JP2020015662A5 - - Google Patents

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JP2020015662A5
JP2020015662A5 JP2019190646A JP2019190646A JP2020015662A5 JP 2020015662 A5 JP2020015662 A5 JP 2020015662A5 JP 2019190646 A JP2019190646 A JP 2019190646A JP 2019190646 A JP2019190646 A JP 2019190646A JP 2020015662 A5 JP2020015662 A5 JP 2020015662A5
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optical glass
content
glass according
cation
less
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JP2019190646A
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JP2020015662A (en
JP7219199B2 (en
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Claims (13)

フツリン酸ガラスからなる光学ガラスであって、
NaOH水溶液中に15時間浸漬したときの単位面積当たりの質量減少量DNaOHが0.25mg/(cm・15h)未満であり、かつ
アッベ数νdと部分分散比Pg,Fとが下記(4)式:
Pg,F > −0.0004νd+0.5718 ・・・(4)
を満たす光学ガラス。
Optical glass made of borosilicate glass
Weight loss D NaOH per unit area when immersed for 15 hours in a NaOH aqueous solution is less than 0.25mg / (cm 2 · 15h) , and the Abbe number νd and partial dispersion ratio Pg, and the F below (4 )formula:
Pg, F> -0.0004νd + 0.5718 ... (4)
Optical glass that meets.
NbNb 5+5+ を1.0カチオン%以上含む、請求項1に記載の光学ガラス。The optical glass according to claim 1, which contains 1.0 cation% or more. AlAl 3+3+ およびNbAnd Nb 5+5+ を合計で10カチオン%以上含む、請求項1または2に記載の光学ガラス。The optical glass according to claim 1 or 2, which contains 10 cation% or more in total. O 2−2- の含有量が10〜85アニオン%であり、かつFContent is 10 to 85 anion% and F の含有量が15〜90アニオン%である、請求項1〜3のいずれか1項に記載の光学ガラス。The optical glass according to any one of claims 1 to 3, wherein the content of the optical glass is 15 to 90 anion%. MgMg 2+2+ 、Ca, Ca 2+2+ 、Sr, Sr 2+2+ およびBaAnd Ba 2+2+ からなる群から選ばれるアルカリ土類金属成分を少なくとも一種含み、かつMgContains at least one alkaline earth metal component selected from the group consisting of Mg 2+2+ 、Ca, Ca 2+2+ 、Sr, Sr 2+2+ およびBaAnd Ba 2+2+ の合計含有量が20カチオン%以上である、請求項1〜4のいずれか1項に記載の光学ガラス。The optical glass according to any one of claims 1 to 4, wherein the total content of the optical glass is 20 cation% or more. P 5+5+ およびNbAnd Nb 5+5+ の合計含有量に対するOO for the total content of 2−2- の含有量のモル比(OMolar ratio of content (O) 2−2- /(P/ (P 5+5+ +Nb+ Nb 5+5+ ))が3.0以上である、請求項1〜5のいずれか1項に記載の光学ガラス。)) Is 3.0 or more, the optical glass according to any one of claims 1 to 5. P 5+5+ の含有量が5〜40カチオン%であり、かつAlThe content of is 5 to 40 cation% and Al. 3+3+ の含有量が5〜40カチオン%である、請求項1〜6のいずれか1項に記載の光学ガラス。The optical glass according to any one of claims 1 to 6, wherein the content of the optical glass is 5 to 40 cation%. LaLa 3+3+ 、Gd, Gd 3+3+ 、Y, Y 3+3+ 、Lu, Lu 3+3+ およびYbAnd Yb 3+3+ からなる群から選ばれる希土類成分を少なくとも一種含み、かつAlContains at least one rare earth component selected from the group consisting of Al 3+3+ の含有量に対するLaLa for the content of 3+3+ 、Gd, Gd 3+3+ 、Y, Y 3+3+ 、Lu, Lu 3+3+ およびYbAnd Yb 3+3+ の合計含有量のモル比((LaMole ratio of total content of ((La) 3+3+ +Gd+ Gd 3+3+ +Y+ Y 3+3+ +Lu+ Lu 3+3+ +Yb+ Yb 3+3+ )/Al) / Al 3+3+ )が0.3以下である、請求項1〜7のいずれか1項に記載の光学ガラス。The optical glass according to any one of claims 1 to 7, wherein) is 0.3 or less. アルカリ金属成分の含有量が1カチオン%以上であり、かつLiThe content of the alkali metal component is 1 cation% or more, and Li の含有量が20カチオン%以下である、請求項1〜8のいずれか1項に記載の光学ガラス。The optical glass according to any one of claims 1 to 8, wherein the content of the optical glass is 20 cation% or less. 原子%で表示されるガラス組成において、AlIn the glass composition expressed in atomic%, Al 3+3+ の含有量に対するOO for the content of 2−2- の含有量の比(OContent ratio of (O 2−2- /Al/ Al 3+3+ )が10未満である、請求項1〜9のいずれか1項に記載の光学ガラス。) Is less than 10, the optical glass according to any one of claims 1 to 9. アッべ数νdが45以上である、請求項1〜10のいずれか1項に記載の光学ガラス。The optical glass according to any one of claims 1 to 10, wherein the abbe number νd is 45 or more. 下記(1)〜(4):The following (1) to (4):
(1)波長400nm〜700nm、厚さ10mmにおける内部透過率が96.5%以上、(1) Internal transmittance of 96.5% or more at a wavelength of 400 nm to 700 nm and a thickness of 10 mm.
(2)D(2) D A が0.35%未満、Is less than 0.35%,
(3)D(3) D STPPSTPP が0.40mg/(cmIs 0.40 mg / (cm 2 ・h)未満、・ Less than h)
(4)D(4) D 0 が5.0×10Is 5.0 × 10 −3-3 mg/(cmmg / (cm 2 ・h)未満、・ Less than h)
の少なくとも1つを満たす、請求項1〜11のいずれか1項に記載の光学ガラス。The optical glass according to any one of claims 1 to 11, which satisfies at least one of the above.
請求項1〜12のいずれか1項に記載の光学ガラスからなる光学素子。 The optical element made of the optical glass according to any one of claims 1 to 12.
JP2019190646A 2017-03-31 2019-10-18 Optical glasses and optical elements Active JP7219199B2 (en)

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JP2017069885 2017-03-31
JP2017069885 2017-03-31
JP2017249428 2017-12-26
JP2017249428 2017-12-26

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JP2020015662A JP2020015662A (en) 2020-01-30
JP2020015662A5 true JP2020015662A5 (en) 2021-02-25
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CN113912290A (en) * 2018-05-10 2022-01-11 Hoya株式会社 Optical glass and optical element
WO2021039815A1 (en) * 2019-08-30 2021-03-04 株式会社ニコン Optical system, optical device, and method for manufacturing optical system
WO2021039814A1 (en) * 2019-08-30 2021-03-04 株式会社ニコン Optical system, optical device, and method for manufacturing optical system
TW202112690A (en) 2019-09-27 2021-04-01 日商Hoya股份有限公司 Optical glass and optical element capable of reducing occurrence of streaks while being manufactured and suitable for chromatic aberration correction
CN111995247B (en) 2020-09-08 2022-04-15 成都光明光电股份有限公司 Optical glass, optical preform, optical element and optical instrument
CN112811815B (en) * 2021-01-21 2022-04-12 成都光明光电股份有限公司 Optical glass, glass preform, optical element and optical instrument
CN114804622B (en) * 2021-01-21 2023-08-01 成都光明光电股份有限公司 Near infrared special dispersion glass

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DE2514017C2 (en) * 1975-03-29 1984-03-29 Ernst Leitz Wetzlar Gmbh, 6330 Wetzlar Process for the production of a fluorophosphate optical glass with a high positive anomalous partial dispersion, a relatively high refractive index and a high Abbe number
JPS604145B2 (en) * 1981-01-20 1985-02-01 株式会社ニコン fluoride phosphate optical glass
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JPS6296346A (en) * 1985-10-19 1987-05-02 エルンスト ライツ ヴエツラ− ゲセルシヤフトミツト ベシユレンクテル ハフツング Optical fluophosphate glass with extraordinary positive partial dispersion and manufacture
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