JP2019202515A - Method for manufacturing decorative molded product - Google Patents

Method for manufacturing decorative molded product Download PDF

Info

Publication number
JP2019202515A
JP2019202515A JP2018100593A JP2018100593A JP2019202515A JP 2019202515 A JP2019202515 A JP 2019202515A JP 2018100593 A JP2018100593 A JP 2018100593A JP 2018100593 A JP2018100593 A JP 2018100593A JP 2019202515 A JP2019202515 A JP 2019202515A
Authority
JP
Japan
Prior art keywords
molded product
decorative
film
base material
resin plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2018100593A
Other languages
Japanese (ja)
Other versions
JP7063725B2 (en
Inventor
正宏 中見
Masahiro Nakami
正宏 中見
久崇 鈴木
Hisataka Suzuki
久崇 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bando Chemical Industries Ltd
Original Assignee
Bando Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bando Chemical Industries Ltd filed Critical Bando Chemical Industries Ltd
Priority to JP2018100593A priority Critical patent/JP7063725B2/en
Publication of JP2019202515A publication Critical patent/JP2019202515A/en
Application granted granted Critical
Publication of JP7063725B2 publication Critical patent/JP7063725B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Abstract

To provide a method for manufacturing a decorative molded product capable of obtaining a decorative molded product that is less susceptible to the influence of surface roughness of a base material and a quality of the base material, and excels in smoothness of the surface.SOLUTION: A method for manufacturing a decorative molded product in which a decorative film is pasted on a surface of a base material includes: a decoration step for vacuum pressure molding in a state in which the base material, the decorative film, and a resin plate are piled up in this order; and a step for removing the resin plate placed on the decorative film and pasted on the base material after the decoration step. The resin plate has an arithmetic average roughness of a surface in contact with the decorative film of 0.1 μm or less, and an elastic modulus at a molding temperature of the vacuum pressure molding of 30 MPa or more.SELECTED DRAWING: Figure 1

Description

本発明は、加飾成形品の製造方法に関するものである。 The present invention relates to a method for producing a decorative molded product.

従来、意匠面を有するフィルムを成形品に貼り付けることによって、成形品に色彩、模様、図柄、文字等の意匠を付与し、加飾することが行われている。加飾成形品の製造方法としては、真空成形や真空圧空成形等を用いて加飾フィルムを貼り付ける方法等が知られている(例えば、特許文献1等)。 Conventionally, by attaching a film having a design surface to a molded product, a design such as a color, a pattern, a design, or a character is imparted to the molded product and decorated. As a method for producing a decorative molded product, a method of attaching a decorative film using vacuum forming, vacuum pressure forming, or the like is known (for example, Patent Document 1).

特許文献1には、延伸可能な剥離フィルムの一方の面に接着剤層が配置されてなる接着シートを、真空成形、圧空成形または真空・圧空成形により、前記接着剤層が凹凸成形品側に配置されるように、前記凹凸成形品の表面に積層する積層工程(1)を有する、積層成形品の製造方法が開示されている。 In Patent Document 1, an adhesive sheet in which an adhesive layer is disposed on one surface of a stretchable release film is subjected to vacuum forming, pressure forming, or vacuum / pressure forming so that the adhesive layer is placed on the uneven molded product side. A method for manufacturing a laminated molded product is disclosed, which includes a laminating step (1) of laminating on the surface of the uneven molded product so as to be arranged.

特開2015−196289号公報Japanese Patent Application Laid-Open No. 2015-196289

加飾フィルムを成形品(基材)の表面に貼り付けて加飾成形品を製造する際に、基材の表面が粗いと、上記基材表面の粗さの程度によっては、基材の表面の凹凸に応じて加飾成形品の表面にも凹凸が生じ、外観の意匠性を損なうことがあった。基材表面の粗さを小さくするためには、基材を形成するための金型の仕上げ精度を上げたり、基材の表面を平滑に加工してから加飾フィルムを貼り付けたりすることが考えられるが、製造工程が増える、コストが上がる等の制約がかかってしまう。 When a decorative film is manufactured by attaching a decorative film to the surface of a molded product (base material), the surface of the base material is rough depending on the degree of roughness of the base material surface. Depending on the unevenness, the surface of the decorative molded product also has unevenness, which may impair the appearance design. In order to reduce the roughness of the substrate surface, it is possible to increase the finishing accuracy of the mold for forming the substrate, or to apply a decorative film after smoothing the surface of the substrate Although conceivable, there are restrictions such as an increase in manufacturing process and cost.

また、キッチン等の建築部材料には、木質繊維を原料とする中密度繊維板(MDF)等の成型板が用いられることがあるが、MDFは、表面が滑らかであったとしても、基材が柔らかく、かつ密度差があるために、加圧された際に密度が低い部分が凹み、基材の表面に凹凸が生じて、加飾成形品の外観の意匠性を損なうことがあった。 In addition, a molding plate such as a medium density fiberboard (MDF) made of wood fiber may be used as a building material for a kitchen or the like, but even if the surface of the MDF is smooth, Because of the softness and the difference in density, when the pressure is applied, the portion with low density is recessed, and the surface of the base material is uneven, which may impair the design of the appearance of the decorative molded product.

本発明は上記現状に鑑みてなされたものであり、基材表面の粗さ及び基材の材質の影響を受け難く、表面の平滑性に優れた加飾成形品が得られる加飾成形品の製造方法を提供することを目的とする。 The present invention has been made in view of the above-mentioned present situation, and is a decorative molded product that is hardly affected by the roughness of the substrate surface and the material of the substrate, and that provides a decorative molded product with excellent surface smoothness. An object is to provide a manufacturing method.

本発明者らは、基材と加飾フィルムとを積層して、真空状態で加圧して加飾フィルムを基材に貼り付ける真空圧空成形を行う際に、上記加飾フィルム上に表面が平滑であり、成形温度において所定の弾性率を有する樹脂板を重ねて成形することで、上記樹脂板面によって、加飾フィルムの表面に対して均一に圧力をかけることができるため、基材表面の粗さ及び基材の材質に関わらず、表面の平滑性に優れた加飾成形品が得られることを見出し、本発明を完成した。 The present inventors laminated the base material and the decorative film, and when performing vacuum / pressure forming to apply the decorative film to the base material by applying pressure in a vacuum state, the surface is smooth on the decorative film. Since it is possible to apply pressure uniformly to the surface of the decorative film by the resin plate surface by forming the resin plate having a predetermined elastic modulus at the molding temperature, The present invention has been completed by finding that a decorative molded product having excellent surface smoothness can be obtained regardless of the roughness and the material of the substrate.

本発明の加飾成形品の製造方法は、基材の表面に加飾フィルムが貼り付けられた加飾成形品の製造方法であって、上記基材、上記加飾フィルム及び樹脂板をこの順で重ねた状態で、真空圧空成形を行う加飾工程と、上記加飾工程の後に、上記基材に貼り付けられた上記加飾フィルム上に載せられた上記樹脂板を取り除く工程とを有し、上記樹脂板は、上記加飾フィルムと接する面の算術平均粗さが0.1μm以下であり、上記真空圧空成形の成形温度における弾性率が30MPa以上であることを特徴とする。 The method for producing a decorative molded product of the present invention is a method for producing a decorative molded product in which a decorative film is attached to the surface of a base material, and the base material, the decorative film and the resin plate are arranged in this order. In a state of being stacked in a vacuum pressure-air forming process, and after the decoration process, the process of removing the resin plate placed on the decorative film affixed to the base material The resin plate has an arithmetic average roughness of a surface in contact with the decorative film of 0.1 μm or less, and an elastic modulus at a molding temperature of the vacuum / pressure forming of 30 MPa or more.

上記樹脂板は、アクリル樹脂を含有することが好ましい。 The resin plate preferably contains an acrylic resin.

上記真空圧空成形の成形温度は、60〜120℃であることが好ましい。 The molding temperature of the vacuum / pressure forming is preferably 60 to 120 ° C.

上記樹脂板を除去した後の上記加飾成形品の最大高さ粗さは、2.0μm以下であることが好ましい。 The maximum height roughness of the decorative molded product after removing the resin plate is preferably 2.0 μm or less.

上記加飾フィルムは、ポリ塩化ビニルを含有する樹脂フィルムを有することが好ましい。 The decorative film preferably has a resin film containing polyvinyl chloride.

本発明によれば、基材表面の粗さ及び基材の材質の影響を受け難く、表面の平滑性に優れた加飾成形品が得られる加飾成形品の製造方法を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the manufacturing method of the decorative molded product which is hard to be influenced by the roughness of a base-material surface and the material of a base material, and can obtain the decorative molded product excellent in surface smoothness can be provided. .

真空圧空成形を行う加飾工程を説明するための模式図である。It is a schematic diagram for demonstrating the decorating process which performs vacuum / pressure forming. 真空圧空成形を行う加飾工程を説明するための模式図である。It is a schematic diagram for demonstrating the decorating process which performs vacuum / pressure forming.

本発明の加飾成形品の製造方法は、基材の表面に加飾フィルムが貼り付けられた加飾成形品の製造方法であって、上記基材、上記加飾フィルム及び樹脂板をこの順で重ねた状態で、真空圧空成形を行う加飾工程と、上記加飾工程の後に、上記基材に貼り付けられた上記加飾フィルム上に載せられた上記樹脂板を取り除く工程とを有し、上記樹脂板は、上記加飾フィルムと接する面の算術平均粗さが0.1μm以下であり、上記真空圧空成形の成形温度における弾性率が30MPa以上であることを特徴とする。 The method for producing a decorative molded product of the present invention is a method for producing a decorative molded product in which a decorative film is attached to the surface of a base material, and the base material, the decorative film and the resin plate are arranged in this order. In a state of being stacked in a vacuum pressure-air forming process, and after the decoration process, the process of removing the resin plate placed on the decorative film affixed to the base material The resin plate has an arithmetic average roughness of a surface in contact with the decorative film of 0.1 μm or less, and an elastic modulus at a molding temperature of the vacuum / pressure forming of 30 MPa or more.

上記加飾工程は、真空圧空成形により行う。真空圧空成形とは、真空条件下で加圧を行いながら、加飾フィルムを成形品に吸着して成形する方法であり、例えば、真空圧空成形装置を用いて行うことができる。真空圧空成形の一例を説明すると、まず、フィルムと、成形品とを大気圧状態で、成形室内にセットする。次に、成形室を気密状態とした後、真空タンクを用いて真空吸引し、成形室内を真空状態とする。続いて、真空状態を維持しつつ、ヒーターを用いて所望の温度まで加熱し、フィルムを軟化させる。軟化させたフィルムに成形品を接触させた後、成形室の真空を開放して大気圧状態とし、更に成形室内に圧空タンクから圧縮空気を入れることにより、フィルムを成形品に押圧させ、その形状に沿って貼り付ける。その後、圧縮空気を解除して加飾成形品を取り出すことができる。 The decoration process is performed by vacuum / pressure forming. Vacuum / pressure forming is a method in which a decorative film is adsorbed to a molded product while being pressurized under vacuum conditions, and can be performed using, for example, a vacuum / pressure forming apparatus. An example of vacuum / pressure forming will be described. First, a film and a molded product are set in a molding chamber under atmospheric pressure. Next, after the molding chamber is airtight, vacuum suction is performed using a vacuum tank, and the molding chamber is vacuumed. Subsequently, while maintaining the vacuum state, the film is heated to a desired temperature using a heater to soften the film. After bringing the molded product into contact with the softened film, the vacuum in the molding chamber is released to atmospheric pressure, and compressed air is introduced from the pressurized air tank into the molding chamber to press the film against the molded product. Paste along. Thereafter, the compressed air can be released and the decorative molded product can be taken out.

以下に、図1及び図2を用いて、本発明の加飾工程の具体例を説明する。図1及び図2は、真空圧空成形を行う加飾工程を説明するための模式図である。図1及び図2に示す真空圧空成形装置100は、上下に成形室(上成形室110及び下成形室120)を具備し、これらの成形室内で、真空圧空成形により基材10の表面に、加飾フィルム20を積層する。 Below, the specific example of the decorating process of this invention is demonstrated using FIG.1 and FIG.2. FIG.1 and FIG.2 is a schematic diagram for demonstrating the decorating process which performs a vacuum pressure forming. A vacuum / pressure forming apparatus 100 shown in FIGS. 1 and 2 includes upper and lower forming chambers (upper forming chamber 110 and lower forming chamber 120). In these forming chambers, the surface of the substrate 10 is formed by vacuum / pressure forming. The decorative film 20 is laminated.

まず、上成形室110が上昇した状態(図示せず)で、下成形室120内のテーブル130に基材10をセットし、基材10に積層する加飾フィルム20を下成形室120上面にセットする。その後、駆動装置140により上成形室110を降下させ、上下成形室内をそれぞれ気密状態とする(図1(a)参照)。次に、上下成形室内をそれぞれ真空タンク150から配管160を介して真空吸引して真空状態(極低圧の状態)とする(図1(b)参照)。その後、赤外線ヒーター170を点灯して加飾フィルム20の加熱を行う(図1(c)参照)。これにより、加飾フィルム20が軟化し、基材10の表面形状に沿った貼り付けが可能となる。次に、下成形室120内のテーブル130を駆動装置140により上昇させ、軟化した加飾フィルム20に基材10を接触させる(図2(d)参照)。続いて、上成形室110側の真空を開放して大気圧状態(下成形室120内は真空状態)とし、更に上成形室110内に圧空タンク180から圧縮空気を入れることにより、加飾フィルム20を基材10に押圧させその形状に沿って積層する(図2(e)参照)。これにより、基材10の表面に加飾フィルム20が積層されることとなる。加飾フィルム20は、伸ばしながら基材10に積層してもよい。その後、上成形室110内及び下成形室120内をそれぞれ大気圧状態に戻し、上成形室110を上昇させ、加飾フィルム20で被覆された基材10を取り出す(図2(f)参照)。このような方法を用いることにより、加飾フィルム20が貼り付けられた基材10を得ることができる。 First, in a state where the upper molding chamber 110 is raised (not shown), the base material 10 is set on the table 130 in the lower molding chamber 120, and the decorative film 20 laminated on the base material 10 is placed on the upper surface of the lower molding chamber 120. set. Thereafter, the upper molding chamber 110 is lowered by the driving device 140, and the upper and lower molding chambers are respectively airtight (see FIG. 1A). Next, each of the upper and lower molding chambers is vacuumed from the vacuum tank 150 through the pipe 160 to be in a vacuum state (very low pressure state) (see FIG. 1B). Thereafter, the infrared heater 170 is turned on to heat the decorative film 20 (see FIG. 1C). As a result, the decorative film 20 is softened and can be attached along the surface shape of the substrate 10. Next, the table 130 in the lower molding chamber 120 is raised by the driving device 140, and the base material 10 is brought into contact with the softened decorative film 20 (see FIG. 2D). Subsequently, the vacuum on the upper molding chamber 110 side is released to an atmospheric pressure state (the inside of the lower molding chamber 120 is in a vacuum state), and further compressed air is put into the upper molding chamber 110 from the pressurized air tank 180, thereby decorating the film. 20 is pressed against the base material 10 and laminated along its shape (see FIG. 2 (e)). Thereby, the decorative film 20 is laminated on the surface of the substrate 10. The decorative film 20 may be laminated on the base material 10 while being stretched. Thereafter, the inside of the upper molding chamber 110 and the lower molding chamber 120 are returned to the atmospheric pressure state, the upper molding chamber 110 is raised, and the base material 10 covered with the decorative film 20 is taken out (see FIG. 2 (f)). . By using such a method, the base material 10 on which the decorative film 20 is attached can be obtained.

上記加飾工程では、基材10、加飾フィルム20及び樹脂板30をこの順で重ねた状態で、真空圧空成形を行う。樹脂板30は、少なくとも、基材10と加飾フィルム20とを接触させるとき(図2(d))、及び、加飾フィルム20を基材10に押圧させるとき(図2(e))に、加飾フィルム20上に重ねられていればよいが、図1(a)に示したように、基材10と加飾フィルム20とを真空圧空成形装置内に搬入する際に重ねておいてもよい。 In the decoration process, vacuum / pressure forming is performed in a state where the base material 10, the decoration film 20, and the resin plate 30 are stacked in this order. The resin plate 30 is at least when the base material 10 and the decorative film 20 are brought into contact with each other (FIG. 2D) and when the decorative film 20 is pressed against the base material 10 (FIG. 2E). As long as it is piled up on the decorative film 20, as shown in FIG. 1 (a), it is piled up when the base material 10 and the decorative film 20 are carried into the vacuum / pressure forming apparatus. Also good.

上記加飾工程において、加飾フィルム上に樹脂板を重ねることで、樹脂板の自重により加飾フィルムが面で押圧される。これにより、基材の曲面形状に追従させる等の理由で高い柔軟性を有する加飾フィルムを用いる場合であっても、基材表面の凹凸形状が加飾成形品の表面に現れるのを防止することが可能になる。よって、基材の表面の粗さに関わらず、得られる加飾成形品の表面の平滑性を向上させ、意匠性を高めることができる。また、上記加飾工程において、基材が加圧された際に、基材の密度差に起因して加飾成形品の表面に凹凸が発生することを抑制することができる。上記樹脂板は、基材の少なくとも一部と重なるように配置されていればよいが、基材を加飾したい領域全体と重なるように配置することが好ましい。 In the decorating step, the decorative film is pressed on the surface by the weight of the resin plate by overlapping the resin plate on the decorative film. Thereby, even when a decorative film having high flexibility is used for the reason of following the curved shape of the base material, the uneven surface shape of the base material surface is prevented from appearing on the surface of the decorative molded product. It becomes possible. Therefore, irrespective of the surface roughness of the substrate, the surface smoothness of the resulting decorative molded product can be improved, and the design can be improved. Moreover, in the said decoration process, when a base material is pressurized, it can suppress that an unevenness | corrugation generate | occur | produces on the surface of a decorative molded product resulting from the density difference of a base material. Although the said resin board should just be arrange | positioned so that it may overlap with at least one part of a base material, it is preferable to arrange | position so that it may overlap with the whole area | region which wants to decorate a base material.

上記樹脂板は、真空圧空成形装置に備え付けられた部材ではなく、加飾工程において別途投入するものである。上記樹脂板を投入することで、従前の真空圧空成形装置の仕様を変更せずに、平滑性に優れた加飾成形品を製造することができる。また、上記樹脂板は加飾工程において、加飾フィルムを軟化させるための加熱により、基材及び加飾フィルムとともに加熱されることが好ましく、別途、上記成形温度とは異なる温度で加熱されるものではないことが好ましい。上記樹脂板には、意匠性を損なうことから、真空圧空成形において加飾フィルムと上記樹脂板との間の空気を抜くための真空孔が設けられていないことが好ましい。 The resin plate is not a member provided in a vacuum / pneumatic forming apparatus, but is added separately in the decoration process. By introducing the resin plate, a decorative molded product having excellent smoothness can be produced without changing the specifications of the conventional vacuum / pressure forming apparatus. Moreover, it is preferable that the said resin board is heated with a base material and a decorating film by the heating for softening a decorating film in a decorating process, and is separately heated at the temperature different from the said molding temperature. Preferably not. Since the design property of the resin plate is impaired, it is preferable that a vacuum hole for removing air between the decorative film and the resin plate in vacuum / pressure forming is not provided.

上記樹脂板の材質は、加飾フィルムの材質として好適な塩化ビニルよりも耐熱性に優れたものが好ましく、例えば、アクリル樹脂、ポリカーボネート、ポリエチレンテレフタレート等が挙げられる。なかでも、上記樹脂板は、アクリル樹脂を含有することがより好ましい。また、上記加飾工程において遠赤外線ヒーターにより加熱が行われる場合には、加飾フィルムの加熱を妨げないように、上記樹脂板は、透明であることが好ましく、着色されていないことが好ましく、なかでも、無色透明であることがより好ましい。 The material of the resin plate is preferably higher in heat resistance than vinyl chloride suitable as a material for the decorative film, and examples thereof include acrylic resin, polycarbonate, and polyethylene terephthalate. Especially, it is more preferable that the said resin board contains an acrylic resin. Further, when heating is performed by a far infrared heater in the decoration step, the resin plate is preferably transparent and preferably not colored so as not to disturb the heating of the decoration film. Especially, it is more preferable that it is colorless and transparent.

上記樹脂板は、上記加飾フィルムと接する面の算術平均粗さが0.1μm以下であり、上記真空圧空成形の成形温度における弾性率が30MPa以上である。上記加飾工程において、加飾フィルム上に樹脂板を重ねることで、上記樹脂板の上記加飾フィルムと接する面の表面形状が加飾フィルムに転写される。そのため、上記樹脂板の上記加飾フィルムと接する面が平滑であることが重要である。また、上記樹脂板は、真空圧空成形の成形温度において、変形し難く、ある程度の硬さを維持していることが重要である。 The resin plate has an arithmetic average roughness of a surface in contact with the decorative film of 0.1 μm or less, and an elastic modulus at a molding temperature of the vacuum / pressure forming of 30 MPa or more. In the said decoration process, the surface shape of the surface which contact | connects the said decoration film of the said resin board is transcribe | transferred to a decoration film by overlapping a resin board on a decoration film. Therefore, it is important that the surface of the resin plate in contact with the decorative film is smooth. Further, it is important that the resin plate is not easily deformed at the molding temperature of vacuum / pressure forming and maintains a certain degree of hardness.

上記樹脂板の上記加飾フィルムと接する面の算術平均粗さ(Ra)を0.1μm以下とすることで、得られる加飾成形品の表面を滑らかにすることができる。上記Raが0.1μmを超えると、得られる加飾成形品の表面の平滑性が不充分となる。上記Raの好ましい上限は0.05μmである。上記Raは低い方がよく、その下限は特に限定されないが、例えば、0.005μmである。本明細書中、「算術平均粗さ(Ra)」は、JIS B 0601:2001に準拠した方法で測定できる。 By setting the arithmetic average roughness (Ra) of the surface in contact with the decorative film of the resin plate to 0.1 μm or less, the surface of the resulting decorative molded product can be smoothed. If the Ra exceeds 0.1 μm, the smoothness of the surface of the decorative molded product obtained will be insufficient. A preferable upper limit of the Ra is 0.05 μm. The lower Ra is better, and the lower limit is not particularly limited, but is, for example, 0.005 μm. In this specification, “arithmetic mean roughness (Ra)” can be measured by a method based on JIS B 0601: 2001.

上記樹脂板の上記真空圧空成形の成形温度における弾性率が30MPa以上であることで、上記成形温度において、上記樹脂板がある程度の硬さを維持していることから、加飾成形品の表面を滑らかにすることができる。また、基材を局所的な加圧から保護し、基材の密度差に起因する基材表面の凹凸の発生を抑制することができる。上記弾性率が30MPa未満であると、真空圧空成形において加飾フィルムを加熱して軟化させる際に樹脂板が変形してしまうため、加飾成形品の表面を滑らかにすることができず、上記基材表面の凹凸の発生も抑制できない。上記弾性率は、5%歪み弾性率をいう。本明細書中、「5%歪み弾性率」は、ASTM規格(ASTM D−638)に準拠した方法で測定できる。 Since the elastic modulus at the molding temperature of the vacuum pressure forming of the resin plate is 30 MPa or more, the resin plate maintains a certain degree of hardness at the molding temperature. Can be smooth. Moreover, a base material can be protected from local pressurization and generation | occurrence | production of the unevenness | corrugation of the base material surface resulting from the density difference of a base material can be suppressed. When the elastic modulus is less than 30 MPa, the resin plate is deformed when the decorative film is heated and softened in vacuum / pressure forming, so that the surface of the decorative molded product cannot be smoothed. The occurrence of unevenness on the substrate surface cannot be suppressed. The elastic modulus refers to a 5% strain elastic modulus. In this specification, the “5% strain elastic modulus” can be measured by a method based on the ASTM standard (ASTM D-638).

上記樹脂板の厚さは、0.4〜1.0mmであることが好ましい。上記樹脂板の厚さが0.4mm未満であると、真空圧空成形において樹脂板が変形しやすくなり、得られる加飾成形品の表面の平滑性を向上できないおそれがある。一方、上記樹脂板の厚さが1.0mmを超えると、遠赤外線ヒーターで発せられるエネルギーを吸収しにくい透明樹脂を用いた場合であってもエネルギー損失が大きくなり、加飾フィルムの加熱に時間がかかったり、充分に加熱できないおそれがある。 The thickness of the resin plate is preferably 0.4 to 1.0 mm. If the thickness of the resin plate is less than 0.4 mm, the resin plate is likely to be deformed in vacuum / pressure forming, and the surface smoothness of the resulting decorative molded product may not be improved. On the other hand, when the thickness of the resin plate exceeds 1.0 mm, energy loss increases even when a transparent resin that hardly absorbs energy emitted by the far-infrared heater is used, and it takes time to heat the decorative film. There is a risk that it will take over or not fully heated.

上記樹脂板の形状は、特に限定されず、基材の形状に合わせた形状とすることができる。例えば、基材の平坦面に平滑性を付与する場合には、樹脂板は平板状であればよいし、曲面を有する基材の表面に平滑性を付与する場合には、樹脂板は基材の曲面に沿って湾曲していてもよい。 The shape of the resin plate is not particularly limited, and can be a shape that matches the shape of the substrate. For example, in the case of imparting smoothness to the flat surface of the substrate, the resin plate may be flat, and in the case of imparting smoothness to the surface of the substrate having a curved surface, the resin plate is a substrate. It may be curved along the curved surface.

上記真空圧空成形の成形温度は、60〜120℃であることが好ましい。上記成形温度を60〜120℃とすることで、特に加飾フィルムがポリ塩化ビニルを含有する樹脂フィルムである場合、加飾フィルムを適度に軟化させて加工することができる。上記成形温度が60℃未満であると加飾フィルムが充分に軟化せず、加飾フィルムを成形品の形状に沿って貼り付けられない場合がある。一方、上記成形温度が120℃を超えると加飾フィルムが軟化し過ぎ、加工性が低下することがある。また、上記成形温度が高すぎると、上記樹脂板が変形して得られる加飾成形品の平滑性が低下するおそれがある。上記成形温度のより好ましい下限は70℃であり、より好ましい上限は110℃である。なお、上記加飾フィルムの加熱は、樹脂板を接触させることによって行われるものではない。上記加飾フィルムは、例えば、遠赤外線等の赤外線により加熱されることが好ましい。 The molding temperature of the vacuum / pressure forming is preferably 60 to 120 ° C. By setting the molding temperature to 60 to 120 ° C., in particular, when the decorative film is a resin film containing polyvinyl chloride, the decorative film can be appropriately softened and processed. If the molding temperature is less than 60 ° C., the decorative film is not sufficiently softened, and the decorative film may not be attached along the shape of the molded product. On the other hand, when the molding temperature exceeds 120 ° C., the decorative film is excessively softened and the workability may be lowered. Moreover, when the said shaping | molding temperature is too high, there exists a possibility that the smoothness of the decorative molded product obtained by the said resin plate deform | transforming may fall. A more preferable lower limit of the molding temperature is 70 ° C, and a more preferable upper limit is 110 ° C. In addition, the heating of the said decoration film is not performed by making a resin plate contact. The decorative film is preferably heated by infrared rays such as far infrared rays.

本発明の加飾成形品の製造方法では、上記加飾工程の後に、上記基材に貼り付けられた上記加飾フィルム上に載せられた樹脂板を取り除く。例えば、図2(f)で、加飾フィルム20で被覆された基材10を取り出す際に、樹脂板30を取り出してもよい。本発明の加飾成形品の製造方法により製造される加飾成形品は、基材の表面に加飾フィルムが貼り付けられている。 In the method for producing a decorative molded product according to the present invention, the resin plate placed on the decorative film attached to the base material is removed after the decorative process. For example, the resin plate 30 may be taken out when the base material 10 covered with the decorative film 20 is taken out in FIG. The decorative molded product manufactured by the method for manufacturing a decorative molded product of the present invention has a decorative film attached to the surface of a base material.

上記樹脂板を除去した後の上記加飾成形品の算術平均粗さ(Ra)は、60μm以下であることが好ましい。上記(Ra)のより好ましい上限は40μmである。上記Raは低い方がよく、その下限は特に限定されないが、例えば、2μmである。 The arithmetic average roughness (Ra) of the decorative molded product after removing the resin plate is preferably 60 μm or less. A more preferable upper limit of (Ra) is 40 μm. The Ra should be low, and the lower limit thereof is not particularly limited, but is 2 μm, for example.

上記基材は、特に限定されず、例えば、自転車、バイク等の二輪車、自動車、バス等の四輪車等の部品;キッチン、洗面台等の化粧パネル等の建築部材料;タブレット端末、携帯電話、スマートフォン等の電子端末のカバー等が挙げられる。上記基材は、加飾フィルムが貼り付けられる面(加飾面)に三次元形状を有してもよい。 The base material is not particularly limited, and includes, for example, bicycles, motorcycles and other motorcycles, automobiles, buses and other four-wheeled vehicles, building parts such as kitchens and washstands, etc .; tablet terminals, mobile phones And a cover of an electronic terminal such as a smartphone. The said base material may have a three-dimensional shape in the surface (decoration surface) on which a decorating film is affixed.

上記基材の加飾フィルムが貼り付けられる面の算術平均粗さ(Ra)は、0.2μm以上、0.8μm以下であることが好ましい。本発明の加飾成形品の製造方法によれば、上記のように表面が粗い基材に対して、加飾フィルムを貼り付けても、基材表面の凹凸形状が加飾成形品の表面に現れるのを防止することができる。 The arithmetic average roughness (Ra) of the surface on which the decorative film of the substrate is attached is preferably 0.2 μm or more and 0.8 μm or less. According to the method for producing a decorative molded product of the present invention, even if a decorative film is attached to a substrate having a rough surface as described above, the uneven shape of the substrate surface is on the surface of the decorative molded product. It can be prevented from appearing.

上記基材の密度は、0.35g/cm以上、0.8g/cm以下であることが好ましい。上記密度のより好ましい上限は0.65g/cmであり、更に好ましい上限は0.45g/cmである。本発明の加飾成形品の製造方法によれば、上記のように柔らかい基材に対しても、加飾成形品の表面に凹凸を発生させることなく、真空圧空成形を行うことができる。 The density of the base material is preferably 0.35 g / cm 3 or more and 0.8 g / cm 3 or less. A more preferred upper limit of the density is 0.65 g / cm 3, still more preferred upper limit is 0.45 g / cm 3. According to the method for producing a decorative molded product of the present invention, vacuum / pressure forming can be performed even on a soft substrate as described above without generating irregularities on the surface of the decorative molded product.

上記基材の材質としては、例えば、樹脂、金属、木材等が挙げられる。上記樹脂としては特に限定されず、例えば、ポリエチレン、ポリプロピレン、ポリスチレン、ポリエチレンテレフタレート、ポリビニルアルコール、ポリ塩化ビニル、ポリアミド、ポリアセタール、ポリカーボネート、アクリロニトリル/ブタジエン/スチレン(ABS)、アイオノマー樹脂、これらの樹脂に無機繊維等の各種添加剤が添加された樹脂組成物等が挙げられる。上記金属としては特に限定されず、例えば、鉄、アルミニウム、銅、SUS等が挙げられる。上記木材としては、無垢材、複数の板材により形成された集成材、木質繊維により形成された成型板等挙げられる。上記成型板としては、ハードボード(JIS A 5905)、中密度繊維板(MDF:Medium Density Fiberboard))(JIS A 5905)、インシュレーションボード(JIS A 5905)、パーティクルボード(JIS A 5908)等が挙げられる。 Examples of the material of the substrate include resin, metal, and wood. The resin is not particularly limited. For example, polyethylene, polypropylene, polystyrene, polyethylene terephthalate, polyvinyl alcohol, polyvinyl chloride, polyamide, polyacetal, polycarbonate, acrylonitrile / butadiene / styrene (ABS), ionomer resin, inorganic resins such as these Examples thereof include resin compositions to which various additives such as fibers are added. It does not specifically limit as said metal, For example, iron, aluminum, copper, SUS etc. are mentioned. Examples of the wood include a solid material, a laminated material formed of a plurality of plate materials, a molded plate formed of wood fibers, and the like. Examples of the molded board include a hard board (JIS A 5905), a medium density fiber board (MDF) (JIS A 5905), an insulation board (JIS A 5905), and a particle board (JIS A 5908). Can be mentioned.

上記加飾フィルムは、単層の樹脂フィルムであってもよいし、複数の樹脂フィルムを積層したものであってもよいし、樹脂フィルムと他の層とを積層したものであってもよい。上記樹脂フィルムは、延伸可能なフィルムであれば特に限定されない。上記樹脂フィルムの材料としては、例えば、ポリ塩化ビニル;ポリエチレン、ポリプロピレン、ポリブテン、ポリブタジエン等のポリオレフィン;ポリウレタン;ポリ(メタ)アクリル酸エステル等が挙げられ、上記材料は、単独で使用されてもあるいは2種以上の混合物の形態で使用されてもよい。 The decorative film may be a single-layer resin film, a laminate of a plurality of resin films, or a laminate of a resin film and another layer. The resin film is not particularly limited as long as it is a stretchable film. Examples of the material for the resin film include polyvinyl chloride; polyolefins such as polyethylene, polypropylene, polybutene, and polybutadiene; polyurethanes; poly (meth) acrylic acid esters, and the like. It may be used in the form of a mixture of two or more.

なかでも、上記加飾フィルムは、ポリ塩化ビニルを含有する樹脂フィルムを有することが好ましい。ポリ塩化ビニルは加熱により軟化するため、真空圧空成形に用いる加飾フィルムの材料として好適である。また、ポリ塩化ビニルはフィルムにした際の伸びがよく、破断し難いことから、ポリ塩化ビニルを含有する樹脂フィルムは、三次元曲面への貼り付けに適している。 Especially, it is preferable that the said decorative film has a resin film containing a polyvinyl chloride. Since polyvinyl chloride softens when heated, it is suitable as a material for a decorative film used for vacuum / pressure forming. In addition, since polyvinyl chloride has a good elongation when formed into a film and is not easily broken, a resin film containing polyvinyl chloride is suitable for application to a three-dimensional curved surface.

上記ポリ塩化ビニルとしては、例えば、塩化ビニルの単独重合体、塩化ビニルと他の単量体との共重合体を挙げることができる。上記他の単量体としては、例えば、酢酸ビニル、プロピオン酸ビニル等のビニルエステル;エチレン、プロピレン、スチレン等のオレフィン;アクリル酸メチル、アクリル酸エチル、メタクリル酸メチル等の(メタ)アクリル酸エステル;マレイン酸ジブチル、マレイン酸ジエチル等のマレイン酸ジエステル;フマル酸ジブチル、フマル酸ジエチル等のフマル酸ジエステル;アクリロニトリル、メタクリロニトリル等のシアン化ビニル;塩化ビニリデン、臭化ビニル等のハロゲン化ビニル;メチルビニルエーテル、エチルビニルエーテル等のビニルエーテル等を挙げることができる。これらは、単独で用いてもよく、2種以上を併用してもよい。 Examples of the polyvinyl chloride include a homopolymer of vinyl chloride and a copolymer of vinyl chloride and other monomers. Examples of the other monomer include vinyl esters such as vinyl acetate and vinyl propionate; olefins such as ethylene, propylene and styrene; (meth) acrylic acid esters such as methyl acrylate, ethyl acrylate and methyl methacrylate. Maleic acid diesters such as dibutyl maleate and diethyl maleate; fumaric acid diesters such as dibutyl fumarate and diethyl fumarate; vinyl cyanides such as acrylonitrile and methacrylonitrile; vinyl halides such as vinylidene chloride and vinyl bromide; Examples thereof include vinyl ethers such as methyl vinyl ether and ethyl vinyl ether. These may be used alone or in combination of two or more.

上記他の単量体の共重合体における含有量は、通常、50重量%以下であり、好ましくは10重量%以下である。上記ポリ塩化ビニルのなかでも、寸法安定性が得られる点から、塩化ビニルの単独重合体が好ましい。 The content of the other monomer in the copolymer is usually 50% by weight or less, preferably 10% by weight or less. Among the polyvinyl chlorides, a homopolymer of vinyl chloride is preferable from the viewpoint of obtaining dimensional stability.

上記ポリ塩化ビニルの平均重合度は特に限定されず、求められるフィルムの硬さや、硬さの調整に用いられる可塑剤の量に応じて調整されるものであり、上記ポリ塩化ビニルの平均重合度は800〜1200であることが好ましい。このような態様とすることにより、加工性を高めることができる。なお、本明細書において、ポリ塩化ビニルの平均重合度は、JIS K6721「塩化ビニル樹脂試験方法」に準拠して測定した平均重合度を意味する。 The average degree of polymerization of the polyvinyl chloride is not particularly limited, and is adjusted according to the required film hardness and the amount of plasticizer used for adjusting the hardness, and the average degree of polymerization of the polyvinyl chloride. Is preferably 800-1200. By setting it as such an aspect, workability can be improved. In the present specification, the average degree of polymerization of polyvinyl chloride means the average degree of polymerization measured in accordance with JIS K6721 “Testing methods for vinyl chloride resin”.

上記樹脂フィルムは、ポリ塩化ビニルに加えて可塑剤を含有してもよい。上記可塑剤の具体例としては、例えば、フタル酸オクチル(ジ−2−エチルヘキシルフタレート(DOP))、フタル酸ジブチル、フタル酸ジノニル、フタル酸ジイソノニル(DINP)等のフタル酸ジエステル;シクロヘキサンジカルボン酸エステル、アジピン酸ジオクチル、セバシン酸ジオクチル等の脂肪族二塩基酸ジエステル;トリクレジルホスフェート、トリオクチルホスフェート等のリン酸トリエステル;エポキシ化大豆油やエポキシ樹脂等のエポキシ系可塑剤;高分子ポリエステル可塑剤等が挙げられる。 The resin film may contain a plasticizer in addition to polyvinyl chloride. Specific examples of the plasticizer include phthalic acid diesters such as octyl phthalate (di-2-ethylhexyl phthalate (DOP)), dibutyl phthalate, dinonyl phthalate, diisononyl phthalate (DINP), and the like; cyclohexane dicarboxylic acid ester , Aliphatic dibasic acid diesters such as dioctyl adipate and dioctyl sebacate; phosphate triesters such as tricresyl phosphate and trioctyl phosphate; epoxy plasticizers such as epoxidized soybean oil and epoxy resins; Agents and the like.

上記高分子ポリエステル可塑剤としては、例えば、フタル酸のポリエチレングリコールジエステル、ポリプロピレングリコールジエステル、ポリエチレングリコールポリプロピレングリコールジエステル等のポリアルキレングリコールジエステル;アジピン酸、セバシン酸等の脂肪族二塩基酸のポリエチレングリコールジエステル;ポリプロピレングリコールジエステル、ポリエチレングリコールポリプロピレングリコールジエステル等のポリアルキレングリコールジエステルが挙げられる。これらは、単独で用いてもよく、2種以上を併用してもよい。 Examples of the polymer polyester plasticizer include polyalkylene glycol diesters such as polyethylene glycol diester, polypropylene glycol diester, and polyethylene glycol polypropylene glycol diester of phthalic acid; polyethylene glycol diesters of aliphatic dibasic acids such as adipic acid and sebacic acid. Polyalkylene glycol diesters such as polypropylene glycol diester and polyethylene glycol polypropylene glycol diester; These may be used alone or in combination of two or more.

上記可塑剤の配合量は、上記ポリ塩化ビニル100重量部に対して、5重量部以上、30重量部以下が好ましい。 The blending amount of the plasticizer is preferably 5 parts by weight or more and 30 parts by weight or less with respect to 100 parts by weight of the polyvinyl chloride.

上記樹脂フィルムは、カレンダー成形を用いて作製することができる。ここで、カレンダー成形とは、一対のロールによって原料樹脂を圧延して成形する方法をいう。上記カレンダー成形に用いられるカレンダー形式としては、例えば、逆L型、Z型、直立2本型、L型、傾斜3本型等が挙げられる。 The resin film can be produced using calendar molding. Here, calendar molding refers to a method of rolling and molding a raw material resin with a pair of rolls. Examples of the calendar format used for the calendar molding include an inverted L shape, a Z shape, an upright two shape, an L shape, and an inclined three shape.

上記加飾フィルムは、上記樹脂フィルムの基材と貼り合わせる側に粘着剤層を有してもよい。上記粘着剤層を有することで、加飾フィルムと基材との密着性をより高めることができる。上記粘着剤層に含まれる粘着剤の種類は特に限定されず、例えば、アクリル系粘着剤層、ポリエステル系粘着剤層、ウレタン系粘着剤層、ゴム系粘着剤層、シリコーン系粘着剤層等が挙げられる。 The decorative film may have an adhesive layer on the side to be bonded to the base of the resin film. By having the said adhesive layer, the adhesiveness of a decorating film and a base material can be improved more. The type of the pressure-sensitive adhesive contained in the pressure-sensitive adhesive layer is not particularly limited, and examples thereof include an acrylic pressure-sensitive adhesive layer, a polyester-based pressure-sensitive adhesive layer, a urethane-based pressure-sensitive adhesive layer, a rubber-based pressure-sensitive adhesive layer, and a silicone-based pressure-sensitive adhesive layer. Can be mentioned.

また、上記粘着剤層は、ホットメルト接着剤からなる層(ホットメルト粘着剤層)であってもよい。ホットメルト粘着剤層は、溶剤を含有しないため、真空圧空成形により加飾フィルムを積層する場合に好適に用いられる。上記ホットメルト粘着剤層としては、例えば、ポリエステル系ホットメルト粘着剤層、アクリル系ホットメルト粘着剤層、ゴム系ホットメルト粘着剤層、シリコーン系ホットメルト粘着剤層等が挙げられ、なかでも、アクリル系ホットメルト粘着剤層が好ましい。 The pressure-sensitive adhesive layer may be a layer made of a hot-melt adhesive (hot-melt pressure-sensitive adhesive layer). Since the hot-melt pressure-sensitive adhesive layer does not contain a solvent, it is suitably used when a decorative film is laminated by vacuum / pressure forming. Examples of the hot-melt pressure-sensitive adhesive layer include a polyester-based hot-melt pressure-sensitive adhesive layer, an acrylic-based hot-melt pressure-sensitive adhesive layer, a rubber-based hot-melt pressure-sensitive adhesive layer, and a silicone-based hot-melt pressure-sensitive adhesive layer. An acrylic hot melt pressure-sensitive adhesive layer is preferred.

上記樹脂フィルムは、着色フィルムであってもよいし、表面には印刷等が施されてもよい。上記加飾フィルムは、インク等により絵柄が印刷された意匠層を有してもよい。更に、上記加飾フィルムは、最表面に上記意匠を保護するオーバーコート層を有してもよい。 The resin film may be a colored film, or may be printed on the surface. The decorative film may have a design layer on which a pattern is printed with ink or the like. Furthermore, the decorative film may have an overcoat layer that protects the design on the outermost surface.

上記加飾フィルムは、100℃での伸張率が200%以上であることが好ましい。上記伸張率が200%以上であれば、3次元曲面への貼り付けに好適である。上記伸張率の上限は特に制限されないが、例えば400%である。上記伸張率は、引張試験機を用いてJIS K 7162に準拠して引張試験を行い、下記式から求めることができる。下記式中、Laは、引張試験を行う前の試験片の長さであり、Lbは、引張試験において試験片が破断した際の時の試験片の長さである。
伸張率(%)={(Lb−La)/La}×100
The decorative film preferably has an elongation rate at 100 ° C. of 200% or more. If the expansion ratio is 200% or more, it is suitable for attachment to a three-dimensional curved surface. The upper limit of the expansion rate is not particularly limited, but is 400%, for example. The elongation rate can be obtained from the following equation by performing a tensile test using a tensile tester in accordance with JIS K 7162. In the following formula, La is the length of the test piece before the tensile test is performed, and Lb is the length of the test piece when the test piece is broken in the tensile test.
Elongation rate (%) = {(Lb−La) / La} × 100

以下、本発明について実施例を掲げて更に詳しく説明するが、本発明はこれらの実施例のみに限定されるものではない。 EXAMPLES Hereinafter, although an Example is hung up and demonstrated in more detail about this invention, this invention is not limited only to these Examples.

(実施例1)
平均重合度が800のポリ塩化ビニル100重量部に対して、フタル酸ジイソノニル(DINP)を8重量部添加し、バンバリーミキサーで溶融混練後、カレンダー成形にて厚み0.15mmのPVCフィルムを作製した。上記PVCフィルムを熱ラミネートにより2枚積層し、厚み0.3mmの加飾フィルムを作製した。
Example 1
8 parts by weight of diisononyl phthalate (DINP) was added to 100 parts by weight of polyvinyl chloride having an average degree of polymerization of 800, melt-kneaded with a Banbury mixer, and then a PVC film having a thickness of 0.15 mm was prepared by calendering. . Two sheets of the above PVC film were laminated by heat lamination to produce a decorative film having a thickness of 0.3 mm.

基材として、縦150mm、横150mm、厚さ18mmの平板状の中密度繊維板(MDF)(密度:0.55g/cm)を準備し、樹脂板として、下記表1に示した平板状のアクリル樹脂製の樹脂板Aを準備した。 A flat medium density fiber board (MDF) (density: 0.55 g / cm 3 ) having a length of 150 mm, a width of 150 mm, and a thickness of 18 mm was prepared as a substrate, and the flat plate shape shown in Table 1 below was used as a resin board. A resin plate A made of acrylic resin was prepared.

上記MDF上に上記で得られた加飾フィルム、樹脂板Aをこの順で重ね、成形温度80℃で真空圧空成形を行った。真空圧空成形は、布施真空株式会社製のTOM成形機(NGF−0406−T)を用いて行った。 The decorative film obtained above and the resin plate A were layered in this order on the MDF, and vacuum / pressure forming was performed at a molding temperature of 80 ° C. The vacuum / pressure forming was performed using a TOM molding machine (NGF-0406-T) manufactured by Fuse Vacuum Co., Ltd.

(実施例2)
真空圧空成形において、樹脂板として下記表1に示した平板状のアクリル樹脂製の樹脂板Bを用いたこと以外は、実施例1と同様の基材及び加飾フィルムを用い、実施例1と同様にして真空圧空成形を行い加飾成形品を作製した。
(Example 2)
In vacuum / pressure forming, the same base material and decorative film as in Example 1 were used except that the flat acrylic resin plate B shown in Table 1 below was used as the resin plate. Similarly, vacuum / pressure forming was performed to produce a decorative molded product.

(比較例1)
真空圧空成形において樹脂板を用いなかったこと以外は、実施例1と同様の基材及び加飾フィルムを用い、実施例1と同様にして真空圧空成形を行い加飾成形品を作製した。
(Comparative Example 1)
Except that the resin plate was not used in the vacuum / pressure forming, the same substrate and decorative film as in Example 1 were used, and vacuum / pressure forming was performed in the same manner as in Example 1 to produce a decorative molded product.

(比較例2)
真空圧空成形において、樹脂板として下記表1に示した平板状のポリ塩化ビニル(PVC)製の樹脂板Cを用いたこと以外は、実施例1と同様の基材及び加飾フィルムを用い、実施例1と同様にして真空圧空成形を行い加飾成形品を作製した。
(Comparative Example 2)
In vacuum / pressure forming, the same base material and decorative film as in Example 1 were used except that a flat-plate polyvinyl chloride (PVC) resin plate C shown in Table 1 below was used as the resin plate. In the same manner as in Example 1, vacuum-compression molding was performed to produce a decorative molded product.

(比較例3)
真空圧空成形において、樹脂板に代えて下記表1に示した平板状のステンレス鋼板Dを用いたこと以外は、実施例1と同様の基材及び加飾フィルムを用い、実施例1と同様にして真空圧空成形を行い加飾成形品を作製した。
(Comparative Example 3)
In vacuum / pressure forming, the same base material and decorative film as in Example 1 were used, except that a flat stainless steel plate D shown in Table 1 below was used instead of the resin plate. Vacuum-pressure forming was performed to produce a decorative molded product.

樹脂板A〜C及びステンレス鋼板Dの表面特性として、以下の方法で、算術平均粗さ(Ra)及び弾性率(5%歪み弾性率)を測定した。結果を下記表1にまとめた。 As surface properties of the resin plates A to C and the stainless steel plate D, arithmetic average roughness (Ra) and elastic modulus (5% strain elastic modulus) were measured by the following methods. The results are summarized in Table 1 below.

上記算術平均粗さ(Ra)は、JIS B 0601:2001に準拠した方法で、以下の測定条件で測定した。
(測定条件)
曲線:R
フィルタ:GAUSS
カットオフ値λc:0.8mm
カットオフ値λs:25μm
区間数:15mm
助走:前後有り
測定速度:0.5mm/秒
The arithmetic average roughness (Ra) was measured under the following measurement conditions by a method based on JIS B 0601: 2001.
(Measurement condition)
Curve: R
Filter: GAUSS
Cut-off value λc: 0.8 mm
Cut-off value λs: 25 μm
Number of sections: 15mm
Run-up: Before and after Measurement speed: 0.5 mm / sec

上記弾性率(5%歪み弾性率)は、ASTM規格(ASTM D−638)に準拠した方法により、以下の測定条件で測定した。
(弾性率の測定条件)
試験速度:5mm/分
サンプルの長さ:150mm
サンプルの幅:20mm
標線間距離:50mm
チャック間の初期距離:100mm±5mm
The elastic modulus (5% strain elastic modulus) was measured under the following measurement conditions by a method based on the ASTM standard (ASTM D-638).
(Measurement conditions of elastic modulus)
Test speed: 5 mm / min Sample length: 150 mm
Sample width: 20mm
Distance between marked lines: 50 mm
Initial distance between chucks: 100mm ± 5mm

Figure 2019202515
Figure 2019202515

上記実施例及び比較例で得られた加飾成形品、並びに、加飾成形前の基材(MDF)の加飾フィルムが貼り付けられる面の表面特性として、Raを上記樹脂板と同様の方法で測定した。それぞれについて、任意の三点でRaを測定した。結果を下記表2にまとめた。 As a surface property of the surface to which the decorative film of the base material (MDF) before the decorative molding obtained in the above examples and comparative examples is attached, Ra is the same method as the above resin plate Measured with For each, Ra was measured at any three points. The results are summarized in Table 2 below.

Figure 2019202515
Figure 2019202515

加飾工程において、加飾フィルムと接する面の算術平均粗さが0.1μm以下であり、かつ真空圧空成形の成形温度における弾性率が30MPa以上であるアクリル樹脂製の樹脂板を用いた実施例1及び2では、加飾成形品の表面が滑らかであり、基材の凹みも確認されなかった。 In the decorating step, an example using an acrylic resin resin plate having an arithmetic average roughness of a surface in contact with the decorating film of 0.1 μm or less and an elastic modulus at a molding temperature of vacuum pressure forming of 30 MPa or more. In 1 and 2, the surface of the decorative molded product was smooth, and the dent of the base material was not confirmed.

一方、加飾工程において樹脂板を用いなかった比較例1では、加飾成形前の基材(MDF)よりはRaが低減されたものの、表面の滑らかさは不充分であり、かつ、MDFの密度差による凹みが確認された。また、加飾フィルムと接する面の算術平均粗さが0.1μmよりも大きく、かつ真空圧空成形の成形温度における弾性率が30MPa以下であるPVC製の樹脂板を用いた比較例2や、加飾フィルムと接する面の算術平均粗さが0.1μmよりも大きいステンレス鋼板を用いた比較例3では、加飾成形前の基材よりもRaを低減する効果は得られなかった。 On the other hand, in Comparative Example 1 in which the resin plate was not used in the decoration process, Ra was reduced as compared with the base material (MDF) before the decoration molding, but the surface smoothness was insufficient and the MDF A dent due to the density difference was confirmed. Further, Comparative Example 2 using a PVC resin plate in which the arithmetic average roughness of the surface in contact with the decorative film is larger than 0.1 μm and the elastic modulus at the molding temperature in vacuum / pressure forming is 30 MPa or less, In Comparative Example 3 using a stainless steel plate having an arithmetic average roughness of the surface in contact with the decorative film larger than 0.1 μm, the effect of reducing Ra as compared with the base material before the decorative molding was not obtained.

10:基材(成形品)
20:加飾フィルム
30:樹脂板
100:真空圧空成形装置
110:上成形室
120:下成形室
130:テーブル
140:駆動装置
150:真空タンク
160:配管
170:赤外線ヒーター
180:圧空タンク
10: Base material (molded product)
20: Decorative film 30: Resin plate 100: Vacuum / pressure forming device 110: Upper forming chamber 120: Lower forming chamber 130: Table 140: Drive device 150: Vacuum tank 160: Piping 170: Infrared heater 180: Pressured air tank

Claims (5)

基材の表面に加飾フィルムが貼り付けられた加飾成形品の製造方法であって、
前記基材、前記加飾フィルム及び樹脂板をこの順で重ねた状態で、真空圧空成形を行う加飾工程と、
前記加飾工程の後に、前記基材に貼り付けられた前記加飾フィルム上に載せられた前記樹脂板を取り除く工程とを有し、
前記樹脂板は、前記加飾フィルムと接する面の算術平均粗さが0.1μm以下であり、前記真空圧空成形の成形温度における弾性率が30MPa以上であることを特徴とする加飾成形品の製造方法。
A method for manufacturing a decorative molded product in which a decorative film is attached to the surface of a substrate,
In a state where the base material, the decorative film and the resin plate are stacked in this order, a decoration process for performing vacuum / pressure forming,
And after the decoration step, removing the resin plate placed on the decorative film affixed to the base material,
The resin plate has an arithmetic average roughness of a surface in contact with the decorative film of 0.1 μm or less, and an elastic modulus at a molding temperature of the vacuum / pressure forming of 30 MPa or more. Production method.
前記樹脂板は、アクリル樹脂を含有することを特徴とする請求項1に記載の加飾成形品の製造方法。 The method for producing a decorative molded product according to claim 1, wherein the resin plate contains an acrylic resin. 前記真空圧空成形の成形温度は、60〜120℃であることを特徴とする請求項1又は2に記載の加飾成形品の製造方法。 The method for producing a decorative molded product according to claim 1 or 2, wherein a molding temperature of the vacuum / pressure forming is 60 to 120 ° C. 前記樹脂板を除去した後の前記加飾成形品の最大高さ粗さは、2.0μm以下であることを特徴とする請求項1〜3のいずれかに記載の加飾成形品の製造方法。 The method for producing a decorative molded product according to any one of claims 1 to 3, wherein a maximum height roughness of the decorative molded product after removing the resin plate is 2.0 µm or less. . 前記加飾フィルムは、ポリ塩化ビニルを含有する樹脂フィルムを有することを特徴とする請求項1〜4のいずれかに記載の加飾成形品の製造方法。 The said decorative film has a resin film containing a polyvinyl chloride, The manufacturing method of the decorative molded product in any one of Claims 1-4 characterized by the above-mentioned.
JP2018100593A 2018-05-25 2018-05-25 Manufacturing method of decorative molded products Active JP7063725B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2018100593A JP7063725B2 (en) 2018-05-25 2018-05-25 Manufacturing method of decorative molded products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2018100593A JP7063725B2 (en) 2018-05-25 2018-05-25 Manufacturing method of decorative molded products

Publications (2)

Publication Number Publication Date
JP2019202515A true JP2019202515A (en) 2019-11-28
JP7063725B2 JP7063725B2 (en) 2022-05-09

Family

ID=68725832

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2018100593A Active JP7063725B2 (en) 2018-05-25 2018-05-25 Manufacturing method of decorative molded products

Country Status (1)

Country Link
JP (1) JP7063725B2 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5276377A (en) * 1975-12-20 1977-06-27 Toppan Printing Co Ltd Method of pressslamination under vacuum
JPH05293895A (en) * 1992-04-20 1993-11-09 Dainippon Printing Co Ltd Device and method for laminated molding with vacuum press
JPH07112483A (en) * 1993-10-20 1995-05-02 Dainippon Printing Co Ltd Vacuum laminate molding method and apparatus
JP2000085088A (en) * 1998-09-09 2000-03-28 Yoshihara Seishiro Apparatus and method for producing decorative sheet laminated plate material
JP2013078898A (en) * 2011-10-04 2013-05-02 Asano Laboratories Co Ltd Molding device and molding method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5276377A (en) * 1975-12-20 1977-06-27 Toppan Printing Co Ltd Method of pressslamination under vacuum
JPH05293895A (en) * 1992-04-20 1993-11-09 Dainippon Printing Co Ltd Device and method for laminated molding with vacuum press
JPH07112483A (en) * 1993-10-20 1995-05-02 Dainippon Printing Co Ltd Vacuum laminate molding method and apparatus
JP2000085088A (en) * 1998-09-09 2000-03-28 Yoshihara Seishiro Apparatus and method for producing decorative sheet laminated plate material
JP2013078898A (en) * 2011-10-04 2013-05-02 Asano Laboratories Co Ltd Molding device and molding method

Also Published As

Publication number Publication date
JP7063725B2 (en) 2022-05-09

Similar Documents

Publication Publication Date Title
JP2018167511A (en) Method for manufacturing decorative formed article
CN106949546B (en) Manufacturing process of gradient-color air conditioner arc-shaped panel
CN113453889B (en) Modified film
JP7063725B2 (en) Manufacturing method of decorative molded products
JP6503628B2 (en) Decorative sheet and decorative resin molded article
JP2018171920A (en) Decorative sheet for thermal adhesion process
KR20080070424A (en) Lamination sheet for decoration and transparent panel having three-dimentional property using the same
JP3253654B2 (en) Vacuum press lamination molding method
KR101262444B1 (en) Molding sheet having three dimensional emboss effect
JP2019072884A (en) Manufacturing method of decorative molded article
JP2017159627A (en) Protection film, laminate for decorative molding, and decorative molding
JP2017196814A (en) Method for imparting embossed shape to acrylic resin laminated film layer
JP2020012112A (en) Resin foam, resin foam sheet, adhesive tape, vehicular member and building member
JP6666196B2 (en) Jet-black decorative film, decorative molded product, and method of manufacturing jet-black decorative film
JP2016078301A (en) Laminate for decorative molding, method for producing decorative molded article and decorative molded article
JP2017159587A (en) Metal like decorative film and decorative molding
JP6467840B2 (en) Laminated sheet and decorative resin molded product
JP6736451B2 (en) Method for producing metal vapor deposition film
JP2018144323A (en) Metal vapor-deposited film and decorative molded article
JP6331576B2 (en) Decorative sheet and decorative resin molded product
JP6953138B2 (en) Decorative film and decorative molded product
JP2016107410A (en) Decorative adhesive sheet
JP7479132B2 (en) Manufacturing method of decorative board
JP2019130727A (en) Laminate and article
KR101772731B1 (en) Sheet with enhanced formability and heat resistance for three dimension overlay method

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20210423

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20220325

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20220405

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20220421

R150 Certificate of patent or registration of utility model

Ref document number: 7063725

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150