite, carbon black, or a graphene-based material, a solvent, and a binder. Further, the conductive carbon composition for circuit wiring of an enzyme battery can optionally contain a dispersant, a thickener, a film-forming aid, a defoaming agent, a leveling agent, a preservative, a pH adjuster, and the like. The proportions of the conductive carbon and the solvent, the binder, and the dispersant are not particularly limited, and can be appropriately selected within a wide range. From the viewpoint of VOC emission, it is preferable to use water or an aqueous solvent, and accordingly, it is preferable that the binder and the dispersant are also aqueous.
＜酵素電池用負極＞
酵素電池用負極では、燃料の酸化反応により発生した電子をカソードに供給する。酵素電池用負極は、導電性支持体やセパレータ等の基材に前記酵素電池回路配線用導電炭素組成物や、導電性炭素材料や酵素電池用炭素触媒などのペーストを直接塗布し乾燥した塗膜や、転写基材などに前記酵素電池回路配線用導電炭素組成物を塗布し乾燥することにより形成された塗膜を支持体やセパレータ等に転写して作製した塗膜に酵素やメディエータを担持させたり、導電性支持体に酵素やメディエータを直接担持させたり、酵素を含む酵素電池回路配線用導電炭素組成物を支持体に塗布し乾燥したりして作製される。
前記組成物の塗布方法としては、特に限定されるものではなく、酵素電池用回路配線の作製の際に使用するような一般的な方法を適用できる。
酵素やメディエータを担持する方法は、上記組成物に含ませて行っても良いし、塗布後乾燥した塗膜や、導電性支持体に後から行っても良い。後から行う場合では、酵素やメディエータを溶解させた液を上記塗膜や、導電性支持体に浸漬等させた後、乾燥させて担持する方法等が使用できる。
<Negative electrode for enzyme battery>
In an anode for an enzyme battery, electrons generated by an oxidation reaction of a fuel are supplied to a cathode. A negative electrode for an enzyme battery is a coating film obtained by directly applying a paste such as the conductive carbon composition for an enzyme battery circuit wiring or a conductive carbon material or a carbon catalyst for an enzyme battery to a substrate such as a conductive support or a separator. Or, the enzyme or mediator is carried on a coating film prepared by transferring the coating film formed by applying and drying the conductive carbon composition for enzymatic battery circuit wiring on a transfer substrate or the like to a support or a separator. Alternatively, an enzyme or a mediator may be directly supported on a conductive support, or a conductive carbon composition for enzyme battery circuit wiring containing an enzyme may be applied to a support and dried.
The method for applying the composition is not particularly limited, and a general method used for producing a circuit wiring for an enzyme battery can be applied.
The method of supporting an enzyme or a mediator may be carried out by incorporating the composition into the above composition, or may be carried out later on a coating film dried after application or a conductive support. In the latter case, a method in which a solution in which an enzyme or a mediator is dissolved is immersed in the above-mentioned coating film or conductive support, and then dried and supported, can be used.
＜酵素電池負極用酵素＞
本発明における酵素としては、反応により電子を授受できる酵素であれば特に制限はなく、供給する燃料やコスト、デバイスの種類等に応じて適宜選択される。酵素としては、物質代謝など生体内での多くの酸化還元反応を触媒する酸化還元酵素が好ましい。
酵素電池の負極に用いる酵素は電子を放出できるものであればよく、糖や有機酸などのオキシダーゼやデヒドロゲナーゼなどが利用できる。中でも、他の酵素に比べ安価で、安定性が高く、人体の血液や尿などの生体試料に含まれるグルコースを燃料にできるグルコースオキシダーゼやグルコースデヒドロゲナーゼが好ましい場合がある。
<Enzyme for negative electrode of enzyme battery>
The enzyme in the present invention is not particularly limited as long as it is an enzyme capable of giving and receiving electrons by a reaction, and is appropriately selected according to the fuel to be supplied, the cost, the type of device, and the like. As the enzyme, an oxidoreductase that catalyzes many in vivo redox reactions such as substance metabolism is preferable.
The enzyme used for the negative electrode of the enzyme battery may be any enzyme that can emit electrons, and oxidases such as sugars and organic acids, dehydrogenases, and the like can be used. Among them, glucose oxidase and glucose dehydrogenase, which are inexpensive and highly stable as compared with other enzymes and can use glucose contained in biological samples such as human blood and urine as fuel, may be preferable.
＜メディエータ＞
酵素の種類によって、電極に直接電子を伝達できる直接電子移動型（ＤＥＴ型）酵素と直接電子を伝達できない酵素が存在する。ＤＥＴ型以外の酵素は、燃料の酸化によって生じた電子を酵素から電極（アノード）に伝達するまたは、アノードから受け取った電子を電極（カソード）から酵素に伝達する役割を担うメディエータと併用することが好ましい。メディエータとしては、電極と電子の授受ができる酸化還元物質であれば特に制限はなく、従来公知のものを使用できる。
メディエータの使用方法としては、電極に担持させる方法や電解液に溶解させて使用する方法等がある。メディエータとしては、テトラチアフルバレン、ハイドロキノンや１，４‐ナフトキノン等のキノン類、フェロセン、フェリシアン化物、オスミウム錯体、及びこれら化合物を修飾したポリマー等が例示できる。分別、廃棄の観点から非金属化合物が好ましい。
<Mediator>
Depending on the type of enzyme, there are direct electron transfer (DET) enzymes that can directly transfer electrons to the electrode, and enzymes that cannot transfer electrons directly. Enzymes other than the DET type can be used in combination with a mediator that transfers electrons generated by fuel oxidation from the enzyme to the electrode (anode), or transfers electrons received from the anode from the electrode (cathode) to the enzyme. preferable. The mediator is not particularly limited as long as it is an oxidation-reduction substance that can exchange electrons with the electrode, and a conventionally known one can be used.
Examples of the method of using the mediator include a method of supporting the electrode on an electrode and a method of dissolving it in an electrolytic solution. Examples of the mediator include quinones such as tetrathiafulvalene, hydroquinone and 1,4-naphthoquinone, ferrocene, ferricyanide, osmium complex, and polymers modified with these compounds. Non-metallic compounds are preferred from the viewpoint of separation and disposal.
＜酵素電池用正極＞
酵素電池用正極では、アノードで発生した電子を受け取り、電極中の還元反応によりこれを消費する。酵素電池用正極の構造としては、例えば、酸素を電子受容体として使用する酸素還元反応の場合では、反応場となる正極触媒の活性点まで電子及びプロトンの伝導パスや酸素の供給パスが確保されていることが効率的な発電を行う上では好ましい。 酵素電池用正極は、触媒に無機化合物を用いるものと酵素を用いるものがある。導電性支持体（カーボンペーパーや導電性カーボン層など）やセパレータ等の基材に正極触媒を含む組成物を直接塗布し乾燥することにより作製する方法や、転写基材などに前記組成物を塗布し乾燥することにより形成された塗膜を前記導電性支持体やセパレータ等に転写する方法等で作製される。また、正極触媒に酵素を用いるものは、酵素電池用負極と同様の方法で組成物作製、塗布を行ってもよい。
組成物の塗布方法としては、特に限定されるものではなく、例えば、ナイフコーター、バーコーター、ブレードコーター、スプレー、ディップコーター、スピンコーター、ロールコーター、ダイコーター、カーテンコーター、スクリーン印刷等の一般的な方法を適用できる。
<Positive electrode for enzyme battery>
The positive electrode for an enzyme battery receives electrons generated at the anode and consumes them by a reduction reaction in the electrode. As the structure of the cathode for an enzyme battery, for example, in the case of an oxygen reduction reaction using oxygen as an electron acceptor, a conduction path for electrons and protons and a supply path for oxygen are ensured up to the active point of the cathode catalyst serving as a reaction field. Is preferable for efficient power generation. The positive electrodes for enzyme batteries include those using an inorganic compound as a catalyst and those using an enzyme. A method in which a composition containing a positive electrode catalyst is directly applied to a substrate such as a conductive support (carbon paper or a conductive carbon layer) or a separator and then dried, or the composition is applied to a transfer substrate or the like. Then, the coating film formed by drying and transferring is transferred to the conductive support, the separator, or the like. In the case of using an enzyme for the positive electrode catalyst, the composition may be prepared and applied in the same manner as in the negative electrode for an enzyme battery.
The method for applying the composition is not particularly limited, and examples thereof include a general method such as a knife coater, a bar coater, a blade coater, a spray, a dip coater, a spin coater, a roll coater, a die coater, a curtain coater, and screen printing. Methods can be applied.
＜酵素電池正極用触媒＞
酵素電池正極で無機化合物を触媒として用いる場合、酸素還元触媒として貴金属触媒、卑金属酸化物触媒、酵素電池用炭素触媒などが挙げられる。コストの面などから炭素触媒が好ましい。
貴金属触媒とは、遷移金属元素のうちルテニウム、ロジウム、パラジウム、銀、オスミウム、イリジウム、白金、金から選択される元素を一種以上含む触媒である。これら貴金属触媒は単体でも別の元素や化合物に担持されたものでも良い。
卑金属酸化物触媒は、ジルコニウム、タンタル、チタン、ニオブ、バナジウム、鉄、マンガン、コバルト、ニッケル、銅、亜鉛、クロム、タングステン、およびモリブデンからなる群より選択された少なくとも１種の卑金属元素を含む酸化物を使用することができ、より好ましくはこれら卑金属元素の炭窒化物や、これら遷移金属元素の炭窒酸化物を使用することができる。
酵素電池用炭素触媒（以下、単に炭素触媒ともいう）とは、炭素元素を基本骨格とした炭素材料からなり、それらの構成単位間に物理的・化学的な相互作用（結合）を有し、異種元素、たとえばＮ、Ｂ、Ｐなどのヘテロ原子を含み、更に場合によって卑金属元素が含まれ酸素還元活性を有する触媒材料である。ここでいう卑金属元素とは、遷移金属元素のうち貴金属元素（ルテニウム、ロジウム、パラジウム、銀、オスミウム、イリジウム、白金、金）を除く金属元素であり、卑金属元素としては、コバルト、鉄、ニッケル、マンガン、銅、チタン、バナジウム、クロム、亜鉛、およびスズからなる群より選ばれる一種以上を含有することが好ましい。
ヘテロ元素と卑金属元素を含有することは、酸素還元活性を有する上で重要な意味をなす。酵素電池用炭素触媒は、その触媒活性点として、例えば、炭素材料の基本骨格を構成する炭素の六角網面のエッジ部に導入された窒素原子やその近傍の炭素原子、また触媒表面上に卑金属元素を中心に４個の窒素が平面上に並んだ卑金属−Ｎ４構造における窒素原子や卑金属原子などが挙げられる。
酵素電池用炭素触媒は、１種または２種以上の、炭素材料と、窒素元素および／または前記卑金属元素を含有する化合物とを混合し、熱処理を行い作製された炭素触媒であって、従来公知のものを使用できる。炭素触媒に用いられる炭素材料は、無機材料由来の炭素粒子および／または有機材料を熱処理して得られる炭素粒子であれば特に限定されない。
また、酵素を触媒として用いる場合、酵素電池の正極では電子を消費できる酵素であれば良く、ビリルビンオキシダーゼ、ラッカーゼ、アスコルビン酸オキシダーゼなどの還元酵素の一種で、分子状酸素の還元を触媒する酸素還元酵素を用いることが出来る。酸素還元酵素を使用する酵素電池用正極では、電位負荷や副反応における酵素の劣化により無機化合物の触媒より使用耐久性が低いことがある。
<Catalyst for enzyme battery positive electrode>
When an inorganic compound is used as a catalyst in the positive electrode of an enzyme battery, a noble metal catalyst, a base metal oxide catalyst, a carbon catalyst for an enzyme battery, and the like can be used as the oxygen reduction catalyst. A carbon catalyst is preferred from the viewpoint of cost and the like.
The noble metal catalyst is a catalyst containing one or more transition metal elements selected from ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold. These noble metal catalysts may be used alone or supported on another element or compound.
The base metal oxide catalyst is an oxide containing at least one base metal element selected from the group consisting of zirconium, tantalum, titanium, niobium, vanadium, iron, manganese, cobalt, nickel, copper, zinc, chromium, tungsten, and molybdenum. A carbonitride of these base metal elements and a carbonitride of these transition metal elements can be more preferably used.
A carbon catalyst for an enzyme battery (hereinafter also simply referred to as a carbon catalyst) is made of a carbon material having a carbon element as a basic skeleton, and has a physical / chemical interaction (bond) between its constituent units. The catalyst material has a heteroatom such as N, B, P and the like, and further contains a base metal element in some cases and has oxygen reduction activity. The term “base metal element” as used herein refers to a metal element excluding noble metal elements (ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold) among transition metal elements. As the base metal element, cobalt, iron, nickel, It is preferable to contain at least one selected from the group consisting of manganese, copper, titanium, vanadium, chromium, zinc, and tin.
The inclusion of a hetero element and a base metal element plays an important role in having oxygen reduction activity. Enzyme battery carbon catalysts have, for example, a nitrogen atom introduced at the edge of a hexagonal mesh plane of carbon constituting a basic skeleton of a carbon material or a carbon atom in the vicinity thereof, and a base metal on a catalyst surface as a catalytic active point. Examples include a nitrogen atom and a base metal atom in a base metal-N4 structure in which four nitrogen atoms are arranged on a plane centering on an element.
A carbon catalyst for an enzyme battery is a carbon catalyst prepared by mixing one or more kinds of a carbon material and a compound containing a nitrogen element and / or the base metal element and subjecting the mixture to a heat treatment. Can be used. The carbon material used for the carbon catalyst is not particularly limited as long as the carbon particles are obtained by heat-treating inorganic material-derived carbon particles and / or an organic material.
In addition, when an enzyme is used as a catalyst, any enzyme capable of consuming electrons can be used at the positive electrode of an enzyme battery, and is a type of reductase such as bilirubin oxidase, laccase, or ascorbate oxidase. Enzymes can be used. A positive electrode for an enzyme battery using an oxygen reductase may have lower use durability than an inorganic compound catalyst due to potential load or deterioration of the enzyme due to side reactions.
＜セパレータ＞
セパレータとしては、負極と正極を電気的に分離できる（短絡の防止）ものであれば、特に限定されず従来公知の材料を用いる事ができる。具体的には、ポリエチレン繊維、ポリプロピレン繊維、ガラス繊維、樹脂不織布、ガラス不織布、フェルト、濾紙、和紙等を用いることができる。また、正極と負極が十分な距離を保ち接触による短絡が無い構造を取るならば、セパレータを用いなくてもよい。
<Separator>
The separator is not particularly limited as long as it can electrically separate the negative electrode and the positive electrode (prevents short circuit), and a conventionally known material can be used. Specifically, polyethylene fiber, polypropylene fiber, glass fiber, resin nonwoven fabric, glass nonwoven fabric, felt, filter paper, Japanese paper, and the like can be used. Further, if the positive electrode and the negative electrode have a structure in which a sufficient distance is maintained and there is no short circuit due to contact, a separator may not be used.
＜イオン伝導体＞
本発明におけるイオン伝導体はアノードとカソードの間でイオンの伝導を行うものである。イオン伝導体の形態はイオン伝導性を有するものであれば特に限定されるものではない。イオン伝導体としては、リン酸塩やナトリウム塩など電解質が溶けている電解液や、固体のポリマー電解質などを使用しても良い。
電解質はおむつに予め内蔵して利用しても良いし、尿中に含まれる電解質を利用して、その両方でも良い。
<Ion conductor>
The ion conductor in the present invention conducts ions between the anode and the cathode. The form of the ion conductor is not particularly limited as long as it has ion conductivity. As the ionic conductor, an electrolyte in which an electrolyte such as a phosphate or a sodium salt is dissolved, a solid polymer electrolyte, or the like may be used.
The electrolyte may be incorporated in the diaper in advance or may be used by utilizing the electrolyte contained in urine.
＜燃料＞
本願の酵素電池を動作させるために必要な燃料としては、酵素で分解できる有機物であれば特に限定はされず、Ｄ−グルコース等の単糖類、デンプン等の多糖類、有機酸などの有機物であれば幅広く利用できる。
おむつに搭載された酵素電池を動作させる場合では、燃料となる一種以上の有機物を予め酵素電池若しくはおむつに内蔵し、尿の水分中に有機物が溶出、拡散することで酵素電池を動作させたり、尿中に含まれる一種以上の有機物、例えばグルコースなどを利用して酵素電池を動作させたり、燃料となる一種以上の有機物を予め酵素電池若しくはおむつに内蔵し、尿の水分中に溶出した前記有機物と、尿中に含まれる一種以上の有機物を利用して、酵素電池を動作させたりできる。
予め燃料を内蔵する場合では、糖等の固体の燃料が好ましい。またコストや汎用性の観点からグルコースを利用することが好ましい
<Fuel>
The fuel required to operate the enzyme battery of the present invention is not particularly limited as long as it is an organic substance that can be decomposed by an enzyme, and may be a monosaccharide such as D-glucose, a polysaccharide such as starch, or an organic substance such as an organic acid. Widely available.
When operating an enzyme battery mounted on a diaper, one or more organic substances serving as fuel are built in the enzyme battery or diaper in advance, and the organic substance is eluted and diffused in the water of urine to operate the enzyme battery, One or more organic substances contained in urine, for example, an enzyme battery is operated using glucose or the like, or one or more organic substances serving as fuel are previously incorporated in an enzyme battery or a diaper, and the organic substances eluted in the water of urine Then, an enzyme battery can be operated using one or more organic substances contained in urine.
In the case where the fuel is incorporated in advance, a solid fuel such as sugar is preferable. It is also preferable to use glucose from the viewpoint of cost and versatility
本発明における酵素電池を搭載したおむつでは前述の様に、尿の供給により酵素電池で発電した電力を用いた電源やセンサー（水分、有機物）として機能できる。使い方としては、従来の抵抗検知型などのセンサー用の電源として本発明の酵素電池を利用したり、電源及びセンサーとして本発明の酵素電池を１種類以上利用したりすることができる。 As described above, the diaper equipped with the enzyme battery according to the present invention can function as a power source or a sensor (moisture, organic matter) using power generated by the enzyme battery by supplying urine. As the usage, the enzyme battery of the present invention can be used as a power source for a conventional sensor such as a resistance detection type, or one or more enzyme batteries of the present invention can be used as a power source and a sensor.
また本発明における酵素電池を搭載したおむつでは、無線送信機と組み合わせ、センシング情報をワイヤレスで外部に送信する使い方ができる。
例えば、排尿センサーの場合、予め燃料を内蔵し尿中の水分をセンシング対象とし、また同時に水分を利用し発電し得られた電力で無線送信機を作動したり、予め燃料を内蔵し尿中の水分を利用し発電し得られた電力で無線送信機及び別方式の排尿センサーを作動したり、また、尿糖値センサーの場合、尿中の糖を燃料及びセンシング対象として利用し、得られた電力で無線送信機を作動したり、尿中の糖をセンシング対象として利用し、予め燃料を内蔵し尿中の水分を利用し発電し得られた電力で無線送信機を作動したりできる。
The diaper equipped with the enzyme battery according to the present invention can be used in combination with a wireless transmitter to wirelessly transmit sensing information to the outside.
For example, in the case of a urination sensor, a fuel is incorporated in advance and moisture in urine is to be sensed, and at the same time, a radio transmitter is operated with electric power obtained by using moisture to generate power, or a fuel is incorporated in advance and moisture in urine is measured. The wireless transmitter and another type of urination sensor are operated with the power obtained and generated, and in the case of a urine sugar level sensor, the sugar in urine is used as fuel and a sensing target, and the obtained power is used as the target. The wireless transmitter can be operated, or the sugar in urine can be used as a sensing target, and the wireless transmitter can be operated with electric power obtained by incorporating fuel in advance and using water in urine to generate power.
以下に、実施例により本発明をさらに具体的に説明するが、以下の実施例は本発明の権利範囲を何ら制限するものではない。なお、実施例および比較例における「部」は「質量部」、％は質量％を表す。 Hereinafter, the present invention will be described more specifically with reference to Examples. However, the following Examples do not limit the scope of the present invention. In Examples and Comparative Examples, "parts" represents "parts by mass", and% represents% by mass.
＜酵素電池回路配線用導電炭素組成物の作製＞
鱗状黒鉛ＣＢ−１５０（日本黒鉛社製）を１８部、ファーネスブラックＶＵＬＣＡＮ（登録商標）ＸＣ７２（ＣＡＢＯＴ社製）を４．５部、バインダーとしてエマルション型アクリル樹脂分散溶液（トーヨーケム社製：Ｗ-１６８）を３部（固形分５０％）、分散剤としてカルボキシメチルセルロース水溶液５０部（固形分２％）、溶剤として水４９．５部をミキサーに入れて混合し、更にサンドミルに入れて分散を行い、酵素電池回路配線用導電炭素組成物（１）を得た。
<Preparation of conductive carbon composition for enzyme battery circuit wiring>
18 parts of scaly graphite CB-150 (manufactured by Nippon Graphite), 4.5 parts of furnace black VULCAN (registered trademark) XC72 (manufactured by CABOT), and an emulsion-type acrylic resin dispersion solution (manufactured by Toyochem: W-168) as a binder. ) (50% solids), 50 parts of carboxymethylcellulose aqueous solution (2% solids) as a dispersant, and 49.5 parts of water as a solvent in a mixer, and further mixed in a sand mill for dispersion. A conductive carbon composition (1) for circuit wiring of an enzyme battery was obtained.
＜酵素電池用回路配線の作製＞
前記酵素電池回路配線用導電炭素組成物（１）を、基材となる定性ろ紙Ｎｏ．１（アドバンテック社製）上にドクターブレードを用いて塗布した後、加熱乾燥し、導電層の厚さが８０μｍとなるよう調整し、酵素電池用回路配線（１）を得た。
<Preparation of circuit wiring for enzyme battery>
The conductive carbon composition for circuit wiring of an enzyme battery (1) was prepared using a qualitative filter paper No. 1 (Advantech Co., Ltd.) was applied using a doctor blade, and then dried by heating to adjust the thickness of the conductive layer to 80 μm, thereby obtaining an enzyme battery circuit wiring (1).
＜酵素電池用導電性支持体の作製＞
酵素電池用回路配線と同様に、前記酵素電池回路配線用導電炭素組成物を、基材となる定性ろ紙Ｎｏ．１（アドバンテック社製）上にドクターブレードを用いて塗布した後、加熱乾燥し、導電層の厚さが８０μｍとなるよう調整した。長さ１２ｃｍ幅１０ｃｍの長方形に切り出したものを酵素電池用導電性支持体（１）とした。
<Preparation of conductive support for enzyme battery>
In the same manner as the enzyme battery circuit wiring, the conductive carbon composition for enzyme battery circuit wiring was prepared using the qualitative filter paper No. 1 (manufactured by Advantech Co., Ltd.) using a doctor blade, and then dried by heating to adjust the thickness of the conductive layer to 80 μm. A rectangular cutout having a length of 12 cm and a width of 10 cm was used as a conductive support (1) for an enzyme battery.
＜酵素電池用負極の作製＞
導電性支持体（１）の導電層部長さ２ｃｍ幅１０ｃｍ部分をテープでマスキングを行った。マスキング処理していない導電層部長さ１０ｃｍ幅１０ｃｍ部分を、導電性炭素材料としてファーネスブラックＶＵＬＣＡＮ（登録商標）ＸＣ７２（ＣＡＢＯＴ社製）の組成物をドクターブレードにより、加熱乾燥後の導電性炭素材料の目付け量が２ｍｇ/ｃｍ２となるように塗布した後、メディエータとしてテトラチアフルバレンのメタノール溶液と、負極触媒としてグルコースオキシダーゼ水溶液をそれぞれ滴下し、自然乾燥させた。その後、マスキングテープを剥がし、酵素電池用負極（１）を得た。
<Preparation of negative electrode for enzyme battery>
The conductive support (1) was masked with a tape at a portion where the length of the conductive layer was 2 cm and the width was 10 cm. A 10 cm long, 10 cm wide unmasked conductive layer portion was coated with a composition of furnace black VULCAN (registered trademark) XC72 (manufactured by CABOT) as a conductive carbon material using a doctor blade to form a conductive carbon material after heating and drying. After application so that the basis weight was 2 mg / cm 2 , a methanol solution of tetrathiafulvalene as a mediator and a glucose oxidase aqueous solution as a negative electrode catalyst were respectively added dropwise and air-dried. Thereafter, the masking tape was peeled off to obtain a negative electrode (1) for an enzyme battery.
＜酵素電池用炭素触媒の製造＞
［製造例１］
グラフェンナノプレートレットｘＧｎＰ−Ｃ−７５０（ＸＧｓｃｉｅｎｃｅ社製）と鉄フタロシアニン Ｐ−２６（山陽色素社製）を、質量比１／０．５（グラフェンナノプレートレット／鉄フタロシアニン）となるようにそれぞれ秤量し、乾式混合を行い、混合物を
得た。上記混合物を、アルミナ製るつぼに充填し、電気炉にて窒素雰囲気下、８００℃で２時間熱処理を行い、酵素電池用炭素触媒（１）を得た。
<Manufacture of carbon catalyst for enzyme batteries>
[Production Example 1]
Graphene nanoplatelet xGnP-C-750 (manufactured by XGscience) and iron phthalocyanine P-26 (manufactured by Sanyo Dyeing Co., Ltd.) were weighed so as to have a mass ratio of 1 / 0.5 (graphene nanoplatelet / iron phthalocyanine). Then, dry mixing was performed to obtain a mixture. The mixture was filled in an alumina crucible and heat-treated at 800 ° C. for 2 hours in a nitrogen atmosphere in an electric furnace to obtain a carbon catalyst (1) for an enzyme battery.
＜酵素電池用正極の作製＞
酵素電池用炭素触媒（１）４．８部、水性液状媒体として水４９．２部、更に分散剤としてカルボキシメチルセルロース水溶液４０部（固形分２％）をミキサーに入れて混合し、更にサンドミルに入れて分散した。その後、バインダーとしてエマルション型アクリル樹脂分散溶液（トーヨーケム社製：Ｗ−１６８）６部（固形分５０％）を加えミキサーで混合し、酵素電池正極用電極組成物（１）を得た。
その後、導電性支持体（１）の導電層部長さ２ｃｍ幅１０ｃｍ部分をテープでマスキングを行った。マスキング処理していない導電層部長さ１０ｃｍ幅１０ｃｍ部分に、酵素電池正極用電極組成物（１）を、ドクターブレードにより、乾燥後の酵素電池用炭素触媒の目付け量が２ｍｇ/ｃｍ２となるように塗布し、待機雰囲気中９５℃、６０分間乾燥した後、マスキングテープを剥がし、酵素電池用正極（１）を得た。
<Preparation of positive electrode for enzyme battery>
4.8 parts of a carbon catalyst for an enzyme battery (1), 49.2 parts of water as an aqueous liquid medium, and 40 parts of a carboxymethylcellulose aqueous solution (2% solid content) as a dispersant are mixed in a mixer, and further mixed in a sand mill. And dispersed. Thereafter, 6 parts (solid content: 50%) of an emulsion type acrylic resin dispersion solution (manufactured by Toyochem Corporation: W-168) was added as a binder and mixed with a mixer to obtain an electrode composition (1) for a positive electrode of an enzyme battery.
Thereafter, the conductive layer portion of the conductive support (1) was masked with a tape at a length of 2 cm and a width of 10 cm. The electrode composition for a positive electrode of an enzyme battery (1) is applied to a portion of the conductive layer portion, which has not been subjected to the masking treatment, to a length of 10 cm and a width of 10 cm by a doctor blade so that the basis weight of the dried carbon catalyst for the enzyme battery is 2 mg / cm 2. After drying at 95 ° C. for 60 minutes in a standby atmosphere, the masking tape was peeled off to obtain a positive electrode (1) for an enzyme battery.
＜酵素電池の作製＞
上記作製した酵素電池用回路配線、同正極、同負極に加えて、燃料となるグルコース、イオン伝導体となる塩化ナトリウムを担持したろ紙を長さ２５ｃｍ幅１１ｃｍに切出し、吸水層とセパレータを兼ねた。マスキング処理を行った正極と負極および上記ろ紙を貼り合わせ、酵素電池（１）を作製した。マスキング処理を行った箇所を導電性支持体、酵素電池から長さ方向にはみ出したろ紙を吸水層として使用した。
<Preparation of enzyme battery>
In addition to the above-prepared circuit wiring for the enzyme battery, the same positive electrode, and the same negative electrode, a filter paper supporting glucose serving as a fuel and sodium chloride serving as an ionic conductor was cut into a length of 25 cm and a width of 11 cm, which also served as a water absorbing layer and a separator. . The masked positive electrode and negative electrode and the filter paper were stuck together to produce an enzyme battery (1). The portion where the masking treatment was performed was used as a water-absorbing layer using a filter paper that protruded in the length direction from the conductive support and the enzyme battery.
［実施例１〜４、比較例１〜２］
＜酵素電池が搭載されたおむつの作製＞
トップシート、吸水材、およびバックシートからなる介護用おむつ（ライフリー４回分吸収用（１５０ｍｌ×４回）ユニ・チャーム社製）を解体し、表１に示す位置に、上記で作製した酵素電池（１）をそれぞれに設置した後、元に戻し酵素電池が搭載されたおむつ（１）〜（６）を作製した。
[Examples 1 to 4, Comparative Examples 1 and 2]
<Production of diapers equipped with enzyme batteries>
The nursing diaper composed of a top sheet, a water-absorbing material, and a back sheet (for four times of lifely absorption (150 ml × 4 times, manufactured by Unicharm Co., Ltd.)) was dismantled, and the enzyme battery ( After each of 1) was installed, the diapers (1) to (6) were returned to the original state and mounted with an enzyme battery.
＜無線通信回路＞
上記作製した酵素電池について、昇圧コンバーター（ＬＴＣ３１０８ ストロベリーリナックス（登録商標）社製）、無線機（送信モジュール ＩＭ３１５ＴＸ、受信モジュール ＩＭ３１５ＲＸ インタープラン社製）を、おむつ内の酵素電池から昇圧コンバーターへ接続し、昇圧コンバーターから無線機の送信モジュールに接続、更に送信モジュールから発信された無線信号を無線機の無線モジュールで受信する無線通信回路を構築した。酵素電池正極（１）および負極（１）から昇圧コンバーターへの接続は、回路配線（１）を貼り合わせて行った。
<Wireless communication circuit>
For the enzyme battery prepared above, a boost converter (LTC3108 made by Strawberry Linux (registered trademark)) and a wireless device (transmitting module IM315TX, receiving module IM315RX manufactured by Interplan) are connected from the enzyme battery in the diaper to the boost converter, A wireless communication circuit was connected from the boost converter to the transmission module of the wireless device, and further, the wireless signal transmitted from the transmission module was received by the wireless module of the wireless device. The connection from the positive electrode (1) and the negative electrode (1) of the enzyme battery to the boost converter was performed by bonding the circuit wiring (1).
＜酵素電池が搭載されたおむつの無線送信の評価＞
作製したおむつを仰向けに寝かせたマネキンに装着した。股下部に尿中の水分を模擬して、超純水１５０ｍｌ投入し、これを4回繰り返し行った。結果を表１に示す。本発明の酵素電池が搭載されたおむつにおいては、超純水を計６００ｍｌ投入後、受信モジュールで信号の受信が確認されたが、比較例１および比較例２では受信モジュールで信号の受信が確認されなかった。
実施例１〜４では、水の投入によって、吸水層に水分が吸収、濡れ広がり、水を4回投入することによって、水が酵素電池まで到達する。さらに、ろ紙内のグルコース及び塩化ナトリウムが溶解、拡散し、それぞれ燃料およびイオン伝導体として機能し酵素電池が発電していることを示している。
一方、比較例１では、股下部に酵素電池を設置したため、装着時に酵素電池に負荷がかかり、電池の変形によって、正極と負極および吸水層（セパレータ）の極間距離が部分的に広がったため、イオン拡散が阻害されたため、発電量が十分でなかったと想定される。
また、比較例２では、股下部に吸水層を設置しなかったため、投入した水の殆どがおむつの吸水材に吸収され、酵素電池まで水が濡れ広がらず、発電出来なかったためと想定される。
<Evaluation of wireless transmission of diapers equipped with enzyme batteries>
The prepared diaper was attached to a mannequin lying on its back. The water in the urine was simulated in the crotch, 150 ml of ultrapure water was charged, and this was repeated four times. Table 1 shows the results. In the diaper equipped with the enzyme battery of the present invention, the reception of the signal was confirmed by the receiving module after a total of 600 ml of ultrapure water was injected. However, in the comparative examples 1 and 2, the reception of the signal was confirmed by the receiving module. Was not done.
In Examples 1 to 4, water is absorbed into the water-absorbing layer and spreads by the introduction of water, and water reaches the enzyme battery by introducing water four times. Furthermore, it shows that glucose and sodium chloride in the filter paper are dissolved and diffused, function as a fuel and an ion conductor, respectively, and the enzyme battery is generating power.
On the other hand, in Comparative Example 1, since the enzyme battery was installed in the crotch, a load was applied to the enzyme battery at the time of attachment, and the distance between the positive electrode, the negative electrode, and the water absorbing layer (separator) was partially widened due to the deformation of the battery. It is assumed that the power generation was not sufficient because the ion diffusion was inhibited.
In Comparative Example 2, it is assumed that the water absorption layer was not provided at the crotch part, so that most of the input water was absorbed by the water absorbing material of the diaper, the water did not spread to the enzyme battery, and power generation was not possible.
以上の結果から、尿中の成分（水分や有機物）でおむつ内に搭載された酵素電池が安定的に駆動可能であることが明らかとなった。また同時に、電源不要で且つ、廃棄も容易で生体に安全な材料で構成された排尿センサーを搭載されたおむつが実現でき、また、発電した電力で送信機が動作することで、センシング情報をワイヤレス、例えば、受信機や携帯端末などに送信できることが可能になる。 From the above results, it was clarified that the enzyme battery mounted in the diaper can be stably driven by the components (moisture and organic substances) in urine. At the same time, it is possible to realize a diaper equipped with a urination sensor made of a material that does not require a power source, is easy to dispose of, and is safe for living organisms. For example, transmission to a receiver, a portable terminal, or the like can be performed.
１・・・おむつ、２・・・吸水材、２１・・・吸水材腹部、２2・・・吸水材股下部、２３・・・吸水材尻部、３・・・トップシート、４・・・バックシート、５・・・酵素電池、５１・・・正極、５２・・・負極、５３・・・導電性支持体、６・・・吸水層、７・・・無線送信機、８・・・外装シート DESCRIPTION OF SYMBOLS 1 ... diaper, 2 ... water absorption material, 21 ... water absorption material belly, 22 ... water absorption material crotch, 23 ... water absorption material buttocks, 3 ... top sheet, 4 ... Back sheet, 5 ... Enzyme battery, 51 ... Positive electrode, 52 ... Negative electrode, 53 ... Conductive support, 6 ... Water absorbing layer, 7 ... Wireless transmitter, 8 ... Exterior sheet
Claims (4)
（１）前記酵素電池が正極または負極の少なくとも一方に酵素を含有する。
（２）前記おむつを腹部、股下部、尻部と３分割した際、腹部または尻部に前記酵素電池が存在する。
（３）前記酵素電池が吸水層と接続され、吸水層が少なくとも股下部に配置されている。 A diaper in which a water-absorbing material and an enzyme battery exist between a liquid-permeable top sheet and a back sheet, and satisfy all of the following conditions (1) to (3).
(1) The enzyme battery contains an enzyme in at least one of a positive electrode and a negative electrode.
(2) When the diaper is divided into three parts, abdomen, crotch and buttocks, the enzyme battery is present in the abdomen and buttocks.
(3) The enzyme battery is connected to a water-absorbing layer, and the water-absorbing layer is arranged at least in a crotch portion.
（１）トップシートと吸水材との間に位置する。
（２）バックシートと吸水材との間に位置する。
（３）吸水材内部に位置する。 The diaper according to any one of claims 1 to 3, wherein the enzyme battery and the water-absorbing layer connected to the enzyme battery are located at any of the following positions.
(1) It is located between the top sheet and the water absorbing material.
(2) It is located between the back sheet and the water absorbing material.
(3) It is located inside the water absorbing material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018164350A JP2020036690A (en) | 2018-09-03 | 2018-09-03 | Diaper having enzyme battery mounted thereon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018164350A JP2020036690A (en) | 2018-09-03 | 2018-09-03 | Diaper having enzyme battery mounted thereon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2020036690A true JP2020036690A (en) | 2020-03-12 |
Family
ID=69737530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018164350A Pending JP2020036690A (en) | 2018-09-03 | 2018-09-03 | Diaper having enzyme battery mounted thereon |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2020036690A (en) |
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2018
- 2018-09-03 JP JP2018164350A patent/JP2020036690A/en active Pending
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