JP2019196535A - Steel - Google Patents

Abstract

To provide a steel that has excellent productivity, and has long-term corrosion resistance and excellent weldability in acid corrosion conditions including sulfuric acid dew point corrosion and hydrochloric acid dew point corrosion.SOLUTION: A steel comprises, in mass%, C: 0.01-0.10%, Si: 0.04-0.40%, Mn: 0.60-1.50%, Cu: 0.02-0.24%, Sb: 0.01-0.23%, Al: 0.005-0.050%, Sn: 0.001-0.20%, Ca: 0.00005-0.010%, one or both of Mo and W: 0.01-0.30% in total, P: 0-0.020%, S: 0-0.015%, N: 0-0.005%, O: 0.0005-0.0035%, with the balance being Fe and impurities, Ca/O of 1.00 or less, a total content of Cu and Sb being 0.05-0.25%, and Ceq(C+Mn/6+(Cu+Ni)/5+(Cr+Mo+V)/15) of 0.180-0.330.SELECTED DRAWING: None

Description

  The present invention relates to a steel material.

Boiler flue gas facilities and gasification melting furnaces that burn various fuels, wastes, sewage sludge, etc. are exposed to the flue gas atmosphere and are exposed to sulfuric acid dew point corrosion, hydrochloric acid dew point corrosive environments, or aqueous solutions of sulfuric acid and hydrochloric acid. It becomes environment to touch. Steel materials exposed to such a severe corrosive environment are required to have excellent acid resistance over a long period of time.

  For such problems, sulfuric acid / hydrochloric acid dew point corrosion steel and highly corrosion resistant stainless steel have been proposed. (For example, refer to Patent Documents 1 to 5.) Among these, Patent Documents 1 to 4 propose steel materials excellent in sulfuric acid dew point corrosion resistance to which Cu, Sb, Co, Cr, or the like is added. Patent Document 5 proposes a high corrosion resistance stainless steel to which Cr, Ni, or the like is added.

JP 2001-164335 A JP 2003-213367 A JP 2007-239094 A JP 2012-57221 A JP 7-316745 A

  Steel materials containing Cu, Sb, Cr, etc. are excellent in sulfuric acid dew point corrosion resistance and exhibit excellent corrosion resistance in sulfuric acid corrosive environments such as boilers and exhaust gas chimneys of incineration facilities. However, in order to extend the life of boilers and incineration facilities, further improvement in corrosion resistance is expected.

  Moreover, not only acid resistance but weldability is calculated | required by the steel materials used for uses, such as a heat exchanger, a gas-gas heater, a desulfurization apparatus, and an electrostatic precipitator. Furthermore, hot workability is also required from the viewpoint of productivity.

  In view of such circumstances, the present invention is excellent in productivity (particularly hot workability), and has a long-term corrosion resistance and excellent weldability in an acid corrosion environment of sulfuric acid dew point corrosion and hydrochloric acid dew point corrosion. Providing is an issue.

The present inventors paid attention to an oxide that becomes a starting point of corrosion, and studied to improve the corrosion resistance of the steel material in an acid corrosion environment. And it turned out that the production | generation of the coarse oxide used as the starting point of corrosion is suppressed by containing Ca which raises the cleanliness of steel, and making Ca / O ratio (mass ratio) 1.00 or less. . Moreover, when Cu and Sb are contained simultaneously, although acid resistance improves, hot workability will fall. On the other hand, by setting the total amount of Cu and Sb to 0.05 to 0.25 and Ceq determined by the following formula (1) to 0.180 to 0.330, excellent acid resistance and heat The knowledge that inter-workability and weldability are obtained was obtained.
Ceq = C + Mn / 6 + (Cu + Ni) / 5 + (Cr + Mo + V) / 15 Formula (1)

This invention is made | formed based on such knowledge, The summary is as follows.
[1] By mass%
C: 0.01-0.10%,
Si: 0.04 to 0.40%,
Mn: 0.60 to 1.50%,
Cu: 0.02 to 0.24%
Sb: 0.01 to 0.23%,
Al: 0.005 to 0.050%,
Sn: 0.001 to 0.20% and Ca: 0.00005 to 0.010%
One or both of Mo and W in total, 0.01 to 0.30%,
P: 0 to 0.020%,
S: 0 to 0.015%,
N: 0 to 0.005%, and O: 0.0005 to 0.0035%
And the balance consists of Fe and impurities,
The content of Ca and the content of O are mass ratios (Ca / O) and are 1.00 or less,
The total amount of Cu and Sb is 0.05 to 0.25 in mass%,
Ceq calculated | required by following formula (1) is 0.180-0.330, The steel materials characterized by the above-mentioned.
Ceq = C + Mn / 6 + (Cu + Ni) / 5 + (Cr + Mo + V) / 15 Formula (1)
Here, in the formula (1), C, Mn, Cu, Mo, Ni, Cr, and V are contents based on mass% of each element, and 0 when not contained.
[2] Furthermore, in mass%,
Ni: 0.30% or less,
The steel material as described in [1] above, comprising one or more selected from the group consisting of As: 0.30% or less and Co: 0.30% or less.
[3] Furthermore, in mass%,
Cr: 0.70% or less,
Ti: 0.050% or less,
Nb: 0.10% or less,
V: 0.10% or less,
Zr: 0.050% or less,
The steel material according to the above [1] or [2], which contains one or more selected from the group consisting of Ta: 0.050% or less and B: 0.010% or less.
[4] Furthermore, in mass%,
One or more types selected from the group consisting of Mg: 0.010% or less and REM: 0.010% or less are described in any one of [1] to [3] above Steel material.

  According to the present invention, excellent corrosion resistance is exhibited in an acid corrosive environment such as a sulfuric acid corrosive environment such as an exhaust gas chimney of a boiler or an incineration facility and a hydrochloric acid corrosive environment such as an exhaust gas chimney of a waste incinerator, etc., and productivity and weldability are improved. It becomes possible to provide excellent steel materials. Therefore, the industrial contribution of the present invention is extremely remarkable.

  Hereinafter, preferred embodiments of the present invention will be described in detail.

  As a result of the study by the present inventors, it has been found that, in order to improve the acid resistance of a steel material containing Cu and Sb, it is effective to suppress the formation of coarse oxides that are likely to become corrosion starting points on the steel material surface. First, in order to suppress the formation of coarse oxides, it is effective to contain Ca having an effect of increasing the cleanliness of steel and to make the amount of Ca with respect to the amount of O below a certain level. The knowledge that the / O ratio is important was obtained. Moreover, in steel which contains Cu and Sb simultaneously, in order to ensure hot workability, the knowledge that the total amount of Cu and Sb was important was acquired. And it turned out that hot workability can be ensured by making the total amount of Cu and Sb into an appropriate range, without reducing acid resistance, without impairing productivity.

Together with these, by making Ceq required by the following formula (1) within an appropriate range, a steel material having excellent acid resistance, hot workability and weldability was successfully obtained.
Ceq = C + Mn / 6 + (Cu + Ni) / 5 + (Cr + Mo + V) / 15 Formula (1)

  The components of the steel material according to this embodiment will be described. In addition, the description of% means the mass% unless there is particular notice.

(C: 0.01-0.10%)
C is an element for improving the strength, and it is necessary to contain 0.01% or more. Preferably, the C content is 0.03% or more, more preferably 0.05% or more. On the other hand, if the amount of C exceeds 0.10%, carbides increase and the acid resistance deteriorates, so the amount of C is made 0.10% or less. Preferably, the C content is 0.09% or less, more preferably 0.08% or less.

(Si: 0.04-0.40%)
Si is an element that contributes to deoxidation and strength improvement, and in order to control the form of the oxide, it is necessary to contain 0.04% or more. Preferably, the Si amount is 0.05% or more, more preferably 0.10% or more. On the other hand, if Si exceeds 0.40%, oxides increase and acid resistance is impaired, so the Si content is set to 0.40% or less. Preferably, the Si content is 0.30% or less.

(Mn: 0.60 to 1.50%)
Mn is an element that improves strength and toughness, and contains 0.60% or more. Preferably, the amount of Mn is 0.80% or more. On the other hand, if Mn is contained in an amount exceeding 1.50%, coarse MnS is generated and the corrosion resistance and mechanical properties are deteriorated, so the Mn amount is made 1.50% or less. Preferably, the Mn content is 1.30% or less, more preferably 1.20% or less.

(Cu: 0.02-0.24%)
Cu is an extremely important element that remarkably exhibits corrosion resistance to sulfuric acid and hydrochloric acid when it is contained simultaneously with Sb. The Cu content necessary for ensuring corrosion resistance in an acidic environment by being contained simultaneously with Sb is 0.02% or more. Preferably, the Cu content is 0.03% or more, more preferably 0.05% or more, and still more preferably 0.06% or more. On the other hand, if the Cu content exceeds 0.24%, the hot workability deteriorates and the productivity is impaired, so the content is made 0.24% or less. Preferably, the Cu content is 0.23% or less, more preferably 0.22% or less.

(Sb: 0.01 to 0.23%)
As described above, Sb is an extremely important element that improves the acid resistance when it is contained simultaneously with Cu, and it is necessary to contain 0.01% or more in order to ensure corrosion resistance in an acidic environment. Preferably, the Sb content is 0.02% or more, more preferably 0.03% or more, and still more preferably 0.04% or more. On the other hand, when the Sb content exceeds 0.23%, the hot workability deteriorates, so the content is made 0.23% or less. Preferably, the Sb content is 0.22% or less, more preferably 0.21% or less, and still more preferably 0.20% or less.

(Al: 0.005 to 0.050%)
Al is a deoxidizer and needs to contain 0.005% or more. Preferably, the Al content is 0.01% or more. On the other hand, if Al is contained excessively, acid resistance is impaired due to an increase in inclusions, so the Al content is made 0.050% or less. Preferably, the Al content is 0.040% or less.

(Sn: 0.001% to 0.20%)
Sn is an element that improves acid resistance by being contained simultaneously with Cu and Sb, and exhibits an effect by containing 0.001% or more. More preferably it is 0.0012% or more, still more preferably 0.0015% or more. On the other hand, when Sn is excessively contained, hot workability is lowered, so the Sn content is 0.20% or less. More preferably, the Sn amount is 0.18% or less, and further preferably 0.15% or less.

(Ca: 0.00005 to 0.010%)
Ca is an element that mainly controls the form of sulfides and oxides and improves the cleanliness of steel, and the effect is exhibited by containing 0.00005% or more. Preferably it is 0.0001% or more, more preferably 0.0005% or more. On the other hand, if the amount of Ca is too large, the mechanical properties of the steel are reduced, so the amount of Ca is set to 0.010% or less. Preferably it is 0.008%, More preferably, it is 0.005%.

(Total of one or both of Mo and W: 0.01 to 0.30%)
Mo and W are elements that improve the corrosion resistance in an acidic environment by being contained simultaneously with Cu and Sb. One of Mo and W may be contained alone, or both may be contained simultaneously. In particular, in order to increase the corrosion resistance against hydrochloric acid, the total content of one or both of Mo and W is set to 0.01% or more. Preferably it is 0.02%, More preferably, it is 0.03% or more, More preferably, it is 0.04% or more. On the other hand, when Mo and W are contained excessively, a carbide that becomes a starting point of corrosion is formed, and acid resistance is lowered. Furthermore, since Mo and W are expensive elements, the total content of one or both of Mo and W is set to 0.30% or less from the viewpoint of cost. Preferably it is 0.25% or less, more preferably 0.20% or less.

(P: 0-0.020%)
P is an impurity, and in order to reduce the mechanical properties and productivity of the steel material, the amount of P is set to 0.020% or less. The lower limit of the amount of P is not limited and may be 0%, but the amount of P may be 0.001% or more from the viewpoint of cost.

(S: 0 to 0.015%)
S is an impurity, and in order to reduce hot workability and mechanical properties of the steel material, the S content is set to 0.015% or less. The lower limit of the amount of S is not limited and may be 0%. When S is contained at the same time as Cu and Sb, the corrosion resistance in an acidic environment is improved, so the amount of S may be 0.001% or more. More preferably, the S amount may be 0.005% or more, and further preferably 0.008% or more.

(N: 0 to 0.005%)
N is an impurity, and in order to reduce the mechanical properties and productivity of the steel material, the N amount is set to 0.005% or less. The lower limit of the N amount is not limited and may be 0%, but the N amount may be 0.001% or more from the viewpoint of cost. When fine nitride is used for improving mechanical properties and the like, the N content may be 0.002% or more.

(O: 0.0005-0.0035%)
O is an element that forms an oxide. In order to suppress the formation of a coarse oxide that becomes a starting point of corrosion in an acidic environment, the amount of O is made 0.0035% or less. Preferably, the amount of O is 0.0032% or less, more preferably 0.0030% or less. On the other hand, if the lower limit of the amount of O is to be made less than 0.0005%, the manufacturing cost increases, so the amount of O is made 0.0005% or more from the viewpoint of cost.

  Furthermore, in order to improve the corrosion resistance in an acidic environment, you may contain 1 type, or 2 or more types selected from the group which consists of Ni, As, and Co. In addition, since these elements are not necessarily essential in the steel material, the lower limit of the content is set to 0%.

(Ni: 0.30% or less)
Ni is an element that improves the corrosion resistance in an acidic environment. When Cu is contained, Ni exhibits the effect of increasing productivity. Cu has a great effect of improving corrosion resistance, but is easily segregated, and if contained alone, it may promote cracking after casting. On the other hand, Ni has the effect | action which reduces the segregation of Cu. When Ni is contained, in addition to suppressing cracking of the slab due to Cu segregation, the occurrence of local corrosion due to segregation is also suppressed, so that the effect of improving corrosion resistance is remarkably exhibited. Preferably, the Ni content is 0.01% or more, more preferably 0.05% or more, and still more preferably 0.10% or more. On the other hand, since Ni is also an expensive element, the Ni content is set to 0.30% or less from the viewpoint of cost. More preferably, it is 0.25% or less.

(As: 0.30% or less)
As is less effective than Sb and Sn, but As is an element effective for improving the corrosion resistance in an acidic environment, 0.01% or more may be contained. More preferably, the As amount is 0.02% or more, and still more preferably the As amount is 0.05% or more. On the other hand, if As is contained excessively, the hot workability deteriorates, so the As amount is made 0.30% or less. More preferably, the amount of As is 0.20% or less, and still more preferably 0.10% or less.

(Co: 0.30% or less)
Co is less effective than Sb and Sn, but is an element that improves the corrosion resistance in an acidic environment, and may be contained in an amount of 0.01% or more. More preferably, the Co content is 0.02% or more, and still more preferably the Co content is 0.05% or more. On the other hand, if Co is excessively contained, the economy is lowered, so the Co content is made 0.30% or less. More preferably, the Co content is 0.20% or less, and still more preferably 0.10% or less.

  Furthermore, in order to improve a mechanical characteristic etc., you may contain 1 type, or 2 or more types selected from the group which consists of Cr, Ti, Nb, V, Zr, Ta, and B. In addition, since these elements are not necessarily essential in the steel material, the lower limit of the content is set to 0%.

(Cr: 0.70% or less)
Cr is an element that improves hardenability and improves strength, and may be contained in an amount of 0.01% or more. More preferably, the Cr amount is 0.05% or more. Moreover, although Cr is an element which improves weather resistance, it may reduce corrosion resistance in an acidic environment, and the Cr content is 0.70% or less. More preferably, the Cr content is 0.50% or less, and further preferably 0.40% or less.

(Ti: 0.050% or less)
Ti is an element that forms a nitride and contributes to refinement of crystal grains and improvement of strength, and may be contained by 0.001% or more. More preferably, the Ti amount is 0.005% or more. On the other hand, if more than 0.050% Ti is contained, the nitride becomes coarse and the mechanical properties may be deteriorated, so the Ti amount is made 0.050% or less. More preferably, the Ti amount is 0.040% or less, further preferably 0.030% or less, and still more preferably 0.020% or less. And

(Nb: 0.10% or less)
Nb, like Ti, is an element that forms a nitride, and may be contained in an amount of 0.001% or more for the purpose of refining crystal grains and improving strength. More preferably, the Nb amount is 0.005% or more. On the other hand, if more than 0.10% of Nb is contained, the mechanical properties may be deteriorated, so the Nb amount is made 0.10% or less. More preferably, the Nb amount is 0.050% or less, further preferably 0.030% or less, and still more preferably 0.020% or less.

(V: 0.10% or less)
V, like Ti and Nb, is an element that forms a nitride, and may be contained mainly for improving the strength by precipitation strengthening. In order to obtain the effect, the V amount is preferably set to 0.005% or more. On the other hand, if more than 0.10% of V is contained, mechanical properties may be deteriorated, so the V amount is made 0.10% or less. More preferably, the V amount is 0.050% or less, further preferably 0.030% or less, and still more preferably 0.020% or less.

(Zr: 0.050% or less)
Zr is an element that forms a nitride, like Ti, Nb, and V, and may be contained mainly for the purpose of improving the strength by precipitation strengthening. In order to obtain the effect, the Zr content is preferably 0.005% or more. On the other hand, Zr is an expensive element. If more than 0.050% of Zr is contained, mechanical properties may be deteriorated, so the amount of Zr is made 0.050% or less. More preferably, the Zr content is 0.040% or less, further preferably 0.030% or less, and still more preferably 0.020% or less.

(Ta: 0.050% or less)
Ta is an element that contributes to the improvement of strength, and may be contained by 0.001% or more. Further, although the mechanism is not necessarily clear, Ta contributes to the improvement of corrosion resistance, and more preferably the Ta amount is 0.005% or more. On the other hand, if Ta is contained excessively, the cost increases, so the Ta amount is made 0.050% or less. More preferably, the amount of Ta is 0.040% or less, still more preferably 0.030% or less, and still more preferably 0.020% or less.

(B: 0.010% or less)
B is an element that improves hardenability and increases strength. In order to obtain the effect, the B content is preferably 0.0003% or more. More preferably, the B amount is 0.0005% or more. On the other hand, even if containing B exceeding 0.010%, the effect is saturated, and the toughness of the base material and HAZ may be lowered, and the B content is made 0.010% or less. More preferably, the B content is 0.0050% or less, further preferably 0.0030% or less, and still more preferably 0.0020% or less.

  Furthermore, you may contain 1 or more types selected from the group which consists of Mg and REM for the purpose of deoxidation and control of inclusions. In addition, since these elements are not necessarily essential in the steel material, the lower limit of the content is set to 0%.

(Mg: 0.010% or less)
Mg may be contained in an amount of 0.0001% or more in order to form a fine oxide. Preferably, the Mg content is 0.0003% or more, more preferably 0.0005% or more. On the other hand, from the viewpoint of manufacturing cost, the Mg amount is set to 0.010% or less. More preferably, the amount of Mg is 0.005% or less, and further preferably 0.003% or less.

(REM: 0.010% or less)
REM (rare earth element) is an element mainly used for deoxidation, and may contain 0.0001% or more in order to form a fine oxide. Preferably, the REM amount is 0.0003% or more, more preferably 0.0005% or more. On the other hand, from the viewpoint of manufacturing cost, the REM amount is set to 0.010% or less. More preferably, the amount of REM is 0.005% or less, and still more preferably 0.003% or less.

  The balance of the chemical components of the steel material according to the present embodiment is iron (Fe) and impurities. Impurities are components that are mixed due to raw materials such as ore and scrap and other factors when industrially manufacturing steel materials, and are allowed within a range that does not adversely affect the steel materials according to this embodiment. To do. However, it is necessary to limit the upper limit of P and S among impurities as described above.

  In order to improve acid resistance, hot workability, and weldability, the steel material according to the present embodiment needs to satisfy the relationship between specific elements.

(Ca / O: 1.00 or less)
The mass ratio (Ca / O) between the Ca content and the O content is an index for suppressing oxides that are likely to be corrosion starting points on the steel material surface. Ca increases the cleanliness of steel by forming fine oxides that do not affect acid resistance, but excessive inclusion of Ca with respect to the amount of O in the steel produces excessive coarse oxides. And reduce acid resistance. In order to suppress the formation of excessive coarse oxide, Ca / O needs to be 1.00 or less. Therefore, Ca / O is set to 1.00 or less. Preferably it is 0.90 or less, More preferably, it is 0.85 or less, More preferably, it is 0.83 or less. The lower limit of Ca / O is not particularly limited. However, if Ca / O is too low, the formation of oxides other than Ca is generated and the acid resistance is lowered. .010 or more, more preferably 0.015 or more.

(Cu + Sb: 0.05-0.25%)
The combined addition of Cu and Sb improves the acid resistance of the steel, but for that purpose the total amount of Cu and Sb must be 0.05% or more. A preferable lower limit of the total amount of Cu and Sb is 0.055% or more, a more preferable upper limit is 0.057% or more, and a still more preferable upper limit is 0.06% or more. On the other hand, if the total amount of Cu and Sb is too large, the hot workability deteriorates, so the total amount of Cu and Sb needs to be 0.25% or less. A preferable upper limit of the total of Cu and Sb is 0.22% or less, and a more preferable upper limit is 0.2% or less.

(Ceq: 0.180 to 0.330)
Ceq is an index indicating the deterioration of weldability due to an increase in hardness, and is 0.330 or less, preferably 0.300 or less, in order to ensure weldability. on the other hand. If Ceq is too low, the mechanical properties become insufficient, so 0.180 or more, preferably 0.190 or more, more preferably 0.200 or more. Ceq is a known index as shown in the following formula (3).
Ceq = C + Mn / 6 + (Cu + Ni) / 5 + (Cr + Mo + V) / 15 Formula (1)
In the formula (1), C, Mn, Cu, Mo, Ni, Cr, and V indicate contents based on mass% of each element, and 0 when not contained.

  A method for manufacturing a steel material according to the present embodiment will be described. The steel materials according to the present embodiment include steel plates, shaped steels, steel pipes, and the like that are manufactured by hot rolling and further cold rolling as necessary. It is preferably a thick steel plate having a plate thickness of 3 mm or more, more preferably 6 mm or more.

  The steel material according to the present embodiment is manufactured by melting steel by a conventional method, adjusting the components, hot rolling a steel piece obtained by casting, and further performing cold rolling as necessary. . After hot rolling, it may be cooled with water as it is, or air-cooled and then reheated and quenched. After hot rolling, it may be wound into a coil. After hot rolling, it may be cold-rolled and further heat-treated.

  When manufacturing a steel pipe, a steel plate may be formed into a tubular shape and welded, and may be a UO steel pipe, an electric resistance steel pipe, a forged steel pipe, a spiral steel pipe, or the like. A seamless steel pipe manufactured by subjecting a steel piece to hot extrusion or piercing and rolling is also included in this embodiment.

  The technical contents of the present invention will be further described below with reference to examples of the present invention. In addition, the conditions in the Example shown below are one example of conditions adopted in order to confirm the feasibility and effect of the present invention, and the present invention is not limited to this one condition example. The present invention can employ various conditions as long as the object of the present invention is achieved without departing from the gist of the present invention.

  Steels having the components shown in Tables 1 and 2 were melted, and the steel ingot was heated at 1150 ° C. for 2 hours, followed by hot rolling and air cooling to produce a steel plate having a thickness of 20 mm. In addition, the remainder of the component of each steel shown in Table 1 and Table 2 is Fe and inevitable impurities.

A test piece of 25 × 25 × 4 mmt was collected from the steel plate central portion from the obtained steel plate, finished by wet # 400 polishing, and used as a test piece for corrosion resistance evaluation. The corrosion resistance was evaluated by a sulfuric acid immersion test and a hydrochloric acid immersion test.
1) Soaked in 50% sulfuric acid aqueous solution at 70 ° C for 6 hours 2) Soaked in 10.5% aqueous hydrochloric acid solution at 40 ° C for 6 hours

  Corrosion rate was calculated from the weight change before and after the test, respectively, with the corrosion resistance improved by 30% or more (corrosion weight loss was reduced to 70% or less of Comparative Example AA) based on Example AA, and the corrosion resistance was 50% or more. Those with improved (corrosion weight loss decreased to 50% or less of Comparative Example AA) were marked with ◎, and those with less than 30% (corrosion weight loss over 70% of Comparative Example AA) were marked with ×. Further, the hot workability was determined by visually observing the appearance on the surface of the hot rolled material rolled under the above conditions.

  Further, as a weld crack evaluation, a y-type weld crack test was performed based on JIS Z 3158. The test piece was 16 mmt, and after welding from both sides with a current of 170 A, the presence or absence of cracks in the surface and cross section was confirmed after a predetermined time had elapsed. In addition, a tensile test piece was prepared in accordance with JIS Z 2241, and a tensile test was performed to obtain a tensile strength. Those with a yield strength of 230 MPa or more were rated as “◯”, and those with a yield strength of less than 230 MPa as “x”. The results are shown in Table 3.

  As shown in Table 3, steel no. A to Z are components, Ca / O ratio, total content of Cu and Sb, Ceq is within the scope of the present invention, corrosion resistance to hydrochloric acid and sulfuric acid, hot workability, weldability, strength (tensile strength) All are good. On the other hand, Steel No. AA to AJ are components, Ca / O ratio, Cu content, Sb content, total Cu and Sb content, and any of Ceq is outside the scope of the present invention. Corrosion resistance to hydrochloric acid and sulfuric acid, heat Interworkability, weldability, and strength are reduced.

Steel No. Although AA is a steel used as a reference for evaluation of hydrochloric acid corrosion test and sulfuric acid corrosion test, it does not contain Ca, and therefore has lower corrosion resistance to hydrochloric acid and sulfuric acid than steel of the present invention.
Steel No. with a Ca / O ratio out of range. Steel No. with less AB and Cu. Steel No. with less AC and Sb Steel No. with small total of AD, Cu amount and Sb amount. AE also has lower corrosion resistance to hydrochloric acid and sulfuric acid than the steel of the present invention. Steel No. Since AF has a large sum of Cu and Sb, workability is reduced. Steel No. with a large Ceq. AG has poor weldability. On the other hand, Steel No. AH has a low Ceq and is insufficient in strength.

  As mentioned above, although preferred embodiment of this invention was described in detail, this invention is not limited to this example. It is obvious that a person having ordinary knowledge in the technical field to which the present invention belongs can come up with various changes or modifications within the scope of the technical idea described in the claims. Of course, it is understood that these also belong to the technical scope of the present invention.

The steel material of the present invention is a boiler that burns fossil fuels such as heavy oil and coal, gas fuel such as liquefied natural gas, general waste such as municipal waste, industrial waste such as waste oil, plastic and exhaust tires, and sewage sludge. Can be used for smoke exhaust equipment. Specifically, gas-gas heaters, desulfurizers, electrostatic precipitators, induction blowers composed of flue ducts, casings, heat exchangers, and two heat exchangers (heat recovery and reheaters) It can be suitably used for a basket material and a heat transfer element plate of a rotary regenerative air preheater.

Claims (4)

% By mass
C: 0.01-0.10%,
Si: 0.04 to 0.40%,
Mn: 0.60 to 1.50%,
Cu: 0.02 to 0.24%,
Sb: 0.01 to 0.23%,
Al: 0.005 to 0.050%,
Sn: 0.001 to 0.200%,
Ca: 0.00005 to 0.010%,
One or both of Mo and W in total, 0.01 to 0.30%,
P: 0 to 0.020%,
S: 0 to 0.015%,
N: 0 to 0.005%, and O: 0.0005 to 0.0035%
And the balance consists of Fe and impurities,
The mass ratio of Ca content to O content (Ca / O) is 1.00 or less,
The total amount of Cu and Sb is 0.05% to 0.25% in mass%,
Ceq calculated | required by following formula (1) is 0.180-0.330, The steel materials characterized by the above-mentioned.
Ceq = C + Mn / 6 + (Cu + Ni) / 5 + (Cr + Mo + V) / 15 Formula (1)
Here, in the formula (1), C, Mn, Cu, Mo, Ni, Cr, and V are contents based on mass% of each element, and 0 when not contained. Furthermore, in mass%,
Ni: 0.30% or less,
The steel material according to claim 1, comprising one or more selected from the group consisting of As: 0.30% or less and Co: 0.30% or less. Furthermore, in mass%,
Cr: 0.70% or less,
Ti: 0.050% or less,
Nb: 0.10% or less,
V: 0.10% or less,
Zr: 0.050% or less,
The steel material according to claim 1 or 2, comprising one or more selected from the group consisting of Ta: 0.050% or less and B: 0.010% or less. Furthermore, in mass%,
The steel material according to any one of claims 1 to 3, comprising one or more selected from the group consisting of Mg: 0.010% or less and REM: 0.010% or less.